CN110478259B

CN110478259B - Application of Al-MOF material in preparation of hair and scalp cleaning products

Info

Publication number: CN110478259B
Application number: CN201910928237.9A
Authority: CN
Inventors: 曹菲; 陈英燕; 李清; 李丽玲
Original assignee: Zhuhai Siyu Biotechnology Co ltd
Current assignee: Zhuhai Siyu Biotechnology Co ltd
Priority date: 2019-09-28
Filing date: 2019-09-28
Publication date: 2020-07-07
Anticipated expiration: 2039-09-28
Also published as: CN110478259A

Abstract

The invention belongs to the field of daily cosmetics, and particularly relates to an application of an aluminum-based MOFs material in preparation of hair and scalp cleaning products. The aluminum-based MOFs material provided by the invention can be used for preparing shampoo, and comprises the following components in percentage by weight: 0.01-1% of Al-MOF material, 0.01-5% of hair conditioner, 0.01-5% of skin conditioner, 8-18% of surfactant, 0.01-5% of humectant, 0-0.3% of preservative, 0.01-0.5% of essence, 0.001-0.2% of chelating agent, 0-0.3% of pH regulator, 0.01-2.0% of dissolving agent, 0.01-2% of thickening agent, 0.01-8% of suspending agent and 52-83.9375% of deionized water. The shampoo provided by the invention has the advantages of good compatibility among the components, strong oil control capability, stable effect and no potential safety hazard, and can obviously reduce the deposition of scalp pollutant sources on the scalp.

Description

Application of Al-MOF material in preparation of hair and scalp cleaning products

Technical Field

The invention belongs to the field of daily cosmetics, and particularly relates to an application of an aluminum-based MOFs material in preparation of hair and scalp cleaning products.

Background

With the public's understanding of environmental pollution, particularly PM 2.5 inhalable particulate matter, the hazard of the pollution is also receiving increasing attention from consumers. Survey data from Mintel corporation indicate that contamination has become a third concern for consumers, 41% of consumers 20-49 years old are concerned about increasingly severe contamination problems, and understand the negative effects of contamination on health and physical appearance. The environmental pollution mainly comes from air pollution, water pollution, heavy metal pollution and the like, and comprises sulfur oxides, nitrogen oxides, carbon monoxide, ozone, volatile organic compounds and the like. When the scalp is in a polluted environment for a long time, pollutants on the scalp can stimulate organisms to generate free radicals, so that normal cells of the scalp are damaged, and the cells are accelerated to age and even die; the attachment of contaminants to the hair tends to cause the hair to dry, frizzy, dull and dull.

The Metal-Organic Frameworks (MOFs) are inorganic-Organic composite materials, which are crystalline materials with periodic network structures formed by self-assembling polydentate Organic ligands containing oxygen or nitrogen atoms and inorganic Metal ions, and are hybrid coordination polymers combining the stability of inorganic substances and the various modifiability of Organic substances. Compared with the traditional porous material, the MOFs material has the greatest characteristics of ultrahigh porosity and huge internal specific surface area, has the advantages of adjustable function, various structures, ordered pore channels, unsaturated metal sites and the like, shows huge application potential in the fields of hydrogen storage, adsorption separation, drug delivery, catalysis, ion exchange and the like, and is favored by a plurality of researchers in recent years. However, most MOFs have poor framework stability, low atomic density and completely open pore space, and have huge defects in terms of adsorption capacity and capture capacity for small molecule substances. The aluminum-based MOFs material (Al-MOF) is one of MIL-68 series materials, is synthesized for the first time by Laval tin research group represented by French scientist Farrey, and has good water stability. The structural unit is formed by mutual bridging of MO4(OH)2 octahedral structural unit and terephthalic acid organic ligand, and a network structure is formed by alternate and ordered arrangement of triangular and hexagonal pore canals with diameters of

And

to date, have beenThe Al-MOF material is mainly applied to aspects of gas storage, catalysis, liquid phase adsorption and the like. The applicant has found that Al-MOF materials possess properties which make them suitable for use in personal care products, particularly hair and scalp cleansing products, with anti-fouling efficacy. At present, no report exists on the application of the Al-MOF material in the field of personal care products.

Chinese patent application CN110102267A discloses an aluminum-based MOFs/chitosan composite microsphere and a preparation method and application thereof. The material takes an aluminum-based MOFs material MIL-68(Al) as a matrix, and the composite microsphere with the surface coated with chitosan is obtained under the joint crosslinking action of sodium alginate and chitosan, and can be used for adsorbing bisphenol A in a water body.

In conclusion, the Al-MOF material in the prior art generally has the defects of narrow application range, poor stability and easy pollution.

Disclosure of Invention

The invention aims to overcome the defects in the prior art and provides an application of an Al-MOF material in preparing hair and scalp cleaning products. The application can expand the application range of the Al-MOF material, has strong stability, no safety risk and strong oil control capability, has strong adsorption capability on scalp pollution sources such as heavy metal, harmful flora and the like, and reduces the deposition of the scalp pollution sources on the scalp.

In order to achieve the purpose, the invention adopts the technical scheme that:

application of Al-MOF material in preparing hair and scalp cleaning products.

Further, the hair and scalp cleansing product is a shampoo.

A shampoo comprises the following components in percentage by weight: 0.01-1% of Al-MOF material, 0.01-5% of oleyl polyether-5 phosphate, 0.01-5% of witch hazel extract, 0.01-0.5% of agilawood essence, 8-18% of ammonium laureth sulfate, 0-0.1% of sodium hydroxide, 0.01-5% of polyglycerol-10 laurate, 0.0015-1% of preservative, 0.001-0.2% of disodium EDTA, 0.01-2.0% of nonylphenol polyether-14, 0.01-2% of ammonium chloride, 0.01-8% of acrylate copolymer and 52.2-91.9175% of deionized water; the Al-MOF material comprises 50-55% of carbon element, 30-35% of oxygen element and 10-20% of aluminum element in percentage by weight.

Preferably, the shampoo consists of the following components in percentage by weight: 0.5% of Al-MOF material, 2.5% of oleyl polyether-5 phosphate, 2.5% of witch hazel extract, 0.25% of agilawood essence, 12% of ammonium laureth sulfate, 0.05% of sodium hydroxide, 2.5% of polyglycerol-10 laurate, 0.5% of preservative, 0.1% of disodium EDTA, 1.0% of nonylphenol polyether-14, 1.0% of ammonium chloride, 4% of acrylic acid (ester) copolymer and 73.1% of deionized water; the Al-MOF material comprises 52% of carbon element, 33% of oxygen element and 15% of aluminum element by weight.

Further, the preservative is replaced by a plant extract, and the preservative is prepared from cinnamon (cinnamon bark extract), soybean (GLYCINE MAX) seed extract, rosemary (ROSMARINUS OFFICINALIS) extract, CITRUS (CITRUS RETICULATA) peel extract, CASSIA TORA (CASSIA TORA) seed extract and Mint (MENTHAARVENSIS) extract according to the mass ratio of 48-52: 20-30: 8-12: 5-10: 3-7: 1 to 3.

Furthermore, the preservative is replaced by plant extracts, wherein the plant extracts comprise cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract in a mass ratio of 50: 25: 10: 8: 5: 2.

The invention also provides a preparation method of the shampoo, which comprises the following steps:

s1, mixing deionized water, ammonium laureth sulfate, disodium EDTA, polyglycerol-10 laurate, disodium EDTA and acrylic acid (ester) copolymer, stirring, mixing, heating to 75-85 ℃, and preserving heat for 30min after the materials are completely dissolved to obtain a mixture I;

s2, cooling the mixture I obtained in the step S1 to 40-45 ℃, adding an Al-MOF material, oleyl polyether-5 phosphate, sodium hydroxide, witch hazel extract, ammonium chloride and preservative, uniformly mixing, and fully and uniformly stirring to obtain a mixture II;

s3, adding nonylphenol polyether-14 and agilawood essence into the mixture II obtained in the step S2, mixing and stirring uniformly, and adjusting the pH value to 5.5-6.5 to obtain the agarwood essence.

Further, the stirring condition in the step S1 is 200-300 rpm, and the time is 20-30 min.

Further, the stirring condition in the step S2 is 150-250 rpm, and the time is 15-25 min.

Further, the stirring condition in the step S3 is 300-500 rpm, and the time is 30-40 min.

In the invention, Al-MOF material is creatively added into the shampoo, so that the oil control capability of the shampoo can be improved, and the added components of oleyl polyether-5 phosphate, witch hazel extract, agilawood essence, laureth ammonium sulfate and the like are mutually matched with the Al-MOF material, so that the product has good water stability and strong decontamination capability, and does not generate side effect.

Compared with the prior art, the shampoo prepared by the Al-MOF material has the following advantages:

(1) the shampoo prepared by the Al-MOF material has good water stability of the product and good compatibility of the Al-MOF material and other components in the formula;

(2) the shampoo prepared by the Al-MOF material can remarkably improve the oil control capability, clean hair and ensure that oil does not appear for a long time;

(3) the shampoo prepared by the Al-MOF material has strong adsorption effect on scalp pollution sources such as heavy metals, harmful flora, fat oxidation rancidity smell and the like, and can efficiently clean hair.

Drawings

FIG. 1 is an XRD crystal form pattern of an Al-MOF material;

FIG. 2 is a comparison of skin oil levels before and after use of example 2 and comparative example 1;

fig. 3 is a graph showing the skin oil secretion rate before and after using example 2 and comparative example 1.

Detailed Description

The present invention is further explained with reference to the following specific examples, but it should be noted that the following examples are only illustrative of the present invention and should not be construed as limiting the present invention, and all technical solutions similar or equivalent to the present invention are within the scope of the present invention. Unless otherwise specified, the technical means used in the examples are conventional means well known to those skilled in the art, and the raw materials used are commercially available products.

The Al-MOF material is in the form of dry powder or water dispersion, the preparation method of the Al-MOF material refers to a patent document (Chenghua et Al, 201710416890.8) of an aluminum-based metal organic framework @ graphene oxide composite material, and a preparation method and application thereof, and the Al-MOF material can be purchased from the innovation center of green functional daily chemical products of the southern cooperative innovation research institute; the witch hazel extract may be obtained from Zhenghe (Guangzhou) Biotechnology, Inc.; the oleyl polyether-5 phosphate ester was available from Hippon Biotech, Guangzhou; the agilawood essence can be purchased from Jiangmen and Xinxiangjing technology Limited; the acrylic copolymer is available from guangzhou megabalance trade development ltd; the skin oil tester is available from couage + khazaka (ck) of germany, model number: sebumeter SM 815.

Example 1A shampoo

The shampoo comprises the following components in percentage by weight: 0.01% of Al-MOF material, 0.01% of oleyl polyether-5 phosphate, 0.01% of witch hazel extract, 0.01% of agilawood essence, 8% of ammonium laureth sulfate, 0.01% of polyglycerol-10 laurate, 0.0015% of preservative, 0.001% of disodium EDTA, 0.01% of nonylphenol polyether-14, 0.01% of ammonium chloride, 0.01% of acrylate copolymer and 91.9175% of deionized water; the Al-MOF material comprises 50% of carbon element, 30% of oxygen element and 20% of aluminum element by weight percent; the preservative is replaced by plant extracts, and the preservative is prepared from cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract in a mass ratio of (20): 8: 5: 3: 1.

The preparation method of the shampoo comprises the following steps:

s1, mixing deionized water, ammonium laureth sulfate, disodium EDTA, polyglycerol-10 laurate, disodium EDTA and acrylic acid (ester) copolymer, stirring for 30min at 200rpm, heating to 75 ℃, and preserving heat for 30min after the materials are completely dissolved to obtain a mixture I;

s2, cooling the mixture I obtained in the step S1 to 40 ℃, adding an Al-MOF material, oleyl polyether-5 phosphate, sodium hydroxide, witch hazel extract, ammonium chloride and preservative, uniformly mixing, and stirring at 150rpm for 25min to obtain a mixture II;

s3, adding nonylphenol polyether-14 and agilawood essence into the mixture II obtained in the step S2, mixing, stirring at 300rpm for 40min, and adjusting the pH value to 5.5 to obtain the finished product.

Example 2A shampoo

The shampoo comprises the following components in percentage by weight: 0.5% of Al-MOF material, 2.5% of oleyl polyether-5 phosphate, 2.5% of witch hazel extract, 0.25% of agilawood essence, 12% of ammonium laureth sulfate, 0.05% of sodium hydroxide, 2.5% of polyglycerol-10 laurate, 0.5% of preservative, 0.1% of disodium EDTA, 1.0% of nonylphenol polyether-14, 1.0% of ammonium chloride, 4% of acrylic acid (ester) copolymer and 73.1% of deionized water; the Al-MOF material comprises 52% of carbon element, 33% of oxygen element and 15% of aluminum element by weight; the preservative is replaced by plant extracts, and the preservative is prepared from cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract in a mass ratio of 50: 25: 10: 8: 5: 2.

The preparation method of the shampoo comprises the following steps:

s1, mixing deionized water, ammonium laureth sulfate, disodium EDTA, polyglycerol-10 laurate, disodium EDTA and acrylic acid (ester) copolymer, stirring for 25min at 250rpm, heating to 80 ℃, and preserving heat for 30min after the materials are completely dissolved to obtain a mixture I;

s2, cooling the mixture I obtained in the step S1 to 43 ℃, adding an Al-MOF material, oleyl polyether-5 phosphate, sodium hydroxide, witch hazel extract, ammonium chloride and preservative, uniformly mixing, and stirring for 20min at 200rpm to obtain a mixture II;

s3, adding nonylphenol polyether-14 and agilawood essence into the mixture II obtained in the step S2, mixing, stirring at 400rpm for 35min, and adjusting the pH value to 6.0 to obtain the finished product.

Example 3A shampoo

The shampoo comprises the following components in percentage by weight: 1% of Al-MOF material, 5% of oleyl polyether-5 phosphate, 5% of witch hazel extract, 0.5% of agilawood essence, 18% of ammonium laureth sulfate, 0.1% of sodium hydroxide, 5% of polyglycerol-10 laurate, 1% of preservative, 0.2% of disodium EDTA, 0% of nonylphenol polyether-14, 2% of ammonium chloride, 8% of acrylate copolymer and 52.2% of deionized water; the Al-MOF material comprises 55% of carbon element, 35% of oxygen element and 10% of aluminum element by weight; the preservative is replaced by plant extracts, and the preservative is prepared from cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract in a mass ratio of 30: 12: 10: 7: 3, and (3).

The preparation method of the shampoo comprises the following steps:

s1, mixing deionized water, ammonium laureth sulfate, disodium EDTA, polyglycerol-10 laurate, disodium EDTA and acrylic acid (ester) copolymer, stirring for 20min at 300rpm, heating to 85 ℃, and preserving heat for 30min after the materials are completely dissolved to obtain a mixture I;

s2, cooling the mixture I obtained in the step S1 to 45 ℃, adding an Al-MOF material, oleyl polyether-5 phosphate, sodium hydroxide, witch hazel extract, ammonium chloride and preservative, uniformly mixing, and obtaining a mixture II under the condition of 250rpm for 15 min;

s3, adding nonylphenol polyether-14 and agilawood essence into the mixture II obtained in the step S2, mixing, stirring at 500rpm for 30min, and adjusting the pH value to 6.5 to obtain the finished product.

Comparative example 1A shampoo

The shampoo comprises the following components in percentage by weight: 2.5 percent of oleyl polyether-5 phosphate, 2.5 percent of witch hazel extract, 0.25 percent of agilawood essence, 12 percent of ammonium laureth sulfate, 0.05 percent of sodium hydroxide, 2.5 percent of polyglycerol-10 laurate, 0.5 percent of preservative, 0.1 percent of EDTA disodium, 1.0 percent of nonylphenol polyether-14, 1.0 percent of ammonium chloride, 4 percent of acrylic acid (ester) copolymer and 73.6 percent of deionized water; the Al-MOF material comprises 50% of carbon element, 30% of oxygen element and 20% of aluminum element by weight percent; the preservative is replaced by plant extracts, and the preservative is prepared from cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract according to the mass ratio of 50: 25: 10: 8: 5: 2 ratio of the components.

The shampoo was prepared in a manner similar to that of example 2;

the difference from example 2 is that comparative example 1 does not contain Al-MOF material.

Comparative example 2A shampoo

The shampoo comprises the following components in percentage by weight: 0.5% of Al-MOF material, 2.5% of oleyl polyether-5 phosphate, 2.5% of witch hazel extract, 0.25% of agilawood essence, 12% of ammonium laureth sulfate, 0.05% of sodium hydroxide, 2.5% of polyglycerol-10 laurate, 0.5% of preservative, 1.0% of nonylphenol polyether-14, 1.0% of ammonium chloride, 4% of acrylic acid (ester) copolymer and 73.2% of deionized water; the Al-MOF material comprises 52% of carbon element, 33% of oxygen element and 15% of aluminum element by weight; the preservative is replaced by plant extracts, and the preservative is prepared from cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract and mint extract according to the mass ratio of 50: 25: 10: 8: 5: 2 ratio of the components.

The shampoo was prepared in a manner similar to that of example 2;

the difference from example 2 is that comparative example 2 does not contain disodium EDTA.

Experimental example 1 Al-MOF Material

1. Test samples: Al-MOF material.

2. The test method comprises the following steps: measuring the specific surface area and the pore diameter structure of the Al-MOF material, diluting the Al-MOF material into 1% aqueous dispersion with water, standing for 30 days at 48 ℃, and observing the XRD crystal form result.

3. And (3) test results: the indexes of the specific surface area and the pore diameter structure of the Al-MOF material are shown in the table 1; the XRD crystal form pattern is shown in figure 1.

TABLE 1 index of specific surface area and pore size Structure for Al-MOF materials

	S_BET(m²/g)	S_Int(m²/g)	V_Total(cm²/g)	V_Micro(cm²/g)
					Al-MOF	1280	965	0.62	0.48

As can be seen from Table 1 and FIG. 1, the specific surface area and the pore size index of the Al-MOF material selected by the invention meet the requirements of technical Specification 2015 for cosmetic safety, the XRD crystal forms have no significant difference, and the water stability is excellent.

Test example 2 shampoo stability verification

1. Test samples: shampoos prepared in examples 1-3 and comparative examples 1-2;

2. the test method comprises the following steps: the appearance and odor of the shampoo were observed at-17 deg.C, 42 deg.C, and 48 deg.C, and the results were recorded at 0 days, 10 days, 20 days, 30 days, 60 days, and 90 days, and then a group of the shampoos prepared in examples 1-3 and comparative examples 1-2 were exposed for 1-7 days, and the results were recorded at-17 deg.C and 45 deg.C, and the results on day 7.

3. And (3) test results: the appearance and odor change results are shown in Table 2, and the cold-heat cycle test results are shown in Table 3.

TABLE 2 appearance and odor profiles

TABLE 3 Cold-Heat cycling test results

Test sample	Cold and hot cycle test results (-17 ℃, 45 ℃)
		Example 1	No abnormality
Example 2	No abnormality
		Example 3	No abnormality
Comparative example 1	No abnormality
		Comparative example 2	No abnormality

As is clear from tables 2 and 3, the shampoos of examples 1-3 and comparative examples 1-2 of the present invention were stable for a long period of time under the conditions of appearance, odor, and alternate heating and cooling.

Test example 3 oil control efficacy test

1. Test samples: example 2 shampoo from comparative example 1;

2. test subjects: 10 volunteers aged 18-65 were selected and randomly divided into 2 groups of 5 persons each, with exclusion criteria: women in gestation or lactation and six months postpartum; suffering from a severe systemic disease, immunodeficiency, or autoimmune disease; the test area has been subjected to skin treatment, cosmetic or other tests that may affect the outcome; those suffering from active allergic disease; those with high constitutional sensitivity; hormone-like drugs or immunosuppressive agents have been used within a month; at present or in nearly 3 months, other tests were performed on the same site; satisfaction of either can be eliminated.

3. The test method comprises the following steps: before using the test sample, the skin oil amount was measured in parallel 2 times in the area on both sides of the scalp by using a skin oil tester, the 2 times of measurement portions were adjacent, and the average value was taken as the measurement value of the area at that time. The amount of skin oil in the corresponding area immediately after use, 4 hours after use and 8 hours after use was measured after the use of the sample, respectively, and the average was taken as the measured value in the area at that time point.

4. And (3) test results: the effect of controlling oil is reflected by the amount of skin oil and the change of the secretion rate of the amount of skin oil, and the results are shown in figure 2 and figure 3 respectively. Compared with comparative examples 1 and 2, the skin oil is reduced in 10 minutes, 4 hours and 8 hours by using the scalp and hair cleaning products containing the Al-MOF. In addition, compared with 10 minutes after the use, the oil content of the skin after 8 hours after the product containing the Al-MOF material is used is lower than that after 4 hours after the product containing the Al-MOF material is used, and the oil control of the Al-MOF material is not only quick and effective, but also has long-lasting property. As can be seen from the observation of the attached figure, the secretion rate of the skin oil quantity is obviously slowed down by using the material product containing Al-MOF.

Test example 4 sensory evaluation of Hair odor and degree of greasiness

2. test subjects: selecting 50 volunteers, randomly dividing into 5 groups of 10 persons each, and requiring that: the difference of the hair length of each volunteer is less than 1 cm;

3. the test method comprises the following steps: the shampoos prepared in examples 1 to 3 and comparative examples 1 to 2 of the present invention were used to cleanse the hair of the volunteers, and the odor level of the hair was evaluated at 4 hours, 12 hours, and 24 hours, respectively, and the control group was a group without using a cleansing product.

Evaluation criteria: no off-flavor/greasy-; mild off-flavor/greasy +; moderate odor/greasiness + +; with a severe off-flavor/greasiness + + +.

4. And (3) test results: the specific test results are shown in Table 4.

TABLE 4 degree of odor and greasy hair results

As can be seen from table 4, the scalp and hair cleansing product containing the Al-MOF material can significantly reduce the odor and greasy feeling of the scalp and hair, especially the odor degree and greasy degree are still not found after 24 hours in example 2, so that example 2 is the best example of the present invention, while in comparative examples 1-2, the effect is much worse, because the Al-MOF material adsorbed on the scalp and hair can adsorb sebum, and reduce the bad odor caused by oxidative rancidity of sebum.

Test example 5 sensory evaluation of antipruritic ability to remove dandruff

1. Test samples: shampoos prepared in examples 1-3 and comparative examples 1-2

3. the test method comprises the following steps: after the hair is moistened, the test sample provided by the invention is used for cleaning, and after the hair is dried, the dandruff removing and itching relieving effects are evaluated by using a sense organ, wherein the itching relieving effect is graded according to the starting time of the itching of the head and the degree of the itching of the head, and the dandruff removing effect is graded according to the amount and the size of the dandruff.

The evaluation period is 2 weeks, the evaluation is divided into 7 points, the 7 point is the highest point, the 1 point is the lowest point, and the higher the point is, the better the effect is. The results are shown in the table.

4. And (3) test results: the specific test results are shown in Table 5.

TABLE 5 evaluation of antidandruff and antipruritic abilities

As can be seen from table 5, the shampoos prepared in examples 1-3 of the present invention had significant antipruritic effect and anti-dandruff effect, and particularly, the shampoo prepared in example 2 group had the highest anti-dandruff effect and excellent antipruritic effect, so example 2 is the best example of the present invention. The shampoo prepared in the comparative example 1 has remarkably reduced dandruff removing and itching relieving capabilities, because the Al-MOF material adsorbed on the scalp and hair can adsorb sebum, so that the growth of malassezia is inhibited, the scalp stimulus is reduced, and the dandruff generation is inhibited.

It should be noted that the above-mentioned embodiments are only preferred embodiments of the present invention, and the present invention is not limited thereto, and although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications and equivalents can be made in the technical solutions described in the foregoing embodiments, or some technical features can be replaced. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims

1. The shampoo is characterized by comprising the following components in percentage by weight: 0.01-1% of Al-MOF material, 0.01-5% of oleyl polyether-5 phosphate, 0.01-5% of witch hazel extract, 0.01-0.5% of agilawood essence, 8-18% of ammonium laureth sulfate, 0-0.1% of sodium hydroxide, 0.01-5% of polyglycerol-10 laurate, 0.0015-1% of preservative, 0.001-0.2% of disodium EDTA, 0.01-2.0% of nonylphenol polyether-14, 0.01-2% of ammonium chloride, 0.01-8% of acrylate copolymer and 52.2-91.9175% of deionized water; the Al-MOF material comprises, by weight, 50-55% of carbon element, 30-35% of oxygen element and 10-20% of aluminum element.

2. The shampoo according to claim 1, which comprises the following components in percentage by weight: 0.5% of Al-MOF material, 2.5% of oleyl polyether-5 phosphate, 2.5% of witch hazel extract, 0.25% of agilawood essence, 12% of ammonium laureth sulfate, 0.05% of sodium hydroxide, 2.5% of polyglycerol-10 laurate, 0.5% of preservative, 0.1% of disodium EDTA, 1.0% of nonylphenol polyether-14, 1.0% of ammonium chloride, 4% of acrylic acid (ester) copolymer and 73.1% of deionized water; the Al-MOF material comprises 52% of carbon element, 33% of oxygen element and 15% of aluminum element by weight.

3. The shampoo according to claim 1, wherein the preservative is replaced with a plant extract comprising cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract, mint extract in an amount of 48 to 52 by mass: 20-30: 8-12: 5-10: 3-7: 1 to 3 ratio.

4. The shampoo of claim 3, wherein the preservative is replaced with a plant extract selected from the group consisting of cinnamon bark extract, soybean seed extract, rosemary extract, citrus peel extract, cassia tora seed extract, mint extract by mass 50: 25: 10: 8: 5: 2 ratio of the components.

5. A method of preparing the shampoo according to any of claims 1 to 4, comprising the steps of:

s1, mixing deionized water, ammonium laureth sulfate, polyglycerol-10 laurate, EDTA disodium and acrylic acid (ester) copolymer, stirring, mixing, heating to 75-85 ℃, and preserving heat for 30min after the materials are completely dissolved to obtain a mixture I;

6. The method for preparing the shampoo of claim 5, wherein the stirring conditions in the step S1 are 200-300 rpm for 20-30 min.

7. The method for preparing the shampoo of claim 5, wherein the stirring conditions in the step S2 are 150-250 rpm for 15-25 min.

8. The method for preparing the shampoo of claim 5, wherein the stirring conditions in the step S3 are 300-500 rpm for 30-40 min.