KR101790180B1 - Perfume composition for expressing the fragrance of Dictamus dasycarpus and the composition for skin external application containing the same - Google Patents

Abstract

The present invention relates to a perfume composition recreating the fragrance of Dictamus dasycarpus and a composition for external application for skin containing the same, and more particularly, A fragrance composition having excellent palatability while reproducing fragrance inherent to white ginseng flower by preparing ocimene, hexanol and benzaldehyde as major fragrance components and adding hedione thereto, To a composition for external application for skin.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition recreating the fragrance of white flowers, and a composition for external application for skin containing the fragrance composition,

The present invention relates to a perfume composition recreating the fragrance of Dictamus dasycarpus and a composition for external application for skin containing the same, and more particularly, A fragrance composition having excellent palatability while reproducing fragrance inherent to white ginseng flower by preparing ocimene, hexanol and benzaldehyde as major fragrance components and adding hedione thereto, To a composition for external application for skin.

It is a perennial herb that is native to the forests of the low tide forests of the southern, central and northern parts of Korea, or the prairies of the both sides. It has a plant height of around 90 cm, roots are medium quality (meat quality), rough and long, . The stem is straight and the bottom is made of wood. Usually there are no hairs in the plant, but a few are rare, but not in the base. Leaves are alternate phyllotaxis of odd-numbered pinnate with 9 ~ 13 leaflets. They usually gather closely in the middle of stem and have petiole. Large flowers bloom from May to June at the end of the stem. Flower stems and flower faucets have dense black spots and dense white hairs. It has 5 petals, long elliptical shape, with a sharp tip at the end, and the bottom is gradually tapered to form a phoenix, with a light red to white color and a petal at the bottom. Flowers and leaves also have a strong flammable substance called "Gas plant" or "Burning bush". In autumn, the roots are peeled off and dried in the sun called white radish (白 鮮 皮), which is used in detoxification, jaundice and cardiovascular treatment.

Generally, there are a variety of methods for reproducing the fragrance of natural products. For example, there are a solvent extraction method for converting the fragrance component of a natural product into an absolute form, a steam extraction method for converting a fragrance component into an essential oil, There is distillation. However, since the above methods require high heat during the extraction process and the processing is complicated and takes a long time, there may be many differences from the original flavor.

As a result of analyzing the scent of white flowers using SPME method, the present inventors found that ocimer, hexanol and benzaldehyde are the main components of white scent flowers and tried to reproduce the scent of white scent flowers using them. However, as a result of the sensory evaluation, the inventors of the present invention found that these components alone can not reproduce the scent of white flowers.

Accordingly, the inventors of the present invention found that a perfume composition containing Hedione, which is an artificial synthetic material, together with the principal component of the white rosacea fragrance can reproduce the original fragrance of white rosemary flowers and exhibits excellent palatability and completes the present invention Respectively.

Accordingly, an object of the present invention is to provide a perfume composition having excellent palatability while reproducing the inherent fragrance of white tiger flowers.

Another object of the present invention is to provide a skin external preparation containing the above-mentioned perfume composition.

In order to achieve the above-mentioned object, the present invention provides a flavor recollecting fragrance of a white flower by further adding a hedonic to a flavor component of a white flower comprising ocimene, hexanol and benzaldehyde Lt; / RTI >

The fragrance composition according to the present invention is composed of the white flower fragrance components analyzed by the SPME method, so that the fragrance of the white flower can be reproduced as it is and the palatability of the fragrance can be improved.

Hereinafter, the present invention will be described more specifically.

In the present invention, SPME (Solid Phase Micro Extraction; SUPELCO international, Vol.13, No.4, p.9-10), which is effective for analyzing the fragrance material of living natural products, The SPME method is capable of rapidly desorbing and injecting the fractions adsorbed on the fiber into the GS-MS column without any special pretreatment, so that the analysis time can be greatly shortened. Therefore, Do. In the present invention, based on the fragrance components of the tinea flowers analyzed by the SPME method, a combined fragrance was prepared, and the similarity to the tinea flowers and the taste preference of the tinea flowers were performed through the olfactory sensory test. The sensory evaluation was carried out by a professional irrigation and general person, and the similarity with the scent of white flowers and the preference of the fragrance were evaluated through questionnaires.

The perfume composition according to the present invention preferably contains 25 to 40% by weight of ocimer, 16 to 30% by weight of hexanol and 5 to 16% by weight of benzaldehyde based on the total weight of the composition. The perfume composition according to the present invention may contain the above three main fragrance components in an amount of 60 to 70% by weight based on the total weight of the composition.

In order to improve the palatability, the fragrance composition according to the present invention may further contain 3 to 7% by weight, more preferably 4 to 6% by weight, of hedeson, which is an artificial synthetic material, ≪ / RTI >

In addition, the perfume composition according to the present invention may further include fragrance components identified as secondary components of white rosacea fragrance in addition to the above-mentioned components. For example, isoprene (iso-Prene) in an amount of 6 to 16% 6 to 16% by weight of hexane, 4 to 12% by weight of Myrcene and 2 to 10% by weight of Linalool.

In the present invention, when ocimene, hexanol, benzaldehyde and hedzone, which are main components used to reproduce the white floral scent, are used in a range outside the above range, the similarity of the fragrance with the white flower is lowered and the palatability of the fragrance is also lowered I do not. However, other components (secondary fragrance components) are preferably used within this range, but as long as they do not significantly affect the fragrance of the white flower, it does not affect the reproducibility of the white flower fragrance, It can also be contained in an amount that is excreted.

The present invention also relates to a composition for external application for skin containing a perfume composition recreating the above-mentioned white scarlet flower scent. That is, the perfume composition of the present invention combined in the above-described ranges can be blended in a skin external base such as perfume and cosmetics, and the blending amount can be appropriately selected in order to achieve the desired effect according to the conventional art, can do.

Examples of the external preparation for skin containing the perfume composition according to the present invention include ointments, lotions, soluble images, suspensions, emulsions, creams, gels, sprays, papermaking agents, But may be incorporated in any base known in the art.

Hereinafter, the present invention will be described more specifically with reference to examples and test examples. It is to be understood that the scope of the present invention is not limited to these embodiments and test examples, and that variations, substitutions, and insertions conventionally known in the art And this is also included in the scope of the present invention.

[Example 1] Flavor analysis of white ring flowers using SPME method

One fragrant white flower was selected and the fragrance component was collected by adsorbing the fragrance component to a polyacrylate fiber coated with 85 탆 of polyacrylate for 2 hours. The capture took place in Gapyeong-gun Mountain for three hours.

After capturing the fragrance components, the fiber was sealed, transferred to the inlet of GC-MS, desorbed for 2 minutes, and analyzed by GC-MS. GC-MS analysis conditions are as follows.

Analysis condition

· Analytical instrument: HP 5890 II GC

· Detector: HP 5972 MSD

Column: DB-1 (60 m x 0.25 mm x 0.25 m)

· Carrier gas: He

Injection Temperature: 250 ° C

Detector Temperature: 280 ° C

Oven Temperature: 70 to 220 DEG C (3 DEG C / min)

Ionization Voltage: 70 eV

· Removal time: 2 minutes

As a result, the fragrance components of the tinea flowers analyzed by the SPME method are shown in Table 1 (unit: wt%).

Fragrance component content Ochemen 31.6 Hexanol 21.5 Benzaldehyde 10.8 Isoprene 8.9 Hexane 7.3 Mirsen 6.1 Linalool 5.6 Other 8.2 Total content 100.0

In the results shown in Table 1, it was confirmed that the white filament flowers contained ocimene, hexanol and benzaldehyde as major fragrance components, and these main components accounted for 63.90% of the total.

[Example 2] Preparation of combined fragrance

Based on the results analyzed in Example 1 above, a newly prepared combined fragrance (Sample B) having the composition shown in Table 2 below was prepared (unit: wt%).

Fragrance component content Ochemen 31.6 Hexanol 21.5 Benzaldehyde 10.8 Isoprene 8.9 Hexane 7.3 Mirsen 6.1 Linalool 5.6 DEP (solvent) 8.2 Total content 100.0

[Test Example 1] Sensory evaluation comparing the flavor of the combination fragrance and natural white flower

The fragrance similarity of the combined fragrance (sample B) prepared in Example 2 and the natural white flowers (sample A) was verified through sensory evaluation.

The sensory evaluation was carried out on 20 normal male and female twenty to forty five year olds. The sample A of the white flower pollen and the sample B of the combined fragrance reproduced by the SPME method were taken respectively, (Question 1) and palatability (Question 2) of Sample A and Sample B were examined, and the results are shown in Table 4 below.

survey
(1) Question 1: How similar are samples A and B?
1) It is not at all similar.
2) Not very similar.
3) Just so.
4) Somewhat similar.
5) Very similar.

(2) Question 2: How much do you like the smell of Sample B?
1) Not at all good.
2) Not very good.
3) Just so.
4) Somewhat good.
5) Very good.

Rating agent Question 1 (similarity) Question 2 (palatability) One 2 2 2 2 2 3 3 2 4 2 2 5 2 One 6 2 2 7 3 3 8 2 One 9 2 3 10 2 2 11 2 2 12 2 2 13 2 2 14 One 2 15 2 2 16 3 3 17 2 2 18 2 One 19 2 2 20 2 2 Average 2.10 2.00

In the results of Table 4, Sample B, which is a combination fragrance, showed a large difference from the flower flavor (Sample A) of white flower pollen, and the palatability was also low.

[Test Example 2] Flavor analysis by a professional evaluation team

As shown in Test Example 1, the fragrance composition composed of the components analyzed by the SPME method had no similarity with the white flower. Thus, the professional team composed of the irrigation scorers performed sensory evaluation on each of the scent components of the white iris.

As a result, three components of benzaldehyde, which produces oscimene, green fragrance and sweet fresh fragrance which produce herbal fragrance among the fragrance components of white purple flowers, It was confirmed that it is the main ingredient which produces the unique fragrance of white flower.

[Example 3] Production of new combination fragrance according to change of main component content of white rosacea fragrance

From the results of Test Example 2, it can be confirmed that the main component of the original scent of white flowers is ocimer, hexanol and benzaldehyde. Therefore, the inventors of the present invention made the new combination fragrances of the following # 1 to # 4 in order to produce a fragrance with good taste while showing the fragrance of the white flower containing these three components.

Combination fragrances # 1 to # 4 were prepared (unit: wt%) while keeping the ratio of the three components constant as shown in Table 5 below. At this time, the content of the three fragrance components was changed to 50 to 80 wt%.

Fragrance component #One #2 # 3 #4 Ochemen 25.7 28.6 33.5 39.3 Hexanol 16.5 21.5 24.6 28.2 Benzaldehyde 7.8 9.9 11.9 12.5 Isoprene 16 12.8 9.6 6.4 Hexane 15.4 12.3 9.2 6.1 Mirsen 10.2 8.2 6.2 4.1 Linalool 8.4 6.7 5 3.4 Total content 100 100 100 100 Three main ingredients 50 60 70 80

[Test Example 3] Sensory evaluation of the combined flavorings prepared in Example 3

Sensory evaluation of similarity and palatability to white scarlet flower scent was carried out on the four newly combined fragrances in the same manner as in Test Example 1. On the other hand, after performing the comparative sensory evaluation on the two fragrances, a resting time of 5 minutes was given to prevent post-sensory paralysis. The results of the sensory evaluation on the fragrance similarity and palatability of the new combination fragrance and the white flower are shown in Table 6 below.

evaluation
agent Question 1 (similarity) Question 2 (palatability) #One #2 # 3 #4 #One #2 # 3 #4 One 3.0 3.0 4.0 3.0 2.0 3.0 3.0 2.0 2 2.0 2.0 3.0 3.0 2.0 2.0 3.0 3.0 3 3.0 3.0 4.0 3.0 3.0 3.0 4.0 3.0 4 2.0 2.0 3.0 3.0 2.0 2.0 3.0 2.0 5 2.0 3.0 4.0 2.0 2.0 3.0 4.0 4.0 6 2.0 3.0 3.0 3.0 1.0 2.0 4.0 2.0 7 2.0 3.0 4.0 3.0 2.0 3.0 4.0 3.0 8 3.0 4.0 5.0 3.0 2.0 2.0 3.0 3.0 9 1.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 10 2.0 3.0 3.0 3.0 2.0 2.0 4.0 2.0 11 3.0 2.0 4.0 3.0 3.0 2.0 4.0 2.0 12 3.0 1.0 4.0 2.0 2.0 2.0 3.0 3.0 13 2.0 2.0 3.0 3.0 2.0 3.0 4.0 3.0 14 3.0 2.0 5.0 2.0 3.0 3.0 5.0 2.0 15 2.0 3.0 3.0 3.0 1.0 3.0 3.0 3.0 16 2.0 2.0 4.0 3.0 2.0 2.0 4.0 2.0 17 2.0 3.0 4.0 3.0 2.0 3.0 5.0 2.0 18 2.0 2.0 4.0 2.0 1.0 2.0 4.0 2.0 19 2.0 3.0 3.0 3.0 2.0 1.0 3.0 3.0 20 2.0 3.0 4.0 3.0 3.0 3.0 2.0 3.0 Average 2.3 2.6 3.7 2.8 2.1 2.5 3.6 2.6

In the results of Table 6 above, Sample # 3, in which the total content of the three fragrance main constituents was 70% by weight, was found to have the highest similarity and palatability among the four combined fragrances, but both similarity and palatability were not satisfied appear.

[Example 4] Preparation of flavor improving fragrance by analysis of a professional evaluation team

In order to improve the similarity and palatability of the fragrance of sample # 3 in which the flavor of white flower appeared to be most similar in Table 6, ocimer, hexanol and benzaldehyde were contained in an amount of 70% by weight as in Sample # 3 , And here, a new combination fragrance was prepared using a heddione which has a unique flavor for reproduction of the white flower scent. At this time, the haze was added in an amount of 2.0, 3.0, 4.0, 5.0, 6.0, 7.0 and 8.0 wt%. The criterion of the content of hedgeon was determined by the judgment of the specialist group. The compositions of these recombinant flavors are shown in Table 7 below (unit: wt%).

Fragrance component #end #I #All #la #hemp #bar #four Ochemen 33.5 33.5 33.5 33.5 33.5 33.5 33.5 Hexanol 24.6 24.6 24.6 24.6 24.6 24.6 24.6 Benzaldehyde 11.9 11.9 11.9 11.9 11.9 11.9 11.9 Hedione 2.0 3.0 4.0 5.0 6.0 7.0 8.0 Isoprene 9.0 8.6 8.3 8.0 7.6 7.4 7.0 Hexane 8.6 8.3 8.0 7.7 7.4 7.0 6.8 Mirsen 5.8 5.6 5.4 5.2 5.0 4.8 4.6 Linalool 4.6 4.5 4.3 4.1 4.0 3.8 3.6 Total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[Test Example 4] Sensory evaluation of the combined flavorings prepared in Example 4

In the above, the sensory evaluation on the similarity and palatability of the fragrance with natural white flowers was carried out in the same manner as in Test Example 1 with respect to the fragrance of # to # combination. After performing a comparative sensory evaluation on the two fragrances, a resting time of 5 minutes was given to prevent posterior sensory paralysis. The results of the similarity and palatability of the new combination fragrance and the tangerine flower are shown in Table 8 below.

Rating agent Question 1 (similarity) Question 2 (palatability) #end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four One 3.0 4.0 4.0 5.0 4.0 3.0 2.0 2.0 3.0 4.0 4.0 4.0 3.0 3.0 2 2.0 3.0 4.0 5.0 4.0 3.0 2.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 3 3.0 3.0 3.0 4.0 4.0 2.0 2.0 2.0 3.0 4.0 5.0 4.0 3.0 2.0 4 3.0 3.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0 3.0 5 3.0 4.0 4.0 5.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 2.0 6 3.0 4.0 3.0 4.0 4.0 3.0 2.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 7 3.0 3.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 5.0 3.0 3.0 8 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 9 3.0 3.0 3.0 5.0 5.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 2.0 10 2.0 3.0 4.0 4.0 4.0 2.0 3.0 3.0 2.0 3.0 5.0 4.0 3.0 3.0 11 3.0 4.0 4.0 5.0 4.0 3.0 3.0 2.0 3.0 4.0 4.0 4.0 3.0 2.0 12 3.0 3.0 4.0 5.0 5.0 4.0 3.0 3.0 3.0 4.0 5.0 4.0 3.0 2.0 13 3.0 2.0 5.0 5.0 5.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 2.0 2.0 14 3.0 3.0 3.0 5.0 5.0 3.0 3.0 3.0 3.0 5.0 5.0 4.0 4.0 2.0 15 2.0 3.0 4.0 5.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 16 3.0 4.0 4.0 4.0 4.0 3.0 2.0 3.0 3.0 4.0 5.0 4.0 3.0 3.0 17 3.0 3.0 5.0 3.0 3.0 4.0 2.0 3.0 3.0 5.0 4.0 4.0 3.0 3.0 18 4.0 3.0 4.0 4.0 4.0 4.0 2.0 2.0 4.0 4.0 4.0 4.0 3.0 2.0 19 2.0 3.0 3.0 5.0 4.0 4.0 2.0 3.0 3.0 4.0 5.0 4.0 2.0 3.0 20 2.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0 Average 2.9 3.3 3.9 4.4 4.1 3.2 2.6 2.8 3.2 3.8 4.3 3.9 3.0 2.6

From the results shown in Table 8, it was confirmed that when the main component of the white line flower scent of ocimer, hexanol and benzaldehyde contains 3.0 to 7.0% by weight of heddione, the fragrance of white ring can be reproduced and the palatability is high Average 3.0 or higher). Particularly, when 4.0 to 6.0 wt% of hedione was contained, it was found that the fragrance similarity and flavor preference with white flower were excellent (average 3.5 or more).

On the other hand, it was found that the similarity and palatability of the fragrance were lowered when the content of the haze was less than 3.0 wt% or more than 7.0 wt%.

[Production Example 1]

A perfume composition containing the perfume composition recreating the white scarlet flower scent with the composition shown in Table 9 below was prepared (unit: wt%).

ingredient content Spice combination of white rose flower fragrance
(# To # bar in Example 4) 15 Alcohol 83 water 2 Pigment Suitable amount Sunscreen Suitable amount

Claims (6)

To the fragrance component of the tinea flower composed of ocimene, hexanol and benzaldehyde,
A fragrance composition for reproducing the scent of white flowers by further adding Hedione,
Wherein the composition contains 29.0 to 39.0% by weight of o-cymene, 22.0 to 28.0% by weight of hexanol, 10.0 to 12.0% by weight of benzaldehyde and 3.0 to 7.0% by weight of hedonic acid based on the total weight of the composition,
Wherein the perfume composition further comprises 6 to 16 wt% of isoprene, 6 to 16 wt% of hexane, 4 to 12 wt% of myrcene, and 2 to 10 wt% of linalool, based on the total weight of the composition. The perfume composition according to claim 1, wherein the fragrance component of the tinea flower is contained in an amount of 60 to 70% by weight based on the total weight of the composition. delete delete delete A cosmetic composition comprising the perfume composition of claim 1 or 2.