CN110944941B - 具有afx结构的含铜微孔铝硅酸盐材料的直接合成以及该材料的用途 - Google Patents

具有afx结构的含铜微孔铝硅酸盐材料的直接合成以及该材料的用途 Download PDF

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CN110944941B
CN110944941B CN201880047834.4A CN201880047834A CN110944941B CN 110944941 B CN110944941 B CN 110944941B CN 201880047834 A CN201880047834 A CN 201880047834A CN 110944941 B CN110944941 B CN 110944941B
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copper
stirring
zeolite
afx structure
temperature
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CN110944941A (zh
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D·博索特
B·哈布扎鲁
E·利多
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IFP Energies nouvelles
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B01J29/0352—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites containing iron group metals, noble metals or copper
    • B01J29/0356—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
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    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
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  • Silicates, Zeolites, And Molecular Sieves (AREA)
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CN201880047834.4A 2017-07-18 2018-07-12 具有afx结构的含铜微孔铝硅酸盐材料的直接合成以及该材料的用途 Expired - Fee Related CN110944941B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1756800A FR3069238B1 (fr) 2017-07-18 2017-07-18 Synthese directe d'un materiau aluminosilicate microporeux de structure afx comprenant du cuivre et utilisation de ce materiau
FR1756800 2017-07-18
PCT/EP2018/068907 WO2019016063A1 (fr) 2017-07-18 2018-07-12 Synthese directe d'un materiau aluminosilicate microporeux de structure afx comprenant du cuivre et utilisation de ce materiau

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CN110944941A CN110944941A (zh) 2020-03-31
CN110944941B true CN110944941B (zh) 2023-05-02

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US (1) US10889502B2 (cg-RX-API-DMAC7.html)
EP (1) EP3655363B1 (cg-RX-API-DMAC7.html)
JP (1) JP7198266B2 (cg-RX-API-DMAC7.html)
KR (1) KR20200030539A (cg-RX-API-DMAC7.html)
CN (1) CN110944941B (cg-RX-API-DMAC7.html)
ES (1) ES2899640T3 (cg-RX-API-DMAC7.html)
FR (1) FR3069238B1 (cg-RX-API-DMAC7.html)
WO (1) WO2019016063A1 (cg-RX-API-DMAC7.html)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3095130B1 (fr) * 2019-04-19 2022-03-11 Ifp Energies Now Synthese rapide d’un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox
FR3111886B1 (fr) 2020-06-29 2022-06-24 Ifp Energies Now Synthese directe d’un catalyseur a base de zeolithe afx contenant du cuivre pour la reduction selective des nox
CN115734816B (zh) * 2020-09-11 2026-07-03 巴斯夫公司 制备具有afx骨架结构的沸石材料的方法及所制备的沸石材料
CN115722214B (zh) * 2022-12-07 2024-03-29 东莞市亿茂滤材有限公司 一种除氨气树脂材料及其制备方法
FR3142917B1 (fr) * 2022-12-09 2024-11-01 Ifp Energies Now Catalyseur comprenant une zéolithe IZM-9 de type structural AFX de très haute pureté et au moins un métal de transition pour la réduction sélective de NOx
CN116196969A (zh) * 2023-03-07 2023-06-02 中国科学院城市环境研究所 一种用于氨气选择性催化还原的Cu-AFX催化剂

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US4482531A (en) * 1983-04-29 1984-11-13 Mobil Oil Corporation Synthesis of ZSM-12 zeolite
US5194235A (en) * 1992-08-27 1993-03-16 Chevron Research And Technology Company Synthesis of SSZ-16 zeolite catalyst
JP2008520536A (ja) * 2004-11-19 2008-06-19 エージェンシー フォー サイエンス，テクノロジー アンド リサーチ 結晶性酸化物材料およびその合成
KR101782432B1 (ko) * 2012-04-27 2017-09-28 할도르 토프쉐 에이/에스 Ｃｕ-ＳＡＰＯ-34의 직접 합성을 위한 방법
KR20150093664A (ko) 2012-12-12 2015-08-18 할도르 토프쉐 에이/에스 Cu-SSZ-13의 합성을 위한 원-포트 방법, 그 방법에 의해 얻어진 화합물 및 그것의 용도
JP6070230B2 (ja) 2013-02-01 2017-02-01 東ソー株式会社 Ａｆｘ型シリコアルミノリン酸塩及びその製造方法、並びにこれを用いた窒素酸化物還元方法
US11266981B2 (en) * 2013-12-02 2022-03-08 Johnson Matthey Public Limited Company Mixed template synthesis of low silica CHA zeolite
CN103599813B (zh) * 2013-12-04 2015-10-14 北京化工大学 一种用于低温scr脱硝的分子筛基催化剂及其制备方法
KR102060413B1 (ko) * 2014-04-07 2019-12-30 할도르 토프쉐 에이/에스 저온에서의 고체-상태 이온 교환에 의한 금속 교환된 제올라이트의 제조 방법
KR20170083606A (ko) 2014-11-14 2017-07-18 존슨 맛쎄이 퍼블릭 리미티드 컴파니 Afx 제올라이트
JP6655959B2 (ja) 2015-04-17 2020-03-04 東ソー株式会社 微結晶ａｆｘ型アルミノシリケート及びその製造方法
CN108136380B (zh) 2015-10-12 2021-07-30 优美科股份公司及两合公司 含铜小孔沸石的一锅合成
CN105523566A (zh) * 2015-12-13 2016-04-27 定州市荣鼎水环境生化技术有限公司 以氨为还原剂的选择性催化还原氮氧化物的沸石分子筛及其制备方法和应用
FR3067020B1 (fr) 2017-05-31 2022-03-18 Ifp Energies Now Synthese directe d'un materiau sapo de structure afx comprenant du cuivre et utilisation de ce materiau

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JP2020527123A (ja) 2020-09-03
EP3655363A1 (fr) 2020-05-27
FR3069238B1 (fr) 2019-07-12
KR20200030539A (ko) 2020-03-20
US20200156949A1 (en) 2020-05-21
WO2019016063A1 (fr) 2019-01-24
ES2899640T3 (es) 2022-03-14
EP3655363B1 (fr) 2021-09-08
US10889502B2 (en) 2021-01-12
FR3069238A1 (fr) 2019-01-25
CN110944941A (zh) 2020-03-31
JP7198266B2 (ja) 2022-12-28

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