CN1112737A - 具二氧化锰电极的高容量可再充电电池 - Google Patents
具二氧化锰电极的高容量可再充电电池 Download PDFInfo
- Publication number
 - CN1112737A CN1112737A CN95103067A CN95103067A CN1112737A CN 1112737 A CN1112737 A CN 1112737A CN 95103067 A CN95103067 A CN 95103067A CN 95103067 A CN95103067 A CN 95103067A CN 1112737 A CN1112737 A CN 1112737A
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 - Prior art keywords
 - battery
 - zinc
 - manganese dioxide
 - electrode
 - electrochemical cell
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 - Primary Cells (AREA)
 
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US08/207,629 | 1994-03-09 | ||
| US08/207,629 US5424145A (en) | 1992-03-18 | 1994-03-09 | High capacity rechargeable cell having manganese dioxide electrode | 
Publications (1)
| Publication Number | Publication Date | 
|---|---|
| CN1112737A true CN1112737A (zh) | 1995-11-29 | 
Family
ID=22771347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| CN95103067A Pending CN1112737A (zh) | 1994-03-09 | 1995-03-09 | 具二氧化锰电极的高容量可再充电电池 | 
Country Status (7)
Cited By (14)
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| CN1322609C (zh) * | 1997-12-31 | 2007-06-20 | 杜拉塞尔公司 | 多孔碱性锌/氧化锰电池 | 
| CN101465440A (zh) * | 2008-11-10 | 2009-06-24 | 胡文斌 | 物理可再充电碱性锌锰蓄电池 | 
| CN101083337B (zh) * | 2006-07-26 | 2011-04-27 | 松下电器产业株式会社 | 电化学装置 | 
| US8039146B2 (en) | 2006-07-26 | 2011-10-18 | Panasonic Corporation | Electrochemical device comprising alkaline electroylte | 
| CN103748726A (zh) * | 2011-07-19 | 2014-04-23 | 亚奎尼能源公司 | 由阳极受限的电化学电池构成的高电压蓄电池 | 
| CN106025284A (zh) * | 2016-05-31 | 2016-10-12 | 卢财鑫 | 一种可充电的碱性锌锰电池 | 
| CN106415980A (zh) * | 2014-04-09 | 2017-02-15 | 丰田自动车株式会社 | 安装有行驶电动机的车辆 | 
| CN106450513A (zh) * | 2016-11-02 | 2017-02-22 | 董亚婵 | 一种可充电的湿电池 | 
| CN106571461A (zh) * | 2016-09-29 | 2017-04-19 | 中山大学 | 一种长寿命、可充放的Zn‑MnO2电池及其应用 | 
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| CN109494382A (zh) * | 2018-12-10 | 2019-03-19 | 杭州长命电池有限公司 | 一种无汞高功率锌锰电池及其电芯粉、锌筒及无汞浆层纸 | 
| CN111542951A (zh) * | 2017-11-17 | 2020-08-14 | 赛伦能源公司 | 具有锌金属负电极和温和水性电解质的二次电化学电池及其方法 | 
| CN112490458A (zh) * | 2020-12-01 | 2021-03-12 | 中山市华舜科技有限责任公司 | 一种用于锌锰电池的锌盐混合电解液和锰正极材料的制备方法 | 
| CN114709409A (zh) * | 2022-04-01 | 2022-07-05 | 三峡大学 | 水系锌离子电池锌汞合金负极的制备方法与应用 | 
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| CA2111757C (en) * | 1993-12-17 | 2004-03-16 | Lijun Bai | Rechargeable manganese dioxide cathode | 
| US5626988A (en) * | 1994-05-06 | 1997-05-06 | Battery Technologies Inc. | Sealed rechargeable cells containing mercury-free zinc anodes, and a method of manufacture | 
| US5639578A (en) * | 1995-06-07 | 1997-06-17 | Eveready Battery Company | Current collectors for alkaline cells | 
| US5599644A (en) * | 1995-06-07 | 1997-02-04 | Eveready Battery Company, Inc. | Cathodes for electrochemical cells having additives | 
| EP0801432B1 (en) * | 1996-04-12 | 2000-01-26 | Rayovac Corporation | Rechargeable alkaline electrochemical cell | 
| DE19615724A1 (de) * | 1996-04-20 | 1997-10-23 | Varta Batterie | Galvanische Zelle | 
| DE19617512A1 (de) * | 1996-05-02 | 1997-11-13 | Univ Dresden Tech | Verfahren zur Herstellung von modifiziertem Magandioxid für wiederaufladbare alkalische Batterien sowie ein wiederaufladbares galvanisches Element | 
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| US6203943B1 (en) * | 1998-11-13 | 2001-03-20 | Eveready Battery Company, Inc. | Electrochemical cell having electrode additives | 
| ATE273567T1 (de) * | 1998-12-15 | 2004-08-15 | Duracell Inc | Verschluss einer elektrochemischen zelle | 
| CN1236514C (zh) | 1999-02-26 | 2006-01-11 | 吉莱特公司 | 高性能碱性电池 | 
| US6344295B1 (en) | 1999-04-30 | 2002-02-05 | Noranda, Inc. | Zinc alloy powder for use in rechargeable cells | 
| US6489060B1 (en) | 1999-05-26 | 2002-12-03 | E-One Moli Energy (Canada) Limited | Rechargeable spinel lithium batteries with greatly improved elevated temperature cycle life | 
| NZ510554A (en) * | 2001-03-15 | 2003-08-29 | Univ Massey | Rechargeable zinc electrode comprising a zinc salt and a derivative of a fatty acid or alkyl sulfonic acid | 
| EP1371103A2 (en) * | 2001-03-15 | 2003-12-17 | Jeffrey Phillips | Methods for production of zinc oxide electrodes for alkaline batteries | 
| US7005213B2 (en) * | 2001-05-24 | 2006-02-28 | Rayovac Corporation | Ionically conductive additive for zinc-based anode in alkaline electrochemical cells | 
| US7008723B2 (en) * | 2001-08-21 | 2006-03-07 | Ecosol Solar Technologies Inc. | Method of manufacture of an anode composition for use in a rechargeable electrochemical cell | 
| US20040229116A1 (en) * | 2002-05-24 | 2004-11-18 | Malinski James Andrew | Perforated separator for an electrochemical cell | 
| JP2007524190A (ja) * | 2003-06-17 | 2007-08-23 | ザ ジレット カンパニー | 電池用アノード | 
| CA2486488A1 (en) * | 2004-01-22 | 2005-07-22 | Pure Energy Visions Inc. | Rechargeable alkaline manganese cell with cathode consistency compensation | 
| JP2006302597A (ja) * | 2005-04-19 | 2006-11-02 | Sii Micro Parts Ltd | ボタン形アルカリ電池 | 
| US7754386B2 (en) * | 2005-11-28 | 2010-07-13 | Pure Energy Visions Corporation | Rechargeable alkaline manganese cell having reduced capacity fade and improved cycle life | 
| US7563537B2 (en) * | 2005-11-30 | 2009-07-21 | Rovcal, Inc. | Ionically conductive clay additive for use in electrochemical cells | 
| US8586244B2 (en) * | 2007-04-02 | 2013-11-19 | Eveready Battery Co., Inc. | Alkaline electrochemical cell having a negative electrode with solid zinc oxide and a surfactant | 
| US8883345B2 (en) | 2007-12-28 | 2014-11-11 | Encell Technology Llc | Prismatic battery | 
| US8137830B2 (en) * | 2011-07-19 | 2012-03-20 | Aquion Energy, Inc. | High voltage battery composed of anode limited electrochemical cells | 
| AU2013222442B2 (en) | 2012-02-21 | 2016-12-01 | Research Foundation Of The City University Of New York | Alkaline battery operational methodology | 
| US8945756B2 (en) | 2012-12-12 | 2015-02-03 | Aquion Energy Inc. | Composite anode structure for aqueous electrolyte energy storage and device containing same | 
| US9406932B2 (en) * | 2014-01-15 | 2016-08-02 | Ford Global Technologies, Llc | Composition for reducing moisture in a battery electrolyte | 
| CN104112861B (zh) * | 2014-08-05 | 2016-11-16 | 河南大学 | 通过锂二次电池正极活性材料添加剂实现表面修饰的方法 | 
| WO2017160691A1 (en) * | 2016-03-14 | 2017-09-21 | Urban Electric Power Inc | Secondary cell with high recharging efficiency and long term stability | 
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Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| NL113624C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1957-10-09 | |||
| BE571910A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1957-10-09 | |||
| US2935547A (en) * | 1958-03-12 | 1960-05-03 | Union Carbide Corp | Air-depolarized deferred action cell | 
| US3113050A (en) * | 1960-09-12 | 1963-12-03 | Union Carbide Corp | Cathodes for primary and rechargeable cells | 
| US3530496A (en) * | 1967-06-26 | 1970-09-22 | Matsushita Electric Industrial Co Ltd | Rechargeable alkaline manganese cell | 
| JPS4841866B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-02-02 | 1973-12-08 | ||
| US3856576A (en) * | 1973-06-25 | 1974-12-24 | Kerr Mc Gee Chem Corp | Process of treating electrolytic manganese dioxide | 
| US3884721A (en) * | 1974-03-18 | 1975-05-20 | Union Carbide Corp | Anode for galvanic cells | 
| US4091178A (en) * | 1977-09-01 | 1978-05-23 | Union Carbide Corporation | Rechargeable alkaline MnO2 -zinc cell | 
| US4312928A (en) * | 1978-05-04 | 1982-01-26 | U.S. Philips Corporation | Rechargeable electrochemical cell | 
| US4275127A (en) * | 1979-06-19 | 1981-06-23 | Trw Inc. | Sealed nickel-cadmium battery with self-regulating precharge adjustment capability | 
| US4451543A (en) * | 1983-09-29 | 1984-05-29 | Ford Motor Company | Rechargeable zinc/manganese dioxide cell | 
| DE3725629A1 (de) * | 1987-08-03 | 1989-02-16 | Varta Batterie | Galvanisches element | 
| JPH01200557A (ja) * | 1987-10-13 | 1989-08-11 | Bridgestone Corp | 非水電解質電池 | 
| CA1307818C (en) * | 1987-10-27 | 1992-09-22 | Karl Kordesch | Catalytic recombination of corrosion evolved hydrogen in alkaline cells | 
| US5043234A (en) * | 1987-10-27 | 1991-08-27 | Battery Technologies Inc. | Recombination of evolved oxygen in galvanic cells using transfer anode material | 
| US5162169A (en) * | 1987-10-27 | 1992-11-10 | Battery Technologies Inc. | Catalytic recombination of hydrogen in alkaline cells | 
| CA1295364C (en) * | 1988-07-08 | 1992-02-04 | Battery Technologies Inc. | Rechargeable alkaline manganese cells with zinc anodes | 
| HU201438B (en) * | 1988-08-31 | 1990-10-28 | Karl Kordesh | Rechargeable zinc-restricted alkali manganese dioxide-zinc cell | 
| US4857424A (en) * | 1988-10-11 | 1989-08-15 | Rayovac Corporation | Zinc alkaline electrochemical cells with reduced mercury anodes | 
| US5034291A (en) * | 1989-08-16 | 1991-07-23 | Rayovac Corporation | Aluminum compound additives to reduce zinc corrosion in anodes of electrochemical cells | 
| US5300371A (en) * | 1990-03-23 | 1994-04-05 | Battery Technologies Inc. | Manganese dioxide positive electrode for rechargeable cells, and cells containing the same | 
| DE4014945A1 (de) * | 1990-05-10 | 1991-11-14 | Reten Electronic Gmbh & Co | Aufladbare zink-mangan-batterie | 
| CA2037744A1 (en) * | 1991-03-07 | 1992-09-08 | Klaus Tomantschger | Rechargeable alkaline manganese cell having improved capacity and improved energy density | 
| HU215866B (hu) * | 1991-12-19 | 1999-03-29 | Battery Technologies Inc. | Katódszerkezet alkáli mangán-dioxid-cink cellákhoz megnövelt kapacitással | 
| AU1333792A (en) * | 1992-03-09 | 1993-10-05 | Battery Technologies Inc. | High capacity rechargeable cell having manganese dioxide electrode | 
| US7893793B2 (en) | 2006-08-25 | 2011-02-22 | Panasonic Corporation | Film bulk acoustic wave resonator and method for manufacturing the same | 
- 
        1994
        
- 1994-03-09 US US08/207,629 patent/US5424145A/en not_active Expired - Lifetime
 
 - 
        1995
        
- 1995-03-08 WO PCT/CA1995/000128 patent/WO1995024742A1/en not_active Application Discontinuation
 - 1995-03-08 MA MA23799A patent/MA23471A1/fr unknown
 - 1995-03-08 AU AU17525/95A patent/AU1752595A/en not_active Abandoned
 - 1995-03-09 CN CN95103067A patent/CN1112737A/zh active Pending
 - 1995-03-11 TW TW084102380A patent/TW281810B/zh active
 
 - 
        1996
        
- 1996-10-08 LT LT96-143A patent/LT4233B/lt not_active IP Right Cessation
 
 
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| CN1322609C (zh) * | 1997-12-31 | 2007-06-20 | 杜拉塞尔公司 | 多孔碱性锌/氧化锰电池 | 
| CN102163700B (zh) * | 2006-07-26 | 2013-11-06 | 松下电器产业株式会社 | 电化学装置 | 
| CN101083337B (zh) * | 2006-07-26 | 2011-04-27 | 松下电器产业株式会社 | 电化学装置 | 
| CN102163700A (zh) * | 2006-07-26 | 2011-08-24 | 松下电器产业株式会社 | 电化学装置 | 
| US8039146B2 (en) | 2006-07-26 | 2011-10-18 | Panasonic Corporation | Electrochemical device comprising alkaline electroylte | 
| CN101465440B (zh) * | 2008-11-10 | 2013-09-25 | 胡文斌 | 物理可再充电碱性锌锰蓄电池 | 
| CN101465440A (zh) * | 2008-11-10 | 2009-06-24 | 胡文斌 | 物理可再充电碱性锌锰蓄电池 | 
| US10026562B2 (en) | 2011-07-19 | 2018-07-17 | Aquion Energy Inc. | High voltage battery composed of anode limited electrochemical cells | 
| CN103748726A (zh) * | 2011-07-19 | 2014-04-23 | 亚奎尼能源公司 | 由阳极受限的电化学电池构成的高电压蓄电池 | 
| US8945751B2 (en) | 2011-07-19 | 2015-02-03 | Aquion Energy, Inc. | High voltage battery composed of anode limited electrochemical cells | 
| CN106415980A (zh) * | 2014-04-09 | 2017-02-15 | 丰田自动车株式会社 | 安装有行驶电动机的车辆 | 
| CN106415980B (zh) * | 2014-04-09 | 2018-12-11 | 丰田自动车株式会社 | 安装有行驶电动机的车辆 | 
| CN106025284A (zh) * | 2016-05-31 | 2016-10-12 | 卢财鑫 | 一种可充电的碱性锌锰电池 | 
| CN106571461A (zh) * | 2016-09-29 | 2017-04-19 | 中山大学 | 一种长寿命、可充放的Zn‑MnO2电池及其应用 | 
| CN106571461B (zh) * | 2016-09-29 | 2019-01-25 | 中山大学 | 一种长寿命、可充放的Zn-MnO2电池及其应用 | 
| CN106450513A (zh) * | 2016-11-02 | 2017-02-22 | 董亚婵 | 一种可充电的湿电池 | 
| CN111542951A (zh) * | 2017-11-17 | 2020-08-14 | 赛伦能源公司 | 具有锌金属负电极和温和水性电解质的二次电化学电池及其方法 | 
| CN109088048A (zh) * | 2018-08-17 | 2018-12-25 | 河南英能新材料科技有限公司 | 一种改性碳锌电池电极的制备方法 | 
| CN109088048B (zh) * | 2018-08-17 | 2021-11-16 | 河南英能新材料科技有限公司 | 一种改性碳锌电池电极的制备方法 | 
| CN109494382A (zh) * | 2018-12-10 | 2019-03-19 | 杭州长命电池有限公司 | 一种无汞高功率锌锰电池及其电芯粉、锌筒及无汞浆层纸 | 
| CN109494382B (zh) * | 2018-12-10 | 2020-11-27 | 杭州长命电池有限公司 | 一种无汞高功率锌锰电池及其电芯粉、锌筒及无汞浆层纸 | 
| CN112490458A (zh) * | 2020-12-01 | 2021-03-12 | 中山市华舜科技有限责任公司 | 一种用于锌锰电池的锌盐混合电解液和锰正极材料的制备方法 | 
| CN114709409A (zh) * | 2022-04-01 | 2022-07-05 | 三峡大学 | 水系锌离子电池锌汞合金负极的制备方法与应用 | 
| CN114709409B (zh) * | 2022-04-01 | 2024-07-05 | 三峡大学 | 水系锌离子电池锌汞合金负极的制备方法与应用 | 
Also Published As
| Publication number | Publication date | 
|---|---|
| LT96143A (en) | 1997-06-25 | 
| LT4233B (en) | 1997-10-27 | 
| US5424145A (en) | 1995-06-13 | 
| MA23471A1 (fr) | 1995-10-01 | 
| TW281810B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1996-07-21 | 
| AU1752595A (en) | 1995-09-25 | 
| WO1995024742A1 (en) | 1995-09-14 | 
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