CN113863004B - Mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition and preparation method of mosquito-repellent antibacterial functional cotton knitted fabric - Google Patents
Mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition and preparation method of mosquito-repellent antibacterial functional cotton knitted fabric Download PDFInfo
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- CN113863004B CN113863004B CN202111140859.9A CN202111140859A CN113863004B CN 113863004 B CN113863004 B CN 113863004B CN 202111140859 A CN202111140859 A CN 202111140859A CN 113863004 B CN113863004 B CN 113863004B
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- knitted fabric
- cotton knitted
- mosquito
- repellent
- essential oil
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- 239000004744 fabric Substances 0.000 title claims abstract description 181
- 229920000742 Cotton Polymers 0.000 title claims abstract description 177
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 127
- 239000000077 insect repellent Substances 0.000 title claims abstract description 127
- 239000000341 volatile oil Substances 0.000 title claims abstract description 118
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 239000003814 drug Substances 0.000 title claims abstract description 66
- 238000002360 preparation method Methods 0.000 title claims description 27
- 241000196324 Embryophyta Species 0.000 claims abstract description 72
- 244000178870 Lavandula angustifolia Species 0.000 claims abstract description 13
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims abstract description 13
- 239000001102 lavandula vera Substances 0.000 claims abstract description 13
- 235000018219 lavender Nutrition 0.000 claims abstract description 13
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims abstract description 12
- 240000006891 Artemisia vulgaris Species 0.000 claims abstract description 12
- 244000166675 Cymbopogon nardus Species 0.000 claims abstract description 11
- 235000018791 Cymbopogon nardus Nutrition 0.000 claims abstract description 11
- 244000166124 Eucalyptus globulus Species 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 38
- 239000003094 microcapsule Substances 0.000 claims description 38
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
- 239000012530 fluid Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
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- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims description 18
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- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 16
- 239000001263 FEMA 3042 Substances 0.000 claims description 16
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 16
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- AZKVWQKMDGGDSV-BCMRRPTOSA-N Genipin Chemical compound COC(=O)C1=CO[C@@H](O)[C@@H]2C(CO)=CC[C@H]12 AZKVWQKMDGGDSV-BCMRRPTOSA-N 0.000 claims description 14
- AZKVWQKMDGGDSV-UHFFFAOYSA-N genipin Natural products COC(=O)C1=COC(O)C2C(CO)=CCC12 AZKVWQKMDGGDSV-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- 229960000583 acetic acid Drugs 0.000 claims description 12
- 239000012362 glacial acetic acid Substances 0.000 claims description 12
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- 238000005406 washing Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 229940126680 traditional chinese medicines Drugs 0.000 claims description 6
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- 230000000694 effects Effects 0.000 abstract description 9
- 230000005764 inhibitory process Effects 0.000 abstract description 6
- 241000222122 Candida albicans Species 0.000 abstract description 5
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- 239000005871 repellent Substances 0.000 abstract 1
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- 241000255925 Diptera Species 0.000 description 8
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- 238000012360 testing method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 3
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- 239000008367 deionised water Substances 0.000 description 3
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- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000008041 oiling agent Substances 0.000 description 3
- 230000001846 repelling effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl acetate Chemical compound CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 208000003251 Pruritus Diseases 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IBFYXTRXDNAPMM-BVTMAQQCSA-N Geniposide Chemical compound O([C@@H]1OC=C([C@@H]2[C@H]1C(=CC2)CO)C(=O)OC)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O IBFYXTRXDNAPMM-BVTMAQQCSA-N 0.000 description 1
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- 239000005792 Geraniol Substances 0.000 description 1
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- PDSNLYSELAIEBU-UHFFFAOYSA-N Longifolene Chemical compound C1CCC(C)(C)C2C3CCC2C1(C)C3=C PDSNLYSELAIEBU-UHFFFAOYSA-N 0.000 description 1
- ZPUKHRHPJKNORC-UHFFFAOYSA-N Longifolene Natural products CC1(C)CCCC2(C)C3CCC1(C3)C2=C ZPUKHRHPJKNORC-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- FAMPSKZZVDUYOS-UHFFFAOYSA-N alpha-Caryophyllene Natural products CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- VGLLGNISLBPZNL-RBUKDIBWSA-N arborescoside Natural products O=C(OC)C=1[C@@H]2C([C@H](O[C@H]3[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O3)OC=1)=C(CO)CC2 VGLLGNISLBPZNL-RBUKDIBWSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 108010047754 beta-Glucosidase Proteins 0.000 description 1
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- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000010238 camphora Substances 0.000 description 1
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- 229940117948 caryophyllene Drugs 0.000 description 1
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
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- 235000000983 citronellal Nutrition 0.000 description 1
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- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
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- 230000001954 sterilising effect Effects 0.000 description 1
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- -1 terpene-4-alcohol Chemical compound 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/238—Tannins, e.g. gallotannic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition, which comprises the following raw materials in percentage by weight: 30-40% of citronella essential oil, 25-35% of lavender essential oil, 20-30% of mugwort essential oil and 10-15% of eucalyptus essential oil. The cotton knitted fabric prepared by the traditional Chinese medicine essential oil composition has the mosquito repellent rate of more than or equal to 73%, the mosquito repellent rate is A, and the cotton knitted fabric has extremely strong repellent effect; meanwhile, the antibacterial rate to staphylococcus aureus is more than or equal to 96.1 percent, the inhibition rate to escherichia coli is more than or equal to 93.2 percent, the inhibition rate to candida albicans is more than or equal to 85.6 percent, and the antibacterial performance is good; and after the cotton knitted fabric with the mosquito-repellent and antibacterial functions is washed for 30 times, the fabric still has better mosquito-repellent and antibacterial effects.
Description
Technical Field
The invention belongs to the field of textiles, and particularly relates to a mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition and a preparation method of a mosquito-repellent antibacterial functional cotton knitted fabric.
Background
Textile products have an irreplaceable role in the life of people and the economic development of society, and with the development of the age, people have not only met the most basic needs of life, but pursue higher quality, healthier life style.
In nature, mosquitoes are sucking insects, taking biting human skin to suck blood as a raw material, and the bitten parts can be immediately red and swollen and itchy and hard, so that people are distracted, sleep is influenced, and the working efficiency in the next day is greatly influenced. Meanwhile, the mosquito body may have various pathogenic substances, and the mosquito body is infected to a human body in a biting manner, so that the mosquito body is greatly damaged. In the living environment of human beings, various microorganisms such as bacteria and fungi exist, and under some special environments, the mass propagation of pathogenic bacteria and fungi can cause health and safety problems.
At present, the mosquito-repellent antibacterial functional agents mainly comprise two major types, one type is a synthetic mosquito-repellent antibacterial functional agent, side effects of the mosquito-repellent antibacterial functional agents are more and more developed, and negative problems are more and more generated; the other is a natural mosquito-repellent and antibacterial functional agent, wherein the natural mosquito-repellent and antibacterial functional agent is represented by a plant extract (essential oil), and the plant traditional Chinese medicine essential oil is used as a natural functional agent, is safe, nontoxic, free of side effects, friendly to human and livestock, environment-friendly, more suitable for people to meet the requirements of environment-friendly life, and has a good development prospect. Therefore, it is necessary to produce a mosquito-repellent and antibacterial plant essential oil composition, and the mosquito-repellent and antibacterial cotton knitted fabric prepared by taking the plant essential oil composition as a mosquito-repellent and antibacterial functional agent.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a mosquito-repellent and antibacterial plant traditional Chinese medicine essential oil composition and a preparation method of a cotton knitted fabric with a mosquito-repellent and antibacterial function, wherein the cotton knitted fabric prepared by adopting the traditional Chinese medicine essential oil composition has a mosquito-repellent rate of more than or equal to 73%, the mosquito-repellent rate is A, and the mosquito-repellent rate is extremely strong, and meanwhile, the cotton knitted fabric has good antibacterial performance; and after the cotton knitted fabric with the mosquito-repellent and antibacterial functions is washed for 30 times, the fabric still has better mosquito-repellent and antibacterial effects.
The specific technical scheme is as follows:
the invention provides a mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition, which comprises the following raw materials in percentage by weight:
30-40% of citronella essential oil, 25-35% of lavender essential oil, 20-30% of mugwort essential oil and 10-15% of eucalyptus essential oil.
The beneficial effects of adopting above-mentioned scheme are: the essential oil of citronella mainly comprises citronellal, geraniol, citral, citronellol and the like, and has good mosquito-repellent effect; the essential oil of Lavender contains linalool, linalool acetate, eucalyptol, lavender acetate, lavender alcohol, terpene-4-alcohol, camphora, etc., and has good mosquito repellent and antibacterial effects; the main components of the mugwort essential oil are eucalyptol, caryophyllene, camphor, juniper, longifolene and the like, and the mugwort essential oil has good sterilization and insect-repellent effects; the main component of eucalyptus essential oil is terpenoid and oxygen-containing derivative thereof, and has the effects of killing insects, expelling mosquitoes, relieving itching and resisting bacteria; after the four components are combined according to the proportion, the material has obvious synergistic effect, and can greatly improve the mosquito-repellent and antibacterial effects of the material; the plant traditional Chinese medicine essential oil composition belongs to a natural functional agent, is safe, nontoxic, free of side effects, friendly to human and livestock, environment-friendly and more suitable for people to meet the requirements of environment-friendly life.
The second aim of the invention is to provide the application of the plant traditional Chinese medicine essential oil composition in the field of mosquito-repellent and antibacterial cotton knitted fabrics.
The third object of the invention is to provide a preparation method of a plant traditional Chinese medicine mosquito-repellent antibacterial cotton knitted fabric, which uses the plant traditional Chinese medicine essential oil composition, and comprises the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
preparing the plant traditional Chinese medicine essential oil composition as a core material and melamine resin as a wall material into microcapsules;
(2) Scouring treatment of cotton knitted fabric:
boiling the cotton knitted fabric in boiling-off treatment liquid, dehydrating and drying to obtain bleached and impurity-removed pretreated cotton knitted fabric;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
preparing a plant traditional Chinese medicine essential oil composition microcapsule and a natural biological cross-linking agent genipin in the step (1) into a treatment liquid, and adding tannic acid into the treatment liquid to obtain a cotton knitted fabric treatment liquid;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and the drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1), and drying the sizing blank to obtain the mosquito-repellent antibacterial cotton knitted fabric.
The beneficial effects of adopting above-mentioned scheme are: genipin in the treatment fluid is a product of geniposide hydrolyzed by beta-glucosidase, is an excellent natural biological cross-linking agent, and can increase the bonding strength and bonding durability of essential oil microcapsules and the cotton fiber surface in cotton knitted fabrics; tannic acid added into the treatment liquid, also called tannic acid, is extracted from plant calyx kaki, galla chinensis, pericarpium Granati, green tea, etc., and has the effect of increasing bonding strength of essential oil microcapsule and cotton fiber surface in cotton knitted fabric; tannic acid is added into the treatment liquid, and the tannic acid and genipin can be cooperated, so that the durability of the mosquito-repellent and antibacterial functions of the plant traditional Chinese medicine is further improved, and the washing resistance of the functions is improved.
Further, in the step (1), microcapsules with two different wall thicknesses of 1:1 and 1:2 are prepared.
Further, the grain diameter of the microcapsule is less than or equal to 2 microns, D 90 =1.6 to 1.8 micrometers.
In the step (2), the scouring treatment fluid comprises water, caustic soda (NaOH) (1-2) g/L, hydrogen peroxide (3-5) g/L and glacial acetic acid (0.3-0.5) g/L, and the bath ratio of the cotton knitted fabric to the scouring treatment fluid is 1 (20-30).
Still further, the scouring treatment fluid comprises deionized water, caustic soda flakes (NaOH) 1.5g/L, hydrogen peroxide 4g/L and glacial acetic acid 0.4g/L, and the bath ratio of the cotton knitted fabric to the scouring treatment fluid is 1:25.
Further, in the step (2), the method for scouring the cotton knitted fabric is as follows: placing the cotton knitted fabric into a treatment container, adding caustic soda flakes at normal temperature to heat to 80 ℃, then adding hydrogen peroxide to heat to 90-100 ℃, preserving heat for 30-60 minutes, cooling to 70-80 ℃, and draining water; adding water, then adding glacial acetic acid, heating to 75-80 ℃, preserving heat for 20-30 minutes, and draining water; then adding water, washing for 15-25 minutes at 40-50 ℃ until the mixture is neutral, and drying after dehydration.
Still further, the scouring treatment method of the cotton knitted fabric comprises the following steps: placing the cotton knitted fabric into a treatment container, adding caustic soda flakes at normal temperature, heating to 80 ℃, then adding hydrogen peroxide, heating to 95 ℃, preserving heat for 45 minutes, cooling to 75 ℃, and draining water; adding deionized water, adding glacial acetic acid, heating to 80 ℃, preserving heat for 25 minutes, and draining water; then deionized water is added, water is washed for 20 minutes at 45 ℃ until the mixture is neutral, and the mixture is dehydrated and dried.
In the step 1), the plant traditional Chinese medicine essential oil composition microcapsule accounts for 2-5wt% of the cotton knitted fabric, the natural biological cross-linking agent genipin accounts for 1-3wt% of the cotton knitted fabric, tannic acid (10-15) g/L in the cotton knitted fabric treatment fluid, and the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment fluid is 1 (20-30).
Still further, the plant traditional Chinese medicine essential oil composition microcapsule is 3.5wt% relative to the cotton knitted fabric, the natural biological cross-linking agent genipin is 2wt% relative to the cotton knitted fabric, tannic acid in the cotton knitted fabric treatment liquid is 12.5g/L, and the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment liquid is 1:25.
Further, in the step 2), the liquid carrying rate after padding is 70-85%, and the treatment time is 20-30 minutes; the baking temperature of the shaped blank is 120-130 ℃ and the time is 8-12 minutes.
Further, the liquid carrying rate after padding is 80%, and the treatment time is 25 minutes; the temperature of the shaped blank is 125 ℃ and the time is 10 minutes.
Compared with the prior art, the invention has the following beneficial effects:
(1) The four components of citronella essential oil, lavender essential oil, mugwort essential oil and eucalyptus essential oil provided by the invention have obvious synergistic effect, and can greatly improve the mosquito-repellent and antibacterial effects of the material;
(2) The plant traditional Chinese medicine essential oil composition provided by the invention belongs to a natural functional agent, is safe and nontoxic, has no side effect, is friendly to human and livestock, is environment-friendly, and meets the requirements of people on environment-friendly life;
(3) The genipin and the tannic acid are added into the cotton knitted fabric treatment liquid to perform synergism, so that the bonding strength of the essential oil microcapsule and the cotton fiber surface in the cotton knitted fabric is increased, the durability of the mosquito-repellent and antibacterial functions of the plant traditional Chinese medicine is improved, and the washability of the functions is improved.
Detailed Description
The principles and features of the present invention are described below with reference to examples, which are provided for illustration only and are not intended to limit the scope of the invention in parts by weight.
Example 1
The mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition comprises the following raw materials in percentage by weight: 35% of citronella essential oil, 30% of lavender essential oil, 25% of mugwort essential oil and 10% of eucalyptus essential oil.
Example 2
The mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition comprises the following raw materials in percentage by weight: 30% of citronella essential oil, 35% of lavender essential oil, 20% of mugwort essential oil and 15% of eucalyptus essential oil.
Example 3
The mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition comprises the following raw materials in percentage by weight: 35% of citronella essential oil, 25% of lavender essential oil, 30% of mugwort essential oil and 10% of eucalyptus essential oil.
Example 4
The mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition comprises the following raw materials in percentage by weight: 40% of citronella essential oil, 25% of lavender essential oil, 20% of mugwort essential oil and 15% of eucalyptus essential oil.
Application example 1
The preparation method of the mosquito-repellent antibacterial cotton knitted fabric using the plant traditional Chinese medicine essential oil composition of the embodiment 1 comprises the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
the plant traditional Chinese medicine essential oil composition with the given components in the example 1 is used as a core material and melamine resin is used as a wall material, and the microcapsule with the mass ratio of the core material to the wall material of 1:1 is prepared by adopting an in-situ polymerization method, wherein the particle size of the microcapsule is less than or equal to 2 microns, and D is prepared 90 =1.6 microns; adjusting the process, taking the plant traditional Chinese medicine essential oil composition with the given components in the example 1 as a core material and melamine resin as a wall material, preparing microcapsules with the mass ratio of the core material to the wall material of 1:2 by adopting an in-situ polymerization method, wherein the particle size of the microcapsules is less than or equal to 2 microns, and D 90 =1.8 micrometers.
(2) Scouring treatment of cotton knitted fabric:
the cotton knitted fabric is put into a scouring treatment fluid for scouring, wherein the scouring treatment fluid comprises water, caustic soda flakes (NaOH) 1.5g/L, hydrogen peroxide 4g/L and glacial acetic acid 0.4g/L;
the specific method for scouring the cotton knitted fabric comprises the following steps: placing cotton knitted fabric into a treatment container, wherein the bath ratio of the cotton knitted fabric to scouring treatment liquid is 1:25, adding caustic soda flakes at normal temperature, heating to 80 ℃, adding hydrogen peroxide, heating to 95 ℃, preserving heat for 45 minutes, cooling to 75 ℃, and draining water; adding water, then adding glacial acetic acid, heating to 80 ℃, preserving heat for 25 minutes, and draining water; then adding water, washing for 20 minutes at 45 ℃ to be neutral, dehydrating and drying to obtain the bleached and pretreated cotton knitted fabric with various waxes, impurities and oiling agents removed;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
mixing the plant traditional Chinese medicine essential oil composition microcapsules with the mass ratio of the two core materials to the wall material in the step (1) according to the mass ratio of 1:1, preparing a treatment solution according to the addition amount of 3.5wt% of the mixed plant traditional Chinese medicine essential oil composition microcapsules relative to the cotton knitted fabric and 2wt% of a natural biological cross-linking agent genipin relative to the cotton knitted fabric, and adding 12.5g/L tannic acid into the treatment solution to obtain the cotton knitted fabric treatment solution;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1) by adopting a setting machine, wherein the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment liquid is 1:25, the liquid carrying rate is 80%, and the treatment time is 25 minutes; and drying the sizing blank at 125 ℃ for 10 minutes to obtain the mosquito-repellent and antibacterial cotton knitted fabric.
Application example 2
The preparation method of the mosquito-repellent antibacterial cotton knitted fabric using the plant traditional Chinese medicine essential oil composition of the embodiment 1 comprises the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
the same as in application example 1.
(2) Scouring treatment of cotton knitted fabric:
the cotton knitted fabric is put into a scouring treatment fluid for scouring, wherein the scouring treatment fluid comprises water, caustic soda flakes (NaOH) 1.2g/L, hydrogen peroxide 3g/L and glacial acetic acid 0.3g/L;
the specific method for scouring the cotton knitted fabric comprises the following steps: placing cotton knitted fabric into a treatment container, wherein the bath ratio of the cotton knitted fabric to scouring treatment liquid is 1:20, adding caustic soda flakes at normal temperature, heating to 80 ℃, adding hydrogen peroxide, heating to 90 ℃, preserving heat for 45 minutes, cooling to 70 ℃, and draining water; adding water, then adding glacial acetic acid, heating to 75 ℃, preserving heat for 20 minutes, and draining water; then adding water, washing for 15 minutes at 40 ℃ to be neutral, dehydrating and drying to obtain the pretreated cotton knitted fabric which is bleached and removed of various waxes, impurities and oiling agents;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
mixing the plant traditional Chinese medicine essential oil composition microcapsules with the mass ratio of the two core materials to the wall material in the step (1) according to the mass ratio of 1:1, preparing a treatment solution according to the addition amount of 2wt% of the mixed plant traditional Chinese medicine essential oil composition microcapsules relative to the cotton knitted fabric and 1wt% of the natural biological cross-linking agent genipin relative to the cotton knitted fabric, and adding 10g/L tannic acid into the treatment solution to obtain the cotton knitted fabric treatment solution;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1) by adopting a setting machine, wherein the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment liquid is 1:20, the liquid carrying rate is 82%, and the treatment time is 30 minutes; and drying the sizing blank at 120 ℃ for 11 minutes to obtain the mosquito-repellent and antibacterial cotton knitted fabric.
Application example 3
The preparation method of the mosquito-repellent antibacterial cotton knitted fabric using the plant traditional Chinese medicine essential oil composition of the embodiment 1 comprises the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
the plant essential oil composition of the given composition of example 1 is used as a core material and melamine resin is used as a wallThe material is prepared into microcapsules with the mass ratio of core materials to wall materials of 1:1 by adopting an in-situ polymerization method, the particle size of the microcapsules is less than or equal to 2 microns, and D 90 =1.7 microns; adjusting the process, taking the plant traditional Chinese medicine essential oil composition with the given components in the example 1 as a core material and melamine resin as a wall material, preparing microcapsules with the mass ratio of the core material to the wall material of 1:2 by adopting an in-situ polymerization method, wherein the particle size of the microcapsules is less than or equal to 2 microns, and D 90 =1.8 micrometers.
(2) Scouring treatment of cotton knitted fabric:
the cotton knitted fabric is put into a scouring treatment fluid for scouring, wherein the scouring treatment fluid comprises water, caustic soda flakes (NaOH) 2g/L, hydrogen peroxide 5g/L and glacial acetic acid 0.5g/L;
the specific method for scouring the cotton knitted fabric comprises the following steps: placing cotton knitted fabric into a treatment container, wherein the bath ratio of the cotton knitted fabric to scouring treatment liquid is 1:30, adding caustic soda flakes at normal temperature, heating to 80 ℃, adding hydrogen peroxide, heating to 100 ℃, preserving heat for 60 minutes, cooling to 80 ℃, and draining water; adding water, then adding glacial acetic acid, heating to 80 ℃, preserving heat for 30 minutes, and draining water; then adding water, washing for 25 minutes at 50 ℃ to neutrality, drying after dehydration, and obtaining the pretreated cotton knitted fabric which is bleached and removed various waxes, impurities and oiling agents;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
mixing the plant traditional Chinese medicine essential oil composition microcapsules with the mass ratio of the two core materials to the wall material in the step (1) according to the mass ratio of 1:1, preparing a treatment solution according to the addition amount of 5wt% of the mixed plant traditional Chinese medicine essential oil composition microcapsules relative to the cotton knitted fabric and 3wt% of the natural biological cross-linking agent genipin relative to the cotton knitted fabric, and adding 15g/L of tannic acid into the treatment solution to obtain the cotton knitted fabric treatment solution;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1) by adopting a setting machine, wherein the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment liquid is 1:30, the liquid carrying rate is 85%, and the treatment time is 30 minutes; and drying the sizing blank at 130 ℃ for 12 minutes to obtain the mosquito-repellent and antibacterial cotton knitted fabric.
Application example 4
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 1 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 2 according to application example 1.
Application example 5
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 2 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared from the plant traditional Chinese medicine essential oil composition of example 2.
Application example 6
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 2.
Application example 7
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 1 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 3 according to application example 1.
Application example 8
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 2 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 3.
Application example 9
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 3.
Application example 10
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 1 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 4 according to application example 1.
Application example 11
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 2 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 4.
Application example 12
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of example 4.
Comparative example 1
A mosquito repellent antibacterial plant traditional Chinese medicine essential oil composition is different from example 1 with reference to example 1 in that the composition does not contain eucalyptus essential oil in a corresponding weight percentage.
Comparative example 2
A mosquito repellent antibacterial herbal essential oil composition, referring to example 1, differs from example 1 in that it does not contain mugwort essential oil in a corresponding weight percentage.
Comparative example 3
A mosquito repellent antibacterial herbal essential oil composition, referring to example 1, differs from example 1 in that it does not contain a corresponding weight percentage of lavender essential oil.
Comparative example 4
A mosquito repellent antibacterial herbal essential oil composition, referring to example 1, differs from example 1 in that it does not contain citronella essential oil in a corresponding weight percentage.
Comparative application example 1
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of comparative example 1.
Comparative application example 2
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of comparative example 2.
Comparative application example 3
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of comparative example 3.
Comparative application example 4
The mosquito-repellent and antibacterial cotton knitted fabric is different from application example 3 in that the mosquito-repellent and antibacterial cotton knitted fabric is prepared by using the plant traditional Chinese medicine essential oil composition of comparative example 4.
Comparative application example 5
The mosquito-repellent and antibacterial cotton knitted fabric is different from the cotton knitted fabric in application example 3 in that genipin is not added into the cotton knitted fabric treatment liquid with reference to application example 3.
Comparative application example 6
The mosquito-repellent and antibacterial cotton knitted fabric is different from the application example 3 in that tannic acid is not added into the cotton knitted fabric treatment liquid with reference to the application example 3.
The test method comprises the following steps:
(1) And (3) detecting mosquito-proof performance: the anti-mosquito performance of the anti-mosquito and antibacterial cotton knitted fabrics of the application examples 1-12 and the comparative application examples 1-6 is tested according to GB/T30126-2013 detection and evaluation of anti-mosquito performance of textiles;
(2) Antibacterial property detection: evaluation of antimicrobial Properties of textiles according to GB/T20944.3-2008 part 3: the vibration method was used for testing the antibacterial performance of the mosquito repellent and antibacterial functional cotton knitted fabrics of the application examples 1 to 12 and the comparative application examples 1 to 6.
The test experimental data of application examples 1 to 12 and comparative application examples 1 to 6 are shown in Table 1.
Table 1 test experimental data of application examples 1 to 12 and comparative application examples 1 to 6
As can be seen from comparison of the test experimental data in Table 1, the mosquito repelling rate of the cotton knitted fabric with the mosquito repelling and antibacterial functions of application examples 1-12 is more than or equal to 73%, and the mosquito repelling rate is A grade; the mosquito-repellent and antibacterial cotton knitted fabric of comparative application examples 1-4 has a mosquito-repellent rate of 38-46% and a mosquito-repellent rating of C, which indicates that the mosquito-repellent and antibacterial cotton knitted fabric provided by the invention has a very strong mosquito-repellent effect.
The antibacterial rate of the cotton knitted fabric with the mosquito-repellent and antibacterial functions in application examples 1-12 on staphylococcus aureus is more than or equal to 96.1 percent, the inhibition rate on escherichia coli is more than or equal to 93.2 percent, and the inhibition rate on candida albicans is more than or equal to 85.6 percent; the comparison of the application examples 1-4 shows that the anti-mosquito and antibacterial cotton knitted fabric has 88.7-90.2% of the antibacterial rate of staphylococcus aureus, 86.9-88.1% of the antibacterial rate of escherichia coli and 80.5-81.6% of candida albicans, and the anti-mosquito and antibacterial cotton knitted fabric provided by the invention has good antibacterial effect.
The four components of citronella essential oil, lavender essential oil, mugwort essential oil and eucalyptus essential oil provided by the invention have obvious synergistic effect, and can greatly improve the mosquito-repellent and antibacterial effects of the material.
In addition, after the cotton knitted fabric with the mosquito-repellent and antibacterial functions of application examples 1-12 is washed for 30 times, the mosquito-repellent rate is more than or equal to 65%, the mosquito-repellent rate is B-grade, the antibacterial rate to staphylococcus aureus is more than or equal to 91.1%, the inhibition rate to escherichia coli is more than or equal to 88.7%, and the inhibition rate to candida albicans is more than or equal to 82.6%; the cotton knitted fabric with the mosquito-repellent and antibacterial functions of comparative application examples 5 and 6 has a mosquito-repellent rate of 31-32% after 30 times of washing, a mosquito-repellent rating of C, a bacteriostatic rate of 75.4-76.2% on staphylococcus aureus, a bacteriostatic rate of 68.8-69.7% on escherichia coli and a bacteriostatic rate of 56.2-57.8% on candida albicans. The cotton knitted fabric with the mosquito-repellent and antibacterial functions provided by the invention is proved to have better mosquito-repellent and antibacterial effects after being washed for 30 times.
The genipin and the tannic acid are added into the cotton knitted fabric treatment liquid to perform synergism, so that the bonding strength of the essential oil microcapsule and the cotton fiber surface in the cotton knitted fabric is increased, the durability of the mosquito-repellent and antibacterial functions of the plant traditional Chinese medicine is improved, and the washability of the functions is improved.
The foregoing description of the preferred embodiments of the invention is not intended to limit the invention to the precise form disclosed, and any such modifications, equivalents, and alternatives falling within the spirit and scope of the invention are intended to be included within the scope of the invention.
Claims (10)
1. The mosquito-repellent antibacterial plant traditional Chinese medicine essential oil composition is characterized by comprising the following raw materials in percentage by weight:
30-40% of citronella essential oil, 25-35% of lavender essential oil, 20-30% of mugwort essential oil and 10-15% of eucalyptus essential oil;
the preparation method of the mosquito-repellent and antibacterial functional cotton knitted fabric using the plant traditional Chinese medicine essential oil composition comprises the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
preparing microcapsules by taking a plant traditional Chinese medicine essential oil composition as a core material and melamine resin as a wall material;
(2) Scouring treatment of cotton knitted fabric:
boiling the cotton knitted fabric in boiling-off treatment liquid, dehydrating and drying to obtain bleached and impurity-removed pretreated cotton knitted fabric;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
preparing a plant traditional Chinese medicine essential oil composition microcapsule and a natural biological cross-linking agent genipin in the step (1) into a treatment liquid, and adding tannic acid into the treatment liquid to obtain a cotton knitted fabric treatment liquid;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and the drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1), shaping and baking to obtain the mosquito-repellent antibacterial cotton knitted fabric.
2. An application of the plant traditional Chinese medicine essential oil composition according to claim 1 in the field of mosquito-repellent and antibacterial cotton knitted fabrics.
3. A method for preparing a mosquito-repellent and antibacterial cotton knitted fabric, which uses the plant traditional Chinese medicine essential oil composition as claimed in claim 1, and is characterized by comprising the following steps:
(1) Preparing a plant traditional Chinese medicine essential oil composition microcapsule:
preparing microcapsules by taking a plant traditional Chinese medicine essential oil composition as a core material and melamine resin as a wall material;
(2) Scouring treatment of cotton knitted fabric:
boiling the cotton knitted fabric in boiling-off treatment liquid, dehydrating and drying to obtain bleached and impurity-removed pretreated cotton knitted fabric;
(3) Preparation of mosquito-repellent antibacterial cotton knitted fabric:
1) Preparation of a mosquito-repellent antibacterial cotton knitted fabric treatment fluid:
preparing a plant traditional Chinese medicine essential oil composition microcapsule and a natural biological cross-linking agent genipin in the step (1) into a treatment liquid, and adding tannic acid into the treatment liquid to obtain a cotton knitted fabric treatment liquid;
2) The preparation method of the knitted fabric with the mosquito-repellent and antibacterial functions by using the plant traditional Chinese medicines comprises the following steps:
padding the pretreated cotton knitted fabric subjected to the scouring treatment and the drying in the step (2) in the cotton knitted fabric treatment liquid in the step (1), shaping and baking to obtain the mosquito-repellent antibacterial cotton knitted fabric.
4. The method for preparing the mosquito-repellent and antibacterial functional cotton knitted fabric according to claim 3, wherein in the step (1), microcapsules with two different wall material thicknesses, namely a core material and a wall material, are prepared in a mass ratio of 1:1 and 1:2.
5. The method for preparing the mosquito-repellent and antibacterial functional cotton knitted fabric according to claim 4, wherein the particle size of the microcapsules is less than or equal to 2 microns, and D is the same as that of the microcapsules 90 =1.6 to 1.8 micrometers.
6. The method for preparing the mosquito-repellent and antibacterial functional cotton knitted fabric according to claim 3, wherein in the step (2), the scouring treatment fluid comprises water, caustic soda flakes (1-2) g/L, hydrogen peroxide (3-5) g/L and glacial acetic acid (0.3-0.5) g/L, and the bath ratio of the cotton knitted fabric to the scouring treatment fluid is 1 (20-30).
7. The method for preparing the mosquito repellent antibacterial functional cotton knitted fabric according to claim 6, wherein in the step (2), the method for scouring the cotton knitted fabric is as follows: placing the cotton knitted fabric into a treatment container, adding caustic soda flakes at normal temperature to heat to 80 ℃, then adding hydrogen peroxide to heat to 90-100 ℃, preserving heat for 30-60 minutes, cooling to 70-80 ℃, and draining water; adding water, then adding glacial acetic acid, heating to 75-80 ℃, preserving heat for 20-30 minutes, and draining water; then adding water, washing for 15-25 minutes at 40-50 ℃ until the mixture is neutral, and drying after dehydration.
8. The method for preparing the mosquito-repellent and antibacterial functional cotton knitted fabric according to claim 3, wherein in the step 1), the plant traditional Chinese medicine essential oil composition microcapsules account for 2-5 wt% of the cotton knitted fabric, and the natural biological cross-linking agent genipin accounts for 1-3 wt% of the cotton knitted fabric.
9. The method for preparing the mosquito-repellent and antibacterial cotton knitted fabric according to claim 8, wherein in the step 1), tannic acid (10-15) g/L in the cotton knitted fabric treatment solution is adopted, and the bath ratio of the cotton knitted fabric to the cotton knitted fabric treatment solution is 1 (20-30).
10. The method for preparing the mosquito-repellent and antibacterial functional cotton knitted fabric according to claim 3, wherein in the step 2), the liquid carrying rate is 70-85% after padding, and the treatment time is 20-30 minutes; the setting and baking temperature is 120-130 ℃ and the time is 8-12 minutes.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090096116A (en) * | 2008-03-07 | 2009-09-10 | 박명숙 | Composition for repelling mosquitoes and mosquito repellents fabrics using the same |
| CN105594755A (en) * | 2016-01-15 | 2016-05-25 | 达利(中国)有限公司 | Plant mosquito repellent and production method of textile with mosquito repelling effect |
| CN106351017A (en) * | 2016-08-23 | 2017-01-25 | 东华大学 | Microcapsule with compound functions of repelling mosquitos, resisting bacteria, accumulating heat and regulating temperature, and preparation method thereof |
| CN106436275A (en) * | 2016-11-08 | 2017-02-22 | 南通大学 | Settling method for long-acting washable natural antibacterial fabric |
| CN110306339A (en) * | 2019-07-29 | 2019-10-08 | 青岛新维纺织研究院有限公司 | A kind of Chinese medicine modifying agent and the method for preparing modified cotton fiber using the modifying agent |
| CN110592954A (en) * | 2019-09-05 | 2019-12-20 | 天津市城西广源电力工程有限公司 | Mosquito-repellent fabric finishing liquid, mosquito-repellent finishing fabric and preparation method thereof |
| CN111621986A (en) * | 2019-12-05 | 2020-09-04 | 山东汇高智慧纺织科技有限公司 | Multifunctional fabric containing mosquito-repellent microcapsules and preparation method thereof |
-
2021
- 2021-09-28 CN CN202111140859.9A patent/CN113863004B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090096116A (en) * | 2008-03-07 | 2009-09-10 | 박명숙 | Composition for repelling mosquitoes and mosquito repellents fabrics using the same |
| CN105594755A (en) * | 2016-01-15 | 2016-05-25 | 达利(中国)有限公司 | Plant mosquito repellent and production method of textile with mosquito repelling effect |
| CN106351017A (en) * | 2016-08-23 | 2017-01-25 | 东华大学 | Microcapsule with compound functions of repelling mosquitos, resisting bacteria, accumulating heat and regulating temperature, and preparation method thereof |
| CN106436275A (en) * | 2016-11-08 | 2017-02-22 | 南通大学 | Settling method for long-acting washable natural antibacterial fabric |
| CN110306339A (en) * | 2019-07-29 | 2019-10-08 | 青岛新维纺织研究院有限公司 | A kind of Chinese medicine modifying agent and the method for preparing modified cotton fiber using the modifying agent |
| CN110592954A (en) * | 2019-09-05 | 2019-12-20 | 天津市城西广源电力工程有限公司 | Mosquito-repellent fabric finishing liquid, mosquito-repellent finishing fabric and preparation method thereof |
| CN111621986A (en) * | 2019-12-05 | 2020-09-04 | 山东汇高智慧纺织科技有限公司 | Multifunctional fabric containing mosquito-repellent microcapsules and preparation method thereof |
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