CN110478259A - A kind of Al-MOF material prepare hair, the application in scalp cleaning products - Google Patents
A kind of Al-MOF material prepare hair, the application in scalp cleaning products Download PDFInfo
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- CN110478259A CN110478259A CN201910928237.9A CN201910928237A CN110478259A CN 110478259 A CN110478259 A CN 110478259A CN 201910928237 A CN201910928237 A CN 201910928237A CN 110478259 A CN110478259 A CN 110478259A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/008—Preparations for oily hair
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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Abstract
The invention belongs to daily cosmetics fields, and in particular to a kind of aluminium base MOFs material prepare hair, the application in scalp cleaning products.Aluminium base MOFs material provided by the invention can be used for preparing a kind of shampoo, including following component and its weight percent: Al-MOF material 0.01~1%, hair conditioner 0.01~5%, skin conditioning agent 0.01~5%, surfactant 8~18%, moisturizer 0.01%~5%, preservative 0%~0.3%, essence 0.01~0.5%, chelating agent 0.001~0.2%, PH regulator 0%~0.3%, lytic agent 0.01~2.0%, thickener 0.01~2%, suspending agent 0.01%~8%, deionized water 52~83.9375%.Compatibility between shampoo each component provided by the invention is good, and oil-control ability is strong, effect stability, no security risk, can substantially reduce scalp contamination sources in the deposition of scalp.
Description
Technical field
The invention belongs to daily cosmetics fields, and in particular to a kind of aluminium base MOFs material is preparing hair, scalp cleaning
Application in product.
Background technique
With public's environmental pollution, understanding especially to 2.5 pellet of PM, hazards of pollutants also day
Concern of the benefit by consumer.Survey data from Mintel company shows that pollution has become the third-largest worry of consumer
Problem has 41% consumer to worry increasingly serious pollution problem in 20~49 years old consumer, and understands pollution to health
With negative effect caused by physical appearance.Environmental pollution mainly from air pollution, water pollution and heavy metal pollution etc., including
Such as oxysulfide, nitrogen oxides, carbon monoxide, ozone and volatile organic matter.It is chronically in pollution environment, on scalp
Pollutant can stimulate body to generate free radicals, and keep the normal cell of scalp impaired, accelerate cell senescence, or even dead；Pollutant
It is attached on hair and is easy to cause hair withered, short-tempered, dim mute.
Metal-organic framework materials (Metal-Organic Frameworks, MOFs), are a kind of inorganic-organic hybrid materials
Material, it is self-assembly of by oxygen-containing or nitrogen-atoms multiple tooth organic ligand and inorganic metal ion with periodic network structure
Crystalline material is the modifiable hydridization coordination polymer of multiplicity of a kind of stability for combining inorganic matter and organic matter.Phase
Than being exactly the porosity with superelevation and huge inner ratio surface area in the feature of traditional porous material, MOFs material maximum,
Its subfunction is adjustable, various structures, duct is orderly and possesses the advantages such as unsatuated metal site, in hydrogen storage, adsorbing separation, medicine
The fields such as object transmission, catalysis and ion exchange show huge application potential, and the exploitation of MOFs in recent years and application be not by
The favor of few researcher.But the skeleton stability of major part MOFs material is poor, atomic density is low and wide-open hole
There is huge defect in space in terms of adsorption capacity and to the capture ability of small-molecule substance.Aluminium base MOFs material (Al-
MOF it) is one of MIL-68 series material, is closed for the first time by the Antoine Lavoisier research group of representative of French scientist F é rey
At with good water stability.Its structural unit be with 2 octahedral structure unit of MO4 (OH) with terephthalic acid (TPA) is organic matches
The mutual bridging of body forms, and replaces ordered arrangement by triangle and the two kinds of duct of hexagon and forms network structure, duct
Diameter is respectivelyWithUp to the present, about the detailed of Al-MOF preparation process and method
Report and about the material water stability and application report, Al-MOF material be applied to more gas storage, catalysis and liquid
Mutually absorption etc..Applicants have discovered that characteristic possessed by Al-MOF material, is suitable for applying in personal care articles, especially
Suitable for hair, scalp cleaning products, have effects that resistant to pollution.There has been no Al-MOF materials at present leads in personal care articles
The report of domain application.
Chinese patent application CN110102267A discloses a kind of aluminium base MOFs/ chitosan compound microsphere and preparation method thereof
And application.This material is with aluminium base MOFs material MIL-68 (Al) for parent, in the common crosslinking of sodium alginate and chitosan
The complex microsphere of surface cladding chitosan is obtained under effect, this microballoon can be used for the bisphenol-A in adsorbed water body, have operation
Simple process requires appointed condition low advantage, and still, the stability of this microballoon is poor, be easy to cause pollution.
In summary, narrow about the generally existing application range of Al-MOF material in the prior art, stability is poor, be easy to cause
The shortcomings that pollution.
Summary of the invention
The purpose of the present invention is being directed to disadvantage of the existing technology, a kind of Al-MOF material is provided and is preparing hair, head
Application in skin cleaning products.The application can expand the application range of Al-MOF material, and stability is strong, no security risks,
Oil-control ability is strong, has stronger adsorption capacity to scalp pollution sources such as heavy metal, pernicious bacteria etc., reduces scalp contamination sources
In the deposition of scalp.
In order to achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of Al-MOF material prepare hair, the application in scalp cleaning products.
Further, the hair, scalp cleaning products are shampoo.
A kind of shampoo, including following component and its weight percent: Al-MOF material is 0.01~1%, oleth-
5 phosphates are 0.01~5%, and witch hazel extract is 0.01~5%, and agalloch eaglewood essence is 0.01~0.5%, laureth sulphur
Acid esters ammonium is 8~18%, and sodium hydroxide is 0%~0.1%, and Natrulon H-10 laurate is 0.01%~5%, and preservative is
0.0015%~1%, EDETATE SODIUM is 0.001~0.2%, and nonyl phenol polyethers -14 are 0.01~2.0%, ammonium chloride 0.01~
2%, acrylic acid esters co-polymer 0.01%~8%, deionized water is 52.2~91.9175%；It is each in the Al-MOF material
The weight percent of element is carbon 50~55%, oxygen element 30~35, aluminium element 10~20%.
Preferably, the shampoo is made of following component and its weight percent: Al-MOF material 0.5%, and oleyl alcohol is poly-
- 5 phosphate 2.5% of ether, witch hazel extract 2.5%, agalloch eaglewood essence 0.25%, laureth sulfuric ester ammonium are 12%, hydrogen
Sodium oxide molybdena is 0.05%, and Natrulon H-10 laurate is 2.5%, preservative 0.5%, EDETATE SODIUM 0.1%, nonyl phenol polyethers-
14 be 1.0%, ammonium chloride 1.0%, acrylic acid (ester) analog copolymer 4%, deionized water 73.1%；It is each in the Al-MOF material
The weight percent of element is carbon 52%, oxygen element 33%, aluminium element 15%.
Further, the preservative is replaced using plant extracts, is mentioned by cortex cinnamomi (CINNAMOMUM CASSIA) bark
Take object, soybean (GLYCINE MAX) seed extract, rosemary (ROSMARINUS OFFICINALIS) extract, citrus
(CITRUS RETICULATA) pericarp extract, little cassia tora (CASSIA TORA) seed extract, peppermint (MENTHA
ARVENSIS) extract 48~52:20 in mass ratio~30:8~12:5~10:3~7:1~3 is formed.
Further, the preservative is replaced using plant extracts, is extracted by cinnamon bark extract, soybean seed
Object, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, mint extract 50:25:10:8:5 in mass ratio:
2 compositions.
The present invention also provides the preparation methods of the shampoo, include the following steps:
S1, by deionized water, laureth sulfuric ester ammonium, EDETATE SODIUM, Natrulon H-10 laurate, EDETATE SODIUM,
Acrylic acid (ester) analog copolymer is mixed mixing and is warming up to 75~85 DEG C, after material is completely dissolved, keeps the temperature 30min, obtains mixed
Close object I；
S2, mixture I obtained by step S1 is cooled to 40~45 DEG C, is added Al-MOF material, -5 phosphate of oleth,
Sodium hydroxide, witch hazel extract, ammonium chloride, preservative are uniformly mixed, stir, obtain mixtures II；
S3, nonyl phenol polyethers -14 being added into mixtures II obtained by step S2, then agalloch eaglewood essence is mixed evenly,
Adjust pH value to 5.5~6.5 to get.
Further, the condition stirred in the step S1 is 200~300rpm, 20~30min of time.
Further, the condition stirred in the step S2 is 150~250rpm, 15~25min of time.
Further, the condition stirred in the step S3 is 300~500rpm, 30~40min of time.
In the present invention, Al-MOF material is added creatively in shampoo, the oil-control ability of shampoo can be improved, and
And -5 phosphate of oleth that the application is added, witch hazel extract, agalloch eaglewood essence, the groups such as laureth sulfuric ester ammonium
Divide and cooperate with Al-MOF material, so that product water stability is good, dirt-removing power is strong, and will not generate side effect.
Compared with prior art, the shampoo of present invention application Al-MOF material preparation has the advantage that
(1) for the present invention using the shampoo of Al-MOF material preparation, product water stability is good, in Al-MOF material and formula
Other components compatibility it is good；
(2) present invention can be obviously improved oil-control ability using the shampoo of Al-MOF material preparation, clean hair, can
It is not fuel-displaced for a long time to guarantee；
(3) shampoo that the present invention is prepared using Al-MOF material, to scalp pollution sources such as heavy metal, pernicious bacteria, oil
Lipid oxidation rancid flavor etc. has stronger suction-operated, can be with high-efficiency washing hair.
Detailed description of the invention
Fig. 1 is Al-MOF material XRD crystal form map；
Fig. 2 is to be compared using embodiment 2 and 1 front and back skin oil and fat amount of comparative example；
Fig. 3 is to use 1 front and back skin oil and fat amount secreting rate of embodiment 2 and comparative example.
Specific embodiment
The present invention is further explained combined with specific embodiments below, it is noted that following embodiment is only
To explain the present invention, and it cannot be used to limit the present invention, all technical solutions same or similar with the present invention are in this hair
Within bright protection scope.Unless otherwise specified, what technological means used in embodiment was well known to those skilled in the art
Conventional means, raw materials used is commercial goods.
The Al-MOF material shape be dry powder or aqueous dispersions, preparation method referenced patent file (Cheng Jianhua etc.,
201710416890.8) a kind of aluminium based metal organic backbone@graphene oxide composite material and its preparation method and application, are purchased from China
Southern collaborative innovation research institute green functional daily chemical products innovation center；The witch hazel extract is purchased from positive standing grain (Guangzhou) biology
Co., Ltd, Science and Technology Ltd.；- 5 phosphate of oleth is purchased from Guangzhou Hui Lang Biotechnology Co., Ltd；It is described
Agalloch eaglewood essence is purchased from Jiangmen Hexin Essence Technology Co., Ltd.；Acrylic acid (ester) analog copolymer is purchased from the weighing apparatus of Guangzhou million
Trade Development Co., Ltd；The skin oil and fat tester is purchased from German COURAGE+KHAZAKA (CK) company, model:
Sebumeter SM815。
A kind of shampoo of embodiment 1
The shampoo is made of following component and its weight percent: Al-MOF material is 0.01%, oleth -5
Phosphate is 0.01%, witch hazel extract 0.01%, and agalloch eaglewood essence is 0.01%, and laureth sulfuric ester ammonium is 8%,
Natrulon H-10 laurate is 0.01%%, preservative 0.0015%%, EDETATE SODIUM 0.001%, nonyl phenol polyethers-
14 be 0.01%, ammonium chloride 0.01%, acrylic acid esters co-polymer 0.01%%, deionized water 91.9175%；The Al-
The weight percent of each element is carbon 50%, oxygen element 30%, aluminium element 20% in MOF material；The preservative uses
Plant extracts replace, by cinnamon bark extract, soybean seed extract, Rosmarinus officinalis extract, orange peel extract, it is small certainly
Bright seed extract, mint extract 20:8:5:3:1 in mass ratio composition.
The shampoo the preparation method comprises the following steps:
S1, by deionized water, laureth sulfuric ester ammonium, EDETATE SODIUM, Natrulon H-10 laurate, EDETATE SODIUM,
The mixing of acrylic acid (ester) analog copolymer, stirs 30min under conditions of 200rpm, and mixing is warming up to 75 DEG C, completely molten to material
Xie Hou keeps the temperature 30min, obtains mixture I；
S2, mixture I obtained by step S1 is cooled to 40 DEG C, Al-MOF material, -5 phosphate of oleth, hydrogen-oxygen is added
Change sodium, witch hazel extract, ammonium chloride, preservative is uniformly mixed, and 25min is stirred under the conditions of 150rpm, obtains mixtures II；
S3, nonyl phenol polyethers -14 are added into mixtures II obtained by step S2, then agalloch eaglewood essence mixes, in 300rpm
Under conditions of stir 40min, adjust pH value to 5.5 to get.
A kind of shampoo of embodiment 2
The shampoo is made of following component and its weight percent: Al-MOF material 0.5%, -5 phosphoric acid of oleth
Ester 2.5%, witch hazel extract 2.5%, agalloch eaglewood essence 0.25%, laureth sulfuric ester ammonium are 12%, and sodium hydroxide is
0.05%, Natrulon H-10 laurate is 2.5%, preservative 0.5%, EDETATE SODIUM 0.1%, and nonyl phenol polyethers -14 are
1.0%, ammonium chloride 1.0%, acrylic acid (ester) analog copolymer 4%, deionized water 73.1%；Each element in the Al-MOF material
Weight percent be carbon 52%, oxygen element 33%, aluminium element 15%；The preservative is replaced using plant extracts,
By cinnamon bark extract, soybean seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, peppermint
Extract 50:25:10:8:5:2 in mass ratio composition.
The shampoo the preparation method comprises the following steps:
S1, by deionized water, laureth sulfuric ester ammonium, EDETATE SODIUM, Natrulon H-10 laurate, EDETATE SODIUM,
The mixing of acrylic acid (ester) analog copolymer, stirs 25min under conditions of 250rpm, and mixing is warming up to 80 DEG C, completely molten to material
Xie Hou keeps the temperature 30min, obtains mixture I；
S2, mixture I obtained by step S1 is cooled to 43 DEG C, Al-MOF material, -5 phosphate of oleth, hydrogen-oxygen is added
Change sodium, witch hazel extract, ammonium chloride, preservative is uniformly mixed, and 20min is stirred under conditions of 200rpm, obtains mixtures II；
S3, nonyl phenol polyethers -14 are added into mixtures II obtained by step S2, then agalloch eaglewood essence mixes, in 400rpm
Under conditions of stir 35min, adjust pH value to 6.0 to get.
A kind of shampoo of embodiment 3
The shampoo is made of following component and its weight percent: Al-MOF material is 1%, -5 phosphorus of oleth
Acid esters is 5%, witch hazel extract 5%, and agalloch eaglewood essence is 0.5%, and laureth sulfuric ester ammonium is 18%, sodium hydroxide
It is 0.1%, Natrulon H-10 laurate is 5%, preservative 1%, EDETATE SODIUM 0.2%, and nonyl phenol polyethers -14 are
.0%, ammonium chloride 2%, acrylic acid esters co-polymer 8%, deionized water 52.2%；Each element in the Al-MOF material
Weight percent is carbon 55%, oxygen element 35, aluminium element 10%；The preservative is replaced using plant extracts, by meat
Cassia tree bark extract, soybean seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, peppermint are extracted
Object 30:12:10:7:3 in mass ratio composition.
The shampoo the preparation method comprises the following steps:
S1, by deionized water, laureth sulfuric ester ammonium, EDETATE SODIUM, Natrulon H-10 laurate, EDETATE SODIUM,
The mixing of acrylic acid (ester) analog copolymer, stirs 20min under conditions of 300rpm, and mixing is warming up to 85 DEG C, completely molten to material
Xie Hou keeps the temperature 30min, obtains mixture I；
S2, mixture I obtained by step S1 is cooled to 45 DEG C, Al-MOF material, -5 phosphate of oleth, hydrogen-oxygen is added
Change sodium, witch hazel extract, ammonium chloride, preservative is uniformly mixed, and the 15min under conditions of 250rpm obtains mixtures II；
S3, nonyl phenol polyethers -14 are added into mixtures II obtained by step S2, then agalloch eaglewood essence mixes, in 500rpm
Under conditions of stir 30min, adjust pH value to 6.5 to get.
A kind of shampoo of comparative example 1
The shampoo is made of following component and its weight percent: -5 phosphate 2.5% of oleth, witch hazel
Extract liquor 2.5%, agalloch eaglewood essence 0.25%, laureth sulfuric ester ammonium are 12%, sodium hydroxide 0.05%, polyglycereol-
10 laurates are 2.5%, preservative 0.5%, EDETATE SODIUM 0.1%, and nonyl phenol polyethers -14 are 1.0%, ammonium chloride 1.0%,
Acrylic acid (ester) analog copolymer 4%, deionized water 73.6%；The weight percent of each element is carbon member in the Al-MOF material
Element 50%, oxygen element 30%, aluminium element 20%；The preservative is replaced using plant extracts, by cinnamon bark extract, greatly
Beans seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, mint extract press quality 50:25:
10:8:5:2 ratio composition.
The preparation method of the shampoo is similar to Example 2；
The difference from example 2 is that not including Al-MOF material in comparative example 1.
A kind of shampoo of comparative example 2
The shampoo is made of following component and its weight percent: Al-MOF material 0.5%, -5 phosphoric acid of oleth
Ester 2.5%, witch hazel extract 2.5%, agalloch eaglewood essence 0.25%, laureth sulfuric ester ammonium are 12%, and sodium hydroxide is
0.05%, Natrulon H-10 laurate is 2.5%, preservative 0.5%, and nonyl phenol polyethers -14 are 1.0%, ammonium chloride 1.0%,
Acrylic acid (ester) analog copolymer 4%, deionized water 73.2%；The weight percent of each element is carbon member in the Al-MOF material
Element 52%, oxygen element 33%, aluminium element 15%；The preservative is replaced using plant extracts, by cinnamon bark extract, greatly
Beans seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, mint extract press quality 50:25:
10:8:5:2 ratio composition.
The preparation method of the shampoo is similar to Example 2；
The difference from example 2 is that not including EDETATE SODIUM in comparative example 2.
1 Al-MOF material of test example
1. test specimen: Al-MOF material.
2. test method: Al-MOF material with water is diluted to by the specific surface area and aperture structure of measurement Al-MOF material
1% aqueous dispersions stand 30 days under the conditions of 48 DEG C, observe XRD crystal form result.
3. test result: the specific surface area and aperture structure index of Al-MOF material are shown in Table 1；Its XRD crystal form map is shown in figure
1。
The specific surface area and aperture structure index of 1 Al-MOF material of table
| SBET(m2/g) | SInt(m2/g) | VTotal(cm2/g) | VMicro(cm2/g) | |
| Al-MOF | 1280 | 965 | 0.62 | 0.48 |
By table 1 and Fig. 1 it is found that the specific surface area and aperture index of the Al-MOF material that the present invention selects meet " cosmetics
Technical specification of security 2015 editions " requirement, and XRD crystal form, without significant difference, water stability is fabulous.
The verifying of 2 shampoo stability of test example
1. test specimen: shampoo made from embodiment 1-3 and comparative example 1-2；
2. test method: respectively at -17 DEG C, 42 DEG C, 48 DEG C of appearances for observing shampoo and smell changed, in 0 day, 10
It, 20 days, 30 days, 60 days, then 90 days record result of variations were chosen again and are washed made from one group of embodiment 1-3 and comparative example 1-2
It is become visible in 1-7 days, thermal cycling test, the 7th day log is carried out under conditions of -17 DEG C and 45 DEG C.
3. test result: appearance and smell result of variations are shown in Table 2, and thermal cycling test the results are shown in Table 3.
2 appearance of table and smell situation of change
3 thermal cycling test result of table
| Test specimen | Thermal cycling test result (- 17 DEG C, 45 DEG C) |
| Embodiment 1 | It is without exception |
| Embodiment 2 | It is without exception |
| Embodiment 3 | It is without exception |
| Comparative example 1 | It is without exception |
| Comparative example 2 | It is without exception |
As table 2, table 3 it is found that the appearance of shampoo made from 1-3 of the embodiment of the present invention and comparative example 1-2, smell and cold and hot
Under the conditions of alternate, stable state can be kept for a long time.
3 oil-control efficacy test of test example
1. test specimen: shampoo made from 2 comparative example 1 of embodiment；
2. subjects: volunteer of 10 ages of selection at 18~65 years old is randomly divided into 2 groups, and every group of 5 people exclude mark
It is quasi- are as follows: gestation or nursing period and postpartum six months women；With serious systemic disease, immune deficiency or autoimmune disease
Disease；Test zone received skin treating, beauty or other may influence the test of result；With activity anaphylactia
Person；The highly sensitive person of constitution；Hormone medicine or immunosuppressor were used in nearly one month；Present or nearly 3 middle of the month participate in
Other tests at same position；Meeting any one can be excluded.
3. test method: before using test specimen, being first measured in parallel 2 in scalp two side areas with skin oil and fat tester
Secondary skin oil and fat amount, 2 measuring points are adjacent, are averaged the measured value as the region at this time.Distinguish using after sample
Measure instantaneous after use, 8 hours corresponding region skin oil and fat amounts after 4 hours and use, were averaged as the time after use
The measured value in the point region.
4. test result: oil-control effect effect is embodied by skin oil and fat amount and the variation of skin oil and fat amount secreting rate, as a result
Such as attached drawing 2 respectively, shown in attached drawing 3.Compared with comparative example 1,2, existed using the scalp containing Al-MOF, hair cleaning products
10 minutes, 4 hours and 8 hours skin oil and fats reduce.In addition, compared in the of 10 minutes, using material containing Al-MOF after using
Skin oil and fat amount after product after 8 hours was lower than after use material product containing Al-MOF after 4 hours, illustrated Al-MOF material control
Oil is not only fast and effective, and has permanence.Attached drawing is observed it is found that using material product containing Al-MOF, skin oil and fat amount is secreted
Rate obviously slows down.
Sensory evaluation of the test example 4 to hair peculiar smell and greasy degree
1. test specimen: shampoo made from embodiment 1-3 and comparative example 1-2；
2. subjects: choosing 50 volunteers, be randomly divided into 5 groups, every group of 10 people, it is desirable that: the hair of each volunteer is long
Difference is spent less than 1cm；
3. test method: respectively using shampoo made from 1-3 of the embodiment of the present invention and comparative example 1-2, cleaning volunteer
Hair, respectively at 4h, 12h, for 24 hours evaluate hair peculiar smell degree, control group be without using cleaning products.
Evaluation criterion: free from extraneous odour/greasy-；Have slight peculiar smell/greasy+；There is moderate peculiar smell/greasy ++；There is severe
Peculiar smell/greasy +++.
4. test result: specific test result is shown in Table 4.
4 peculiar smell degree of table and the greasy result of hair
As shown in Table 4, scalp, hair cleaning products containing Al-MOF material, can significantly reduce scalp, hair it is different
Taste and greasy feeling, especially embodiment 2 peculiar smell degree and greasy degree after for 24 hours do not have still, therefore embodiment 2 is of the invention
Most preferred embodiment, and in comparative example 1-2, effect is just poor very much, this is because being adsorbed on the Al-MOF material of scalp, hair position
Material can adsorb sebum, bad smell caused by reducing because of sebum oxidative rancidity.
The sensory evaluation of 5 anti-dandruff and itching-relieving ability of test example
1. test specimen: shampoo made from embodiment 1-3 and comparative example 1-2
2. subjects: choosing 50 volunteers, be randomly divided into 5 groups, every group of 10 people, it is desirable that: the hair of each volunteer is long
Difference is spent less than 1cm；
3. test method: after hair is soaked, being cleaned with test specimen provided by the invention, sensory evaluation is utilized after drying
Anti-dandruff and antipruritic effect, wherein antipruritic effect is to itch the time of beginning according to head and degree that head is itched scores, and anti-dandruff effect is
It is scored according to the number of dandruff and size.
Evaluation cycle is 2 weeks, and evaluation is using 7 points of systems, and 7 points are best result, and 1 point is minimum point, and score more high effect is better.
As a result it is as shown in the table.
4. test result: specific test result is shown in Table 5.
5 anti-dandruff and itching-relieving merit rating of table
As shown in Table 5, shampoo made from 1-3 of the embodiment of the present invention has significant antipruritic effect and chip-removing capacity, especially
It is shampoo made from 2 groups of embodiment, and anti-dandruff effect reaches best result, and antipruritic effect is also splendid, therefore embodiment 2 is this hair
Bright most preferred embodiment.And shampoo made from comparative example 1, anti-dandruff and itching-relieving ability significantly reduce, this is because be adsorbed on scalp,
The Al-MOF material at hair position can adsorb sebum, and then inhibit the growth of chlosma, reduce scalp irritation source, suppression
The generation of dandruff is made.
Finally it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not limited to this hair
It is bright, although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still
It is possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is equally replaced
It changes.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention
Protection scope within.
Claims (10)
1. a kind of Al-MOF material prepare hair, the application in scalp cleaning products.
2. application as described in claim 1, which is characterized in that the hair, scalp cleaning products are shampoo.
3. a kind of shampoo, which is characterized in that including following component and its weight percent: Al-MOF material is 0.01~1%,
- 5 phosphate of oleth is 0.01~5%, and witch hazel extract is 0.01~5%, and agalloch eaglewood essence is 0.01~0.5%, the moon
Laureth sulfuric ester ammonium be 8~18%, sodium hydroxide be 0%~0.1%, Natrulon H-10 laurate be 0.01%~
5%, preservative is 0.0015%~1%, and EDETATE SODIUM is 0.001~0.2%, and nonyl phenol polyethers -14 are 0.01~2.0%,
Ammonium chloride 0.01~2%, acrylic acid esters co-polymer 0.01%~8%, deionized water are 52.2~91.9175%；The Al-
The weight percent of each element is carbon 50~55%, oxygen element 30~35, aluminium element 10~20% in MOF material.
4. shampoo as claimed in claim 3, which is characterized in that be made of following component and its weight percent: Al-MOF
Material 0.5%, -5 phosphate 2.5% of oleth, witch hazel extract 2.5%, agalloch eaglewood essence 0.25%, laureth sulphur
Acid esters ammonium is 12%, sodium hydroxide 0.05%, and Natrulon H-10 laurate is 2.5%, preservative 0.5%, EDETATE SODIUM
0.1%, nonyl phenol polyethers -14 are 1.0%, ammonium chloride 1.0%, acrylic acid (ester) analog copolymer 4%, deionized water 73.1%；
The weight percent of each element is carbon 52%, oxygen element 33%, aluminium element 15% in the Al-MOF material.
5. shampoo as claimed in claim 3, which is characterized in that the preservative is replaced using plant extracts, by cortex cinnamomi
Bark extract, soybean seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed extract, mint extract
By 48~52:20 of quality~30:8~12:5~10:3~7:1~3 than forming.
6. shampoo as claimed in claim 5, which is characterized in that it is characterized in that, the preservative uses plant extracts
Replace, is extracted by cinnamon bark extract, soybean seed extract, Rosmarinus officinalis extract, orange peel extract, little cassia tora seed
Object, mint extract are formed by quality 50:25:10:8:5:2 ratio.
7. a kind of preparation method of such as described in any item shampoo of claim 3~6, which comprises the steps of:
S1, by deionized water, laureth sulfuric ester ammonium, EDETATE SODIUM, Natrulon H-10 laurate, EDETATE SODIUM, propylene
Sour (ester) analog copolymer is mixed mixing and is warming up to 75~85 DEG C, after material is completely dissolved, keeps the temperature 30min, obtains mixture
I；
S2, mixture I obtained by step S1 is cooled to 40~45 DEG C, Al-MOF material, -5 phosphate of oleth, hydrogen-oxygen is added
Change sodium, witch hazel extract, ammonium chloride, preservative is uniformly mixed, stirs, obtains mixtures II；
S3, nonyl phenol polyethers -14 are added into mixtures II obtained by step S2, then agalloch eaglewood essence is mixed evenly, adjust
PH value to 5.5~6.5 to get.
8. the preparation method of shampoo as claimed in claim 7, which is characterized in that the condition stirred in the step S1 is
200~300rpm, 20~30min of time.
9. the preparation method of shampoo as claimed in claim 7, which is characterized in that the condition stirred in the step S2 is
150~250rpm, 15~25min of time.
10. the preparation method of shampoo as claimed in claim 7, which is characterized in that the condition stirred in the step S3 is
300~500rpm, 30~40min of time.
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| CN111621029A (en) * | 2020-05-29 | 2020-09-04 | 珠海市丝域生物科技有限公司 | Modified aluminum-based MOF material, preparation method and application thereof in hair products |
| CN111616984A (en) * | 2020-05-29 | 2020-09-04 | 珠海市丝域生物科技有限公司 | Antibacterial and anti-dandruff composition containing aluminum-based MOFs material, and preparation method and application thereof |
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| CN111686189A (en) * | 2020-05-25 | 2020-09-22 | 广州润峰婴儿用品有限公司 | Plant composition for treating red wind buttocks and application thereof |
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| CN111494240A (en) * | 2020-05-29 | 2020-08-07 | 珠海市丝域生物科技有限公司 | Composition containing aluminum-based MOFs material and application of composition in scalp care product |
| CN111621029A (en) * | 2020-05-29 | 2020-09-04 | 珠海市丝域生物科技有限公司 | Modified aluminum-based MOF material, preparation method and application thereof in hair products |
| CN111616984A (en) * | 2020-05-29 | 2020-09-04 | 珠海市丝域生物科技有限公司 | Antibacterial and anti-dandruff composition containing aluminum-based MOFs material, and preparation method and application thereof |
| CN111616984B (en) * | 2020-05-29 | 2022-11-01 | 珠海市丝域生物科技有限公司 | Antibacterial and anti-dandruff composition containing aluminum-based MOFs material, and preparation method and application thereof |
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