CN110498813B - 一种含氯含磷丙烯酸酯低聚物及其制备方法 - Google Patents
一种含氯含磷丙烯酸酯低聚物及其制备方法 Download PDFInfo
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- CN110498813B CN110498813B CN201910670511.7A CN201910670511A CN110498813B CN 110498813 B CN110498813 B CN 110498813B CN 201910670511 A CN201910670511 A CN 201910670511A CN 110498813 B CN110498813 B CN 110498813B
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- acrylate
- phosphorus
- chlorine
- oligomer
- polymerization inhibitor
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 18
- 239000000460 chlorine Substances 0.000 title claims abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 16
- 239000011574 phosphorus Substances 0.000 title claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title description 11
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 36
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 7
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 5
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 14
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 14
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 7
- TUOBEAZXHLTYLF-UHFFFAOYSA-N [2-(hydroxymethyl)-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(CC)COC(=O)C=C TUOBEAZXHLTYLF-UHFFFAOYSA-N 0.000 claims description 3
- YACTZEZVNPAVGJ-UHFFFAOYSA-N P.C(=O)(O)C=C.C(=O)(O)C=C.C(=O)(O)C=C Chemical compound P.C(=O)(O)C=C.C(=O)(O)C=C.C(=O)(O)C=C YACTZEZVNPAVGJ-UHFFFAOYSA-N 0.000 claims 2
- 238000000576 coating method Methods 0.000 abstract description 21
- 239000011248 coating agent Substances 0.000 abstract description 17
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000003063 flame retardant Substances 0.000 abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000002023 wood Substances 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- HONKEGXLWUDTCF-YFKPBYRVSA-N (2s)-2-amino-2-methyl-4-phosphonobutanoic acid Chemical compound OC(=O)[C@](N)(C)CCP(O)(O)=O HONKEGXLWUDTCF-YFKPBYRVSA-N 0.000 description 1
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- 235000002687 Caesalpinia echinata Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241001424361 Haematoxylum brasiletto Species 0.000 description 1
- 101000979001 Homo sapiens Methionine aminopeptidase 2 Proteins 0.000 description 1
- 101000969087 Homo sapiens Microtubule-associated protein 2 Proteins 0.000 description 1
- 101000616438 Homo sapiens Microtubule-associated protein 4 Proteins 0.000 description 1
- 101000969594 Homo sapiens Modulator of apoptosis 1 Proteins 0.000 description 1
- 102100023174 Methionine aminopeptidase 2 Human genes 0.000 description 1
- 108090001040 Microtubule-associated protein 1B Proteins 0.000 description 1
- 102000004866 Microtubule-associated protein 1B Human genes 0.000 description 1
- 102100021794 Microtubule-associated protein 4 Human genes 0.000 description 1
- 102100021440 Modulator of apoptosis 1 Human genes 0.000 description 1
- 101100131116 Oryza sativa subsp. japonica MPK3 gene Proteins 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 101100456045 Schizosaccharomyces pombe (strain 972 / ATCC 24843) map3 gene Proteins 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4015—Esters of acyclic unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Fireproofing Substances (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
代号或术语 | 中文名称 |
PETA | 季戊四醇三丙烯酸酯,得自长兴化学 |
TPO | 2,4,6-三甲基苯甲酰基-二苯基氧化膦,得自天津久日化学 |
TMPDA | 三羟甲基丙烷二丙烯酸酯,得自利田化学 |
TMPTA | 三羟甲基丙烷三丙烯酸酯,得自长兴化学 |
TPGDA | 三丙二醇二丙烯酸酯,得自长兴化学 |
HEMQ | 对羟基苯甲醚,得自Ciba |
THQ | 甲基氢醌,得自Ciba |
611B-85 | 丙烯酸聚氨酯,得自长兴化学 |
621-80 | 环氧丙烯酸酯,得自长兴化学 |
184 | 光引发剂,得自久日化学 |
HDDA | 1.6己二醇而丙烯酸酯,得自长兴化学 |
Claims (3)
Priority Applications (1)
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CN201910670511.7A CN110498813B (zh) | 2019-07-24 | 2019-07-24 | 一种含氯含磷丙烯酸酯低聚物及其制备方法 |
Applications Claiming Priority (1)
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CN201910670511.7A CN110498813B (zh) | 2019-07-24 | 2019-07-24 | 一种含氯含磷丙烯酸酯低聚物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN110498813A CN110498813A (zh) | 2019-11-26 |
CN110498813B true CN110498813B (zh) | 2022-05-03 |
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CN201910670511.7A Active CN110498813B (zh) | 2019-07-24 | 2019-07-24 | 一种含氯含磷丙烯酸酯低聚物及其制备方法 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111848839B (zh) * | 2020-08-07 | 2022-11-29 | 深圳飞扬骏研新材料股份有限公司 | 一种无溶剂阻燃型uv树脂及其制备方法、及相应的涂料 |
CN113755071B (zh) * | 2021-09-09 | 2022-05-03 | 江南大学 | 一种光固化阻燃地板涂料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3574794A (en) * | 1968-01-22 | 1971-04-13 | Dow Chemical Co | Acrylic or methacrylic esters of hydroxyalkyl phosphate esters and process for making same |
CN101781486A (zh) * | 2010-03-11 | 2010-07-21 | 苏州市明大高分子科技材料有限公司 | 紫外光固化阻燃涂料及其制备方法 |
CN106699577A (zh) * | 2016-11-30 | 2017-05-24 | 湖南师范大学 | 新型抗静电功能单体的制备及其在uv固化涂料中的应用 |
-
2019
- 2019-07-24 CN CN201910670511.7A patent/CN110498813B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3574794A (en) * | 1968-01-22 | 1971-04-13 | Dow Chemical Co | Acrylic or methacrylic esters of hydroxyalkyl phosphate esters and process for making same |
CN101781486A (zh) * | 2010-03-11 | 2010-07-21 | 苏州市明大高分子科技材料有限公司 | 紫外光固化阻燃涂料及其制备方法 |
CN106699577A (zh) * | 2016-11-30 | 2017-05-24 | 湖南师范大学 | 新型抗静电功能单体的制备及其在uv固化涂料中的应用 |
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Address after: 313000 Liangshan Road 159, Linghu Town Industrial Function Zone, Nanxun District, Huzhou City, Zhejiang Province Applicant after: Ruitong polymer technology (Zhejiang) Co.,Ltd. Address before: 313018 No. 159, Ling Shan Road, industrial zone, Linghu Town, Nanxun District, Huzhou, Zhejiang Applicant before: ZHEJIANG RUITONG PHOTOELECTRIC MATERIAL Co.,Ltd. |
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Denomination of invention: A chlorine containing phosphorus containing acrylate oligomer and its preparation method Effective date of registration: 20230627 Granted publication date: 20220503 Pledgee: Zhejiang Nanxun Rural Commercial Bank branch Linghu Limited by Share Ltd. Pledgor: Ruitong polymer technology (Zhejiang) Co.,Ltd. Registration number: Y2023330001272 |