CN112236312A - 具有包括一种或多种热塑性弹性体和一种或多种合成二烯弹性体的外胎侧的轮胎 - Google Patents
具有包括一种或多种热塑性弹性体和一种或多种合成二烯弹性体的外胎侧的轮胎 Download PDFInfo
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- CN112236312A CN112236312A CN201980036644.7A CN201980036644A CN112236312A CN 112236312 A CN112236312 A CN 112236312A CN 201980036644 A CN201980036644 A CN 201980036644A CN 112236312 A CN112236312 A CN 112236312A
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- thermoplastic
- styrene
- elastomer
- thermoplastic elastomer
- block
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- UYCAUPASBSROMS-AWQJXPNKSA-M sodium;2,2,2-trifluoroacetate Chemical compound [Na+].[O-][13C](=O)[13C](F)(F)F UYCAUPASBSROMS-AWQJXPNKSA-M 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
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- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
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FR1854668A FR3081873B1 (fr) | 2018-05-31 | 2018-05-31 | Pneumatique pourvu d'un flanc externe comportant un ou plusieurs elastomeres thermoplastiques et un ou plusieurs elastomeres dieniques synthetiques |
FR18/54668 | 2018-05-31 | ||
PCT/FR2019/051128 WO2019229327A2 (fr) | 2018-05-31 | 2019-05-17 | Pneumatique pourvu d'un flanc externe comportant un ou plusieurs elastomeres thermoplastiques et un ou plusieurs elastomeres dieniques synthetiques |
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CN112236312A true CN112236312A (zh) | 2021-01-15 |
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CN201980036644.7A Pending CN112236312A (zh) | 2018-05-31 | 2019-05-17 | 具有包括一种或多种热塑性弹性体和一种或多种合成二烯弹性体的外胎侧的轮胎 |
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CN (1) | CN112236312A (fr) |
FR (1) | FR3081873B1 (fr) |
WO (1) | WO2019229327A2 (fr) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1255150A (zh) * | 1997-05-05 | 2000-05-31 | 埃克森化学专利公司 | 用于轮胎侧壁和其它橡胶制品的组合物 |
CN103975012A (zh) * | 2011-12-16 | 2014-08-06 | 米其林集团总公司 | 设置有由二烯弹性体和热塑性弹性体的混合物制成的胎面的轮胎 |
CN103987776A (zh) * | 2011-12-16 | 2014-08-13 | 米其林集团总公司 | 设置有包含二烯弹性体和热塑性弹性体的混合物的外部胎侧的轮胎 |
CN106661279A (zh) * | 2014-06-30 | 2017-05-10 | 米其林集团总公司 | 具有包含热塑性弹性体和二烯弹性体的胎面的轮胎 |
CN107709039A (zh) * | 2015-06-18 | 2018-02-16 | 米其林集团总公司 | 设置有包含二烯弹性体和热塑性弹性体体系的胎面的轮胎 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63156841A (ja) | 1986-12-22 | 1988-06-29 | Yokohama Rubber Co Ltd:The | 空気入りラジアルタイヤ |
US4946899A (en) | 1988-12-16 | 1990-08-07 | The University Of Akron | Thermoplastic elastomers of isobutylene and process of preparation |
FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
AU2600097A (en) | 1996-04-01 | 1997-10-22 | Cabot Corporation | Novel elastomer composites, method and apparatus |
FR2765882B1 (fr) | 1997-07-11 | 1999-09-03 | Michelin & Cie | Composition de caoutchouc a base de noir de carbone ayant de la silice fixee a sa surface et de polymere dienique fonctionnalise alcoxysilane |
EP0958298B2 (fr) | 1997-08-21 | 2008-10-22 | Momentive Performance Materials Inc. | Agents de couplage a base de mercaptosilanes bloques, utilises dans des caoutchoucs a charge |
EP1019228B1 (fr) | 1997-09-30 | 2004-12-01 | Cabot Corporation | Melanges composites a base d'elastomere et procedes d'elaboration |
US6761198B2 (en) | 1999-03-02 | 2004-07-13 | The Goodyear Tire & Rubber Company | Pneumatic tire having lug and groove configuration extending from tread over at least 30% of sidewall |
US20020011293A1 (en) | 1999-03-02 | 2002-01-31 | David John Zanzig | Tire with reinforced rubber sidewall |
FR2800741A1 (fr) | 1999-11-08 | 2001-05-11 | Michelin Soc Tech | Enveloppe de pneumatique dont les flancs comprennent une composition de caoutchouc vulcanisee |
EP1127909B1 (fr) | 2000-02-24 | 2005-03-09 | Société de Technologie Michelin | Composition de caoutchouc vulcanisable, utilisable pour fabriquer un pneumatique, et pneumatique comprenant cette composition |
CA2380375A1 (fr) | 2000-05-26 | 2001-12-06 | Michelin Recherche Et Technique S.A. | Composition de caoutchouc utilisable comme bande de roulement de pneumatique |
CN1263792C (zh) | 2000-10-13 | 2006-07-12 | 米其林技术公司 | 包含多官能有机硅烷作为偶联剂的橡胶组合物 |
MXPA03003244A (es) | 2000-10-13 | 2003-10-15 | Michelin Rech Tech | Organosilano polifuncional utilizable como agente de acoplamiento y su procedimiento de obtencion. |
FR2823215B1 (fr) | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
EP1285926B1 (fr) | 2001-08-06 | 2004-05-12 | Degussa AG | Composés Organosiliciés |
SE519792C2 (sv) | 2001-08-17 | 2003-04-08 | Volvo Lastvagnar Ab | Metod för estimering av massan hos ett fordon vilket framförs på en väg med en varierande lutning samt metod för estimering av lutningen av den väg där ett fordon framförs |
US6994137B2 (en) | 2002-04-26 | 2006-02-07 | The Goodyear Tire & Rubber Company | Tire with component of carbon black rich rubber composition which contains alkylphenoxypoly (alkyleneoxy) alkanol |
JP4562384B2 (ja) | 2003-03-26 | 2010-10-13 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
FR2854404B1 (fr) | 2003-04-29 | 2005-07-01 | Michelin Soc Tech | Procede d'obtention d'un elastomere greffe a groupes fonctionnels le long de la chaine et compositions de caoutchouc |
US7928258B2 (en) | 2004-08-20 | 2011-04-19 | Momentive Performance Materials Inc. | Cyclic diol-derived blocked mercaptofunctional silane compositions |
FR2880354B1 (fr) | 2004-12-31 | 2007-03-02 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise |
FR2880349B1 (fr) | 2004-12-31 | 2009-03-06 | Michelin Soc Tech | Nanoparticules de polyvinylaromatique fonctionnalise |
FR2886305B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
FR2886304B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
FR2886306B1 (fr) | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
WO2007061550A1 (fr) | 2005-11-16 | 2007-05-31 | Dow Corning Corporation | Organosilanes et leur preparation et utilisation dans des compositions d’elastomere |
US7510670B2 (en) | 2006-02-21 | 2009-03-31 | Momentive Performance Materials Inc. | Free flowing filler composition based on organofunctional silane |
FR2903416B1 (fr) | 2006-07-06 | 2008-09-05 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polymere vinylique non aromatique fonctionnalise |
FR2903411B1 (fr) | 2006-07-06 | 2012-11-02 | Soc Tech Michelin | Nanoparticules de polymere vinylique fonctionnalise |
FR2908410A1 (fr) | 2006-11-10 | 2008-05-16 | Rhodia Recherches & Tech | Procede de preparation d'alcoxysilanes (poly)sulfures et nouveaux produits intermediaires dans ce procede |
FR2940290B1 (fr) | 2008-12-22 | 2010-12-31 | Michelin Soc Tech | Agent de couplage mercaptosilane bloque |
FR3059004A1 (fr) * | 2016-11-18 | 2018-05-25 | Compagnie Generale Des Etablissements Michelin | Pneumatique pourvu d'un flanc externe a base d'au moins un melange d'elastomere dienique et de cire |
-
2018
- 2018-05-31 FR FR1854668A patent/FR3081873B1/fr active Active
-
2019
- 2019-05-17 CN CN201980036644.7A patent/CN112236312A/zh active Pending
- 2019-05-17 WO PCT/FR2019/051128 patent/WO2019229327A2/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1255150A (zh) * | 1997-05-05 | 2000-05-31 | 埃克森化学专利公司 | 用于轮胎侧壁和其它橡胶制品的组合物 |
CN103975012A (zh) * | 2011-12-16 | 2014-08-06 | 米其林集团总公司 | 设置有由二烯弹性体和热塑性弹性体的混合物制成的胎面的轮胎 |
CN103987776A (zh) * | 2011-12-16 | 2014-08-13 | 米其林集团总公司 | 设置有包含二烯弹性体和热塑性弹性体的混合物的外部胎侧的轮胎 |
CN106661279A (zh) * | 2014-06-30 | 2017-05-10 | 米其林集团总公司 | 具有包含热塑性弹性体和二烯弹性体的胎面的轮胎 |
CN107709039A (zh) * | 2015-06-18 | 2018-02-16 | 米其林集团总公司 | 设置有包含二烯弹性体和热塑性弹性体体系的胎面的轮胎 |
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FR3081873B1 (fr) | 2020-05-22 |
WO2019229327A3 (fr) | 2020-01-23 |
FR3081873A1 (fr) | 2019-12-06 |
WO2019229327A2 (fr) | 2019-12-05 |
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