CN110325622A - 使用包含沸石混合物的催化剂裂化烃流如原油的系统和方法 - Google Patents

使用包含沸石混合物的催化剂裂化烃流如原油的系统和方法 Download PDF

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Publication number
CN110325622A
CN110325622A CN201880013291.4A CN201880013291A CN110325622A CN 110325622 A CN110325622 A CN 110325622A CN 201880013291 A CN201880013291 A CN 201880013291A CN 110325622 A CN110325622 A CN 110325622A
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China
Prior art keywords
weight
cracking catalyst
zeolite
framework
amount
Prior art date
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Pending
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CN201880013291.4A
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English (en)
Chinese (zh)
Inventor
阿伦·奇·阿卡
阿纳斯·萨利赫·阿齐利
穆塞德·塞伦·阿尔-赫拉米
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Saudi Arabian Oil Co
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Saudi Arabian Oil Co
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Publication of CN110325622A publication Critical patent/CN110325622A/zh
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/005Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084Y-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28Phosphorising
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201880013291.4A 2017-02-23 2018-02-16 使用包含沸石混合物的催化剂裂化烃流如原油的系统和方法 Pending CN110325622A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762462689P 2017-02-23 2017-02-23
US62/462,689 2017-02-23
PCT/US2018/018482 WO2018156427A1 (en) 2017-02-23 2018-02-16 Systems and methods for cracking hydrocarbon streams such as crude oils utilizing catalysts which include zeolite mixtures

Publications (1)

Publication Number Publication Date
CN110325622A true CN110325622A (zh) 2019-10-11

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CN201880013291.4A Pending CN110325622A (zh) 2017-02-23 2018-02-16 使用包含沸石混合物的催化剂裂化烃流如原油的系统和方法

Country Status (8)

Country Link
US (1) US10494574B2 (https=)
EP (1) EP3585864B1 (https=)
JP (1) JP2020509122A (https=)
KR (1) KR102574535B1 (https=)
CN (1) CN110325622A (https=)
SA (1) SA519402509B1 (https=)
SG (1) SG11201907671XA (https=)
WO (1) WO2018156427A1 (https=)

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CN116601269A (zh) * 2020-08-05 2023-08-15 沙特阿拉伯石油公司 用含有改性β沸石添加剂的催化剂体系的流化催化裂化
CN116635354A (zh) * 2020-07-23 2023-08-22 沙特阿拉伯石油公司 用改性β沸石使烯烃相互转化的方法

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US11225612B2 (en) 2020-03-27 2022-01-18 Saudi Arabian Oil Company Catalyst and process for catalytic steam cracking of heavy distillate
US20230347330A1 (en) * 2020-06-24 2023-11-02 China Petroleum & Chemical Corporation ZSM-5/Beta CORE-SHELL MOLECULAR SIEVE AND SYNTHESIS AND USE THEREOF
US11332678B2 (en) 2020-07-23 2022-05-17 Saudi Arabian Oil Company Processing of paraffinic naphtha with modified USY zeolite dehydrogenation catalyst
US11154845B1 (en) 2020-07-28 2021-10-26 Saudi Arabian Oil Company Hydrocracking catalysts containing USY and beta zeolites for hydrocarbon oil and method for hydrocracking hydrocarbon oil with hydrocracking catalysts
US11420192B2 (en) 2020-07-28 2022-08-23 Saudi Arabian Oil Company Hydrocracking catalysts containing rare earth containing post-modified USY zeolite, method for preparing hydrocracking catalysts, and methods for hydrocracking hydrocarbon oil with hydrocracking catalysts
WO2022026878A1 (en) * 2020-07-31 2022-02-03 Basf Corporation Fluid catalytic cracking catalyst composition for enhanced butylene to propylene selectivity ratio
US11370975B2 (en) 2020-09-30 2022-06-28 Saudi Arabian Oil Company Steam-enhanced catalytic cracking of hydrocarbons to produce light olefins
TW202224767A (zh) * 2020-10-01 2022-07-01 美商W R 康格雷氏公司 用於流體催化裂解的催化劑組成物及其製備方法
EP4247550A4 (en) * 2020-11-20 2024-10-23 Basf Corporation LIQUID CATALYTIC CRACKING ADDITIVE COMPOSITION FOR INCREASED BUTYLENE SELECTIVITY OVER PROPYLENE
US11230676B1 (en) 2021-01-12 2022-01-25 Saudi Arabian Oil Company Processes for producing petrochemical products from crude oil
US11618858B1 (en) 2021-12-06 2023-04-04 Saudi Arabian Oil Company Hydrodearylation catalysts for aromatic bottoms oil, method for producing hydrodearylation catalysts, and method for hydrodearylating aromatic bottoms oil with hydrodearylation catalysts
WO2024069636A1 (en) * 2022-09-27 2024-04-04 Hindustan Petroleum Corporation Limited A catalyst composition for catalytic cracking of paraffin rich feed into light olefins
US12351760B2 (en) * 2023-03-10 2025-07-08 Saudi Arabian Oil Company Modified ZSM-5 for steam enhanced catalytic cracking of crude oil to light olefins and aromatics
US12606750B2 (en) 2023-10-10 2026-04-21 Saudi Arabian Oil Company Catalyst compositions that include zeolites with different silica to alumina molar ratios
WO2025090456A1 (en) * 2023-10-27 2025-05-01 W.R. Grace & Co.-Conn. Processes for fluid catalytic cracking bio-renewable feeds

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CN116635354A (zh) * 2020-07-23 2023-08-22 沙特阿拉伯石油公司 用改性β沸石使烯烃相互转化的方法
CN116635354B (zh) * 2020-07-23 2024-12-06 沙特阿拉伯石油公司 用改性β沸石使烯烃相互转化的方法
CN116601269A (zh) * 2020-08-05 2023-08-15 沙特阿拉伯石油公司 用含有改性β沸石添加剂的催化剂体系的流化催化裂化

Also Published As

Publication number Publication date
KR20190116485A (ko) 2019-10-14
KR102574535B1 (ko) 2023-09-06
WO2018156427A1 (en) 2018-08-30
EP3585864A1 (en) 2020-01-01
SA519402509B1 (ar) 2022-11-09
JP2020509122A (ja) 2020-03-26
EP3585864B1 (en) 2024-06-05
US10494574B2 (en) 2019-12-03
US20180237702A1 (en) 2018-08-23
SG11201907671XA (en) 2019-09-27

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