CN112176717A - 一种可以降低织物在洗涤过程中织物磨损的处理工艺 - Google Patents
一种可以降低织物在洗涤过程中织物磨损的处理工艺 Download PDFInfo
- Publication number
- CN112176717A CN112176717A CN202011033004.1A CN202011033004A CN112176717A CN 112176717 A CN112176717 A CN 112176717A CN 202011033004 A CN202011033004 A CN 202011033004A CN 112176717 A CN112176717 A CN 112176717A
- Authority
- CN
- China
- Prior art keywords
- fabric
- concentration
- solution
- solid
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 101
- 238000005406 washing Methods 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 44
- 230000008569 process Effects 0.000 title claims abstract description 37
- 238000005299 abrasion Methods 0.000 title claims abstract description 25
- 238000007747 plating Methods 0.000 claims abstract description 59
- 239000002131 composite material Substances 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000002135 nanosheet Substances 0.000 claims abstract description 32
- 238000001035 drying Methods 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 206010070834 Sensitisation Diseases 0.000 claims abstract description 17
- 230000004913 activation Effects 0.000 claims abstract description 17
- 239000012153 distilled water Substances 0.000 claims abstract description 17
- 230000008313 sensitization Effects 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 108
- 239000000243 solution Substances 0.000 claims description 94
- 239000007787 solid Substances 0.000 claims description 68
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 66
- 238000003756 stirring Methods 0.000 claims description 48
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 44
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 32
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 32
- 238000005303 weighing Methods 0.000 claims description 31
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 29
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 29
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 29
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 29
- 235000019441 ethanol Nutrition 0.000 claims description 28
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 22
- 239000004310 lactic acid Substances 0.000 claims description 22
- 235000014655 lactic acid Nutrition 0.000 claims description 22
- 239000001632 sodium acetate Substances 0.000 claims description 22
- 235000017281 sodium acetate Nutrition 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 20
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 18
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 17
- 239000003381 stabilizer Substances 0.000 claims description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000003960 organic solvent Substances 0.000 claims description 16
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 12
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 229910021389 graphene Inorganic materials 0.000 claims description 11
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 9
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 8
- 229920002334 Spandex Polymers 0.000 claims description 8
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 8
- 230000003213 activating effect Effects 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 8
- 230000001235 sensitizing effect Effects 0.000 claims description 8
- 239000004759 spandex Substances 0.000 claims description 8
- 239000001119 stannous chloride Substances 0.000 claims description 8
- 235000011150 stannous chloride Nutrition 0.000 claims description 8
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 7
- 229910001453 nickel ion Inorganic materials 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- -1 iron ions Chemical class 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 229920004933 Terylene® Polymers 0.000 claims description 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 2
- UUYKGYZJARXSGB-UHFFFAOYSA-N ethanol;ethoxy(trihydroxy)silane Chemical compound CCO.CCO[Si](O)(O)O UUYKGYZJARXSGB-UHFFFAOYSA-N 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 7
- 230000000052 comparative effect Effects 0.000 description 10
- NASVITFAUKYCPM-UHFFFAOYSA-N ethanol;tetraethyl silicate Chemical compound CCO.CCO[Si](OCC)(OCC)OCC NASVITFAUKYCPM-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910001447 ferric ion Inorganic materials 0.000 description 2
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229910018104 Ni-P Inorganic materials 0.000 description 1
- 229910018536 Ni—P Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013400 design of experiment Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Chemically Coating (AREA)
Abstract
本发明公开了一种可以降低织物在洗涤过程中织物磨损的处理工艺,涉及织物处理技术领域,具体工艺如下:1)制得改性类水滑石纳米片复合物;2)配制纳米二氧化硅溶胶;3)配制复合镀液;4)将织物面料清洗后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,将活化处理好的织物面料放入复合镀液中进行施镀,取出织物面料后用蒸馏水反复冲洗,烘干后即可。本发明中,采用化学镀的方式将改性类水滑石纳米片复合物固定在织物表面,在织物表面形成具有减摩作用的复合物层,可以有效的降低织物在洗涤过程中受到的摩擦作用,从而降低织物表面的磨损,提升织物的服用性能。
Description
技术领域
本发明属于织物处理技术领域,具体涉及一种可以降低织物在洗涤过程中织物磨损的处理工艺。
背景技术
洗衣机洗涤时,衣物在洗涤桶内被水流冲击、穿透,随之翻滚、缠绕、拧搅,再被洗净的同时也不可能避免的被磨损,随着洗涤次数的增多可能会导致其破裂。
洗涤机械力是洗净衣物必不可少的作用力。洗涤时的机械力可分为水流冲击力、水流弯曲作用力、摩擦力等,其中对洗净衣物贡献最大的是摩擦力。然而在洗涤时,织物与筒壁及波轮间的摩擦力会导致织物磨损更严重。洗涤时波轮的转速及洗涤时间与洗净率及磨损有直接相关的关系。在一定范围内,随着转速的增大及洗涤周期的增长,在洗净率提高的同时,衣物的缠绕及磨损也会变大。因此,如何在保证衣物洗净率的同时减少面料磨损,对提高织物的服用性能尤为重要。
发明内容
本发明的目的是针对现有的问题,提供了一种可以降低织物在洗涤过程中织物磨损的处理工艺。
本发明是通过以下技术方案实现的:
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1)将适量的氧化石墨烯分散于质量分数为50-55%的甲酰胺溶液中,得到浓度为0.3-0.5mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,控制混合液中铁离子的浓度为10-15mM,镍离子的浓度为20-30mM,在100-160r/min搅拌过程中,缓慢滴加0.7-0.8M氢氧化钠溶液,持续反应5-6h,待pH为10-10.5时终止反应,继续搅拌1-2h后静置4-6h,收集沉淀,用无水乙醇和去离子水交替清洗3-4次,经55-65℃烘干10-15h,得到改性类水滑石纳米片复合物;本发明中,在甲酰胺溶液中,由于正负离子键的静电作用,富含羟基和羧基、带负电的氧化石墨烯会将溶液中的金属镍离子和铁离子吸附在其表面,在进行共沉淀时,这些固定在氧化石墨烯表面的金属离子可以作为氧化石墨烯纳米片上镍铁类水滑石纳米片原位生长的成核位点,并且在水滑石纳米片的生长过程中,甲酰胺分子通过吸附在镍铁类水滑石表面,强烈抑制水滑石层Z轴方向上的横长,从而使得可到超薄结构的改性类水滑石纳米片复合物,形成的改性类水滑石纳米片复合物具有多片层结构,固着在织物表面时,片层与片层之间的剪切滑移代替了两物体之间的的摩擦滑移,可以降低摩擦力,从而可以降低对织物表面的磨损;
2)量取两份等体积的无水乙醇,称取适量的正硅酸乙酯固体,溶解于一份无水乙醇中搅拌30-40min,得到质量浓度为2-6%的正硅酸乙酯乙醇溶液,量取一定量质量分数为22-25%的浓氨水添加到另一份无水乙醇中,控制浓氨水与正硅酸乙酯乙醇溶液的比例为0.5-2mL/L,在20-40℃和80-120r/min搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置3-4h后将得到的乳浊液放在通风处2-3h,即可得到纳米二氧化硅溶胶;
3)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为4.5-5.5,得到复合镀液;本发明中,通过在常规的Ni-P化学镀液中引入纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,引入的纳米二氧化硅会直接影响基质金属的整个结晶过程,细化晶粒,使得晶粒达到纳米尺度,获得纳米晶结构的镀层,从而提高了镀层的致密度和均匀度,并且纳米二氧化硅与镀层结合,均匀分布在镀层内部和表面,从而使得镀层硬度得到提升,从而提高了镀层的耐磨性,使得镀层在长期洗涤过程中不易断裂,从而可以降低改性类水滑石纳米片复合物的流失,可以间接的降低织物表面的磨损;引入的改性类水滑石纳米片复合物嵌固的镀层表面,在镀层表面形成多片层结构的复合物层,形成的复合物层在织物表面起到减摩作用,从而实现织物在洗涤过程中磨损量降低的技术效果;
4)选用丙酮和乙醇(质量分数95%)按体积比为2-3:1组成有机溶剂,将织物面料采用有机溶剂以200-300W超声处理30-40min,取出后在70-90℃下干燥40-50min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75-95℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8-10min搅拌一次,转速为100-300r/min,施镀40-60min后取出织物面料,用蒸馏水反复冲洗,在70-90℃下干燥40-50min后即可;本发明中,通过化学镀的方式,将具有减摩作用的改性类水滑石纳米片复合物固定在织物表面,形成的镀层可以提高该复合物与织物基体之间的结合强度,提高改性类水滑石纳米片复合物在织物表面的附着性能。
进一步,复合镀液中,硫酸镍浓度20-30g/L,次亚磷酸钠浓度为15-35g/L,乙酸钠浓度为10-13g/L,柠檬酸浓度为20-24g/L,乳酸浓度为15-19mL/L,稳定剂浓度为0.5-2.5mg/L,纳米二氧化硅溶胶的含量为10-25mL/L,改性类水滑石纳米片复合物的含量为15-25g/L;所述稳定剂选自2-巯基苯并噻唑、2-巯基苯并咪唑中至少一种。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5-6g/L,pH值为1.5-2;所述敏化处理温度为30-35℃,处理时间10-15min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2-2.3L组成;所述活化处理温度为30-35℃,处理时间8-10min。
进一步,所述织物面料为化学合成防治面料,为涤纶、氨纶、腈纶、腈纶中至少一种。
本发明相比现有技术具有以下优点:
本发明中,采用化学镀的方式将改性类水滑石纳米片复合物固定在织物表面,在织物表面形成具有减摩作用的复合物层,可以有效的降低织物在洗涤过程中受到的摩擦作用,从而降低织物表面的磨损,提升织物的服用性能。
具体实施方式
下面结合具体实施方法对本发明做进一步的说明。
实施例1
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1)将适量的氧化石墨烯分散于质量分数为50%的甲酰胺溶液中,得到浓度为0.3mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,控制混合液中铁离子的浓度为10mM,镍离子的浓度为20mM,在100r/min搅拌过程中,缓慢滴加0.7M氢氧化钠溶液,持续反应5h,待pH为10时终止反应,继续搅拌1h后静置4h,收集沉淀,用无水乙醇和去离子水交替清洗3次,经55℃烘干10h,得到改性类水滑石纳米片复合物;
2)量取两份等体积的无水乙醇,称取适量的正硅酸乙酯固体,溶解于一份无水乙醇中搅拌30min,得到质量浓度为2%的正硅酸乙酯乙醇溶液,量取一定量质量分数为22%的浓氨水添加到另一份无水乙醇中,控制浓氨水与正硅酸乙酯乙醇溶液的比例为0.5mL/L,在20℃和80r/min搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置3h后将得到的乳浊液放在通风处2h,即可得到纳米二氧化硅溶胶;
3)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为4.5,得到复合镀液;
4)选用丙酮和乙醇(质量分数95%)按体积比为2:1组成有机溶剂,将涤纶织物面料采用有机溶剂以200W超声处理30min,取出后在70℃下干燥40min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8min搅拌一次,转速为100r/min,施镀40min后取出织物面料,用蒸馏水反复冲洗,在70℃下干燥40min后即可。
进一步,复合镀液中,硫酸镍浓度20g/L,次亚磷酸钠浓度为35g/L,乙酸钠浓度为10g/L,柠檬酸浓度为24g/L,乳酸浓度为19mL/L,稳定剂2-巯基苯并噻唑浓度为2.5mg/L,纳米二氧化硅溶胶的含量为25mL/L,改性类水滑石纳米片复合物的含量为25g/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5g/L,pH值为1.5;所述敏化处理温度为30℃,处理时间10min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2L组成;所述活化处理温度为30℃,处理时间8min。
实施例2
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1)将适量的氧化石墨烯分散于质量分数为52%的甲酰胺溶液中,得到浓度为0.4mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,控制混合液中铁离子的浓度为12mM,镍离子的浓度为24mM,在150r/min搅拌过程中,缓慢滴加0.75M氢氧化钠溶液,持续反应5.5h,待pH为10.3时终止反应,继续搅拌1.5h后静置5h,收集沉淀,用无水乙醇和去离子水交替清洗3次,经60℃烘干12h,得到改性类水滑石纳米片复合物;
2)量取两份等体积的无水乙醇,称取适量的正硅酸乙酯固体,溶解于一份无水乙醇中搅拌35min,得到质量浓度为4%的正硅酸乙酯乙醇溶液,量取一定量质量分数为23%的浓氨水添加到另一份无水乙醇中,控制浓氨水与正硅酸乙酯乙醇溶液的比例为1.5mL/L,在30℃和100r/min搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置4h后将得到的乳浊液放在通风处2h,即可得到纳米二氧化硅溶胶;
3)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为5.0,得到复合镀液;
4)选用丙酮和乙醇(质量分数95%)按体积比为2.5:1组成有机溶剂,将氨纶织物面料采用有机溶剂以250W超声处理35min,取出后在80℃下干燥45min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为85℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔9min搅拌一次,转速为200r/min,施镀50min后取出织物面料,用蒸馏水反复冲洗,在80℃下干燥45min后即可。
进一步,复合镀液中,硫酸镍浓度25g/L,次亚磷酸钠浓度为25g/L,乙酸钠浓度为11g/L,柠檬酸浓度为22g/L,乳酸浓度为17mL/L,稳定剂2-巯基苯并咪唑浓度为2.0mg/L,纳米二氧化硅溶胶的含量为18mL/L,改性类水滑石纳米片复合物的含量为20g/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5.5g/L,pH值为2;所述敏化处理温度为32℃,处理时间13min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2.1L组成;所述活化处理温度为32℃,处理时间9min。
实施例3
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1)将适量的氧化石墨烯分散于质量分数为55%的甲酰胺溶液中,得到浓度为0.5mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,控制混合液中铁离子的浓度为15mM,镍离子的浓度为30mM,在160r/min搅拌过程中,缓慢滴加0.8M氢氧化钠溶液,持续反应6h,待pH为10.5时终止反应,继续搅拌2h后静置6h,收集沉淀,用无水乙醇和去离子水交替清洗4次,经65℃烘干15h,得到改性类水滑石纳米片复合物;
2)量取两份等体积的无水乙醇,称取适量的正硅酸乙酯固体,溶解于一份无水乙醇中搅拌40min,得到质量浓度为6%的正硅酸乙酯乙醇溶液,量取一定量质量分数为25%的浓氨水添加到另一份无水乙醇中,控制浓氨水与正硅酸乙酯乙醇溶液的比例为2mL/L,在40℃和120r/min搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置4h后将得到的乳浊液放在通风处3h,即可得到纳米二氧化硅溶胶;
3)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为5.5,得到复合镀液;
4)选用丙酮和乙醇(质量分数95%)按体积比为3:1组成有机溶剂,将腈纶织物面料采用有机溶剂以300W超声处理40min,取出后在90℃下干燥50min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75-95℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔10min搅拌一次,转速为300r/min,施镀60min后取出织物面料,用蒸馏水反复冲洗,在90℃下干燥50min后即可。
进一步,复合镀液中,硫酸镍浓度30g/L,次亚磷酸钠浓度为15g/L,乙酸钠浓度为10g/L,柠檬酸浓度为20g/L,乳酸浓度为15mL/L,稳定剂2-巯基苯并噻唑浓度为0.5mg/L,纳米二氧化硅溶胶的含量为10mL/L,改性类水滑石纳米片复合物的含量为15g/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为6g/L,pH值为2;所述敏化处理温度为35℃,处理时间15min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2.3L组成;所述活化处理温度为35℃,处理时间10min。
对比例1
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1)将适量的氧化石墨烯分散于质量分数为50%的甲酰胺溶液中,得到浓度为0.3mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,控制混合液中铁离子的浓度为10mM,镍离子的浓度为20mM,在100r/min搅拌过程中,缓慢滴加0.7M氢氧化钠溶液,持续反应5h,待pH为10时终止反应,继续搅拌1h后静置4h,收集沉淀,用无水乙醇和去离子水交替清洗3次,经55℃烘干10h,得到改性类水滑石纳米片复合物;
2)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为4.5,得到复合镀液;
3)选用丙酮和乙醇(质量分数95%)按体积比为2:1组成有机溶剂,将涤纶织物面料采用有机溶剂以200W超声处理30min,取出后在70℃下干燥40min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8min搅拌一次,转速为100r/min,施镀40min后取出织物面料,用蒸馏水反复冲洗,在70℃下干燥40min后即可。
进一步,复合镀液中,硫酸镍浓度20g/L,次亚磷酸钠浓度为35g/L,乙酸钠浓度为10g/L,柠檬酸浓度为24g/L,乳酸浓度为19mL/L,稳定剂2-巯基苯并噻唑浓度为2.5mg/L,改性类水滑石纳米片复合物的含量为25g/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5g/L,pH值为1.5;所述敏化处理温度为30℃,处理时间10min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2L组成;所述活化处理温度为30℃,处理时间8min。
对比例2
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
1))量取两份等体积的无水乙醇,称取适量的正硅酸乙酯固体,溶解于一份无水乙醇中搅拌30min,得到质量浓度为2%的正硅酸乙酯乙醇溶液,量取一定量质量分数为22%的浓氨水添加到另一份无水乙醇中,控制浓氨水与正硅酸乙酯乙醇溶液的比例为0.5mL/L,在20℃和80r/min搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置3h后将得到的乳浊液放在通风处2h,即可得到纳米二氧化硅溶胶;
2)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶,混匀后缓慢滴加氨水调节pH值为4.5,得到复合镀液;
3)选用丙酮和乙醇(质量分数95%)按体积比为2:1组成有机溶剂,将涤纶织物面料采用有机溶剂以200W超声处理30min,取出后在70℃下干燥40min,然后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8min搅拌一次,转速为100r/min,施镀40min后取出织物面料,用蒸馏水反复冲洗,在70℃下干燥40min后即可。
进一步,复合镀液中,硫酸镍浓度20g/L,次亚磷酸钠浓度为35g/L,乙酸钠浓度为10g/L,柠檬酸浓度为24g/L,乳酸浓度为19mL/L,稳定剂2-巯基苯并噻唑浓度为2.5mg/L,纳米二氧化硅溶胶的含量为25mL/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5g/L,pH值为1.5;所述敏化处理温度为30℃,处理时间10min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2L组成;所述活化处理温度为30℃,处理时间8min。
对比例3
一种可以降低织物在洗涤过程中织物磨损的处理工艺,具体工艺如下:
选用丙酮和乙醇(质量分数95%)按体积比为2:1组成有机溶剂,将涤纶织物面料采用有机溶剂以200W超声处理30min,取出后在70℃下干燥40min,然后依次进行敏化和活化处理,将化学镀液加入到化学镀容器中,然后将容器放入温度为75℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8min搅拌一次,转速为100r/min,施镀40min后取出织物面料,用蒸馏水反复冲洗,在70℃下干燥40min后即可。
进一步,化学镀液中,硫酸镍浓度20g/L,次亚磷酸钠浓度为35g/L,乙酸钠浓度为10g/L,柠檬酸浓度为24g/L,乳酸浓度为19mL/L,稳定剂2-巯基苯并噻唑浓度为2.5mg/L。
进一步,所述敏化液为氯化亚锡水溶液,浓度为5g/L,pH值为1.5;所述敏化处理温度为30℃,处理时间10min,
进一步,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2L组成;所述活化处理温度为30℃,处理时间8min。
测试实验1
1.1实验材料
采用细度为2000x2000,经密23根/cm,纬密19根/cm,厚度0.248mm,平纹组织的涤纶作为样品,大小为12cmx6cm,面料是标准磨损布EMPA304(组织结构稀疏的脱线布,符合国外标准IEC PAS 62473-2007),并且是标准炭黑污染布,符合GB/T4288标准,采用实施例1-3以及对比例1-3提供的工艺方法对样品进行加工处理,对照组的涤纶样品不进行加工处理,各组提供面料样品50块,即可得到待洗涤的面料样品;标准IEC B型洗衣粉及消泡剂用于洗涤。
1.2.试验设计
选用青岛海尔洗衣机有限公司生产的全自动变频波轮洗衣机(型号XQS70-BZ1228SAM),其电脑板经重新改装可以调节多相洗涤参数,设定程序为转速50Hz,洗涤时间20min,每个程度每次洗涤7中面料样品各一块,每个程序重复三次,负载为2kg(为了达到负载量,在桶内添加标准纯棉及纯涤陪洗布),整个洗涤过程中水温控制在30±2℃;在洗涤前,记录每块面料样品经纬向的纱线根数,洗后再记录一次,用洗涤脱掉的经纬纱总根数除以洗前总根数,即得织物总磨损量,公式如下:织物总磨损率=(洗涤脱落的经纱根数+洗涤脱落的纬纱根数)/(洗前经纱总根数+洗前纬纱总根数)x100%。
1.3.试验结果分析
将每组中面料样品的总磨损率汇总统计后取平均值,即为该组面料样品的总磨损率,结果如下:实施例1中,总磨损率为10.8%;实施例1中,总磨损率为10.2%;实施例3中,总磨损率为11.3%;对比例中1,总磨损率为15.6%;对比例中2中,总磨损率为28.6%;对比例中3中,总磨损率为39.4%;对照组中,总磨损率为52.3%。
测试实验2
采用与测试实验1中同样的实验方法,区别在于重复洗涤的次数为10次,得到的结果如下:实施例1中,总磨损率为11.2%;实施例1中,总磨损率为10.7%;实施例3中,总磨损率为11.8%;对比例1中,总磨损率为28.5%;对比例中2中,总磨损率为31.6%;对比例中3中,总磨损率为56.2%;对照组中,总磨损率为78.2%。
通过上述实验结果可知,本发明提供的加工工艺,可以有效的降低织物在洗涤过程中受到的摩擦作用,从而降低织物表面的磨损,提升织物的服用性能,并且具有长期高效的降低织物表面磨损的技术效果。
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何不经过创造性劳动想到的变换或替换,都应涵盖在本发明的保护范围内。
Claims (8)
1.一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,具体工艺如下:
1)将适量的氧化石墨烯分散于甲酰胺溶液中,得到浓度为0.3-0.5mg/mL的分散液,将适量的硝酸铁和硝酸镍溶解在分散液中,混匀后得到混合液,在搅拌过程中,缓慢滴加氢氧化钠溶液,持续反应5-6h,待pH为10-10.5时终止反应,继续搅拌1-2h后静置4-6h,收集沉淀,用无水乙醇和去离子水交替清洗3-4次,烘干后得到改性类水滑石纳米片复合物;
2)称取适量的正硅酸乙酯固体,溶解于无水乙醇中搅拌30-40min,量取一定量的浓氨水添加到另一份无水乙醇中,在一定的温度和搅拌条件下,将溶有氨水的乙醇溶液缓慢滴加到溶有正硅酸乙酯的乙醇溶液中,静置3-4h后将得到的乳浊液放在通风处2-3h,即可得到纳米二氧化硅溶胶;
3)称取适量的硫酸镍固体溶于温水中,待其充分溶解后,依次加入柠檬酸固体、乙酸钠以及乳酸,搅拌至完全溶解,再称取适量的次亚磷酸钠固体溶于温水中,搅拌至完全溶解,再加入适量的稳定剂,将两种溶液混合到一起,加入适量的纳米二氧化硅溶胶以及改性类水滑石纳米片复合物,混匀后缓慢滴加氨水调节pH值为4.5-5.5,得到复合镀液;
4)将织物面料采用有机溶剂超声处理30-40min,烘干后依次进行敏化和活化处理,将复合镀液加入到化学镀容器中,然后将容器放入温度为75-95℃恒温槽中,将活化处理好的织物面料放入复合镀液中,每隔8-10min搅拌一次,施镀40-60min后取出织物面料,用蒸馏水反复冲洗,烘干后即可。
2.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤1)中,所述甲酰胺溶液的质量分数为50-55%;所述混合液中,铁离子的浓度为10-15mM,镍离子的浓度为20-30mM;所述氢氧化钠为0.7-0.8M;所述搅拌转速为100-160r/min;所述烘干温度为55-65℃,烘干时间10-15h。
3.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤2)中,所述正硅酸乙酯乙醇溶液的质量浓度为2-6%;所述浓氨水与正硅酸乙酯乙醇溶液的比例为0.5-2mL/L;所述浓氨水的质量分数为22-25%;所述两次使用的无水乙醇为等体积量;所述温度为20-40℃,转速为80-120r/min。
4.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤3)中,所述复合镀液中,硫酸镍浓度20-30g/L,次亚磷酸钠浓度为15-35g/L,乙酸钠浓度为10-13g/L,柠檬酸浓度为20-24g/L,乳酸浓度为15-19mL/L,稳定剂浓度为0.5-2.5mg/L,纳米二氧化硅溶胶的含量为10-25mL/L,改性类水滑石纳米片复合物的含量为15-25g/L;所述稳定剂选自2-巯基苯并噻唑、2-巯基苯并咪唑中至少一种。
5.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤4)中,所述有机溶剂为丙酮和乙醇按体积比为2-3:1组成;所述超声处理的功率为200-300W;所述搅拌转速为100-300r/min;所述干燥温度为70-90℃,干燥时间40-50min。
6.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤4)中,所述织物面料为化学合成防治面料,为涤纶、氨纶、腈纶、腈纶中至少一种。
7.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤4)中,所述敏化液为氯化亚锡水溶液,浓度为5-6g/L,pH值为1.5-2;所述敏化处理温度为30-35℃,处理时间10-15min。
8.如权利要求1所述的一种可以降低织物在洗涤过程中织物磨损的处理工艺,其特征在于,工艺步骤4)中,所述活化液由氯化钯、质量分数95%乙醇以及蒸馏水按质量体积比为1g:2L:2-2.3L组成;所述活化处理温度为30-35℃,处理时间8-10min。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011033004.1A CN112176717A (zh) | 2020-09-27 | 2020-09-27 | 一种可以降低织物在洗涤过程中织物磨损的处理工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011033004.1A CN112176717A (zh) | 2020-09-27 | 2020-09-27 | 一种可以降低织物在洗涤过程中织物磨损的处理工艺 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN112176717A true CN112176717A (zh) | 2021-01-05 |
Family
ID=73944248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011033004.1A Pending CN112176717A (zh) | 2020-09-27 | 2020-09-27 | 一种可以降低织物在洗涤过程中织物磨损的处理工艺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112176717A (zh) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07102484A (ja) * | 1993-09-30 | 1995-04-18 | Nisshinbo Ind Inc | 合成繊維製構造物表面の金属被覆方法 |
CN101397657A (zh) * | 2008-10-31 | 2009-04-01 | 华东理工大学 | 采用纳米二氧化硅溶胶和稀土强化复合镀层的方法 |
CN101851751A (zh) * | 2010-06-28 | 2010-10-06 | 西安工程大学 | 在锦纶织物表面制备纳米氮化硅复合镍磷镀层的方法 |
US20170348642A1 (en) * | 2016-06-07 | 2017-12-07 | Council Of Scientific & Industrial Research | Electrode and process for preparing the electrode and devices thereof |
CN109012675A (zh) * | 2018-08-14 | 2018-12-18 | 青岛科技大学 | 一步法制备石墨烯/镍铁类水滑石纳米片双功能氧催化剂的方法 |
CN109468838A (zh) * | 2018-09-12 | 2019-03-15 | 杭州鹏图化纤有限公司 | 一种耐磨抗静电无纺布 |
CN111321587A (zh) * | 2020-03-16 | 2020-06-23 | 中国科学院兰州化学物理研究所 | 一种碳纤维织物复合材料及其制备方法 |
-
2020
- 2020-09-27 CN CN202011033004.1A patent/CN112176717A/zh active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07102484A (ja) * | 1993-09-30 | 1995-04-18 | Nisshinbo Ind Inc | 合成繊維製構造物表面の金属被覆方法 |
CN101397657A (zh) * | 2008-10-31 | 2009-04-01 | 华东理工大学 | 采用纳米二氧化硅溶胶和稀土强化复合镀层的方法 |
CN101851751A (zh) * | 2010-06-28 | 2010-10-06 | 西安工程大学 | 在锦纶织物表面制备纳米氮化硅复合镍磷镀层的方法 |
US20170348642A1 (en) * | 2016-06-07 | 2017-12-07 | Council Of Scientific & Industrial Research | Electrode and process for preparing the electrode and devices thereof |
CN109012675A (zh) * | 2018-08-14 | 2018-12-18 | 青岛科技大学 | 一步法制备石墨烯/镍铁类水滑石纳米片双功能氧催化剂的方法 |
CN109468838A (zh) * | 2018-09-12 | 2019-03-15 | 杭州鹏图化纤有限公司 | 一种耐磨抗静电无纺布 |
CN111321587A (zh) * | 2020-03-16 | 2020-06-23 | 中国科学院兰州化学物理研究所 | 一种碳纤维织物复合材料及其制备方法 |
Non-Patent Citations (2)
Title |
---|
熊党生 等: "《特种环境固体润滑涂层技术》", 31 July 2016, 国防工业出版社 * |
郑德 等: "《热稳定剂的生产应用及进展》", 30 June 2011, 国防工业出版社 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103805971B (zh) | 一种镍盐活化化学镀铜纺织品的方法 | |
CN110484994B (zh) | 一种抗菌轻盈纺织面料及其制备方法 | |
CN101876144B (zh) | 一种采用钛酸丁酯对棉织物进行改性的方法 | |
CN101446036B (zh) | 在真丝织物上固着丝胶与纳米材料的方法 | |
CN105200773A (zh) | 壳聚糖改性织物的纳米银涂层制备方法 | |
CN103114437B (zh) | 一种纺织品表面无钯化学镀金属镍的方法 | |
CN112176717A (zh) | 一种可以降低织物在洗涤过程中织物磨损的处理工艺 | |
CN102634778B (zh) | 基于pamam /钯配位体的电磁屏蔽织物化学镀前活化方法 | |
CN112458745B (zh) | 一种浸轧制备柔性无机半导体纺织复合材料的方法 | |
CN102517887B (zh) | 一种硅保护原位沉积光催化功能织物的制备方法 | |
CN105332087B (zh) | 一种介孔磷酸锆负载纳米银抗菌聚酯纤维及其制备方法 | |
CN110356059A (zh) | 一种抗菌防紫外线面料 | |
CN103920436A (zh) | 一种改性空心微球及其应用 | |
CN107377005B (zh) | 一种可见光复合光催化剂的制备方法及其对织物整理方法 | |
CN112853755A (zh) | 一种沙发垫用抗菌面料及其生产工艺 | |
CN101851751B (zh) | 在锦纶织物表面制备纳米氮化硅复合镍磷镀层的方法 | |
CN102505454A (zh) | 基于Bi系光催化半导体功能织物的低温原位制备方法 | |
CN111501356A (zh) | 一种抗皱西服面料的制备方法 | |
CN116442615A (zh) | 一种含有无机复合锦纶的凉爽抗菌面料及其制备方法、应用 | |
CN115839027A (zh) | 一种含有细旦涤纶长丝的吸湿透气化纤面料及其生产工艺 | |
CN113355915A (zh) | 一种透气且具有防紫外功能面料的制备方法 | |
CN112030542B (zh) | 一种铜离子抗菌纱线的生产方法 | |
CN112725854A (zh) | 一种电镀前处理的加工处理方法 | |
CN114734689A (zh) | 基于锌离子抗菌、发热的面料及其织造方法 | |
CN106391003A (zh) | 一种口罩用甲醛吸收降解抗菌纳米催化剂的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210105 |
|
RJ01 | Rejection of invention patent application after publication |