CN112812906A

CN112812906A - Shampoo soap containing selenium sulfide plant extract and preparation method and application thereof

Info

Publication number: CN112812906A
Application number: CN202110089128.XA
Authority: CN
Inventors: 邓建华; 王建功
Original assignee: Individual
Current assignee: Individual
Priority date: 2021-01-22
Filing date: 2021-01-22
Publication date: 2021-05-18

Abstract

The invention is suitable for the technical field of daily chemical articles, and provides a shampoo soap containing selenium sulfide plant extract, a preparation method and an application thereof, wherein the shampoo soap comprises the following components: stearic acid, coronene acid of phaseolus angularis, lauric acid, sorbitol, propylene glycol, glycerol, sodium laureth sulfate, sodium hydroxide, beeswax, polyglycerol, camellia seed extract, selenium disulfide, essence and water. According to the shampoo soap provided by the embodiment of the invention, selenium disulfide (which can form a colloidal copolymer with glycerol) and camellia seed extract are uniformly dispersed in a hot-melt soap base by a physical dispersion means to form a stable system, so that the shampoo soap has strong effects of cleaning, deoiling and moisturizing, and also has the effects of removing dandruff, relieving itching, preventing and treating folliculitis.

Description

Shampoo soap containing selenium sulfide plant extract and preparation method and application thereof

Technical Field

The invention belongs to the technical field of daily chemical articles, and particularly relates to a shampoo soap containing selenium sulfide plant extracts, and a preparation method and application thereof.

Background

The shampoo products on the market at present represent a plurality of shampoos, and basically clean the scalp of hair and increase the smoothness of the hair, and have low user satisfaction degree on the oil control and anti-dandruff effects of the scalp. The cationic surfactant and the preservative which are necessary in the shampoo technical system have strong irritation to the scalp, thereby bringing about a plurality of scalp problems. And the ingredients with the selenium sulfide as the efficacy are difficult to be added into the shampoo system (the selenium sulfide has high density, is insoluble in water and oil, has strong reducibility, is easy to generate chemical reaction with a plurality of common suspending agents, and is difficult to suspend in the shampoo system). And the cation conditioner and the preservative which are commonly used in the shampoo are difficult to degrade in nature, which brings environmental burden.

The selenium disulfide lotion on the market is a medical lotion, the general content is 2.5 percent, and the selenium disulfide lotion has good curative effect on bacteria on the scalp and seborrheic dermatitis. However, the selenium disulfide has strong skin irritation, and the solid content in the medicament is too high to be used for a long time. In addition, the selenium disulfide has strong effect of inhibiting sebaceous gland secretion, and the high-content dosage form easily causes excessive dryness of scalp, and causes the problems of dandruff increase and scalp itching. In addition, the selenium sulfide lotion has poor cleaning capability and needs to be matched with shampoo for use, so that the selenium sulfide lotion brings no change to users.

In addition, all of the shampoo soaps on the market are cold soaps, which do not use a soap base as a main surfactant, strictly speaking, the shampoo in a solid form has only the shape of soap, and cannot be regarded as soap. When hot soap specially used for washing hair is not available in the market, the hair is difficult to comb and has strong sticky feeling due to soap base residue after the hair is washed by common soap.

Disclosure of Invention

The embodiment of the invention aims to provide a shampoo soap containing selenium disulfide plant extract, and aims to solve the problems in the background art.

The embodiment of the invention is realized in such a way that the shampoo soap containing the selenium sulfide plant extract comprises the following components in percentage by mass: 13-17% of stearic acid, 1-5% of coronene acid, 1-5% of lauric acid, 15-25% of sorbitol, 5-12% of propylene glycol, 3-8% of glycerol, 5-10% of sodium laureth sulfate, 2-4% of sodium hydroxide, 0.5-3% of beeswax, 0.5-3% of polyglycerol, 5-12% of CAMELLIA (CAMELLIA japonica) seed extract, 0.1-0.5% of selenium disulfide, 0.3-0.8% of essence and the balance of water, wherein the sum of the mass percentages of the components is 100%.

As a preferable aspect of the embodiment of the present invention, the shampoo soap comprises the following components in percentage by mass: 14-16% of stearic acid, 2-4% of coronene acid, 2-4% of lauric acid, 18-22% of sorbitol, 8-10% of propylene glycol, 4-6% of glycerol, 7-9% of sodium laureth sulfate, 2.8-3.6% of sodium hydroxide, 1-2% of beeswax, 1-2% of polyglycerol, 7-10% of camellia seed extract, 0.2-0.4% of selenium disulfide, 0.5-0.7% of essence and the balance of water, wherein the sum of the mass percentages of the components is 100%.

As another preferred embodiment of the present invention, the polyglycerol is polyglycerol-10.

Another object of an embodiment of the present invention is to provide a method for preparing the above shampoo soap containing selenium sulfide plant extract, which comprises the following steps:

weighing stearic acid, coronene acid, lauric acid, sorbitol, propylene glycol, glycerin, sodium laureth sulfate, sodium hydroxide, beeswax, polyglycerol, camellia seed extract, selenium disulfide, essence and water according to the mass percentage of the components;

mixing and dissolving stearic acid, caro coronene acid, lauric acid, sorbitol, propylene glycol, glycerol and sodium laureth sulfate to obtain a mixture A;

mixing sodium hydroxide with water, and then mixing with the mixture A to obtain a mixture B;

mixing the mixture B with beeswax, polyglycerol and camellia seed extract to obtain a mixture C;

grinding selenium disulfide into powder to obtain selenium disulfide powder;

and mixing the mixture C with selenium disulfide powder, and then adding essence for mixing to obtain the shampoo soap.

As another preferable scheme of the embodiment of the present invention, in the step, a mixed dissolution temperature of stearic acid, coronene acid, lauric acid, sorbitol, propylene glycol, glycerin, and sodium laureth sulfate is 60 to 80 ℃.

In another preferable scheme of the embodiment of the invention, in the step, the mixing temperature of the mixture B, the beeswax, the polyglycerol and the camellia seed extract is 60-80 ℃.

As another preferable scheme of the embodiment of the invention, in the step, the mixing temperature of the mixture C and the selenium disulfide powder is 60-80 ℃.

As another preferable scheme of the embodiment of the invention, in the step, the particle size of the selenium disulfide powder is not less than 1000 meshes.

Another object of the embodiments of the present invention is to provide a shampoo soap prepared by the above preparation method.

Another object of the present invention is to provide a use of the above shampoo soap in preparing an oil control and/or anti-dandruff hair care product.

In the invention, the soap is a dosage form capable of well suspending selenium sulfide, and the oil control and dandruff removal effects after the selenium sulfide and the camellia seed extract are compounded are good, and the irritation is low. Meanwhile, after the soap base is matched with other surfactants and the camellia seed extract, the sticky and greasy feeling of the washed hair can be well solved, so that the hair has good refreshing feeling and conditioning property. Finally, the hot soap has low moisture content and high surface activity, can be added with large amount of polyalcohol, and can not be rancid under the condition of not adding a preservative, so that the special shampoo soap naturally avoids the damage from the preservative to the scalp.

According to the shampoo soap containing the selenium sulfide plant extract, the selenium sulfide (which can form a colloid copolymer with glycerol) and the camellia seed extract are uniformly dispersed in a hot-melt soap base by a physical dispersion method to form a stable system, so that the shampoo soap has strong effects of cleaning, deoiling and moisturizing, and also has the effects of removing dandruff, relieving itching, preventing and treating folliculitis.

Many clinical tests prove that the selenium sulfide has more obvious anti-dandruff effect than sulfur and salicylic acid, has the effects of resisting seborrhea, fungi and bacteria, can inhibit epidermal cell replacement and reduction caused by nuclear division, plays the roles of controlling oil, relieving itching, diminishing inflammation and reducing dandruff, and has no absorption of the intact skin. The extract of Camellia JAPONICA (Camellia JAPONICA) seed has good antibacterial and antibacterial effects. After the selenium disulfide and the CAMELLIA (Camellia JAPONICA) seed extract are compounded, the oil control and anti-dandruff effects of the product can be guaranteed, and the irritation of the selenium disulfide to the scalp can be effectively reduced. Therefore, the invention organically combines the selenium disulfide, CAMELLIA JAPONICA (CAMELLIA JAPONICA) seed extract, the surfactant and the humectant together to prepare the multifunctional shampoo soap with the functions of cleaning, controlling oil, removing scurf and the like.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Example 1

The embodiment provides a shampoo soap containing selenium disulfide plant extract, and the preparation method comprises the following steps:

s1, weighing 13g of stearic acid, 1g of coronene acid, 1g of lauric acid, 25g of sorbitol, 12g of propylene glycol, 8g of glycerol, 5g of sodium laureth sulfate, 2g of sodium hydroxide, 0.5g of beeswax, 100.5 g of polyglycerol, 5g of CAMELLIA (Camellia JAPONICA) seed extract, 0.1g of selenium disulfide, 0.3g of essence and 26.6g of water for later use.

S2, mixing the weighed stearic acid, coronene acid, lauric acid, sorbitol, propylene glycol, glycerin and sodium laureth sulfate, and heating to 60 ℃ for dissolving to obtain a mixture A.

S3, stirring and mixing the weighed sodium hydroxide and water, cooling to room temperature, slowly adding the mixture A, stirring and mixing for 15min to obtain a mixture B.

S4 adding Cera flava, polyglycerol-10, and herba Camelliae Japonicae (Camellia JAP ONICA) seed extract into the mixture B, and stirring at 60 deg.C to dissolve completely to obtain mixture C.

And S5, grinding the weighed selenium disulfide into powder by using a grinder to obtain selenium disulfide powder with the granularity not less than 1000 meshes.

S6, placing the obtained mixture C and selenium disulfide powder in a homogenizer, stirring and mixing for 10 min, keeping the temperature at 60 ℃, stirring for 30min, adding essence, mixing to obtain a hot material body, placing the hot material body into a mold, molding, cooling and cutting into blocks to obtain the shampoo soap.

Example 2

s1, weighing 17g of stearic acid, 5g of coronene acid, 5g of lauric acid, 15g of sorbitol, 5g of propylene glycol, 3g of glycerol, 10g of sodium laureth sulfate, 4g of sodium hydroxide, 3g of beeswax, 103 g of polyglycerol, 12g of CAMELLIA (Camellia JAPONICA) seed extract, 0.5g of selenium disulfide, 0.8g of essence and 16.7g of water for later use.

S2, mixing the weighed stearic acid, coronene acid, lauric acid, sorbitol, propylene glycol, glycerin and sodium laureth sulfate, and heating to 80 ℃ for dissolving to obtain a mixture A.

S4 adding Cera flava, polyglycerol-10, and herba Camelliae Japonicae (Camellia JAP ONICA) seed extract into the mixture B, and stirring at 80 deg.C to dissolve completely to obtain mixture C.

S6, placing the obtained mixture C and selenium disulfide powder in a homogenizer, stirring and mixing for 15min, keeping the temperature of 80 ℃, stirring for 30min, adding essence, mixing to obtain a hot material body, placing the hot material body into a mold, molding, cooling and cutting into blocks to obtain the shampoo soap.

Example 3

s1, weighing 17g of stearic acid, 5g of coronene acid, 5g of lauric acid, 25g of sorbitol, 12g of propylene glycol, 8g of glycerol, 10g of sodium laureth sulfate, 2g of sodium hydroxide, 2.5g of beeswax, 102.5 g of polyglycerol, 5g of CAMELLIA (Camellia JAPONICA) seed extract, 0.5g of selenium disulfide, 0.5g of essence and 5g of water for later use.

S2, mixing the weighed stearic acid, coronene acid, lauric acid, sorbitol, propylene glycol, glycerin and sodium laureth sulfate, and heating to 70 ℃ for dissolving to obtain a mixture A.

S4 adding Cera flava, polyglycerol-10, and herba Camelliae Japonicae (Camellia JAP ONICA) seed extract into the mixture B, and stirring at 70 deg.C to dissolve completely to obtain mixture C.

S6, placing the obtained mixture C and selenium disulfide powder in a homogenizer, stirring and mixing for 12 min, keeping the temperature at 70 ℃, stirring for 30min, adding essence, mixing to obtain a hot material body, placing the hot material body into a mold, molding, cooling and cutting into blocks to obtain the shampoo soap.

Example 4

s1, weighing 17g of stearic acid, 4g of coronene acid, 4g of lauric acid, 24.5g of sorbitol, 11g of propylene glycol, 7g of glycerol, 8g of sodium laureth sulfate, 3g of sodium hydroxide, 2g of beeswax, 102 g of polyglycerol, 10g of CAMELLIA (Camellia JAPONICA) seed extract, 0.1g of selenium disulfide, 0.4g of essence and 7g of water for later use.

Example 5

s1, weighing 14g of stearic acid, 2g of coronene acid, 2g of lauric acid, 22g of sorbitol, 10g of propylene glycol, 6g of glycerol, 9g of sodium laureth sulfate, 2.8g of sodium hydroxide, 1g of beeswax, 1g of polyglycerol, 7g of camellia (C AMELLIA JAPONICA) seed extract, 0.2g of selenium sulfide, 0.5g of essence and 22.5g of water for later use.

Example 6

s1, weighing 16g of stearic acid, 4g of coronene acid, 4g of lauric acid, 18g of sorbitol, 8g of propylene glycol, 4g of glycerol, 7g of sodium laureth sulfate, 3.6g of sodium hydroxide, 2g of beeswax, 2g of polyglycerol, 10g of camellia (C AMELLIA JAPONICA) seed extract, 0.4g of selenium sulfide, 0.7g of essence and 20.3g of water for later use.

Example 7

s1, weighing 15g of stearic acid, 3g of coronene acid, 3g of lauric acid, 21g of sorbitol, 9g of propylene glycol, 5g of glycerol, 8g of sodium laureth sulfate, 3.5g of sodium hydroxide, 1.8g of beeswax, 1.8g of polyglycerol, 9g of CAMELLIA (Camellia JAPONICA) seed extract, 0.3g of selenium disulfide, 0.6g of essence and 19g of water for later use.

Example 8

s1, weighing 15g of stearic acid, 4g of coronene acid, 4g of lauric acid, 24g of sorbitol, 12g of propylene glycol, 8g of glycerol, 10g of sodium laureth sulfate, 3.2g of sodium hydroxide, 1.5g of beeswax, 1.5g of polyglycerol, 10g of CAMELLIA (Camellia JAPONICA) seed extract, 0.3g of selenium disulfide, 0.5g of essence and 6g of water for later use.

Test example:

preparing 20 pieces of 100 g of shampoo soap according to the method provided by the embodiment 8, distributing the soap to 20 accurate groups with 12-60 years old, high hair oil and dandruff, taking four weeks as a test period, carrying out curative effect statistics, wherein 10 people respectively wash the sample once in the morning and at night every day, and then rub and wash for 1-2 minutes and flush after staying on hair and scalp for 3-5 minutes every time, and 10 people wash the sample once in the evening every day and then rub and wash for 1-2 minutes after staying on hair and scalp for 3-5 minutes every time, and then flush; the curative effect of 20 patients in the use period is shown in the following table 1. In addition, the criteria for efficacy are as follows:

and (3) healing: the hair is not greasy within 72 hours, and the scalp is not visible with symptoms such as scurf, pruritus and the like;

remarkably: the hair is not greasy within 48 hours, and the scalp is not visible with symptoms such as scurf, pruritus and the like;

the method has the following advantages: the hair is not greasy within 24 hours, and the scalp is not visible with symptoms such as scurf, pruritus and the like;

and (4) invalidation: the improvement was not significant or exacerbated.

TABLE 1

Number of times and number of people used per day	Recovery method	Is remarkable in that	Is effective	Invalidation
					Using 10 persons twice daily	3	6	1	0
Is used for 10 people once a day	2	6	2	0

As can be seen from table 1, the shampoo soap is not ineffective, the total effective rate is 100%, which indicates that the shampoo soap provided by the embodiment of the invention has the treatment universality, the effective proportion is 15%, the significant proportion is 20%, the recovery proportion is 65%, the recovery rate is high, and no repetition is found in the use period;

in conclusion, the shampoo soap provided by the embodiment of the invention is reasonable in formula, is clean, smooth and moisturizing, is obvious in oil control and dandruff removal, is cool and comfortable to use, can obviously prolong and reduce the generation frequency of the hair oil and dandruff from the beginning of use, can generate a large amount of dandruff hair oil, is prolonged to 1-3 days from the original 12 hours, is not itchy on scalp after use, and is a good washing and protecting product for oily and dandruff scalp.

Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims

1. The shampoo soap containing the selenium sulfide plant extract is characterized by comprising the following components in percentage by mass: 13-17% of stearic acid, 1-5% of coronene acid, 1-5% of lauric acid, 15-25% of sorbitol, 5-12% of propylene glycol, 3-8% of glycerol, 5-10% of sodium laureth sulfate, 2-4% of sodium hydroxide, 0.5-3% of beeswax, 0.5-3% of polyglycerol, 5-12% of camellia seed extract, 0.1-0.5% of selenium disulfide, 0.3-0.8% of essence and the balance of water, wherein the sum of the mass percentages of the components is 100%.

2. The shampoo soap containing the selenium sulfide plant extract as claimed in claim 1, wherein the shampoo soap comprises the following components in percentage by mass: 14-16% of stearic acid, 2-4% of coronene, 2-4% of lauric acid, 18-22% of sorbitol, 8-10% of propylene glycol, 4-6% of glycerol, 7-9% of sodium laureth sulfate, 2.8-3.6% of sodium hydroxide, 1-2% of beeswax, 1-2% of polyglycerol, 7-10% of camellia seed extract, 0.2-0.4% of selenium disulfide, 0.5-0.7% of essence and the balance of water, wherein the sum of the mass percentages of the components is 100%.

3. The shampoo soap containing selenium sulfide plant extract as claimed in claim 1 or 2, wherein the polyglycerol is polyglycerol-10.

4. A method for preparing a shampoo soap containing selenium sulphide plant extract according to any one of claims 1 to 3, comprising the following steps:

grinding selenium disulfide into powder to obtain selenium disulfide powder;

5. The method for preparing the shampoo soap containing the selenium sulfide plant extract as claimed in claim 4, wherein in the step, the mixing and dissolving temperature of stearic acid, coronene, lauric acid, sorbitol, propylene glycol, glycerin and sodium laureth sulfate is 60-80 ℃.

6. The method for preparing the shampoo soap containing selenium sulfide plant extracts as claimed in claim 4, wherein in the step, the mixing temperature of the mixture B, the beeswax, the polyglycerol and the camellia seed extract is 60-80 ℃.

7. The method for preparing the shampoo soap containing selenium sulfide plant extract as claimed in claim 4, wherein in the step, the mixing temperature of the mixture C and the selenium sulfide powder is 60-80 ℃.

8. The method for preparing the shampoo soap containing selenium sulfide plant extract as claimed in claim 4, wherein in the step, the particle size of the selenium sulfide powder is not less than 1000 meshes.

9. A shampoo soap produced by the production method according to any one of claims 4 to 8.

10. Use of a shampoo soap according to any one of claims 1 to 3 or 9 in the manufacture of an oil and/or dandruff control hair care product.