CN112647312B - 一种可生物降解的手套及其制备方法 - Google Patents

一种可生物降解的手套及其制备方法 Download PDF

Info

Publication number
CN112647312B
CN112647312B CN202011448686.2A CN202011448686A CN112647312B CN 112647312 B CN112647312 B CN 112647312B CN 202011448686 A CN202011448686 A CN 202011448686A CN 112647312 B CN112647312 B CN 112647312B
Authority
CN
China
Prior art keywords
biodegradable
yarn
gloves
water
glove
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202011448686.2A
Other languages
English (en)
Other versions
CN112647312A (zh
Inventor
秦爽
李健男
王星
严成锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Shuque Trading Co ltd
Magic Weiwei Shanghai Clothing Technology Co ltd
Original Assignee
Shanghai Shuque Trading Co ltd
Magic Weiwei Shanghai Clothing Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Shuque Trading Co ltd, Magic Weiwei Shanghai Clothing Technology Co ltd filed Critical Shanghai Shuque Trading Co ltd
Priority to CN202011448686.2A priority Critical patent/CN112647312B/zh
Publication of CN112647312A publication Critical patent/CN112647312A/zh
Application granted granted Critical
Publication of CN112647312B publication Critical patent/CN112647312B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12—Threads containing metallic filaments or strips
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/16—Yarns or threads made from mineral substances
    • D02G3/18—Yarns or threads made from mineral substances from glass or the like
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
    • D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
    • D04B1/28—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel gloves
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0034—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0038—Polyolefin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/146—Soilproof, soil repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1607—Degradability
    • D06N2209/1614—Biodegradable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1635—Elasticity
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • D06N2211/103—Gloves

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Gloves (AREA)

Abstract

本发明属于手套技术领域，具体涉及一种可生物降解的手套及其制备方法。一种可生物降解的手套的制备方法包括如下步骤：S1，将络好纱的铝杯固定在纱锭上，将玻璃纤维或钢纱金属穿过纱线张力控制器和纱锭孔作为纱芯，或将玻璃纤维或钢纱金属穿过纱线张力控制器后穿在捻线机器上作为纱芯，将生物可降解长丝纱或短纤维纱作为外纱进行缠绕包覆，形成手套用包覆纱线，再在手套机上织成纺织品手套；或将生物可降解长丝纱或短纤维纱直接在手套机上织成纺织品手套；S2,纺织品手套浸胶后形成可降解的手套。该制备方法简单易操作，适合大规模生产，且制备出的可生物降解手套不仅有好的防滑性和耐磨性，还有好的生物降解性能。

Description

一种可生物降解的手套及其制备方法
技术领域
本发明属于手套技术领域，具体涉及一种可生物降解的手套及其制备方法。
背景技术
为了防滑和耐磨，目前市场上工业用或民用手套会使用合成丁腈，聚氨酯等高分子聚合物作为原料，而手套为消耗品，更换频率高，废弃的手套会对环境造成污染。随着国家对环境问题的重视，人们对清洁的生产方式和环境友好的材料有了更深的认识，因此在解决耐磨和防滑性能的同时，如何提高手套的降解性能成为亟待解决的问题。
发明内容
为了克服现有技术中存在的缺点和不足，本发明的目的在于提供一种可生物降解的手套的制备方法，该制备方法简单易操作，且制备出的手套不仅有好的防滑、耐磨和防尘性，还有可降解性能。本发明的又一目的在于提高一种可生物降解的手套。
本发明的目的通过下述技术方案实现：一种可生物降解的手套的制备方法，包括如下步骤：
S1，将络好纱的铝杯固定在纱锭上，将玻璃纤维或钢纱金属穿过纱线张力控制器和纱锭孔作为纱芯，将生物可降解长丝纱作为外纱进行缠绕包覆，形成手套用包覆纱线，在手套机上织成纺织品手套;
S2,纺织品手套浸胶后形成可降解的手套；
所述浸胶过程包括如下步骤，
S21拌料；
S22手模预热：将手套套在手模上后，将手模预热到40-90℃；
S23浸涂，匀胶；
S24烘烤：将套有手套的手模置入温度为90-120℃的环境中烘烤1-20min；
S25用清水冲洗，浸泡；
S26烘烤：将冲洗和浸泡后的手套置入温度为90-120℃的环境中烘烤1-20min。
步骤S21拌料中所述原料包括水、聚氨酯、二甲基甲酰胺和生物可降解添加剂或水、丁腈和生物可降解添加剂，所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
所述纱锭孔里共混加入陶瓷部件。
纱线在络筒和喂纱时会有张力不均的情况，通过张力控制器，可以有效的避免张力不均的问题。
在纱锭孔里共混加入陶瓷部件，可以增加包纱过程中的流畅性，起到润滑的作用。减少玻璃纤维、钢纱金属等与纱锭的金属摩擦，减少纱线断头率和纱线的磨损。
该制备方法简单易操作，且制备出的手套不仅有好的防滑、耐磨和防尘性，还有可降解性能。
所述步骤S1中所述生物可降解长丝纱的制备方法为：将生物可降解添加剂在50-90℃的环境中烘烤2-6h后，共混加入到经预结晶和干燥后的聚对苯二甲酸乙二醇酯中，经纺丝的初生纤维、牵伸后得到预牵伸的长丝纱，再经热牵伸及假捻卷曲工艺，制备为生物可降解长丝纱；步骤S1中所述短纤维纱的制备方法为：将生物可降解添加剂在50-90℃的环境中烘烤2-6h后，共混加入到经预结晶和干燥后的聚对苯二甲酸乙二醇酯中，经纺丝的初生纤维、牵伸后再经卷曲和切断制造得到的短纤维，再纺纱后得到短纤维纱；所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
聚酯纤维纺纱，要求很低的含水率；而生物可降解的母粒为亲水性母粒，含有一定的水份，在纺纱流中，会导致聚酯大分子发生水解。经过经2-6小时，温度为50-90度的烘干，可以保证纺纱含水率达到聚酯纺纱的要求，不会产生聚酯分子的水解。
所述的生物可降解添加剂占生物可降解添加剂和聚对苯二甲酸乙二醇酯总重量的0.5%-10%。
优选的，所述生物可降解添加剂为可生物降解的低聚物聚酯、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:（1-3）:（1-3）组成的组合物。
本发明用上述比例的混合物作为生物可降解添加剂，使得制备的手套更易降解，还保持了好的防滑、耐磨和高弹性。
更为优选的，所述生物可降解添加剂为可生物降解的低聚物聚酯、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:1:1组成的组合物。
在另一技术方案中，步骤S1中所述生物可降解长丝纱的制备方法为：将生物可降解添加剂共混加入到聚酰胺中，经纺丝的初生纤维、牵伸后得到预牵伸的长丝纱，再经热牵伸及假捻卷曲工艺，制备为生物可降解长丝纱，其中，牵伸时第一罗拉由喂纱罗拉和皮圈组成，所述假捻卷曲工艺中假捻器为聚氨酯软盘；步骤S1中所述短纤维纱的制备方法为：将生物可降解添加剂共混加入到聚酰胺中，经纺丝的初生纤维、牵伸后再经卷曲和切断制造得到的短纤维，再纺纱后得短纤维纱；所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
由于锦纶纤维的外表有靴层包覆，且锦纶纤维为亲水性，当共混加入亲水性的生物可降解的纤维后，POY表面摩擦系数很小，容易打滑。为保证牵伸时候的握持纤维的力，第一罗拉（喂入罗拉）由喂纱罗拉和皮圈组成，而不用皮辊；假捻器用软盘，如聚氨酯pu类。
所述的生物可降解添加剂占生物可降解添加剂和聚酰胺总重量的0.5%-10%。
优选的，所述生物可降解添加剂为可生物降解的低聚物聚酯和己醛醣以1:（1-3）组成的组合物。
本发明采用上述比例的可降解添加剂，不仅保持了手套好的防滑性和耐磨性，使得手套有更好的降解性，而且生产成本低，适合批量生产。
更为优选的，所述生物可降解添加剂为聚乙烯醇和己醛醣已1:1组成的组合物。
在另一技术方案中，步骤S1中所述生物可降解长丝纱的制备方法为：将生物可降解添加剂共混加入到聚丙烯切片中，经纺丝的初生纤维、牵伸后得到预牵伸的长丝纱，再经热牵伸及假捻卷曲工艺，制备为生物可降解丙纶纤维长丝纱；步骤S1中所述短纤维纱的制备方法为：将生物可降解添加剂共混加入到聚丙烯切片中，经纺丝的初生纤维、牵伸后再经卷曲和切断制造得到的短纤维，再纺纱后得到短纤维纱；所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
所述的生物可降解添加剂占生物可降解添加剂和丙纶纤维总重量的0.5%-10%。
所述步骤S21拌料步骤为将水、聚氨酯、二甲基甲酰胺和生物可降解添加剂混合后高速搅拌10-60min后静置1-120min，所述水、聚氨酯、二甲基甲酰胺和生物可降解添加剂按重量份数计为：
水 10-80份
聚氨酯 20-80份
二甲基甲酰胺 10-50份
生物可降解添加剂 0.5-10份
二甲基甲酰胺作为聚氨酯PU的溶剂在常态下难挥发、去除。故用水作为稀释剂加快二甲基甲酰胺DMF的去除，使手套尽快成型。
所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
在另一技术方案中，所述步骤S21拌料步骤为将水、丁腈和生物可降解添加剂混合后高速搅拌10-60min后静置1-48min，所述水、丁腈和生物可降解添加剂按重量份数计为：
水 5-80份
丁腈 15-94.5份
生物可降解添加剂 0.5-10份
且在S23中匀胶后共混加入喷盐步骤，所述喷盐为喷氯化钠或芒硝。
共混加入生物可降解助剂后，丁晴表面光滑，对丁晴表面进行喷盐而后又去除，形成胶面形成凹凸结构的防滑手套，增加手套的防滑性能。
所述生物可降解添加剂为天然纤维素、人工合成聚己内酯、聚乙烯醇、可生物降解的低聚物聚酯、芳香族一脂肪族的酯聚物、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖、己醛醣中的至少一种。
与现有技术相比，本发明的优点在于：
该制备方法简单易操作，适合大规模生产，且制备出的手套不仅有好的防滑、耐磨、高弹性和防尘性，还有可降解性能。
具体实施方式
下面结合实施例对本发明作进一步详细的描述，但本发明的实施方式不限于此。
Figure DEST_PATH_IMAGE001
实施例1
一种可生物降解的手套的制备方法，包括如下步骤：
1、聚酰胺切片进入螺杆熔融纺纱区，将生物可降解添加剂按重量比为1%的比例通过注射器共混加入到纺纱流体中；经常规纺纱工艺，制备POY纤维，再经常规DTY的牵伸与假捻工艺，获得150D/48F的DTY纤维。纤维强度为3.8cn/dtex, 断裂伸长率为25%。所述生物可降解添加剂为可生物降解的低聚物聚酯和己醛醣以1:1组成的组合物。
2、采用普通手套机，织得手套，单只手套10-15克。
3、将水、丁腈和生物可降解添加剂混合后高速搅拌60min后静置60min充分硫化，得到可以使用的丁腈胶。
所述水、丁腈和生物可降解添加剂按重量份数计为：水5份，丁腈30份，生物可降解添加剂1份。所述生物可降解添加剂为可生物降解的低聚物聚酯和己醛醣已1:1组成的组合物。
4、将手套套在手模上后，将手模预热到40℃后浸胶，其中，将手芯表面浸粘丁腈胶后；通过盐池均匀的喷洒2g的氯化钠在丁腈胶上，形成附着后再将套有手套的手模置入温度为120℃的环境中烘烤5min；用清水冲洗，浸泡；将冲洗和浸泡后的手套置入温度为90℃的环境中烘烤5min。得到普通锦纶DTY的可生物降解的丁晴防滑手套。
实施例2，
一种可生物降解的手套的制备方法，包括如下步骤：
1、聚对苯二甲酸乙二酯切片经预结晶和干燥后，进入螺杆，在螺杆口处，用注射器注入重量比为1.5%比例的在50℃的环境中烘烤6h后的生物可降解添加剂，所述生物可降解添加剂为基于可生物降解的低聚物聚酯、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:1:1组成的组合物；在加热箱体中，两者共混成为熔融纺纱流体，经纺丝的初生纤维板及牵伸，卷曲和切断等常规纺纱工艺制备得到可生物降解的涤纶短纤维，规格是38mm*1.5dtex。纤维的强度为4.0cn/dtex，伸长率为25%。将可生物降解的涤纶短纤维经环锭纺的棉纺纺纱系统及常规纺纱工艺，得到可生物降解的涤纶短纤维的纱。
2、采用普通手套机，织得手套，单只手套10-15克。
3、在聚氨酯中共混加入二甲基甲酰胺和水作为溶剂，并同时共混加入含量为2%的生物可降解添加剂，高速搅拌30min后静置48min消泡，制得浸胶料备用。所述水、聚氨酯、二甲基甲酰胺和生物可降解添加剂按重量份数计为：水10份，聚氨酯 20份，二甲基甲酰胺10份，生物可降解添加剂2份。所述生物可降解添加剂为基于可生物降解的低聚物聚酯、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:1:1组成的组合物。
4、将手套套在手模上后，将手模预热到40℃后浸胶，手芯表面浸粘聚氨酯胶后。通过手模翻转匀胶，再进入水池中，通过1小时的流水浸泡，稀释掉二甲基甲酰胺，使聚氨酯凝固成型。再经过80℃烘箱，烘干。得到可生物降解的涤纶PU防滑手套。
实施例3，
一种可生物降解的手套的制备方法，包括如下步骤：
1、聚对苯二甲酸乙二酯切片经预结晶和干燥后，进入螺杆，在螺杆口处，用注射器注入重量比为1.5%比例的在50℃的环境中烘烤6h后的生物可降解添加剂，所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)、可生物降解的低聚物聚酯和己醛醣已1:3:3组成的组合物；在加热箱体中，两者共混成为熔融纺纱流体，经纺丝的初生纤维板及牵伸等常规的高强涤纶的纺纱工艺制备制得400D/96F的FDY涤纶长丝纱。长丝纱的强度为7.5cn/dtex，伸长率为20%。
将络好400D高强涤纶长丝纱的铝杯固定在纱锭上，将200D玻璃纤维长丝纱穿过纱线张力控制器和纱锭孔作为纱芯，将高强涤纶长丝纱作为外纱进行缠绕包覆，约500捻，制成高强涤纶包玻璃纤维长丝纱的手套用包覆纱线。
2、采用普通手套机，用针织组织和锦纶包氨纶纱线。用U2双层结构织得手套，单只手套20克。
3、将水、丁腈和生物可降解添加剂混合后高速搅拌60min后静置48min充分硫化，得到可以使用的丁腈胶。
所述水、丁腈和生物可降解添加剂按重量份数计为：水5份，丁腈50份，生物可降解添加剂1份。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)、可生物降解的低聚物聚酯和己醛醣已1:3:3组成的组合物。
4、将手套套在手模上后，将手模预热到60℃后浸胶，将手芯表面浸粘丁腈胶后；通过盐池均匀的喷洒3g的氯化钠在丁腈胶上，形成附着后再将套有手套的手模置入温度为100℃的环境中烘烤5min；用清水冲洗，浸泡；将冲洗和浸泡后的手套置入温度为90℃的环境中烘烤120min。得到可生物降解的高强涤纶防切割丁晴防滑手套。
实施例4
一种可生物降解的手套的制备方法，包括如下步骤：
在聚酰胺切片进入螺杆熔融纺纱区，将生物可降解添加剂按2%的比例，通过注射器共混加入到纺纱流体中；经常规的高强锦纶的纺纱工艺，制得到100D/48F的高强锦纶长丝纱。纤维强度为7cn/dtex, 断裂伸长率为110%。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)和己醛醣以质量比为1:1组成的组合物。
将络好100D/48F高强锦纶长丝纱的铝杯和络好400D高强聚乙烯HPPE的铝杯上下固定在纱锭上，将100D玻璃纤维长丝纱和0.05mm规格的304/316L的钢纱穿过纱线张力控制器和纱锭孔作为纱芯。将高强锦纶长丝纱（S向，800捻）和高强聚乙烯（Z向，300捻）作为外纱进行缠绕包覆。形成高强锦纶包玻纤/钢纱/HPPE的手套用切割包覆纱线。
2、采用普通手套机，用针织组织和锦纶包氨纶纱线。用U2双层结构织得手套，单只手套30克。
3、将水、丁腈和生物可降解添加剂混合后高速搅拌60min后静置48min充分硫化，得到可以使用的丁腈胶。
所述水、丁腈和生物可降解添加剂按重量份数计为：水30份，丁腈90份，生物可降解添加剂1份。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)和己醛醣以质量比为1:1组成的组合物。
4、将手套套在手模上后，将手模预热到60℃后浸胶，将手芯表面浸粘丁腈胶后；通过盐池均匀的喷洒 3g的芒硝在丁腈胶上，形成附着。通过初步90℃烘干硫化定性，再用水冲洗、浸泡附着在丁腈胶上的芒硝附着物。让芒硝彻底去掉，85℃两小时烘干。得到可生物降解的高强锦纶防切割丁晴防滑手套。
实施例5
一种可生物降解的手套的制备方法，包括如下步骤：
1、在聚酰胺切片，进入螺杆熔融纺纱区，将生物可降解添加剂按1.5%的比例，通过注射器，共混加入到纺纱流体中；经常规纺纱工艺，制备POY纤维，再经常规DTY的牵伸与假捻工艺，获得200D/96F的DTY纤维。纤维强度为4.2cn/dtex, 断裂伸长率为19%。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)和丁二胺的改性聚乳酸(BMPLA)以质量比为1:2的混合物。
将络好70D锦纶DTY长丝纱的铝杯和络好200D高强聚乙烯HPPE的铝杯上下固定在纱锭上，将0.02mm规格的钨纱穿过纱线张力控制器和纱锭孔作为纱芯。将锦纶DTY长丝纱（S向，700捻）和高强聚乙烯HPPE（Z向，300捻）作为外纱进行缠绕包覆。制成锦纶DTY包/HPPE/钨纱手套用切割包覆纱线。
2、采用普通手套机，用针织组织和锦纶包氨纶纱线。用U2双层结构织得手套，单只手套20克。
3、聚氨酯中共混加入二甲基甲酰胺和水作为溶剂，并同时共混加入含量为2%的生物可降解添加剂，高速搅拌30min后静置3h消泡，制得浸胶料备用。所述水、聚氨酯、二甲基甲酰胺和生物可降解添加剂按重量份数计为：水10份，聚氨酯 20份，二甲基甲酰胺10份，生物可降解添加剂2份。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:1:1组成的组合物。
将手套套在手模上后，将手模预热到40℃后浸胶，手芯表面浸粘聚氨酯胶后。通过手模翻转匀胶，再进入水池中，通过1小时的流水浸泡，稀释掉二甲基甲酰胺，使聚氨酯凝固成型。再经过80℃烘箱，烘干。得到高防切割的轻薄舒适的可生物降解的PU防滑手套。
对比例1
一种手套的制备方法，包括如下步骤：
1、经常规纺纱工艺，制备POY纤维，再经常规DTY的牵伸与假捻工艺，获得200D/96F的DTY纤维。
将络好70D锦纶DTY长丝纱的铝杯和络好200D高强聚乙烯HPPE的铝杯上下固定在纱锭上，将0.02mm规格的钨纱穿过纱线张力控制器和纱锭孔作为纱芯。将锦纶DTY长丝纱（S向，700捻）和高强聚乙烯HPPE（Z向，300捻）作为外纱进行缠绕包覆。制成锦纶DTY包/HPPE/钨纱手套用切割包覆纱线。
2、采用普通手套机，用针织组织和锦纶包氨纶纱线。用U2双层结构织得手套，单只手套20克。
3、聚氨酯中共混加入二甲基甲酰胺和水，高速搅拌30min后静置3h消泡，制得浸胶料备用。所述水、聚氨酯和二甲基甲酰胺按重量份数计为：水10份，聚氨酯 20份，二甲基甲酰胺10份。
将手套套在手模上后，将手模预热到40℃后浸胶，手芯表面浸粘聚氨酯胶后。通过手模翻转匀胶，再进入水池中，通过1小时的流水浸泡，稀释掉二甲基甲酰胺，使聚氨酯凝固成型。再经过80℃烘箱，烘干。得到高防切割的轻薄舒适的PU防滑手套。
对比例2
一种可生物降解的手套的制备方法，包括如下步骤：
1、经常规纺纱工艺，制备POY纤维，再经常规DTY的牵伸与假捻工艺，获得200D/96F的DTY纤维。
将络好70D锦纶DTY长丝纱的铝杯和络好200D高强聚乙烯HPPE的铝杯上下固定在纱锭上，将0.02mm规格的钨纱穿过纱线张力控制器和纱锭孔作为纱芯。将锦纶DTY长丝纱（S向，700捻）和高强聚乙烯HPPE（Z向，300捻）作为外纱进行缠绕包覆。制成锦纶DTY包/HPPE/钨纱手套用切割包覆纱线。
2、采用普通手套机，用针织组织和锦纶包氨纶纱线。用U2双层结构织得手套，单只手套20克。
3、聚氨酯中共混加入二甲基甲酰胺和水作为溶剂，并同时共混加入含量为2%的生物可降解添加剂，高速搅拌30min后静置3h消泡，制得浸胶料备用。所述水、聚氨酯、二甲基甲酰胺和生物可降解添加剂按重量份数计为：水10份，聚氨酯 20份，二甲基甲酰胺10份，生物可降解添加剂2份。所述生物可降解添加剂为基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)和己醛醣已1:1:1组成的组合物。
将手套套在手模上后，将手模预热到40℃后浸胶，手芯表面浸粘聚氨酯胶后。通过手模翻转匀胶，再进入水池中，通过1小时的流水浸泡，稀释掉二甲基甲酰胺，使聚氨酯凝固成型。再经过80℃烘箱，烘干。得到高防切割的轻薄舒适的可生物降解的PU防滑手套。
分别对实施例1-5和对比例1-2制备出来的可生物降解手套进行性能测试，其中，耐磨性测试标准使用欧盟EN388；防滑性评价是让5员工戴上手套，握持直径为30mm不锈钢棒，评价为1-5分。5分表示夹紧力非常高，4分表示夹紧力高，3分表示略有夹紧力，2分表示不易滑动，1份表示夹紧力低；可降解性能测试；生物降解率：ISO ：14855。
测试结果见下表：
防滑性 耐磨性 可降解率
实施例1 4 4级 大于80%
实施例2 4 4级 大于80%
实施例3 5 4级 大于75%
实施例4 5 4级 大于75%
实施例5 4 4级 大于75%
对比例1 4 4级 不易降解
对比例2 4 4级 不易降解
由上表可见，本发明制备的可生物降解的手套不仅保持了良好的防滑性和耐磨性且有好的生物降解性。
以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变形或修改，这并不影响本发明的实质内容。

Claims (2)

1.一种可生物降解的手套的制备方法，其特征在于，包括如下步骤：
S1， 将络好纱的铝杯固定在纱锭上，将玻璃纤维或钢纱金属穿过纱线张力控制器和纱锭孔作为纱芯，或将玻璃纤维或钢纱金属穿过纱线张力控制器后穿在捻线机器上作为纱芯，将生物可降解长丝纱或短纤维纱作为外纱进行缠绕包覆，形成手套用包覆纱线，再在手套机上织成纺织品手套；S2,纺织品手套浸胶后形成可生物降解的手套；
步骤S1中所述生物可降解长丝纱的制备方法为：将生物可降解添加剂在50-90℃的环境中烘烤2-6h后，共混加入到经预结晶和干燥后的聚对苯二甲酸乙二醇酯中，经纺丝的初生纤维、牵伸后得到预牵伸的长丝纱，再经热牵伸及假捻卷曲工艺，制备为生物可降解长丝纱；
步骤S1中所述短纤维纱的制备方法为：将生物可降解添加剂在50-90℃的环境中烘烤2-6h后，共混加入到经预结晶和干燥后的聚对苯二甲酸乙二醇酯中，经纺丝的初生纤维、牵伸后再经卷曲和切断制造得到的短纤维，再纺纱后得到短纤维纱；
所述浸胶过程包括如下步骤，
S21拌料；
S22手模预热：将手套套在手模上后，将手模预热到40-90℃；
S23浸涂，匀胶；
S24烘烤：将套有手套的手模置入温度为90-120℃的环境中烘烤1-20min；
S25用清水冲洗，浸泡；
S26烘烤：将冲洗和浸泡后的手套置入温度为90-120℃的环境中烘烤1-20min；
步骤S21拌料中所述原料包括水、聚氨酯、二甲基甲酰胺和生物可降解添加剂或水、丁腈和生物可降解添加剂；
当原料为水、聚氨酯、二甲基甲酰胺和生物可降解添加剂时，拌料步骤为将水、聚氨酯、二甲基甲酰胺和生物可降解添加剂混合后高速搅拌10-60min后静置1-48min，所述水、聚氨酯、二甲基甲酰胺和生物可降解添加剂按重量份数计为：
水 10-80份
聚氨酯 20-80份
二甲基甲酰胺 10-50份
生物可降解添加剂 0.5-10份
当原料为水、丁腈和生物可降解添加剂时，拌料步骤为将水、丁腈和生物可降解添加剂混合后高速搅拌10-60min后静置1-48h，所述水、丁腈和生物可降解添加剂按重量份数计为：
水 5-80份
丁腈 15-94.5份
生物可降解添加剂 0.5-10份
所述生物可降解添加剂为天然纤维素、聚乙烯醇、可生物降解的低聚物聚酯、基于马来酸酐改性聚乳酸(MPLA)、丁二胺的改性聚乳酸(BMPLA)、单糖中的至少一种。
2.一种生物可降解手套，其特征在于：使用权利要求1所述制备方法制备而得。
CN202011448686.2A 2020-12-09 2020-12-09 一种可生物降解的手套及其制备方法 Active CN112647312B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011448686.2A CN112647312B (zh) 2020-12-09 2020-12-09 一种可生物降解的手套及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011448686.2A CN112647312B (zh) 2020-12-09 2020-12-09 一种可生物降解的手套及其制备方法

Publications (2)

Publication Number Publication Date
CN112647312A CN112647312A (zh) 2021-04-13
CN112647312B true CN112647312B (zh) 2021-12-21

Family

ID=75353733

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011448686.2A Active CN112647312B (zh) 2020-12-09 2020-12-09 一种可生物降解的手套及其制备方法

Country Status (1)

Country Link
CN (1) CN112647312B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2813722C1 (ru) * 2023-03-09 2024-02-15 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" ФГБОУВО "ЯГТУ" Полимерный композиционный материал, содержащий стимуляторы биоразложения, для производства маканых изделий

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114214783B (zh) * 2021-12-20 2023-03-17 浙江优全护理用品科技股份有限公司 一种可降解的去油污湿巾及其制备方法
US20230357964A1 (en) * 2022-05-05 2023-11-09 Molyvivi (Shanghai) Clothing Technology Co., Ltd. Biodegradable glove and a preparation method thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY142766A (en) * 2005-08-26 2010-12-31 Duramitt Sdn Bhd Method and article of manufacturing a waterborne polyurethane coated glove liner
US20070207282A1 (en) * 2006-03-01 2007-09-06 Hamann Curtis P Polylactic Acid Gloves and Methods of Manufacturing Same
CN102746689A (zh) * 2012-06-15 2012-10-24 盐城金沃医疗科技有限公司 生物可降解医用塑料的生产方法
CN109072490A (zh) * 2016-04-04 2018-12-21 罗地亚聚酰胺特殊品公司 可生物降解的聚酰胺纤维，用于获得此种纤维的方法以及由其制成的聚酰胺制品
CN107668807B (zh) * 2017-10-23 2021-04-13 南通强生安全防护科技股份有限公司 一种聚氨酯浸胶手套的制备方法
CN108384222B (zh) * 2018-02-28 2021-08-10 山东星宇手套有限公司 一种水性聚氨酯涂层手套及其制备方法
CN108556390B (zh) * 2018-04-18 2021-03-16 山东星宇手套有限公司 一种防滑防化磨砂手套的制作方法
CN109454792B (zh) * 2018-09-23 2020-12-01 南通嘉得利安全用品有限公司 一种水性聚氨酯浸胶手套及其生产方法
CN109322002A (zh) * 2018-10-10 2019-02-12 无锡沛莱斯纺织有限公司 一种生物可降解聚酯织物及其制备方法
CN111235688A (zh) * 2020-03-19 2020-06-05 苏州市佩发刺绣工艺品有限公司 一种可生物降解的聚酯纤维及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2813722C1 (ru) * 2023-03-09 2024-02-15 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" ФГБОУВО "ЯГТУ" Полимерный композиционный материал, содержащий стимуляторы биоразложения, для производства маканых изделий

Also Published As

Publication number Publication date
CN112647312A (zh) 2021-04-13

Similar Documents

Publication Publication Date Title
AU606462B2 (en) High-tenacity conjugated fiber and process for preparation thereof
CN112647312B (zh) 一种可生物降解的手套及其制备方法
JP2530805B2 (ja) ナイロンの絨緞用繊維の染色性を改善する方法
CN112941924B (zh) 一种抗起毛起球涤棉针织面料及其制备方法
CN112501702B (zh) 一种功能性聚酰胺56长丝及其制备方法
TWI555889B (zh) Polyester fiber for rubber reinforcing and its manufacturing method
CN1066212C (zh) 制造连续聚酯长丝纱的方法及该长丝纱的用途
CN107326456B (zh) 一种利用基础油剂作为第一道上油的活化丝生产方法
CN1323210C (zh) 甲壳质应用于纤维抗菌的加工方法
JPS5953736A (ja) ポリエステルタイヤコ−ド及びその製法
JPH05156513A (ja) 高強度ポリアミド繊維及びその製造方法
US20230357964A1 (en) Biodegradable glove and a preparation method thereof
CN108914228A (zh) 土工织物用高模低伸涤纶工业丝及其生产方法
AU704513B2 (en) Delustered nylon filaments with striations of polymethylpentene
JP2023548124A (ja) エラストマー製品、特には車両用タイヤのためのゴム被覆された少なくとも１種の第一のヤーンを含む強度メンバー、ゴム被覆された強度メンバーを製造するための方法、及び少なくとも１種のゴム被覆された強度メンバーを有する車両用タイヤ
US2339408A (en) Manufacture of artificial materials
CN113604932A (zh) 全涤消光磨毛仿棉面料及其生产方法
CN113186615A (zh) 一种环保性抗菌锦纶复合包覆丝及其制备方法
JPS60185833A (ja) ゴム補強用ポリエステル繊維デイツプコ−ド
JP5302739B2 (ja) 高強力ポリヘキサメチレンアジパミド繊維
JP2858429B2 (ja) 予備接着剤が施されているポリエステルフィラメント系の製造方法およびこのポリエステルフィラメント系から製造したタイヤコード
JPH0274612A (ja) 高強度複合繊維
JP2853961B2 (ja) 伝動ベルト用ポリエステル繊維及びその製法
CN101705560A (zh) 经向粘胶面料及其制造方法
CN112941684A (zh) 一种高韧性抗断裂的纺织丝线

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant