CN111939093A - Bath oil with foaming and moistening effects, and its preparation method - Google Patents

Bath oil with foaming and moistening effects, and its preparation method Download PDF

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CN111939093A
CN111939093A CN202010870032.2A CN202010870032A CN111939093A CN 111939093 A CN111939093 A CN 111939093A CN 202010870032 A CN202010870032 A CN 202010870032A CN 111939093 A CN111939093 A CN 111939093A
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parts
oil
foaming
bath oil
bath
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CN111939093B (en
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莫远清
廖声友
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Guangzhou Yixuan Fine Chemical Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The invention relates to bath oil with foaming property and moistening property and a preparation method thereof. The bath oil comprises the following raw materials in parts by weight: 25-35 parts of ethylhexyl palmitate, 22-25 parts of propylene glycol, 19-23 parts of sodium laureth sulfate, 7-11 parts of water, 305-7 parts of laureth, 3-5 parts of chinlon oil, 0.4-0.6 part of tocopherol nicotinate, 2-4 parts of cocamide, 0.8-1.2 parts of sodium lauroyl oat amino acid, 0.8-1.2 parts of PEG-6 caprylic/capric glyceride, 0.8-1.2 parts of sodium cocoyl malate and 0.08-0.12 part of essence. The sensory and physical and chemical properties of the bath oil meet the national standard, and the bath oil has no irritation to skin, good moistening property and good foaming effect; the preparation method only needs simple mixing, is simple to operate, has easily-controlled process, and is beneficial to large-scale production.

Description

Bath oil with foaming and moistening effects, and its preparation method
Technical Field
The invention belongs to the field of daily chemicals, and particularly relates to bath oil with foaming property and moisturizing property and a preparation method thereof.
Background
The bath oil is a product integrating cleaning and skin care, and the common use method comprises the steps of firstly wetting the skin of the whole body by water, directly wiping and rubbing the skin by the bath oil, and then washing the skin clean; or squeezing appropriate amount of bath oil on wet bath ball, kneading to obtain foam, rubbing whole body, and washing.
The existing bath oil inevitably has damage to skin, and has poor moistening effect and foaming effect.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides bath oil with foaming property and moistening property and a preparation method thereof. The sensory and physical and chemical properties of the bath oil meet the national standard, and the bath oil has no irritation to skin, good moistening property and good foaming effect; the preparation method only needs simple mixing, is simple to operate, has easily-controlled process, and is beneficial to large-scale production.
The invention provides bath oil with foaming property and moistening property, which comprises the following raw materials in parts by weight: 25-35 parts of ethylhexyl palmitate, 22-25 parts of propylene glycol, 19-23 parts of sodium laureth sulfate, 7-11 parts of water, 305-7 parts of laureth, 3-5 parts of chinlon oil, 0.4-0.6 part of tocopherol nicotinate, 2-4 parts of cocamide, 0.8-1.2 parts of sodium lauroyl oat amino acid, 0.8-1.2 parts of PEG-6 caprylic/capric glyceride, 0.8-1.2 parts of sodium cocoyl malate and 0.08-0.12 part of essence.
Preferably, the bath oil with foaming property and moisturizing property comprises the following raw materials in parts by weight: 30 parts of ethylhexyl palmitate, 23.4 parts of propylene glycol, 21 parts of sodium laureth sulfate, 9 parts of water, 306 parts of laureth, 4 parts of white chinlon oil, 0.5 part of tocopherol nicotinate, 3 parts of cocoamide, 1 part of sodium lauroyl oat amino acid, 1 part of PEG-6 caprylic/capric glyceride, 1 part of sodium cocoyl malate and 0.1 part of essence.
Preferably, the preparation method of the meadowfoam seed oil comprises the following steps:
(1) taking the white pond flower and the white pond flower seeds, cleaning, mixing with water, distilling and extracting to obtain a primary extracting solution and primary distillation residues;
(2) mixing the primary distillation residues obtained in the step (1) with ethanol, and performing secondary distillation extraction to obtain a secondary extracting solution and secondary distillation residues;
(3) mixing the primary extract and the secondary extract to obtain a mixed solution; and (4) centrifuging the combined solution, and taking an oil phase to obtain the white chinaberry seed oil.
Preferably, in the step (1), the weight ratio of the white pond flowers to the white pond flower seeds is 1: 2-3.
Preferably, in the step (1), the weight ratio of the total amount of the white pond flowers and the white pond flower seeds to the water is 1: 3-5.
Preferably, in the step (1), the temperature of the distillation extraction is 85-93 ℃, and the time of the distillation extraction is 2-4 h.
Preferably, in the step (2), the weight ratio of the primary distillation residues to the ethanol is 1: 1-3.
Preferably, in the step (2), the temperature of the secondary distillation extraction is 65-70 ℃, and the time of the secondary distillation extraction is 4-6 h.
Preferably, in the step (3), the rotation speed of the centrifugal separation is 8000-10000 r/min.
Based on the same technical conception, the invention also provides a preparation method of the bath oil with foamability and moisturizing property, which comprises the following steps: the raw materials are mixed and then fully stirred uniformly.
The invention has the beneficial effects that:
1. the bath oil with foamability and moistening property provided by the invention has the advantages that various effective components are reasonably combined, and the sensory and physical and chemical properties of the bath oil meet the national standards through verification, and the bath oil has no irritation to skin, and has good moistening property and foaming effect.
2. The preparation method of the bath oil with foamability and moisturizing property only needs simple mixing, has simple operation and easily controlled process, and is beneficial to large-scale production.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
Example 1
This example provides a method for preparing a bath oil having foaming and moisturizing properties, comprising the steps of:
(I) the method for preparing the meadowrue root oil comprises the following steps:
(1) cleaning 1kg of white Potentilla chinensis and 2kg of seeds of the white Potentilla chinensis, mixing with 9kg of water, and distilling at 85 deg.C for 2 hr to obtain primary extractive solution and primary distilled residue;
(2) mixing the primary distillation residue obtained in the step (1) with ethanol according to a weight ratio of 1:1, and performing secondary distillation extraction at 65 ℃ for 4 hours to obtain a secondary extraction solution and secondary distillation residue;
(3) mixing the primary extract and the secondary extract to obtain a mixed solution; and (4) carrying out centrifugal separation on the combined solution at 8000r/min, and taking an oil phase to obtain the white chinlon oil.
(II) preparing the bath oil with foaming property and moistening property, the method comprises the following steps:
250g of ethylhexyl palmitate, 220g of propylene glycol, 190g of sodium laureth sulfate, 70g of water, 50g of laureth-30, 30g of white chinlon oil, 4g of tocopherol nicotinate, 20g of coconut oil amide, 8g of sodium lauroyl oat amino acid, 8g of PEG-6 caprylic/capric glyceride, 8g of sodium cocoyl malate and 0.8g of essence are mixed and stirred, and after the system is uniform, the bath oil with foamability and moisturizing property is obtained by sequentially discharging, standing, inspecting, filling, packaging, code spraying, sampling and warehousing.
Example 2
This example provides a method for preparing a bath oil having foaming and moisturizing properties, comprising the steps of:
(I) the method for preparing the meadowrue root oil comprises the following steps:
(1) cleaning 1kg of white Potentilla chinensis and 3kg of seeds of the white Potentilla chinensis, mixing with 20kg of water, and distilling at 93 ℃ for 4h to obtain a primary extract and primary distillation residues;
(2) mixing the primary distillation residue obtained in the step (1) with ethanol according to a weight ratio of 1:3, and carrying out secondary distillation extraction at 70 ℃ for 6 hours to obtain a secondary extraction solution and secondary distillation residue;
(3) mixing the primary extract and the secondary extract to obtain a mixed solution; centrifuging the combined solution at 10000r/min, and collecting oil phase to obtain white Potentilla chinensis seed oil.
(II) preparing the bath oil with foaming property and moistening property, the method comprises the following steps:
350g of ethylhexyl palmitate, 250g of propylene glycol, 230g of sodium laureth sulfate, 110g of water, 70g of laureth-30, 50g of white chinlon oil, 6g of tocopherol nicotinate, 40g of coconut oil amide, 12g of sodium lauroyl oat amino acid, 12g of PEG-6 caprylic/capric glyceride, 12g of sodium cocoyl malate and 1.2g of essence are mixed and stirred, and after the system is uniform, the bath oil with foamability and moisturizing property is obtained by sequentially discharging, standing, inspecting, filling, packaging, code spraying, sampling and warehousing.
Example 3
This example provides a method for preparing a bath oil having foaming and moisturizing properties, comprising the steps of:
(I) the method for preparing the meadowrue root oil comprises the following steps:
(1) cleaning 1kg of white Potentilla chinensis and 2.5kg of seeds of the white Potentilla chinensis, mixing with 14kg of water, and distilling at 89 deg.C for 3 hr to obtain primary extractive solution and primary distilled residue;
(2) mixing the primary distillation residue obtained in the step (1) with ethanol according to a weight ratio of 1:2, and carrying out secondary distillation extraction at 68 ℃ for 5 hours to obtain a secondary extraction solution and secondary distillation residue;
(3) mixing the primary extract and the secondary extract to obtain a mixed solution; centrifuging the combined solution at 9000r/min, and collecting oil phase to obtain white Potentilla chinensis seed oil.
(II) preparing the bath oil with foaming property and moistening property, the method comprises the following steps:
300g of ethylhexyl palmitate, 234g of propylene glycol, 210g of sodium laureth sulfate, 90g of water, 60g of laureth-30, 40g of white chinlon oil, 5g of tocopherol nicotinate, 30g of coconut oil amide, 10g of sodium lauroyl oat amino acid, 10g of PEG-6 caprylic/capric glyceride, 10g of sodium cocoyl malate and 1g of essence are mixed and stirred, and after the system is uniform, the bath oil with foaming property and moisturizing property is obtained by sequentially discharging, standing, inspecting, filling, packaging, code spraying, sampling and warehousing.
Comparative example
The comparative example differs from example 3 in that it does not contain meadowfoam seed oil and the other components and amounts are the same.
In order to verify various performances of the bath oil with foamability and moisturizing property, the test is carried out by referring to GB/T34857-2017 bathing agent, the sensory and physicochemical test standards are shown in Table 1, and the sensory and physicochemical test results are shown in Table 2.
The appearance detection method comprises the following steps: not less than 200mL of sample was taken and placed in a dry, clean, colorless, stoppered glass jar for observation under non-direct light conditions.
The odor detection method comprises the following steps: taking a proper amount of sample and identifying by smell sense.
Stability: measuring two parts of a sample with the volume not less than 100mL, respectively placing the two parts in a 250mL colorless wide-mouth glass bottle with a plug, placing one part in a heat preservation box with the temperature of (38-42) DEG C for 24 hours, taking out the sample, returning the sample to the room temperature, and then comparing the sample with the sample before the test for analysis; and the other part is placed in a refrigerator at (-7 to-3) DEG C for 24 hours, taken out and restored to the room temperature, and then is compared with the sample before the test for analysis.
The total effective substances are as follows: the measurement was carried out according to method A defined in chapter 7 of GB/T13173-2008.
pH: the method is carried out according to the method specified in technical Specification for cosmetic safety (2015 edition).
Formaldehyde: the method is carried out according to the method specified in technical Specification for cosmetic safety (2015 edition).
TABLE 1 sensory and physicochemical test standards
Figure BDA0002650769400000061
TABLE 2 sensory and physicochemical test results
Figure BDA0002650769400000071
To verify the irritation of the bath oil, a skin irritation/corrosion test was performed by:
(1) shearing off hairs on two sides of the spine of the white rabbit about 24 hours before the test, wherein the epidermis cannot be damaged, and the hair removing range is about 3cm multiplied by 3cm respectively on the left side and the right side;
(2) the test substance (bath oil) was applied directly to the skin in an amount of about 0.5mL (g), covered with two layers of gauze (2.5 cm. times.2.5 cm) and a layer of cellophane or the like, and fixed with a non-irritating adhesive tape and bandage. The other side of the skin served as a control. Adopting a closed test, wherein the application time is 2h, and removing residual test substances by using warm water or a non-irritant solvent after the test is finished;
(3) skin reactions at the smeared sites were observed for 1, 24, 48 and 72h after removal of the test substances, skin reaction scores were made according to table 3, comprehensive evaluations were made with the mean values of the tested animal scores, and skin irritation intensity was determined according to table 4 based on the highest mean values of the scores at each observation time point of 24, 48 and 72 h.
TABLE 3 skin irritation response score
Figure BDA0002650769400000082
Table 4 skin irritation intensity grading
Figure BDA0002650769400000081
Figure BDA0002650769400000091
The test results are shown in table 5.
TABLE 5 test results
Group of Example 1 Example 2 Example 3 Comparative example
Results Has no irritation Has no irritation Has no irritation Middle irritation
10 volunteers were selected to try out the bath oil of the invention and compared with similar products on the market to test the foaming effect, and the scores were averaged. The evaluation criteria for the foaming effect are shown in Table 6, and the evaluation results are shown in Table 7.
TABLE 6 Scoring standards
ScoringStandard of merit Corresponding score/score
No obvious foam after use 1~3
Has less foam after use 4~7
After use, the foam is full 8~10
TABLE 7 scoring results
Group of Example 1 Example 2 Example 3 The same kind of products sold in the market
Score/score 9 9 10 6
In conclusion, the bath oil with foamability and moisturizing property of the invention has the sensory and physical and chemical properties meeting the national standard; after animal tests, the bath oil obtained in the examples 1 to 3 has no skin irritation; the bath oil obtained by the comparative example has moderate irritation, which shows that the meadowfoam seed oil can well moisten skin and reduce irritation; and compared with similar products, the foaming performance is good.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.

Claims (10)

1. The bath oil with foaming property and moistening property is characterized by comprising the following raw materials in parts by weight: 25-35 parts of ethylhexyl palmitate, 22-25 parts of propylene glycol, 19-23 parts of sodium laureth sulfate, 7-11 parts of water, 305-7 parts of laureth, 3-5 parts of chinlon oil, 0.4-0.6 part of tocopherol nicotinate, 2-4 parts of cocamide, 0.8-1.2 parts of sodium lauroyl oat amino acid, 0.8-1.2 parts of PEG-6 caprylic/capric glyceride, 0.8-1.2 parts of sodium cocoyl malate and 0.08-0.12 part of essence.
2. The bath oil with foaming and moisturizing properties according to claim 1, comprising the following raw materials in parts by weight: 30 parts of ethylhexyl palmitate, 23.4 parts of propylene glycol, 21 parts of sodium laureth sulfate, 9 parts of water, 306 parts of laureth, 4 parts of white chinlon oil, 0.5 part of tocopherol nicotinate, 3 parts of cocoamide, 1 part of sodium lauroyl oat amino acid, 1 part of PEG-6 caprylic/capric glyceride, 1 part of sodium cocoyl malate and 0.1 part of essence.
3. The bath oil having foaming and moisturizing properties according to claim 1 or 2, wherein the method for preparing the meadowfoam seed oil comprises the steps of:
(1) taking the white pond flower and the white pond flower seeds, cleaning, mixing with water, distilling and extracting to obtain a primary extracting solution and primary distillation residues;
(2) mixing the primary distillation residues obtained in the step (1) with ethanol, and performing secondary distillation extraction to obtain a secondary extracting solution and secondary distillation residues;
(3) mixing the primary extract and the secondary extract to obtain a mixed solution; and (4) centrifuging the combined solution, and taking an oil phase to obtain the white chinaberry seed oil.
4. The bath oil with foaming and moisturizing effects as claimed in claim 3, wherein in the step (1), the weight ratio of the Potentilla chinensis to the Potentilla chinensis seeds is 1: 2-3.
5. The bath oil with foaming and moisturizing effects as claimed in claim 3, wherein in the step (1), the weight ratio of the total amount of the Potentilla alba and the Potentilla alba seeds to water is 1: 3-5.
6. The bath oil with foaming and moisturizing effects as claimed in claim 3, wherein in the step (1), the temperature of the distillation extraction is 85-93 ℃, and the time of the distillation extraction is 2-4 h.
7. The bath oil with foaming and moisturizing effects as claimed in claim 3, wherein in the step (2), the weight ratio of the primary distilled residues to the ethanol is 1: 1-3.
8. The bath oil with foaming and moisturizing effects as claimed in claim 3, wherein in the step (2), the temperature of the secondary distillation extraction is 65-70 ℃, and the time of the secondary distillation extraction is 4-6 h.
9. The bath oil having foaming and moisturizing properties according to claim 3, wherein the rotational speed of the centrifugal separation in step (3) is 8000 to 10000 r/min.
10. The method for producing the shower oil having foamability and moisturizing ability according to any one of claims 1 to 9, wherein the raw materials are mixed and then sufficiently stirred uniformly.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4924223B1 (en) * 1969-02-17 1974-06-21
CN103271860A (en) * 2013-06-18 2013-09-04 菏泽尧舜牡丹生物科技有限公司 Skin care oil containing peony oil and preparation method thereof
CN110897937A (en) * 2019-12-20 2020-03-24 广州蜜妆生物科技有限公司 Bubble bath oil and preparation method thereof
CN111265437A (en) * 2020-04-10 2020-06-12 中山爱护日用品有限公司 Multi-effect repair oil for infants and children and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4924223B1 (en) * 1969-02-17 1974-06-21
CN103271860A (en) * 2013-06-18 2013-09-04 菏泽尧舜牡丹生物科技有限公司 Skin care oil containing peony oil and preparation method thereof
CN110897937A (en) * 2019-12-20 2020-03-24 广州蜜妆生物科技有限公司 Bubble bath oil and preparation method thereof
CN111265437A (en) * 2020-04-10 2020-06-12 中山爱护日用品有限公司 Multi-effect repair oil for infants and children and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
钱洁等: "婴童沐浴产品温和表面活性剂的研究", 《《中国洗涤用品工业》个人与家居清洁护理》 *

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