CN109464300A - Foam mildy wash and preparation method thereof after one kind - Google Patents
Foam mildy wash and preparation method thereof after one kind Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/046—Aerosols; Foams
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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Abstract
The invention belongs to cosmetic technical fields, and in particular to foam mildy wash and preparation method thereof after a kind of.Foam mildy wash after described, the ingredient including following mass fraction: surfactant 10~20%, vaseline 15~20%, propylene glycol 5~10%, triethanolamine 1~2.5%, acrylic copolymer 6~14%, rear foaming agent 3~6%, hydroxyethyl cellulose 0.1~0.5%, parahydroxyacet-ophenone 0.3~0.7%, essence 0.1~0.5%, nitrogen 0.1~1% and water 35~45%.The mildy wash that foams after the present invention without rubbing can form that foam, foam stability are good, easy to use, small to skin irritation, cleaning capacity is good and with good performance of keeping humidity.
Description
Technical field
The invention belongs to cosmetic technical fields, and in particular to foam mildy wash and preparation method thereof after a kind of.
Background technique
Face cleaning product currently on the market can be divided into soap base type mildy wash and non-soap base surface-active according to formula and performance
Agent mildy wash two types, wherein soap base type mildy wash due to alkalinity it is higher, easily make to have dry skin, therefore to the irritation of skin
It is larger, rather than soap base surfactant mildy wash is the face cleaning product that active constituent is wanted based on non-soap based surfactants, property
Can be mild, cleaning force is good, and mild performance and functional characteristic are different with the type and proportion of surfactant.This
Outside, current face cleaning milk product needs to form foam after rubbing mostly, can just dissolve the extra grease of skin surface, clearly
Clean skin simultaneously removes color make-up, and still, during rubbing, the problem of can not being not only kneaded there is part, but also strength is rubbed
Wiping may result in skin injury infection, and often this is previous, can cause to damage to the cuticula of skin, to cause sensitive flesh.Cause
This, can form foam, to the more mild good mildy wash of cleaning force simultaneously of skin without rubbing there is an urgent need to a kind of.
108618985 A of Chinese patent literature CN discloses foaming moisturizing face cleaning gel after one kind, and the face cleaning gel is by A
Component and B component mix, and wherein component A by forming following weight percentage components: surfactant 5~15%, rouge
Fat acid 5~16%, polyalcohol 10~25%, polyhydric alcohol amine 5~13%, hydroxypropyl cellulose 0.01~0.5%, guar gum 0.05
~0.6%, chelating agent 0.05~1%, auxiliary agent 0.05~1%, flavors and fragrances 0.001~0.5% and water surplus, B component are carbon
Atomicity is not more than 5 one or more of alkane, and under the body temperature effect of human body, natural foaming forms clean the face cleaning gel
Papula foam, to play the role of clean, but the surfactant in the face cleaning gel has biggish stimulation to human skin
Property.107536773 A of Chinese patent literature CN discloses the production technology of foaming face cleaning gel after one kind, the face cleaning gel packet
Include following component: pure water, saponification agent, foaming agent, alkyl polyglycoside, laureth, thickener, moisturizer, skin-care agent,
Other components, which can form foam, easy to use without rubbing, but the saponification agent ingredient wherein contained is to skin
Certain irritation is had, long-time service can make to have dry skin.
Accordingly, it is desirable to provide a kind of can form foam, easy to use, small to skin irritation, cleaning energy without rubbing
Power is good and has the rear foaming mildy wash and preparation method thereof of good performance of keeping humidity.
Summary of the invention
The present invention is directed to overcome the deficiencies of the prior art and provide the mildy wash and preparation method thereof that foams after one kind, this is clean
Face cream without rubbing can form that foam, foam stability are good, easy to use, small to skin irritation, cleaning capacity is good and
With good performance of keeping humidity.
In order to achieve the goal above, technical scheme is as follows:
Foam mildy wash after one kind, the ingredient including following mass fraction: surfactant 10~20%, vaseline 15~
20%, propylene glycol 5~10%, triethanolamine 1~2.5%, acrylic copolymer 6~14%, rear foaming agent 3~6%, ethoxy
Cellulose 0.1~0.5%, parahydroxyacet-ophenone 0.3~0.7%, essence 0.1~0.5%, nitrogen 0.1~1% and water 35~
45%.
Further, the rear mildy wash that foams, the ingredient including following mass fraction: surfactant 16%, all scholars
Woods 17%, propylene glycol 8%, triethanolamine 2%, acrylic copolymer 10%, rear foaming agent 5%, hydroxyethyl cellulose 0.4%,
Parahydroxyacet-ophenone 0.5%, essence 0.4%, nitrogen 0.7% and water 40%.
Further, the surfactant be cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate,
The mass ratio of the cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is 1:(0.1~0.3): (0.02~
0.05)。
Further, the mass ratio of the cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is
1:0.2:0.04.
Further, the rear foaming agent is trans- 1- chloro-3,3,3 ,-trifluoropropene.
The preparation method of foaming mildy wash after above-mentioned, comprising the following steps:
S1, mixed liquor A is made after propylene glycol and hydroxyethyl cellulose mixing are uniformly dispersed according to formula ratio；
S2, the water of formula ratio is added in reaction kettle, and the mixed liquor A being added in the step S1 is heated to while stirring
80~85 DEG C, 15~25min of stirring is complete to dissolution of raw material, and mixed liquid B is made；
S3, according to formula ratio, vaseline, surfactant, parahydroxyacet-ophenone, acrylic copolymer are sequentially added into institute
In the mixed liquid B for stating step S2, is dissolved completely after stirring 15~25min, mixed liquor C is made；
S4, the mixed liquor C is cooled to 55~65 DEG C, the essence of formula ratio is added, is then cooled to 43~45 DEG C, after
It is continuous that triethanolamine is added, be stirring evenly and then adding into rear foaming agent, continue to be filled with after mixing after 15~25min of stirring nitrogen into
Row sealing, foam mildy wash after being made.
In the inventive solutions, the main component cocounut oil acyl isethionic acid ester sodium of surfactant be it is a kind of yin from
Sub- surfactant, have good biological degradability, cloud point is low, resistance to hard water is strong, foaming characteristic is good and stabilization and with
Other surfactants have good concertedness, therefore are widely used in personal cleansing skincare product.Cocounut oil acyl isethionic acid
Ester sodium and the other two kinds of Surfactants Alkyls of the present invention and ammonium lauryl sulfate compatibility, and inventor is by groping
Its suitable proportion is 1:(0.1~0.3): (0.02~0.05), within this range, three's synergistic effect has face skin
There is good cleaning function, it is mild nonirritant.
In addition, trans- 1- chloro-3,3,3 ,-trifluoropropene is as a kind of rear foaming agent, normal body temperature of the boiling point relative to human body
It is lower, have the advantages that zero odp and extremely low GWP value, human body normal body temperature effect under, can natural foaming at face cleaning
Foam still if its additive amount and other cleansing ratios are not suitable for, can destroy the normal moisture-keeping functions of skin instead, because
The invention people is by groping the compound proportion of itself and other active constituent surfactants of the invention, and the mildy wash of preparation is neither
Water adipose membrane etc. of skin holding can be destroyed normally containing the structure of lipid component, at the same be capable of spontaneous generation enrich fine and smooth foam and
Foam stability is good, the moisture-keeping functions with good cleaning skin and maintenance skin.
Therefore, compared with prior art, the invention has the following advantages:
(1) present invention is using cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate as surface-active
Agent, three's synergistic effect, ratio is reasonable, has good cleaning function for face skin, mild nonirritant.
(2) for the present invention using trans- 1- chloro-3,3,3 ,-trifluoropropene as rear foaming agent, the mildy wash of preparation can be without
Rubbing can natural foaming it is good at the foam and foam stability of abundant exquisiteness, and with other cleaning constituents mixing ratios
It is suitable for water adipose membrane that will not destroy skin holding etc. normally containing the structure of lipid component, while there is good skin moisture-keeping
Function.
Specific embodiment
The following describes the present invention further through the description of specific embodiments, but it is to limit of the invention that this, which is not,
System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this
The basic thought of invention, it is within the scope of the present invention.
The mildy wash and preparation method thereof to foam after embodiment 1, the present invention
Foam mildy wash after the embodiment of the present invention 1, by following quality at being grouped as: surfactant 10kg, vaseline
The chloro- 3,3,3- trifluoro propene 4kg of 20kg, propylene glycol 10kg, triethanolamine 1kg, acrylic copolymer 9kg, trans- 1-, ethoxy
Cellulose 0.1kg, parahydroxyacet-ophenone 0.3kg, essence 0.1kg, nitrogen 0.5kg and water 45kg.
The surfactant is cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate, the cocounut oil
The mass ratio of acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is 1:0.1:0.02.
The preparation method of foaming mildy wash after described, comprising the following steps:
S1, mixed liquor A is made after propylene glycol and hydroxyethyl cellulose mixing are uniformly dispersed according to formula ratio；
S2, the water of formula ratio is added in reaction kettle, and the mixed liquor A being added in the step S1 is heated to while stirring
80~85 DEG C, 15~25min of stirring is complete to dissolution of raw material, and mixed liquid B is made；
S3, according to formula ratio, vaseline, surfactant, parahydroxyacet-ophenone, acrylic copolymer are sequentially added into institute
In the mixed liquid B for stating step S2, is dissolved completely after stirring 15~25min, mixed liquor C is made；
S4, the mixed liquor C is cooled to 55~65 DEG C, the essence of formula ratio is added, is then cooled to 43~45 DEG C, after
It is continuous that triethanolamine is added, it is stirring evenly and then adding into trans- 1- chloro-3,3,3 ,-trifluoropropene, is mixed after continuing 15~25min of stirring
It is filled with nitrogen after uniformly to be sealed, foam mildy wash after being made.
The mildy wash and preparation method thereof to foam after embodiment 2, the present invention
Foam mildy wash after the embodiment of the present invention 2, by following quality at being grouped as: surfactant 16kg, vaseline
The chloro- 3,3,3- trifluoro propene 5kg of 17kg, propylene glycol 8kg, triethanolamine 2kg, acrylic copolymer 10kg, trans- 1-, ethoxy
Cellulose 0.4kg, parahydroxyacet-ophenone 0.5kg, essence 0.4kg, nitrogen 0.7kg and water 40kg.
The surfactant is cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate, the cocounut oil
The mass ratio of acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is 1:0.2:0.04.
The preparation method of foaming mildy wash after described, comprising the following steps:
S1, mixed liquor A is made after propylene glycol and hydroxyethyl cellulose mixing are uniformly dispersed according to formula ratio；
S2, the water of formula ratio is added in reaction kettle, and the mixed liquor A being added in the step S1 is heated to while stirring
80~85 DEG C, 15~25min of stirring is complete to dissolution of raw material, and mixed liquid B is made；
S3, according to formula ratio, vaseline, surfactant, parahydroxyacet-ophenone, acrylic copolymer are sequentially added into institute
In the mixed liquid B for stating step S2, is dissolved completely after stirring 15~25min, mixed liquor C is made；
S4, the mixed liquor C is cooled to 55~65 DEG C, the essence of formula ratio is added, is then cooled to 43~45 DEG C, after
It is continuous that triethanolamine is added, it is stirring evenly and then adding into trans- 1- chloro-3,3,3 ,-trifluoropropene, is mixed after continuing 15~25min of stirring
It is filled with nitrogen after uniformly to be sealed, foam mildy wash after being made.
The mildy wash and preparation method thereof to foam after embodiment 3, the present invention
Foam mildy wash after the embodiment of the present invention 3, by following quality at being grouped as: surfactant 20kg, vaseline
The chloro- 3,3,3- trifluoro propene 6kg of 15kg, propylene glycol 5kg, triethanolamine 2.5kg, acrylic copolymer 6kg, trans- 1-, hydroxyl second
Base cellulose 0.5kg, parahydroxyacet-ophenone 0.7kg, essence 0.5kg, nitrogen 1kg and water 42.8kg.
The surfactant is cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate, the cocounut oil
The mass ratio of acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is 1:0.3:0.05.
The preparation method of foaming mildy wash after described, comprising the following steps:
S1, mixed liquor A is made after propylene glycol and hydroxyethyl cellulose mixing are uniformly dispersed according to formula ratio；
S2, the water of formula ratio is added in reaction kettle, and the mixed liquor A being added in the step S1 is heated to while stirring
80~85 DEG C, 15~25min of stirring is complete to dissolution of raw material, and mixed liquid B is made；
S3, according to formula ratio, vaseline, surfactant, parahydroxyacet-ophenone, acrylic copolymer are sequentially added into institute
In the mixed liquid B for stating step S2, is dissolved completely after stirring 15~25min, mixed liquor C is made；
S4, the mixed liquor C is cooled to 55~65 DEG C, the essence of formula ratio is added, is then cooled to 43~45 DEG C, after
It is continuous that triethanolamine is added, it is stirring evenly and then adding into trans- 1- chloro-3,3,3 ,-trifluoropropene, is mixed after continuing 15~25min of stirring
It is filled with nitrogen after uniformly to be sealed, foam mildy wash after being made.
Comparative example 1
Compared with Example 2, the difference of this comparative example is only that: the surfactant is cocounut oil acyl isethionic acid ester sodium
And alkyl glycosides, the constant rate of the two.
Comparative example 2
Compared with Example 2, the difference of this comparative example is only that: the cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and
The mass ratio of ammonium lauryl sulfate is 1:0.5:0.1.
Comparative example 3
Compared with Example 2, the difference of this comparative example is only that: the additive amount of surfactant is 16kg, and trans- 1- is chloro-
The additive amount of 3,3,3- trifluoro propene is 8kg.
Comparative example 4
Compared with Example 2, the difference of this comparative example is only that: the additive amount of surfactant is 22kg, and trans- 1- is chloro-
The additive amount of 3,3,3- trifluoro propene is 5kg.
Comparative example 5
Compared with Example 2, the difference of this comparative example is only that: replacing dodecyl sulphate using lauryl sodium sulfate
Ammonium.
Comparative example 6
Compared with Example 2, the difference of this comparative example is only that: replacing cocounut oil acyl using sodium cocoyl methyl sodium taurocholate
Isethionic acid ester sodium.
The performance test of test example one, rear foaming mildy wash
1, test material: rear foaming mildy wash prepared by Examples 1 to 3 and comparative example 1~4；
2, test crowd: healthy skin subject 140, women the age 20~40 years old, is randomly divided into 7 groups, every group 20
People；
3, test method: every group of subject selectes within the scope of inboard arm 5cm × 6cm healthy skin, uniform application area
For the eyebrow pencil and lipstick of 3cm × 1cm, then tested region is soaked with water and smears diameter respectively as 0.5~0.8cm implementation
Rear foaming mildy wash prepared by example 1~3 and comparative example 1~4, observes foam production, and is rinsed and done with flowing water after 20s
Only, it records respectively from foamed time, foam situation, rinse sense, cleaning effect and wash rear skin sense；
4, test result is as shown in table 1.
The performance test results of foaming mildy wash after table 1
(1) You Shangbiao 1 it is found that the mildy wash of the preparation of the embodiment of the present invention 1~3 is short from foamed time, imitate by Yi Chongxi, cleaning
Fruit is obvious and to wash rear skin sense good, moistens not tight, wherein comprehensive performance is best with the most short from foamed time of embodiment 2, is
Highly preferred embodiment of the present invention；
(2) compared with Example 2, surfactant is cocounut oil acyl isethionic acid ester sodium and alkyl glycosides, system in comparative example 1
Standby mildy wash slightly sticks greasy, need to repeatedly rinse well, and cleaning effect is also unobvious, wash rear skin occur it is slight dry and tight；
The mass ratio of 2 cocounut oil acyl isethionic acid ester sodium, alkyl glycosides and ammonium lauryl sulfate is 1:0.5:0.1, preparation in comparative example
Mildy wash slightly stick greasy, need to repeatedly rinse well, cleaning effect is also unobvious, and washing rear skin, moderate occur dry and tight；It is right
The additive amount of surfactant is constant in ratio 3, and the additive amount of trans- 1- chloro-3,3,3 ,-trifluoropropene increases, the face cleaning of preparation
Cream is obviously shortened from foamed time, slightly sticks greasy, need to repeatedly be rinsed well, although cleaning effect is obvious, is washed during rear skin occurs
Degree is dry and tight；The additive amount of surfactant increases in comparative example 4, the additive amount of trans- 1- chloro-3,3,3 ,-trifluoropropene
Constant, the mildy wash of preparation slightly sticks greasy, need to repeatedly rinse well, although cleaning effect is obvious, washing rear skin, moderate occur dry
With it is tight, thus illustrate, surfactant cocounut oil acyl isethionic acid ester sodium of the present invention, alkyl glycosides and ammonium lauryl sulfate are multiple
It is suitable for ratio, while acts synergistically with trans- 1- chloro-3,3,3 ,-trifluoropropene, the mildy wash of preparation is not only from foamed time
It is short, and there is good cleaning function, it is good to wash rear skin sense, moistens not tight.
Test example two, the foam height and foam stability detection of rear foaming mildy wash
1, test material: rear foaming mildy wash prepared by Examples 1 to 3 and comparative example 1~4；
2, test method: the rear foaming mildy wash prepared using 1g Examples 1 to 3 and comparative example 1~4 is added and is added water to
10g records foam height under 37 DEG C of heating water baths, for assessing foaming characteristic/initial foam height, after static 5min, and record
The height (drain height) of the foam lower layer water surface, for assessing the stability of foam；
3, test result: as shown in table 2.
The foam height and foam stability testing result of foaming mildy wash after table 2
| Project | Initial foam height (cm) | Drain height (cm) |
| Embodiment 1 | 11.2 | 0.8 |
| Embodiment 2 | 13.5 | 0.6 |
| Embodiment 3 | 10.9 | 0.9 |
| Comparative example 3 | 20.2 | 2.8 |
| Comparative example 4 | 7.1 | 1.6 |
| Comparative example 5 | 6.5 | 1.8 |
| Comparative example 6 | 3.8 | 2.3 |
(1) You Shangbiao 2 is it is found that the foam height of rear foaming mildy wash prepared by the embodiment of the present invention 1~3 is suitable for draining
Highly low, foaming mildy wash has good foaming characteristic and foam stability after illustrating the present invention, wherein prepared with embodiment 2
The initial foam height highest of foaming mildy wash afterwards, drain height is minimum, and effect is best, is highly preferred embodiment of the present invention；
(2) compared with Example 2, the additive amount of 3 surfactant of comparative example is constant, increases the addition of rear foaming agent
The initial foam height of amount, the rear foaming mildy wash of preparation obviously increases, but drain height also obviously increases simultaneously, illustrates to steep
Foam is excessive, while the stability decline of foam；Comparative example 4 increases the additive amount of surfactant, the additive amount of rear foaming agent
Constant, the initial foam of the rear foaming mildy wash of preparation height is substantially reduced, and drain height increased, and illustrates foaming characteristic and steady
Qualitative decline；Comparative example 5 is using ammonium lauryl sulfate for lauryl sodium sulfate, the initial bubble of the rear foaming mildy wash of preparation
Foam height is substantially reduced, and drain height increased；Comparative example 6 replaces cocounut oil acyl hydroxyl second using sodium cocoyl methyl sodium taurocholate
The initial foam height of sulphonic acid ester sodium, the rear foaming mildy wash of preparation is substantially reduced, and drain height increased, and illustrate foaming characteristic
Decline with stability, thus illustrate, surfactant of the present invention and rear foaming agent interact, and ratio is reasonable, the rear hair of preparation
The foam that mildy wash is capable of the abundant exquisiteness of spontaneous generation is steeped, while the stability of foam is good.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (7)
1. foam mildy wash after one kind, which is characterized in that the ingredient including following mass fraction: surfactant 10~20%,
Vaseline 15~20%, propylene glycol 5~10%, triethanolamine 1~2.5%, acrylic copolymer 6~14%, rear foaming agent 3~
6%, hydroxyethyl cellulose 0.1~0.5, parahydroxyacet-ophenone 0.3~0.7%, essence 0.1~0.5%, 0.1~1% and of nitrogen
Water 35~45%.
2. foam mildy wash after as described in claim 1, which is characterized in that the ingredient including following mass fraction: surface-active
Agent 16%, vaseline 17%, propylene glycol 8%, triethanolamine 2%, acrylic copolymer 10%, rear foaming agent 5%, ethoxy are fine
Dimension element 0.4%, parahydroxyacet-ophenone 0.5%, essence 0.4%, nitrogen 0.7% and water 40%.
3. foam mildy wash after as claimed in claim 1 or 2, which is characterized in that the surfactant is cocounut oil acyl hydroxyl second sulphur
Acid esters sodium, alkyl glycosides and ammonium lauryl sulfate.
4. foam mildy wash after as claimed in claim 3, which is characterized in that the cocounut oil acyl isethionic acid ester sodium, alkyl glycosides
Mass ratio with ammonium lauryl sulfate is 1:(0.1~0.3): (0.02~0.05).
5. foam mildy wash after as claimed in claim 4, which is characterized in that the cocounut oil acyl isethionic acid ester sodium, alkyl glycosides
Mass ratio with ammonium lauryl sulfate is 1:0.2:0.04.
6. foam mildy wash after as claimed in claim 1 or 2, which is characterized in that the rear foaming agent is trans- 1- chloro- 3,3,3-
Trifluoro propene.
7. a kind of preparation method of the mildy wash of foaming as claimed in claim 1 or 2, which comprises the following steps:
S1, mixed liquor A is made after propylene glycol and hydroxyethyl cellulose mixing are uniformly dispersed according to formula ratio；
S2, the mixed liquor A for the water of formula ratio being added in reaction kettle, and being added in the step S1 is heated to 80 while stirring~
85 DEG C, 15~25min of stirring is complete to dissolution of raw material, and mixed liquid B is made；
S3, according to formula ratio, vaseline, surfactant, parahydroxyacet-ophenone, acrylic copolymer are sequentially added into the step
In the mixed liquid B of rapid S2, is dissolved completely after stirring 15~25min, mixed liquor C is made；
S4, the mixed liquor C is cooled to 55~65 DEG C, the essence of formula ratio is added, is then cooled to 43~45 DEG C, continue to add
Enter triethanolamine, be stirring evenly and then adding into rear foaming agent, continues to be filled with nitrogen after mixing after 15~25min of stirring and be sealed
Mouthful, foam mildy wash after being made.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111214389A (en) * | 2020-03-16 | 2020-06-02 | 中山市天图精细化工有限公司 | Post-foaming makeup-removing bubble composition aerosol and preparation method thereof |
| WO2020200239A1 (en) * | 2019-04-01 | 2020-10-08 | Honeywell International Inc. | Personal care compositions and methods comprising trans-1-chloro-3, 3, 3-trifluoropropene and trans-1, 3, 3, 3-tetrafluoropropene |
| CN114224759A (en) * | 2022-01-25 | 2022-03-25 | 广州臻颜化妆品有限公司 | Submicron vaseline composition and submicron vaseline bath essence |
| WO2022072997A1 (en) * | 2020-03-20 | 2022-04-07 | Honeywell International Inc. | Personal care compositions and methods comprising trans-1-chloro-3,3,3-trifluoropropene and trans- 1,3,3,3-tetrafluoropropene |
| WO2022117289A1 (en) * | 2020-12-02 | 2022-06-09 | Unilever Ip Holdings B.V. | Skin cleansing composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100672247B1 (en) * | 2006-08-21 | 2007-01-22 | (주) 제이더블유테크널러지 | Shave supplement composition |
| CN108289853A (en) * | 2015-09-29 | 2018-07-17 | 盖尔德马研究及发展公司 | Including the wash type of ivermectin is from frothing cleaning composition |
| CN108852945A (en) * | 2018-09-14 | 2018-11-23 | 广州艾蓓生物科技有限公司 | A kind of amino acid cleansing cream from foaming |
-
2018
- 2018-12-28 CN CN201811653151.1A patent/CN109464300B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100672247B1 (en) * | 2006-08-21 | 2007-01-22 | (주) 제이더블유테크널러지 | Shave supplement composition |
| CN108289853A (en) * | 2015-09-29 | 2018-07-17 | 盖尔德马研究及发展公司 | Including the wash type of ivermectin is from frothing cleaning composition |
| CN108852945A (en) * | 2018-09-14 | 2018-11-23 | 广州艾蓓生物科技有限公司 | A kind of amino acid cleansing cream from foaming |
Non-Patent Citations (1)
| Title |
|---|
| 肖学智: "《含氢氯氟烃HCFCs替代技术指南》", 30 June 2016, 中国环境出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020200239A1 (en) * | 2019-04-01 | 2020-10-08 | Honeywell International Inc. | Personal care compositions and methods comprising trans-1-chloro-3, 3, 3-trifluoropropene and trans-1, 3, 3, 3-tetrafluoropropene |
| CN113727695A (en) * | 2019-04-01 | 2021-11-30 | 霍尼韦尔国际公司 | Personal care compositions and methods comprising trans-1-chloro-3, 3, 3-trifluoropropene and trans-1, 3,3, 3-tetrafluoropropene |
| CN111214389A (en) * | 2020-03-16 | 2020-06-02 | 中山市天图精细化工有限公司 | Post-foaming makeup-removing bubble composition aerosol and preparation method thereof |
| WO2022072997A1 (en) * | 2020-03-20 | 2022-04-07 | Honeywell International Inc. | Personal care compositions and methods comprising trans-1-chloro-3,3,3-trifluoropropene and trans- 1,3,3,3-tetrafluoropropene |
| WO2022117289A1 (en) * | 2020-12-02 | 2022-06-09 | Unilever Ip Holdings B.V. | Skin cleansing composition |
| CN114224759A (en) * | 2022-01-25 | 2022-03-25 | 广州臻颜化妆品有限公司 | Submicron vaseline composition and submicron vaseline bath essence |
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