CN110306339A - A kind of Chinese medicine modifying agent and the method for preparing modified cotton fiber using the modifying agent - Google Patents
A kind of Chinese medicine modifying agent and the method for preparing modified cotton fiber using the modifying agent Download PDFInfo
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- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
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Abstract
The invention discloses a kind of Chinese medicine modifying agent, are related to linen-cotton field of material preparation；The modifying agent includes the following Chinese medical extract micro mist according to weight percent: cortex dictamni 15%~25%, artemisia annua 20%~30%, the tuber of stemona 25%~35%, hill gooseberry's root skin 20%~30%.Modifying agent in the present invention does not use any chemical addition agent, and raw material is derived from the plant of nature, does not generate toxic side effect to human body, and skin-friendly is good, color is natural, and faint scent is pleasant, ecological good；Cotton fiber is handled using promotor of the invention, not only contains various effective components, but also contain tannic acid, treated, and cotton fiber is functional more preferable, and function is more longlasting.
Description
Technical field
The present invention relates to linen-cotton field of material preparation, specifically a kind of Chinese medicine modifying agent and utilization modifying agent preparation are modified
The method of cotton fiber.
Background technique
Cotton fiber is due to unique excellent property such as its soft, warming, good hygroscopicity, comfortable from ancient times to the present, always by people
Be widely employed as textile material.But cotton fiber itself easily wrinkles, purposes is single there is also such as easy mouldy, Yi Zisheng bacterium
The deficiencies of.Bacterium and acarid are widely present in nature.In life, people inevitably touch various bacteriums and
Acarid etc..Bacterium is one kind of prokaryotic micro-organisms, and shape is carefully short, and structure is simple, is mostly bred in a manner of binary fission.Bacterium
Breeding can be mushroomed out on cotton fiber textile under suitable environmental condition, given off an unpleasant smell, and by connecing
Touching spreads the disease, influences human health.Acarid belongs to the small animal of a kind of figure of Arthropoda Arachnoidea Acari,
They household textiles such as: carpet, bedding, mattress, sheet, pillow, pillowcase, or even multiply on underwear, with the sweat of people,
Secretion, exuviae bits are food, and reproduction speed is exceedingly fast.Acarid can cause a variety of diseases such as asthma, rhinitis, dermatitis, ringworm of the body, right
The health of the mankind causes to seriously endanger.
Mainly organic (synthesis) the antibiosis anti-acarien functional agent of antibiosis anti-acarien functional agent used at present, strictly speaking absolutely mostly
Number organic anti-bacterial mite-proof agent belongs to the scope of pesticide, there is certain irritation and toxic side effect, and this kind of function to human skin
Energy agent is largely to be attached to cotton fiber surface by the method for final finishing, and water-wash resistance is poor, and function persistence is bad.
Summary of the invention
The purpose of the present invention is to provide a kind of Chinese medicine modifying agent, to solve the above problems.
To achieve the above object, the invention provides the following technical scheme:
A kind of Chinese medicine modifying agent, including below according to the Chinese medical extract micro mist of weight percent: cortex dictamni 15%~25%, chrysanthemum
Wormwood artemisia 20%~30%, the tuber of stemona 25%~35%, hill gooseberry's root skin 20%~30%.
In further embodiment: including below according to the Chinese medical extract micro mist of weight percent: cortex dictamni 15%, Huang
Flower wormwood artemisia 30%, the tuber of stemona 35%, hill gooseberry's root skin 20%.
In further embodiment: the Chinese medical extract micro mist be dried to obtain by traditional Chinese medicine extyaction liquid it is micro-
Powder.
In further embodiment: the traditional Chinese medicine extyaction liquid is extracted using water extraction and alcohol precipitation method.
The pharmacological action of each traditional Chinese medicine ingredients in the Chinese medicine composition are as follows:
Cortex dictamni is the root skin of Rutaceae herbaceos perennial shaggy-fruited dittany and Dictamnus angustifolius.Mainly contain dictamine, preceding mattress in root skin
Taro alkali, shaggy-fruited dittany alcohol, fraxinellon, obakunone, limonin, cupreol, Lay oil sterol, saponin etc..With antimycotic, resist thin
Bacterium, anti-tinea bacterium and antipruritic effect；
Artemisia annua, is composite family artemisia herbaceos perennial, and principle active component is cineole, borneol, camphor, carypohyllene, different
Carypohyllene etc., extract is to enterococcus, escherichia coli, staphylococcus, Candida albicans and streptococcus fecalis, green pus bar
Bacterium, the primary Salmonella of pneumonia Crewe, hay bacillus, lichens bud pole have antibacterial activity.Simultaneously, it may have preferable desinsection, mite killing
Activity.
The tuber of stemona is the dried root of Stemonaceae plant radix stemonae sessilifoliae, Radix stemonae japonicae or radix stemonae tuberosae.The tuber of stemona is rich in a large amount of
Alkaloid and acetic acid, formic acid, malic acid, succinic acid, oxalic acid etc..Can desinsection, antipruritic, delousing, have very strong sterilization, mite killing
Effect.
Hill gooseberry is Myrtaceae, belongs to shrub, and complete stool hyoscine has promoting blood circulation and removing obstruction in channels, astringing to arrest diarrhea, the function of qi-restoratives hemostasis
Effect.Hill gooseberry's root skin is the skin of hill gooseberry root, and sweet in flavor, puckery, mild-natured, the chemical analysis such as tannic acid rich in, are very
A kind of good lasting promotor of function, meanwhile, also there is good inhibiting effect to bacterium.
A method of modified cotton fiber is prepared using above-mentioned modifying agent, comprising the following steps:
1) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber；
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 0.5~2.0g/L and is reacted, instead
Answering temperature is 50~60 DEG C, and the reaction time is 0.5~1 hour, obtains the pre- place that aldehyde group content is 0.082~0.088mmol/g
Manage cotton fiber；
3) modification:
3-1) modifying agent is added in 70 DEG C~90 DEG C deionized waters and is dissolved, the lysate that concentration is 30%~50% is made, it is right
Lysate is filtered, and obtains modification liquid, in the modification liquid dry weight of modifying agent be pre-process cotton fiber dry weight 8%~
20%；
Modification liquid 3-2) is warming up to 80 DEG C~90 DEG C, according to bath raio 1:20~30 be added pretreatment cotton fiber, 120w~
25~35 minutes accumulative, the ultrasonic treatment of stopping in every 5 minutes 10 minutes is ultrasonically treated under 240w power；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
In further embodiment: the pretreatment liquid includes deionized water, piece alkali, hydrogen peroxide and glacial acetic acid, wherein piece
The concentration of alkali is 1g~2g/L, and the concentration of hydrogen peroxide is 3g~5g/L, and the concentration of glacial acetic acid is 0.3g~0.5g/L；Pretreatment liquid
Bath raio with cotton fiber is 1:20~30.
In further embodiment: the method handled using pretreatment liquid cotton fiber are as follows: in process container
Middle addition deionized water is put into cotton fiber, piece alkali is added under room temperature and then heats to 80 DEG C, adds hydrogen peroxide and is warming up to 90 DEG C
~100 DEG C keep the temperature 30~60 minutes, cool to 70 DEG C~80 DEG C drainings, and addition glacial acetic acid is warming up to 80 after supplementing deionized water
DEG C, heat preservation drains for 20~30 minutes again, and finally supplement deionized water allows cotton fiber water in the environment of 40 DEG C~50 DEG C again
15~25 minutes are washed until neutral to get.
Compared to the prior art, beneficial effects of the present invention are as follows:
1, the modifying agent in the present invention does not use any chemical addition agent, and raw material is derived from the plant of nature, does not produce to human body
Raw toxic side effect, and skin-friendly is good, color is natural, and faint scent is pleasant, ecological good.
2, cotton fiber is handled using promotor of the invention, not only contains various effective components, but also contain tannic acid, after processing
Cotton fiber it is functional more preferable, and function is more longlasting, modified cotton fiber wash 20 times after to the inhibiting rate of staphylococcus aureus
It is 86.2%~92.5%, is 87.1%~91.3% to the inhibiting rates of Escherichia coli, the inhibiting rate to Candida albicans is 83.2%~
87.3%(GB/T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to acarid after washing 20 times
Scattering ratio be 70%~90%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
3, cotton fiber before modified is pre-processed using sodium periodate oxidation, makes the glucosyl group in cotton fiber molecule
C2, C3 two adjacent secondary hydroxy oxidations are active aldehyde radical on ring, and cotton fiber contains active aldehyde radical, can be with-NH2 ,-OH
Reaction, therefore sodium periodate oxidation treated cotton fiber can be with the macromolecular of Chinese medicament extract effective component with covalent bond
Mode is crosslinked, and " implantation " amount and function persistence of modifying agent are improved, and ultrasonication makes modifying agent " implantation "
Complexity and " implantation " amount have been got back and have further been improved.
4, modified cotton fiber preparation method of the invention, production technology is reliable for operation simple, there is unique production procedure, and
Realize function and service after cotton fiber botanical herbs are handled.
Specific embodiment
Each embodiment cited by the present invention is only to illustrate the present invention, is not used to limit the scope of the present invention.To this
Any modification apparent easy to know or change are without departure from spirit and scope of the invention made by invention.
Embodiment 1
In the embodiment of the present invention, a kind of Chinese medicine (botanical herbs) modifying agent, including below according to the traditional Chinese medicine extraction of weight percent
Object micro mist: cortex dictamni 18%, artemisia annua 32%, the tuber of stemona 30%, hill gooseberry's root skin 30%.
The Chinese medical extract micro mist is the micro mist being dried to obtain by traditional Chinese medicine extyaction liquid, wherein preparing Chinese medicine
Water extraction and alcohol precipitation method is preferably used when effective component extracting solution.
Embodiment 2
In the embodiment of the present invention, a kind of Chinese medicine (botanical herbs) modifying agent, including below according to the traditional Chinese medicine extraction of weight percent
Object micro mist: cortex dictamni 25%, artemisia annua 30%, the tuber of stemona 25%, hill gooseberry's root skin 20%.
The Chinese medical extract micro mist is the micro mist being dried to obtain by traditional Chinese medicine extyaction liquid, wherein preparing Chinese medicine
Water extraction and alcohol precipitation method is preferably used when effective component extracting solution.
Embodiment 3
In the embodiment of the present invention, a kind of Chinese medicine (botanical herbs) modifying agent, including below according to the traditional Chinese medicine extraction of weight percent
Object micro mist: cortex dictamni 22%, artemisia annua 23%, the tuber of stemona 28%, hill gooseberry's root skin 27%.
The Chinese medical extract micro mist is the micro mist being dried to obtain by traditional Chinese medicine extyaction liquid, wherein preparing Chinese medicine
Water extraction and alcohol precipitation method is preferably used when effective component extracting solution.
Embodiment 4
In the embodiment of the present invention, a kind of Chinese medicine (botanical herbs) modifying agent, including below according to the traditional Chinese medicine extraction of weight percent
Object micro mist: cortex dictamni 15%, artemisia annua 30%, the tuber of stemona 35%, hill gooseberry's root skin 20%.
The Chinese medical extract micro mist is the micro mist being dried to obtain by traditional Chinese medicine extyaction liquid, wherein preparing Chinese medicine
Water extraction and alcohol precipitation method is preferably used when effective component extracting solution.
Embodiment 5
In the embodiment of the present invention, a kind of Chinese medicine (botanical herbs) modifying agent, including below according to the traditional Chinese medicine extraction of weight percent
Object micro mist: cortex dictamni 15%, artemisia annua 30%, the tuber of stemona 25%, hill gooseberry's root skin 30%.
The Chinese medical extract micro mist is the micro mist being dried to obtain by traditional Chinese medicine extyaction liquid, wherein preparing Chinese medicine
Water extraction and alcohol precipitation method is preferably used when effective component extracting solution.
Embodiment 6
In the embodiment of the present invention, a method of modified cotton fiber is prepared, this method uses modifying agent as described in Example 1,
The following steps are included:
1) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber.
The pretreatment liquid includes deionized water, piece alkali, hydrogen peroxide and glacial acetic acid, and wherein the concentration of piece alkali is 1g/L, double
The concentration of oxygen water is 5g/L, and the concentration of glacial acetic acid is 0.3g/L；The bath raio of pretreatment liquid and cotton fiber is 1:20.
The method that cotton fiber is handled using pretreatment liquid are as follows: deionized water is added in process container, puts
Enter cotton fiber, piece alkali is added under room temperature and then heats to 80 DEG C, adds hydrogen peroxide and be warming up to 90 DEG C of heat preservations 30 minutes, cool to
70 DEG C of drainings, addition glacial acetic acid is warming up to 80 DEG C after supplementing deionized water, and heat preservation drains for 20 minutes again, and finally supplement is gone again
Ionized water allowed in the environment of 40 DEG C cotton fiber washing until neutrality until to get.
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 1.25g/L and is reacted, instead
Answering temperature is 55 DEG C, and the reaction time is 0.75 hour, obtains the pretreatment cotton fiber that aldehyde group content is 0.085mmol/g；
3) modification:
3-1) modifying agent is added in 70 DEG C of DEG C of deionized waters and is dissolved, the lysate that concentration is 30% is made, is filtered using 300 mesh
Net is filtered lysate, obtains modification liquid, and the dry weight of modifying agent is pre-process cotton fiber dry weight 8% in the modification liquid；
Modification liquid 3-2) is warming up to 80 DEG C, pretreatment cotton fiber is added according to bath raio 1:20, is ultrasonically treated under 120w power
25 minutes accumulative, stopping in every 5 minutes is ultrasonically treated 10 minutes；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
Through performance test, to Staphylococcus aureus after the washing of modified cotton fiber obtained by the method using the present embodiment 20 times
The inhibiting rate of bacterium is 86.2%, and the inhibiting rate to Escherichia coli is 87.1%, and the inhibiting rate to Candida albicans is 83.2%(GB/
T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to the scattering ratio of acarid after washing 20 times
For 70%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
Embodiment 7
In the embodiment of the present invention, a method of modified cotton fiber is prepared, this method uses modifying agent as described in Example 2,
The following steps are included:
2) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber.
The pretreatment liquid includes deionized water, piece alkali, hydrogen peroxide and glacial acetic acid, and wherein the concentration of piece alkali is 1.5g/L,
The concentration of hydrogen peroxide is 4g/L, and the concentration of glacial acetic acid is 0.4g/L；The bath raio of pretreatment liquid and cotton fiber is 1:25.
The method that cotton fiber is handled using pretreatment liquid are as follows: deionized water is added in process container, puts
Enter cotton fiber, piece alkali is added under room temperature and then heats to 80 DEG C, adds hydrogen peroxide and be warming up to 95 DEG C of heat preservations 45 minutes, cool to
75 DEG C of drainings, addition glacial acetic acid is warming up to 80 DEG C after supplementing deionized water, and heat preservation drains for 25 minutes again, and finally supplement is gone again
Ionized water allowed in the environment of 45 DEG C cotton fiber washing until neutrality until to get.
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 0.5g/L and is reacted, instead
Answering temperature is 50 DEG C, and the reaction time is 0.5 hour, obtains the pretreatment cotton fiber that aldehyde group content is 0.082mmol/g；
3) modification:
3-1) modifying agent is added in 80 DEG C of deionized waters and is dissolved, the lysate that concentration is 40% is made, uses 300 mesh filter screens
Lysate is filtered, modification liquid is obtained, the dry weight of modifying agent is pre-process cotton fiber dry weight 12% in the modification liquid；
Modification liquid 3-2) is warming up to 85 DEG C, pretreatment cotton fiber is added according to bath raio 1:25, is ultrasonically treated under 160w power
30 minutes accumulative, stopping in every 5 minutes is ultrasonically treated 10 minutes；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
Through performance test, to Staphylococcus aureus after the washing of modified cotton fiber obtained by the method using the present embodiment 20 times
The inhibiting rate of bacterium is 88.3%, and the inhibiting rate to Escherichia coli is 88.9%, and the inhibiting rate to Candida albicans is 85.1%(GB/
T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to the scattering ratio of acarid after washing 20 times
For 80%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
Embodiment 8
In the embodiment of the present invention, a method of modified cotton fiber is prepared, this method uses modifying agent as described in Example 3,
The following steps are included:
3) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber.
The pretreatment liquid includes deionized water, piece alkali, hydrogen peroxide and glacial acetic acid, and wherein the concentration of piece alkali is 2g/L, double
The concentration of oxygen water is 3g/L, and the concentration of glacial acetic acid is 0.5g/L；The bath raio of pretreatment liquid and cotton fiber is 1:30.
The method that cotton fiber is handled using pretreatment liquid are as follows: deionized water is added in process container, puts
Enter cotton fiber, piece alkali is added under room temperature and then heats to 80 DEG C, adds hydrogen peroxide and be warming up to 100 DEG C of heat preservations 60 minutes, cooling
It is drained to 80 DEG C, addition glacial acetic acid is warming up to 80 DEG C after supplementing deionized water, and heat preservation drains for 30 minutes again, finally supplements again
Deionized water allowed in the environment of 50 DEG C cotton fiber washing until neutrality until to get.
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 1.5g/L and is reacted, instead
Answering temperature is 58 DEG C, and the reaction time is 0.8 hour, obtains the pretreatment cotton fiber that aldehyde group content is 0.086mmol/g；
3) modification:
3-1) modifying agent is added in 85 DEG C of deionized waters and is dissolved, the lysate that concentration is 45% is made, uses 300 mesh filter screens
Lysate is filtered, modification liquid is obtained, the dry weight of modifying agent is pre-process cotton fiber dry weight 16% in the modification liquid；
Modification liquid 3-2) is warming up to 88 DEG C, pretreatment cotton fiber is added according to bath raio 1:28, is ultrasonically treated under 200w power
30 minutes accumulative, stopping in every 5 minutes is ultrasonically treated 10 minutes；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
Through performance test, to Staphylococcus aureus after the washing of modified cotton fiber obtained by the method using the present embodiment 20 times
The inhibiting rate of bacterium is 91.4%, and the inhibiting rate to Escherichia coli is 89.2%, and the inhibiting rate to Candida albicans is 86.5%(GB/
T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to the scattering ratio of acarid after washing 20 times
For 85%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
Embodiment 9
In the embodiment of the present invention, a method of modified cotton fiber is prepared, this method uses modifying agent as described in Example 4,
The following steps are included:
4) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber.
The pretreatment liquid includes deionized water, piece alkali, hydrogen peroxide and glacial acetic acid, and wherein the concentration of piece alkali is 1.6g/L,
The concentration of hydrogen peroxide is 4.5g/L, and the concentration of glacial acetic acid is 0.45g/L；The bath raio of pretreatment liquid and cotton fiber is 1:25.
The method that cotton fiber is handled using pretreatment liquid are as follows: deionized water is added in process container, puts
Enter cotton fiber, piece alkali is added under room temperature and then heats to 80 DEG C, adds hydrogen peroxide and be warming up to 95 DEG C of heat preservations 50 minutes, cool to
80 DEG C of drainings, addition glacial acetic acid is warming up to 80 DEG C after supplementing deionized water, and heat preservation drains for 27 minutes again, and finally supplement is gone again
Ionized water allowed in the environment of 45 DEG C cotton fiber washing until neutrality until to get.
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 2.0g/L and is reacted, instead
Answering temperature is 60 DEG C, and the reaction time is 1 hour, obtains the pretreatment cotton fiber that aldehyde group content is 0.088mmol/g；
3) modification:
3-1) modifying agent is added in 90 DEG C of deionized waters and is dissolved, the lysate that concentration is 50% is made, uses 300 mesh filter screens
Lysate is filtered, modification liquid is obtained, the dry weight of modifying agent is pre-process cotton fiber dry weight 20% in the modification liquid；
Modification liquid 3-2) is warming up to 90 DEG C, pretreatment cotton fiber is added according to bath raio 1:30, is ultrasonically treated under 240w power
35 minutes accumulative, stopping in every 5 minutes is ultrasonically treated 10 minutes；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
Through performance test, to Staphylococcus aureus after the washing of modified cotton fiber obtained by the method using the present embodiment 20 times
The inhibiting rate of bacterium is 92.5%, and the inhibiting rate to Escherichia coli is 91.3%, and the inhibiting rate to Candida albicans is 87.3%(GB/
T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to the scattering ratio of acarid after washing 20 times
For 90%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
The principle of the present invention are as follows:
1, the modifying agent in the present invention does not use any chemical addition agent, and botanical herbs functional agent and the lasting promoter source of function
In the plant of nature, toxic side effect is not generated to human body, and skin-friendly is good, color is natural, and faint scent is pleasant, ecological good.
2, cotton fiber is handled using promotor of the invention, that is, contains various effective components, and contain tannic acid, after processing
Cotton fiber it is functional more preferable, and function is more longlasting, modified cotton fiber wash 20 times after to the inhibiting rate of staphylococcus aureus
It is 86.2%~92.5%, is 87.1%~91.3% to the inhibiting rates of Escherichia coli, the inhibiting rate to Candida albicans is 83.2%~
87.3%(GB/T20944.3~2008 " the evaluation third portion of antibacterial textile performance: concussion method "), to acarid after washing 20 times
Scattering ratio be 70%~90%(GB/T24253-2009 " evaluation of the anti-mite performance of textile ").
3, cotton fiber before modified is pre-processed using sodium periodate oxidation, makes the glucosyl group in cotton fiber molecule
C2, C3 two adjacent secondary hydroxy oxidations are active aldehyde radical on ring, and cotton fiber contains active aldehyde radical, can be with-NH2 ,-OH
Reaction, therefore sodium periodate oxidation treated cotton fiber can be with the macromolecular of Chinese medicament extract effective component with covalent bond
Mode is crosslinked, and " implantation " amount and function persistence of modifying agent are improved, and ultrasonication makes modifying agent " implantation "
Complexity and " implantation " amount have been got back and have further been improved.
4, modified cotton fiber preparation method of the invention, production technology is reliable for operation simple, there is unique production procedure, and
Realize function and service after cotton fiber botanical herbs are handled.
The above, the only specific embodiment of the disclosure, but the protection scope of the disclosure is not limited thereto, it is any
Those familiar with the art can easily think of the change or the replacement in the technical scope that the disclosure discloses, and should all contain
It covers within the protection scope of the disclosure.Therefore, the protection scope of the disclosure should be subject to the protection scope in claims.
Claims (7)
1. a kind of Chinese medicine modifying agent, which is characterized in that including below according to the Chinese medical extract micro mist of weight percent: cortex dictamni
15%~25%, artemisia annua 20%~30%, the tuber of stemona 25%~35%, hill gooseberry's root skin 20%~30%.
2. Chinese medicine modifying agent according to claim 1, which is characterized in that mentioned including the Chinese medicine below according to weight percent
Take object micro mist: cortex dictamni 15%, artemisia annua 30%, the tuber of stemona 35%, hill gooseberry's root skin 20%.
3. Chinese medicine modifying agent according to claim 1, which is characterized in that the Chinese medical extract micro mist is effective by Chinese medicine
The micro mist that constituents extraction liquid is dried to obtain.
4. Chinese medicine modifying agent according to claim 3, which is characterized in that the traditional Chinese medicine extyaction liquid is mentioned using water
Alcohol deposition method extracts.
5. a kind of method that the modifying agent using as described in claim 1-4 is any prepares modified cotton fiber, which is characterized in that packet
Include following steps:
1) pre-treatment: being handled cotton fiber using pretreatment liquid, is bleached and removes deimpurity pre-treatment cotton fiber；
2) it pre-processes: pre-treatment cotton fiber being put into the sodium periodate solution that concentration is 0.5~2.0g/L and is reacted, instead
Answering temperature is 50~60 DEG C, and the reaction time is 0.5~1 hour, obtains the pre- place that aldehyde group content is 0.082~0.088mmol/g
Manage cotton fiber；
3) modification:
3-1) modifying agent is added in 70 DEG C~90 DEG C deionized waters and is dissolved, the lysate that concentration is 30%~50% is made, it is right
Lysate is filtered, and obtains modification liquid, in the modification liquid dry weight of modifying agent be pre-process cotton fiber dry weight 8%~
20%；
Modification liquid 3-2) is warming up to 80 DEG C~90 DEG C, according to bath raio 1:20~30 be added pretreatment cotton fiber, 120w~
25~35 minutes accumulative, the ultrasonic treatment of stopping in every 5 minutes 10 minutes is ultrasonically treated under 240w power；
The pretreatment cotton fiber being ultrasonically treated 3-3) is washed till neutrality with deionized water, is dried after dehydration fine to get modified cotton
Dimension.
6. the method according to claim 5 for preparing modified cotton fiber, which is characterized in that the pretreatment liquid include go from
Sub- water, piece alkali, hydrogen peroxide and glacial acetic acid, wherein the concentration of piece alkali is 1g~2g/L, and the concentration of hydrogen peroxide is 3g~5g/L, ice vinegar
The concentration of acid is 0.3g~0.5g/L；The bath raio of pretreatment liquid and cotton fiber is 1:20~30.
7. the method according to claim 6 for preparing modified cotton fiber, which is characterized in that described to utilize pretreatment liquid to cotton
The method that fiber is handled are as follows: deionized water is added in process container, is put into cotton fiber, piece alkali is added under room temperature and then rises
Temperature adds hydrogen peroxide and is warming up to 90 DEG C~100 DEG C heat preservations 30~60 minutes, cool to 70 DEG C~80 DEG C drainings, mend to 80 DEG C
Addition glacial acetic acid is warming up to 80 DEG C after filling deionized water, and heat preservation drains for 20~30 minutes again, finally supplements deionized water again
Allowed in the environment of 40 DEG C~50 DEG C cotton fiber wash 15~25 minutes until neutrality until to get.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923885A (en) * | 2019-11-29 | 2020-03-27 | 南通天虹银海实业有限公司 | Preparation method of functional traditional Chinese medicine health-care core-spun yarn based on biological extraction |
| CN111021053A (en) * | 2019-11-26 | 2020-04-17 | 杭州优标科技有限公司 | Fiber containing artemisia annua composite extract and preparation method thereof |
| CN111996796A (en) * | 2020-08-27 | 2020-11-27 | 青岛迭代新材料发展有限公司 | Antibacterial and mildewproof plant traditional Chinese medicine composition, modified fibrilia and preparation method thereof |
| CN113123122A (en) * | 2021-06-04 | 2021-07-16 | 百事基材料（青岛）股份有限公司 | Cotton macrofiber containing yucca active ingredient and preparation method thereof |
| CN113494022A (en) * | 2021-07-31 | 2021-10-12 | 百事基材料（青岛）股份有限公司 | Cotton macrofiber containing orange active component and preparation method thereof |
| CN113863004A (en) * | 2021-09-28 | 2021-12-31 | 衣拉拉集团股份有限公司 | Mosquito-repelling antibacterial plant traditional Chinese medicine essential oil composition and preparation method of cotton knitted fabric with mosquito-repelling antibacterial function |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102561058A (en) * | 2012-02-16 | 2012-07-11 | 武汉纺织大学 | Method for improving dyeing property of cotton fabric natural dye by using silk peptide |
| CN105040436A (en) * | 2015-08-22 | 2015-11-11 | 苏州正业昌智能科技有限公司 | Finishing method of antibacterial cotton fabric |
| CN108611849A (en) * | 2018-08-20 | 2018-10-02 | 顾翚 | A kind of cotton fiber modification agent, modified cotton fiber and preparation method thereof |
-
2019
- 2019-07-29 CN CN201910686252.7A patent/CN110306339A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102561058A (en) * | 2012-02-16 | 2012-07-11 | 武汉纺织大学 | Method for improving dyeing property of cotton fabric natural dye by using silk peptide |
| CN105040436A (en) * | 2015-08-22 | 2015-11-11 | 苏州正业昌智能科技有限公司 | Finishing method of antibacterial cotton fabric |
| CN108611849A (en) * | 2018-08-20 | 2018-10-02 | 顾翚 | A kind of cotton fiber modification agent, modified cotton fiber and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 戴好富，梅文莉主编: "《黎族药志（第一册）》", 31 January 2008, 中国科学技术出版社 * |
| 梅全喜主编: "《现代中药药理与临床应用手册》", 3 January 2016, 中国中医药出版社 * |
| 邱文清主编: "《常用中草药汇编 原植物彩色图鉴 下》", 31 May 2012, 中医古籍出版社 * |
| 郭岁洋主编: "《四百味药性歌括解》", 30 June 2019, 甘肃科学技术出版社 * |
Cited By (8)
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| CN111021053A (en) * | 2019-11-26 | 2020-04-17 | 杭州优标科技有限公司 | Fiber containing artemisia annua composite extract and preparation method thereof |
| CN110923885A (en) * | 2019-11-29 | 2020-03-27 | 南通天虹银海实业有限公司 | Preparation method of functional traditional Chinese medicine health-care core-spun yarn based on biological extraction |
| CN111996796A (en) * | 2020-08-27 | 2020-11-27 | 青岛迭代新材料发展有限公司 | Antibacterial and mildewproof plant traditional Chinese medicine composition, modified fibrilia and preparation method thereof |
| CN113123122A (en) * | 2021-06-04 | 2021-07-16 | 百事基材料（青岛）股份有限公司 | Cotton macrofiber containing yucca active ingredient and preparation method thereof |
| CN113494022A (en) * | 2021-07-31 | 2021-10-12 | 百事基材料（青岛）股份有限公司 | Cotton macrofiber containing orange active component and preparation method thereof |
| CN113863004A (en) * | 2021-09-28 | 2021-12-31 | 衣拉拉集团股份有限公司 | Mosquito-repelling antibacterial plant traditional Chinese medicine essential oil composition and preparation method of cotton knitted fabric with mosquito-repelling antibacterial function |
| CN113863004B (en) * | 2021-09-28 | 2024-01-26 | 衣拉拉集团股份有限公司 | Mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition and preparation method of mosquito-repellent antibacterial functional cotton knitted fabric |
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