RU2739304C1 - Способ газофазной полимеризации олефинов - Google Patents

Способ газофазной полимеризации олефинов Download PDF

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RU2739304C1
RU2739304C1 RU2020112283A RU2020112283A RU2739304C1 RU 2739304 C1 RU2739304 C1 RU 2739304C1 RU 2020112283 A RU2020112283 A RU 2020112283A RU 2020112283 A RU2020112283 A RU 2020112283A RU 2739304 C1 RU2739304 C1 RU 2739304C1
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reactor
gas
riser
polymerization
downdraft
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Антонио МАЦЦУККО
Энрико БАЛЕСТРА
Роберто ПАНТАЛЕОНИ
Давиде ТАРТАРИ
Риккардо РИНАЛДИ
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Базелл Полиолефин Италия С.Р.Л.
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00734Controlling static charge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00991Disengagement zone in fluidised-bed reactors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02Anti-static agent incorporated into the catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15Isotactic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU2020112283A 2017-09-21 2018-09-13 Способ газофазной полимеризации олефинов RU2739304C1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17192309 2017-09-21
EP17192309.7 2017-09-21
PCT/EP2018/074705 WO2019057595A1 (en) 2017-09-21 2018-09-13 PROCESS FOR THE GASEOUS POLYMERIZATION OF OLEFINS

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RU2739304C1 true RU2739304C1 (ru) 2020-12-22

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US (1) US11098143B2 (enExample)
EP (1) EP3684824B1 (enExample)
JP (1) JP6975861B2 (enExample)
KR (1) KR102336485B1 (enExample)
CN (1) CN111094360B (enExample)
AR (1) AR112897A1 (enExample)
BR (1) BR112020004713B8 (enExample)
RU (1) RU2739304C1 (enExample)
SA (1) SA520411541B1 (enExample)
WO (1) WO2019057595A1 (enExample)

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JP7608608B2 (ja) * 2020-12-09 2025-01-06 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン気相重合用反応器

Citations (7)

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RU2223974C2 (ru) * 1998-07-08 2004-02-20 Монтелл Текнолоджи Компани Б.В. Способ и устройство для газофазной полимеризации
WO2006067052A1 (en) * 2004-12-20 2006-06-29 Basell Poliolefine Italia S.R.L. Process and apparatus for the polymerization of propylene
EP1720913A1 (en) * 2004-03-03 2006-11-15 Basell Poliolefine Italia S.r.l. Method for controlling the polymer flow in a polymerization process
US20090149610A1 (en) * 2007-12-11 2009-06-11 Sumitomo Chemocal Company, Limited Olefin polymerization reactor, polyolefin production system, and polyolefin production process
EP2281010A1 (en) * 2008-05-27 2011-02-09 Basell Poliolefine Italia S.r.l. Process for the gas-phase polymerization of olefins
US20110152424A1 (en) * 2009-12-21 2011-06-23 Dow Global Technologies Inc. Gas-phase polymerization process having multiple flow regimes
US20110184131A1 (en) * 2008-10-15 2011-07-28 Univation Technologies, Llc Circulating Fluidized Bed Reactor

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US4981929A (en) * 1986-06-23 1991-01-01 Union Carbide Chemicals And Plastics Company, Inc. Catalyst productivity in the polymerization of olefins
JPH0478626A (ja) * 1990-07-13 1992-03-12 Morisawa & Co Ltd 自動車の停車時間計測表示装置
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
JP2006502263A (ja) 2002-10-09 2006-01-19 バセル ポリオレフィン イタリア エス.アール.エス. オレフィン類の気相触媒重合
CN1229400C (zh) 2003-09-18 2005-11-30 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
US7071137B2 (en) 2004-08-25 2006-07-04 Novolen Technology Holdings, C.V. Method of making a ziegler-natta catalyst
MX2009012580A (es) * 2007-05-22 2009-12-08 Basell Poliolefine Srl Procedimiento para la preparacion de composiciones suaves de polimero de propileno.
US8198383B2 (en) * 2007-12-21 2012-06-12 Basell Poliolefine Italia, s.r.l. Process for the gas-phase polymerization of olefins
BR112012005542B1 (pt) 2009-09-11 2019-08-20 Basell Poliolefine Italia S.R.L Processo para polimerização em fase gasosa de olefinas
US9073027B2 (en) 2010-09-09 2015-07-07 Basell Poliolefine Italia S.R.L. Process and apparatus for the gas-phase polymerization of olefins
KR102379360B1 (ko) 2014-09-11 2022-03-25 릴라이언스 인더스트리즈 리미티드 폴리에틸렌을 제조하기 위한 지글러-나타 촉매 조성물
RU2733752C9 (ru) * 2017-03-27 2020-11-24 Базелл Полиолефин Италия С.Р.Л. Способ газофазной полимеризации олефинов

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2223974C2 (ru) * 1998-07-08 2004-02-20 Монтелл Текнолоджи Компани Б.В. Способ и устройство для газофазной полимеризации
EP1720913A1 (en) * 2004-03-03 2006-11-15 Basell Poliolefine Italia S.r.l. Method for controlling the polymer flow in a polymerization process
WO2006067052A1 (en) * 2004-12-20 2006-06-29 Basell Poliolefine Italia S.R.L. Process and apparatus for the polymerization of propylene
US20090149610A1 (en) * 2007-12-11 2009-06-11 Sumitomo Chemocal Company, Limited Olefin polymerization reactor, polyolefin production system, and polyolefin production process
EP2281010A1 (en) * 2008-05-27 2011-02-09 Basell Poliolefine Italia S.r.l. Process for the gas-phase polymerization of olefins
US20110184131A1 (en) * 2008-10-15 2011-07-28 Univation Technologies, Llc Circulating Fluidized Bed Reactor
US20110152424A1 (en) * 2009-12-21 2011-06-23 Dow Global Technologies Inc. Gas-phase polymerization process having multiple flow regimes

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KR20200042951A (ko) 2020-04-24
AR112897A1 (es) 2019-12-26
KR102336485B1 (ko) 2021-12-07
CN111094360A (zh) 2020-05-01
JP6975861B2 (ja) 2021-12-01
SA520411541B1 (ar) 2023-02-07
US11098143B2 (en) 2021-08-24
US20200216588A1 (en) 2020-07-09
EP3684824B1 (en) 2025-02-26
BR112020004713A2 (pt) 2020-09-08
EP3684824A1 (en) 2020-07-29
JP2020533477A (ja) 2020-11-19
CN111094360B (zh) 2022-04-01
WO2019057595A1 (en) 2019-03-28
BR112020004713B8 (pt) 2023-10-31
BR112020004713B1 (pt) 2023-06-27

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