CN108285711A - A kind of imitative lime fluorspar coating and preparation method thereof - Google Patents
A kind of imitative lime fluorspar coating and preparation method thereof Download PDFInfo
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- CN108285711A CN108285711A CN201810137673.XA CN201810137673A CN108285711A CN 108285711 A CN108285711 A CN 108285711A CN 201810137673 A CN201810137673 A CN 201810137673A CN 108285711 A CN108285711 A CN 108285711A
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- Prior art keywords
- base
- ludox
- acrylic emulsion
- silicone acrylic
- thickener
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- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 239000011248 coating agent Substances 0.000 title claims abstract description 33
- 235000008733 Citrus aurantifolia Nutrition 0.000 title claims abstract description 28
- 235000011941 Tilia x europaea Nutrition 0.000 title claims abstract description 28
- 239000010436 fluorite Substances 0.000 title claims abstract description 28
- 239000004571 lime Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 128
- 239000000463 material Substances 0.000 claims abstract description 70
- 239000000839 emulsion Substances 0.000 claims abstract description 59
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000003381 stabilizer Substances 0.000 claims abstract description 32
- 238000012856 packing Methods 0.000 claims abstract description 26
- 239000002270 dispersing agent Substances 0.000 claims abstract description 25
- -1 coalescents Substances 0.000 claims abstract description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 84
- 239000002562 thickening agent Substances 0.000 claims description 42
- 239000000377 silicon dioxide Substances 0.000 claims description 38
- 235000013312 flour Nutrition 0.000 claims description 36
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 26
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 26
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000002518 antifoaming agent Substances 0.000 claims description 21
- 241000276489 Merlangius merlangus Species 0.000 claims description 19
- LHYBFKLQIPFQAP-UHFFFAOYSA-N NC(C(C(C)(C)O)O)N Chemical compound NC(C(C(C)(C)O)O)N LHYBFKLQIPFQAP-UHFFFAOYSA-N 0.000 claims description 14
- 229920002678 cellulose Polymers 0.000 claims description 13
- 239000001913 cellulose Substances 0.000 claims description 13
- 159000000000 sodium salts Chemical group 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 235000019738 Limestone Nutrition 0.000 abstract description 14
- 239000006028 limestone Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 12
- 239000004575 stone Substances 0.000 abstract description 9
- 239000003973 paint Substances 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 4
- 244000137852 Petrea volubilis Species 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005498 polishing Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007096 poisonous effect Effects 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 238000005034 decoration Methods 0.000 description 3
- 235000015110 jellies Nutrition 0.000 description 3
- 239000008274 jelly Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- BVWUNQADJNOXKU-UHFFFAOYSA-N 1-amino-3-methylbutane-2,3-diol Chemical compound CC(C)(O)C(O)CN BVWUNQADJNOXKU-UHFFFAOYSA-N 0.000 description 2
- IDEOPBXRUBNYBN-UHFFFAOYSA-N 2-methylbutane-2,3-diol Chemical compound CC(O)C(C)(C)O IDEOPBXRUBNYBN-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of imitative lime fluorspar coatings, it is made of base's main material knead dough layer decorative pattern color dot two parts, base's main material includes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water, and face layer decorative pattern color dot includes silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer and water.A kind of imitative lime fluorspar coating of the present invention, it is environment-protecting and non-poisonous, production prepares simple, it is changed using the filming performance after silicone acrylic emulsion and Ludox compounding, the grinability of paint film is set to obtain larger improvement, be conducive to be polished flat with sand paper, after the completion of finished product construction, it obtains being similar to the surface effect after lime stone stone polishing, and the intrinsic strength of coating, hardness is similar to lime stone, color of guaranteeing the quality exists for a long time, durability is up to 20 years or more, its effect is similar to the decorative effect of lime stone, weight but only has the weight of lime stone 1/30, compared with lime stone, energy conservation and environmental protection, without security risk, decorative effect is good.
Description
【Technical field】
The present invention relates to the technical field of building coating, more particularly to a kind of imitative lime fluorspar coating and preparation method thereof.
【Background technology】
The imitative lime fluorspar coating used currently on the market is usually silicon pure-acrylic emulsion for the coating of single film forming matter, have compared with
Good weatherability and polluting proofing property, the disadvantage is that paint film feels like jelly, grinability is too poor, especially summer, when polishing occur scab paper,
Phenomena such as rubbing leather, is serious, is difficult to tie whole on imitative lime fluorspar coating surface, in addition film forming matter is organic silicone acrylic emulsion, firmly
Degree is insufficient, the result is that lime stone stone surface effect and inherent hardness cannot be similar to.In order to solve silicon pure-acrylic emulsion at
Paint film after film feels like jelly phenomenon, improves the grinability of coating, imitates lime fluorspar coating surface to enhance and obtains lime stone stone
The flat smooth effect on material surface, it is necessary to propose a kind of imitative lime fluorspar coating and preparation method thereof.
【Invention content】
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, a kind of imitative lime fluorspar coating and its preparation side are provided
Method aims to solve the problem that the paint film after the film forming of silicon pure-acrylic emulsion in the prior art feels like jelly phenomenon, the grinability of coating is poor, hardness not
The technical issues of causing to cannot get lime stone stone surface flat smooth effect enough.
To achieve the above object, the present invention proposes a kind of imitative lime fluorspar coating, by base's main material knead dough layer decorative pattern color dot
Two parts form,
Base's main material includes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water, each component
Weight percent be respectively：Silicone acrylic emulsion 10~20%, Ludox 5~10%, packing material 65~70%, coalescents 1
~1.5%, stabilizer 0.1~0.2%, remaining is water；
The face layer decorative pattern color dot includes silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer
And water, the weight percent of each component are respectively：Silicone acrylic emulsion 12.5~20%, Ludox 7.5~10%, packing material 40~
50%, coalescents 1~1.5%, dispersant 0.05~0.15%, stabilizer 0.1~0.2%, remaining is water.
Preferably, base's main material removes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water
Except, further include weight percent be 0.1%~0.2% adhesive, weight percent be 0.5%~1.5% antifoaming agent
With suitable thickener and mill base, the packing material in base's main material is silica flour, the mesh number of silica flour is 120~
280 mesh, coalescents are alcohol ester-12, and stabilizer is diamino dimethyl monopropylene glycol, and adhesive is hydroxyethyl cellulose, defoaming
Agent is propylene glycol, and thickener is cellulose thickener；
The described face layer decorative pattern color dot except silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer and
Except water, further include weight percent be 0.05~0.15% adhesive, weight percent be 0.5~1.5% antifoaming agent
With suitable thickener and mill base, the face layer decorative pattern color dot in packing material include silica flour and powdered whiting, stone
The mesh number of English powder is 200~400 mesh, and the mesh number of powdered whiting is 400 mesh, and coalescents are alcohol ester-12, and dispersant is sodium salt
Dispersant, stabilizer are diamino dimethyl monopropylene glycol, and adhesive is hydroxyethyl cellulose, and antifoaming agent is propylene glycol, thickener
For cellulose thickener；
The solid content of silicone acrylic emulsion in base's main material knead dough layer decorative pattern color dot is 49%, the solid content of Ludox
It is 25%.
Preferably, base's main material is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion 10%, silicon
Colloidal sol 10%, silica flour 70%, alcohol ester-12 1.2%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.2%,
Propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
Preferably, base's main material is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion 15%, silicon
Colloidal sol 5%, silica flour 70%, alcohol ester-12 1.2%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%,
Propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
Preferably, base's main material is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion 20%, silicon
Colloidal sol 5%, silica flour 65%, alcohol ester-12 1.2%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%,
Propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
Preferably, the face layer decorative pattern color dot is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion
12.5%, Ludox 7.5%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, two
Amino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, thickener and mill base 0.1%, remaining is
Water.
Preferably, the face layer decorative pattern color dot is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion
15%, Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, diamino
Base dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
Preferably, the face layer decorative pattern color dot is by weight percentage, it is grouped as by following group：Silicone acrylic emulsion
20%, Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, diamino
Base dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
The invention also provides a kind of preparation methods of imitative lime fluorspar coating, and knead dough layer decorative pattern color dot is prepared by base's main material
Two parts composition is prepared, it is as follows that base's main material prepares the step of prepared by knead dough layer decorative pattern color dot：
It is prepared by S1, base's main material：
It after each component for weighing base's main material by weight percentage, first adds water in blender, it is fine that ethoxy is then added
Element, stabilizer, silicone acrylic emulsion, Ludox, coalescents, silica flour are tieed up, is stirred evenly using 600r/min, is then put into right amount
Antifoaming agent avoids blistering, and color paste toning is added, and adds thickener, and stirring is adjusted to suitable viscosity；
It is prepared by S2, face layer decorative pattern color dot：
It after each component for weighing face layer decorative pattern color dot by weight percentage, first adds water in blender, hydroxyl second is then added
Base cellulose, stabilizer, silica flour, powdered whiting, antifoaming agent, 1500r/min high speed dispersion 30min add the third breast of silicon
Liquid, Ludox, coalescents, about 600r/min stir evenly, and are put into proper quantity of defoaming agent and avoid blistering, and appropriate mill base tune is added
Color adds thickener and adjusts viscosity to 4000cps.
Beneficial effects of the present invention：Compared with prior art, a kind of imitative lime fluorspar coating provided by the invention, environmentally friendly nothing
Poison, production are prepared simply, are changed using the filming performance after silicone acrylic emulsion and Ludox compounding, the grinability of paint film is made to obtain
To larger improvement, be conducive to be polished flat with sand paper, after the completion of finished product construction, obtain after being similar to lime stone stone polishing
Surface effect, and the intrinsic strength of coating, hardness are similar to lime stone, color of guaranteeing the quality exists for a long time, and durability is up to 20
Year or more, it can be used for architecture inside and outside decorations, the effects such as villa, row room and high-grade hotel and be similar to the decoration of lime stone
Effect, weight but only has the weight of lime stone 1/30, compared with lime stone, energy conservation and environmental protection, and no security risk, decoration
Effect is good.
The feature and advantage of the present invention will be described in detail by embodiment.
【Specific implementation mode】
In order to make the objectives, technical solutions and advantages of the present invention clearer, below by embodiment, to the present invention into
Row is further described.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, and do not have to
In limiting the scope of the invention.In addition, in the following description, descriptions of well-known structures and technologies are omitted, to avoid need not
Obscure idea of the invention in strategic point.
The embodiment of the present invention provides a kind of imitative lime fluorspar coating, is made of base's main material knead dough layer decorative pattern color dot two parts,
Base's main material includes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water, each component
Weight percent be respectively：Silicone acrylic emulsion 10~20%, Ludox 5~10%, packing material 65~70%, coalescents 1
~1.5%, stabilizer 0.1~0.2%, remaining is water；
The face layer decorative pattern color dot includes silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer
And water, the weight percent of each component are respectively：Silicone acrylic emulsion 12.5~20%, Ludox 7.5~10%, packing material 40~
50%, coalescents 1~1.5%, dispersant 0.05~0.15%, stabilizer 0.1~0.2%, remaining is water.
In embodiments of the present invention, the full name of silicone acrylic emulsion is that organosilicon is grafted pure acrylic acid synthetic resin emulsion, referred to as
For silicone acrylic emulsion.When silicone acrylic emulsion itself has excellent weatherability, water resistance and Ludox collocation film forming, silicone acrylic emulsion point
Dehydrating polycondensation reaction occurs between son and Ludox molecule, between Ludox and Ludox molecule into complicatedReticular structure, to make the hardness after film forming, weatherability, water resistance, stain resistant, adhesive strength obtain
It greatly improves, and Ludox improves the tacky phenomenon of paint film in the event of high temperatures after silicone acrylic emulsion film forming, makes paint film
Grinability obtains larger improvement.
Further, base's main material removes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water
Except, further include weight percent be 0.1%~0.2% adhesive, weight percent be 0.5%~1.5% antifoaming agent
With suitable thickener and mill base, the packing material in base's main material is silica flour, the mesh number of silica flour is 120~
280 mesh, coalescents are alcohol ester-12, and stabilizer is diamino dimethyl monopropylene glycol, and adhesive is hydroxyethyl cellulose, defoaming
Agent is propylene glycol, and thickener is cellulose thickener；Select fineness for the silica flour packing material of 120~280 mesh, and stone
The main component of English powder is SiO2, a part of SiO in such silica flour2With main film forming substance silicone acrylic emulsion and Ludox one
Dehydrating polycondensation reaction can also be occurred into complicated by risingReticular structure.
The described face layer decorative pattern color dot except silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer and
Except water, further include weight percent be 0.05~0.15% adhesive, weight percent be 0.5~1.5% antifoaming agent
With suitable thickener and mill base, the face layer decorative pattern color dot in packing material include silica flour and powdered whiting, stone
The mesh number of English powder is 200~400 mesh, and the mesh number of powdered whiting is 400 mesh, and coalescents are alcohol ester-12, and dispersant is sodium salt
Dispersant, stabilizer are diamino dimethyl monopropylene glycol, and adhesive is hydroxyethyl cellulose, and antifoaming agent is propylene glycol, thickener
For cellulose thickener；Main function using powdered whiting, silica flour is formed similar to lime stone stone patterns color
Component part in point.
The solid content of silicone acrylic emulsion in base's main material knead dough layer decorative pattern color dot is 49%, the solid content of Ludox
It is 25%.
The preparation of imitative lime fluorspar coating proposed by the invention includes that base's main material prepares the preparation of knead dough layer decorative pattern color dot, institute
It is as follows that the base's main material stated prepares the step of prepared by knead dough layer decorative pattern color dot：
It is prepared by S1, base's main material：
It after each component for weighing base's main material by weight percentage, first adds water in blender, it is fine that ethoxy is then added
Element, stabilizer, silicone acrylic emulsion, Ludox, coalescents, silica flour are tieed up, is stirred evenly using 600r/min, is then put into right amount
Antifoaming agent avoids blistering, and color paste toning is added, and adds thickener, and stirring is adjusted to suitable viscosity；
It is prepared by S2, face layer decorative pattern color dot：
It after each component for weighing face layer decorative pattern color dot by weight percentage, first adds water in blender, hydroxyl second is then added
Base cellulose, stabilizer, silica flour, powdered whiting, antifoaming agent, 1500r/min high speed dispersion 30min add the third breast of silicon
Liquid, Ludox, coalescents, about 600r/min stir evenly, and are put into proper quantity of defoaming agent and avoid blistering, and appropriate mill base tune is added
Color adds thickener and adjusts viscosity to 4000cps.
Embodiment one,
A kind of imitative lime fluorspar coating is made of base's main material knead dough layer decorative pattern color dot two parts, and base's main material is pressed
Weight percent meter is grouped as by following group：Silicone acrylic emulsion 10%, Ludox 10%, silica flour 70%, alcohol ester-12 1.2%,
Diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.2%, propylene glycol 1%, cellulose thickener and mill base
0.1%, remaining is water；The face layer decorative pattern color dot by weight percentage, is grouped as by following group：Silicone acrylic emulsion
12.5%, Ludox 7.5%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, two
Amino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, cellulose thickener and mill base 0.1%,
Remaining is water.
Embodiment two,
A kind of imitative lime fluorspar coating is made of base's main material knead dough layer decorative pattern color dot two parts, and base's main material is pressed
Weight percent meter is grouped as by following group：Silicone acrylic emulsion 15%, Ludox 5%, silica flour 70%, alcohol ester-12 1.2%,
Diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, cellulose thickener and mill base
0.1%, remaining is water；The face layer decorative pattern color dot by weight percentage, is grouped as by following group：Silicone acrylic emulsion 15%,
Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, diamino diformazan
Base monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, cellulose thickener and mill base 0.1%, remaining is
Water.
Embodiment three,
A kind of imitative lime fluorspar coating is made of base's main material knead dough layer decorative pattern color dot two parts, and base's main material is pressed
Weight percent meter is grouped as by following group：Silicone acrylic emulsion 20%, Ludox 5%, silica flour 65%, alcohol ester-12 1.2%,
Diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, cellulose thickener and mill base
0.1%, remaining is water；The face layer decorative pattern color dot by weight percentage, is grouped as by following group：Silicone acrylic emulsion 20%,
Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-12 1.2%, sodium salt dispersant 0.1%, diamino diformazan
Base monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, cellulose thickener and mill base 0.1%, remaining is
Water.
In embodiment one to embodiment three, the effect of alcohol ester-12 is to improve the filming performance of silicone acrylic emulsion；Diamino two
The PD-15 of Total SA's production can be selected in methyl monopropylene glycol, and SN5040 can be selected in sodium salt dispersant.
A kind of construction method for imitative lime fluorspar coating that embodiment one to embodiment three is proposed is：
1, base's main material is using batch scraping or spraying application, forms base after construction 2~3 times, and thickness need to reach 1~
1.5mm；
2, face layer sprayed in substrate surface using spray gun and roller, roller coating, or carries out chromatography with sponge or wipes color, prints
Line；
3, it after drying to be coated, is polished flat with 240 mesh sand paper, then with semi-matte silicon the third cover agent cover.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.
Claims (9)
1. a kind of imitative lime fluorspar coating is made of base's main material knead dough layer decorative pattern color dot two parts, it is characterised in that：
Base's main material includes silicone acrylic emulsion, Ludox, packing material, coalescents, stabilizer and water, the weight of each component
Measuring percentage is respectively：Silicone acrylic emulsion 10~20%, Ludox 5~10%, packing material 65~70%, coalescents 1~
1.5%, stabilizer 0.1~0.2%, remaining is water；
The described face layer decorative pattern color dot include silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer and
The weight percent of water, each component is respectively：Silicone acrylic emulsion 12.5~20%, Ludox 7.5~10%, packing material 40~
50%, coalescents 1~1.5%, dispersant 0.05~0.15%, stabilizer 0.1~0.2%, remaining is water.
2. a kind of imitative lime fluorspar coating as described in claim 1, it is characterised in that：Base's main material except silicone acrylic emulsion,
Further include the gluing that weight percent is 0.1%~0.2% except Ludox, packing material, coalescents, stabilizer and water
Agent, weight percent are 0.5%~1.5% antifoaming agent and suitable thickener and mill base, filling out in base's main material
It is silica flour to fill material, and the mesh number of silica flour is 120~280 mesh, and coalescents are alcohol ester-12, and stabilizer is diamino diformazan
Base monopropylene glycol, adhesive are hydroxyethyl cellulose, and antifoaming agent is propylene glycol, and thickener is cellulose thickener；
The described face layer decorative pattern color dot except silicone acrylic emulsion, Ludox, packing material, coalescents, dispersant, stabilizer and water it
Outside, further include adhesive, the weight percent antifoaming agent that is 0.5~1.5% and suitable that weight percent is 0.05~0.15%
The thickener and mill base of amount, the face layer decorative pattern color dot in packing material include silica flour and powdered whiting, silica flour
Mesh number be 200~400 mesh, the mesh number of powdered whiting is 400 mesh, and coalescents are alcohol ester-12, and dispersant is sodium salt dispersion
Agent, stabilizer are diamino dimethyl monopropylene glycol, and adhesive is hydroxyethyl cellulose, and antifoaming agent is propylene glycol, and thickener is fibre
The plain class thickener of dimension；
The solid content of silicone acrylic emulsion in base's main material knead dough layer decorative pattern color dot is 49%, and the solid content of Ludox is
25%.
3. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：Base's main material is by weight percentage
Meter, is grouped as by following group：Silicone acrylic emulsion 10%, Ludox 10%, silica flour 70%, alcohol ester-12 1.2%, diamino diformazan
Base monopropylene glycol 0.15%, hydroxyethyl cellulose 0.2%, propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
4. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：Base's main material is by weight percentage
Meter, is grouped as by following group：Silicone acrylic emulsion 15%, Ludox 5%, silica flour 70%, alcohol ester-12 1.2%, diamino diformazan
Base monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
5. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：Base's main material is by weight percentage
Meter, is grouped as by following group：Silicone acrylic emulsion 20%, Ludox 5%, silica flour 65%, alcohol ester-12 1.2%, diamino diformazan
Base monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol 1%, thickener and mill base 0.1%, remaining is water.
6. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：The face layer decorative pattern color dot by weight hundred
Divide than meter, is grouped as by following group：Silicone acrylic emulsion 12.5%, Ludox 7.5%, silica flour 15%, powdered whiting 30%, alcohol
Ester -12 1.2%, sodium salt dispersant 0.1%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol
1%, thickener and mill base 0.1%, remaining is water.
7. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：The face layer decorative pattern color dot by weight hundred
Divide than meter, is grouped as by following group：Silicone acrylic emulsion 15%, Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-
12 1.2%, sodium salt dispersant 0.1%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol
1%, thickener and mill base 0.1%, remaining is water.
8. a kind of imitative lime fluorspar coating as claimed in claim 2, it is characterised in that：The face layer decorative pattern color dot by weight hundred
Divide than meter, is grouped as by following group：Silicone acrylic emulsion 20%, Ludox 10%, silica flour 15%, powdered whiting 30%, alcohol ester-
12 1.2%, sodium salt dispersant 0.1%, diamino dimethyl monopropylene glycol 0.15%, hydroxyethyl cellulose 0.1%, propylene glycol
1%, thickener and mill base 0.1%, remaining is water.
9. a kind of preparation method of imitative lime fluorspar coating, it is characterised in that：Knead dough layer decorative pattern color dot is prepared by base's main material to prepare
Two parts form, and it is as follows that base's main material prepares the step of prepared by knead dough layer decorative pattern color dot：
It is prepared by S1, base's main material：
It after each component for weighing base's main material by the weight percent in claim 2, first adds water in blender, is then added
Hydroxyethyl cellulose, stabilizer, silicone acrylic emulsion, Ludox, coalescents, silica flour, are stirred evenly using 600r/min, then
It is put into antifoaming agent in right amount to avoid blistering, color paste toning is added, add thickener, stirring is adjusted to suitable viscosity；
It is prepared by S2, face layer decorative pattern color dot：
After each component for weighing face layer decorative pattern color dot by the weight percent in claim 2, first add water in blender, then
Hydroxyethyl cellulose, stabilizer, silica flour, powdered whiting, antifoaming agent, 1500r/min high speed dispersion 30min is added, then adds
Enter silicone acrylic emulsion, Ludox, coalescents, about 600r/min is stirred evenly, and is put into proper quantity of defoaming agent and is avoided blistering, and is added appropriate
Color paste toning adds thickener and adjusts viscosity to 4000cps.
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| CN201810137673.XA CN108285711B (en) | 2018-02-10 | 2018-02-10 | Limestone-like coating and preparation method thereof |
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| CN201810137673.XA CN108285711B (en) | 2018-02-10 | 2018-02-10 | Limestone-like coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111040535A (en) * | 2019-12-02 | 2020-04-21 | 嘉宝莉化工集团股份有限公司 | Stone-imitated textured paint and preparation method thereof |
| CN111116103A (en) * | 2019-12-02 | 2020-05-08 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN111690303A (en) * | 2019-03-12 | 2020-09-22 | 上海三银涂料科技股份有限公司 | Water-in-water coating imitating long-strip limestone and corresponding construction method |
| CN112341889A (en) * | 2020-11-30 | 2021-02-09 | 富思特新材料科技发展股份有限公司 | Texture coating and preparation method and application thereof |
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| CN104804482A (en) * | 2015-05-04 | 2015-07-29 | 常熟市优德爱涂料有限公司 | Water-based coating with natural limestone imitating effect and preparation method of water-based coating |
| CN107286785A (en) * | 2017-06-30 | 2017-10-24 | 常州豫春化工有限公司 | A kind of stone-like coating and preparation method thereof |
| CN107446449A (en) * | 2017-07-27 | 2017-12-08 | 芜湖市三山龙城新材料有限公司 | Colorful imitation marble paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104804482A (en) * | 2015-05-04 | 2015-07-29 | 常熟市优德爱涂料有限公司 | Water-based coating with natural limestone imitating effect and preparation method of water-based coating |
| CN107286785A (en) * | 2017-06-30 | 2017-10-24 | 常州豫春化工有限公司 | A kind of stone-like coating and preparation method thereof |
| CN107446449A (en) * | 2017-07-27 | 2017-12-08 | 芜湖市三山龙城新材料有限公司 | Colorful imitation marble paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111690303A (en) * | 2019-03-12 | 2020-09-22 | 上海三银涂料科技股份有限公司 | Water-in-water coating imitating long-strip limestone and corresponding construction method |
| CN111040535A (en) * | 2019-12-02 | 2020-04-21 | 嘉宝莉化工集团股份有限公司 | Stone-imitated textured paint and preparation method thereof |
| CN111116103A (en) * | 2019-12-02 | 2020-05-08 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN111116103B (en) * | 2019-12-02 | 2021-12-07 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN112341889A (en) * | 2020-11-30 | 2021-02-09 | 富思特新材料科技发展股份有限公司 | Texture coating and preparation method and application thereof |
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|---|---|
| CN108285711B (en) | 2021-01-22 |
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Denomination of invention: A limestone like coating and its preparation method Effective date of registration: 20231111 Granted publication date: 20210122 Pledgee: Henggang sub branch of Zhejiang Haiyan Rural Commercial Bank Co.,Ltd. Pledgor: Zhejiang Delphi new building materials Co.,Ltd. Registration number: Y2023330002625 |
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