CN113737357A - 一种铜氨长丝色织高档面料的加工方法 - Google Patents

一种铜氨长丝色织高档面料的加工方法 Download PDF

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CN113737357A
CN113737357A CN202111073124.9A CN202111073124A CN113737357A CN 113737357 A CN113737357 A CN 113737357A CN 202111073124 A CN202111073124 A CN 202111073124A CN 113737357 A CN113737357 A CN 113737357A
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yarn
cuprammonium
filament
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CN113737357B (zh
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王平
王庆淼
鱼水朋
罗潇
周杭
江伟权
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Yageer Group Co ltd
Yagor Garment Manufacturing Co ltd
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Abstract

本发明公开的铜氨长丝色织高档面料的加工方法,工艺流程为:铜氨长丝加捻、筒管涤纶线包覆、松纱、染纱、织造和坯布后整理,染纱包括纯碱前处理工序和染色工序,纯碱前处理工序采用的前处理剂的配方为:前处理精炼剂2‑4 g/L、纯碱2~4 g/L、质量浓度27.5%的双氧水1~5g/L,纯碱前处理工序中的保温温度为80~110℃、保温时间为30~60分钟、水流采用双向循环模式;染色工序采用活性染料,染色后采用浓度为5~10 g/L的纯碱溶液作为固色剂进行固色。该加工方法的制成率高,加工得到的面料的强力和物理测试指标高,颜色均匀性良好,纤维损伤小,利用率高,且面料手感柔滑、光泽优雅,是高档服装的首选面料。

Description

一种铜氨长丝色织高档面料的加工方法
技术领域
本发明属于纺织品领域,具体是一种铜氨长丝色织高档面料的加工方法。
背景技术
随着人们的精神和物质生活水平不断提高,人们对纺织品服装的追求也越来越高。在纺织服装领域,真丝产品一直是高档奢华的代表性面料,但是近几年随着原材料真丝价格上涨,同时真丝产品的成品不易打理,而且需要定期保养护理,这些因素在一定程度上降低了真丝产品的消费市场推广。
铜氨长丝纤维,纱线外观可媲美真丝。铜氨长丝纤维属于环保可自然降解的环境友好材料,既保留了棉纤维的吸湿透气、清爽柔软、舒适抗静电、易清洗等性能,同时集真丝的光泽、艳亮、悬垂感于一身,此外,铜氨长丝纤维的价格比真丝低,因而铜氨长丝纤维是一种高性价比的纤维。铜氨长丝纤维制成的铜氨面料成本低,是一款高性价比的高档面料,但铜氨面料的推广却受到了限制,原因在于目前铜氨面料加工存在以下技术难点:1)铜氨长丝纤维极其细腻和丝滑,纤维亲和力较大,同时由于铜氨长丝纤维的横截面呈圆形,纤维结构较均匀,染色亲和力较大,导致染色上色较快、着色率高,但容易染花和染深,染色难度较大;2)铜氨纤维比较光滑,如按照常规的织造工艺,即便使用高效率的喷气织布机,织布时气流也容易吹散纤维,并且容易滑脱纱筒,导致布面有稀密路,影响织布制成率以及成衣的外观;3)铜氨纤维耐酸和耐碱性都不佳,所以对纱线的前处理漂白、后整理丝光等工艺要求极高。鉴于以上铜氨面料染色和练漂等技术难点,目前市面上的铜氨面料大多数以匹染为主,导致这类纺织品存在花型颜色单一、光泽和手感欠缺等一些列问题。
发明内容
本发明所要解决的技术问题是,针对现有技术的不足,提供一种铜氨长丝色织高档面料的加工方法,该加工方法的制成率高,加工得到的铜氨长丝色织高档面料的强力和物理测试指标高,颜色均匀性良好,纤维损伤小,利用率高,且面料手感柔滑、光泽优雅,是高档服装的首选面料。
本发明解决上述技术问题所采用的技术方案为:一种铜氨长丝色织高档面料的加工方法,工艺流程为:铜氨长丝加捻、筒管涤纶线包覆、松纱、染纱、织造和坯布后整理,所述的染纱包括纯碱前处理工序和染色工序,所述的纯碱前处理工序采用的前处理剂的配方为:前处理精炼剂2-4g/L、纯碱2~4g/L、质量浓度27.5%的双氧水1~5g/L,所述的纯碱前处理工序中的保温温度为80~110℃、保温时间为30~60分钟、水流采用先从内向外4分钟再从外向内6分钟的双向循环模式或先从内向外3分钟再从外向内7分钟的双向循环模式;所述的染色工序采用活性染料,染色后采用浓度为5~10g/L的纯碱溶液作为固色剂进行固色。
本发明铜氨长丝色织高档面料的加工方法首先对铜氨长丝进行加捻预处理,目的是便于后续的松纱和织造加工,使纤维不易松散,提高加工效率和布面质量,同时便于染纱过程中染液更容易穿透筒纱,减少筒纱的内外层色差,保证染色的均匀性以及最终成品的制成率。染色工序中使用的活性染料采用市售产品。因铜氨长丝较滑,退绕后期容易全部滑脱,筒管涤纶线包覆可在筒管表面预包覆形成一定厚度的涤纶线,从而有效避免铜氨长丝的滑脱,此外,筒管表面预包覆一定厚度的涤纶线后,即使筒管因生产运输等原因产生毛刺,在后续纱线退绕时不容易勾纱。染纱过程中的纯碱前处理工序采用特定配方的前处理剂和前处理工艺,而不是常规的烧碱,可避免烧碱对铜氨纤维的强力损失;染纱过程中的染色工序结束后,采用浓度为5~10g/L的纯碱溶液作为固色剂进行固色,以降低染料反应速度,避免因染料反应速度过快而造成筒纱的内外层色差。
本发明铜氨长丝色织高档面料的加工方法通过对铜氨长丝进行加捻预处理、筒管涤纶线包覆并采用特定的纯碱前处理工序和染色工序等工序,可保证铜氨长丝在筒染过程的匀染性、筒纱的成型稳定性以及织造的效率和布面效果,使铜氨长丝色织高档面料的制成率达到98%以上,可扩大铜氨产品的色织布种,实现不同纱线配比,满足面料颜色花型多样性要求,丰富铜氨色织产品类型,加工得到的铜氨长丝色织高档面料的强力和物理测试指标高,颜色均匀性良好,纤维损伤小,利用率高,且面料手感柔滑、光泽优雅,是高档服装的首选面料。
作为优选,所述的前处理精炼剂为亨斯迈公司生产的
Figure BDA0003261127350000021
ONE三合一漂白处理剂。
作为优选,所述的织造采用喷气织机,并将铜氨的筒子纱线横向摆放在喷气织机的台面上,织造过程中喷气织机的车速为400~550转/分。因竖直摆放的筒子纱线容易破坏成型,且容易带纱滑脱,本发明通过将铜氨的筒子纱线横向摆放并限定喷气织机的车速,可有效解决上述问题。
作为优选,所述的筒管涤纶线包覆为:在表面带孔且底角为82~88°的圆台形的塑料筒管上包覆一定厚度的涤纶线。在纱线退绕时,上述塑料筒管不易带纱和粘连。
作为优选,所述的松纱为:将加捻过的铜氨长丝松络到包覆有涤纶线的塑料筒管上,且包覆的加捻过的铜氨长丝的松纱密度为0.35~0.40g/cm3,得到铜氨的筒子纱线。铜氨长丝0.35~0.40g/cm3的松纱密度,可保证染色的均匀性。
作为优选,每个所述的塑料筒管上包覆的涤纶线的重量为60~140g,包覆的加捻过的铜氨长丝的重量为300~600g。包覆的铜氨长丝不宜过多,避免后续染色过程中形成内外色差。
作为优选,所述的铜氨长丝加捻为:对铜氨长丝的原纱进行加捻预处理,加捻的捻度范围为500~1200TPM。
作为优选,所述的铜氨长丝的原纱为纱支规格50D/45F、75D/54F、100D/60F、120D/90F或150D/90F的FDY长丝。
作为优选,所述的坯布后整理包括的工序为:坯检、烧毛、退浆、液氨整理、定型、预缩,其中,坯检、烧毛和退浆分别采用已知工艺,液氨整理的车速为50~70m/min,定型和预缩采用已知的棉面料的定型和预缩工艺。液氨整理是一种高档温和的丝光工艺,对铜氨纤维不产生强力损伤,同时可提高铜氨纤维的光泽和尺寸稳定性。
作为优选,加工的铜氨长丝色织高档面料为弹力面料时,在所述的退浆与所述的液氨整理工序之间增加干布定型工序,干布定型工序的温度为150~200℃,车速为30~80m/min。
与现有技术相比,本发明具有如下优点:本发明铜氨长丝色织高档面料的加工方法通过对铜氨长丝进行加捻预处理、筒管涤纶线包覆并采用特定的纯碱前处理工序和染色工序等工序,可保证铜氨长丝在筒染过程的匀染性、筒纱的成型稳定性以及织造的效率和布面效果,使铜氨长丝色织高档面料的制成率达到98%以上,可扩大铜氨产品的色织布种,实现不同纱线配比,满足面料颜色花型多样性要求,丰富铜氨色织产品类型,加工得到的铜氨长丝色织高档面料的强力和物理测试指标高,颜色均匀性良好,纤维损伤小,利用率高,且面料手感柔滑、光泽优雅,是高档服装的首选面料。
具体实施方式
以下结合实施例对本发明作进一步详细描述。
实施例1:面料规格为CPT100/2*CU100D/60F 150*100的铜氨长丝蓝色色织高档面料的加工。
实施例1的面料规格中,CPT100/2指紧密纺纯棉100英支股线,CU100D/60F指纱支粗细为100D、孔数为60F的铜氨丝,面料成分为:55%棉、45%铜氨纤维。该面料的加工工艺流程为:
首先对纬纱CU100D/60F原纱进行加捻处理,捻度加至760TPM。选择表面带孔且底角为86°、重量为140g的圆台形的塑料筒管,用40S/2的涤纶半漂纱进行包覆,包覆重量100g,包覆后备用。随后将加捻过的铜氨长丝松络到包覆有涤纶半漂纱的塑料筒管上,且包覆的加捻过的铜氨长丝的松纱密度为0.38g/cm3,单纱重量0.6kg,得到铜氨的筒子纱线。将筒子纱线装进溢流筒纱染色缸进行纯碱前处理和染色,其中,纯碱前处理工序采用的前处理剂的配方为:前处理精炼剂2g/L、纯碱4g/L、质量浓度27.5%的双氧水4g/L,纯碱前处理工序中的保温温度为100℃、保温时间为30分钟、水流采用先从内向外4分钟再从外向内6分钟的双向循环模式的双向循环模式;染色工序采用市售活性染料:Sumifix Supra BlueBRF0.4%(owf),染色后采用浓度为5g/L的纯碱溶液保温固色,染色完成后,同样选择备用的包覆有涤纶线的塑料筒管进行络筒处理,待做纬纱。经向纯棉CPT100/2按照常规纯棉筒纱染色工艺,并整经浆纱。再采用喷气织机进行织造,并将铜氨的筒子纱线横向摆放在喷气织机的台面上,织造过程中喷气织机的车速为500转/分,制得坯布。
然后,进行坯布后整理,对坯布依次进行坯检、烧毛、退浆、液氨整理、定型、预缩等工序。坯检、烧毛和退浆分别采用已知同常规棉质面料工艺,液氨整理的车速为60m/min,定型、预缩采用已知的棉面料的定型和预缩工艺。最终获得布面颜色均匀、光泽淡雅、测试指标符合要求的CPT100/2*CU100D/60F 150*100铜氨长丝蓝色色织高档面料,其性能测试结果见表1。
表1:CPT100/2*CU100D/60F 150*100面料的性能测试结果
Figure BDA0003261127350000041
实施例2:面料规格为CPT100/2*CU100D/60F+DL40+40D(1:1)140*110的卡其色铜氨长丝色织高档面料的加工。
实施例2的面料规格中,CPT100/2指紧密纺纯棉100英支股线,CU100D/60F指纱支粗细为100D、孔数为60F的铜氨丝,DL40+40D为棉包氨纶纱线,即40英支棉包芯40D的氨纶,面料成分为:74%棉、23%铜氨纤维、3%氨纶。该面料的加工工艺流程为:
首先对纬纱CU100D/60F原纱进行加捻处理,捻度加至800TPM。选择表面带孔且底角为85°、重量为140g的圆台形的塑料筒管,用60S/3的涤纶半漂纱进行包覆,包覆重量120g,包覆后备用。随后将加捻过的铜氨长丝松络到包覆有涤纶半漂纱的塑料筒管上,且包覆的加捻过的铜氨长丝的松纱密度为0.37g/cm3,单纱重量0.5kg,得到铜氨的筒子纱线。将筒子纱线装进溢流筒纱染色缸进行纯碱前处理和染色,其中,纯碱前处理工序采用的前处理剂的配方为:前处理精炼剂2g/L、纯碱3g/L、质量浓度27.5%的双氧水4g/L,纯碱前处理工序中的保温温度为100℃、保温时间为40分钟、水流采用先从内向外3分钟再从外向内7分钟的双向循环模式;染色工序采用市售活性染料组合染液:Remazol Red RB 0.2%、Remazol Yellow RNL 0.2%、Remazol Blue R-X 0.14%(owf),染色后采用浓度为5g/L的纯碱溶液保温固色,染色完成后,同样选择备用的包覆有涤纶线的塑料筒管进行络筒处理,待做纬纱。经向纯棉CPT100/2和纬向DL40+40D按照常规纯棉筒纱染色工艺,并将CPT100/2整经浆纱,然后采用喷气织机进行织造,织造时纬纱分别为CU100D/60F和DL40+40D交替打纬并将铜氨的筒子纱线横向摆放在纱架上,织造过程中喷气织机的车速为480转/分,制得坯布。
然后,进行坯布后整理,对坯布依次进行坯检、烧毛、退浆、干布定型、液氨整理、定型、预缩等工序。坯检、烧毛和退浆分别采用已知同常规棉质面料工艺,干布定型的温度为180℃、车速为50m/min,液氨整理的车速为50m/min,定型、预缩采用已知的棉面料的定型和预缩工艺。最终获得布面颜色均匀、光泽淡雅、测试指标符合要求的CPT100/2*CU100D/60F+DL40+40D(1:1)140*110卡其色铜氨长丝色织高档面料,其性能测试结果见表2。
表2:PT100/2*CU100D/60F+DL40+40D(1:1)140*110面料的性能测试结果
Figure BDA0003261127350000051
上述实施例中,采用的前处理精炼剂为亨斯迈公司生产的
Figure BDA0003261127350000061
ONE三合一漂白处理剂,其化学组成为络合分散剂、表面活性剂以及双氧水稳定剂的复配物,不含APEO,是一种阴离子性液态漂白处理剂,浓度10g/L时的pH值约为5.5,20℃时的比重约为1.1g/cm3,在20℃下密闭容器中妥善保存可稳定一年,对0℃以下低温和40℃以上高温敏感,对浓度250g/L的NaOH溶液的耐碱稳定性为100%,氧化剂稳定性很好,粘度(Rheomat180,25℃)<250mPas,20℃时的电导率约为15mS/cm。

Claims (10)

1.一种铜氨长丝色织高档面料的加工方法,其特征在于,工艺流程为:铜氨长丝加捻、筒管涤纶线包覆、松纱、染纱、织造和坯布后整理,所述的染纱包括纯碱前处理工序和染色工序,所述的纯碱前处理工序采用的前处理剂的配方为:前处理精炼剂2-4g/L、纯碱2~4g/L、质量浓度27.5%的双氧水1~5g/L,所述的纯碱前处理工序中的保温温度为80~110℃、保温时间为30~60分钟、水流采用先从内向外4分钟再从外向内6分钟的双向循环模式或先从内向外3分钟再从外向内7分钟的双向循环模式;所述的染色工序采用活性染料,染色后采用浓度为5~10g/L的纯碱溶液作为固色剂进行固色。
2.根据权利要求1所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的前处理精炼剂为亨斯迈公司生产的
Figure FDA0003261127340000011
ONE三合一漂白处理剂。
3.根据权利要求1所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的织造采用喷气织机,并将铜氨的筒子纱线横向摆放在喷气织机的台面上,织造过程中喷气织机的车速为400~550转/分。
4.根据权利要求1所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的筒管涤纶线包覆为:在表面带孔且底角为82~88°的圆台形的塑料筒管上包覆一定厚度的涤纶线。
5.根据权利要求4所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的松纱为:将加捻过的铜氨长丝松络到包覆有涤纶线的塑料筒管上,且包覆的加捻过的铜氨长丝的松纱密度为0.35~0.40g/cm3,得到铜氨的筒子纱线。
6.根据权利要求5所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,每个所述的塑料筒管上包覆的涤纶线的重量为60~140g,包覆的加捻过的铜氨长丝的重量为300~600g。
7.根据权利要求1所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的铜氨长丝加捻为:对铜氨长丝的原纱进行加捻预处理,加捻的捻度范围为500~1200TPM。
8.根据权利要求7所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的铜氨长丝的原纱为纱支规格50D/45F、75D/54F、100D/60F、120D/90F或150D/90F的FDY长丝。
9.根据权利要求1所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,所述的坯布后整理包括的工序为:坯检、烧毛、退浆、液氨整理、定型、预缩,其中,坯检、烧毛和退浆分别采用已知工艺,液氨整理的车速为50~70m/min,定型和预缩采用已知的棉面料的定型和预缩工艺。
10.根据权利要求9所述的一种铜氨长丝色织高档面料的加工方法,其特征在于,加工的铜氨长丝色织高档面料为弹力面料时,在所述的退浆与所述的液氨整理工序之间增加干布定型工序,干布定型工序的温度为150~200℃,车速为30~80m/min。
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