CN111690303A - Water-in-water coating imitating long-strip limestone and corresponding construction method - Google Patents
Water-in-water coating imitating long-strip limestone and corresponding construction method Download PDFInfo
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- CN111690303A CN111690303A CN201910184023.5A CN201910184023A CN111690303A CN 111690303 A CN111690303 A CN 111690303A CN 201910184023 A CN201910184023 A CN 201910184023A CN 111690303 A CN111690303 A CN 111690303A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to a water-in-water coating imitating a long-strip limestone, which comprises a continuous phase and colored particles dispersed in the continuous phase, wherein the colored particles comprise the following components: emulsion, protective glue solution, thickening agent, pigment and filler, dispersing and wetting agent and organic silicon defoaming agent; the continuous phase comprises the following components: emulsion, film forming assistant, antifreezing agent and thickening agent. By adopting the long-strip limestone water-in-water coating, the surface is sprayed by a special spray gun and dried, then the plastic paper is used for dipping the coating part for patting, and the plastic paper is polished after being dried, so that the decorative effect of the water-in-water coating is improved, the water-in-water coating has the high-end elegant stone-like effect of limestone, and the attractive design requirement is met.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a water-in-water coating imitating long-strip limestone and a corresponding construction method.
Background
The traditional water-in-water multicolor paint is also called liquid granite paint, is a high-end technical product with pure water property, no public hazard, rich granite texture and high molecular element structure, is prepared by refining liquid water-based resin to wrap colloidal water-based color particles, and uniformly suspending the colloidal water-based color particles in specific water-based emulsion to finally form a high molecular liquid colloidal copolymer with various colors and random particle sizes.
Compared with the sand wall-shaped varieties such as natural real stone paint, granite stone paint, texture paint, sandstone paint and the like, the liquid granite coating has completely different concepts in essence and state. The sprayed building finished product has the advantages of simple, elegant and luxurious appearance, natural, smooth and blended granite texture, smooth and soft surface, smooth and non-rough hand feeling, tough coating film, high adhesion, no cracking, high weather resistance, temperature change resistance, high pollution resistance, easy cleaning and strong self-cleaning function; the texture coating shows a unique space visual angle by the infinite three-dimensional texture and the multiple-choice individual matching, is rich and vivid, and is novel.
The traditional water-in-water coating adopts a special spray gun for spraying construction, the sprayed effect tends to granite texture, and the stone-like effect of natural limestone is difficult to achieve.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the water-based multicolor paint which can endow the paint with the functions of decoration and protection of the outer wall, can imitate the limestone outer wall decoration effect in a higher-end market and has a more beautiful effect.
In order to achieve the aim, the water-in-water coating imitating the long-strip limestone disclosed by the invention comprises the following components in percentage by mass:
the emulsion is preferably pure acrylic emulsion and silicone acrylic emulsion, the pure acrylic emulsion can be flexible water-based pure acrylic emulsion, and the emulsion has better extensibility and crack resistance and can be used in water-based colorful luminous paint base stock; preferably Japanese Showa emulsion 1048-3, Shanghai Baodefu industries, Ltd 6733 emulsion; the silicone-acrylate emulsion can be various aqueous silicone-acrylate emulsions used in aqueous coatings in the field, has excellent calcium ion stability, dilution stability, mechanical stability and freeze-thaw stability, has the characteristics of weather resistance, scrub resistance, alkali resistance and good adhesion, and is preferably one or more of silicone-acrylate emulsion KD96 of Shanghai Baolijia chemical industry Co., Ltd and silicone-acrylate emulsion 3788 of Shanghai Badekui Fukuyu Co., Ltd.
Preferably, the protective glue is an artificially synthesized inorganic silicate substance with the particle size of 25nm and the structure similar to natural montmorillonite, and is a trioctahedral layered silicate mineral, a large number of exchangeable cations exist between layers, the protective glue and a high polymer substance can form the characteristic of gel under certain conditions to form a water-insoluble flexible film, the flexible film can prevent the coating components in the film and the protective glue components except the film from mutually diffusing, the preferred protective glue is Kokoku S482 protective glue powder, and the protective glue powder is dispersed into a 7% aqueous solution for later use.
Preferably, the pigment and filler is kaolin filler, carbon black and one or more of iron oxide red and iron oxide yellow. Wherein, the pigment is more preferably one or more of rutile type titanium dioxide, iron oxide red and iron oxide black. The rutile type titanium dioxide is preferably one or more of DUPONT R706 titanium dioxide, DUPONT R960 titanium dioxide and DUPONT R826 titanium dioxide.
Preferably, the neutralizing agent is used to adjust the pH of the coating to be within the range of 7.5 to 9.3, preferably 2-amino-2-methyl-1-propanol, such as AMP-95 from the Dow chemical company.
Preferably, the preservative is MBS, UK Soler.
Preferably, the film forming aid is Texanol of Istman chemical company (EASTMAN).
Preferably, the anti-freezing agent can be selected from anti-freezing agents conventionally used in the coating field, preferably propylene glycol.
Preferably, the water is deionized water.
Preferably, the dispersing wetting agent may be one or more of dispersing wetting agent SN-5027 sold by Novaco auxiliary Co., Ltd, and dispersing wetting agent SN-5029 sold by Novaco auxiliary Co., Ltd.
Preferably, the silicone antifoaming agent may be one or more of antifoaming agent SN-154 sold by Norpunaceae auxiliary company, Japan, and Shenzhen Shanghai chemical company, Japan, antifoaming agent A-10.
Preferably, the thickener may be a 30000 viscosity hydroxyethylcellulose and hydrophobically modified alkali swellable thickener, more preferably 250HBR cellulose and thickener TT-615.
The invention also provides a preparation method of the imitated long-strip limestone water-in-water coating, which comprises the following steps of:
step (1): uniformly mixing an organic silicon defoaming agent, the dispersing and wetting agent, the pigment and filler, the thickening agent and the residual water at room temperature according to the mass percentage, and grinding the mixture to be less than 40 mu m to obtain a mixture;
step (2): adding the rest of the organic silicon defoaming agent, the pure acrylic emulsion, the protective adhesive and the thickening agent into the mixture at the stirring speed of 300-500 rpm, and uniformly mixing to obtain the strip-shaped lime stone water-in-water coating base material;
and (3): adding 30-50% of the imitated long-strip limestone water-in-water coating base material into a protective glue solution at a stirring rotating speed of 100-300 rpm, and dispersing and granulating to obtain imitated long-strip limestone water-in-water coating color particles;
and (4): adding the rest of emulsion, a film forming aid, an antifreezing agent, a thickening agent and water at a stirring speed of 300-500 rpm, and uniformly mixing to obtain the strip-like limestone water-in-water coating continuous phase emulsion;
and (5): and mixing the colored particles of the imitated long-strip limestone water-in-water coating with the continuous phase emulsion of the imitated long-strip limestone water-in-water coating at the stirring speed of 100-200 rpm to obtain the finished product of the imitated long-strip limestone water-in-water coating.
And (6): the imitative long-strip limestone water-in-water coating is sprayed by a special spray gun, and after the surface is dried, plastic paper is dipped with a small amount of diluted coating to perform patting according to a limestone pattern.
And (7): and after the surface of the patted coating is dried, polishing to be smooth by using abrasive paper.
And (8): and (7) covering the surface.
The room temperature is defined by the conventional definition in the field, and is generally 5-40 ℃.
By adopting the imitated long-strip limestone water-in-water coating, the surface is sprayed by a special spray gun and dried, then the plastic paper is used for dipping the coating part for patting, and the plastic paper is polished after being dried, so that the decorative effect of the water-in-water coating is improved, the water-in-water coating has the high-end elegant stone-like effect of limestone, and the attractive design requirement is met.
The coating disclosed by the invention not only has the decorative effect of limestone, but also has strong adaptability to a base layer, can be used on various building materials, also belongs to an environment-friendly material, is convenient to construct, can achieve a stone-like effect which can be achieved only by multi-gun spraying of texture paint through one-time spraying, and has a stone-like decorative effect which is difficult to imitate by natural limestone.
The raw materials used by the imitated long-strip limestone water-in-water are available in the market, the raw material obtaining mode is simple and environment-friendly, the cost is low, and the environment-friendly concept is very met. The preparation method has the advantages of simple process, no toxic or harmful substances in production, environmental protection and suitability for large-scale industrial production.
Detailed Description
In order to clearly understand the technical contents of the present invention, the following examples are given in detail.
The following are the source of raw materials used in the examples:
pure acrylic emulsion 1048-3; japanese Showa Polymer Ltd;
silicone-acrylate emulsion 3788: shanghai Bade Fukuji Co., Ltd;
protective rubber powder S482: konai European Shanghai trade Co., Ltd;
pigment and filler: titanium dioxide is rutile type titanium dioxide, preferably R706 of DuPont; the filler may be various conventionally used fillers having weather resistance up to 5 grades and 7 grades.
Defoaming agents SN-154 and SN-345: nophaceae auxiliary agents, japan;
thickener TT-615: dow chemical company;
film-forming aid Texanol: istman chemical company;
neutralizer AMP-95: dow chemical company;
preservative MBS: UK Soll;
dispersing and wetting agent: nophaceae auxiliary agents, japan;
example 1
The raw material formula (wt%) of the imitated long-strip limestone water-in-water coating is shown in the following table 1
TABLE 1 raw material formulation (wt%) of imitated long-strip limestone water-in-water paint
Base paint
| Deionized water | 51％ |
| Organic silicon defoaming agent | 0.2％ |
| Dispersing agent | 0.3％ |
| 3 ten thousand cellulose | 0.9％ |
| Neutralizing agent | 0.2％ |
| Pigment and filler | 15％ |
| Emulsion and method of making | 20％ |
| Thickening agent | 0.4％ |
| Protective glue solution | 12％ |
Finished product color particle
| Protective glue solution | 40％ |
| Base paint | 60％ |
Finished paint
| Deionized water | 37.7％ |
| Silicone-acrylic emulsion | 30％ |
| Film forming aid | 2％ |
| Finished particle | 30％ |
| Thickening agent | 0.3％ |
The preparation method comprises the following steps:
according to the formula of the strip-shaped limestone water-in-water coating base paint, uniformly mixing an organic silicon defoamer, a wetting dispersant, a pigment filler, thirty-thousand cellulose and water at room temperature, grinding to be less than 40 mu m, adding an emulsion, a protective adhesive, a thickening agent and water at the stirring rotation speed of 300-500 rpm, and uniformly mixing to prepare the strip-shaped limestone water-in-water coating base paint; wherein the percentages are mass percentages relative to the mass of each corresponding component.
According to the formula of the finished colored particles of the long-strip limestone water-in-water coating, uniformly mixing the protective glue solution and the base paint of the long-strip limestone water-in-water coating, and stirring at the rotating speed of 100-300 rpm to obtain the finished colored particles.
According to the formula of the long-strip-shaped limestone water-in-water coating finished paint, the silicone-acrylic emulsion, the film forming aid, the thickening agent and the rest water are stirred and mixed uniformly at 100-300 rpm to prepare the long-strip-shaped limestone water-in-water coating finished paint.
Spraying the long-strip limestone water-in-water coating by using a special spray gun, and after the surface is dried, dipping a small amount of diluted coating by using plastic paper to perform patting according to a limestone pattern.
And (4) polishing to be smooth by using abrasive paper after the surface of the imitative strip-shaped limestone water-in-water coating is dried.
And (5) finishing with finish paint according to the polished and leveled coating.
Example 2
The raw material formula (wt%) of the imitated long-strip limestone water-in-water coating is shown in the following table 2.
Base paint
| Deionized water | 54.3％ |
| Organic silicon defoaming agent | 0.15％ |
| Dispersing agent | 0.4％ |
| 3 ten thousand cellulose | 0.8％ |
| Neutralizing agent | 0.15％ |
| Pigment and filler | 12％ |
| Emulsion and method of making | 22％ |
| Thickening agent | 0.2％ |
| Protective glue solution | 10％ |
Finished product color particle
| Protective glue solution | 50％ |
| Base paint | 50％ |
Finished paint
| Deionized water | 41.45％ |
| Silicone-acrylic emulsion | 28％ |
| Film forming aid | 2.2％ |
| Finished particle | 28％ |
| Thickening agent | 0.35％ |
The preparation method comprises the following steps:
the preparation method and the corresponding construction method are the same as in example 1.
Example 3
The raw material formula (wt%) of the imitated long-strip limestone water-in-water coating is shown in the following table 3.
Raw material formula (wt%) of imitated long-strip limestone water-in-water coating of example 3
Base paint
| Deionized water | 53.12％ |
| Organic silicon defoaming agent | 0.18％ |
| Dispersing agent | 0.35％ |
| 3 ten thousand cellulose | 1.0％ |
| Neutralizing agent | 0.15％ |
| Pigment and filler | 13％ |
| Emulsion and method of making | 21％ |
| Thickening agent | 0.2％ |
| Protective glue solution | 11％ |
Finished product color particle
| Protective glue solution | 40％ |
| Base paint | 60％ |
Finished paint
| Deionized water | 35.5％ |
| Silicone-acrylic emulsion | 32％ |
| Film forming aid | 2.1％ |
| Finished particle | 30％ |
| Thickening agent | 0.4％ |
The preparation method and the corresponding construction method are the same as in example 1.
Example 4
The raw material formula (wt%) of the imitated long-strip limestone water-in-water coating is shown in the following table 4.
Raw material formula (wt%) of imitated long-strip limestone water-in-water coating of example 4
Base paint
Finished product color particle
| Protective glue solution | 40％ |
| Base paint | 60％ |
Finished paint
| Deionized water | 38.1％ |
| Silicone-acrylic emulsion | 25％ |
| Film forming aid | 1.5％ |
| Finished particle | 35％ |
| Thickening agent | 0.4％ |
The preparation method and the corresponding construction method are the same as in example 1.
TABLE 5 Performance indices of the elongated limestone water-in-water coatings of examples 1-4
TABLE 6 Environment-friendly Performance index of the water-in-water coating of limestone in strip shape of examples 1 to 4
As can be seen from tables 5 and 6, the performances of the long-strip limestone water-in-water coating of the invention, such as weather resistance, water resistance, alkali resistance, durability and the like, are greatly the same and slightly different, and the long-strip limestone water-in-water coating conforms to various performance indexes of environmental protection, does not generate any harmful gas, and is a real environment-friendly pollution-free coating.
In this specification, the invention has been described with reference to specific embodiments thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the invention. The description is thus to be regarded as illustrative instead of limiting.
Claims (9)
1. The water-in-water coating imitating the elongated limestone is characterized by comprising a continuous phase and color grains dispersed in the continuous phase, wherein the color grains comprise the following components: emulsion, protective glue solution, thickening agent, pigment and filler, dispersing and wetting agent and organic silicon defoaming agent; the continuous phase comprises the following components: emulsion, film forming assistant, antifreezing agent and thickening agent.
2. The water-in-water coating for imitating long-strip limestone as claimed in claim 1, which is characterized by comprising the following components in percentage by mass:
3. the water-in-water coating imitating long-strip limestone as claimed in claim 1, wherein the emulsion is flexible pure acrylic emulsion or water-based silicone acrylic emulsion.
4. The water-in-water coating of imitated linear limestone as claimed in claim 3, wherein the emulsion is a pure acrylic emulsion, the pure acrylic emulsion comprises Japanese Showa emulsion 1048-3 and/or Shanghai Baddy Fuji corporation's 6733 emulsion; or the emulsion is silicone-acrylate emulsion, and the silicone-acrylate emulsion comprises silicone-acrylate emulsion KD96 of Shanghai Baoligai chemical industry Co., Ltd and/or silicone-acrylate emulsion 3788 of Shanghai Bade Fukuyu Co., Ltd.
5. The water-in-water coating imitating long-strip limestone as claimed in claim 1, wherein the protective glue is Kochou S482 protective glue powder.
6. The water-in-water coating imitating long-strip limestone as claimed in claim 1, wherein the pigment and filler is one or more of kaolin filler, carbon black, iron oxide red and iron oxide yellow.
7. The water-in-water coating of the imitated long-strip limestone as claimed in claim 1, wherein the pigment in the pigment and filler is one or more of DUPONT R706 titanium dioxide, DUPONT R960 titanium dioxide and DUPONT R826 titanium dioxide.
8. The water-in-water coating imitating long-strip limestone as claimed in claim 1, wherein the neutralizing agent is 2-amino-2-methyl-1-propanol, AMP-95 manufactured by Dow chemical company; the preservative is MBS (methyl methacrylate-butadiene-styrene) of British Sol; the film-forming additive is Texanol of Istmann chemical company; the antifreezing agent is propylene glycol; the dispersing wetting agent can be one or more of a dispersing wetting agent SN-5027 sold by Novaceae auxiliary agent Co.Ltd, and a dispersing wetting agent SN-5029 sold by Novaceae auxiliary agent Co.Ltd; the organic silicon defoaming agent is one or more of defoaming agent SN-154 sold by Norppocrate auxiliary agent Co., Ltd, defoaming agent SN-345 sold by Norppocrate auxiliary agent Co., Ltd and defoaming agent A-10 sold by Shenzhen Shang Sichuan chemical industry Co., Ltd; the thickener is 250HBR cellulose and a thickener TT-615.
9. A construction method of the water-in-water paint based on the imitated long-strip limestone as claimed in any one of claims 1 to 8, characterized in that the method comprises the following steps:
(1) spraying the coating;
(2) after the surface is dried, dipping the diluted coating by using plastic paper, and patting according to the limestone pattern;
(3) after the surface of the patted coating is dried, polishing the patted coating to be flat by using abrasive paper;
(4) and (7) covering the surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910184023.5A CN111690303A (en) | 2019-03-12 | 2019-03-12 | Water-in-water coating imitating long-strip limestone and corresponding construction method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910184023.5A CN111690303A (en) | 2019-03-12 | 2019-03-12 | Water-in-water coating imitating long-strip limestone and corresponding construction method |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280817A (en) * | 2015-05-12 | 2017-01-04 | 上海三银涂料科技股份有限公司 | Aqueous colorful luminous paint and preparation method thereof |
| CN108285711A (en) * | 2018-02-10 | 2018-07-17 | 浙江德尔福涂料有限公司 | A kind of imitative lime fluorspar coating and preparation method thereof |
| CN109233508A (en) * | 2017-05-23 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Water-water imitation marble paint and its preparation method and application |
-
2019
- 2019-03-12 CN CN201910184023.5A patent/CN111690303A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280817A (en) * | 2015-05-12 | 2017-01-04 | 上海三银涂料科技股份有限公司 | Aqueous colorful luminous paint and preparation method thereof |
| CN109233508A (en) * | 2017-05-23 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Water-water imitation marble paint and its preparation method and application |
| CN108285711A (en) * | 2018-02-10 | 2018-07-17 | 浙江德尔福涂料有限公司 | A kind of imitative lime fluorspar coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 唐直贤等: "仿石灰石效果涂料的制备", 《上海涂料》 * |
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Application publication date: 20200922 |
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