KR102428986B1 - Perfume composition for reproducibly expressing the fragrance of Nelumbo nucifera Gaertner - Google Patents

Abstract

The present invention relates to a perfume composition that reproduces the scent of white lotus, and more specifically, pentadecane and 1,4-dimethoxybenzene (1,4- Dimethoxybenzene), heptadecane, sabinene, limonene, myrcene, α-terpineol, etc., 2-Phenylethyl alcohol It relates to a perfume composition that reproduces the fragrance of white lotus with excellent palatability by adding it.
The perfume composition according to the present invention contains 2-phenylethyl alcohol along with the main ingredients for the scent of white lotus such as pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and α-terpineol. By containing it, the scent of white lotus can be reproduced, and the palatability of the scent can also be improved.

Description

Perfume composition for reproducibly expressing the fragrance of Nelumbo nucifera Gaertner

The present invention relates to a perfume composition that reproduces the scent of white lotus, and more specifically, pentadecane, 1,4-dimethoxybenzene (1,4- Dimethoxybenzene), heptadecane, sabinene, limonene, myrcene, α-terpineol, etc., 2-Phenylethyl alcohol It relates to a perfume composition that reproduces the fragrance of white lotus with excellent palatability by adding it.

The lotus flower ( Nelumbo nucifera Gaertner) is a perennial herbaceous plant belonging to the water lily family. It is a plant that grows in ponds and is also cultivated in paddy fields. Roots extend sideways, are columnar, and have many nodes, and the tip becomes especially thick in autumn. The leaves emerge from the rhizome and rise high above the water, close to a circle, white green, with veins spreading in all directions, about 40cm in diameter, and are not easily wet by water. Petiole (葉柄: petiole) is columnar and has short thorn-like projections. Flowers bloom in July and August and are 15-20 cm in diameter and are light red or white. The flower stalk has thorns like a petiole and has 1 flower at the end. The calyx is green and falls early, and the petals are 8~12cm long and 3~7cm wide, obovate and blunt. The fruit is oval in shape and can be eaten as about 2 cm in length. The place of origin is India, and it has been cultivated in Korea for about 500 years (Encyclopedia of Korean National Culture, Central Research Institute of Korean Studies). In particular, baeknyeon (Hoesan baeknyeon), which inhabits a lot in Muan, Jeollanam-do, is the lotus flower ( Nelumbo ). nucifera Gaertner) has the same scientific name, but leaves, flowers, roots, and stems are larger than other lotuses, and the edge of the bud has a red color. As time goes by, it gradually turns white and the petals begin to fall from the third day of flowering.

Despite the fact that white lotus has a considerable value as a fragrance due to its rich fragrance, scientific research to reproduce the fragrance of white lotus is insufficient. In particular, Muan white lotus flower has a special scent due to the geographical and soil characteristics of Muan, Jeollanam-do, so research as a fragrance began.

There may be many ways to reproduce the scent of this Muan white lotus flower. For example, there are a solvent extraction method for making the fragrance component of Muan white lotus into an absolute form by a conventional method, and a steam distillation method for making the fragrance component into an essential oil. However, since the above methods require high heat in the extraction process and the processing process is complicated and takes a lot of time, there may be a lot of difference from the original flavor, and in the case of Muan white lotus, which has a small number of individuals, sufficient raw materials It has limitations in that it is difficult to supply.

Recently, to compensate for these shortcomings, head space methods including SPME (Solid Phase Micro Extraction; SUPELCO international, Vol.13, No.4, p.9-10) have been developed. became Unlike the conventional extraction method, the head space method does not use a solvent and does not require pre-treatment, so it has the advantage of being able to quickly and easily analyze odor components. On the other hand, although odor components with good volatility are easy to analyze, odor components with low volatility or high molecular weight are not easily analyzed by this method.

On the other hand, GC (Gas Chromatography) is a very useful instrumental analysis for qualitative and quantitative analysis of volatile substances, so it is widely used for analysis of all odor components. However, there are perfume components that have a very low threshold value and express a strong fragrance even at a low concentration, while there are also volatile components that cannot express a fragrance even at a high concentration because the threshold value is very high. Therefore, it cannot be simply said that the volatile component quantitatively and predominantly found through GC is the main odor component of a specific substance. In order to solve this problem, the method of GC-O (Gas Chromatography Olfactometry, Guth H, Grosch W (1993) Lebensm Wiss U Technol, 196, 22-28) has been developed and used. GC-O is a method to analyze the fragrance component through the peak of the chromatogram, and at the same time directly smell the fragrance, and identify the component that does not appear as a peak but actually produces the fragrance.

Therefore, the present inventors tried to reproduce the scent of Muan white lotus by using the SPME method, which is effective for analyzing scent substances of living natural products. Although it was not possible to reproduce the scent of Muan white lotus with only the main component of the scent analyzed by SPME method, when 2-phenylethyl alcohol is used here, the unique scent of Muan white lotus can be reproduced and excellent palatability. Found and completed the present invention.

Accordingly, it is an object of the present invention to provide a perfume composition that reproduces the unique scent of Muan White Lotus.

Another object of the present invention is to provide a composition for external application for skin and an article for fragrance containing the fragrance composition.

In order to achieve the above object, the present invention provides a perfume composition that reproduces the smell of white lotus, containing the perfume component of white lotus and 2-phenylethyl alcohol.

The present invention also provides a composition for external application to the skin and an article for fragrance containing the perfume composition.

The perfume composition according to the present invention contains 2-phenylethyl alcohol along with the main ingredients for the scent of white lotus such as pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and α-terpineol. By containing it, the scent of white lotus can be reproduced, and the palatability of the scent can also be improved.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In general, the nomenclature used herein is those well known and commonly used in the art.

The present invention is a white lotus flower ( Nelumbo nucifera pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene And α-terpineol (α-terpineol) and an artificial synthetic material 2-phenylethyl alcohol (2-Phenylethyl alcohol) as active ingredients It relates to a perfume composition that reproduces the scent of white lotus flowers.

In addition, the perfume composition includes β-caryophyllen, 1,8-cineole, terpinen-4-ol, linalool, α-pinene. (α-pinene), α-thujene (α-thujene), β-pinene (β-pinene), and α-terpinene (α-terpinene) may be characterized in that it further contains as a secondary fragrance component.

Hereinafter, the present invention will be described in more detail.

The composition according to the present invention contains, as an essential component, 2-phenylethyl alcohol, an artificial synthetic material, along with the fragrance component of the white lotus flower, in particular, the fragrance component of the white lotus flower living in Hoesan white lotus in Muan, Jeollanam-do. By reproducing the original scent, it can increase the similarity of the scent with the actual Muan white lotus and show excellent palatability. White lily of the same species ( Nelumbo nucifera ) Gaertner) can have a special smell depending on the geographical and soil characteristics of the habitat. %, 1-Heptadecene (1-Heptadecene) 16.57% by weight, 6(Z),9(E)-Heptadecadiene (6(Z),9(E)-Heptadecadiene) 15.28% by weight, 1-pentadecene ( 1-Pentadecene) 7.59% by weight, Nonadecane 4.15% by weight, Heptadecane 2.67% by weight, Dimethyl hydroquinone 2.05% by weight, etc. It can be seen from the fact that there is a significant difference from the main odor component of

Among the fragrance components of white lotus of the present invention, pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, α-terpineol, etc. may be used as main components, and minor components As the examples, β-caryophyllene, 1,8-cineol, terpinenol, linalool α-pinene, α-tuzen, β-pinene, α-terpinene, and the like may be used.

The perfume composition according to the present invention contains 23 to 44% by weight of pentadecane, preferably 30 to 35% by weight, and 23 to 44% by weight of 1,4-dimethoxybenzene, preferably 30 to based on the total weight of the composition. 35% by weight, 6 to 14% by weight of heptadecane, preferably 8 to 12% by weight, 4.5 to 6.5% by weight of sabinene, preferably 5.2 to 5.9% by weight, 1.5 to 3.5% by weight of limonene, preferably 1.8 to 2.8% by weight, myrcene 1-3% by weight, preferably 1.8 to 2.3% by weight, α-terpineol 1 to 2.6% by weight, preferably 1.4 to 2.2% by weight, β-caryophyllene 1.5 to 3.5% by weight, preferably 2 to 3% by weight, 1,8-cineol 1-3% by weight, preferably 1.5 to 2.5% by weight, 0.8 to 2.8% by weight of terpinenol, preferably 1.3 to 2.3% by weight, 0.6 to 1.8% by weight of linalool, preferably 0.9 to 1.5% by weight, 0.5 to 1.1% by weight of α-pinene, preferably 0.6 to 1% by weight, and 0.5 to 0.9 of α-Tyuzen % by weight, preferably 0.6 to 0.8% by weight, 0.28 to 0.68% by weight of β-pinene, preferably 0.38 to 0.58% by weight, 0.2 to 0.5% by weight of α-terpinene, preferably 0.3 to 0.4% by weight , and 2-phenylethyl alcohol in an amount of 1 to 3.5% by weight, preferably 2 to 3% by weight.

Pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, α-terpineol, and 2-phenylethyl alcohol, which are artificial synthetic substances, are the main ingredients for reproducing the scent of white lotus flowers. When used outside the range, the similarity of the scent to the white lotus is lowered, and the palatability of the scent is also lowered, so it is not preferable. However, other secondary components such as β-caryophyllene, 1,8-cineol, terpinenol, linalool, α-pinene, α-tuzen, β-pinene and α-terpinene may be used within the above range. However, since it does not significantly affect the scent of white lotus, it may be contained in an amount outside the above range as long as it does not affect the reproduction of the scent of white lotus.

In addition, the present invention relates to a composition for external application to the skin containing the perfume composition. The perfume composition according to the present invention includes perfume, softening lotion, astringent lotion, nourishing lotion, eye cream, nourishing cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence, shampoo, conditioner, pack, ointment, lotion, It can be formulated in bases for external use on the skin including cosmetics such as solubilization, suspension, emulsion, cream, gel, spray, patch, warning agent, patch, or water paste, but is not limited thereto, and any It can also be formulated for external use. The blending amount may be appropriately selected and blended to achieve the desired effect according to a conventional technique in the art.

The present invention also relates to an article for fragrance containing the perfume composition. The perfume composition according to the present invention may be commercialized as a perfume article by being included in a perfume, a deodorant, a diffuser, a candle, an oil, a gel, a bead, a plug-in, etc., but is not limited thereto.

Meanwhile, in the present invention, the SPME method may be used as a method for analyzing the fragrance component of white lotus flowers. The SPME method is advantageous for analyzing the fragrance components of white lotus flowers, which are highly volatile, because the analysis time can be greatly reduced as the odor components adsorbed on the fibers can be quickly desorbed and injected into the GS-MS column without special pretreatment. do. In addition, the SPME method is simpler and easier to concentrate than the existing pretreatment method, and it is not limited by the shape of the matrix. It has the advantage of increasing the credibility of the

In the present invention, a combination fragrance was prepared based on the fragrance component of white lotus flower analyzed by the SPME method, and the similarity to that of white lotus flower and the palatability of the fragrance were performed through olfactory sensory tests. The sensory test was conducted by professional perfumers and the general public, and the similarity to the scent of white lotus and the palatability of the scent were evaluated through a survey.

Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and it will be apparent to those of ordinary skill in the art that the scope of the present invention is not to be construed as being limited by these examples. Accordingly, the substantial scope of the present invention will be defined by the appended claims and their equivalents.

[Reference Example 1] Analysis of scent of white lotus flowers using SPME method

From Hoesan Baekryeonji, Illo-eup, Muan-gun, Jeollanam-do, a white lotus flower with a strong fragrance was selected and the fragrance component was collected by adsorbing the fragrance component emitted from the white lotus flower on a polyacrylate fiber coated with 85㎛ for 2 hours. . Collection took place over two days.

After the odor component was collected, the fiber was sealed, transferred to the GC-MS inlet, and then desorbed for 2 minutes, followed by GC-MS analysis. GC-MS analysis conditions are as follows.

analysis conditions

. Analyzer: HP 5890 II GC

. Detector: HP 5972 MSD

. Column: DB-1 (60m X 0.25mm X 0.25um)

. Carrier Gas: He

. Injection Temperature: 250℃

. Detector Temperature: 280℃

. Oven Temperature: 70℃~220℃(3℃/min)

. Ionization Voltage: 70 eV

. Desorption time: 2 minutes

As a result, the fragrance components of white lotus flowers analyzed by the SPME method are shown in Table 1 below.

spice name content(%) pentadecane 27.08 1,4-dimethoxybenzene 26.96 heptadecane 8.49 Sabinen 4.64 limonene 1.89 myrsen 1.63 α-terpineol 1.54 β-Caryophyllene 0.77 1,8-Cineole 0.63 Terpinenol 0.59 linalul 0.38 α-pinene 0.25 α-Tyuzen 0.22 β-pinene 0.15 α-terpinene 0.11 Etc 24.67 total 100

As shown in Table 1 above, white lotus flowers have pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and α-terpineol as main fragrance components, and these main components It was confirmed that it occupies 72.23% by weight of the total.

[Test Example 1] Comparative sensory evaluation of the fragrance prepared as a result of the analysis and the fragrance of natural white lotus flower

Based on the results analyzed in Reference Example 1, a freshly formulated fragrance (Sample B) having the composition shown in Table 2 was prepared, and the similarity of smell between this fragrance and natural white lotus flower (Sample A) was verified through sensory evaluation.

spice name content(%) pentadecane 27.08 1,4-dimethoxybenzene 26.96 heptadecane 8.49 Sabinen 4.64 limonene 1.89 myrsen 1.63 α-terpineol 1.54 β-Caryophyllene 0.77 1,8-Cineole 0.63 Terpinenol 0.59 linalul 0.38 α-pinene 0.25 α-Tyuzen 0.22 β-pinene 0.15 α-terpinene 0.11 DPG 24.67 total 100

The sensory evaluation was conducted on 20 normal men and women aged 20 to 45 years, and sample A of the fragrance component collected from natural white lotus flowers by the method of Reference Example 1 and sample B of the combined fragrance reproduced by the SPME method. The similarity of smell (question 1) and taste preference (question 2) of sample A and sample B were investigated by asking them to take it and answering the questionnaire in Table 3 below. The results are shown in Table 4.

survey
(1) Question 1: How similar is the smell of Sample A and Sample B?
1) Not at all similar.
2) Not very similar.
3) Just so.
4) are somewhat similar.
5) Very similar.
(2) Question 2: How much do you like the smell of Sample B?
1) Not good at all.
2) Not very good.
3) Just so.
4) Slightly good.
5) Very good.

evaluator Question 1 (similarity) Question 2 (symbolic) One 3 One 2 2 3 3 3 2 4 4 3 5 2 2 6 3 2 7 2 3 8 3 3 9 4 One 10 2 3 11 3 2 12 3 2 13 2 3 14 One 2 15 2 One 16 3 2 17 3 2 18 2 3 19 3 2 20 2 2 Average 2.6 2.2

As shown in Table 4, sample B, which is a fragrance combination, was found to have many differences from that of natural white lotus flowers, and it was confirmed that the palatability was also low.

[Test Example 2] Comparison of scent analysis with white lotus and scent analysis by a professional evaluation team

As shown in Test Example 1, the perfume composition artificially blended with the components analyzed by the SPME method had very low similarity to the natural white lotus scent.

Accordingly, a professional evaluation team composed of perfumers performed a sensory evaluation on each fragrance component of white lotus flower. As a result, pentadecane, which produces a waxy odor, 1,4-dimethoxybenzene, which creates a sweet green odor, and waxy odor, among the fragrance components of white lotus flowers Heptadecane, Sabinene for a woody spicy scent, Limonene for a sweet citrus scent, Myrcene for a peppery spicy scent, Pine woody ) It was confirmed that the seven components of α-terpineol, which produce a unique fragrance, are the main components that produce the unique fragrance of white lotus flowers.

[Example 1] Preparation of a new combination fragrance according to the change in the content of the main ingredient

From Test Example 2, it was confirmed that the main components of the original scent of white lotus were pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and α-terpineol. Accordingly, the present inventors prepared novel combination fragrances #1 to #4 as shown in Table 5 below to prepare a fragrance with good palatability while containing these seven components as it is, while showing the fragrance of white lotus flower.

Combination fragrances #1 to #4 were prepared by changing the total content of the seven fragrances to 80 to 95% by weight while maintaining the ratio of these seven main ingredients constant (unit: weight%). The specific composition is shown in Table 5 below.

spice name #One #2 #3 #4 (80% by weight) (85% by weight) (90% by weight) (95% by weight) pentadecane 29.99 31.87 33.74 35.62 1,4-dimethoxybenzene 29.87 31.74 33.60 35.47 heptadecane 9.41 9.99 10.58 11.17 Sabinen 5.13 5.46 5.78 6.10 limonene 2.09 2.22 2.35 2.48 myrsen 1.80 1.91 2.03 2.14 α-terpineol 1.70 1.81 1.91 2.02 β-Caryophyllene 4.97 3.73 2.48 1.24 1,8-Cineole 4.06 3.05 2.03 1.02 Terpinenol 3.81 2.85 1.90 0.95 linalul 2.45 1.84 1.23 0.61 α-pinene 1.61 1.21 0.81 0.40 α-Tyuzen 1.42 1.06 0.71 0.35 β-pinene 0.97 0.73 0.48 0.24 α-terpinene 0.71 0.53 0.35 0.18 total 100 100 100 100

[Test Example 3] Sensory evaluation of the perfumes prepared in Example 1

For the four fragrances (#1 to #4) of Example 1, which were newly combined, sensory evaluation was performed in the same manner as in Test Example 1 in order to examine the similarity and palatability to the scent of white lotus. On the other hand, after performing comparative sensory evaluation on the two combination fragrances, a rest period of 5 minutes was given so that there was no olfactory sensory paralysis. The sensory evaluation results regarding the similarity of smell and palatability of the new combination fragrance and white lotus flower are shown in Table 6 below.

evaluation
agent Question 1 (similarity) Question 2 (Preference) Combination Fragrance No. Combination Fragrance No. #One #2 #3 #4 #One #2 #3 #4 One 3 3 3 2 3 4 3 3 2 4 3 4 3 2 2 3 3 3 4 4 5 4 3 3 5 3 4 3 4 4 4 2 3 4 4 5 4 2 3 5 4 4 3 3 6 One 4 4 4 4 4 4 3 7 4 3 3 3 3 3 4 2 8 2 3 2 4 2 4 3 2 9 3 4 4 4 3 3 4 4 10 3 2 5 3 3 2 4 4 11 3 3 3 3 One 2 5 3 12 3 4 4 4 4 2 4 4 13 2 2 4 4 3 4 5 4 14 3 3 3 4 4 3 3 2 15 4 4 4 3 One 4 4 4 16 2 4 5 4 3 3 5 4 17 4 2 4 4 3 4 4 4 18 2 3 5 5 3 3 4 3 19 4 2 5 4 3 3 3 4 20 2 4 4 3 2 2 4 3 Average 3 3.15 3.9 3.7 2.8 3.1 3.9 3.3

As shown in Table 6, sample #3, which accounts for 90% by weight of the total content of the seven main components of the white lotus fragrance, was shown to have the best similarity and palatability among the four combined fragrances. However, it was found that both similarity and palatability did not meet expectations.

[Example 2] Preparation of fragrance improving fragrance by analysis of professional evaluation group

In order to improve the similarity and palatability of the fragrance of Sample #3, which is most similar to the fragrance of white lotus in Table 6, pentadecane, 1,4-dimethoxybenzene, heptadecane, and wasabi, as shown in Table 7 below. Nene, limonene, myrcene, and α-terpineol were maintained at a content of 90% by weight (same as sample #3 in Table 6), and 2-phenylethyl alcohol, an artificial synthetic material, was further added thereto. # Company's new combination fragrance sample was prepared.

At this time, by the judgment of the expert group of perfumers, 2-phenylethyl alcohol was selected as an artificial synthetic material and the content standard of 2-phenylethyl alcohol was set. Weight %, 2.0 wt %, 2.5 wt %, 3.0 wt %, and 3.5 wt % were added while changing, and other components were adjusted to match the total content of 100 according to the change in the content of 2-phenylethyl alcohol. The composition of these recombinant fragrances is shown in Table 7 below.

Combination spice number #go #me #all #la #mind #bar #buy spice name content(%) content(%) content(%) content(%) content(%) content(%) content(%) pentadecane 33.57 33.41 33.24 33.07 32.90 32.73 32.56 1,4-dimethoxybenzene 33.43 33.27 33.10 32.93 32.76 32.59 32.43 heptadecane 10.53 10.48 10.42 10.37 10.32 10.27 10.21 Sabinen 5.75 5.72 5.69 5.66 5.63 5.60 5.57 limonene 2.34 2.33 2.32 2.31 2.29 2.28 2.27 myrsen 2.02 2.01 2.00 1.99 1.98 1.97 1.96 α-terpineol 1.90 1.89 1.88 1.87 1.87 1.86 1.85 β-Caryophyllene 2.47 2.46 2.45 2.43 2.42 2.41 2.40 1,8-Cineole 2.02 2.01 2.00 1.99 1.98 1.97 1.96 Terpinenol 1.89 1.88 1.87 1.87 1.86 1.85 1.84 linalul 1.22 1.21 1.21 1.20 1.20 1.19 1.18 α-pinene 0.80 0.80 0.79 0.79 0.79 0.78 0.78 α-Tyuzen 0.71 0.70 0.70 0.70 0.69 0.69 0.68 β-pinene 0.48 0.48 0.48 0.47 0.47 0.47 0.47 α-terpinene 0.35 0.35 0.35 0.35 0.35 0.34 0.34 2-phenylethyl alcohol 0.50 1.00 1.50 2.00 2.50 3.00 3.50 total 100.00 100.00 100.00 100.00 100.00 100.00 100.00

[ comparative example ] 2- In addition to phenylethyl alcohol Manufacture of Recombinant Fragrance with Other Artificial Synthetic Substances

The content of Example 2 and the seven main fragrance components were the same, and instead of adding 2-phenylethyl alcohol as an artificial synthetic material, an artificial synthetic material hydroxycitronellal component or benzyl acetate ) components were added in an amount of 3.0 wt%, and samples of #a and #bar were prepared in the composition shown in Table 8 below.

Combination spice number #ah #ruler spice name content(%) content(%) pentadecane 32.73 32.73 1,4-dimethoxybenzene 32.59 32.59 heptadecane 10.27 10.27 Sabinen 5.60 5.60 limonene 2.28 2.28 myrsen 1.97 1.97 α-terpineol 1.86 1.86 β-Caryophyllene 2.41 2.41 1,8-Cineole 1.97 1.97 Terpinenol 1.85 1.85 linalul 1.19 1.19 α-pinene 0.78 0.78 α-Tyuzen 0.69 0.69 β-pinene 0.47 0.47 α-terpinene 0.34 0.34 hydroxycitronellal 3.0 0 benzyl acetate 0 3.0 total 100 100

[ test example 4] Example Sensory evaluation of the combined fragrances prepared in step 2

For the seven (#A~#Sa) combination fragrances of Example 2 and the two (#ah, #character) combination fragrances of the comparative example, find out the similarity of smell with white lotus and the palatability of smell In order to see, sensory evaluation was performed in the same manner as in Test Example 1. On the other hand, after performing comparative sensory evaluation on the two combination fragrances, a rest period of 5 minutes was given, so that there was no olfactory sensory paralysis. The smell similarity and flavor palatability results between the new combination perfume and white lotus flower are shown in Tables 9 and 10 below.

evaluator Question 1 (similarity) Question 2 (Preference) Combination Fragrance No. Combination Fragrance No. #go #me #all #la #mind #bar #buy #go #me #all #la #mind #bar #buy One 3 4 4 4 5 5 3 5 2 5 5 5 4 4 2 5 3 4 4 5 5 4 3 4 5 4 5 4 3 3 5 4 5 5 4 5 5 4 4 4 5 4 5 3 4 3 4 4 4 5 4 4 2 4 3 4 5 5 3 5 2 5 3 5 4 3 3 4 4 3 5 4 5 4 6 5 4 4 4 4 4 4 3 4 4 4 5 3 5 7 5 3 3 3 4 5 3 2 3 3 5 4 4 5 8 3 4 3 4 5 5 5 4 4 3 4 5 5 4 9 3 4 4 4 5 5 4 5 4 4 5 5 5 4 10 5 5 5 4 4 5 5 5 5 4 5 4 5 5 11 4 3 5 4 5 5 3 4 3 3 4 5 5 3 12 3 4 4 5 4 4 4 3 4 5 5 3 4 4 13 4 5 5 5 5 5 5 4 5 5 5 3 5 5 14 2 4 5 5 5 5 4 2 4 5 5 5 5 4 15 5 3 4 3 4 4 3 5 3 4 5 4 4 3 16 4 4 5 5 5 5 4 4 4 5 4 5 5 4 17 4 4 4 4 3 4 4 4 4 4 4 3 4 4 18 3 5 5 3 5 5 5 5 5 5 3 5 5 4 19 5 4 5 4 5 5 4 5 4 5 4 5 5 5 20 4 3 4 3 5 5 3 4 3 4 3 5 5 4 Average 3.85 3.95 4.25 4.1 4.55 4.65 3.95 3.85 3.85 4.15 4.4 4.45 4.6 4

evaluator Question 1 (similarity) Question 2 (Preference) Combination Fragrance No. Combination Fragrance No. #ah #ruler #ah #ruler One 3 3 3 5 2 4 3 3 3 3 4 4 3 4 4 3 4 5 2 5 2 5 4 4 6 5 4 4 3 7 5 3 5 2 8 3 4 4 4 9 4 4 3 5 10 4 3 3 5 11 4 3 2 4 12 3 4 4 3 13 3 5 2 4 14 4 2 3 2 15 3 5 4 5 16 4 4 4 4 17 4 3 4 4 18 3 5 5 5 19 5 4 4 5 20 4 3 5 4 Average 3.7 3.75 3.7 3.85

As shown in Table 9, pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and α-terpineol are the main fragrance components of white lotus, 2-phenylethyl alcohol In the case of #da, #la, #ma, and #bar containing in the range of 1.5 to 3.0% by weight, it was confirmed that the similarity of the smell and the palatability were high (average more than 4.0). In particular, in the case of #ra, #ma, and #bar containing 2-phenylethyl alcohol in the range of 2.0 to 3.0% by weight, the scent similarity to white lotus and flavor palatability are very excellent, so that the scent of white lotus can be reproduced well. It could be confirmed that it could be possible (average 4.4 or higher).

On the other hand, it was found that when 2-phenylethyl alcohol was contained in an amount of less than 1.5% by weight or more than 3% by weight, the similarity and palatability of the smell were rather lowered.

In addition, as shown in Table 10, when a hydroxycitronellal component or a benzyl acetate component other than 2-phenylethyl alcohol as an artificial synthetic material is contained in an amount of 3.0% by weight, the similarity and palatability of 2-phenylethyl alcohol It was found that it was significantly lower than the case containing From this, it was confirmed that 2-phenylethyl alcohol was most suitable as an artificial synthetic material that can maximize palatability while reproducing the scent of white lotus flowers.

[ Example 3] Manufacture of fragrance containing only the main fragrance component of white lotus and artificial synthetic materials

In the component composition of sample #da~#bar in Table 7, which had high odor similarity and palatability with white lotus, secondary odor components were excluded, and the content of seven main odor components and an artificial synthetic material, 2-phenylethyl alcohol Samples #tea ~ #green onion, which are combination fragrances containing different , were prepared (Table 11).

Combination spice number #car #card #get on #green onion spice name content(%) content(%) content(%) content(%) pentadecane 33 33 33 33 1,4-dimethoxybenzene 33 33 33 33 heptadecane 10 10 10 10 Sabinen 6 6 6 6 limonene 3 3 3 3 myrsen 2 2 2 2 α-terpineol 2 2 2 2 2-phenylethyl alcohol 1.5 2.0 2.5 3 DPG 9.5 9 8.5 8 total 100 100 100 100

As a result of conducting the same sensory evaluation as in Test Example 1 for odor similarity and palatability of the samples of Table 11, #cha to #wave, the similarity showed an average of 4.45 points, and the palatability was an average of 4.50 points, and secondary It was confirmed that even if the phosphorus odor component was excluded, the odor similarity and palatability with the white lotus flower could be maintained to a certain degree.

[Formulation example]

As described above, a perfume composition (sample # bar in Table 7) having a similar smell to that of white lotus was mixed with alcohol, water, a colorant, and a sunscreen, to prepare the perfume of Table 12 below.

Perfume containing a perfume composition that reproduces the scent of white lotus flowers Combination fragrance that reproduces the scent of white lotus
Alcohol
water
pigment
sunscreen 15% by weight
83 wt%
2% by weight
appropriate amount
appropriate amount

As described above in detail a specific part of the content of the present invention, for those of ordinary skill in the art, this specific description is only a preferred embodiment, and it is clear that the scope of the present invention is not limited thereby. something to do. Accordingly, it is intended that the substantial scope of the present invention be defined by the appended claims and their equivalents.

Claims (8)

The main odor component and the secondary odor component of white lotus flower; And 2-phenylethyl alcohol (2-Phenylethyl alcohol) containing as an active ingredient, as a perfume composition that reproduces the scent of white lotus,
The main fragrance ingredients are pentadecane, 1,4-dimethoxybenzene, heptadecane, sabinene, limonene, myrcene, and Consists of α-terpineol (α-terpineol),
The secondary fragrance component is β-caryophyllen, 1,8-cineole, terpinen-4-ol, linalool, α-pinene (α-pinene), α-thujene (α-thujene), β-pinene (β-pinene), and α-terpinene (α-terpinene), characterized in that consisting of, a fragrance reproducing the scent of white lotus flowers composition. According to claim 1, wherein the perfume composition, pentadecane 23 to 44% by weight, 1,4-dimethoxybenzene 23 to 44% by weight, heptadecane 6 to 14% by weight, sabinene 4.5 to 6.5 with respect to the total weight of the composition Weight%, limonene 1.5 to 3.5% by weight, myrcene 1-3% by weight, and α- terpineol 1 to 2.6% by weight, characterized in that it contains a perfume composition that reproduces the scent of white lotus. According to claim 1, wherein the perfume composition, β- caryophyllene 1.5 to 3.5% by weight, 1,8-cineol 1-3% by weight, terpinenol 0.8 to 2.8% by weight, linalool 0.6 with respect to the total weight of the composition -1.8 wt%, α-pinene 0.5-1.1 wt%, α-Tyuzen 0.5-0.9 wt%, β-pinene 0.28-0.68 wt%, and α-terpinene 0.2-0.5 wt%, A perfume composition that reproduces the scent of white lotus flowers. The perfume composition according to claim 1, wherein the 2-phenylethyl alcohol is contained in an amount of 1.5 to 3.0% by weight based on the total weight of the composition. A composition for external application to the skin comprising the fragrance composition of any one of claims 1 to 4. An article for fragrance containing the perfume composition of any one of claims 1 to 4. delete delete