CN104072662B - The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial - Google Patents
The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial Download PDFInfo
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- CN104072662B CN104072662B CN201410325649.0A CN201410325649A CN104072662B CN 104072662 B CN104072662 B CN 104072662B CN 201410325649 A CN201410325649 A CN 201410325649A CN 104072662 B CN104072662 B CN 104072662B
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Abstract
The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial, relates to artificial color sand preparation field.Artificial color sand is prepared with acrylic resin modified, is made up of butyl acetate 27～33 parts, propylene glycol methyl ether acetate 7～15 parts, methacrylic acid 0.9～4 parts, butyl acrylate 8～13 parts, methyl methacrylate 10～15 parts, butyl methacrylate 5～15 parts, hydroxyethyl methylacrylate 10～15 parts, hexafluorobutyl acrylate 2～10 parts, tertiary carbonic acid glycidyl ester 2～10 parts and di-t-butyl peroxide 1～3 parts.By introducing fluorine monomer in acrylic resin, and access certain tertiary carbonic acid glycidyl ester, the weather resistances such as the adhesive force of resin, hardness, acid and alkali-resistance can be obviously improved.Can meet or exceed the properties of common color sand in the artificial color sand performance the most in every respect made, there is good weatherability, so that the color variety of true mineral varnish coating is more diversified.
Description
Technical field
The present invention relates to artificial color sand preparation field, be specifically related to a kind of artificial color sand preparation modified acroleic acid tree
Fat, the preparation method of artificial color sand.
Background technology
Artificial color sand forms through purity quartzite dye system, has non-fading feature, and the color sand of dyeing compensate for sky
The shortcomings the such as so color of color sand is the most bright-coloured and color kind is few, color is firm, lasting, colour-fast.It is mainly used in all kinds of colour circle
Oxygen terrace, true mineral varnish, various building coatings, sand rock plate, ABS modified felt, waterproof roll, artware etc., it is bright in luster, resistance to
Hou Xingqiang, wear-resisting acid and alkali-resistance, anti-skidding, seamless, high-grade attractive in appearance, it is mainly used in the various industries such as decoration, artware.
Utilize the products such as novel inner-outer wall mineral varnish, embossment that artificial color sand makes, have wear-resisting, waterproof, anticorrosion, nontoxic,
The features such as cohesive force is the most lucuriant in design, are widely used in architectural engineering and interior decoration, embossment etc..With artificial color sand making
Senior spraying paint, has the features such as nontoxic, tasteless, gloss is bright-coloured, tone is soft, third dimension is strong.Variegation is utilized to lay
Ground, road surface can play beautify the environment, the effect of health of body.
Artificial color sand preparation existing certain paper, product and patent report, such as: Publication No. CN102464460A
Chinese invention patent " a kind of color sand and preparation method thereof ", resin used is acrylic resin, does not has modification." the color sand of artificial system
And the preparation technology of sand texture coating " the civilian preparation method reported of (http://www.caisand.com/news/118.html)
Resin used by is styrene-acrylate copolymer emulsion；Patent of invention 200510120760.7 " a kind of water-base epoxy color sand mortar and system thereof
Preparation Method and construction method ", then utilize epoxy resin to prepare dye sand and paint.
Utilize artificial color sand prepared by above-mentioned resin material, be primarily present the weatherabilities such as resin adhesive force, hardness, acid and alkali-resistance
The defect that energy is poor.
Summary of the invention
In order to overcome present in above-mentioned prior art in place of shortcoming, the present invention provides a kind of artificial color sand successively and prepares
With color sand acrylic resin modified and preparation method thereof, artificial prepare with dye sand paint and preparation method thereof, artificial color sand and
True mineral varnish of application of its preparation method, manually coloured silk sand and preparation method thereof.
In order to solve the technical problem of the present invention, the technical scheme used is: a kind of acrylic resin modified, by as follows
The raw material of weight portion is made:
Acrylic resin modified preparation method, is first placed in reaction vessel by butyl acetate and propylene glycol methyl ether acetate
In be heated to backflow, then remaining ingredient 4h is dropped in reaction vessel, drips off and maintain the reflux at least 4h, after sampling detection is qualified
Cooling discharge.
The dye sand utilizing acrylic resin modified preparation is painted, and is made up of the raw material of following weight portion:
The preparation method that dye sand is painted, by all raw material mix homogeneously, being ground to fineness is below 15 μm.
Utilize dye sand to paint the artificial color sand of preparation, be made up of the raw material of following weight portion:
All raw materials are mixed to color even by the preparation method of artificial color sand, dry or room temperature is placed.
The true mineral varnish utilizing artificial color sand to prepare, is made up of the raw material of following weight portion:
The preparation method of true mineral varnish, true mineral varnish silicone acrylic emulsion, the pre-dispersed slurry of 2.5%H4BR cellulose and 2%HHBR is fine
Tie up plain pre-dispersed slurry to stir, be slow added into antibacterial, propylene glycol and pure water, be slow added into after stirring 40～
80 mesh manually color sand and 80～120 mesh manually color sand, adds coalescents and defoamer, is uniformly mixing to obtain after stirring
True mineral varnish.
The present invention is by introducing fluorine monomer in acrylic resin, and accesses certain tertiary carbonic acid glycidyl ester, in tree
There is innovation in fat component, the weather resistances such as the adhesive force of resin, hardness, acid and alkali-resistance can be obviously improved, with this resin furnishing
Paint dye sand can meet the properties of color sand.Meanwhile, such artificial color sand spare resin is currently without report.
The present invention utilizes the acrylic resin modified of synthesis, makes after then paint colour common white sand and prepares color sand, warp
Can meet or exceed the properties of common color sand in detection performance in every respect, there is good weatherability, so that
The color variety of true mineral varnish coating is more diversified.
Detailed description of the invention
Below by embodiment, the present invention is specifically described, is served only for the present invention being further described, no
Being understood that as limiting the scope of the present invention, the present invention can be made by person skilled in art according to the content of foregoing invention
Go out some nonessential improvement and adjustment.
Embodiment 1
Artificial color sand preparation is with acrylic resin modified formula, as shown in the table:
Preparation technology: first A group is put into 500ml with the four of agitator, reflux condensing tube, thermometer and Dropping funnel
In mouth flask, it is heated to backflow while stirring, the most uniformly drips B component, within 4 hours, drip off；Drip off insulation backflow 4 little
Time, cooling after then sampling detection is qualified, filter, discharging, packaging.
Prepared by the present embodiment acrylic resin modified, has a technical specification as shown in the table:
| Project | Index | Remarks |
| Solid part | 60.0 ± 2% | |
| Viscosity | The 20-50 second | Form pipe, 25 DEG C |
| Acid number | 3-6 | |
| Hydroxy radical content | 3.0% | Calculate by 100% solid |
Embodiment 2
Artificial color sand preparation is with acrylic resin modified formula, as shown in the table:
Preparation technology is with embodiment 1.
Embodiment 3
Artificial color sand preparation is with acrylic resin modified formula, as shown in the table:
Preparation technology is with embodiment 1.
Embodiment 4
The formula that dye sand (coloring) is painted, as shown in the table:
| Raw material | Weight (g) |
| Embodiment 1 is prepared acrylic resin modified | 56 |
| Ferric oxide red colorant | 28 |
| Dispersant | 1 |
| PMA | 5 |
| Butyl acetate | 10 |
| Amount to | 100 |
Preparation technology: above-mentioned material is used high speed agitator mix homogeneously, grinds 2-4 road on sand mill, thin to paint
Degree is below 15 microns.
Embodiment 5
The formula that dye sand (coloring) is painted, as shown in the table:
| Raw material | Weight (g) |
| Embodiment 1 is prepared acrylic resin modified | 60 |
| Ferric oxide red colorant | 27 |
| Dispersant | 1.5 |
| PMA | 3.5 |
| Butyl acetate | 8 |
| Amount to | 100 |
Preparation technology is with embodiment 4.
Embodiment 6
The formula that dye sand (coloring) is painted, as shown in the table:
| Raw material | Weight (g) |
| Embodiment 1 is prepared acrylic resin modified | 50 |
| Ferric oxide red colorant | 29.5 |
| Dispersant | 0.5 |
| PMA | 8 |
| Butyl acetate | 12 |
| Amount to | 100 |
Preparation technology is with embodiment 4.
Embodiment 7
The formula of artificial color sand, as shown in the table:
| Raw material | Weight (g) |
| Common quartz white sand (10-120 mesh) | 1000 |
| The dye sand (coloring) of embodiment 4 preparation is painted | 10 |
| Butyl acetate | 20 |
| Firming agent: 3390 | 1.5 |
| Amount to | 1031.5 |
Coloring process: above-mentioned material adds sealed stirrer, stirring causes color even, then toasts in 70 DEG C of baking ovens
1 hour, or place 24 hours in room temperature.
The key property of artificial color sand prepared by the present embodiment is as shown in the table:
Embodiment 8
The formula of artificial color sand, as shown in the table:
| Raw material | Weight (g) |
| Common quartz white sand (10-120 mesh) | 1050 |
| The dye sand (coloring) of embodiment 4 preparation is painted | 6 |
| Butyl acetate | 24 |
| Firming agent: 3390 | 1 |
| Amount to | 1081 |
Coloring process is with embodiment 7.
Embodiment 9
The formula of artificial color sand, as shown in the table:
| Raw material | Weight (g) |
| Common quartz white sand (10-120 mesh) | 950 |
| The dye sand (coloring) of embodiment 4 preparation is painted | 18 |
| Butyl acetate | 15 |
| Firming agent: 3390 | 3 |
| Amount to | 986 |
Coloring process is with embodiment 7.
Embodiment 10
The formula of true mineral varnish, as shown in the table:
Painting technique: adding 1-3 component and stir, the mixed liquor being slow added into 4-6 component stirs, then limit
Stirring limit is slowly added into 7-8 component successively, adds 9-10 component, is stirred for more than 15 minutes, prepare true stone after stirring 15 minutes
Paint.
The performance of true mineral varnish prepared by the present embodiment has met or exceeded industry standard JG-T24-2000 (synthetic resin breast
Liquid sand textured building coating), its performance test is as shown in the table:
Embodiment 11
The formula of true mineral varnish, as shown in the table:
Painting technique is with embodiment 10.
Embodiment 12
The formula of true mineral varnish, as shown in the table:
Painting technique is with embodiment 10.
The general description of the above-mentioned invention to relating in the application and the description to its detailed description of the invention should not be understood
For being the restriction to this inventive technique forecast scheme configuration.Those skilled in the art, according to disclosure herein, can not disobey
On the premise of invention element involved by the back of the body, general describe or/and detailed description of the invention (including embodiment) to above-mentioned
In public technology feature carry out increasing, reduce or combining, formed and belong to other technical scheme of described invention.
Claims (8)
1. one kind acrylic resin modified, it is characterized in that being made up of the raw material of following weight portion:
2. an acrylic resin modified preparation method as claimed in claim 1, it is characterised in that: first by butyl acetate
It is placed in reaction vessel with propylene glycol methyl ether acetate and is heated to backflow, then remaining ingredient 4h is dropped in reaction vessel,
Dripping off and maintain the reflux at least 4h, sampling detects qualified rear cooling discharge.
3. the dye sand utilizing acrylic resin modified preparation as claimed in claim 1 is painted, and it is characterized in that by weighing as follows
The raw material of amount part is made:
4. the preparation method that a dye sand as claimed in claim 3 is painted, it is characterised in that: by all raw material mix homogeneously,
Being ground to fineness is below 15 μm.
5. utilize dye sand as claimed in claim 3 to paint an artificial color sand for preparation, it is characterized in that by following weight portion
Raw material is made:
6. the preparation method of the most artificial color sand, it is characterised in that: all raw materials are mixed to face
Color is uniform, dries or room temperature is placed.
7. the true mineral varnish utilizing the most artificial color sand to prepare, is characterized in that by the raw material of following weight portion
Make:
8. the preparation method of a true mineral varnish as claimed in claim 7, it is characterised in that: by true mineral varnish silicone acrylic emulsion, 2.5%
The pre-dispersed slurry of H4BR cellulose and the 2% pre-dispersed slurry of HHBR cellulose stir, and are slow added into antibacterial, propylene glycol
And pure water, it is slow added into 40～80 mesh manually color sand and 80～120 mesh manually color sand after stirring, stirs
After add coalescents and defoamer, be uniformly mixing to obtain true mineral varnish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410325649.0A CN104072662B (en) | 2014-07-07 | 2014-07-07 | The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410325649.0A CN104072662B (en) | 2014-07-07 | 2014-07-07 | The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial |
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| CN104072662B true CN104072662B (en) | 2016-09-14 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104310832A (en) * | 2014-10-10 | 2015-01-28 | 浙江厦光涂料有限公司 | Nature-imitated high-temperature colored sands and production process thereof |
| CN104844036B (en) * | 2015-04-30 | 2017-03-01 | 山西亮龙涂料有限公司 | One kind manually color sand and preparation method thereof |
| CN106223155B (en) * | 2016-07-22 | 2019-04-12 | 李来宾 | A kind of color aggregate road surface coiled material and moulding process |
| CN106904868A (en) * | 2017-03-24 | 2017-06-30 | 重庆市环卫集团有限公司 | A kind of detection method of color sand not easy to fade and its fading extent |
| CN111019281B (en) * | 2019-12-19 | 2021-12-10 | 上海贝塔建筑科技有限公司 | Acrylate epoxy resin hybrid emulsion, preparation method and application thereof, and artificial colored sand using acrylate epoxy resin hybrid emulsion |
| CN113563747A (en) * | 2021-07-20 | 2021-10-29 | 安徽朗凯奇防水科技股份有限公司 | Waterproof real stone paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113192A (en) * | 2007-07-07 | 2008-01-30 | 中国化工建设总公司常州涂料化工研究院 | Cross-linking type fluorine-containing acrylic resin |
| CN102190988A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Waterborne adhesive for metal ceramic color sand decorative coating and preparation method thereof |
| CN102464460A (en) * | 2010-11-16 | 2012-05-23 | 王明军 | Colored sand and preparation method thereof |
| CN103304185A (en) * | 2013-06-19 | 2013-09-18 | 山东圣泉化工股份有限公司 | Real mineral varnish |
| CN103772597A (en) * | 2014-01-26 | 2014-05-07 | 浙江环达漆业集团有限公司 | Preparation method of organosilicone modified hydroxy acrylic resin aqueous dispersion |
-
2014
- 2014-07-07 CN CN201410325649.0A patent/CN104072662B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113192A (en) * | 2007-07-07 | 2008-01-30 | 中国化工建设总公司常州涂料化工研究院 | Cross-linking type fluorine-containing acrylic resin |
| CN102190988A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Waterborne adhesive for metal ceramic color sand decorative coating and preparation method thereof |
| CN102464460A (en) * | 2010-11-16 | 2012-05-23 | 王明军 | Colored sand and preparation method thereof |
| CN103304185A (en) * | 2013-06-19 | 2013-09-18 | 山东圣泉化工股份有限公司 | Real mineral varnish |
| CN103772597A (en) * | 2014-01-26 | 2014-05-07 | 浙江环达漆业集团有限公司 | Preparation method of organosilicone modified hydroxy acrylic resin aqueous dispersion |
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