KR100687624B1 - Perfume composition for expressing the fragrance of narcissus tazetta var. chinensis - Google Patents

Abstract

A perfume composition for expressing fragrance of Narcissus tazetta var. chinensis is provided to reproduce fragrance of Narcissus tazetta var. chinensis and improve preference of the perfume by identifying fragrance components of Narcissus tazetta var. chinensis and adding synthetic material. The perfume composition for expressing fragrance of Narcissus tazetta var. chinensis comprises 39-51 wt.% of benzyl acetate, 17-24 wt.% of ocimene, 3-5 wt.% of linalool, 9.2-10.2 wt.% of phenylpropyl acetate, 7.2-8.7 wt.% of 1,8-cineol, 4.3-5.1 wt.% of phenylethyl acetate, 0.5-0.6 wt.% of indole, 0.6-0.9 wt.% of limonene, 0.6-0.8 wt.% of benzyl alcohol, 0.3 wt.% of benzaldehyde, 0.3-0.4 wt.% of methyl benzoate and 3-7 wt.% of methyl dihydrojasmonate. A skin external composition comprises the perfume composition for expressing fragrance of Narcissus tazetta var. chinensis.

Description

Perfume composition for expressing the fragrance of Narcissus tazetta var. chinensis}

The present invention relates to methyl dihydrojasmonate, which is an artificial synthetic material, in benzyl acetate, Ocimene, Linalool, etc., analyzed as a fragrance component of Geomundo narcissus by SPME method. The present invention relates to a perfume composition having excellent palatability while reproducing the inherent odor of narcissus by containing.

Narcissus is a perennial bulb of Liliumaceae Narcissus family, which is native to all over the world, and stands out at an angle with linear leaves from the egg-shaped scaly line. A flower stem comes out between the leaves and grows straight about 20 ~ 40㎝, and 5 ~ 6 flowers grow to the side at the end of the flower stem. The calyx segment is 6, white, and the hatch tube is 4mm in height and yellow.

Among them, Narcissus tazetta var. chinensis is a type of lily of the valley , which blooms in early December compared to the narcissus poeticus and narcissus jonquilla , which blooms in Europe. The name is not widely known because it was not visible to people. However, the flower shape and color are beautiful, and the fragrance is also excellent, and the Geomundo is excellent in color and fragrance compared to the Japanese daffodil, which is the same. The shape of the flower is also neat and white petals have a golden crown (noble crown), which has nothing but elegance and aesthetic beauty.

There are many ways to recreate the scent of the noble Geomdo. For example, conventional methods include solvent extraction, which makes the fragrance component of Geomundo Narcissus into Absolute form, and steam distillation, which makes the fragrance component into essential oil. However, since the methods require high heat during the extraction process and the process is complicated and takes a lot of time, there may be a lot of difference from the original flavor.

Recently, the head space method and the SPME method have been developed to compensate for these disadvantages. Among them, the SPME method (Solid Phase Micro Extraction; SUPELCO international, Vol. 13, No. 4, p. 9-10), unlike conventional extraction methods, does not require solvents and does not require pretreatment. Can be analyzed.

Therefore, the present inventors attempted to reproduce the fragrance of Geomundo narcissus using the SPME method which is effective in analyzing the fragrance substances of living natural products. As a result, Benzyl acetate, Ocimene and Linalool were found to be the main components of Geomundo narcissus scent, and a combination perfume was prepared to reproduce the scent of Geomundo narcissus. . However, as a result of performing a sensory test on the combination perfume, it was found that only these components could not reproduce the smell of narcissus daffodil.

Accordingly, the present inventors have continued the research to reproduce the scent of Geomundo narcissus, as a result, benzyl acetate, occimen (Ocimene) and linalul (Linalool), such as artificial synthetic material in the fragrance component of narcissus daffodil The composition containing dihydrojasmonate as an essential component was found to exhibit excellent palatability while reproducing the intrinsic odor of geomundo narcissus, thus completing the present invention.

Accordingly, it is an object of the present invention to provide a fragrance composition which can reproduce the inherent odor of macrosomia narcissus and has excellent palatability.

Another object of the present invention is to provide an external preparation for skin containing the perfume composition as a component.

In order to achieve the above object, the composition according to the present invention is a benzyl acetate, Ocimene and Linalul (Linalool) as the main component of the narcissus daffodil odor, and phenylpropyl acetate as a secondary component ), 1,8-cineol, phenethylethyl, indole, limonene, benzyl alcohol, benzaldehyde, and methylbenzoate (1,8-cineol) Geomundo, consisting of Methyl benzoate, is characterized in that it contains, as an essential ingredient, methyl dihydrojasmonate as an artificial synthetic material in the odor component of narcissus.

Hereinafter, the present invention will be described in more detail.

The composition according to the present invention contains methyl dihydrojasmonate as an essential component in the fragrance component of Geomundo narcissus as an essential component, thereby reproducing the inherent odor of Geomundo narcissus and exhibiting excellent palatability. have.

The fragrance composition of the present invention comprises 39-51 wt% of Benzyl acetate, 17-24 wt% of Ocimene, and Linalool (Linalool) as a odor component of Geomundo narcissus with respect to 100 wt% of the composition. 3 to 5% by weight, 9.2 to 10.2% by weight of phenylpropyl acetate, 0.6 to 0.9% by weight of limonene, 7.2 to 8.7% by weight of 1,8-cineol , 4.3-5.1 wt% of phenethylethyl acetate, 0.5-0.6 wt% of Indole, 0.6-0.8% of Benzyl alcohol, 0.3 wt% of Benzaldehyde, methylbenzoate (Methyl benzoate) is contained in the range of 0.3 to 0.4% by weight, and methyl dihyfrojasmonate is contained in the range of 3 to 7% by weight as an artificial synthetic material. As the main ingredients for reproducing the Geomundo daffodil scent, benzyl acetate, ocimen, linalul and methyl dihydrojasmonate, an artificial synthetic material, when used in a range outside the above range, the odor similarity with that of the Geomundo daffodil is lowered, The palatability of is also lowered, which is not preferable. However, the other ingredients are preferably used within the above range, but since the content of macromolecule does not significantly affect the scent of narcissus, the content of macromolecule may be contained in an amount outside the range as long as it does not affect the reproduction of the narcissus odor. have.

The composition according to the present invention mixed in the above range may be blended into the skin external base such as perfume and cosmetics, and the blending amount may be appropriately selected and blended to achieve the desired effect according to the conventional techniques in the art. .

Such external base materials include, but are not limited to, ointments, lotions, soluble burns, suspensions, emulsions, creams, gels, sprays, papes, warning agents, patches or water pastes, and the like. It can be formulated in any base that has been formulated.

In the present invention, the SPME method was used as an analysis method for the fragrance component of Geomundo narcissus. The SPME method is advantageous for analyzing the fragrance component of narcissus, which has high volatility, because the fragrance components adsorbed on the fiber can be quickly desorbed and injected into the GS-MS column without any special pretreatment. In the present invention, a combination fragrance was prepared based on the fragrance components of the Geomundo daffodil analyzed by the SPME method, and the similarity with the Geomundo daffodil daffodil and palatability were carried out through olfactory sensory test. Sensory tests were conducted by professional steering staff and the general public, and similarity with the taste of Geomundo daffodil and palatability were evaluated by questionnaire.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto, and other applications, modifications, and the like of the present invention will be apparent to those skilled in the art.

[ Example ]

[Reference Example  One] SPME Perfume Analysis of Geomundo Daffodil Using

A scent of Geomundo narcissus was selected and the fragrance component was collected by adsorbing the fragrance component to the fiber (Polyacrylate Fiber) coated with 85 μm polyacrylate for 2 hours. The collection site was the low hill of Geomundo, located in Samsan-myeon, Yeosu-si, Jeollanam-do, and the collection took place for 2 hours.

After collecting the odor component, the fiber (Fiber) was sealed and transferred to the inlet of GC-MS, and then desorbed for 2 minutes, and GC-MS analysis was performed. GC-MS analysis conditions are as follows.

As a result, the fragrance components of Geomundo narcissus analyzed by the SPME method are shown in Table 1 below.

Spices people Content (% by weight) Benzyl acetate 56.600 Oshimen 26.000 Linalule 5.500 Phenylpropyl Acetate 3.650 1,8-cineol 3.100 Phenethyl acetate 1.780 Indole 0.500 Limonene 0.300 Benzyl alcohol 0.300 Benzaldehyde 0.100 Methyl benzoate 0.070 Etc 2.100 Total content 100.0000

As shown in Table 1, Geomundo narcissus contains benzyl acetate, osmenene, linalulol, phenylpropyl acetate, 1,8-cineol as main odorants, and these main components account for 94.85% of the total.

[Reference Example  2] between the fragrance and the odor of natural Geomundo daffodil Comparative sensory evaluation

Based on the results of the analysis, a newly prepared combination flavor (Sample B) having the composition of Table 2 was prepared, and the taste similarity between the perfume and natural daffodils was verified through sensory evaluation.

Spices people Content (% by weight) Benzyl acetate   56.600 Oshimen   26.000 Linalule   5.500 Phenylpropyl Acetate   3.650 1,8-cineol   3.100 Phenethyl acetate   1.780 Indole   0.500 Limonene   0.300 Benzyl alcohol   0.300 Benzaldehyde   0.100 Methyl benzoate   0.070 DEP (Solvent)   2.100 Total content  100.0000

The sensory evaluation was performed on 20 general men and women aged 20 to 45 years, and each sample A of Geomundo narcissus pollen and the smell of sample B of the combination perfume reproduced by the SPME method were asked to respond to the questionnaire of Table 3 below. The taste similarity (question 1) and palatability (question 2) of sample A and sample B were investigated by doing so. The results are shown in Table 4.

Questionnaire (1) Question 1: How similar are the smells of Sample A and Sample B? 1) Not at all similar 2) Not very similar. 3) It is so. 4) Somewhat similar. 5) very similar. (2) Question 2: How much do you like the smell of Sample B? 1) Not good at all 2) Not so good 3) It is so. 4) Slightly good 5) Very good

Evaluation Agent Question 1 (similarity) Question 2 (symbolic) One 2 2 2 2 2 3 One 2 4 3 3 5 3 3 6 2 2 7 2 3 8 One 2 9 3 2 10 2 2 11 3 2 12 3 One 13 2 3 14 2 3 15 2 2 16 3 2 17 2 One 18 One 2 19 One 2 20 3 3 Average 2.15 2.20

As shown in Table 4, Sample B of the combination fragrance was found to have a lot of difference with the floral scent of the narcissus pollen, and also showed a low palatability.

[Reference Example  3] by professional evaluation team Perfume Analysis  With daffodils Scent Comparison

As shown in Reference Example 1, the fragrance composition composed of the components analyzed by the SPME method did not have a similar effect to Geomundo daffodil. Therefore, a professional evaluation group composed of steering yarns performed sensory evaluation on each flavor component of Geomundo narcissus. As a result, among the fragrant ingredients of Geomundo Narcissus, Benzyl Acetate, which produces Jasmine, Ocimeneee, which produces citrus or anise, and Linalul, which produces sweet floral, The three components of (Linalool) were identified as the main ingredients that produce the unique scent of narcissus. In particular, the linalul present in the flower of the narcissus has more than 99% of the R-(-) form, which is softer than the S-(+) form and has a soft, natural, floral odor. It was confirmed that the more natural and elegant Geomundo expresses the scent of narcissus.

[ Example  One] Three  Preparation of New Combination Fragrances According to Changes in Contents of Main Components

From Reference Example 3, it was confirmed that the main components of the original fragrance of Geomundo narcissus are benzyl acetate, osmenene and linalulul. Therefore, the inventors of these three components, to produce a flavor of good palatability while expressing the scent of the Geomundo narcissus as it is, the new combination perfume of # 1 to # 8 was made.

Combination fragrances # 1 to # 8 were prepared by varying the total content of the three fragrances to 60-95% while maintaining a constant ratio of these three components (see Table 5).

[ Example  2] Example  Sensory Evaluation of Perfumes Prepared in 1

The eight fragrances of Example 1, which were newly combined, were subjected to the similarity and palatability to Geomundo daffodil scent by sensory evaluation in the same manner as in Reference Example 2. On the other hand, after performing the comparative sensory evaluation of the two combination flavors, a 5-minute rest period was given so that there was no post-sensory paralysis. Sensory evaluation results on the taste similarity and palatability between the new combination perfume and Geomundo Narcissus are shown in Table 6 below.

Evaluation Agent Question 1 (similarity) Question 2 (symbolity) Combination flavor number Combination flavor number #One #2 # 3 #4 # 5 # 6 # 7 #8 #One #2 # 3 #4 # 5 # 6 # 7 #8 One 2.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 2.0 3.0 2.0 3.0 2.0 2.0 2.0 1.0 2 2.0 3.0 2.0 3.0 3.0 1.0 1.0 1.0 2.0 3.0 3.0 4.0 3.0 2.0 1.0 2.0 3 3.0 3.0 3.0 4.0 2.0 3.0 2.0 2.0 2.0 3.0 3.0 3.0 2.0 2.0 2.0 1.0 4 2.0 2.0 3.0 3.0 3.0 2.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 2.0 2.0 5 2.0 3.0 2.0 3.0 3.0 3.0 2.0 1.0 1.0 3.0 3.0 3.0 4.0 2.0 3.0 1.0 6 1.0 2.0 3.0 3.0 2.0 2.0 2.0 2.0 1.0 2.0 4.0 3.0 2.0 3.0 2.0 2.0 7 2.0 3.0 4.0 4.0 4.0 2.0 3.0 3.0 2.0 1.0 2.0 2.0 3.0 2.0 2.0 2.0 8 2.0 2.0 3.0 3.0 3.0 2.0 2.0 1.0 3.0 2.0 2.0 3.0 3.0 1.0 2.0 1.0 9 3.0 3.0 2.0 3.0 2.0 3.0 1.0 3.0 2.0 3.0 3.0 3.0 3.0 2.0 3.0 2.0 10 2.0 2.0 2.0 3.0 3.0 1.0 2.0 2.0 2.0 3.0 3.0 4.0 2.0 2.0 2.0 1.0 11 2.0 2.0 3.0 4.0 2.0 3.0 3.0 1.0 3.0 2.0 2.0 3.0 3.0 2.0 1.0 2.0 12 3.0 3.0 2.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 2.0 3.0 2.0 3.0 13 2.0 3.0 3.0 2.0 2.0 3.0 2.0 1.0 2.0 2.0 3.0 3.0 2.0 2.0 2.0 2.0 14 3.0 2.0 2.0 3.0 3.0 2.0 1.0 2.0 3.0 3.0 2.0 2.0 4.0 2.0 2.0 2.0 15 3.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 2.0 3.0 2.0 3.0 16 2.0 2.0 3.0 4.0 4.0 3.0 1.0 1.0 3.0 1.0 2.0 3.0 2.0 3.0 1.0 2.0 17 2.0 3.0 3.0 3.0 2.0 3.0 2.0 1.0 3.0 2.0 3.0 3.0 3.0 3.0 2.0 3.0 18 1.0 1.0 2.0 3.0 2.0 1.0 1.0 1.0 2.0 2.0 2.0 4.0 2.0 2.0 1.0 1.0 19 2.0 3.0 4.0 3.0 3.0 2.0 2.0 2.0 1.0 3.0 3.0 4.0 3.0 1.0 2.0 2.0 20 2.0 3.0 3.0 2.0 2.0 1.0 1.0 1.0 2.0 2.0 3.0 3.0 2.0 2.0 2.0 2.0 Average 2.2 2.6 2.8 3.1 2.7 2.2 1.9 1.7 2.1 2.4 2.7 3.1 2.6 2.2 1.9 1.9

As shown in Table 6, Sample # 4, which has 75% of the total content of the three main components, was shown to have the best similarity and palatability among the eight combination perfumes, but both the similarity and palatability were not as expected. .

[ Example  3] Production of flavor-enhancing fragrance by analysis of professional evaluation team

In order to improve the similarity and palatability of the fragrance of sample # 4 in which the fragrance of Geomundo narcissus is the most similar in Table 6, it contained 75% of the total content of benzyl acetate, osmenene, linalul as in sample # 4, Here, a new combination perfume was prepared using methyl dihydrojasmonate having a sweet floral fruity scent. The content of methyl dihydrojasmonate is added at a concentration of 1%, 3%, 5%, 7%, 10%, 13%, 15%, and other components according to the change in the content of methyl dihydrojasmonate. Adjust to fit total content 100. The composition of these recombinant flavors is shown in Table 7 below.

[ Example  4] Example  Sensory Evaluation of Combination Flavors Prepared in Part 3

Regarding the combination flavors of the seven types (# is, #, #, # d, # d, # d, # bar, # t) of Example 3, the taste similarity and palatability with Geomundo narcissus are described in Reference Example 2 It was carried out by the sensory evaluation of the same method as. On the other hand, after performing the comparative sensory evaluation of the two combination flavors, a 5-minute rest period was given so that there was no post-sensory paralysis. Sensory evaluation results on the taste similarity and palatability of the new combination perfume and Geomundo Narcissus are shown in Table 8 below.

Evaluation Agent Question 1 (similarity) Question 2 (symbolity) Combination flavor number Combination flavor number #end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four One 3.0 4.0 4.0 4.0 3.0 3.0 3.0 2.0 3.0 4.0 4.0 3.0 3.0 2.0 2 3.0 4.0 4.0 3.0 3.0 2.0 3.0 3.0 3.0 4.0 4.0 3.0 2.0 3.0 3 3.0 3.0 4.0 3.0 2.0 3.0 2.0 3.0 4.0 5.0 4.0 4.0 3.0 2.0 4 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 3.0 5 3.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 6 2.0 3.0 4.0 4.0 3.0 2.0 2.0 4.0 3.0 3.0 4.0 4.0 3.0 3.0 7 3.0 4.0 4.0 3.0 4.0 3.0 2.0 3.0 3.0 4.0 5.0 4.0 4.0 3.0 8 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 3.0 9 3.0 3.0 4.0 4.0 3.0 3.0 3.0 2.0 3.0 4.0 4.0 3.0 3.0 2.0 10 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 5.0 4.0 3.0 3.0 3.0 11 3.0 4.0 5.0 4.0 3.0 3.0 4.0 2.0 3.0 3.0 3.0 4.0 3.0 3.0 12 4.0 3.0 4.0 5.0 4.0 3.0 3.0 4.0 4.0 5.0 4.0 3.0 3.0 2.0 13 2.0 4.0 4.0 3.0 3.0 4.0 3.0 3.0 3.0 3.0 4.0 2.0 3.0 2.0 14 3.0 3.0 3.0 3.0 3.0 3.0 2.0 4.0 5.0 5.0 4.0 3.0 2.0 2.0 15 3.0 4.0 5.0 5.0 4.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 16 4.0 4.0 4.0 4.0 3.0 3.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 17 3.0 3.0 4.0 4.0 3.0 3.0 2.0 4.0 5.0 4.0 3.0 4.0 4.0 4.0 18 3.0 4.0 5.0 4.0 3.0 4.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 19 3.0 3.0 4.0 3.0 3.0 2.0 2.0 3.0 4.0 4.0 3.0 2.0 3.0 3.0 20 2.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 4.0 3.0 3.0 4.0 3.0 Average 3.0 3.6 4.1 3.7 3.1 2.9 2.7 3.1 3.7 4.1 3.6 3.2 3.0 2.8

As shown in Table 8, when the main fragrance component of benzyl acetate, osmenene, linalulul of the main fragrance daffodil contains 3% to 7% of methyl dihydrojasmonate, the fragrance of the geomundo can be reproduced, It was confirmed that it showed excellent palatability (average 3.5 or more).

On the other hand, containing less than 3% or more than 7% methyl dihydrojasmonate, it can be seen that the similarity and palatability of the flavor is similar or lower than the combination perfume containing no methyl dihydrojasmonate (Table 6, See # 4).

[ Production Example ]

The perfume of Table 9 was prepared by combining the fragrance composition having similarity with the odor of Geomundo narcissus as described above.

Perfume containing fragrance composition which reproduces scent of Geomundo Narcissus Geomundo daffodil scent reproduction reproduction fragrance alcohol water pigment sunscreen 15% by weight 83% by weight 2% by weight Suitable amount

As described above, the fragrance composition according to the present invention contains methyl dihydrojasmonate in the main components of Geomundo narcissus scent of benzyl acetate, osmenene, linalul and the like analyzed by SPME method to achieve scent of Geomundo narcissus. It can be reproduced and the palatability of a smell can also be improved.

Claims (2)

Benzyl Acetate (39-51%), Ocimene (17-24%), Linalool (3-5%), Phenylpropyl acetate (Benzyl Acetate) based on 100% by weight of the composition 9.2-10.2 wt%, 7.2-8.7 wt% 1,8-cineol, 4.3-5.1 wt% phenethylethyl, 0.5-0.6 wt% Indole %, Limonene 0.6-0.9% by weight, Benzyl alcohol 0.6-0.8%, Benzaldehyde 0.3% by weight, Methyl benzoate 0.3-0.4% by weight and methyl di Geomundo narcissus daffodil aroma reproducing fragrance composition characterized in that it contains a hydrojamonate (Methyl dihydrojasmonate) in the range of 3 to 7% by weight. An external preparation composition for skin, comprising the perfume composition according to claim 1.