CN111759753B - Mild amino acid facial cleanser and preparation method thereof - Google Patents

Mild amino acid facial cleanser and preparation method thereof Download PDF

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Publication number
CN111759753B
CN111759753B CN202010800083.8A CN202010800083A CN111759753B CN 111759753 B CN111759753 B CN 111759753B CN 202010800083 A CN202010800083 A CN 202010800083A CN 111759753 B CN111759753 B CN 111759753B
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parts
sodium glutamate
amino acid
sodium
stirring
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CN111759753A (en
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廖伦辉
戴成兰
戴丽杰
彭志华
许怡然
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Guangzhou Haiya Supply Chain Technology Co.,Ltd.
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Guangzhou Meixi Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds

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Abstract

The invention provides a mild amino acid cleansing cream and a preparation method thereof, and the mild amino acid cleansing cream comprises the following raw materials in parts by weight: 15 to 35 parts of N-lauroyl sodium glutamate, 10 to 40 parts of polyhydric alcohol, 1 to 10 parts of methyl cocoyl sodium taurate, 2 to 10 parts of sodium glutamate, 1 to 5 parts of polyethylene glycol, 1 to 5 parts of thickening agent, 1 to 5 parts of fatty acid, 1 to 5 parts of ethylene glycol distearate, 1 to 5 parts of polyglycerol-10 laurate, 0.1 to 1 part of PEG-120 methyl glucose dioleate, 0.1 to 1 part of tocopherol acetate, 0.1 to 0.5 part of chelating agent and 10 to 70 parts of water. The amino acid facial cleanser disclosed by the invention is fine and smooth in cream body, smooth and rich in foam, excellent in stability, mild in use, safe and non-irritant, suitable for various skin types and strong in cleaning performance, and the pH value is 5.3-5.8 and is close to the pH value of human skin.

Description

Mild amino acid facial cleanser and preparation method thereof
Technical Field
The invention relates to the technical field of cosmetics, in particular to a mild amino acid facial cleansing cream and a preparation method thereof.
Background
Skin cleansing is a necessary process for skin care, and the main purpose is to remove dust, residues of beauty cosmetics, sebum, stratum corneum fragments and oxidative decomposition products thereof, etc. from the surface of the skin, so as to maintain the normal physiological state of the skin. With the improvement of the living standard of people and the progress of modern cosmetic science and technology, more efficient, safe and mild facial cleanser products gradually enter the mass market, and amino acid type facial cleansers are the most representative products.
At present, most of the products of the amino acid facial cleanser sold in the market are milky or cream, and the amino acid facial cleanser is prepared by compounding N-fatty acid amino acid with other conventional surfactants, so that the N-fatty acid amino acid facial cleanser is low in foam amount and unstable, is not mild enough to use and cannot be suitable for all skin types.
Disclosure of Invention
In view of the above, the invention aims to provide a mild amino acid facial cleanser and a preparation method thereof, and the mild amino acid facial cleanser is prepared by compounding and synergizing N-lauroyl sodium glutamate, polyhydric alcohol, methyl cocoyl sodium taurate, sodium glutamate, polyethylene glycol, a thickening agent, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate, PEG-120 methyl glucose dioleate and tocopherol acetate, so that the obtained amino acid facial cleanser is fine and smooth in cream body, smooth and rich in foam, excellent in stability, mild in use, safe, free of stimulation, suitable for various skin types and strong in cleaning performance, and the pH value is between 5.3 and 5.8 and is close to the pH value of human skin.
In order to achieve the above purpose, the invention provides the following technical scheme:
the mild amino acid facial cleanser comprises the following raw materials in parts by weight: 15 to 35 parts of N-lauroyl sodium glutamate, 10 to 40 parts of polyhydric alcohol, 1 to 10 parts of methyl cocoyl sodium taurate, 2 to 10 parts of sodium glutamate, 1 to 5 parts of polyethylene glycol, 1 to 5 parts of thickening agent, 1 to 5 parts of fatty acid, 1 to 5 parts of ethylene glycol distearate, 1 to 5 parts of polyglycerol-10 laurate, 0.1 to 1 part of PEG-120 methyl glucose dioleate, 0.1 to 1 part of tocopherol acetate, 0.1 to 0.5 part of chelating agent and 10 to 70 parts of water.
As a further improvement of the above technical scheme, the polyhydric alcohol comprises at least one of glycerol, 1, 2-propylene glycol, 70% sorbitol, 1, 3-butylene glycol and 1, 3-propylene glycol;
preferably, the polyol is 1, 3-butanediol and/or 1, 3-propanediol.
As a further improvement of the above technical solution, the thickener comprises an acrylate copolymer;
preferably, the acrylate copolymer comprises at least one of acrylic acid (ester)/steareth-20 methacrylate copolymer, acrylic acid (ester)/palmitoleeth-25 acrylate copolymer and acrylic acid (ester)/beheneth-25 methacrylate copolymer.
As a further improvement of the above technical solution, the polyethylene glycol comprises at least one of polyethylene glycol-6, polyethylene glycol-8 and polyethylene glycol-32;
as a further improvement of the technical scheme, the sodium glutamate comprises at least one of anhydrous sodium glutamate and monosodium glutamate.
As a further improvement of the above technical solution, the chelating agent comprises at least one of disodium EDTA and tetrasodium EDTA;
as a further improvement of the above technical solution, the fatty acid includes at least one of lauric acid, myristic acid, palmitic acid, and stearic acid.
As a further improvement of the above technical solution, the raw materials further comprise: preservatives and/or fragrances.
As a further improvement of the technical scheme, the dosage of the preservative is 0.1-1 part, and the dosage of the essence is 0.1-1 part.
A preparation method of a mild amino acid facial cleanser is disclosed, wherein the mild amino acid facial cleanser is the mild amino acid facial cleanser; the preparation method comprises the following steps:
mixing N-lauroyl sodium glutamate, polyhydric alcohol and water, and heating to 70-85 ℃ to obtain solution A;
mixing the A liquid, sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate, heating to 70-85 ℃, then cooling to 4555 ℃, adding the rest components and mixing.
As a further improvement of the above technical solution, the preparation method further comprises: and keeping the temperature of the solution A at 70-85 ℃, and stirring until the solution surface is free from bubbles.
The invention has the beneficial effects that:
(1) According to the invention, N-lauroyl sodium glutamate, polyalcohol, methyl cocoyl sodium taurate, sodium glutamate, polyethylene glycol, an acrylate copolymer thickener, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate, PEG-120 methyl glucose dioleate and tocopherol acetate are compounded to realize synergistic interaction, specifically, an amino acid surfactant N-lauroyl sodium glutamate and sodium glutamate are utilized to realize synergistic interaction to form a stable crystalline thickening system, and the heat resistance stability of the formula is further increased by matching the acrylate copolymer and the PEG-120 methyl glucose dioleate, so that the defects of unstable foam and quick defoaming of the N-lauroyl sodium glutamate are overcome by adding the polyglycerol-10 laurate, the foam of the product is more durable and softer, and the phenomenon that the formula turns yellow due to high temperature or long-term storage is remarkably improved by adding the tocopherol acetate; the obtained amino acid facial cleanser is mild in use, fine and smooth in cream body, smooth and rich in foam, excellent in stability, safe, free of stimulation and strong in cleaning performance, and the pH value of the amino acid facial cleanser is 5.3-5.8 and close to that of human skin.
(2) The composition disclosed by the invention is simple in preparation method, low in preparation cost, wide in market prospect and suitable for large-scale production.
In order to make the aforementioned and other objects, features and advantages of the invention more comprehensible, preferred embodiments accompanied with figures are described in detail below.
Detailed Description
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention.
This invention may, however, be embodied in many different forms than those specifically described herein, and it will be apparent to those skilled in the art that many more modifications are possible without departing from the spirit and scope of the invention.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
The term as used herein:
"by 8230; \ 8230; preparation" is synonymous with "comprising". As used herein, the terms "comprises," "comprising," "includes," "including," "has," "having," "contains" or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
The conjunction "consisting of 823070, 8230composition" excludes any unspecified elements, steps or components. If used in a claim, the phrase is intended to claim as closed, meaning that it does not contain materials other than those described, except for the conventional impurities associated therewith. When the phrase "consisting of 8230' \8230"; composition "appears in a clause of the subject matter of the claims and not immediately after the subject matter, it defines only the elements described in the clause; other elements are not excluded from the claims as a whole.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or range defined by a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted to include the ranges "1 to 4," "1 to 3," "1 to 2 and 4 to 5," "1 to 3 and 5," and the like. When a range of values is described herein, unless otherwise specified, the range is intended to include the endpoints thereof, and all integers and fractions within the range.
In these examples, the parts and percentages are by mass unless otherwise indicated.
"part by mass" means a basic unit of measure indicating a mass ratio of a plurality of components, and 1 part may represent an arbitrary unit mass, for example, 1g or 2.689 g. If we say that the part by mass of the component A is a part by mass and the part by mass of the component B is B part by mass, the ratio of the part by mass of the component A to the part by mass of the component B is a: b. alternatively, the mass of the A component is aK and the mass of the B component is bK (K is an arbitrary number, and represents a multiple factor). It is not to be misunderstood that the sum of the parts by mass of all the components is not limited to the limit of 100 parts, unlike the parts by mass.
"and/or" is used to indicate that one or both of the illustrated conditions may occur, e.g., a and/or B includes (a and B) and (a or B).
The invention provides mild amino acid facial cleansing cream which comprises the following raw materials: sodium N-lauroyl glutamate, polyhydric alcohol, sodium methylcocoyltaurate, sodium glutamate, polyethylene glycol, thickener, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate, PEG-120 methylglucdioleate, tocopheryl acetate, chelating agent, and water.
Further, the dosage of each raw material is as follows: 15 to 35 parts of N-lauroyl sodium glutamate, 10 to 40 parts of polyhydric alcohol, 1 to 10 parts of methyl cocoyl sodium taurate, 2 to 10 parts of sodium glutamate, 1 to 5 parts of polyethylene glycol, 1 to 5 parts of thickening agent, 1 to 5 parts of fatty acid, 1 to 5 parts of ethylene glycol distearate, 1 to 5 parts of polyglycerol-10 laurate, 0.1 to 1 part of PEG-120 methyl glucose dioleate, 0.1 to 1 part of tocopherol acetate, 0.1 to 0.5 part of chelating agent and 10 to 70 parts of water.
The sodium N-lauroyl glutamate has foaming and cleaning effects; the invention mainly forms the cleansing cream by crystallization of the amino acid surfactant, and better separates out crystals of the N-lauroyl sodium glutamate by adding the sodium glutamate.
The polyhydric alcohol mainly plays a role in moisturizing in the invention; optionally, the polyol comprises at least one of glycerol, 1, 2-propanediol, 70% sorbitol, 1, 3-butanediol, and 1, 3-propanediol; preferably, the 1, 3-butanediol and/or 1, 3-propanediol is selected as the polyhydric alcohol, so that the prepared cleansing cream has the advantages of optimal cleansing cream temperature and stability, lowest requirements on production equipment and best stability.
The heat resistance of the cleansing cream can be improved by adding polyethylene glycol; preferably, the polyethylene glycol comprises at least one of polyethylene glycol-6, polyethylene glycol-8 and polyethylene glycol-32.
The sodium methyl cocoyl taurate can effectively assist the forming of the cleansing cream and increase the foam quantity.
The fatty acids described above are effective in the present invention to synergistically contribute to the improvement in the amount and the feeling of lather of the resulting cleansing cream.
The ethylene glycol distearate can effectively improve the appearance of the paste synergistically and increase the consistency;
the polyglycerol-10 laurate is effective in synergistically improving the dry and astringent feeling of the skin after washing and reducing the irritation of the surfactant.
Further, the thickener comprises an acrylate copolymer thickener which is weakly acidic, preferably, the acrylate copolymer comprises at least one of an acrylic acid (ester)/steareth-20 methacrylate copolymer (e.g., ACULYN 88POLMER available from dow chemical), an acrylic acid (ester)/palmitoeth-25 acrylate copolymer (e.g., synthalen W2000 available from 3V SIGAMA s.p.a, italy) and an acrylic acid (ester)/beheneth-25 methacrylate copolymer (e.g., noveth L-10 available from luobu); the three acrylic acid (ester) copolymers have better thickening performance in the formula than the common acrylic acid (ester) copolymers, and have better matching performance with the whole formula system.
According to the invention, N-lauroyl sodium glutamate, polyhydric alcohol, methyl cocoyl sodium taurate, sodium glutamate, polyethylene glycol, an acrylate copolymer thickener, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate, PEG-120 methyl glucose dioleate and tocopherol acetate are compounded to realize synergistic interaction, specifically, an amino acid surfactant N-lauroyl sodium glutamate and sodium glutamate are utilized to realize synergistic interaction to form a stable crystalline thickening system, and the acrylate copolymer and the PEG-120 methyl glucose dioleate are matched to further increase the heat resistance stability of the formula, so that the defects of unstable foam and quick defoaming of the N-lauroyl sodium glutamate are compensated by adding the polyglycerol-10 laurate, the foam of the product is more durable and soft, and the phenomenon that the formula turns yellow due to high temperature or long-term storage is obviously improved by adding the tocopherol acetate; the obtained amino acid facial cleanser is mild in use, fine in cream body, smooth and rich in foam, excellent in stability, safe, free of stimulation and strong in cleaning performance, and the pH value is 5.3-5.8 and is close to the pH value of human skin.
Furthermore, the inventor obtains through a large number of research statistical analyses that the N-lauroyl sodium glutamate, the polyalcohol, the sodium methyl cocoyl taurate, the sodium glutamate, the polyethylene glycol, the acrylate copolymer thickener, the fatty acid, the ethylene glycol distearate, the polyglycerol-10 laurate, the PEG-120 methyl glucose dioleate and the tocopherol acetate are mixed according to the weight part ratio, so that the good synergistic effect can be exerted, and meanwhile, no side effect is generated.
Preferably, the sodium glutamate comprises at least one of anhydrous sodium glutamate and monosodium glutamate.
Preferably, the chelating agent comprises at least one of disodium EDTA and tetrasodium EDTA.
Preferably, the fatty acid comprises at least one of lauric acid, myristic acid, palmitic acid and stearic acid.
Preferably, the mild amino acid facial cleanser of the present application further comprises the following raw materials: preservatives and/or fragrances.
Preferably, the dosage of the preservative is 0.1-1 part, and the dosage of the essence is 0.1-1 part.
A preparation method of a mild amino acid facial cleanser is disclosed, wherein the mild amino acid facial cleanser is the mild amino acid facial cleanser; the preparation method comprises the following steps:
(1) Mixing N-lauroyl sodium glutamate, polyalcohol and water, and heating to 70-85 ℃ to obtain solution A.
(2) Mixing the A liquid, sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol, fatty acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate, heating to 70-85 ℃, then cooling to 45-55 ℃, adding the rest components, and mixing.
Preferably, the preparation method further comprises: and keeping the temperature of the solution A at 70-85 ℃, and stirring until the solution surface is free from bubbles.
Preferably, in step (2) of the above preparation method: cooling to 45-55 ℃, adding the acrylate copolymer thickener, homogenizing and stirring uniformly at low speed, adding the rest components such as tocopheryl acetate, chelating agent and the like, stirring and cooling to 40-42 ℃ to obtain the amino acid facial cleanser.
The water may be pure water, distilled water or deionized water, preferably deionized water.
Embodiments of the present invention will be described in detail below with reference to specific examples, but those skilled in the art will appreciate that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention. The examples, in which specific conditions are not specified, were carried out according to conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
Example 1
The cleansing cream comprises the following raw materials in parts by weight: 67 parts of deionized water, 15 parts of N-lauroyl sodium glutamate, 10 parts of 1, 3-propylene glycol, 3 parts of sodium methyl cocoyl taurate, 2 parts of sodium glutamate, 1 part of polyethylene glycol-8, 1 part of lauric acid, 1 part of ethylene glycol distearate, 1 part of polyglycerol-10 laurate, 0.1 part of PEG-120 methyl glucose dioleate, 1 part of acrylic acid (ester)/steareth-20 methacrylate copolymer, 0.5 part of preservative, 0.1 part of tocopherol acetate, 0.1 part of disodium EDTA (ethylene diamine tetraacetic acid) and 0.2 part of essence.
The preparation process of the facial cleanser is as follows:
(1) Adding N-lauroyl sodium glutamate and polyalcohol into deionized water, heating to 70 deg.C while stirring to dissolve to obtain solution A, stirring at 70 deg.C while maintaining the temperature until the solution surface is free of bubbles, and stopping heating;
(2) Adding sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate into the solution A obtained in the step (1), uniformly stirring and mixing, heating to 75 ℃ to dissolve, stopping heating, then stirring until the temperature is reduced to about 45 ℃, adding acrylic acid (ester)/steareth-20 methacrylate copolymer, uniformly stirring at low speed, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
Example 2
The face cleansing cream comprises the following raw materials in parts by weight: 40.8 parts of deionized water, 20 parts of N-lauroyl sodium glutamate, 20 parts of 1, 3-propylene glycol, 5 parts of sodium methyl cocoyl taurate, 3 parts of sodium glutamate, 2 parts of polyethylene glycol-8, 2 parts of lauric acid, 1.5 parts of ethylene glycol distearate, 1.5 parts of polyglycerol-10 laurate, 0.3 part of PEG-120 methyl glucose dioleate, 2 parts of acrylic acid (ester)/steareth-20 methacrylate copolymer, 0.5 part of preservative, 0.1 part of tocopherol acetate, 0.3 part of disodium EDTA and 0.9 part of essence.
The preparation process of the facial cleanser is as follows:
(1) Adding N-lauroyl sodium glutamate and polyalcohol into deionized water, heating to 70 deg.C while stirring to dissolve to obtain solution A, stirring at 70 deg.C while maintaining the temperature until the solution surface is free of bubbles, and stopping heating;
(2) Adding sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate into the solution A obtained in the step (1), uniformly stirring and mixing, heating to 75 ℃ to dissolve, stopping heating, then stirring until the temperature is reduced to about 45 ℃, adding the acrylic acid (ester)/steareth-20 methacrylate copolymer, uniformly stirring at low speed, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
Example 3
The cleansing cream comprises the following raw materials in parts by weight: 29 parts of deionized water, 19 parts of N-lauroyl sodium glutamate, 25 parts of 1, 3-propylene glycol, 8 parts of sodium methyl cocoyl taurate, 5 parts of sodium glutamate, 3 parts of polyethylene glycol-8, 2.5 parts of lauric acid, 2 parts of ethylene glycol distearate, 2 parts of polyglycerol-10 laurate, 0.5 part of PEG-120 methyl glucose dioleate, 2 parts of acrylic acid (ester)/steareth-20 methacrylate copolymer, 0.8 part of preservative, 0.8 part of tocopherol acetate, 0.1 part of disodium EDTA and 0.2 part of essence.
The preparation process of the facial cleansing cream comprises the following steps:
(1) Adding N-lauroyl sodium glutamate and polyalcohol into deionized water, heating to 70 deg.C while stirring to dissolve to obtain solution A, stirring at 70 deg.C until the solution surface is free of bubbles, and stopping heating;
(2) Adding sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate into the solution A obtained in the step (1), uniformly stirring and mixing, heating to 75 ℃ to dissolve, stopping heating, then stirring until the temperature is reduced to about 45 ℃, adding acrylic acid (ester)/steareth-20 methacrylate copolymer, uniformly stirring at low speed, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
Example 4
The cleansing cream comprises the following raw materials in parts by weight: 18 parts of deionized water, 15 parts of sodium N-lauroyl glutamate, 30 parts of 1, 3-propylene glycol, 10 parts of sodium methyl cocoyl taurate, 5 parts of sodium glutamate, 5 parts of polyethylene glycol-8, 3 parts of lauric acid, 2 parts of ethylene glycol distearate, 5 parts of polyglycerol-10 laurate, 1 part of PEG-120 methyl glucose dioleate, 5 parts of acrylic acid (ester)/steareth-20 methacrylate copolymer, 0.1 part of preservative, 0.3 part of tocopherol acetate, 0.3 part of disodium EDTA and 0.2 part of essence.
The preparation process of the facial cleansing cream comprises the following steps:
(1) Adding N-lauroyl sodium glutamate and polyalcohol into deionized water, heating to 70 deg.C while stirring to dissolve to obtain solution A, stirring at 70 deg.C until the solution surface is free of bubbles, and stopping heating;
(2) Adding sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate into the solution A obtained in the step (1), uniformly stirring and mixing, heating to 75 ℃ to dissolve, stopping heating, then stirring until the temperature is reduced to about 45 ℃, adding the acrylic acid (ester)/steareth-20 methacrylate copolymer, uniformly stirring at low speed, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
Example 5
The cleansing cream comprises the following raw materials in parts by weight: 24 parts of deionized water, 30 parts of N-lauroyl sodium glutamate, 30 parts of 1, 3-propylene glycol, 1 part of sodium methyl cocoyl taurate, 1 part of sodium glutamate, 5 parts of polyethylene glycol-8, 3 parts of lauric acid, 2 parts of ethylene glycol distearate, 1 part of polyglycerol-10 laurate, 0.1 part of PEG-120 methyl glucose dioleate, 1 part of acrylic acid (ester)/steareth-20 methacrylate copolymer, 0.1 part of preservative, 1 part of tocopherol acetate, 0.5 part of EDTA disodium and 0.2 part of essence.
The preparation process of the facial cleansing cream comprises the following steps:
(1) Adding N-lauroyl sodium glutamate and polyalcohol into deionized water, heating to 70 deg.C while stirring to dissolve to obtain solution A, stirring at 70 deg.C while maintaining the temperature until the solution surface is free of bubbles, and stopping heating;
(2) Adding sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate into the solution A obtained in the step (1), uniformly stirring and mixing, heating to 75 ℃ to dissolve, stopping heating, then stirring until the temperature is reduced to about 45 ℃, adding the acrylic acid (ester)/steareth-20 methacrylate copolymer, uniformly stirring at low speed, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
Comparative example 1
This comparative example differs from example 1 in that: the raw material component, sodium glutamate, in example 1 was removed.
Comparative example 2
This comparative example differs from example 1 in that: the starting material, PEG-120 methyl glucose dioleate, in example 1 was removed.
Comparative example 3
The comparative example differs from example 3 in that: the starting material component, tocopheryl acetate, in example 1 was removed.
Comparative example 4
This comparative example differs from example 3 in that: the raw material component, polyglycerol-10 laurate, of example 1 was removed.
Comparative example 5
The amino acid facial cleanser sold in the market is adopted.
The acrylic/steareth-20 methacrylate copolymer was ACULYN 88POLMER available from Dow chemical.
The performance indexes of the cleansing creams prepared in the embodiments 1 to 5 and the comparative examples 1 to 5 of the present invention were measured, and the specific measurement results are shown in table 1 below.
TABLE 1
Figure BDA0002627066460000121
Figure BDA0002627066460000131
The method for measuring the foam (i.e., the foaming power) in Table 1 is specifically described in GB/T13173.6-2000.
In conclusion, the facial cleanser prepared by the invention is mild in use, fine in cream body, good in foaming power, rich in foam, excellent in heat resistance and cold resistance stability, safe and non-irritant, and strong in cleaning performance, and the pH value of the facial cleanser is 5.3-5.8 and is close to the pH value of human skin.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and these modifications or substitutions do not depart from the spirit of the corresponding technical solutions of the embodiments of the present invention. Furthermore, those skilled in the art will appreciate that while some embodiments herein include some features included in other embodiments, rather than other features, combinations of features of different embodiments are meant to be within the scope of the invention and form different embodiments. For example, in the claims above, any of the claimed embodiments may be used in any combination. The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.

Claims (2)

1. The preparation method of the mild amino acid cleansing cream is characterized by comprising the following raw materials in parts by weight: 15-30 parts of N-lauroyl sodium glutamate, 10-30 parts of 1, 3-propylene glycol, 1-10 parts of sodium methyl cocoyl taurate, 2-5 parts of sodium glutamate, 1-5 parts of polyethylene glycol-8, 1-5 parts of acrylate/steareth-20 methacrylate copolymer, 1-3 parts of lauric acid, 1-2 parts of ethylene glycol distearate, 1-5 parts of polyglycerol-10 laurate, 0.1-1 part of PEG-120 methyl glucose dioleate, 0.1-1 part of tocopheryl acetate, 0.1-0.5 part of EDTA disodium, 0.1-0.8 part of preservative, 0.2-0.9 part of essence and 18-67 parts of deionized water;
the preparation method comprises the following steps:
mixing N-lauroyl sodium glutamate, 1, 3-propylene glycol and deionized water, heating to 70 deg.C under stirring, keeping the temperature at 70 deg.C, stirring until the liquid surface is bubble-free, and stopping heating to obtain solution A;
uniformly mixing the solution A, sodium methyl cocoyl taurate, sodium glutamate, polyethylene glycol-8, lauric acid, ethylene glycol distearate, polyglycerol-10 laurate and PEG-120 methyl glucose dioleate, heating to 75 ℃, then cooling to 45 ℃, adding the acrylate/steareth-20 methacrylate copolymer, uniformly stirring, adding the rest components, stirring and cooling to 40 ℃ to obtain the cleansing cream.
2. The method of preparing a mild amino acid facial cleanser of claim 1, wherein said sodium glutamate comprises at least one of anhydrous sodium glutamate and monosodium glutamate.
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