CN110644286B - 一种高导热防静电热升华转移印花纸 - Google Patents

一种高导热防静电热升华转移印花纸 Download PDF

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CN110644286B
CN110644286B CN201910891012.0A CN201910891012A CN110644286B CN 110644286 B CN110644286 B CN 110644286B CN 201910891012 A CN201910891012 A CN 201910891012A CN 110644286 B CN110644286 B CN 110644286B
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刘燕韶
马厚悦
张凤山
李晓亮
魏文光
冯好伟
周景蓬
魏国华
王海荣
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Abstract

本发明涉及造纸领域,具体来提供了一种高导热防静电热升华转移印花纸,该转移印花纸用于纺织品的印花,由原纸和涂料层组成,其中原纸以的针叶木浆、短切碳纤维和阔叶木浆抄造而成,所述的涂料层由羧甲基纤维素、碳酸钙、淀粉和碳纤维组成,两者共同作用在不降低纸张克重、挺度、高承墨量等优点的基础上,提高了纸张的导热性和导电性,提高生产效率,降低生产成本,避免了静电危害。

Description

一种高导热防静电热升华转移印花纸
技术领域
本发明涉及造纸领域,涉及一种用于纺织品印花的高导热防静电热升华转移印花纸。
背景技术
热升华转移印花纸主要用于纺织品的印花,使用专用墨水将既定图案使用喷墨打印机打印到热升华转移印花纸正面,再通过对纸张的反面高温加热,使墨水升华到与纸紧密贴合的纺织品表面,完成图案的转移。目前,热升华转移印花纸由原来的70-100g逐渐向50g以下的低克重发展,降低克重的主要原因是高克重的纸张传热慢,在热转移的过程中热效率低,车速提不起来,影响生产效率和生产成本。但纸张的克重降低后虽然提高了热效率,但也带来一系列的问题,例如:纸张克重纸,纸页薄,挺度差,在打印和转移的过程中均容易起折形成废品;热升华转移印花的专用墨水基本都是水性墨,而低克重的纸页厚度小,承载的墨量有限,不适用于大面积重墨、深墨的使用,易发生透墨、洇墨等现象,只适合浅色印花,并且纸页轻薄后,经过高温,纸页易带静电,特别是用于热升华转移印花的面料基本都是涤纶或高涤纶含量,静电的存在对后续加工带来障碍。
因此如何提供一种高导热防静电热升华转移印花纸成文本领域亟待解决的问题之一。
发明内容
本发明针对现有技术存在的诸多问题,提供了一种高导热防静电热升华转移印花纸,该转移印花纸用于纺织品的印花,由原纸和涂料层组成,其中原纸以的针叶木浆、短切碳纤维和阔叶木浆抄造而成,所述的涂料层由羧甲基纤维素、碳酸钙、淀粉和碳纤维组成,两者共同作用在不降低纸张克重、挺度、高承墨量等优点的基础上,提高了纸张的导热性和导电性,提高生产效率,降低生产成本,避免了静电危害。
本发明的最大特点就是在原纸和涂料层中均添加了碳纤维材料,碳纤维是由碳元素组成的一种特种纤维,具有耐高温、抗摩擦、导电、导热及耐腐蚀等特性外形呈纤维状、柔软、可加工成各种织物,但是在造纸领域中还未有人尝试过将其应用在造纸材料中去,本发明首次在原纸中添加了短切碳纤维,在涂料层中添加了碳纤维粉,从而从根本上改变了印花纸的性能;
本申请的具体技术方案如下:
一种高导热防静电热升华转移印花纸,包括原纸和涂料层,其中原纸规格为65-90g/m2,涂料层涂布量为5-10g/m2
其中所述的原纸组成按重量份计为:
20-30份的针叶木浆;5-10份的短切碳纤维;60-75份的阔叶木浆;
除此之外,还含有50-100kg/t纸的研磨碳酸钙;3-8kg/t纸的ASA施胶剂;0.5-1.0kg/t纸的阳离子聚丙烯酰胺;6-12kg/t纸的阳离子淀粉;
上述组成中针叶木浆打浆度控制在31-33°SR,湿重控制在5-8g,主要用于提高纸页的撕裂强度;短切碳纤维采购于江苏创宇碳纤维科技有限公司,使用长度在1-1.5mm,不打浆,使用PEO分散剂单独进行任意比分散,是导热和导电的主要原料;阔叶木打浆度控制在35-38°SR,湿重控制在2-4g,主要用于提高匀度和结合强度;
为了减少短切碳纤维的流失,该纤维的加入点设置在进入纸机前的最后一道冲浆泵阴程,由于在分散该纤维时使用了PEO分散剂,可以保证该碳纤维与浆料的均匀混合;
所述的涂料层涂料的组成按重量份计为:
A原料包括羧甲基纤维素钠、羧甲基淀粉钠、羧甲基纤维素、羧甲基淀粉中的一种或几种,用量30±10份;
B原料包括研磨碳酸钙、轻钙、瓷土中的一种或几种,用量30±10份;
C原料包括玉米淀粉、木薯淀粉中的一种或几种,用量30±10份;
D原料为碳纤维粉,用量10±2份;
其中A原料取代度≥0.8;D原料的目数≥325目,购自江苏创宇碳纤维科技有限公司;
综上所述,采用本发明的组方和工艺制备的转印印花纸,由于在原纸和涂料层中均加入了碳纤维材料,在不降低纸张克重、挺度、高承墨量等优点的基础上,提高了纸张的导热性和导电性,提高生产效率,降低生产成本,避免了静电危害。
具体实施方式
下面结合实施例来进一步说明本发明,可以使本领域技术人员更全面的理解本发明,但不以任何方式限制本发明。下述实施例中的短切碳纤维和碳纤维粉均采购于江苏创宇碳纤维科技有限公司;
实施例1
一种高导热防静电热升华转移印花纸,其组方和制备工艺具体步骤如下:
原纸组成按重量百分比计:针叶木浆20%,阔叶木浆75%,短切碳纤维5%;
针叶木浆打浆度31-33°SR,阔叶木浆打浆度35-38°SR,分别打浆完成后混合,泵送至抄前池;短切碳纤维用PEO分散剂分散成3%浓度悬浮液,用量1kg/t纤维,在冲浆泵的阴程按比例加入;
抄纸辅料:研磨碳酸钙加入量80kg/t纸;ASA施胶剂加入量3kg/t纸;阳离子PAM加入量0.5kg/t纸;阳离子淀粉加入量12kg/t纸,均泵入抄前池混合均匀;
混合浆料上抄纸机抄造90g/m2原纸,进入下一道工序;
涂料按下述重量份进行配比:羧甲基纤维素钠20份;研磨碳酸钙30份;木薯淀粉40份;碳纤维粉10份,使用热水分散至50%浓度,通蒸汽保证涂料温度50-70℃;
在刮刀涂布机上,对上述90g/m2原纸进行涂布,涂布量调整到6g/m2,形成96g/m2的热升华转移印花纸。
实施例2
一种高导热防静电热升华转移印花纸,其组方和制备工艺具体步骤如下:
原纸:针叶木浆30%,阔叶木浆60%,短切碳纤维10%;针叶木浆打浆度31-33°SR,阔叶木浆打浆度35-38°SR,分别打浆完成后混合,泵送至抄前池;短切碳纤维用PEO分散剂分散成3%浓度悬浮液,用量1kg/t纤维,在冲浆泵的阴程按比例加入;
抄纸辅料:研磨碳酸钙加入量100kg/t纸;ASA施胶剂加入量7kg/t纸;阳离子PAM加入量0.9kg/t纸;阳离子淀粉加入量10kg/t纸,均泵入抄前池混合均匀;
混合浆料上抄纸机抄造80g/m2原纸,进入下一道工序。
涂料:羧甲基淀粉钠30份;研磨碳酸钙32份;木薯淀粉30份;碳纤维粉8份,使用热水分散至40%浓度,通蒸汽保证涂料温度50-70℃;
在刮刀涂布机上,对上述80g/m2原纸进行涂布,涂布量调整到7g/m2,形成87g/m2的热升华转移印花纸。
实施例3
一种高导热防静电热升华转移印花纸,其组方和制备工艺具体步骤如下:
原纸:针叶木浆25%,阔叶木浆70%,短切碳纤维5%;针叶木浆打浆度31-33°SR,阔叶木浆打浆度35-38°SR,分别打浆完成后混合,泵送至抄前池;短切碳纤维用PEO分散剂分散成3%浓度悬浮液,用量1kg/t纤维,在冲浆泵的阴程按比例加入;
抄纸辅料:研磨碳酸钙加入量50kg/t纸;ASA施胶剂加入量8kg/t纸;阳离子PAM加入量7kg/t纸;阳离子淀粉加入量8kg/t纸,均泵入抄前池混合均匀;混合浆料上抄纸机抄造65g/m2原纸,进入下一道工序;
涂料:羧甲基纤维素钠20份,羧甲基淀粉15份;轻钙23份;玉米淀粉30份;碳纤维粉12份,使用热水分散至30%浓度,通蒸汽保证涂料温度50-70℃;
在刮刀涂布机上,对上述65g/m2原纸进行涂布,涂布量调整到8g/m2,形成73g/m2的热升华转移印花纸。
比较例
使用了本专利技术生产的87g、96g、73g热升华转移印花纸,与市场上较好的85g、50g两种正常使用的产品进行对比,均打印四色黑色块,墨量、布料、辊筒温度等指标均一致,高速印花机车速使用转印后的面料色泽肉眼看相一致,测量转印后的色密度。对比效果如下:
Figure GDA0003226985740000041
根据上述结果可知,本专利的产品可以提高一倍左右的车速,生产效率提高了近一倍,对应的是降低了电耗、人工费等生产成本。市场上的低克重纸张在高墨量的情况下表现比较差,主要表现在背透严重,在压烫的过程中需要增加一层衬纸,更加提高了成本,并且经过高温压烫,纸与布都静电严重,有较大的运行障碍。而本专利产品则表现良好,完全克服了这些缺点。

Claims (4)

1.一种高导热防静电热升华转移印花纸,包括原纸和涂料层,其特征在于:其中原纸规格为65-90g/m2,涂料层涂布量为5-10g/m2
其中所述的原纸组成按重量份计为:
20-30份的针叶木浆;5-10份的短切碳纤维;60-75份的阔叶木浆;
所述的涂料层涂料的组成按重量份计为:
A原料包括羧甲基纤维素钠、羧甲基淀粉钠、羧甲基纤维素、羧甲基淀粉中的一种或几种,用量30±10份;
B原料包括研磨碳酸钙、轻钙、瓷土中的一种或几种,用量30±10份;
C原料包括玉米淀粉、木薯淀粉中的一种或几种,用量30±10份;
D原料为碳纤维粉,用量10±2份。
2.根据权利要求1所述高导热防静电热升华转移印花纸,其特征在于:
所述的原纸组成中还含有50-100kg/t纸的研磨碳酸钙;3-8kg/t纸的ASA施胶剂;0.5-1.0kg/t纸的阳离子聚丙烯酰胺;6-12kg/t纸的阳离子淀粉。
3.根据权利要求1所述高导热防静电热升华转移印花纸,其特征在于:
所述针叶木浆打浆度控制在31-33°SR,湿重控制在5-8g;
所述短切碳纤维使用长度在1-1.5mm;
所述阔叶木浆打浆度控制在35-38°SR,湿重控制在2-4g。
4.根据权利要求1所述高导热防静电热升华转移印花纸,其特征在于:
所述涂料层中,A原料取代度≥0.8,D原料的目数≥325目。
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