CN110194990B - Perfume composition for reproducing red fragrance of cymbidium hybridum - Google Patents
Perfume composition for reproducing red fragrance of cymbidium hybridum Download PDFInfo
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- CN110194990B CN110194990B CN201910136458.2A CN201910136458A CN110194990B CN 110194990 B CN110194990 B CN 110194990B CN 201910136458 A CN201910136458 A CN 201910136458A CN 110194990 B CN110194990 B CN 110194990B
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/003—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing less than six carbon atoms
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11B9/00—Essential oils; Perfumes
- C11B9/0069—Heterocyclic compounds
- C11B9/0073—Heterocyclic compounds containing only O or S as heteroatoms
- C11B9/008—Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing six atoms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
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Abstract
The present invention relates to a perfume composition capable of reproducing the fragrance of cymbidium hybridum pink aroma. The flavor composition of the present invention can reproduce a flavor very similar to that of cymbidium red aroma and can realize an excellent flavor preference by adding one or more components selected from the group consisting of Convallaria (Florosa), hindiole (Hedione) and methacrolein (Muguet Aldehyde) to the main flavor component of cymbidium red aroma.
Description
Technical Field
The present invention relates to a perfume composition capable of reproducing the fragrance of cymbidium hybridum pink (cymbidium Aroma Pink), and relates to a perfume composition having improved similarity and satisfaction with the fragrance inherent to cymbidium hybridum pink.
Background
Cymbidium (Cymbidium) is one of western orchid, and the growing period is spring to autumn and the growing period is stopped in winter. The name cymbidium is derived from latin language cymba which means a ship, and the name is obtained by a ship which floats on water because the flower buds are large and round. Cymbidium showing big flowers and gorgeous colors is taken as a ground-rooted cymbidium growing in the ground, and is said to grow in asia areas of subtropical climates (north india, china, japan, malaysia, philippines, sallowness and himalaya mountain regions) and north australia. Depending on the species, cymbidium hybridum grows to about 60 to 90cm, and flowers of about 5 to 10cm in size are opened. More than 15 flowers can be cut at a time, and the colors are various, and white, grass green, light green, yellow, brown, pink, red and black are available.
Cymbidium has become a popular orchid since the time of the UK Victoria king. Is not easy to bloom in summer, but is easy to bloom in winter, so the flower is often used as a bouquet on graduation ceremony or open school ceremony. And is also commonly used to make ornamental corselets on dress. Thus, the cymbidium with wide use degree occupies 60 percent of market share in China and Phalaenopsis (Phalaenopsis) together with sales as a reference, and occupies a remarkable position in orchid market.
Cymbidium pink variety is bred by systematically breeding and selecting Lucky Rainbow Rainbow 'LapinHot' and exclusive spring (Eburn) from 2001 to 2010, and then is subjected to characteristic verification from 2011 to 2016. The red aroma of cymbidium is light pink on a part of calyx on a white ground color, the middle of a shield sheet is yellow, and the whole gives a luxurious feel to people. The flower is small in size and round in shape. It is a late-maturing variety that flowers around 3 months, and can be cultivated in all regions of the country as a plant cultivated in a facility, as long as the temperature in the facility is in the range of 15 ℃. Compared with exclusive spring, the flower fragrance is beautiful and better. Therefore, there is a need to develop a fragrance composition having new characteristics, which reproduces the original fragrance of cymbidium hybridum pink fragrance to differentiate it.
Disclosure of Invention
Problems to be solved by the invention
The inventor of the present invention analyzes the main aroma components and contents of cymbidium hybridum pink aroma and reproduces the original aroma of cymbidium hybridum pink aroma. However, the present invention has been completed on the basis that it has been confirmed that the aroma similar to the aroma inherent to cymbidium hybridum pink cannot be reproduced by merely combining the above-described analyzed components and contents, and thus, by adding a new aroma component to the above-described aroma, the aroma inherent to cymbidium hybridum pink can be reproduced.
In view of the above, an object of the present invention is to provide a flavor composition which can reproduce the flavor inherent to the red aroma of cymbidium hybridum and has an excellent preference.
Another object of the present invention is to provide a cosmetic material, an aromatic product, a skin external agent, a personal care product, a household care product, etc. to which the above-described perfume composition is applied.
Means for solving the problems
The present invention provides a perfume composition for reproducing the fragrance of cymbidium hybridum pink, which comprises Linalool (Linalool), alpha-Farnesene (alpha-Farnesene), methyl benzoate (Methyl benzoate), ocimene (Ocimene), myrcene (Myrcene), palmitic acid (Palmitic acid) and beta-Caryophyllene (beta-Caryophyllene), and comprises one or more ingredients selected from the group consisting of Convallaria (Florosa), hindii (Hedione) and methacrolein (Muguet Aldehyde).
The present invention also provides a cosmetic material, an aromatic product, a skin external preparation, a personal care product, and a home care product each comprising the above-mentioned perfume composition.
Effects of the invention
In the present invention, by adding one or more components selected from the group consisting of Convallaria (Florosa), hildering (Hedione) and melon (Muguet Aldehyde) to the aroma component combined flavor of cymbidium hybridum pink, the similarity and satisfaction of aroma can be significantly improved. Thus, the composition of the present invention can be effectively used as a perfume composition for reproducing the red aroma of cymbidium hybridum.
Detailed Description
The perfume composition of the present invention will be described in more detail below.
The present invention relates to a perfume composition for reproducing the fragrance of cymbidium hybridum pink, which comprises Linalool (Linalool), alpha-Farnesene (alpha-Farnesene), methyl benzoate (Methyl benzoate), ocimene (Ocimene), myrcene (Myrcene), palmitic acid (Palmitic acid) and beta-Caryophyllene (beta-Caryophyllene), and comprises one or more ingredients selected from the group consisting of Convallaria (Florosa), clitoria (Hedione) and methacrolein (Muguet Aldehyde).
Generally, as a method for collecting fragrance, a method such as a solvent extraction method (extraction) using a solvent, a steam distillation method (steam distillation) using steam, or the like is used. However, in the case of such a method, the aroma component is lost or changed by heating, depressurizing, or the like during the extraction of the aroma component, and thus there is a difference from the aroma of the original substance.
To overcome such drawbacks, SPME (Solid-phase-Phase Micro Extraction: solid-phase microextraction) method, headspace (Headspace) method, and the like have been developed. The above method is a good method for recovering the original flavor of a sample, because it is a simple method for concentrating volatile organic compounds by adsorbing the volatile organic compounds to fibers (fibers) without using any additional pretreatment technique or solvent, and it is unnecessary to heat or reduce the pressure. In the SPME method, a Fiber (Fiber) for adsorbing a fragrance is provided in a state of isolating the fragrance emitted to be analyzed from the outside air, and the adsorbed fragrance is quantitatively analyzed by a gas chromatography-mass spectrometry (Gas Chromatograph-Mass spectro photometry, GC-MS) after adsorbing the fragrance component. The gas chromatography-mass spectrometry (GC-MS) method is an analysis device mainly used for content analysis of volatile substances. In GC-MS, the content of the compound can be analyzed by separating a plurality of compounds in a sample injected by the SPME by Gas Chromatography (GC) and measuring the atomic weight (MS) of the inflowing material. By such an analysis method, the structural component of the flavor to be reproduced and the content thereof can be detected.
In one specific example, the aroma component of cymbidium pink obtained by the above aroma component analysis technique contains Linalool (linalol), α -Farnesene (alpha-Farnesene), methyl benzoate (Methyl benzoate), ocimene (Ocimene), myrcene (Myrcene), palmitic acid (palmitical) and β -Caryophyllene (beta-Caryophyllene) as main aroma components.
However, the aroma of cymbidium hybridum pink aroma cannot be reproduced well only by the main aroma components of cymbidium hybridum pink aroma, and the preference of the aroma is lowered. Thus, in the present invention, one or more aroma components selected from the group consisting of Convallaria (Florosa), hildering (Hedione) and melon (Muguet Aldehyde) are added to the main aroma component of the cymbidium pink aroma to improve the reproducibility of aroma.
Accordingly, the perfume composition for reproducing the fragrance of cymbidium hybridum pink according to the present invention comprises Linalool (Linalool), α -Farnesene (alpha-Farnesene), methyl benzoate (Methyl benzoate), ocimene (Ocimene), myrcene (Myrcene), palmitic acid (Palmitic acid) and β -Caryophyllene (beta-Caryophyllene) as the main fragrance components of natural cymbidium hybridum pink, and at least one fragrance component selected from the group consisting of Convallaria sinensis (Florosa), hindine (Hedione) and methacrolein (Muguaet Aldehyde).
In one embodiment, the major aroma component of cymbidium pinnatifida pink aroma may comprise 25 to 35 wt% Linalool (Linalool), 20 to 25 wt% alpha-Farnesene (alpha-Farnesene), 1 to 5 wt% Methyl benzoate (Methyl benzoate), 1 to 5 wt% Ocimene (Ocimene), 1 to 5 wt% Myrcene (Myrcene), 1 to 3 wt% Palmitic acid (Palmitic acid), and 0.1 to 2 wt% beta-Caryophyllene (beta-Caryophyllene) relative to the total weight of the composition.
In one embodiment, the aroma component contained together with the main aroma component of cymbidium pink, that is, one or more components selected from the group consisting of Convallaria (Florosa), hildering (Hedione) and melon (Muguet Aldehyde) may be contained in an amount of 1 to 20% by weight, specifically 3 to 16% by weight, based on the total weight of the composition.
In the present invention, a clitoral (Hedione) and a melon (Muguet Aldehyde) may be used together. In addition, all of the Convallaria (Florosa), the Hildering (Hedione) and the melon Aldehyde (Muguet Aldride) may be contained, and in this case, 1 to 5% by weight of the Convallaria (Florosa), 0.1 to 5% by weight of the Hildering (Hedione) and 0.1 to 10% by weight of the melon Aldehyde (Muguet Aldride) may be contained with respect to the total weight of the composition.
Regarding Linalool (Linalool), alpha-Farnesene (alpha-Farnesene), methyl benzoate (Methyl benzoate), ocimene (Ocimene), myrcene (palmitone), palmitic acid (palmitoleic acid), beta-Caryophyllene (beta-Caryophyllene), convallaria (Florosa), clitoria (Hedione) and methacrolein (Muguet Aldehyde) contained in the perfume composition of the present invention, products sold on the market or produced by isolation, semisynthesis or synthesis from plants can be used.
In order to further improve the satisfaction of the fragrance of cymbidium pink fragrance, the fragrance composition of the present invention additionally contains a fragrance solubilizing agent known in the art. The content of the above-mentioned incense dissolving agent may be 0.1 to 10% by weight, specifically, 1 to 5% by weight, relative to the total weight of the above-mentioned composition.
The perfume composition of the present invention can be provided in combination with a cosmetic material or a skin external agent within a range that does not affect the object of the present invention.
The cosmetic materials include basic cosmetics, makeup cosmetics, body care products, and the like, and examples of the basic cosmetics include, but are not limited to, essence, skin lotion, face cream, gel, water make-up, face pack, massage cream, and emulsion, and examples of the makeup cosmetics include foundation cream, barrier cream, and the like, and examples of the body care products include toilet soaps, liquid detergents, bathing agents, sun creams, sun oils, and the like. The external preparation for skin is ointment, skin lotion, solubilizing aid, suspension, emulsion, facial cream, gel, spray, cataplasm, hardener, patch or ointment. The content of the active ingredient in the composition varies depending on the formulation and purpose. For example, a water-washable (wash-off) cosmetic such as a makeup remover, a cleansing agent, or the like, in which an active ingredient stays on the skin for a short period of time, may have a relatively high concentration, whereas a water-washable (leave-on) cosmetic such as a lotion, an emulsion, a cream, an essential oil, or the like, in which an active ingredient stays on the skin for a long period of time, may have a lower concentration than a water-washable cosmetic.
The perfume composition of the present invention can be provided by being incorporated into a fragrance product within a range that does not affect the object of the present invention. In particular, the fragrance compositions of the present invention may be included in fragrances, deodorants, fireless fragrance oils, wax, oils, gels, beads, inserts, and the like, as fragrance products.
Also, the perfume composition of the present invention may be provided in combination with a personal care product or a home care product within a range that does not affect the object of the present invention.
The personal care products are hair care products such as shampoo, hair conditioner, hair mask, hair care essence, oral products such as toothpaste, mouthwash, skin cleaning agent such as shower gel, body cleaning gel, soap, etc., and the home care products are aromatic agents such as perfume, fiber softener, laundry detergent such as kitchen detergent, etc., but are not limited thereto.
In the following, specific description will be given by way of examples in order to facilitate understanding of the present invention. However, the embodiment of the present invention may be modified into other forms, and the scope of the present invention is not limited to the following embodiments.
Examples
1. Aroma component analysis of cymbidium hybridum pink aroma
In order to analyze the aroma components and contents of cymbidium pink aroma, aroma components were extracted by Solid Phase microextraction (Solid Phase MicroExtraction, SPME), and then analyzed by gas chromatography-mass spectrometry (GC-MS).
The periphery of the flower bud, which is optimal for the fragrance emission in the cymbidium hybridum pink fresh flower, was sealed by using a tedlar sampling bag (Tedler bag) to be isolated from the outside air, and a SPME special syringe (syringe) was inserted to collect the fragrance component for 60 minutes. The type and content of the adsorbed fragrance component were analyzed by connecting a syringe (syringe) having the adsorbed fragrance component to a gas chromatography apparatus.
At this time, the analysis conditions for analyzing the types and contents of the aroma components of the collected cymbidium hybridum red aroma are as follows.
< analysis conditions >
An analyzer: agilent 6890GC/5975MSD
A detector: MSD (MSD)
Test column: DB-WAX 60 m.times.250. Mu.times.0.25. Mu.m
Injection part temperature: 230 DEG C
Detection part temperature: 230 DEG C
Oven temperature: 50 ℃ (5 minutes) to 230 ℃ ([ 0033]20 minutes), 3.0 ℃/minute dispensing ratio: 20:1
Mobile phase gas: he (He)
Injection amount: 0.5 μl
The analysis results are shown in table 1 below.
TABLE 1
NO. | Material name | Weight (%) |
1 | Linalool (Linalool) | 33.2 |
2 | alpha-Farnesene (alpha-Farnesene) | 22.0 |
3 | Methyl benzoate (methyl benzoate) | 4.6 |
4 | Ocimene (Ocimene) | 3.5 |
5 | Myrcene (Myrcene) | 3.1 |
6 | Palmitic acid (palmitical) | 1.6 |
7 | beta-Caryophyllene (beta-Caryophyllene) | 0.9 |
8 | Other ingredients | 31.1 |
9 | Totals to | 100.0 |
2. Manufacturing and sensory evaluation of aroma reproduced by cymbidium hybridum pink aroma
(1) Examples 1 to 6 and comparative example 1
The components of table 2 below were uniformly mixed to prepare a perfume composition.
TABLE 2
(2) Experimental example 1 sensory evaluation
Sensory evaluation of similarity and preference of fragrance to the pink aroma of cymbidium hybridum was performed on the fragrance compositions produced in examples 1 to 6 and comparative example 1. The sensory evaluation subjects were 20 normal men and women with a healthy body between 27 and 50 years old, 4 men and 16 women.
The similarity was evaluated by a 5-point scoring method, and a 5-point scoring method was also used for the evaluation of preference. The evaluation chamber and the sample preparation chamber are separated, so that the evaluator does not recognize the sample in advance.
< similarity >
1, the method comprises the following steps: the fragrance of the cymbidium is greatly different from that of the red fragrance of cymbidium.
2, the method comprises the following steps: the fragrance of the cymbidium is slightly different from that of the red fragrance of cymbidium.
3, the method comprises the following steps: the fragrance of the cymbidium is almost the same as that of the red fragrance of cymbidium.
4, the following steps: the fragrance of the cymbidium is somewhat similar to that of the red fragrance of cymbidium.
5, the method comprises the following steps: the fragrance of the cymbidium is very similar to that of the red fragrance of cymbidium.
< preference >
1, the method comprises the following steps: very bad.
2, the method comprises the following steps: not good.
3, the method comprises the following steps: generally, the method is used for the treatment of a disease.
4, the following steps: good.
5, the method comprises the following steps: very good.
Tables 3 and 4 show the results of the above-described similarity and preference. TABLE 3
TABLE 4
Regarding the similarity, in the present invention, comparative example 1 is a perfume composition manufactured according to the analyzed main perfume components and contents of the red aroma of the naturally occurring cymbidium faberi, but the similarity to the original perfume of the red aroma of the natural cymbidium faberi is very low.
In contrast, in the case of using the main flavor component as in examples 1 to 6, when one or more flavor components selected from the group consisting of Convallaria (Florosa), hildering (Hedione) and melon (Muguetadide) are added, the flavor similarity is improved. In particular, when the above 3 aroma components are mixed together, the natural aroma of the cymbidium pink aroma is more similar to that of cymbidium pink aroma.
In addition, the flavor composition of comparative example 1, which was produced based on the main flavor component and content of the naturally occurring cymbidium hybridum pink aroma, had very low preference in terms of flavor.
In contrast, in the case of the perfume compositions of examples 1 to 6, in which one or more aroma components selected from the group consisting of Convallaria (Florosa), hildering (Hedione) and Honey-guarsede (Muguealdehyde) were added, the flavor preference was improved as compared with the comparative examples. In particular, the preference obtained when the above 3 aroma components are mixed together is optimal.
Claims (3)
1. A perfume composition for reproducing the fragrance of cymbidium pink scent, which comprises linalool, alpha-farnesene, methyl benzoate, ocimene, myrcene, palmitic acid and beta-caryophyllene, and comprises Convallaria, hindi and methacrolein,
wherein the composition comprises, relative to the total weight of the composition, from 1 to 5% by weight of the mugwort pyran, from 0.1 to 5% by weight of the clitoris and from 0.1 to 10% by weight of the honey melon aldehyde.
2. A fragrance composition reproducing the fragrance of cymbidium pink fragrance according to claim 1, wherein the fragrance composition comprises 25 to 35% by weight of linalool, 20 to 25% by weight of α -farnesene, 1 to 5% by weight of methyl benzoate, 1 to 5% by weight of ocimene, 1 to 5% by weight of myrcene, 1 to 3% by weight of palmitic acid and 0.1 to 2% by weight of β -caryophyllene, relative to the total weight of the composition.
3. The flavor composition for reproducing the red aroma of cymbidium hybride according to claim 1, wherein the flavor composition is used for manufacturing cosmetic materials, skin external preparations, aromatic products, personal care products or home care products.
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KR1020180022756A KR102104269B1 (en) | 2018-02-26 | 2018-02-26 | Perfume composition for expressing the fragrance of Cymbidium cultiva'Aroma Pink' |
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KR101614066B1 (en) * | 2014-10-14 | 2016-04-20 | (주)더페이스샵 | Perfume composition for expressing the fragrance of Citrus reticulate |
KR102406007B1 (en) * | 2015-02-06 | 2022-06-08 | (주)아모레퍼시픽 | Perfume composition for expressing the fragrance of Citrus |
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- 2019-01-24 JP JP2019010150A patent/JP7258395B2/en active Active
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JPH11269482A (en) * | 1998-03-24 | 1999-10-05 | Shiseido Co Ltd | Orchid-like perfume composition |
JP2003300811A (en) * | 2002-04-05 | 2003-10-21 | Lion Corp | Composition containing rosmarinic acid |
CN102170859A (en) * | 2008-10-28 | 2011-08-31 | 株式会社爱茉莉太平洋 | Perfume composition for expressing the fragrance of silk tree flower |
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JP2019147942A (en) | 2019-09-05 |
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