KR20150095327A - Method for producing detergent - Google Patents

Abstract

The present invention relates to a method for preparing a natural detergent. The natural detergent is prepared by mixing natural ingredients such as Zingiber officinale, leaves of Camellia sinensis, Arctium lappa, Allium cepa, Citrus, and Toxicodendron vernicifluum with useful liquid microorganisms, extracting and fermenting active ingredients of the natural ingredients by using the useful liquid microorganisms, and conducting an ion exchange operation. The present invention uses the useful liquid microorganisms to extract the active ingredients of the natural ingredients such as the Zingiber officinale, leaves of Camellia sinensis, Arctium lappa, Allium cepa, Citrus, and Toxicodendron vernicifluum without damage. The present invention also ferments the extract by the action of the useful microorganisms to decompose the active ingredients and synthesize novel ingredients. The present invention does not harm the human body and has excellent storability to be used as the detergent for an extended period.

Description

[0001] The present invention relates to a method for producing detergent,

The present invention relates to a method of extracting effective ingredients possessed by these natural materials by a liquid useful microorganism after mixing natural materials such as onion, green tea leaves, burdock, ginger, citrus, And is used when removing impurities in everyday life, thereby exhibiting a detergent effect.

In general, detergents are used to remove impurities that contain grease as a chemical component. However, conventional detergents containing chemical components are excellent for removing impurities including oil, but they have a problem of damaging organs such as absorption time in the body as well as damaging the skin of the human body.

On the other hand, Effective Microorganisms (EM) is a combination of several microorganisms which are useful to humans among microorganisms.

Representative complex beneficial microorganisms were liquids developed in 1982 by Professor Higaderuo of the Faculty of Agriculture, Ryukyu University in Japan, and were used as EM-1, EM-5, EM-X, EM-Z, EM Bokashi, EM Ceramics, Activated EM, and related companies include EM Corporation of Japan, EM Korea of Korea, and evermiracle. Recently, sugar can be diluted in water, and a small amount of EM can be mixed with a rice bran, a degreasing steel or a rice flour, and aerobic fermentation can be carried out at an appropriate temperature to produce a useful microorganism, .

These useful microorganisms were first used mainly as agricultural materials. Since then, its efficacy and ability have been clarified, it has been applied to environmental purification, water quality improvement, public health, etc. Korean Patent No. 1073887 discloses a sulfur fermentation broth and its preparation method, a plant disease therapeutic composition using the same, And Korean Patent No. 10-1334157 discloses a virgin sulfur produced using a useful microorganism and its use.

In addition, the useful microorganisms of the above-mentioned liquid are advantageously used as detergents for kitchen detergents or dermal penetration of the human body by diluting them with water-borne beneficial microorganisms or water.

However, a method for extracting and fermenting an effective ingredient suitable as a detergent from a natural material by using a useful microorganism so as to exhibit a cleaning effect has not been known.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above-mentioned problems occurring in the prior art.

In order to solve the above problems, the present invention has excellent fat decomposition ability, and after mixing onion, green tea leaf, ginger, green tea leaf, burdock, citrus, and lacquer tree into useful microorganisms in liquid form, The present invention provides a method for producing a natural detergent which is obtained by extracting an active ingredient and fermenting the extract to obtain a composition which can be used over a long period of time as a detergent as well as an ion exchange treatment of the composition.

According to the present invention, it is possible to extract and effectively ferment an effective component of a natural material such as onion, green tea leaf, burdock, ginger, citrus, or lacquer by a liquid microorganism without damaging an effective ingredient, The shelf life thereof is advantageous over the long term, and it is advantageous to provide a natural detergent which is harmless to the human body.

Hereinafter, the present invention will be described more specifically.

The method for producing the natural detergent of the present invention is as follows.

a) obtaining a useful microorganism obtained by extracting useful microorganisms in a liquid phase;

b) preparing at least one of natural materials such as ginger, green tea leaves, burdock, onion, citrus, and sumac;

c) 1 to 80% of at least one selected from the group of onion, green tea leaf, ginger, green tea leaf, burdock, citrus and Rhus verniciflora is added to the liquid useful microorganism obtained in the step a, And fermenting the mixture at a temperature of 20 to 40 占 폚 for about 10 days to 6 months to extract an active ingredient from the liquid useful microorganism and fermenting the extract to obtain a useful microorganism containing a natural ingredient effective ingredient;

d) performing an ion exchange treatment using the useful microorganism containing the natural material effective ingredient of the step c.

The liquid phase useful microorganism of the step a according to the present invention is not particularly limited as long as it can achieve the object of the present invention, but it is preferable that EM (Em) is any one or more of lactic acid bacteria, yeast strain, yeast, acetic acid bacteria and photosynthetic bacteria Sugar, fructose, maltose, lactose, sucrose, honey, sugar, tallow, oligosaccharide, fructose, sugar, sugar, glucose, molasses, sugar and the like as a food source. Such liquid-phase useful microorganisms can be obtained by purchasing commercially available EMs, culturing them as they are or using the method of producing a useful microbial distillation culture of Korean Patent Application No. 10-2014-10-2014-0016440, 10-2014-0016430, a method for producing a microorganism fermented beverage in Korean Patent Application No. 10-2014-10-2014-0016461, a method for producing a fermented beverage using the herb medicine and Korean cabbage in Korean Patent No. 10-1268079 It is possible to obtain a useful microorganism in liquid form prepared by the technique of the method for producing a useful microorganism such as the method for producing the useful microorganism according to claim 1, step b of the composition for food additive and the method for producing the same.

The commercially available EM1 and the like can be used, for example, by purchasing a product manufactured by Evermiracle in Jeonju University and using it as it is or culturing it. As an example of a method of culturing EM1; The remainder of the mixture was added to the fermentation tank in an amount of 0.5 to 30%, 0.5 to 10%, 0.5 to 2%, 0.5 to 2%, and 0.5 to 10% of useful microorganisms (manufactured by Evermirac) Is fermented at a temperature of 28 to 30 DEG C for 7 to 30 days, and when the fermentation is completed, the fermented product is filtered using a broad-leaved bed or the like as a filter to obtain a liquid useful microorganism. Such EM1 culture medium or EM1 stock solution is suitable for use in the material of the useful microorganism of the present invention. Particularly, the useful microorganisms obtained by the method of producing useful microorganisms using the fermented food of Patent Application No. 10-2014-10-2014-0016430 and the method of the Japanese Patent Application No. 10-2014-10-2014-0016461, It is more suitable because it has no irritation to skin when used as a useful microorganism of the present invention.

The natural material of step (b) according to the present invention may be at least one selected from ginger, green tea leaf, burdock, onion, citrus, and sumac.

The ginger contains a large amount of threonine and thus plays a role in decomposing vegetable or vegetable fats.

The green tea leaf contains a large amount of catechin (threonine), and plays a role of decomposing vegetable or vegetable fats.

The onion contains a large amount of a component called emulsified profile, and plays a role of decomposing vegetable or vegetable fats.

The citrus fruits contain a large amount of flavonoid components and thus serve to decompose vegetable or vegetable fats.

The Rhus verniciflua contains a large amount of urushiol, which is responsible for decomposing vegetable or vegetable fats.

The above-mentioned burdock contains a large amount of saponin component, and plays a role of decomposing vegetable or vegetable fats.

Natural materials such as ginger, green tea leaves, burdock, onion, citrus, and lacquer are not only harmful to human body but also contain substances with excellent fat decomposition ability of vegetable or vegetable. However, it is preferable to use the lacquer tree because of the toxicity of the lacquer, or to choose the modified lacquer tree without toxicity.

These natural materials may be used as such, washed, dried, cut, crushed, ground, crushed, pressed, heated, liquid, The present invention can be applied to the present invention without being limited to the shape and the shape. Of course, these natural materials should be prepared hygienically.

In addition to the above, any one or more selected from lecithin and burdock, which are soybean extracts that degrade fat, may be selected and added.

The amount of these additives should be controlled at 1 to 50% of the total weight of the composition, and it is of course added so as not to interfere with the detergent effect.

The step c according to the present invention may be carried out by mixing the liquid microorganism obtained in the step a with the natural microorganism prepared in the step b and fermenting the microorganism so that the active ingredient contained in the natural material is extracted and fermented by the liquid microorganism, Is a step of producing a useful microorganism containing an active ingredient of the material.

The content of the natural material to be mixed with the useful microorganisms in the liquid phase is not limited as long as it can sufficiently mix with the useful microorganisms in the liquid phase. However, the proportion of the natural materials mixed in the liquid microorganism is appropriately adjusted within the range of 1 to 80% As well as natural materials, it should be chosen accordingly.

For example, when the dried natural material is mixed too much, the dry natural material absorbs the useful microorganisms in the liquid phase, so that the proportion of the dry natural material can not be mixed with the whole of the dry natural material, or the content of the natural material is too low It is not recommended that the amount of active ingredient extracted by adjustment is too small.

Particularly, when the natural material is mixed with the useful microorganisms in a liquid phase, the content of the liquid natural material is 5 to 80%, preferably 5 to 50%, and preferably 10 to 20% The ratio can be determined within the range. In particular, it is desirable that the concentration of the high concentrate should be adjusted to 20% or less.

Subsequently, the composition in which the beneficial microorganism in liquid form is mixed with the natural material is fermented at a temperature of 20 to 40 캜, preferably 25 to 35 캜, more preferably 30 to 32 캜, indoors so that the active ingredient contained in the natural material And the extract is fermented.

In the fermentation process, the composition continuously bubbles in the fermentation tank after 36-48 hours from the start of fermentation, and gas is continuously produced. In order to protect itself from external bacteria after 3 to 4 days, do. At this time, the composition may be maintained in a state where the lid of the fermentation tank is closed, but the anaerobic fermentation may be continued. However, the lid of the fermentation tank should be opened for at least one time in 1-3 days to evacuate gas or stir once more, When oxygen is supplied and aerobically fermented, more intensive fermentation proceeds.

The fermentation period is somewhat different depending on the content of the selected natural material or the natural material type, the fermentation temperature and the fermentation method, and is about 10 to 6 months. However, if necessary, the fermentation period may be shortened or extended.

The resultant product is extracted without damaging the active ingredient possessed by the natural material, and at the same time, the active ingredient is decomposed by the action of the useful microorganism, and the new ingredient is synthesized, and thus, it has an excellent effect as a detergent. Of course, these results are superior to the extracts extracted by the hydrothermal extraction method, so that they are not spoiled for a long time even in a natural state, and are harmless to the human body.

The step (d) according to the present invention is a step of ion-exchanging the useful microorganism containing the effective ingredient of the natural material in the step (c).

The ion exchange treatment of the useful microorganism containing the active ingredient of the natural material is not particularly limited, and an ion exchange solution is obtained by an ion exchange method, and an ion exchange resin, an ion exchange membrane, or the like, Is selectively removed by adsorption to obtain an ion exchange liquid. Further, useful microorganisms containing an effective component of a natural material subjected to an ion exchange treatment can obtain an ion exchange solution which is increasingly transparent by repeating the ion exchange treatment at least once.

The beneficial microorganism containing the ion-exchanged natural material effective component thus obtained is much more tinted or transparent in color than before the ion exchange treatment, without damaging the inherent microbial component containing the effective ingredient of the natural material.

Useful microorganisms containing such an ion-exchanged natural material effective ingredient have the advantage of being able to prevent pigmentation of useful microorganisms containing natural ingredients effective ingredients in advance when using white laundry.

Hereinafter, the present invention will be described more specifically with reference to Examples and Experimental Examples. However, the technical scope of the present invention is not limited to these.

Example

Example 1

(1) Processes for obtaining useful microorganisms

The fermented product was fermented for 30 days at 25 ~ 32 ℃ and mixed with 0.3L of fermented soybean paste, fermented for 3 ~ The lid of the closed fermenter was opened and stirred with a rod and discharged through a single fine hole (diameter 0.2 mm) formed in the lid of the fermentation tank to discharge the gas generated in the closed fermenter. The fermented useful microorganisms were filtered by using a broad-leaved filter as a filter to obtain about 15 L of a fermented soybean miscellaneous microorganism extracted and cultured in doenjang.

(2) Natural material preparation process

The ginger was washed and ground with a grinder to prepare 10 L of ginger dressing.

(3) Natural detergent manufacturing process

10 L of the liquid fermented soybean miscellaneous microorganism obtained in the step of obtaining the beneficial microorganism and 10 L of the ginger fermented product prepared in the natural material preparation ball were mixed in a fermenter and then closed at the entrance of the fermenter with a lid to perform fermentation at a temperature of 25 to 32 캜 for 3 months The fermented product was taken out from the fermentation tank on the end of fermentation, and 18 liters of natural detergent containing ginger - effective component of gum brown was prepared using the ginkgo as a filter.

Example 2

(4) a step of obtaining the ion-exchanged natural detergent by ion-exchanging the natural detergent of Example 1

The water tank containing the natural detergent of Example 1 and the first ion exchange resin filter are attached to the suction port. The outlet port is connected to the water filter and the first pipeline, and the water filter and the water filter are composed of a first stage sediment filter, Filter → three-stage UF filter post → four-stage post-carbon filter, the water filter inlet is connected to the first pipeline, and the water filter outlet is connected to the second pipeline. And the second ion exchange resin filter is connected to the second pipeline. The process of ion exchange treatment of the natural detergent of Example 1 using such an ion exchange treatment apparatus is as follows.

First, 8 liters of the natural detergent of Example 1, which is colored brown, is filled in a water bath. Then, the natural detergent of Example 1 of the water tank filled in the water tank is sucked into the suction port through the first ion exchange resin filter mounted on the underwater motor intake port. At this time, the natural detergent of Example 1 becomes the ion-exchange natural detergent which is subjected to the primary ion exchange treatment through the first ion exchange resin filter. The natural detergent, which has been subjected to the first ion exchange treatment, is transferred to the water filter through the first pipeline connected to the underwater motor outlet through the underwater motor outlet. In the water filter, the natural detergent, which is subjected to the first ion exchange treatment, is sequentially filtered through the first stage sediment filter, the second stage free carbon filter, the third stage UF filter post, and the fourth stage post carbon filter. And then subjected to a secondary ion exchange treatment. As a result, the obtained natural detergent, which is an ion exchange liquid, was in a state in which the color was removed to some extent without damaging the inherent effective ingredient.

And, as the natural detergent for the secondary ion exchange treatment was repeatedly performed the same method 5 times more, 6L of a natural detergent as a transparent ion exchange liquid was obtained.

Experimental Example

(1) Visual sensory test for storage stability of natural detergents

Experimental Example 1

The natural detergent formulation of Example 1, 500 g of ginger, and 2 L of water were placed in a kettle, and the first formulation of hot-water extract, which was hot-water-extracted at a temperature of 100 ° C. or higher, was filled into a 1.5 L transparent PET bottle, From the beginning of July to the middle of September) It was left for 72 days in a sunny house at 25 ~ 45 ℃ and visually observed when the mold was formed on the upper surface of each formulation. The results of one sensory test are shown in Table 1 below.

  division     When the blue fungus is generated (as of the start date of the experiment) The first formulation             5 days The natural detergent formulation of Example 1        Not observed during the experiment

Observations: Each formulation was observed at least once on days 1-10.

<Result>

As a result of comparing the degree of corruption after visual observation of the time when the blue mold was formed on the upper surface of each formulation, the degree of corruption was visually observed. As a result, in the first formulation, blue mold was visually observed However, in the natural detergent formulation of Example 1 manufactured by the technique of the present invention, no blue mold was observed until the end of the experiment, and thus it was found that the preservative was very excellent.

For reference, blue mold was formed in the formulation and spread to the whole membrane. Soon afterwards, it was possible to confirm smell of human feces in a similar manner. Of course, corrupt formulations can not be used as detergents.

(2) Sensory test for dishwashing power

Experimental Example 2

Table 2 shows the results of the sensory test in which the natural detergent formulations of Example 1 were put in a small spray bottle, and the impregnating ability including animal fat was measured by spraying on a surface of a frying pan on which beef was baked and wiping with a tissue paper.

division
           Measuring dishwashing force   Measurement of impurity removal including animal fat The natural detergent formulation of Example 1 5

1) The number is the average of three experiments

2) Acceptance criteria; 5; Very good, 4; Good, 3; Usually, 2; Poor, 1: Very bad

<Result>

The natural detergent formulation of Example 1 was used as a detergent to measure the impurity removing power including animal fats. As a result, the impurities including animal fats buried in the dishware were cleanly removed and the dishwashing detergent was suitable. Good.

Particularly, the natural detergent formulations of Example 1 above would be suitable for washing dishware without water in a place where it is difficult to obtain water (for example, when it is acidic or when tap water is singled) I think. Furthermore, the natural detergent of Example 1 is washed and then the bacteria that may remain in the tableware are decomposed and sterilized, so that the smell is not generated, and the surface of the tableware is coated to prevent water scarcely.

(3) Sensory evaluation of detergency of laundry

Experiment 3

The infant clothes worn were immersed in a dilution of the formulation of Example 2 and water diluted at a ratio of 1: 2 for 1 hour, cleaned with tap water, dried naturally and then washed with white colored underwear After immersing the formulation of Example 2 and diluted water at a ratio of 1: 5 in water for 30 minutes, rinsing with a washing machine, followed by a dehydration process, a visual measurement of washing power against the naturally dried second laundry, The results of the sensory evaluation of the olfactory measurement on the removing power are shown in Table 3 below.

Form
  Visual measurement of cleaning power   Olfactory measurement of deodorizing power   The first laundry  The second laundry   The first laundry    The second laundry Formulation of Example 2                        5                        5                        5                         5

1) The number is the average of three experiments

2) Acceptance criteria; 5; Very good, 4; Good, 3; Usually, 2; Poor, 1: Very bad

<Result>

The visual measurement of washing power and the sensory evaluation of deodorizing power against the formulation of Example 2 were excellent as shown in Table 3.

In particular, in the case of infant clothes, it is common that the laundry washed with the chemical detergent does not completely disappear the odor such as milk feces, but it is very good because it does not remain in the first laundry using the formulation of Example 2 at all. Also, the second laundry was washed more clearly in white. This is because the formulation of Example 2 was cleanly decomposed and removed from the contamination source.

(4) Sensitivity to washing of human skin

Experimental Example 4

A person in their 20s, a person in their 50s and a person in a females, when washing their hands, washing their hands, wrapping their hair, and bathing, the formulations of Example 2 were charged into a small atomizer And the sensory test results of measuring the detergency against the transdermal tissue of the human body are shown in Table 4 below.

 Form      Measurement of detergency against dermal penetration of human body Formulation of Example 2                         5

1) The number is the average of 10 experiments

2) Acceptance criteria; 5; Very good, 4; Good, 3; Usually, 2; Poor, 1: Very bad

<Result>

As a result of measuring the detergency against the skin of the human body in everyday life such as washing the hands, washing the hands, washing the hair, bathing, etc., the formulation of Example 2 showed that the contamination sources on the skin of the human body were cleanly removed As shown in Table 4, the cleaning ability of the scalp was excellent. Especially, when applied to the scalp, the cleansing power of the scalp fat was excellent and it was found that the hair was excellent. The hair loss progression is remarkably reduced, and the skin disease is also disappearing. As a result, the rating was also excellent as shown in Table 4. Of course, no adverse effects occurred in the human body during all of the participants during use.

For reference, if the formulation of Example 2 is used for a person who has a constitution showing side effects such as hair loss, skin dryness, eczema, and athlete's foot caused by using a detergent containing a chemical ingredient, a detergent containing a chemical ingredient It is considered that the same problem as that in use is not caused.

Although specific embodiments of the method of making a natural detergent according to the present invention as described above have been illustrated and described hereinabove, the present invention is not limited by the above-described embodiments, examples and experimental examples, It will be understood by those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention as defined by the appended claims. You will have to belong.

Using the technology of the present invention, it is possible to produce a natural detergent which does not contain any chemical component at all, thereby making it possible to strategically utilize a niche market in the detergent industry field, thereby generating economic profit.

Claims (4)

a) obtaining a useful microorganism obtained by extracting useful microorganisms in a liquid phase; b) preparing at least one of natural materials such as ginger, green tea leaves, burdock, onion, citrus, and sumac; c) a microorganism of the liquid phase obtained in the step (a), at least one selected from the group consisting of ginger, green tea leaf, burdock, onion, citrus and Rhus verniciflora in a proportion of 1 to 80% Mixing and fermenting the mixture at a temperature of 20 to 40 占 폚 for 10 days to 6 months to extract an active ingredient from the liquid useful microorganism and fermenting the extract to obtain a useful microorganism containing a natural ingredient effective ingredient; and d) carrying out an ion exchange treatment using a useful microorganism containing the effective ingredient of the natural material of the step c). The method according to claim 1, wherein the ion exchange treatment in step d is carried out by repeating at least one or more ion exchange treatments of a useful microorganism containing an effective ingredient of a natural material in an ion exchange apparatus composed of an ion exchange resin, &Lt; RTI ID = 0.0 &gt; 1, &lt; / RTI &gt; A natural detergent characterized in that a natural detergent is produced by the process for producing a natural detergent according to any one of claims 1 to 2. The use of a natural detergent according to claim 3, wherein the natural detergent is applied to the cleaning of an object surface including a tableware, washing of a fabric, removal of impurities from a transdermal product, and the like.