CN110904672A - 一种羊毛条制备方法 - Google Patents
一种羊毛条制备方法 Download PDFInfo
- Publication number
- CN110904672A CN110904672A CN201911318668.XA CN201911318668A CN110904672A CN 110904672 A CN110904672 A CN 110904672A CN 201911318668 A CN201911318668 A CN 201911318668A CN 110904672 A CN110904672 A CN 110904672A
- Authority
- CN
- China
- Prior art keywords
- wool
- tank
- tops
- treatment
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000002268 wool Anatomy 0.000 title claims abstract description 140
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000003063 flame retardant Substances 0.000 claims abstract description 35
- 239000000835 fiber Substances 0.000 claims abstract description 34
- 230000003647 oxidation Effects 0.000 claims abstract description 23
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 18
- 230000004048 modification Effects 0.000 claims abstract description 14
- 238000012986 modification Methods 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000011001 backwashing Methods 0.000 claims abstract description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 40
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 235000017550 sodium carbonate Nutrition 0.000 claims description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 230000010355 oscillation Effects 0.000 claims description 10
- 230000001590 oxidative effect Effects 0.000 claims description 10
- 229920006122 polyamide resin Polymers 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- HIVGXUNKSAJJDN-UHFFFAOYSA-N [Si].[P] Chemical compound [Si].[P] HIVGXUNKSAJJDN-UHFFFAOYSA-N 0.000 claims description 5
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 239000002518 antifoaming agent Substances 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 239000012362 glacial acetic acid Substances 0.000 claims description 5
- RLAWWYSOJDYHDC-BZSNNMDCSA-N lisinopril Chemical compound C([C@H](N[C@@H](CCCCN)C(=O)N1[C@@H](CCC1)C(O)=O)C(O)=O)CC1=CC=CC=C1 RLAWWYSOJDYHDC-BZSNNMDCSA-N 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000011241 protective layer Substances 0.000 abstract description 4
- 238000009950 felting Methods 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010410 layer Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 3
- 239000004744 fabric Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种羊毛条制备方法，包括以下步骤：羊毛纤维亲水处理、浸轧预整理、烘焙处理、成条处理、氧化、复洗改性和烘干。本发明的优点：本发明所述的工艺，先通过对羊毛纤维阻燃整理，使得羊毛纤维具有阻燃防护层，该阻燃防护层还能有效避免羊毛纤维的毡缩，具有一举两得的效果；同时本发明采用特定的氧化工艺使羊毛条润湿并均匀渗透，腐蚀羊毛条上的一部分毛鳞片，复洗改性工艺脱除残留在羊毛条上的氧成分和毛鳞片并在剩余毛鳞片的毛干上包覆一层薄膜，然后经过烘干的回潮率和室温下的固化保持，能获得无氯防缩、处理质量一致且稳定的毛条。
Description
技术领域
本发明涉及羊毛条制备技术领域，具体是指一种羊毛条制备方法。
背景技术
羊毛是纺织工业的重要原料，它具有许多优良特性，如弹性好、吸湿性强、不易沾污、保暖性好、光泽柔和。
现有的阻燃羊毛产品，大都是对成品羊毛织物或羊毛条直接进行阻燃整理，以期在提高阻燃性能的同时避免其毡缩，但效果较差；且现有的阻燃羊毛产品有些虽然可机洗且不会毡缩，但仍不可进行滚筒烘干。
发明内容
本发明为了解决上述的各种问题，提供了一种毛条处理质量一致且稳定、可机洗可滚筒烘干且防缩的羊毛条制备方法。
为解决上述技术问题，本发明提供的技术方案为：一种羊毛条制备方法，包括以下步骤：
步骤一，羊毛纤维亲水处理：将羊毛纤维置入亲水处理剂中，在超声震荡的作用下，浸泡预处理一段时间，然后水洗干净备用；
步骤二，浸轧预整理：将步骤一中得到的羊毛纤维浸渍于阻燃整理液中进行浸轧预整理；
步骤三，烘焙处理：将浸轧预整理后的羊毛纤维进行烘焙处理，得到阻燃整理羊毛纤维；
步骤四，成条处理：将步骤三中得到的阻燃整理羊毛采用成条机制备成羊毛条；
步骤五，氧化：以羊毛条重量为基准，同时在Kroy机中加入双氧水和1.2-1.8％英国史提芬逊公司的LISTRIL NGS润湿渗透剂，使步骤五中得到的羊毛条在Kroy机中6-8m/min匀速依次通过氧化溶液喷淋装置进行氧化，得到氧化处理后的羊毛条；双氧水的浓度为27-33wt％，所述双氧水的重量占原料羊毛条重量的2-3％，氧化时还加入了0.5-1.5％的消泡剂；
步骤六，复洗改性：将所述氧化处理后的羊毛条依次进入六个复洗槽，分别在第一槽中对所述氧化处理后的羊毛条脱氧、在第二槽中脱鳞、在第三、第四槽中漂洗、在第五槽中用2.5-3.5％聚酰胺树脂处理、在第六槽中软化；在第一槽中加入焦亚硫酸钠和碳酸钠对羊毛条脱氧，在第二槽中加入碳酸钠、片碱和小苏打调节pH值至9.5-9.8对羊毛条脱鳞，在第五槽先用纯碱调整pH值至7.8-8后再加入2.5-3.5％聚酰胺树脂处理，在第六槽中加入阳离子硅酮体柔软剂和冰醋酸；
步骤七，烘干：将所述复洗改性后的羊毛条烘干至毛条回潮率为5-8％，然后室温下放置46-50h得到所需羊毛条。
优选的，所述步骤一中的亲水处理剂包括如下配方量组分：双氧水3-4.5g/L、渗透剂0.35-0.45g/L和去离子水。
优选的，所述步骤一中的亲水处理的工艺条件为：温度42-48℃，超声震荡频率350-450次/min，超声时间16-19min。
优选的，所述步骤二中的阻燃整理液为硅磷杂化阻燃液。
优选的，所述步骤三中的烘焙处理的工艺条件为：真空条件下，先在62-68℃下预烘3.5-4.5min，再在112-118℃下焙烘6-9min。
本发明与现有技术相比的优点在于：本发明所述的工艺，先通过对羊毛纤维阻燃整理，使得羊毛纤维具有阻燃防护层，该阻燃防护层还能有效避免羊毛纤维的毡缩，具有一举两得的效果；同时本发明采用特定的氧化工艺使羊毛条润湿并均匀渗透，腐蚀羊毛条上的一部分毛鳞片，复洗改性工艺脱除残留在羊毛条上的氧成分和毛鳞片并在剩余毛鳞片的毛干上包覆一层薄膜，然后经过烘干的回潮率和室温下的固化保持，能获得无氯防缩、处理质量一致且稳定的毛条；再有，本发明工艺在纤维表面形成柔软薄膜，并使薄膜与纤维紧密相贴，达到抗起球抗收缩作用，并最大限度保持了羊毛原有性能及手感，使产品由仅可小心手洗到可机洗的功能性突破；在可机洗的基础上，能够滚筒烘干，迎合了欧美家庭洗涤毛衫的要求。
具体实施方式
下面结合实施例对本发明做进一步的详细说明。
实施例1
一种羊毛条制备方法，包括以下步骤：
步骤一，羊毛纤维亲水处理：将羊毛纤维置入亲水处理剂中，在超声震荡的作用下，浸泡预处理一段时间，然后水洗干净备用；
步骤二，浸轧预整理：将步骤一中得到的羊毛纤维浸渍于阻燃整理液中进行浸轧预整理；
步骤三，烘焙处理：将浸轧预整理后的羊毛纤维进行烘焙处理，得到阻燃整理羊毛纤维；
步骤四，成条处理：将步骤三中得到的阻燃整理羊毛采用成条机制备成羊毛条；
步骤五，氧化：以羊毛条重量为基准，同时在Kroy机中加入双氧水和1.2％英国史提芬逊公司的LISTRIL NGS润湿渗透剂，使步骤五中得到的羊毛条在Kroy机中6m/min匀速依次通过氧化溶液喷淋装置进行氧化，得到氧化处理后的羊毛条；双氧水的浓度为27wt％，所述双氧水的重量占原料羊毛条重量的2％，氧化时还加入了0.5％的消泡剂；
步骤六，复洗改性：将所述氧化处理后的羊毛条依次进入六个复洗槽，分别在第一槽中对所述氧化处理后的羊毛条脱氧、在第二槽中脱鳞、在第三、第四槽中漂洗、在第五槽中用2.5％聚酰胺树脂处理、在第六槽中软化；在第一槽中加入焦亚硫酸钠和碳酸钠对羊毛条脱氧，在第二槽中加入碳酸钠、片碱和小苏打调节pH值至9.5对羊毛条脱鳞，在第五槽先用纯碱调整pH值至7.8后再加入2.5％聚酰胺树脂处理，在第六槽中加入阳离子硅酮体柔软剂和冰醋酸；
步骤七，烘干：将所述复洗改性后的羊毛条烘干至毛条回潮率为5％，然后室温下放置46h得到所需羊毛条。
所述步骤一中的亲水处理剂包括如下配方量组分：双氧水3g/L、渗透剂0.35g/L和去离子水。
所述步骤一中的亲水处理的工艺条件为：温度42℃，超声震荡频率350次/min，超声时间16min。
所述步骤二中的阻燃整理液为硅磷杂化阻燃液。
所述步骤三中的烘焙处理的工艺条件为：真空条件下，先在62℃下预烘3.5min，再在112-118℃下焙烘6min。
实施例2
一种羊毛条制备方法，包括以下步骤：
步骤一，羊毛纤维亲水处理：将羊毛纤维置入亲水处理剂中，在超声震荡的作用下，浸泡预处理一段时间，然后水洗干净备用；
步骤二，浸轧预整理：将步骤一中得到的羊毛纤维浸渍于阻燃整理液中进行浸轧预整理；
步骤三，烘焙处理：将浸轧预整理后的羊毛纤维进行烘焙处理，得到阻燃整理羊毛纤维；
步骤四，成条处理：将步骤三中得到的阻燃整理羊毛采用成条机制备成羊毛条；
步骤五，氧化：以羊毛条重量为基准，同时在Kroy机中加入双氧水和1.8％英国史提芬逊公司的LISTRIL NGS润湿渗透剂，使步骤五中得到的羊毛条在Kroy机中8m/min匀速依次通过氧化溶液喷淋装置进行氧化，得到氧化处理后的羊毛条；双氧水的浓度为33wt％，所述双氧水的重量占原料羊毛条重量的3％，氧化时还加入了1.5％的消泡剂；
步骤六，复洗改性：将所述氧化处理后的羊毛条依次进入六个复洗槽，分别在第一槽中对所述氧化处理后的羊毛条脱氧、在第二槽中脱鳞、在第三、第四槽中漂洗、在第五槽中用3.5％聚酰胺树脂处理、在第六槽中软化；在第一槽中加入焦亚硫酸钠和碳酸钠对羊毛条脱氧，在第二槽中加入碳酸钠、片碱和小苏打调节pH值至9.8对羊毛条脱鳞，在第五槽先用纯碱调整pH值至8后再加入3.5％聚酰胺树脂处理，在第六槽中加入阳离子硅酮体柔软剂和冰醋酸；
步骤七，烘干：将所述复洗改性后的羊毛条烘干至毛条回潮率为8％，然后室温下放置50h得到所需羊毛条。
所述步骤一中的亲水处理剂包括如下配方量组分：双氧水4.5g/L、渗透剂0.45g/L和去离子水。
所述步骤一中的亲水处理的工艺条件为：温度48℃，超声震荡频率450次/min，超声时间19min。
所述步骤二中的阻燃整理液为硅磷杂化阻燃液。
所述步骤三中的烘焙处理的工艺条件为：真空条件下，先在68℃下预烘4.5min，再在118℃下焙烘9min。
实施例3
一种羊毛条制备方法，包括以下步骤：
步骤一，羊毛纤维亲水处理：将羊毛纤维置入亲水处理剂中，在超声震荡的作用下，浸泡预处理一段时间，然后水洗干净备用；
步骤二，浸轧预整理：将步骤一中得到的羊毛纤维浸渍于阻燃整理液中进行浸轧预整理；
步骤三，烘焙处理：将浸轧预整理后的羊毛纤维进行烘焙处理，得到阻燃整理羊毛纤维；
步骤四，成条处理：将步骤三中得到的阻燃整理羊毛采用成条机制备成羊毛条；
步骤五，氧化：以羊毛条重量为基准，同时在Kroy机中加入双氧水和1.5％英国史提芬逊公司的LISTRIL NGS润湿渗透剂，使步骤五中得到的羊毛条在Kroy机中7m/min匀速依次通过氧化溶液喷淋装置进行氧化，得到氧化处理后的羊毛条；双氧水的浓度为30wt％，所述双氧水的重量占原料羊毛条重量的2.5％，氧化时还加入了1％的消泡剂；
步骤六，复洗改性：将所述氧化处理后的羊毛条依次进入六个复洗槽，分别在第一槽中对所述氧化处理后的羊毛条脱氧、在第二槽中脱鳞、在第三、第四槽中漂洗、在第五槽中用3％聚酰胺树脂处理、在第六槽中软化；在第一槽中加入焦亚硫酸钠和碳酸钠对羊毛条脱氧，在第二槽中加入碳酸钠、片碱和小苏打调节pH值至9.7对羊毛条脱鳞，在第五槽先用纯碱调整pH值至7.9后再加入3％聚酰胺树脂处理，在第六槽中加入阳离子硅酮体柔软剂和冰醋酸；
步骤七，烘干：将所述复洗改性后的羊毛条烘干至毛条回潮率为6％，然后室温下放置48h得到所需羊毛条。
所述步骤一中的亲水处理剂包括如下配方量组分：双氧水4g/L、渗透剂0.4g/L和去离子水。
所述步骤一中的亲水处理的工艺条件为：温度45℃，超声震荡频率400次/min，超声时间18min。
所述步骤二中的阻燃整理液为硅磷杂化阻燃液。
所述步骤三中的烘焙处理的工艺条件为：真空条件下，先在65℃下预烘4min，再在115℃下焙烘7min。
以上实施例仅用于说明本发明，而并非对本发明的限制，本领域的普通技术人员，在不脱离本发明的精神和范围的情况下，还可以做出各种变化和变型，因此，所有等同的技术方案也属于本发明的范畴，本发明的专利保护范围应由权利要求限定。
Claims (5)
1.一种羊毛条制备方法，其特征在于:包括以下步骤：
步骤一，羊毛纤维亲水处理：将羊毛纤维置入亲水处理剂中，在超声震荡的作用下，浸泡预处理一段时间，然后水洗干净备用；
步骤二，浸轧预整理：将步骤一中得到的羊毛纤维浸渍于阻燃整理液中进行浸轧预整理；
步骤三，烘焙处理：将浸轧预整理后的羊毛纤维进行烘焙处理，得到阻燃整理羊毛纤维；
步骤四，成条处理：将步骤三中得到的阻燃整理羊毛采用成条机制备成羊毛条；
步骤五，氧化：以羊毛条重量为基准，同时在Kroy机中加入双氧水和1.2-1.8％英国史提芬逊公司的LISTRIL NGS润湿渗透剂，使步骤五中得到的羊毛条在Kroy机中6-8m/min匀速依次通过氧化溶液喷淋装置进行氧化，得到氧化处理后的羊毛条；双氧水的浓度为27-33wt％，所述双氧水的重量占原料羊毛条重量的2-3％，氧化时还加入了0.5-1.5％的消泡剂；
步骤六，复洗改性：将所述氧化处理后的羊毛条依次进入六个复洗槽，分别在第一槽中对所述氧化处理后的羊毛条脱氧、在第二槽中脱鳞、在第三、第四槽中漂洗、在第五槽中用2.5-3.5％聚酰胺树脂处理、在第六槽中软化；在第一槽中加入焦亚硫酸钠和碳酸钠对羊毛条脱氧，在第二槽中加入碳酸钠、片碱和小苏打调节pH值至9.5-9.8对羊毛条脱鳞，在第五槽先用纯碱调整pH值至7.8-8后再加入2.5-3.5％聚酰胺树脂处理，在第六槽中加入阳离子硅酮体柔软剂和冰醋酸；
步骤七，烘干：将所述复洗改性后的羊毛条烘干至毛条回潮率为5-8％，然后室温下放置46-50h得到所需羊毛条。
2.根据权利要求1所述的一种羊毛条制备方法，其特征在于：所述步骤一中的亲水处理剂包括如下配方量组分：双氧水3-4.5g/L、渗透剂0.35-0.45g/L和去离子水。
3.根据权利要求1所述的一种羊毛条制备方法，其特征在于：所述步骤一中的亲水处理的工艺条件为：温度42-48℃，超声震荡频率350-450次/min，超声时间16-19min。
4.根据权利要求1所述的一种羊毛条制备方法，其特征在于：所述步骤二中的阻燃整理液为硅磷杂化阻燃液。
5.根据权利要求1所述的一种羊毛条制备方法，其特征在于：所述步骤三中的烘焙处理的工艺条件为：真空条件下，先在62-68℃下预烘3.5-4.5min，再在112-118℃下焙烘6-9min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911318668.XA CN110904672A (zh) | 2019-12-19 | 2019-12-19 | 一种羊毛条制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911318668.XA CN110904672A (zh) | 2019-12-19 | 2019-12-19 | 一种羊毛条制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110904672A true CN110904672A (zh) | 2020-03-24 |
Family
ID=69826569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911318668.XA Pending CN110904672A (zh) | 2019-12-19 | 2019-12-19 | 一种羊毛条制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110904672A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112647288A (zh) * | 2020-12-08 | 2021-04-13 | 常熟市新光毛条处理有限公司 | 一种环保的毛条丝光防缩处理工艺 |
| CN114000204A (zh) * | 2021-12-06 | 2022-02-01 | 天宇羊毛工业（张家港保税区）有限公司 | 一种高污泥高支羊毛的洗毛制条工艺 |
| CN114411291A (zh) * | 2022-02-08 | 2022-04-29 | 张家港天宇精梳羊毛有限公司 | 一种非均匀缩率羊毛条生产制条工艺 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102936833B (zh) * | 2012-11-15 | 2015-05-20 | 浙江中新毛纺织有限公司 | 一种全面易护理羊毛条的制备方法及其产品 |
| CN105986484A (zh) * | 2015-02-13 | 2016-10-05 | 天津滨海东方科技有限公司 | 无氯羊毛条及羊毛制品防缩处理的连续加工工艺 |
| CN110205810A (zh) * | 2019-07-12 | 2019-09-06 | 常熟市新光毛条处理有限公司 | 一种耐洗防缩羊毛条的制备方法 |
-
2019
- 2019-12-19 CN CN201911318668.XA patent/CN110904672A/zh active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102936833B (zh) * | 2012-11-15 | 2015-05-20 | 浙江中新毛纺织有限公司 | 一种全面易护理羊毛条的制备方法及其产品 |
| CN105986484A (zh) * | 2015-02-13 | 2016-10-05 | 天津滨海东方科技有限公司 | 无氯羊毛条及羊毛制品防缩处理的连续加工工艺 |
| CN110205810A (zh) * | 2019-07-12 | 2019-09-06 | 常熟市新光毛条处理有限公司 | 一种耐洗防缩羊毛条的制备方法 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112647288A (zh) * | 2020-12-08 | 2021-04-13 | 常熟市新光毛条处理有限公司 | 一种环保的毛条丝光防缩处理工艺 |
| CN114000204A (zh) * | 2021-12-06 | 2022-02-01 | 天宇羊毛工业（张家港保税区）有限公司 | 一种高污泥高支羊毛的洗毛制条工艺 |
| CN114411291A (zh) * | 2022-02-08 | 2022-04-29 | 张家港天宇精梳羊毛有限公司 | 一种非均匀缩率羊毛条生产制条工艺 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110904672A (zh) | 一种羊毛条制备方法 | |
| CN107044051A (zh) | 一种羊毛面料的芳香防蛀整理工艺 | |
| CN103981708A (zh) | 一种羊毛织物的防缩整理方法 | |
| CN109295735A (zh) | 一种纯亚麻筒子纱的生产工艺 | |
| CN105926275A (zh) | 一种毛棉面料的抗菌防霉整理方法 | |
| CN106758259A (zh) | 一种羊毛条无氯防缩整理工艺 | |
| CN110670197A (zh) | 一种凉感纱线及其氨纶平纹面料染整方法 | |
| CN113882159B (zh) | 一种高舒适汉麻织物前处理工艺 | |
| CN105951423A (zh) | 一种毛棉面料的抗紫外线整理方法 | |
| CN113564791A (zh) | 一种玄武岩纤维针织布的制备工艺 | |
| CN105696353A (zh) | 一种基于棉织物的酶精练方法 | |
| CN104420215A (zh) | 亚麻织物的柔软化整理方法 | |
| CN108823859B (zh) | 麻布ario整理后烧毛去粒头的方法 | |
| CN111139641A (zh) | 一种全面易护理羊毛条的制备方法及其产品 | |
| CN112941917B (zh) | 一种利用纤维素酶湿法进行全棉织物柔软光洁处理的方法 | |
| EP2286017B1 (en) | A composition and a process to obtain wrinkle free woolen garments | |
| CN111777756B (zh) | 一种赋予织物悬垂性的整理剂及其制备方法和应用 | |
| CN110904678B (zh) | 一种硅烷偶联剂和甲基丙烯酸羟乙酯对棉织物原位免烫的方法 | |
| CN113062021A (zh) | 一种亚麻纱生产处理工艺 | |
| CN103485173A (zh) | 织物的壳聚糖季铵盐抗菌整理工艺 | |
| CN105970631A (zh) | 一种全毛精纺面料的低温染色工艺 | |
| CN111088707A (zh) | 一种抗菌的筒染氨纶包芯纱的加工方法 | |
| CN110747635A (zh) | 纯棉面料的抗菌处理方法 | |
| CN114808321B (zh) | 一种毛麻混纺纱线柔软养生处理工艺 | |
| CN113718525B (zh) | 亚麻织物的柔软整理方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200324 |
|
| RJ01 | Rejection of invention patent application after publication |