CN110511835A - A kind of plant composite enzyme and its hand-guarding liquid detergent obtained - Google Patents
A kind of plant composite enzyme and its hand-guarding liquid detergent obtained Download PDFInfo
- Publication number
- CN110511835A CN110511835A CN201910881522.XA CN201910881522A CN110511835A CN 110511835 A CN110511835 A CN 110511835A CN 201910881522 A CN201910881522 A CN 201910881522A CN 110511835 A CN110511835 A CN 110511835A
- Authority
- CN
- China
- Prior art keywords
- composite plant
- dish washing
- washing liquid
- plant ferment
- fermentation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention discloses a kind of plant composite enzyme and its hand-guarding liquid detergents obtained, the preparation method of the composite plant ferment is the following steps are included: by Cortex Phellodendri 10%, folium artemisiae argyi 15%, safflower 3%, motherwort 10%, the fleece-flower root 2%, fermentation medium is made in the root of Dahurain angelica 5%, Radix Notoginseng 3%, honeysuckle 4%, penthorum chinense pursh 8%, ganoderma lucidum 8% and ginseng 2%, inoculation yeast bacteria culture fluid fermentation, by deacidification, supercritical CO2Extraction, concentration, obtain composite plant ferment.Composite plant ferment produced by the present invention can decompose that agriculture is residual, can allow fat-soluble agriculture is residual to be dissolved in water, and " decomposition " and " cleaning " is combined into one, to utterly destroy pesticide residue.Composite plant ferment and soapberry fruit extract in dish washing liquid of the present invention have the function of synergy, have both played the decontamination effect residual except agriculture, have decreased the stimulation to hand skin, play the role of handguard.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, and in particular to a kind of plant composite enzyme and its hand-guarding liquid detergent obtained.
Background technique
In daily life, people clean tableware, melon fruits and vegetables etc. with commercially available dish washing liquid, residual to reach removing dirt and agriculture
Purpose.
Pesticide residue on fruits and vegetables is concentrated mainly on the surface of agricultural product.Early stage pesticide is usually water soluble pesticide, is easy
Fallen by rain drop erosion, pesticide residue is less.Present pesticide, which is substantially all upgrading, becomes fat-soluble pesticide, and fat-soluble pesticide is
A kind of organic substance not soluble in water can firmly be attached to the surface of crops, because they are not soluble in water, rainwater is difficult handle
Fat-soluble pesticide falls from the surface erosion of crops, substantially exceeded so as to cause pesticide residue, has seriously threatened the body of the mankind
Health.
Although current dish washing liquid has stronger dirt-removing power, synthetics are too many, and being used for a long time will cause
Hand skin decortication and allergy, and synthetics non-degradable, pollute environment.
Ferment is commonly called as " enzyme ", and it is residual that it can decompose agriculture, can allow fat-soluble agriculture is residual to be dissolved in water, and " decomposition " and " cleaning " closes two
It is one, to thoroughly remove pesticide residue.
Summary of the invention
The primary purpose of the present invention is that provide a kind of composite plant ferment, the composite plant ferment can decompose agriculture it is residual,
It can allow fat-soluble agriculture is residual to be dissolved in water, " decomposition " and " cleaning " is combined into one, to utterly destroy pesticide residue；Its property simultaneously
Mildly, small to hand skin irritation.
Another object of the present invention is to provide the dish washing liquids for containing above-mentioned composite plant ferment, in decontamination except residual same of agriculture
When, play hand protecting function.
The purpose of the invention is achieved by the following technical solution:
A kind of preparation method of composite plant ferment, comprising the following steps:
(1) required plant material is crushed, prepares fermentation medium；The fermentation medium contains: by weight
Percentage meter, Cortex Phellodendri 10%, folium artemisiae argyi 15%, safflower 3%, motherwort 10%, the fleece-flower root 2%, the root of Dahurain angelica 5%, Radix Notoginseng 3%, gold
Honeysuckle flower 4%, penthorum chinense pursh 8%, ganoderma lucidum 8%, ginseng 2%, surplus are water, pH value 6-7；
(2) after fermentation medium sterilizing, inoculation yeast bacteria culture fluid, in 32 DEG C, continuous darkness condition, filtrated air ventilation
Amount is 1:0.4m per minute3Under v/v, tank pressure 0.04MPa, fermented and cultured 72h is stirred, fermentation liquid pH value is down to 4.5-5.0；
Saccharomycete circular candidiasis described in step (2)；
(3) calcium carbonate 1wt.%, 30 DEG C of deacidification 3h are added into fermentation liquid, guarantee that effective component is unlikely to lose in fermentation liquid
It is living, 3.0-3.5, total acidity 2.8-3.0 are down to fermentation liquid pH value；Fermentation liquid is first through colloid mill homogeneous, then through high-pressure homogeneous,
With 200 mesh plate-frame filterings；
(4) resulting fermentation liquid is used into supercritical CO2Extraction, supercritical extract will not in low-temperature operation, effective component
Inactivation, with CO2It ensure that no solvent residue for extractant；Extraction temperature control is at 33 DEG C, extracting pressure 7.15MPa；Extract
It is concentrated into concentration 25% (in terms of solid contents), obtains composite plant ferment.
Composite plant ferment of the invention can be used for preparing daily use chemicals articles for washing.
A kind of dish washing liquid contains above-mentioned composite plant ferment；
Further, the dish washing liquid also contains soapberry fruit extract；
Further, the dish washing liquid contains 1-3% composite plant ferment and 1-5% soapberry fruit extract；
Further, the dish washing liquid contains the ingredient of following mass percent:
The other surfaces activating agent is preferably by sodium sulfate of polyethenoxy ether of fatty alcohol and Cocoamidopropyl betaine
Composition；
The moisturizer is one or more of glycerol, Anjidew NL50, ethoxy urea or propylene glycol；
Further, the dish washing liquid contains the ingredient of following mass percent:
The preservative is one or more of Phenoxyethanol, Kathon CG, methyl esters or propyl ester.
The present invention has the following advantages and effects with respect to the prior art:
1, composite plant ferment produced by the present invention can decompose that agriculture is residual, can allow fat-soluble agriculture is residual to be dissolved in water, " decomposition "
" cleaning " is combined into one, to utterly destroy pesticide residue.
2, the soapberry fruit extract that dish washing liquid of the present invention contains is a kind of natural surfactant, and there is biology can drop
Solution improves the features such as foam stability, good cleaning force.
3, the composite plant ferment in dish washing liquid of the present invention and soapberry fruit extract have the function of synergy, both rise
The effect residual except agriculture to decontamination, decreases the stimulation to hand skin, plays the role of handguard.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
Embodiment
A kind of dish washing liquid, formula are as shown in table 1:
Table 1: dish washing liquid formula
Wherein the dosage of composite plant ferment and soapberry fruit extract is as shown in table 2:
Table 2: the dosage of composite plant ferment and soapberry fruit extract in embodiment and comparative example
| Example | Composite plant ferment | Soapberry fruit extract object |
| Comparative example 1 | 0% | 0% |
| Embodiment 1 | 0% | 5% |
| Embodiment 2 | 2.5% | 4% |
| Embodiment 3 | 3% | 5% |
| Embodiment 4 | 3% | 0% |
The preparation method of dish washing liquid of the present invention the following steps are included:
It by A heat phase to 80-85 degree, stirs evenly, after being cooled to 45 degree, Kathon CG, composite plant ferment is added.Stirring is equal
Even, it is qualified to examine, filtering and discharging.
In order to better illustrate the present invention the advantages of, be given below it is provided by the invention containing composite plant ferment, without trouble
Sub- berry extract dish washing liquid efficacy test:
50 age 25-60 years old volunteers are chosen, wherein male 25, is equally divided into 5 groups, every group of 10 people by female 25.Even
Dish washing liquid 1 month made from continuous embodiment and comparative example on probation, washed one's hands once with fixed amount dish washing liquid sooner or later daily, and take pictures and deposit
Shelves.Wherein one group is to compare the 0th day and the 30th day photo to contrasting.
Table 3: the handguard effect (number) of dish washing liquid
| Example | Normally | It is slight sensitive |
| Comparative example 1 | 5 | 5 |
| Embodiment 1 | 7 | 3 |
| Embodiment 2 | 10 | 0 |
| Embodiment 3 | 10 | 0 |
| Embodiment 4 | 8 | 2 |
The experiment of table 3 shows: when being free of composite plant ferment and soapberry fruit extract in component, tester has 5 to have
Slight sensitivity phenomenon (such as comparative example 1).
When dish washing liquid contains only soapberry fruit extract, normal number is risen to 7 (embodiments 1), but when addition
When composite plant ferment, have clear improvement effect, and normal number becomes 8 (embodiments 4) from 5.
When composite plant ferment and soapberry fruit extract are used in compounding by dish washing liquid, the effect that has clear improvement is (strictly according to the facts
Apply example 2,3).When the trial scale of composite plant ferment and soapberry fruit extract is 2.5:4, effect is preferably (embodiment 2).
When continuing growing its ratio, effect is identical (such as experimental example 3).
In addition, being checked by authoritative institution, cleaned after the dish washing liquid (embodiment 2) impregnates 15 minutes, in tableware
The average removal rate of remains of pesticide is 99.6%.
In conclusion composite plant ferment and soapberry fruit extract compound proportion play in the invention dish washing liquid to pass
Important role, the two have the function of synergy.Soapberry fruit extract belongs to natural mild surfactant, therefore big
The mild and biodegradability for improving the dish washing liquid greatly, are in addition detected through authoritative institution, which can efficiently drive
Except agriculture is residual, consumer health is takeed good care of.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (10)
1. a kind of preparation method of composite plant ferment, it is characterised in that the following steps are included:
(1) required plant material is crushed, prepares fermentation medium；The fermentation medium contains: percentage by weight
Number meter, Cortex Phellodendri 10%, folium artemisiae argyi 15%, safflower 3%, motherwort 10%, the fleece-flower root 2%, the root of Dahurain angelica 5%, Radix Notoginseng 3%, honeysuckle
4%, penthorum chinense pursh 8%, ganoderma lucidum 8%, ginseng 2%, surplus are water, pH value 6-7；
(2) after fermentation medium sterilizing, inoculation yeast bacteria culture fluid is in 32 DEG C, continuous darkness condition, filtrated air ventilatory capacity
1:0.4m per minute3Under v/v, tank pressure 0.04MPa, fermented and cultured 72h is stirred, fermentation liquid pH value is down to 4.5-5.0；
(3) calcium carbonate 1wt.%, 30 DEG C of deacidification 3h are added into fermentation liquid, fermentation liquid pH value is down to 3.0-3.5, and total acidity is
2.8-3.0；Fermentation liquid is first through colloid mill homogeneous, then through high-pressure homogeneous, with 200 mesh plate-frame filterings；
(4) resulting fermentation liquid is used into supercritical CO2Extraction, 33 DEG C of extraction temperature, extracting pressure 7.15MPa；Extract concentration
To concentration 25% (in terms of solid contents), composite plant ferment is obtained.
2. a kind of composite plant ferment, it is characterised in that: be made by method described in claim 1.
3. application of the composite plant ferment as claimed in claim 2 in preparation daily use chemicals articles for washing.
4. a kind of dish washing liquid, it is characterised in that contain composite plant ferment as claimed in claim 2.
5. dish washing liquid according to claim 4, it is characterised in that: contain soapberry fruit extract.
6. dish washing liquid according to claim 4, it is characterised in that: contain 1-3% composite plant ferment and 1-5% soapberry
Berry extract.
7. dish washing liquid according to claim 4, it is characterised in that: the ingredient containing following mass percent:
8. dish washing liquid according to claim 7, it is characterised in that: the other surfaces activating agent is by fatty alcohol polyoxy second
Alkene ether sodium sulfate and Cocoamidopropyl betaine composition.
9. dish washing liquid according to claim 7, it is characterised in that: the moisturizer is glycerol, Anjidew NL50, ethoxy urea
Or one or more of propylene glycol.
10. dish washing liquid according to claim 4, it is characterised in that the ingredient containing following mass percent:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910881522.XA CN110511835A (en) | 2019-09-18 | 2019-09-18 | A kind of plant composite enzyme and its hand-guarding liquid detergent obtained |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910881522.XA CN110511835A (en) | 2019-09-18 | 2019-09-18 | A kind of plant composite enzyme and its hand-guarding liquid detergent obtained |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110511835A true CN110511835A (en) | 2019-11-29 |
Family
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|---|---|---|---|
| CN201910881522.XA Pending CN110511835A (en) | 2019-09-18 | 2019-09-18 | A kind of plant composite enzyme and its hand-guarding liquid detergent obtained |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178379A (en) * | 2014-08-08 | 2014-12-03 | 福州喜自然生物科技有限公司 | Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity |
| CN105124577A (en) * | 2015-09-01 | 2015-12-09 | 福建天斯顿生物科技有限公司 | Preparation method of fruit and vegetable ferment nutrition |
| CN105255601A (en) * | 2015-10-09 | 2016-01-20 | 湖北穆兰同大科技有限公司 | Coconut oil fruit and vegetable cleaning agent |
| WO2016037992A1 (en) * | 2014-09-11 | 2016-03-17 | Henkel Ag & Co. Kgaa | Peroxidases having activity for carotenoids |
| CN106190651A (en) * | 2016-07-20 | 2016-12-07 | 福州喜自然生物科技有限公司 | A kind of zinc cation liquid and preparation method thereof |
| CN106995758A (en) * | 2016-01-23 | 2017-08-01 | 袁洁 | A kind of preparation method of natural plant type detergent raw material |
| CN107974435A (en) * | 2016-10-24 | 2018-05-01 | 张艳 | The preparation method and its product of a kind of ferment |
-
2019
- 2019-09-18 CN CN201910881522.XA patent/CN110511835A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178379A (en) * | 2014-08-08 | 2014-12-03 | 福州喜自然生物科技有限公司 | Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity |
| WO2016037992A1 (en) * | 2014-09-11 | 2016-03-17 | Henkel Ag & Co. Kgaa | Peroxidases having activity for carotenoids |
| CN105124577A (en) * | 2015-09-01 | 2015-12-09 | 福建天斯顿生物科技有限公司 | Preparation method of fruit and vegetable ferment nutrition |
| CN105255601A (en) * | 2015-10-09 | 2016-01-20 | 湖北穆兰同大科技有限公司 | Coconut oil fruit and vegetable cleaning agent |
| CN106995758A (en) * | 2016-01-23 | 2017-08-01 | 袁洁 | A kind of preparation method of natural plant type detergent raw material |
| CN106190651A (en) * | 2016-07-20 | 2016-12-07 | 福州喜自然生物科技有限公司 | A kind of zinc cation liquid and preparation method thereof |
| CN107974435A (en) * | 2016-10-24 | 2018-05-01 | 张艳 | The preparation method and its product of a kind of ferment |
Non-Patent Citations (1)
| Title |
|---|
| 杭州市科学技术协会: "<<第十三届杭州市青少年科技创新大赛优秀作品集>>", 31 December 2016 * |
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Application publication date: 20191129 |