CN111094360B - 烯烃气相聚合方法 - Google Patents

烯烃气相聚合方法 Download PDF

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CN111094360B
CN111094360B CN201880057521.7A CN201880057521A CN111094360B CN 111094360 B CN111094360 B CN 111094360B CN 201880057521 A CN201880057521 A CN 201880057521A CN 111094360 B CN111094360 B CN 111094360B
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reactor
gas
downcomer
liquid
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CN111094360A (zh
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A·马祖科
E·巴莱斯特拉
R·潘塔莱昂尼
D·塔尔塔里
R·里纳尔迪
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
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    • C08F2/00—Processes of polymerisation
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00734—Controlling static charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00991—Disengagement zone in fluidised-bed reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201880057521.7A 2017-09-21 2018-09-13 烯烃气相聚合方法 Active CN111094360B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17192309 2017-09-21
EP17192309.7 2017-09-21
PCT/EP2018/074705 WO2019057595A1 (en) 2017-09-21 2018-09-13 PROCESS FOR THE GASEOUS POLYMERIZATION OF OLEFINS

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CN111094360A CN111094360A (zh) 2020-05-01
CN111094360B true CN111094360B (zh) 2022-04-01

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US (1) US11098143B2 (enExample)
EP (1) EP3684824B1 (enExample)
JP (1) JP6975861B2 (enExample)
KR (1) KR102336485B1 (enExample)
CN (1) CN111094360B (enExample)
AR (1) AR112897A1 (enExample)
BR (1) BR112020004713B8 (enExample)
RU (1) RU2739304C1 (enExample)
SA (1) SA520411541B1 (enExample)
WO (1) WO2019057595A1 (enExample)

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JP7608608B2 (ja) * 2020-12-09 2025-01-06 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン気相重合用反応器

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US6818187B2 (en) * 1998-07-08 2004-11-16 Basell Poliolefine Italia S.P.A. Apparatus for gas-phase polymerization
CN101679557A (zh) * 2007-05-22 2010-03-24 巴塞尔聚烯烃意大利有限责任公司 用于制备软质丙烯聚合物组合物的方法
CN102186575A (zh) * 2008-10-15 2011-09-14 尤尼威蒂恩技术有限公司 循环流化床反应器
CN102812056A (zh) * 2009-12-21 2012-12-05 陶氏环球技术有限责任公司 具有多个流动型态的气相聚合方法

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US4981929A (en) * 1986-06-23 1991-01-01 Union Carbide Chemicals And Plastics Company, Inc. Catalyst productivity in the polymerization of olefins
JPH0478626A (ja) * 1990-07-13 1992-03-12 Morisawa & Co Ltd 自動車の停車時間計測表示装置
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
JP2006502263A (ja) 2002-10-09 2006-01-19 バセル ポリオレフィン イタリア エス．アール．エス． オレフィン類の気相触媒重合
CN1229400C (zh) 2003-09-18 2005-11-30 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
RU2380379C2 (ru) * 2004-03-03 2010-01-27 Базелль Полиолефин Италия С.Р.Л. Способ регулирования течения полимера в процессе полимеризации
US7071137B2 (en) 2004-08-25 2006-07-04 Novolen Technology Holdings, C.V. Method of making a ziegler-natta catalyst
EP1827673B1 (en) * 2004-12-20 2012-02-01 Basell Poliolefine Italia S.r.l. Process and apparatus for the polymerization of propylene
JP5308797B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
US8198383B2 (en) * 2007-12-21 2012-06-12 Basell Poliolefine Italia, s.r.l. Process for the gas-phase polymerization of olefins
US8148478B2 (en) * 2008-05-27 2012-04-03 Basell Poliolefine Italia S.R.L. Process for the gas-phase polymerization of olefins
BR112012005542B1 (pt) 2009-09-11 2019-08-20 Basell Poliolefine Italia S.R.L Processo para polimerização em fase gasosa de olefinas
US9073027B2 (en) 2010-09-09 2015-07-07 Basell Poliolefine Italia S.R.L. Process and apparatus for the gas-phase polymerization of olefins
KR102379360B1 (ko) 2014-09-11 2022-03-25 릴라이언스 인더스트리즈 리미티드 폴리에틸렌을 제조하기 위한 지글러-나타 촉매 조성물
RU2733752C9 (ru) * 2017-03-27 2020-11-24 Базелл Полиолефин Италия С.Р.Л. Способ газофазной полимеризации олефинов

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6818187B2 (en) * 1998-07-08 2004-11-16 Basell Poliolefine Italia S.P.A. Apparatus for gas-phase polymerization
CN101679557A (zh) * 2007-05-22 2010-03-24 巴塞尔聚烯烃意大利有限责任公司 用于制备软质丙烯聚合物组合物的方法
CN102186575A (zh) * 2008-10-15 2011-09-14 尤尼威蒂恩技术有限公司 循环流化床反应器
CN102812056A (zh) * 2009-12-21 2012-12-05 陶氏环球技术有限责任公司 具有多个流动型态的气相聚合方法

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KR20200042951A (ko) 2020-04-24
AR112897A1 (es) 2019-12-26
KR102336485B1 (ko) 2021-12-07
CN111094360A (zh) 2020-05-01
JP6975861B2 (ja) 2021-12-01
SA520411541B1 (ar) 2023-02-07
US11098143B2 (en) 2021-08-24
US20200216588A1 (en) 2020-07-09
EP3684824B1 (en) 2025-02-26
BR112020004713A2 (pt) 2020-09-08
EP3684824A1 (en) 2020-07-29
JP2020533477A (ja) 2020-11-19
RU2739304C1 (ru) 2020-12-22
WO2019057595A1 (en) 2019-03-28
BR112020004713B8 (pt) 2023-10-31
BR112020004713B1 (pt) 2023-06-27

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