CN109628242A - A kind of mildly stable Soap-base facial cleanser and preparation method thereof - Google Patents
A kind of mildly stable Soap-base facial cleanser and preparation method thereof Download PDFInfo
- Publication number
- CN109628242A CN109628242A CN201811603306.0A CN201811603306A CN109628242A CN 109628242 A CN109628242 A CN 109628242A CN 201811603306 A CN201811603306 A CN 201811603306A CN 109628242 A CN109628242 A CN 109628242A
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- CN
- China
- Prior art keywords
- facial cleanser
- soap
- base facial
- mildly
- starch
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/005—Preparations for sensitive skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Abstract
The invention belongs to daily chemicals fields, and in particular to a kind of mildly stable Soap-base facial cleanser and preparation method thereof.The Soap-base facial cleanser is made of fatty acid, polyalcohol, potassium hydroxide, emulsifier, polyquaternium -7, chelating agent, purslane extract, essence, preservative and deionized water, the wherein content of each component are as follows: fatty acid 28%~32%, polyalcohol 20%~30%, potassium hydroxide 5.5%~6.5%, thickening stabilizing agent 2%~4%, amphoteric surfactant 2%~10%, polyquaternium -7 1%~3%, chelating agent 0.05%~0.1%, purslane extract 1%~3%, essence 0.2%~0.3%, preservative 0.1%~0.5%.The present invention other than the foam for having exquisiteness abundant stable, also has deep layer cleaning, mildly not tight and good high-temperature stability feature compared with prior art.
Description
Technical field
The present invention relates to a kind of face cleaning cream, and in particular to a kind of mildly stable Soap-base facial cleanser and preparation method thereof.
Background technique
Soap base type face cleaning cream is using soap base as the mildy wash system of primary vehicle and foaming agent, is that daily use chemicals line is non-in recent years
One of the product that washes one's face of Chang Liuhang, foaming power is good, and foaming abundancy is fine and smooth, and decontamination is clean thorough, is easy to rinse well after, give
The clean salubrious sense of skin, in addition its pearly-lustre toothpaste-like appearance seems very noble, the beautiful great kindness for obtaining consumer and producer.
Although the appearance of soap base type face cleaning cream has had many years, Soap-base facial cleanser is because of its manufacturing process and formula
Complexity, domestic Management of Cosmetics Enterprises are deep not enough to the research of such product, grasp not enough thoroughly, according at present in society
On the analysis of domestic enterprise's face cleaning cream product produced that can see, most enterprises face cleaning cream product produced all do not have
There is the performance indicator that can reach same kind of products at abroad, there is also some disadvantages, such as: 1. dry and astringent tight with rear skin；2. height
The stability of temperature is bad, and high temperature is easy layering and is precipitated, and low temperature is easy to be hardened；3. production technology poor reproducibility, production process is easy
Mass problem.
Therefore, it is particularly significant to research and develop a kind of mildly stable Soap-base facial cleanser.
Summary of the invention
In order to solve the problems in the existing technology, the present invention provides a kind of high-temperature stable and it is dry after it is not tight steady
Fixed mild Soap-base facial cleanser；The present invention also provides a kind of preparation method of mild stable Soap-base facial cleanser, this method produces work
Skill is easy to control, and has reproducibility.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of mildly stable Soap-base facial cleanser, is made of the component of following weight percentage: fatty acid 28%~32%,
Polyalcohol 20%~30%, potassium hydroxide 5.5%~6.5%, thickening stabilizing agent 2%~5%, amphoteric surfactant 2%~
10%, polyquaternium -7 1%~3%, chelating agent 0.05%~0.1%, purslane extract 1%~3%, essence 0.1%~
0.3%, preservative 0.1%~0.5%, surplus is water；The thickening stabilizing agent is modified starch.
Further, the fatty acid is at least one of lauric acid, myristic acid, palmitinic acid, stearic acid；Preferably,
The fatty acid is lauric acid, myristic acid, palmitinic acid, stearic combination.
Further, the polyalcohol is glycerol, propylene glycol, 1,3-BDO, PEG-400, sorbierite, glycerin polyether-
At least one of 26；Preferably, the polyalcohol is glycerol, 1,3-BDO, PEG-400.
Further, the modified starch is hydrophilic chemistries modified starch.
Further, the hydrophilic chemistries modified starch is modified potato starch, modified tapioca starch, modified corn
Starch, hydroxypropul starch, hydroxypropyl starch phosphate wherein at least one；Preferably, the hydrophilic chemistries modified starch is
Hydroxypropyl starch phosphate.
Further, the amphoteric surfactant is at least one of glycine betaine, the surfactant of imidazoline.
The glycine betaine is Cocoamidopropyl betaine, lauroylamidopropyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine, the moon
Osmanthus base hydroxy sulfo lycine.The imidazoline is cocoyl both sexes sodium acetate and lauryl both sexes sodium acetate.
Preferably, the amphoteric surfactant is cocamidopropyl propyl amide hydroxy sulfo lycine.
Further, the chelating agent is one of tetra- sodium of EDETATE SODIUM or EDTA.
Further, the preservative is the mixture of one or both of methyl hydroxybenzoate, Nipasol.
Preferably, the preservative is the mixture of methyl hydroxybenzoate and Nipasol, and wherein methyl hydroxybenzoate content is
0.05%~0.3%, Nipasol content is 0.05%~0.2%.
Purslane extract of the invention is from purslane whole plant using obtained by low temperatural extraction.Purslane extract
Class containing alkaloids and Flavonoid substances can be used as anti-irritant, antiallergy functional component applied to cosmetics, and have anti-dry
The effect of dry, increase skin comfort is spent.
The preparation method of above-mentioned mildly stable Soap-base facial cleanser, comprising the following steps:
A. chelating agent, part polyalcohol are added in deionized water, potassium hydroxide are then added, is heated to 70~80 DEG C,
Obtain water phase；
B. fatty acid, methyl hydroxybenzoate, Nipasol are mixed and heated to 70~80 DEG C, obtain oily phase, be mutually pumped into cream for oily
Change in pot；
C. the water phase heated is pumped into emulsion pot, is quickly dispersed with stirring, and 80 DEG C of temperatures above is kept to be saponified 30 points
Clock；
D. the polyalcohol of stable thickener and remaining part is mixed and made into premix, will be pre- after keeping the temperature to step C
What mixture was added enters emulsion pot, stirring, it is ensured that stablizes thickener and is completely dissolved；
Polyquaternium -7, amphoteric surfactant is added when being E. cooled to 55~60 DEG C；
Essence, purslane extract is added when being F. cooled to 40~45 DEG C, stirs evenly, discharging, which obtains, stablizes mildly
Soap-base facial cleanser.
Compared with prior art, the invention has the benefit that
(1) present invention selects appropriate thickening stabilizing agent, has synergy with polyalcohol inside the system of water, occupies water
Volume, and reach the performance of thick stabilization, can suspend unneutralized free-fat in the case where no emulsifier
Acid, therefore the problems such as lotion is thinning, and nozzle is discharged will not occur because of the variation of ambient temperature condition, show product good
Stability.
(2) by the present invention in that with the collocation of amphoteric surfactant and polyquaternium -7, wherein amphoteric surfactant
Be conducive to the dispersion of fatty acid soaps, further promote the foaming properties of face cleaning cream, reduce the irritation of soap, change to rear skin sense is washed
It is apt to beneficial；Polyquaternium -7 can make foam denser due to its cationic, more stable, and bring soft and smooth skin sense, subtract
The tight feeling of few dry rear skin, so that Soap-base facial cleanser of the present invention is with not tight good skin sense not dry after mildly washing.
(3) purslane extract that the present invention selects can have the stimulation of shielding chemical substance, avoid dry skin not tight
It is taut, stimulation of the fragrance to sensitive skin can be also reduced, allergic reaction is reduced.
(4) the preparation method simple process of the Soap-base facial cleanser of offer of the invention, easily operated, material dispersion is uniform,
Production is relatively easy to control, and improves production efficiency, reduces energy consumption.
Specific embodiment
The present invention is further illustrated below in conjunction with specific embodiment, but the present invention is not limited to these implementations
Example.
The formula of Examples 1 to 4 and comparative example 1~4 is shown in Table 1.
The formula table of table 1 Examples 1 to 4 and comparative example 1~4
The preparation method of above-described embodiment and comparative example, comprising the following steps:
A. chelating agent, part polyalcohol are added in deionized water, potassium hydroxide are then added, is heated to 70~80 DEG C,
Obtain water phase；
B. fatty acid, methyl hydroxybenzoate, Nipasol are mixed and heated to 70~80 DEG C, obtain oily phase, be mutually pumped into cream for oily
Change in pot；
C. the water phase heated is pumped into emulsion pot, is quickly dispersed with stirring, and 80 DEG C of temperatures above is kept to be saponified 30 points
Clock；
D. the polyalcohol of stable thickener and remaining part is mixed and made into premix, will be pre- after keeping the temperature to step C
What mixture was added enters emulsion pot, stirring, it is ensured that stablizes thickener and is completely dissolved；
Polyquaternium -7, amphoteric surfactant is added when being E. cooled to 55~60 DEG C；
Essence, purslane extract is added when being F. cooled to 40~45 DEG C, stirs evenly, discharges to obtain the final product.
The use feeling and stability of above embodiments and comparative example are evaluated.
Wherein the use feeling evaluation method is: 80 testers of selection (men and women is impartial, age bracket 15 years old~55 years old), often
A embodiment and comparative example extracts 10 testers respectively and carries out Blind Test to embodiment and comparative example.Each embodiment and comparative example
It is measured in parallel 3 times.Tester evaluates product according to the use feeling of oneself, mainly includes mildness and spreadability.Evaluation
It as a result is the average mark of all tester's scores, average mark more high effect is better.
Application method: hand and face are soaked；Take 0.5 gram of sample in one of wetting on hand, with another hand by sample
Product are spread out, and both hands rubbing blistering is coated in face, gently rub face skin one minute.It is finally cleaned up with clear water, allows hand and face
Portion's naturally dry.
Wherein method for estimating stability is: embodiment and comparative example being attached separately in 30mL transparent plastic bottle, is set respectively
In room temperature, in -15 DEG C and 48 DEG C of insulating boxs, it is observed continuously 3 months.Referring to RT sample, to embodiment and comparative example -15
DEG C, 48 DEG C when form variation degree score.Comprehensive score standard uses ten point system, 1 point to be worst, 10 points be it is best,
8 people are selected to score, evaluation result is the average mark of 8 people's comprehensive scores, and higher its height temperature stability of expression of average mark is more
It is good.
The use feeling evaluation result and estimation of stability result of embodiment and comparative example are shown in Table 2 and table 3 respectively.
The use feeling evaluation result table of 2 embodiment of table and comparative example
| Number | Mildness | Spreadability | Foaming abundancy sense | Foam texture | Bath skin sense | Skin sense after dry |
| Embodiment 1 | 9.2 | 9.0 | 9.2 | 9.4 | 9.0 | 9.0 |
| Embodiment 2 | 9.3 | 9.4 | 9.7 | 9.8 | 9.5 | 9.6 |
| Embodiment 3 | 9.7 | 8.5 | 8.5 | 8.5 | 8.8 | 8.7 |
| Embodiment 4 | 9.1 | 9.2 | 9.1 | 9.3 | 9.1 | 9.0 |
| Comparative example 1 | 8.6 | 8.1 | 8.0 | 8.1 | 7.2 | 7.2 |
| Comparative example 2 | 8.3 | 8.5 | 8.0 | 8.5 | 8.6 | 7.1 |
| Comparative example 3 | 7.7 | 7.6 | 7.0 | 7.7 | 6.8 | 6.5 |
| Comparative example 4 | 7.3 | 8.2 | 7.9 | 8.3 | 8.0 | 7.1 |
The estimation of stability result table of 3 embodiment of table and comparative example
It, can be with from table 1, table 2 as can be seen that the present invention selects hydroxypropyl starch phosphate that the stability of soap base can be improved
Improve the stability of foam；The embodiment of the present invention product is mild, and the spreadability having had, and foaming abundancy, texture are good.
The foregoing is merely better embodiments of the invention, and the invention is not limited to above embodiment, are implementing
The structural modification small there may be part in the process, if various changes or modifications of the invention are not departed from essence of the invention
Mind and range, and belong within the scope of claim and equivalent technologies of the invention, then the present invention is also intended to encompass these changes
And modification.
Claims (10)
1. a kind of mildly stable Soap-base facial cleanser, which is characterized in that be made of the component of following weight percentage: fatty acid
28%~32%, polyalcohol 20%~30%, potassium hydroxide 5.5%~6.5%, thickening stabilizing agent 2%~5%, amphoteric surface
Activating agent 2%~10%, polyquaternium -7 1%~3%, chelating agent 0.05%~0.1%, purslane extract 1%~3%,
Essence 0.1%~0.3%, preservative 0.1%~0.5%, surplus are water；The thickening stabilizing agent is modified starch.
2. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the fatty acid is laurel
At least one of acid, myristic acid, palmitinic acid, stearic acid.
3. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the polyalcohol is sweet
At least one of oil, propylene glycol, 1,3-BDO, PEG-400, sorbierite, glycerin polyether -26.
4. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the modified starch is parent
Aqueous chemical modified starch.
5. a kind of mildly stable Soap-base facial cleanser according to claim 4, which is characterized in that the hydrophilic chemistries change
Property starch be modified potato starch, modified tapioca starch, modified corn starch, hydroxypropul starch, hydroxypropyl starch phosphate
Wherein at least one.
6. a kind of mildly stable Soap-base facial cleanser according to claim 5, which is characterized in that the hydrophilic chemistries change
Property starch be hydroxypropyl starch phosphate.
7. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the amphoteric surface
Activating agent is at least one of glycine betaine, the surfactant of imidazoline.
8. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the chelating agent is EDTA
One of tetra- sodium of disodium or EDTA.
9. a kind of mildly stable Soap-base facial cleanser according to claim 1, which is characterized in that the preservative is oxybenzene
The mixture of one or both of methyl esters, Nipasol.
10. a kind of preparation method of the mildly stable Soap-base facial cleanser as described in any item of claim 1~9, special
Sign is, comprising the following steps:
A. chelating agent, part polyalcohol are added in deionized water, potassium hydroxide is then added, is heated to 70~80 DEG C, obtains
Water phase；
B. fatty acid, methyl hydroxybenzoate, Nipasol are mixed and heated to 70~80 DEG C, obtain oily phase, be mutually pumped into emulsion pot for oily
In；
C. the water phase heated is pumped into emulsion pot, is quickly dispersed with stirring, and 80 DEG C of temperatures above is kept to be saponified 30 minutes；
D. the polyalcohol of stable thickener and remaining part is mixed and made into premix, after keeping the temperature to step C, will be pre-mixed
What object was added enters emulsion pot, stirring, it is ensured that stablizes thickener and is completely dissolved；
Polyquaternium -7, amphoteric surfactant is added when being E. cooled to 55~60 DEG C；
Essence, purslane extract is added when being F. cooled to 40~45 DEG C, stirs evenly, discharging, which obtains, stablizes mild soap base
Face cleaning cream.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811603306.0A CN109628242B (en) | 2018-12-26 | 2018-12-26 | Mild and stable soap-based facial cleanser and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811603306.0A CN109628242B (en) | 2018-12-26 | 2018-12-26 | Mild and stable soap-based facial cleanser and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109628242A true CN109628242A (en) | 2019-04-16 |
| CN109628242B CN109628242B (en) | 2020-11-13 |
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| CN201811603306.0A Active CN109628242B (en) | 2018-12-26 | 2018-12-26 | Mild and stable soap-based facial cleanser and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111617005A (en) * | 2020-06-30 | 2020-09-04 | 广州市瑞芬化妆品有限公司 | High-foam fine soap-based mixed facial cleanser and preparation method thereof |
| CN113845984A (en) * | 2021-11-04 | 2021-12-28 | 天津郁美净集团有限公司 | Mild and stable soap-based cleansing cream and preparation process thereof |
| CN114099382A (en) * | 2021-11-22 | 2022-03-01 | 福建片仔癀化妆品有限公司 | Soap-based facial cleanser and preparation method thereof |
| CN115040426A (en) * | 2022-06-10 | 2022-09-13 | 广东嘉丹婷日用品有限公司 | Skin cleaning composition based on soap-based system |
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| CN103126911A (en) * | 2011-11-30 | 2013-06-05 | 南京华狮化工有限公司 | Mild soap base cleansing cream composition and production process thereof |
| CN107260579A (en) * | 2017-08-08 | 2017-10-20 | 广州蜜妆生物科技有限公司 | A kind of gentle face cleaning bubble and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103126911A (en) * | 2011-11-30 | 2013-06-05 | 南京华狮化工有限公司 | Mild soap base cleansing cream composition and production process thereof |
| CN107260579A (en) * | 2017-08-08 | 2017-10-20 | 广州蜜妆生物科技有限公司 | A kind of gentle face cleaning bubble and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111617005A (en) * | 2020-06-30 | 2020-09-04 | 广州市瑞芬化妆品有限公司 | High-foam fine soap-based mixed facial cleanser and preparation method thereof |
| CN113845984A (en) * | 2021-11-04 | 2021-12-28 | 天津郁美净集团有限公司 | Mild and stable soap-based cleansing cream and preparation process thereof |
| CN114099382A (en) * | 2021-11-22 | 2022-03-01 | 福建片仔癀化妆品有限公司 | Soap-based facial cleanser and preparation method thereof |
| CN114099382B (en) * | 2021-11-22 | 2024-03-12 | 福建片仔癀化妆品有限公司 | Soap-based facial cleanser and preparation method thereof |
| CN115040426A (en) * | 2022-06-10 | 2022-09-13 | 广东嘉丹婷日用品有限公司 | Skin cleaning composition based on soap-based system |
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