CN111149460B - A method for improving desertified land by combining biochemical materials with commercial crops - Google Patents
A method for improving desertified land by combining biochemical materials with commercial crops Download PDFInfo
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- CN111149460B CN111149460B CN202010049357.4A CN202010049357A CN111149460B CN 111149460 B CN111149460 B CN 111149460B CN 202010049357 A CN202010049357 A CN 202010049357A CN 111149460 B CN111149460 B CN 111149460B
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
- A01B79/00—Methods for working soil
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
- A01B79/00—Methods for working soil
- A01B79/02—Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Soil Sciences (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
Description
技术领域technical field
本发明涉及一种改良荒漠化土地的方法,尤其涉及一种利用生物化学材料与经济作物种植相结合改良荒漠化土地的方法,属于水土保持领域和农业种植领域。The invention relates to a method for improving desertified land, in particular to a method for improving desertified land by combining biochemical materials with commercial crop planting, belonging to the fields of soil and water conservation and agricultural planting.
背景技术Background technique
荒漠化的定义由“荒漠化公约”(UNCCD) 提出:在脆弱环境(干旱、半干旱和亚湿润干旱地区)主要因过度人类活动和气候变化引起的土地退化。土壤侵蚀退化的诱因是流体(例如风或水)拖曳与土壤颗粒间抗剪切力之间的相互作用。而水侵蚀引起的水土流失是全球土壤侵蚀的最大来源。荒漠化是全球最为严峻的环境和社会经济问题,主要威胁着农业和经济的可持续发展,其中,沙漠化是荒漠化的主要类型,因此土地荒漠化的防治是重中之重。在荒漠化防治过程中,逐渐形成了生物、工程和化学三种主要防治方式。然而,采用工程方法在成本、时效性和施工等方面具有诸多局限,而使用高分子材料的化学方式由于具有施工简便、成本低、见效快等优点。因此,将化学-生物手段相结合,不仅可迅速改良荒漠化土地,还可为植物生长创造良好的水土条件,对于沙化土地的治理、农作物种植、生态环境改善有及其重大而深远的现实意义。Desertification is defined by the "Convention on Desertification" (UNCCD): Land degradation in fragile environments (arid, semi-arid and dry sub-humid areas) mainly due to excessive human activities and climate change. The cause of soil erosion degradation is the interaction between the drag of fluids (eg wind or water) and the shear resistance between soil particles. And soil erosion caused by water erosion is the largest source of global soil erosion. Desertification is the most serious environmental and socio-economic problem in the world, which mainly threatens the sustainable development of agriculture and economy. Among them, desertification is the main type of desertification, so the prevention and control of land desertification is the top priority. In the process of desertification control, three main control methods of biology, engineering and chemistry have gradually formed. However, the use of engineering methods has many limitations in terms of cost, timeliness and construction, while the chemical method using polymer materials has the advantages of simple construction, low cost, and quick results. Therefore, the combination of chemical and biological means can not only rapidly improve desertified land, but also create good soil and water conditions for plant growth.
发明内容SUMMARY OF THE INVENTION
本发明的目的是提供一种利用生物化学材料与经济作物种植相结合改良荒漠化土地的方法,可以有效防止水肥渗漏,提高土地水肥利用率,土壤有机质、微生物种类和数量,从而提高土壤生态功能。The purpose of the present invention is to provide a method for improving desertified land by combining biochemical materials with commercial crop planting, which can effectively prevent water and fertilizer leakage, improve land water and fertilizer utilization, soil organic matter, and microbial species and quantity, thereby improving soil ecological function. .
(1)生物化学土地改良材料的制备(1) Preparation of biochemical land improvement materials
将混合土、改性纤维素、植物秸秆粉末、腐熟的动物粪便混合均匀,即得荒漠化土地改良材料。Mix the mixed soil, modified cellulose, plant straw powder, and decomposed animal manure evenly to obtain the desertification land improvement material.
改性纤维素的制备,是在浓硫酸催化作用下,纤维素与含多亲水基团化合物在70~140℃,反应2.5~12时间而得;其中,纤维素为羧甲基纤维素钠、羟甲基纤维素钠、羟乙基纤维素、羟丙基纤维素、羟丙基甲基纤维素、甲基纤维素和乙基纤维素中的至少一种;含多亲水基团化合物为多元羟基化合物(如乙二醇、丙三醇、聚乙二醇)或多元羧基化合物(草酸、柠檬酸、苹果酸、腐殖酸、氨基酸),且纤维素与含多亲水基团化合物的摩尔比在1:1~1:8的范围内;浓硫酸的用量为纤维素质量的2~10%。The preparation of modified cellulose is obtained by reacting cellulose and compounds containing multiple hydrophilic groups at 70-140 ° C for 2.5-12 times under the catalysis of concentrated sulfuric acid; wherein, the cellulose is sodium carboxymethyl cellulose , at least one of sodium hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, methyl cellulose and ethyl cellulose; compounds containing multiple hydrophilic groups It is a polyhydroxy compound (such as ethylene glycol, glycerol, polyethylene glycol) or a polycarboxy compound (oxalic acid, citric acid, malic acid, humic acid, amino acid), and cellulose and compounds containing multiple hydrophilic groups The molar ratio of cellulose is in the range of 1:1~1:8; the amount of concentrated sulfuric acid is 2~10% of the mass of cellulose.
纤维素和多元羟基化合物的反应方程式如下:The reaction equation of cellulose and polyhydroxy compound is as follows:
纤维素和多元羧基化合物的反应方程式如下:The reaction equation between cellulose and polycarboxylate is as follows:
纤维素作为一种天然高分子材料,和含多亲水基团的化合物反应,生成的改性纤维素具有很强的粘聚作用,不仅能防止水土流失、较好的抑制土壤水分蒸发性能,而且具有保水、保肥、增产等效用。改性纤维素用量为混合土质量的0.05~2 wt%。 另外,纤维素具有来源广泛、可再生、生物可降解、无毒无害等优点,避免了对土壤的二次污染。As a natural polymer material, cellulose reacts with compounds containing multiple hydrophilic groups, and the resulting modified cellulose has a strong cohesive effect, which can not only prevent soil erosion, but also better inhibit soil moisture evaporation. And it has the functions of water retention, fertilizer retention, and yield increase. The dosage of modified cellulose was 0.05-2 wt% of the mass of the mixed soil. In addition, cellulose has the advantages of a wide range of sources, renewable, biodegradable, non-toxic and harmless, which avoids secondary pollution to the soil.
混合土为黏土(红土、蒙脱土、高岭土、凹凸棒黏土)和黄土的混合物,且黏土与黄土的质量比1:1~1:5。混合土的作用是为沙地增加各种植物生长所需的微量元素及矿物质。The mixed soil is a mixture of clay (latterite, montmorillonite, kaolin, attapulgite clay) and loess, and the mass ratio of clay to loess is 1:1~1:5. The role of the mixed soil is to increase the trace elements and minerals required for the growth of various plants in the sandy land.
植物秸秆粉末的主要作用是引进微生物并促进微生物的繁殖。植物秸秆为小麦秸秆、玉米秸秆、棉花秸秆、高粱秸秆中的一种,植物秸秆粉末用量为混合土质量的3~15 wt%。The main function of plant straw powder is to introduce microorganisms and promote the reproduction of microorganisms. The plant straw is one of wheat straw, corn straw, cotton straw and sorghum straw, and the amount of plant straw powder is 3-15 wt% of the mass of the mixed soil.
动物粪便在60~70℃的高温厌氧环境下腐熟后分解快,有利于植物吸收,同时有害虫卵、杂草种子大部分会死亡。腐熟的动物粪便的主要功效是增加土壤有机质及N、P元素的含量。腐熟的动物粪便用量为混合土质量的5~25 wt%。Animal manure decomposes quickly after being decomposed under the high temperature anaerobic environment of 60~70℃, which is conducive to the absorption of plants. At the same time, most of the eggs of pests and weed seeds will die. The main effect of decomposed animal manure is to increase the content of soil organic matter and N and P elements. The amount of decomposed animal manure was 5-25 wt% of the mass of the mixed soil.
混合土、植物秸秆粉末和腐熟的动物粪便不但可降低沙地改良材料的生产成本,而且可以为植物生长提供必需的营养物质。Mixed soil, plant straw powder and decomposed animal manure can not only reduce the production cost of sand improvement materials, but also provide necessary nutrients for plant growth.
(2)经济作物的种植(2) Planting of cash crops
先在荒漠化土地表面撒入肥料,再将上述制备的荒漠化土地改良材料铺在地面,用旋耕机旋耕后在播种经济作物的种子,灌溉,使土壤保持湿润以保证种子发芽、出苗、生长,并根据不同植物种类在不同时期使用黄腐酸钾。黄腐酸钾具有降低作物蒸腾量,促进根系发育,提高作物抗旱、抗病能力等优点。First sprinkle fertilizer on the surface of the desertified land, then spread the above-prepared desertification land improvement materials on the ground, and then use the rotary tiller to sow the seeds of commercial crops, irrigate, and keep the soil moist to ensure the seeds germinate, emerge and grow. , and use potassium humate at different times according to different plant species. Potassium humate has the advantages of reducing crop transpiration, promoting root development, and improving crop drought and disease resistance.
经济作物可以为豆科固氮植物、非豆科固氮植物、壳类谷物和蔬菜作物中的至少一种。作物的播种可以是撒播,栽种,也可以按40~60 cm的距离条播。种子发芽、出苗后,根据具体天气状况及生长季节需要,酌情浇水30~200 mm。The commercial crops may be at least one of legume nitrogen-fixing plants, non-legume nitrogen-fixing plants, shell grains and vegetable crops. The sowing of crops can be broadcast, planted, or drilled at a distance of 40-60 cm. After the seeds germinate and emerge, according to the specific weather conditions and the needs of the growing season, water 30-200 mm as appropriate.
本发明制备的荒漠化土地改良材料实施在甘肃兰州、酒泉、张掖、敦煌,新疆哈密等地后,可以有效防止水肥渗漏,持水持肥效果显著,浇水施肥次数和用量明显减少,水肥利用率提高25~52%,且土壤有机质、微生物种类和数量显著增加,土壤生态功能明显提高,同时,作物蒸腾量下降、根系变长、抗病能力提高,植物得到了更好的生长环境。在改良荒漠化土地的同时带动当地经济发展。After the desertification land improvement material prepared by the invention is implemented in Lanzhou, Jiuquan, Zhangye, Dunhuang, Hami, Xinjiang and other places in Gansu, the leakage of water and fertilizer can be effectively prevented, the effect of holding water and fertilizer is remarkable, the frequency and dosage of watering and fertilizing are obviously reduced, and the utilization of water and fertilizer The soil organic matter and microbial species and quantity increased significantly, and the soil ecological function was significantly improved. At the same time, the crop transpiration decreased, the root system became longer, and the disease resistance was improved, and the plants got a better growth environment. While improving desertified land, it drives local economic development.
具体实施方式Detailed ways
下面通过具体实施例对本发明的改良荒漠化土地的方法作进一步说明。The method for improving desertified land of the present invention will be further described below through specific examples.
实施例1、改性纤维素和豆科固氮植物对荒漠化土地的改良Example 1. Improvement of desertified land by modified cellulose and leguminous nitrogen-fixing plants
(1)在浓硫酸催化下,羧甲基纤维素钠和丙三醇以1:3的摩尔比在140℃下反应12h,得到羟基化羧甲基纤维素钠;再将羟基化羧甲基纤维素钠(混合土的0.5wt%)与混合土(红土与黄土质量比为1:2),小麦秸秆粉末(混合土的5 wt%),在70 ℃的高温厌氧环境下腐熟的羊粪(混合土10 wt%)混合并搅拌混匀,即得荒漠化土地改良材料;(1) Under the catalysis of concentrated sulfuric acid, sodium carboxymethyl cellulose and glycerol were reacted at 140 °C for 12 h at a molar ratio of 1:3 to obtain hydroxylated sodium carboxymethyl cellulose; Cellulose sodium (0.5 wt% of the mixed soil) and mixed soil (the mass ratio of laterite to loess is 1:2), wheat straw powder (5 wt% of the mixed soil), sheep decomposed under the high temperature anaerobic environment of 70 ℃ The manure (mixed soil 10 wt%) is mixed and mixed to obtain the desertification land improvement material;
(2)在需要改良的土地表面撒入磷酸二胺12kg/亩,再将荒漠化土地改良材料铺在地面,用旋耕机旋耕。在旋耕后的地面撒播豆科植物的种子,灌溉,使土壤保持湿润以保证种子发芽、出苗、生长,在果实生长期喷洒黄腐酸钾和多菌灵的混合液,以防叶斑病的发生。种子发芽、出苗后,在初花期刈割并翻埋,并根据具体天气状况及生长季节需要酌情浇水。(2) Sprinkle 12kg/mu of phosphoric acid diamine on the surface of the land to be improved, and then spread the desertification land improvement materials on the ground, and use a rotary tiller. Sow the seeds of leguminous plants on the ground after rotary tillage, irrigate to keep the soil moist to ensure the germination, emergence and growth of the seeds, and spray the mixture of potassium fulvic acid and carbendazim during the fruit growth period to prevent leaf spot disease happened. After the seeds germinate and emerge, they are cut and buried at the early flowering stage, and watered as appropriate according to specific weather conditions and growing seasons.
该方法在甘肃张掖地区实施一年后,防止水肥渗漏、持水持肥效果显著,叶斑病的发病率明显下降且效果优于单独使用多菌灵,水肥有效利用率提高约43%以上;2年后土壤有机质,微生物数量、种类显著增加。具体见表1:One year after the method was implemented in Zhangye, Gansu, the effect of preventing water and fertilizer leakage and retaining water and fertilizer was remarkable, the incidence of leaf spot disease was significantly reduced, and the effect was better than that of using carbendazim alone, and the effective utilization rate of water and fertilizer was increased by more than 43%. ; After 2 years, soil organic matter, microbial quantity and species increased significantly. See Table 1 for details:
实施例2、改性纤维素和非豆科固氮植物对荒漠化土地的改良Example 2. Improvement of desertified land by modified cellulose and non-legume nitrogen-fixing plants
(1)在浓硫酸催化下,羟甲基纤维素钠和草酸以1:5的摩尔比在110℃下反应2.5h,得到羧基化羟甲基纤维素钠;再将羧基化羟甲基纤维素钠(混合土的0.8 wt%)与混合土(凹凸棒土与黄土质量比为1:2),玉米秸秆粉末(混合土的8wt%)、在65 ℃的高温厌氧环境下腐熟的猪粪(混合土的18 wt%)混合,并搅拌混匀,即得荒漠化土地改良材料;(1) Under the catalysis of concentrated sulfuric acid, sodium hydroxymethyl cellulose and oxalic acid were reacted at a molar ratio of 1:5 at 110 ° C for 2.5 h to obtain sodium carboxymethyl cellulose; Plain sodium (0.8 wt% of mixed soil) and mixed soil (mass ratio of attapulgite to loess is 1:2), corn stalk powder (8 wt% of mixed soil), pigs decomposed under high temperature anaerobic environment at 65 ℃ The dung (18 wt% of the mixed soil) is mixed, and stirred and mixed to obtain the desertification land improvement material;
(2)在1.5 m×1.5 m的树穴中放入根瘤菌剂,按撒入10 kg/亩在树穴中撒入磷酸二胺,将荒漠化土地改良材料铺在树穴中,栽种桤木和沙棘幼苗,埋土,灌溉,使土壤保持湿润以保证树苗生根、生长,在植物越冬期喷洒1200倍黄腐酸钾液。树苗栽种后,根据具体天气状况及生长季节需要酌情浇水。(2) Put the rhizobia agent in the tree hole of 1.5 m×1.5 m, sprinkle 10 kg/mu, sprinkle diamine phosphate in the tree hole, spread the desertification land improvement material in the tree hole, and plant alder And sea buckthorn seedlings, bury the soil, irrigate, keep the soil moist to ensure that the seedlings take root and grow, and spray 1200 times potassium fulvic acid solution during the wintering period of the plants. After the saplings are planted, they need to be watered as appropriate according to the specific weather conditions and growing season.
该方法在新疆哈密地区实施一年后,防止水肥渗漏、持水持肥效果显著,叶片衰老推迟、绿叶数保持多,水肥有效利用率提高约40 %以上;2年后土壤有机质,微生物数量、种类显著增加。桤木生长迅速,固沙保土效果优异。具体见表2:One year after the method was implemented in Hami area of Xinjiang, the effect of preventing water and fertilizer leakage, retaining water and fertilizer is remarkable, leaf senescence is delayed, the number of green leaves is maintained, and the effective utilization rate of water and fertilizer is increased by about 40%; after 2 years, soil organic matter, microbial quantity , the species increased significantly. Alder grows rapidly and has excellent sand-fixing and soil-preserving effects. See Table 2 for details:
实施例3、改性纤维素和壳类谷物对荒漠化土地的改良Example 3. Improvement of desertified land by modified cellulose and shell grains
(1)在浓硫酸催化下,羟丙基纤维素和聚乙二醇以1:2的摩尔比在140 ℃下反应4h,得到羟基化羟丙基纤维素;再将羟基化羟丙基纤维素(混合土的1.5 wt%),混合土(蒙脱土与黄土质量比为1:2),植物秸秆粉末(混合土的12 wt%),在60 ℃的高温厌氧环境下腐熟的牛粪(混合土的25 wt%)混合,搅拌混匀,即得荒漠化土地改良材料;(1) Under the catalysis of concentrated sulfuric acid, hydroxypropyl cellulose and polyethylene glycol were reacted at a molar ratio of 1:2 at 140 °C for 4 h to obtain hydroxylated hydroxypropyl cellulose; plain (1.5 wt% of the mixed soil), mixed soil (the mass ratio of montmorillonite and loess is 1:2), plant straw powder (12 wt% of the mixed soil), cattle decomposed under the high temperature anaerobic environment of 60 ℃ The manure (25 wt% of the mixed soil) is mixed, stirred and mixed to obtain the desertification land improvement material;
(2)在土地表面撒入15 kg尿素和磷酸二胺,将荒漠化土地改良材料铺在地面,用旋耕机旋耕。将壳类谷物种子用0.5%的黄腐酸钾拌种,在旋耕后的地面按50 cm的距离条播,灌溉,使土壤保持湿润以保证种子发芽、出苗、生长。种子发芽、出苗后,根据具体天气状况及生长季节需要酌情浇水。(2) Sprinkle 15 kg of urea and diamine phosphate on the surface of the land, spread the desertification land improvement materials on the ground, and use a rotary tiller. The seeds of shell grains were dressed with 0.5% potassium fulvic acid, drilled on the ground after rotary tillage at a distance of 50 cm, and irrigated to keep the soil moist to ensure the germination, emergence and growth of the seeds. After the seeds germinate and emerge, they need to be watered as appropriate according to specific weather conditions and growing seasons.
该方法在甘肃敦煌地区实施一年后,防止水肥渗漏、持水持肥效果显著,平均根长明显增加,水肥有效利用率提高约32 %以上;2年后土壤有机质,微生物数量、种类显著增加。在改良荒漠化土地的同时带动当地经济发展。具体见表3:After the method was implemented in Dunhuang area of Gansu for one year, the effect of preventing the leakage of water and fertilizer, retaining water and fertilizer is remarkable, the average root length is obviously increased, and the effective utilization rate of water and fertilizer is increased by about 32%; after 2 years, the soil organic matter, the number and species of microorganisms are remarkable Increase. While improving desertified land, it drives local economic development. See Table 3 for details:
实施例4、改性纤维素和蔬菜作物对荒漠化土地的改良Example 4. Improvement of desertified land by modified cellulose and vegetable crops
(1)在浓硫酸催化下,羟乙基纤维素和氨基酸1:4的摩尔比在70℃下反应3 h,得到改性羟乙基纤维素;再将改性羟乙基纤维素(混合土1.2 wt%)与混合土(高岭土与黄土质量比为1:2),玉米秸秆粉末(混合土12 wt%),在70 ℃的高温厌氧环境下腐熟的马粪(混合土25 wt%)混合,搅拌混匀,即得荒漠化土地改良材料。(1) Under the catalysis of concentrated sulfuric acid, the molar ratio of hydroxyethyl cellulose and amino acid 1:4 was reacted at 70 °C for 3 h to obtain modified hydroxyethyl cellulose; then modified hydroxyethyl cellulose (mixed soil 1.2 wt%) and mixed soil (the mass ratio of kaolin to loess is 1:2), corn stover powder (mixed soil 12 wt%), and horse manure (mixed soil 25 wt%) decomposed in a high-temperature anaerobic environment at 70 °C ), and stir and mix to obtain the desertification land improvement material.
(2)在土地表面撒入20 kg洋丰复合肥,将荒漠化土地改良材料铺在地面,用旋耕机旋耕。将蔬菜作物种子用0.5%的黄腐酸钾拌种,在旋耕后的地面按40 cm的距离条播,灌溉,使土壤保持湿润以保证种子发芽、出苗、生长,在生长期按每10~15天一次,连续喷洒3次1500倍黄腐酸钾液。 种子发芽、出苗后,根据具体天气状况及生长季节需要酌情浇水。(2) Sprinkle 20 kg of Yangfeng compound fertilizer on the surface of the land, spread the desertification land improvement materials on the ground, and use a rotary tiller. Dress the seeds of vegetable crops with 0.5% potassium fulvic acid, drill and sown at a distance of 40 cm on the ground after rotary tillage, and irrigate to keep the soil moist to ensure the germination, emergence and growth of the seeds. Once every 15 days, spray 3 times of 1500 times potassium humate solution continuously. After the seeds germinate and emerge, they need to be watered as appropriate according to specific weather conditions and growing seasons.
该方法在甘肃敦煌地区实施一年后,防止水肥渗漏、持水持肥效果显著,作物蒸腾作用明显下降,水肥有效利用率提高约27 %以上;2年后土壤有机质,微生物数量、种类显著增加。在改良荒漠化土地的同时带动当地经济发展。具体见表4:One year after the method was implemented in the Dunhuang area of Gansu, the effect of preventing water and fertilizer leakage, retaining water and fertilizer is remarkable, crop transpiration is significantly reduced, and the effective utilization rate of water and fertilizer is increased by about 27%; after 2 years, soil organic matter, microbial quantity and species are significantly Increase. While improving desertified land, it drives local economic development. See Table 4 for details:
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