CN111440070B - 一种碳酸二紫苏酯香料 - Google Patents

一种碳酸二紫苏酯香料 Download PDF

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CN111440070B
CN111440070B CN201910038741.1A CN201910038741A CN111440070B CN 111440070 B CN111440070 B CN 111440070B CN 201910038741 A CN201910038741 A CN 201910038741A CN 111440070 B CN111440070 B CN 111440070B
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perilla
fragrance
dicarbonate
spice
products
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CN111440070A (zh
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杨绍祥
田红玉
刘永国
梁森
孙宝国
王皓
戴慧康
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Shenzhen Chengze Information Technology Co ltd
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Beijing Technology and Business University
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/96—Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
    • C11B9/0034—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Fats And Perfumes (AREA)
  • Cosmetics (AREA)

Abstract

本发明公开了一种化合物碳酸二紫苏酯，具体化学结构式如下所示：

Description

一种碳酸二紫苏酯香料
技术领域
本发明涉及一种芳香化合物，它适于在化妆品、香精、洗涤用品等产品中产生香气。
背景技术
在香料工业中越来越要求提供一种新的化合物，使调香师能够以其作为香原料，为香精、化妆品、洗涤用品制造新香味。
碳酸酯类化合物是一类重要的香料，现已广泛用于各种食品饮料等食用香精的配方中，到目前为止已有三种碳酸酯类香料被批准为可食用香料，分别为1-薄荷醇乙二醇碳酸酯(FEMA号为3805)，无色液体，具有薄荷样的凉味；1-薄荷醇丙二醇碳酸酯(FEMA号为3806)，无色液体具有薄荷样的凉味；d1-薄荷脑(+/-)-1，2-丙二醇碳酸酯(FEMA号为3992)，无色清凉液体，具有薄荷香气，主要用于焙烤食品，饮料、奶酪、口香糖、调味料等食品的加香。
尽管部分碳酸酯类香料已经被广泛应用，仍需提供其他新的香料化合物，使香料商为各种应用制造新的香味，满足人们对新香味日益增长的需求。
发明内容
本发明目的是提供一种化合物，它适于在化妆品、香精、洗涤用品等产品中产生香气。
更具体的是，本发明涉及化合物碳酸二紫苏酯，它通过以下通式表示：
Figure BSA0000177717430000011
具体实施方式
实施例1.碳酸二紫苏酯的制备
合成路线如下式所示：
Figure BSA0000177717430000012
将1.52g(10mmol)紫苏醇，4.86g(30mmol)羰基二咪唑，20mL四氢呋喃加入到100mL三口烧瓶中，加热回流3小时，过滤，依次用二氯甲烷、水洗涤，无水硫酸镁干燥，旋蒸，得白色透明粘稠物，加入到50mL三口烧瓶中，再加入1.82g(12mmol)紫苏醇、20mL N，N-二甲基甲酰胺，90℃搅拌6小时。到入到含50mL二氯甲烷和50mL水分液漏斗中，分液，有机相一次用水、饱和氯化钠溶液洗涤，旋蒸，柱层析分离纯化，得白色透明液体1.19g，产率36％。
产物经过核磁氢谱及核磁碳谱表征。
1H NMR(300MHz，CDCl3)δ：5.79(s，2H)，4.70(d，J＝5.6Hz，4H)，4.50(s，4H)，2.11(dd，J＝7.3，3.3Hz，8H)，1.82(d，J＝2.2Hz，4H)，1.72(s，6H)，1.47(s，2H).
13C NMR(75MHz，CDCl3)δ：155.21，149.38，132.12，126.53，108.76，71.80，40.66，30.38，27.18，26.20，20.67.
实施例2.香气评价
取0.01g碳酸二紫苏酯样品配制为10％丙二醇溶液，用评香条沾取少量溶液，在无其他气味干扰的情况下嗅闻评香条上的气味，进行香气评价。
碳酸二紫苏酯样品具有清甜的奶香、木香、草香、水果香。

Claims (1)

1.一种芳香化合物碳酸二紫苏酯，具体化学结构式如下所示：
Figure FSA0000177717420000011
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