CN110483054B - 一种大尺寸复杂形状人造宝石工艺品的制备方法 - Google Patents
一种大尺寸复杂形状人造宝石工艺品的制备方法 Download PDFInfo
- Publication number
- CN110483054B CN110483054B CN201910854754.6A CN201910854754A CN110483054B CN 110483054 B CN110483054 B CN 110483054B CN 201910854754 A CN201910854754 A CN 201910854754A CN 110483054 B CN110483054 B CN 110483054B
- Authority
- CN
- China
- Prior art keywords
- silicon carbide
- carbon support
- placing
- slurry
- porous carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 39
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical class [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 35
- 239000002002 slurry Substances 0.000 claims abstract description 24
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 11
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000007605 air drying Methods 0.000 claims abstract description 5
- 238000009835 boiling Methods 0.000 claims abstract description 5
- 239000011204 carbon fibre-reinforced silicon carbide Substances 0.000 claims abstract description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 5
- 238000001179 sorption measurement Methods 0.000 claims abstract description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 5
- 238000005470 impregnation Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 14
- 240000009087 Crescentia cujete Species 0.000 claims description 10
- 235000005983 Crescentia cujete Nutrition 0.000 claims description 10
- 235000009797 Lagenaria vulgaris Nutrition 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 239000011863 silicon-based powder Substances 0.000 claims description 6
- 235000015895 biscuits Nutrition 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 239000011856 silicon-based particle Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 claims description 2
- 238000003763 carbonization Methods 0.000 claims description 2
- 238000010411 cooking Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000002612 dispersion medium Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 102000020897 Formins Human genes 0.000 claims 1
- 108091022623 Formins Proteins 0.000 claims 1
- 238000010000 carbonizing Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000010025 steaming Methods 0.000 abstract 1
- 239000010437 gem Substances 0.000 description 10
- 229910001751 gemstone Inorganic materials 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000005475 siliconizing Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/04—Modelling plastic materials, e.g. clay
- B44C3/046—Modelling plastic materials, e.g. clay using a modelling surface, e.g. plate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/573—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by reaction sintering or recrystallisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/428—Silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5276—Whiskers, spindles, needles or pins
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/94—Products characterised by their shape
Abstract
本发明公开了一种大尺寸复杂形状人造宝石工艺品的制备方法，取蔓藤科植物果实为原料，沸水蒸煮烘干，置于高温炉中，在真空条件下高温炭化，制得多孔碳支架，以去离子水为分散介质，加入碳化硅晶须和六偏磷酸钠或羧甲基纤维素钠为分散剂，以HCl和NaOH为调节剂调节料浆的pH值在8～10，机械搅拌配置碳化硅晶须的悬浮料浆；将多孔碳支架置于碳化硅晶须料浆中，在真空罐中抽真空，碳化硅晶须通过毛细管力和吸附作用进入碳支架内部，浸渍后通气至真空罐内至常压，取出多孔碳支架；将经碳化硅晶须料浆浸渍过的多孔碳支架置于鼓风干燥箱中烘干，制得C/SiCw素坯；本发明的有益效果是工艺简单，制造周期短，能够有效降低成本。
Description
技术领域
本发明属于人造宝石制备技术领域，涉及一种大尺寸复杂形状人造宝石工艺品的制备方法。
背景技术
碳化硅俗称金刚砂，是媲美金刚石的人造宝石品种之一，耐温2000℃以上，莫氏硬度约9.5，高于刚玉(红宝石、蓝宝石)、玛瑙和硬质合金。300℃以下可承受所有强酸强碱、包括王水的长时间腐蚀。人造宝石制造成本高、产品尺寸小，且由于硬度高，加工困难，难以生产大尺寸和形状复杂的产品，本发明另辟蹊径，以生物模板法为基础，结合浸渍法和反应烧结技术制备碳化硅材质的大尺寸复杂形状人造宝石工艺品，克服了人造宝石由于硬度高导致的加工困难问题。
发明内容
本发明的目的在于提供一种大尺寸复杂形状人造宝石工艺品的制备方法，本发明的有益效果是工艺简单，制造周期短，能够有效降低成本，提高生产效率，适合于大规模工业化生产。
本发明所采用的技术方案是取蔓藤科植物果实为原料，沸水蒸煮后，烘干制得原始生物模板，置于高温炉中，在真空条件下高温炭化，制得多孔碳支架，以去离子水为分散介质，加入碳化硅晶须，再加入六偏磷酸钠或羧甲基纤维素钠为分散剂，以HCl和NaOH为调节剂调节料浆的pH值在8-10，机械搅拌配置碳化硅晶须的悬浮料浆；将多孔碳支架置于碳化硅晶须料浆中，在真空罐中抽真空，碳化硅晶须通过毛细管力和吸附作用进入碳支架内部，浸渍后通气至真空罐内至常压，取出多孔碳支架；将经碳化硅晶须料浆浸渍过的多孔碳支架置于鼓风干燥箱中烘干，制得C/SiCw素坯；
将烘干后的素坯置于石墨坩埚中，加入单质硅粒或硅粉，置于高温炉中，抽真空，高温保温，单质硅高温熔融后通过毛细管力进入多孔坯体内部，与坯体中的碳反应形成与原始葫芦形状相同、尺寸相近的碳化硅结构；将反应后的碳化硅质产品冷却后，通过酸洗去除表面附着的单质硅，经打磨、抛光工艺处理，制得大尺寸复杂形状的人造宝石工艺品葫芦。
进一步，沸水蒸煮10min后，经80℃烘干8h制得原始生物模板；将烘干后的生物模板置于高温炉中，在真空条件下以2℃﹒min-1的升温速率升至800℃，保温1h，模板炭化后制得多孔碳支架；以去离子水为分散介质，加入以相对于溶剂的质量分数计质量分数5％-15％的碳化硅晶须，和以相对于碳化硅晶须的质量分数计质量分数为1％-2％的六偏磷酸钠或羧甲基纤维素钠为分散剂，以HCl和NaOH为调节剂调节料浆的pH值在8-10，机械搅拌30min配置碳化硅晶须的悬浮料浆；将多孔碳支架置于碳化硅晶须料浆中，在真空罐中抽真空至3000Pa以下，碳化硅晶须通过毛细管力和吸附作用进入碳支架内部，浸渍5min后通气至真空罐内至常压，取出多孔碳支架；将经碳化硅晶须料浆浸渍过的多孔碳支架置于鼓风干燥箱中，80℃烘干8h-12h，制得C/SiCw素坯；将烘干后的素坯置于石墨坩埚中，加入多孔碳支架质量2.5-3倍的单质硅粒或硅粉，置于高温炉中，抽真空至200Pa以下，以5℃﹒min-1的升温速率升至1500℃-1600℃，保温1h，单质硅高温熔融后通过毛细管力进入多孔坯体内部，与坯体中的碳反应形成与原始葫芦形状相同、尺寸相近的碳化硅结构。
附图说明
图1是实施例的实物产品示意图。
具体实施方式
下面结合具体实施方式对本发明进行详细说明。
以葫芦造型工艺品为例，选取爬藤植物葫芦的果实为原料，以生物模板法为基础，结合反应烧结技术，经蒸煮、晾干后制得原始生物模板，也可以直接以市售工艺品葫芦为原始模板，经80℃烘干8h、800℃炭化1h后形成多孔碳支架，将多孔碳支架放入碳化硅晶须料浆中真空浸渍5min后烘干，在高温炉中加入硅粉埋烧，硅粉在1410℃熔融，熔融硅在毛细管力的作用下进入多孔碳支架，与碳反应形成碳化硅结构，经腐蚀或抛光去除表面沉积的部分硅，制得与原始葫芦结构形状相同、尺寸相近的人造宝石工艺品葫芦。产品表面呈黑色，抛光后具有金属光泽；图1为实物产品。
本发明制备方法加工和制备成本低，所使用的原始模板不限于葫芦，可采用任意加工性能好的木材或其他多孔碳质材料，预先经机械加工或雕刻形成所需要的形状和尺寸，经炭化和渗硅后制得所需要的人造宝石产品。由于碳化硅材料的优异性能，本工艺制得的产品应用范围不限于工艺品，也可用于各种工业和机械结构部件、异形件，用于替代耐高温、耐腐蚀、耐磨损工况下的其他材料，提高部件性能和使用寿命。
以上所述仅是对本发明的较佳实施方式而已，并非对本发明作任何形式上的限制，凡是依据本发明的技术实质对以上实施方式所做的任何简单修改，等同变化与修饰，均属于本发明技术方案的范围内。
Claims (2)
1.一种大尺寸复杂形状人造宝石工艺品的制备方法，其特征在于：取蔓藤科植物果实为原料，沸水蒸煮后，烘干制得原始生物模板，置于高温炉中，在真空条件下高温炭化，制得多孔碳支架，以去离子水为分散介质，加入碳化硅晶须，再加入六偏磷酸钠或羧甲基纤维素钠为分散剂，以HCl和NaOH为调节剂调节料浆的pH值在8-10，机械搅拌配置碳化硅晶须的悬浮料浆；将多孔碳支架置于碳化硅晶须料浆中，在真空罐中抽真空，碳化硅晶须通过毛细管力和吸附作用进入碳支架内部，浸渍后通气至真空罐内至常压，取出多孔碳支架；将经碳化硅晶须料浆浸渍过的多孔碳支架置于鼓风干燥箱中烘干，制得C/SiCw素坯；
将烘干后的素坯置于石墨坩埚中，加入单质硅粒或硅粉，置于高温炉中，抽真空，高温保温，单质硅高温熔融后通过毛细管力进入多孔坯体内部，与坯体中的碳反应形成与原始葫芦形状相同、尺寸相近的碳化硅结构；将反应后的碳化硅质产品冷却后，通过酸洗去除表面附着的单质硅，经打磨、抛光工艺处理，制得大尺寸复杂形状的人造宝石工艺品葫芦。
2.按照权利要求1所述一种大尺寸复杂形状人造宝石工艺品的制备方法，其特征在于：所述沸水蒸煮10min后，经80℃烘干8h制得原始生物模板；将烘干后的生物模板置于高温炉中，在真空条件下以2℃﹒min-1的升温速率升至800℃，保温1h，模板炭化后制得多孔碳支架；以去离子水为分散介质，加入以相对于溶剂的质量分数计质量分数5％-15％的碳化硅晶须，和以相对于碳化硅晶须的质量分数计质量分数为1％-2％的六偏磷酸钠或羧甲基纤维素钠为分散剂，以HCl和NaOH为调节剂调节料浆的pH值在8-10，机械搅拌30min配置碳化硅晶须的悬浮料浆；将多孔碳支架置于碳化硅晶须料浆中，在真空罐中抽真空至3000Pa以下，碳化硅晶须通过毛细管力和吸附作用进入碳支架内部，浸渍5min后通气至真空罐内至常压，取出多孔碳支架；将经碳化硅晶须料浆浸渍过的多孔碳支架置于鼓风干燥箱中，80℃烘干8h-12h，制得C/SiCw素坯；将烘干后的素坯置于石墨坩埚中，加入多孔碳支架质量2.5-3倍的单质硅粒或硅粉，置于高温炉中，抽真空至200Pa以下，以5℃﹒min-1的升温速率升至1500℃-1600℃，保温1h，单质硅高温熔融后通过毛细管力进入多孔坯体内部，与坯体中的碳反应形成与原始葫芦形状相同、尺寸相近的碳化硅结构。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910854754.6A CN110483054B (zh) | 2019-09-10 | 2019-09-10 | 一种大尺寸复杂形状人造宝石工艺品的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910854754.6A CN110483054B (zh) | 2019-09-10 | 2019-09-10 | 一种大尺寸复杂形状人造宝石工艺品的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110483054A CN110483054A (zh) | 2019-11-22 |
| CN110483054B true CN110483054B (zh) | 2022-02-08 |
Family
ID=68557264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910854754.6A Active CN110483054B (zh) | 2019-09-10 | 2019-09-10 | 一种大尺寸复杂形状人造宝石工艺品的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110483054B (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115849880B (zh) * | 2022-11-29 | 2023-11-07 | 湖南圣瓷新材料有限公司 | 基于热压铸成型的陶瓷手臂的制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961493A (zh) * | 2015-06-30 | 2015-10-07 | 哈尔滨工业大学 | 一种生物质基多孔碳化硅吸波材料的制备方法 |
| CN106220227A (zh) * | 2016-08-16 | 2016-12-14 | 仇颖莹 | 一种多孔碳化硅陶瓷的制备方法 |
| CN106478121A (zh) * | 2016-09-30 | 2017-03-08 | 巩义市泛锐熠辉复合材料有限公司 | 一种碳纤维增韧碳化硅木质陶瓷的制备方法 |
| CN107778012A (zh) * | 2017-09-18 | 2018-03-09 | 山东理工大学 | 一种碳化硅复相陶瓷的制备方法 |
| CN108484210A (zh) * | 2018-06-01 | 2018-09-04 | 界首市静峰新型建材有限公司 | 一种孔隙率高的碳化硅多孔陶瓷制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04130058A (ja) * | 1990-09-20 | 1992-05-01 | Japan Metals & Chem Co Ltd | 炭化珪素ウィスカー複合炭化珪素焼結体 |
-
2019
- 2019-09-10 CN CN201910854754.6A patent/CN110483054B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961493A (zh) * | 2015-06-30 | 2015-10-07 | 哈尔滨工业大学 | 一种生物质基多孔碳化硅吸波材料的制备方法 |
| CN106220227A (zh) * | 2016-08-16 | 2016-12-14 | 仇颖莹 | 一种多孔碳化硅陶瓷的制备方法 |
| CN106478121A (zh) * | 2016-09-30 | 2017-03-08 | 巩义市泛锐熠辉复合材料有限公司 | 一种碳纤维增韧碳化硅木质陶瓷的制备方法 |
| CN107778012A (zh) * | 2017-09-18 | 2018-03-09 | 山东理工大学 | 一种碳化硅复相陶瓷的制备方法 |
| CN108484210A (zh) * | 2018-06-01 | 2018-09-04 | 界首市静峰新型建材有限公司 | 一种孔隙率高的碳化硅多孔陶瓷制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110483054A (zh) | 2019-11-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105130438B (zh) | 一种基于反应烧结制备碳化硼陶瓷复合材料的方法 | |
| CN110483054B (zh) | 一种大尺寸复杂形状人造宝石工艺品的制备方法 | |
| CN108059479B (zh) | 一种新型多孔陶瓷加热体的制备工艺 | |
| CN106380201B (zh) | 一种制备异形碳化硼陶瓷的方法 | |
| CN105506716A (zh) | 一种强结合耐磨复合涂层的制备方法 | |
| CN109694251A (zh) | 一种具有抗氧化功能的低电阻率石墨材料及其制备方法 | |
| CN109881072A (zh) | 一种硬质合金密封环及其制备方法 | |
| CN114380611A (zh) | 一种反应烧结碳化硅陶瓷研磨盘的制作方法 | |
| CN113968742B (zh) | 一种高导热高稳定性的覆铜基板及其加工工艺 | |
| CN108424146B (zh) | 一种四硼化钨基陶瓷的制备方法 | |
| CN110627504A (zh) | 碳化硼复合材料的无压烧结制备方法 | |
| CN111892414A (zh) | 一种短碳纤维增强碳化硼复合材料及其制备方法 | |
| CN110029220A (zh) | 一种两步法还原氧化铬制备金属铬粉的方法 | |
| CN109702188A (zh) | 一种金刚石工具用铜基预合金粉添加剂及其制备方法 | |
| CN113582700A (zh) | 一种低成本硼化钛陶瓷复合材料的制备方法 | |
| CN116496103B (zh) | 一种高强度、低密度碳化硅及其制备方法和应用 | |
| CN108892476A (zh) | 多孔堇青石及其制备方法和应用 | |
| CN104911384B (zh) | 一种钨基难熔碳化物复合材料的低温制备方法 | |
| CN110240483B (zh) | 一种利用晶硅废砂浆制备碳化硅多孔陶瓷的方法 | |
| EP0079903B1 (en) | Making silicon carbide bodies | |
| CN113481603B (zh) | 一种pvt法碳化硅晶体生长原料的制备方法 | |
| CN108046834A (zh) | 一种具有镶嵌结构的多孔陶瓷加热体的制备工艺 | |
| CN108975918A (zh) | 一种高韧性高温结构材料MoSi2-Mo5Si3复合陶瓷的制备 | |
| CN103465347B (zh) | 一种研磨设备中碳化硅研磨桶的制造方法 | |
| CN102034854A (zh) | 一种金刚石晶圆及其生产方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240111 Address after: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Dragon totem Technology (Hefei) Co.,Ltd. Address before: 261000 no.5600 Fenghuang Road, Mizhou street, Zhucheng City, Weifang City, Shandong Province Patentee before: WEIFANG BUSINESS VOCATIONAL College |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20240417 Address after: Room 301, No. 101, Building 3, Qianshan Commercial Center, High tech Zone, Suzhou City, Jiangsu Province, 215000 Patentee after: Suzhou Jiutian Sculpture Art Co.,Ltd. Country or region after: China Address before: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee before: Dragon totem Technology (Hefei) Co.,Ltd. Country or region before: China |