KR20120109021A - Perfume composition for expressing the fragrance of chrysanthemum indicum and the composition for skin external application containing the same - Google Patents

Perfume composition for expressing the fragrance of chrysanthemum indicum and the composition for skin external application containing the same Download PDF

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KR20120109021A
KR20120109021A KR1020110026233A KR20110026233A KR20120109021A KR 20120109021 A KR20120109021 A KR 20120109021A KR 1020110026233 A KR1020110026233 A KR 1020110026233A KR 20110026233 A KR20110026233 A KR 20110026233A KR 20120109021 A KR20120109021 A KR 20120109021A
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chrysanthemum
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scent
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KR101770682B1 (en
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우창식
서형제
황경환
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(주)아모레퍼시픽
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • A61K36/28Asteraceae or Compositae (Aster or Sunflower family), e.g. chamomile, feverfew, yarrow or echinacea
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations

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Abstract

PURPOSE: An external use skin composition containing perfume composition of Chrysanthemum indicum is provided to express fragrance of Chrysanthemum indicum and to ensure excellent preference. CONSTITUTION: A perfume composition which expresses the flavor of Chrysanthemum indicum contains the fragrance ingredient of Chrysanthemum indicum and hedione ingredient as an active ingredient. The fragrance ingredient is phenyl acetaldehyde, benzaldehyde, camphor, or phenyl ethyl alcohol. The composition contains 25-40 wt% of phenyl acetaldehyde, 20-30 wt% of benzaldehyde, 7-15 wt% of camphor, and 5-10 wt% of phenyl ethyl alcohol. The composition further contains 5-15 wt% of benzylalcohol, 3-12 wt% of hexanol, and 2-10 wt% of linalool. An external use skin composition contains the perfume composition.

Description

감국꽃의 향취를 재현한 향료 조성물 및 이를 함유하는 피부 외용제 조성물{PERFUME COMPOSITION FOR EXPRESSING THE FRAGRANCE OF CHRYSANTHEMUM INDICUM AND THE COMPOSITION FOR SKIN EXTERNAL APPLICATION CONTAINING THE SAME}PERFUME COMPOSITION FOR EXPRESSING THE FRAGRANCE OF CHRYSANTHEMUM INDICUM AND THE COMPOSITION FOR SKIN EXTERNAL APPLICATION CONTAINING THE SAME}

본 발명은 국화의 향취를 재현한 향료 조성물 및 이를 함유하는 피부 외용제 조성물에 관한 것이다.The present invention relates to a fragrance composition reproducing the scent of chrysanthemum and an external composition for skin containing the same.

국화는 전세계적으로 1만 5,000 내지 2만 종(種)과 940여 속(屬)이 있고, 우리나라에는 200여종이 분포하는 것으로 알려지고 있다. 그 중 대표적인 것이 감국, 산국, 구절초, 쑥부쟁이, 벌개미취, 엉겅퀴, 각시취 등이 있다. 국화는 Compositae 또는 Asteraceae로 명명될 수 있다. Chrysanthemums are 15,000-20,000 species and 940 genera around the world, and 200 species are known to be distributed in Korea. The representative ones are Gamguk, Sanguk, Gujeolcho, Wormwood worm, Beetle taste, Thistle, and each taste. Chrysanthemum can be named Compositae or Asteraceae.

이 중에서도 감국은 주로 산에서 자라고 풀 전체에 짧은 털이 나 있고 줄기의 높이는 60 ~ 90cm이며 검은색으로 가늘고 길다. 잎은 짙은 녹색이고 어긋나며 잎자루가 있고 달걀 모양인데 보통 깃꼴로 갈라지며 끝이 뾰족하다. 갈라진 조각은 긴 타원형이고 가장자리가 패어 들어간 모양의 톱니가 있다. 9 ~ 10월에 줄기 윗부분에 산방꼴로 두화(頭花)가 핀다. 이러한 감국꽃을 Chrysanthemum indicum이라고 명명하기도 한다. 감국꽃은 향취면에서 향기가 강하고 은은하며 기호성이 우수하고, 지름이 2.5cm 정도이며, 노란색이나 흰색도 있다. 10월에 감국꽃을 말려서 술에 넣어 마시고, 어린 잎은 나물로 쓴다. 꽃에 진한 향기가 있어 관상용으로도 가꾼다. 한방에는 열감기, 폐렴, 기관지염, 두통, 위염, 장염, 종기 등의 치료에 처방한다. 민간요법으로는 풀 전체를 짓찧어서 환부에 붙이거나 생초를 달인 물로 환부를 씻어낸다. Among them, Gam-guk is mainly grown in the mountains, with short hairs all over the grass, and the stem is 60-90 cm in height, black and thin. Leaves are dark green, alternate, petioles, egg-shaped, usually divided into quills and pointed ends. Cracks are long oval and have serrated teeth. From September to October, the upper part of the stem blooms in a mountain shape. These chrysanthemum flowers are also called Chrysanthemum indicum. Persimmon flower has strong scent in fragrance, soft and palatability, 2.5cm in diameter, yellow or white. In October, the persimmons are dried and drunk, and young leaves are used as herbs. The flower has a rich scent and can be used for ornamental purposes. Herbal medicine is prescribed for the treatment of cold, pneumonia, bronchitis, headache, gastritis, enteritis, boil. Folk remedies crush the entire grass and attach it to the affected area or wash the affected area with fresh herbs.

일반적으로 천연물의 향취를 재현하기 위한 방법으로는 여러 가지가 있을 수 있으며, 예를 들면, 천연물의 향취성분을 화정유(Absolute) 형태로 만드는 용매추출법과 향기성분을 정유(Essential oil)로 만드는 수증기증류법이 있다. 그러나, 상기 방법들은 추출과정에서 높은 열을 가해야 하고 처리 과정이 복잡하여 많은 시간이 소요되므로 본래의 향취와는 많은 차이가 있을 수 있다.
In general, there can be a variety of ways to reproduce the smell of natural products, for example, the solvent extraction method to make the natural flavor of the odor component (Absolute) form and the steam to make the scent component of the essential oil (Essential oil) There is a distillation method. However, since the methods require high heat during the extraction process and the process is complicated and takes a lot of time, the methods may be different from the original flavor.

본 발명자들은 SPME법을 이용하여, 국화의 향취를 재현하고자 하였다. 그 결과로, 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)가 국화 향취의 주성분임을 발견하고, 이를 이용하여 국화의 향취를 재현하고자 하였다. 그러나, 본 발명자들이 관능검사를 수행한 결과, 이들 성분만으로는 국화의 향취를 재현할 수 없음을 발견하였다.The present inventors attempted to reproduce the scent of chrysanthemum by using the SPME method. As a result, phenylacetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), Camphor (Camphor) and phenylethyl alcohol (Phenyl ethyl alcohol) was found to be the main components of the chrysanthemum scent, by using this to reproduce the scent of chrysanthemum. However, as a result of the sensory test performed by the present inventors, it was found that only the components could not reproduce the smell of chrysanthemum.

이에, 본 발명자들은 상기 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)의 국화 향취의 주성분과 함께 인공합성물질인 헤디온(Hedione)을 함유하는 향료 조성물이 국화의 고유향취를 재현함은 물론, 뛰어난 기호성을 나타냄을 발견하고 본 발명을 완성하였다.Therefore, the present inventors contain Hedione, which is an artificial synthetic material, together with the main components of the chrysanthemum odor of the phenyl acetaldehyde, benzaldehyde, benzaldehyde, camphor, and phenyl ethyl alcohol. The fragrance composition was found not only to reproduce the intrinsic odor of chrysanthemum, but also exhibits excellent palatability and completed the present invention.

따라서, 본 발명의 목적은 국화의 고유 향취를 재현하면서 기호성이 우수한 향료 조성물을 제공하는 것이다.Therefore, the objective of this invention is providing the fragrance composition excellent in palatability while reproducing the intrinsic odor of chrysanthemum.

또한, 본 발명의 또 다른 목적은 상기 향료 조성물을 함유하는 피부 외용제를 제공하는 것이다.
Another object of the present invention is to provide an external preparation for skin containing the perfume composition.

상기와 같은 목적을 해결하기 위하여, 본 발명은 국화의 향취 성분 및 헤디온(Hedione) 성분을 유효성분으로 함유하는 국화의 향취를 재현한 향료 조성물을 제공한다.In order to solve the above object, the present invention provides a fragrance composition that reproduces the scent of chrysanthemum containing the odor component and Hedione component of the chrysanthemum as an active ingredient.

본 발명의 일실시예에 있어서, 상기 국화의 향취 성분은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)로 구성된 군으로부터 선택된 하나 이상을 포함할 수 있다.In one embodiment of the present invention, the flavor component of the chrysanthemum includes one or more selected from the group consisting of phenyl acetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), Camphor (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol) can do.

본 발명의 일실시예에 있어서, 상기 조성물은 조성물 총 중량에 대하여 페닐아세트알데히드(Phenyl acetaldehyde) 25 내지 40중량%, 벤즈알데히드(Benzldehyde) 20 내지 30중량%, 캠퍼(Camphor) 7 내지 15중량%, 및 페닐에틸알코올(Phenyl ethyl alcohol) 5 내지 10중량%로 포함할 수 있다.In one embodiment of the present invention, the composition is based on the total weight of the composition of phenyl acetaldehyde (Phenyl acetaldehyde) 25 to 40% by weight, Benzaldehyde 20 to 30% by weight, Camphor (Camphor) 7 to 15% by weight, And phenyl ethyl alcohol (Phenyl ethyl alcohol) 5 to 10% by weight.

본 발명의 일실시예에 있어서, 상기 조성물은 벤질알코올(Benzyl alcohol), 헥산올(Hexanol) 및 리날로울(Linalool)로 구성된 군으로부터 선택된 하나 이상을 더 포함할 수 있다.In one embodiment of the present invention, the composition may further include one or more selected from the group consisting of benzyl alcohol, hexanol (Hexanol) and linalool (Linalool).

본 발명의 일실시예에 있어서, 상기 조성물은 조성물 총 중량에 대하여 벤질알코올(Benzyl alcohol) 5 내지 15중량%, 헥산올(Hexanol) 3 내지 12 중량%, 리날로울(Linalool) 2 내지 10중량%를 더 포함할 수 있다.In one embodiment of the present invention, the composition is based on the total weight of the composition benzyl alcohol (benzyl alcohol) 5 to 15% by weight, hexanol (hexanol) 3 to 12% by weight, linalool 2 to 10% by weight It may further include%.

또한, 본 발명은 상기 향료 조성물을 함유하는 피부 외용제 조성물을 제공한다.
The present invention also provides an external composition for skin containing the perfume composition.

본 발명에 따른 향료 조성물은 국화 향취의 주요 성분인 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)과 인공합성물질인 헤디온(Hedione)을 함유함으로써, 국화의 고유 향취를 재현할 수 있고 우수한 기호성을 나타낼 수 있다.The fragrance composition according to the present invention is a phenyl acetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), Camphor (Phenyl ethyl alcohol) and the synthetic synthetic Hedione (Hedione) which is the main component of the chrysanthemum scent By containing, the intrinsic odor of chrysanthemum can be reproduced and excellent palatability can be shown.

이하에서는, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명을 용이하게 실시할 수 있도록 하기 위하여, 본 발명의 바람직한 실시예들에 관하여 상세히 설명하기로 한다.
Hereinafter, preferred embodiments of the present invention will be described in detail in order to facilitate the present invention by those skilled in the art.

본 발명은 국화의 향취 성분 및 헤디온(Hedione) 성분을 유효성분으로 함유하는 국화의 향취를 재현한 향료 조성물을 제공한다.
The present invention provides a fragrance composition that reproduces the fragrance of chrysanthemum containing the fragrance component of the chrysanthemum and Hedione component as an active ingredient.

향취 성분 분석은 통상의 방법이 사용될 수 있으나, 바람직하게는 고상 마이크로 추출법(Solid Phase Micro Extraction, SPME법)에 의해 포집된 국화의 향취 성분을 가스크로마토그래피-질량 분석기(GC-MS) 컬럼 안으로 탈착, 주입하여 분석하는 단계를 포함하여 제조될 수 있다. The odor component analysis may be a conventional method, but preferably the odor component of the chrysanthemum collected by the solid phase micro extraction (SPME method) is desorbed into a gas chromatography-mass spectrometer (GC-MS) column. It may be prepared, including the step of injecting and analyzing.

상기 SPME법은 특별한 전처리 없이 화이버(Fiber)에 흡착된 향취 성분들이 GC-MS 컬럼 안으로 빠르게 탈착, 주입될 수 있어 분석시간이 크게 단축될 수 있으므로 휘발성이 강한 국화의 향취성분을 분석하는데 유리하며, 용매추출법 및 수증기증류법과 같은 기존의 추출법과는 달리 용매를 사용하지 않고 전처리 또한 필요 없어, 신속하고 간편하게 국화의 향취 성분을 분석할 수 있다.
The SPME method is advantageous in analyzing the fragrance component of the volatile chrysanthemum because the fragrance component adsorbed on the fiber can be quickly desorbed and injected into the GC-MS column without any special pretreatment. Unlike conventional extraction methods such as solvent extraction and steam distillation, no solvent is used and no pretreatment is required, so that the flavor component of chrysanthemum can be analyzed quickly and simply.

상기 국화의 향취 성분은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)로 구성된 군으로부터 선택된 하나 이상을 포함할 수 있다.The odor component of the chrysanthemum may include at least one selected from the group consisting of phenyl acetaldehyde, benzaldehyde, benzaldehyde, camphor and phenyl ethyl alcohol.

바람직하게, 상기 국화의 향취 성분은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)을 모두 포함하는 성분일 수 있으며, 하기 실시예 및 실험예를 통해 확인할 수 있는 바와 같이, 위 성분들을 조합한 향료 조성물의 경우 뛰어난 유사성과 기호성을 나타낼 수 있다.Preferably, the flavor component of the chrysanthemum may be a component containing all of phenyl acetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), camphor (Camphor) and phenyl ethyl alcohol (Examples and Experimental Examples) As can be seen through, in the case of a perfume composition combining the above components can exhibit excellent similarity and palatability.

본 발명에 의한 향료 조성물은 조성물 총 중량에 대하여 페닐아세트알데히드(Phenyl acetaldehyde) 25 내지 40중량%, 벤즈알데히드(Benzldehyde) 20 내지 30중량%, 캠퍼(Camphor) 7 내지 15중량%, 및 페닐에틸알코올(Phenyl ethyl alcohol) 5 내지 10중량%로 포함하는 것이 바람직하다. 상기 중량비로 포함된 성분이 조합된 향료 조성물은 소망하는 정도로 은은하고 품위있는 국화의 향취를 재현할 수 있다.
Perfume composition according to the present invention is 25 to 40% by weight phenylacetaldehyde (Phenyl acetaldehyde), 20 to 30% by weight Benzdedede (Benzaldehyde), 7 to 15% by weight Camphor (Camphor), and phenylethyl alcohol ( Phenyl ethyl alcohol) 5 to 10% by weight is preferably included. The fragrance composition in which the components contained in the above weight ratios are combined can reproduce the fragrance of the chrysanthemum that is as delicate and elegant as desired.

본 발명에 의한 향료 조성물은 기호성을 향상시키기 위하여 상기 국화의 향취 성분에 인공합성물질인 헤디온(Hedione) 성분을 유효 성분으로서 포함시킨다.
The fragrance composition according to the present invention includes a Hedione component, which is an artificial synthetic material, as an active ingredient in the fragrance component of the chrysanthemum in order to improve palatability.

본 발명에 의한 향료 조성물은 앞서 언급한 성분들 이외에 국화 향취의 부차적인 성분으로 확인된 향취 성분들을 더 포함할 수 있으며, 예를 들면, 벤질알코올(Benzyl alcohol), 헥산올(Hexanol) 및 리날로울(Linalool)로 구성된 군으로부터 선택된 하나 이상을 더 포함할 수 있다.The fragrance composition according to the present invention may further include fragrance components identified as secondary components of the chrysanthemum scent, in addition to the aforementioned components, for example, benzyl alcohol, hexanol and linalol. It may further comprise one or more selected from the group consisting of (Linalool).

바람직하게는, 상기 조성물은 벤질알코올(Benzyl alcohol), 헥산올(Hexanol) 및 리날로울(Linalool) 모두를 더 포함하는 것일 수 있다.Preferably, the composition may further include all of benzyl alcohol, benzyl alcohol, hexanol, and linalool.

또한, 바람직하게는, 조성물 총 중량에 대하여 벤질알코올(Benzyl alcohol) 5 내지 15중량%, 헥산올(Hexanol) 3 내지 12 중량%, 리날로울(Linalool) 2 내지 10중량%를 더 포함할 수 있다.
Also, preferably, 5 to 15% by weight of Benzyl alcohol, 3 to 12% by weight of hexanol, and 2 to 10% by weight of linalool, based on the total weight of the composition, may be further included. have.

본 발명의 향료 조성물은 국화의 향취 성분 및 헤디온(Hedione)을 유효 성분으로 포함하며, 상기 국화의 향취 성분은 소망하는 정도의 향취를 낼 수 있으면 특별히 제한되지 않으나, 예를 들어 조성물 총 중량을 기준으로 70중량% 초과 내지 80중량% 미만의 함량으로 포함될 수 있다. 위 범위 내에 속할 때 국화의 본연의 향취와 가장 유사하고 기호성도 우수하기 때문이다.The fragrance composition of the present invention includes a scent component of the chrysanthemum and Hedione as an active ingredient, and the scent component of the chrysanthemum is not particularly limited as long as it can give a desired scent. It may be included in an amount of more than 70% by weight to less than 80% by weight on a basis. This is because it is the most similar to the natural flavor of chrysanthemum when it falls within the above range and has excellent palatability.

상기 헤디온은 향료 조성물에 적합하도록 소망하는 정도의 기호성을 가지는 향취를 낼 수 있으면, 함량 범위가 특별히 제한되지 않으나, 예를 들어 조성물 총 중량을 기준으로 3 내지 7 중량%로, 보다 바람직하게는 4 내지 6 중량%의 함량으로 포함될 수 있다. 위 범위 내에 속할 때 국화의 본연의 향취와 가장 유사하고 기호성도 우수하기 때문이다.
The hedione is not particularly limited in the content range as long as it can give a odor having a desired degree of palatability to the fragrance composition, for example, 3 to 7% by weight based on the total weight of the composition, more preferably It may be included in an amount of 4 to 6% by weight. This is because it is the most similar to the natural flavor of chrysanthemum when it falls within the above range and has excellent palatability.

본 발명에서 국화 향취를 재현하기 위하여 사용한 주성분들인 페닐아세트알데히드, 캠퍼, 페닐에틸알코올 및 헤디온은 상기 범위를 벗어난 범위로 사용할 경우, 국화와의 향취 유사성이 낮아지고, 향취의 기호성도 낮아지므로 바람직하지 않다. 그러나, 그 외의 성분들(부차적인 향취 성분들)은 상기 범위 내에서 사용하는 것이 바람직하지만, 국화의 향취에 크게 영향을 미치지 않기 때문에 국화 향취를 재현하는데 영향을 미치지 않는 한, 상기 범위를 벗어나는 양으로도 함유될 수 있다.
Phenylacetaldehyde, camphor, phenylethyl alcohol, and hedion, which are the main components used to reproduce the odor of chrysanthemum in the present invention, are used in a range outside the above range, so that the odor similarity with chrysanthemum is lowered, and the taste of the odor is lowered. Not. However, the other components (subsidiary fragrance components) are preferably used within the above range, but they do not greatly affect the fragrance of chrysanthemum, so that the amount outside of the above range is not affected unless reproducing the chrysanthemum odor. It may also be contained.

또한, 본 발명은 상기 향료 조성물을 함유하는 피부 외용제 조성물을 제공한다. 즉, 상기의 범위로 조합된 본 발명의 향료 조성물은 향수, 화장품 등의 피부 외용 기제에 배합될 수 있고, 배합량은 당업계에 통상적인 기술에 따라, 목적하는 효과를 이루기 위해 적절하게 선택하여 배합할 수 있다. The present invention also provides an external composition for skin containing the perfume composition. That is, the fragrance composition of the present invention combined in the above range can be blended into the base for external skin such as perfume and cosmetics, and the blending amount is appropriately selected and blended in order to achieve the desired effect according to the conventional techniques in the art. can do.

본 발명에 의한 향료 조성물을 함유하는 피부 외용제 조성물로는 예를 들면, 연고, 로션, 가용화상, 현탁액, 에멀젼, 크림, 젤, 스프레이, 파프제, 경고제, 패치제 또는 물파스 등이 있지만, 이들에만 한정되지 않고, 당업계에 주지된 어떠한 기제에도 배합될 수 있다.
The external preparation composition for skin containing the fragrance composition according to the present invention includes, for example, an ointment, a lotion, a soluble burn, a suspension, an emulsion, a cream, a gel, a spray, a pape, a warning, a patch, or a water paste. It is not limited to, but may be formulated in any base well known in the art.

이하, 본 발명의 내용을 실시예 및 시험예를 통하여 보다 구체적으로 설명한다. 이들 실시예는 본 발명의 내용을 이해하기 위해 제시되는 것일 뿐 본 발명의 권리범위가 이들 실시예 및 실험예로 한정되는 것은 아니고, 당업계에서 통상적으로 주지된 변형, 치환 및 삽입 등을 수행할 수 있으며, 이에 대한 것도 본 발명의 범위에 포함된다.
Hereinafter, the present invention will be described more specifically with reference to examples and test examples. These examples are provided only for understanding the contents of the present invention, and the scope of the present invention is not limited to these examples and experimental examples, and modifications, substitutions, and insertions commonly known in the art may be performed. It may be included in the scope of the present invention.

[ 비교예 1] 감국꽃의 향취를 재현한 향료 조성물의 제조 [Comparative Example 1] Production of fragrance composition reproduces the fragrance of flower gamguk

1-1. 1-1. SPMESPME 법을 이용한 국화의 향취 분석Perfume Analysis of Chrysanthemum Using

국화의 향취 성분을 분석하기 위하여 살아있는 천연물의 향취물질을 분석하는데 효과적인 SPME법(Solid Phase Micro Extraction)을 사용하였다. In order to analyze the fragrance component of chrysanthemum, SPME (Solid Phase Micro Extraction) was used to analyze the fragrance substance of living natural products.

국화과로서 향취면에서 향기가 강하고 은은하며 기호성이 우수한 감국(Chrysanthemum indicum)을 선택하고, 향기가 강한 감국 한 그루를 골라 2시간 동안 85 ㎛의 폴리아크릴레이트로 코팅된 화이버(Polyacrylate Fiber)에 향기성분을 흡착시켜 향취 성분을 포집하였다. 춘천시 국야농원에서 3시간 동안 포집이 이루어졌다.As a chrysanthemum, it selects Chrysanthemum indicum which has strong scent in fragrance and excellent taste. Was adsorbed to collect the odor component. The collection took place for 3 hours at Chuncheon National Farm.

향취 성분을 포집한 후 화이버(Fiber)를 밀봉하고, 이를 GC-MS의 주입구에 옮겨 꽂은 다음, 2분간 탈착시키고 GC-MS 분석하였다. GC-MS 분석조건은 다음과 같다.After collecting the odor component, the fiber was sealed and transferred to the inlet of GC-MS, and then desorbed for 2 minutes and analyzed by GC-MS. GC-MS analysis conditions are as follows.

분석 조건Analysis condition

. 분석기기: HP 5890 II GC. Analytical instrument: HP 5890 II GC

. 검출기: HP 5972 MSD. Detector: HP 5972 MSD

. 컬럼(Column): DB-1(60m×0.25mm×0.25um). Column: DB-1 (60m × 0.25mm × 0.25um)

. 이동 기체(Carrier Gas): He. Carrier gas: He

. 주입부 온도(Injection Temperature): 250℃. Injection Temperature: 250 ° C

. 검출부 온도(Detector Temperature): 280℃. Detector Temperature: 280 ° C

. 오븐 온도(Oven Temperature): 70~220℃(3℃/min) . Oven Temperature: 70 ~ 220 ℃ (3 ℃ / min)

. 이온화 전압(Ionization Voltage): 70 eV. Ionization Voltage: 70 eV

. 탈착 시간: 2분
. Desorption time: 2 minutes

그 결과, SPME법에 의해 분석된 감국꽃의 향취성분은 하기 표 1과 같았다(단위: 중량%).
As a result, the perfume components of the persimmon flower analyzed by the SPME method were as shown in Table 1 (unit: wt%).

향취 성분Fragrance ingredients 함량(단위: 중량%)Content (unit: weight%) 페닐아세트알데히드Phenylacetaldehyde 35.235.2 벤즈알데히드Benzaldehyde 25.625.6 캠퍼Camper 10.810.8 페닐 에틸 알코올Phenyl ethyl alcohol 8.98.9 벤질 알코올Benzyl alcohol 5.15.1 헥산올Hexanol 4.54.5 리날로울Linalool 3.03.0 기타Etc 6.96.9 총 함량Total content 100.0100.0

상기 표 1에서 볼 수 있는 바와 같이, 감국꽃은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)를 주요 향취성분으로 하고 있으며, 이들 주성분이 전체의 80.50%를 차지하는 것을 확인하였다.
As can be seen in Table 1, the persimmon flower is phenyl acetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), camphor (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol) as the main odor component, these main components are It confirmed that it occupies 80.50% of the whole.

1-2. 향료 조성물 제조1-2. Perfume Composition Preparation

상기 실시예 1-1의 SPME법에 의해서 분석된 결과를 토대로 새로이 조성한 하기 표 2의 조성을 갖는 조합향료(샘플 B)를 제조하였다(단위: 중량%).
On the basis of the results analyzed by the SPME method of Example 1-1 was prepared a combination perfume (Sample B) having a composition of Table 2 (unit: wt%).

향취 성분Fragrance ingredients 함량(단위: 중량%)Content (unit: weight%) 페닐아세트알데히드Phenylacetaldehyde 35.235.2 벤즈알데히드Benzaldehyde 25.625.6 캠퍼Camper 10.810.8 페닐 에틸 알코올Phenyl ethyl alcohol 8.98.9 벤질 알코올Benzyl alcohol 5.15.1 헥산올Hexanol 4.54.5 리날로울Linalool 3.03.0 DEP(용매)DEP (Solvent) 6.96.9 총 함량Total content 100.0100.0

[ 비교실험예 1] 조합향료와 천연 감국꽃의 향취를 비교한 관능평가 [Comparative Experimental Example 1] Comparative sensory test the fragrance of perfumes in combination with natural flowers gamguk

상기 비교예 1에서 제조한 조합향료(샘플 B)와 천연 감국꽃(샘플A)의 향취의 유사성 및 향취의 기호성을 후각관능검사를 통해 수행하였다.The similarity between the flavor of the combination perfume (Sample B) and natural persimmon flower (Sample A) prepared in Comparative Example 1 and palatability of the flavor was performed through olfactory sensory test.

관능평가는 20~45세의 일반남녀 20명을 대상으로 하였으며, 감국꽃 화분의 샘플 A와, SPME법으로 재현한 조합향료의 샘플 B의 향취를 각각 맡아보도록 하고, 하기 표 3의 설문지에 응답하도록 함으로써, 샘플 A와 샘플 B의 향취 유사성(질문 1) 및 향취의 기호성(질문 2)을 조사하였으며, 그 결과는 하기 표 4에 나타내었다.
The sensory evaluation was conducted on 20 general men and women aged 20 to 45 years. The sample A of the persimmon flower pollen and sample B of the combination perfume reproduced by the SPME method were in charge of each and responded to the questionnaire of Table 3 below. By doing so, the taste similarity (question 1) and taste preference (question 2) of sample A and sample B were investigated, and the results are shown in Table 4 below.

설문지
(1) 질문 1: 샘플A와 샘플B의 향취가 얼마나 유사(비슷)한가?
1) 전혀 유사하지 않다.
2) 별로 유사하지 않다.
3) 그저 그렇다.
4) 어느 정도 유사하다.
5) 매우 유사하다.

(2) 질문 2: 샘플 B의 향취를 얼마나 좋아하는가?
1) 전혀 좋지 않다.
2) 별로 좋지 않다.
3) 그저 그렇다.
4) 약간 좋다.
5) 매우 좋다.
survey
(1) Question 1: How similar are samples A and B?
1) It is not at all similar.
2) Not very similar.
3) Just so.
4) Somewhat similar.
5) Very similar.

(2) Question 2: How much do you like the smell of Sample B?
1) Not at all good.
2) Not very good.
3) Just so.
4) Somewhat good.
5) Very good.

평가요원Rating agent 질문 1
(유사성)
Question 1
(Similarity)
질문 2
(기호성)
Question 2
(Symbol)
1One 22 1One 22 22 22 33 22 22 44 22 22 55 1One 22 66 22 22 77 22 33 88 22 1One 99 22 22 1010 22 22 1111 22 1One 1212 33 22 1313 22 22 1414 1One 22 1515 22 33 1616 22 33 1717 22 22 1818 22 1One 1919 1One 22 2020 22 33 평균Average 1.91.9 2.02.0

상기 표 4의 결과에서, 조합향료인 샘플 B는 감국꽃 화분의 꽃 향취(샘플 A)와 많은 차이가 있는 것으로 나타났으며, 기호성도 낮게 나타났다.
In the results of Table 4, Sample B, which is a combination fragrance, was found to have a lot of difference from the floral scent (Sample A) of the persimmon flower pot, and the palatability was low.

[ 비교실험예 2] 전문 평가단에 의한 향취 분석 [Comparative Experiment 2] flavor analysis by a professional assessors

상기 비교실험예 1에서 보는 바와 같이, SPME법에 의해 분석된 성분으로 조성한 향료 조성물이 감국꽃과 항취 유사성이 없었다. 이에, 조향사로 구성된 전문 평가단은 감국꽃의 각각의 향취 성분들에 대하여 관능평가를 수행하였다. As shown in Comparative Experiment 1, the fragrance composition composed of the components analyzed by the SPME method did not have a similar smell to persimmon flowers. Therefore, the professional evaluation group composed of the steering company performed the sensory evaluation for each flavor component of persimmon flower.

그 결과, 감국꽃의 향취 성분들 중, 후로랄(Floral)한 향취를 만들어내는 페닐 아세트알데히드, 스위트 프레쉬(Sweet fresh)한 향취를 내는 벤즈알데히드, 민트(Mint)한 캠퍼, 장미꽃느낌을 주는 페닐 에틸 알코올의 네 성분이 감국꽃의 고유향취를 만들어내는 주성분임을 확인하였다.
As a result, among the scents of persimmon flowers, phenyl acetaldehyde, which produces a floral scent, benzaldehyde, which gives sweet fresh scent, mint camphor, and phenyl ethyl, which gives a rose feel It is confirmed that the four components of alcohol are the main components that produce the unique scent of persimmon flower.

[ 비교예 2] 감국꽃 향취의 주성분 함량 변화에 따른 새로운 향료조성물의 제조 [Comparative Example 2] Preparation of new perfume compositions according to the main component of the contents in gamguk floral scent

상기 비교실험예 2의 결과로부터, 감국꽃의 독창적 향취의 주성분이 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)를 확인할 수 있었다. 따라서, 본 발명자들은 이들 네 성분을 함유하여 감국꽃의 향취를 그대로 나타내면서, 기호성이 좋은 향료를 제조하기 위해서 하기 #1 내지 #4의 새로운 조합향료들을 만들었다.From the results of Comparative Example 2, the main components of the original odor of persimmon flowers can be confirmed phenyl acetaldehyde, benzaldehyde (Benzldehyde), camphor (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol). Therefore, the present inventors have prepared the new combination fragrances of # 1 to # 4 in order to produce flavors with palatability while containing the four components and expressing the scent of persimmon flowers.

하기 표 5에 기재된 조성으로 상기 네 성분의 비율은 일정하게 유지하면서 조합향료 #1부터 #4를 제조하였다(단위: 중량%). 이때, 네 성분의 총함량을 60 내지 90중량%로 변화시켜 제조하였다.
Combination fragrance # 1 to # 4 were prepared while maintaining the ratio of the four components in the composition shown in Table 5 (unit: wt%). At this time, it was prepared by changing the total content of the four components to 60 to 90% by weight.

향취 성분
(단위: 중량%)
Fragrance ingredients
(Unit: weight%)
#1#One #2#2 #3# 3 #4#4
페닐아세트알데히드Phenylacetaldehyde 25.525.5 30.530.5 35.535.5 40.540.5 벤즈알데히드Benzaldehyde 15.515.5 20.520.5 25.525.5 25.525.5 캠퍼Camper 10.510.5 10.510.5 10.510.5 15.515.5 페닐 에틸 알코올Phenyl ethyl alcohol 8.58.5 8.58.5 8.58.5 8.58.5 벤질 알코올Benzyl alcohol 15.015.0 13.513.5 7.57.5 5.55.5 헥산올Hexanol 14.514.5 10.510.5 6.56.5 3.53.5 리날로울Linalool 10.510.5 6.06.0 6.06.0 1.01.0 총함량Total content 100100 100100 100100 100100 주성분 함량Main ingredient content 6060 7070 8080 9090

[ 비교실험예 3] 비교예 2에서 제조한 향료 조성물들의 관능평가 [Comparative Example 3] Sensory evaluation of the fragrance composition prepared in Comparative Example 2

새로이 조합된 4가지의 향료에 대하여, 상기 비교실험예 1과 동일한 방법으로 감국꽃 향취와의 유사성 및 기호성에 대한 관능평가를 수행하였다. 한편, 두 개의 향료에 대한 비교관능평가를 실시한 후, 5분 동안의 휴식시간을 주어 후감각 마비현상이 없도록 하였다. 새로운 조합향료와 감국꽃과의 향취 유사성 및 기호성에 관한 관능평가 결과는 하기 표 6에 나타내었다.
With respect to the four fragrances newly combined, the sensory evaluation on the similarity and palatability with the scent of persimmon flower was carried out in the same manner as in Comparative Experiment 1. On the other hand, after conducting a comparative sensory evaluation of the two flavors, a 5-minute rest period was given so that there was no post-sensory paralysis. Sensory evaluation results on the taste similarity and palatability of the new combination perfume and persimmon flower are shown in Table 6 below.

평가
요원
evaluation
agent
질문1 (유사성)Question 1 (similarity) 질문2 (기호성)Question 2 (symbolity)
#1#One #2#2 #3# 3 #4#4 #1#One #2#2 #3# 3 #4#4 1One 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 22 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 33 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 44 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 2.0 2.0 55 2.0 2.0 3.0 3.0 4.0 4.0 2.0 2.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 66 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 1.0 1.0 2.0 2.0 4.0 4.0 2.0 2.0 77 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 88 3.0 3.0 4.0 4.0 5.0 5.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 99 1.0 1.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 1010 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 4.0 4.0 2.0 2.0 1111 3.0 3.0 2.0 2.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 4.0 4.0 2.0 2.0 1212 3.0 3.0 1.0 1.0 4.0 4.0 2.0 2.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 1313 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 1414 3.0 3.0 2.0 2.0 5.0 5.0 2.0 2.0 3.0 3.0 3.0 3.0 5.0 5.0 2.0 2.0 1515 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 1.0 1.0 3.0 3.0 3.0 3.0 3.0 3.0 1616 2.0 2.0 2.0 2.0 4.0 4.0 3.0 3.0 2.0 2.0 2.0 2.0 4.0 4.0 2.0 2.0 1717 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 5.0 5.0 2.0 2.0 1818 2.0 2.0 2.0 2.0 4.0 4.0 2.0 2.0 1.0 1.0 2.0 2.0 4.0 4.0 2.0 2.0 1919 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 1.0 1.0 3.0 3.0 3.0 3.0 2020 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 평균Average 2.3 2.3 2.6 2.6 3.7 3.7 2.8 2.8 2.1 2.1 2.5 2.5 3.6 3.6 2.6 2.6

상기 표 6의 결과에서 알 수 있듯이, 네 가지 향취 주성분의 총 함량이 80중량%를 차지하는 샘플 #3이 4개의 조합향료 중 가장 뛰어난 유사성과 기호성을 갖는 것으로 보여졌으나, 유사성과 기호성이 모두 기대에 미치지 못하는 것으로 나타났다.
As can be seen from the results of Table 6, Sample # 3, in which the total content of the four flavor main ingredients accounted for 80% by weight, was shown to have the most similarity and palatability among the four combination perfumes, but both similarity and palatability were expected. It appeared to be insane.

[ 실시예 1] 감국꽃 향취 개선 향료 조성물의 제조 Example 1 Preparation of improved gamguk floral fragrance perfume composition

상기 표 6에서 감국꽃의 향취가 가장 유사한 것으로 나타난 샘플 #3의 향료의 유사성 및 기호성을 개선하기 위해서, 상기 샘플 #3에서와 같이 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)를 80중량%의 함량으로 함유하고, 여기에 감국꽃 향기의 재현에 특유의 향을 갖게 만드는 헤디온을 사용하여 새로운 조합향료를 제조하였다. 이때, 헤디온은 2.0, 3.0, 4.0, 5.0, 6.0, 7.0 및 8.0 중량%(각각 #가, #나, #다, #라, #마, #바, #사)의 함량으로 첨가하였다. 헤디온의 함량기준은 조향사 전문가 집단의 판단에 의해서 기준을 잡았다. 이들 재조합향료의 조성은 하기 표 7과 같다(단위: 중량%).
In order to improve the similarity and palatability of the fragrance of Sample # 3 in which the scent of persimmon flower is the most similar in Table 6, as in Sample # 3, Phenyl acetaldehyde, Benzaldehyde, Camper (Camphor) ) And phenylethyl alcohol (Phenyl ethyl alcohol) in an amount of 80% by weight, and a new combination fragrance was prepared using Hedion which has a unique aroma for reproducing persimmon flowers. At this time, Hedion was added in the amount of 2.0, 3.0, 4.0, 5.0, 6.0, 7.0 and 8.0 wt% (#, #, #, # d, # d, # hemp, # bar, # company, respectively). Hedion content criteria were based on the judgment of the steering expert group. The composition of these recombinant perfume is shown in Table 7 (unit: wt%).

향취 성분Fragrance ingredients #가#end #나#I #다#All #라#la #마#hemp #바#bar #사#four 페닐아세트알데히드Phenylacetaldehyde 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 35.5 벤즈알데히드Benzaldehyde 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 25.5 캠퍼Camper 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 10.5 페닐 에틸 알코올Phenyl ethyl alcohol 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 8.5 헤디온Hedion 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 6.0 6.0 7.0 7.0 8.0 8.0 벤질 알코올Benzyl alcohol 8.6 8.6 8.3 8.3 8.0 8.0 7.7 7.7 7.4 7.4 7.0 7.0 6.8 6.8 헥산올Hexanol 4.8 4.8 4.8 4.8 5.0 5.0 5.0 5.0 4.5 4.5 4.0 4.0 4.0 4.0 리날로울Linalool 4.6 4.6 3.9 3.9 3.0 3.0 2.3 2.3 2.1 2.1 2.0 2.0 1.2 1.2 총 함량Total content 100100 100100 100100 100100 100100 100100 100100

[ 실험예 1] 향료 조성물들의 관능평가 [Test Example 1] Sensory evaluation of fragrance compositions

상기에서 #가 내지 #사 조합향료들에 대하여, 상기 비교실험예 1과 동일한 방법으로 천연 감국꽃과의 향취 유사성 및 향취의 기호성에 대한 관능평가를 실시하였다. 두 개의 향료에 대한 비교관능평가를 실시한 후, 5분 동안의 휴식시간을 주어, 후감각 마비현상이 없도록 하였다. 새로운 조합향료와 감국꽃과의 향취 유사성 및 향취 기호성에 결과는 하기 표 8에서 보는 바와 같다
In the above # # to # 4 combination fragrance, the sensory evaluation of the taste similarity and taste of the flavor with natural persimmon flower was carried out in the same manner as in Comparative Experiment 1. After conducting the comparative sensory evaluation of the two flavors, a 5-minute rest period was provided to prevent the parasensory paralysis. The results of the odor similarity and odor palatability of the new combination perfume and persimmon flower are shown in Table 8 below.

평가요원Rating agent 질문1 (유사성)Question 1 (similarity) 질문2 (기호성)Question 2 (symbolity) #가#end #나#I #다#All #라#la #마#hemp #바#bar #사#four #가#end #나#I #다#All #라#la #마#hemp #바#bar #사#four 1One 2.0 2.0 3.0 3.0 5.0 5.0 5.0 5.0 4.0 4.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 2.0 2.0 22 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 33 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 2.0 2.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 44 3.0 3.0 3.0 3.0 5.0 5.0 5.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 55 2.0 2.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 66 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 2.0 2.0 2.0 2.0 77 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 88 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 2.0 2.0 4.0 4.0 4.0 4.0 5.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 99 3.0 3.0 3.0 3.0 3.0 3.0 5.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 1010 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 5.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 1111 3.0 3.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 1212 3.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 5.0 5.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 2.0 2.0 1313 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 2.0 2.0 2.0 2.0 1414 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 2.0 2.0 1515 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 1616 3.0 3.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 1717 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 1818 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 1919 2.0 2.0 3.0 3.0 3.0 3.0 5.0 5.0 4.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 2020 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 평균Average 2.6 2.6 3.4 3.4 3.9 3.9 4.5 4.5 3.9 3.9 3.4 3.4 2.6 2.6 2.8 2.8 3.4 3.4 3.8 3.8 4.4 4.4 3.7 3.7 3.0 3.0 2.6 2.6

상기 표 8의 결과에서 알 수 있듯이, 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)의 감국꽃 향취의 주성분에 헤디온 3.0 내지 7.0중량%를 함유할 때, 감국꽃의 향취를 재현할 수 있는 동시에 기호성이 높은 것을 확인할 수 있었다(평균 3.0이상). 특히, 헤디온을 4.0 내지 6.0중량%로 함유할 경우에는 감국꽃과의 향취 유사성 및 향취 기호성이 매우 뛰어남을 알 수 있었다(평균 3.5이상).As can be seen from the results of Table 8, Hedion 3.0 to 7.0% by weight in the main components of the persimmon odor of phenyl acetaldehyde, benzaldehyde, benzaldehyde (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol) When contained, the fragrance of persimmon flower could be reproduced and palatability was high (average 3.0 or more). In particular, when containing 4.0 to 6.0% by weight of hedion was found to be very good odor similarity and taste preference with persimmon flower (average 3.5 or more).

한편, 헤디온을 3.0중량% 미만 또는 7.0중량% 초과로 함유하면 오히려 향취의 유사성 및 기호성이 낮아짐을 알 수 있었다.
On the other hand, containing less than 3.0% by weight or more than 7.0% by weight was found that the similarity and palatability of the odor rather lower.

[ 제조예 1] 향수의 제조 [Preparation Example 1] Preparation of perfume

상기 실시예 1에서 제조한 향료 조성물을 사용하여, 하기 표 9의 향수를 제조하였다(단위: 중량%).
Using the perfume composition prepared in Example 1, to prepare a perfume of Table 9 (unit: wt%).

성분ingredient 함량
(단위: 중량%)
content
(Unit: weight%)
감국꽃 향료 조성물
(실시예 1의 #나 내지 #바)
Persimmon flower fragrance composition
(#B to #bar of Example 1)
1515
알코올Alcohol 8383 water 22 색소Pigment 적량Suitable amount 자외선차단제Sunscreen 적량Suitable amount

Claims (10)

국화의 향취 성분 및 헤디온(Hedione) 성분을 유효성분으로 함유하는 국화의 향취를 재현한 향료 조성물.Flavor composition which reproduces the fragrance of chrysanthemum which contains the fragrance component of chrysanthemum and Hedione component as an active ingredient. 제 1항에 있어서,
상기 국화의 향취 성분은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)로 구성된 군으로부터 선택된 하나 이상을 포함하는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 1,
Fragrance component of the chrysanthemum is to reproduce the scent of chrysanthemum is one or more selected from the group consisting of phenyl acetaldehyde (Phenyl acetaldehyde), Benzaldehyde (Benzldehyde), Camper (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol) Fragrance composition.
제 2항에 있어서,
상기 국화의 향취 성분은 페닐아세트알데히드(Phenyl acetaldehyde), 벤즈알데히드(Benzldehyde), 캠퍼(Camphor) 및 페닐에틸알코올(Phenyl ethyl alcohol)을 포함하는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 2,
Flavor component of the chrysanthemum is a fragrance composition that reproduces the scent of chrysanthemum, including phenyl acetaldehyde (Phenyl acetaldehyde), benzaldehyde (Benzldehyde), Camper (Camphor) and phenyl ethyl alcohol (Phenyl ethyl alcohol).
제 3항에 있어서,
상기 조성물은 조성물 총 중량에 대하여 페닐아세트알데히드(Phenyl acetaldehyde) 25 내지 40중량%, 벤즈알데히드(Benzldehyde) 20 내지 30중량%, 캠퍼(Camphor) 7 내지 15중량%, 및 페닐에틸알코올(Phenyl ethyl alcohol) 5 내지 10중량%로 포함하는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 3, wherein
The composition comprises 25 to 40% by weight of phenyl acetaldehyde, 20 to 30% by weight of Benzdehyde, 7 to 15% by weight of Camphor, and phenylethyl alcohol Perfume composition reproducing the scent of chrysanthemum to be contained in 5 to 10% by weight.
제 1항에 있어서,
상기 조성물은 벤질알코올(Benzyl alcohol), 헥산올(Hexanol) 및 리날로울(Linalool)로 구성된 군으로부터 선택된 하나 이상을 더 포함하는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 1,
The composition is a fragrance composition reproducing the scent of chrysanthemum is one or more selected from the group consisting of benzyl alcohol (Benzyl alcohol), hexanol (Hexanol) and Linalool (Linalool).
제 5항에 있어서,
상기 조성물은 벤질알코올(Benzyl alcohol), 헥산올(Hexanol) 및 리날로울(Linalool)을 더 포함하는 것인 국화의 향취를 재현한 향료 조성물.
6. The method of claim 5,
The composition is a fragrance composition reproducing the scent of chrysanthemum will further include benzyl alcohol (Benzyl alcohol), hexanol (Hexanol) and Linalool (Linalool).
제 6항에 있어서,
상기 조성물은 조성물 총 중량에 대하여 벤질알코올(Benzyl alcohol) 5 내지 15중량%, 헥산올(Hexanol) 3 내지 12 중량%, 리날로울(Linalool) 2 내지 10중량%를 더 포함하는 것인 국화의 향취를 재현한 향료 조성물.
The method according to claim 6,
The composition of the chrysanthemum further comprises 5 to 15% by weight of Benzyl alcohol, 3 to 12% by weight of hexanol, 2 to 10% by weight of linalool based on the total weight of the composition Perfume composition that reproduces the smell.
제 1항에 있어서,
상기 국화의 향취 성분은 조성물 총 중량에 대하여 70 내지 80 중량%로 포함되는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 1,
Flavor component of the chrysanthemum is a flavor composition of the chrysanthemum is contained in 70 to 80% by weight relative to the total weight of the composition.
제 1항에 있어서,
상기 헤디온 성분은 조성물 총 중량에 대하여 3 내지 7 중량%로 포함되는 것인 국화의 향취를 재현한 향료 조성물.
The method of claim 1,
The Hedion component is a flavor composition reproducing the smell of chrysanthemum is contained in 3 to 7% by weight based on the total weight of the composition.
제 1항 내지 제 9항 중 어느 한 항에 따른 향료 조성물을 함유하는 피부 외용제 조성물.An external preparation composition for skin containing the perfume composition according to any one of claims 1 to 9.
KR1020110026233A 2011-03-24 2011-03-24 Perfume composition for expressing the fragrance of chrysanthemum indicum and the composition for skin external application containing the same KR101770682B1 (en)

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* Cited by examiner, † Cited by third party
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KR20160097767A (en) * 2015-02-10 2016-08-18 주식회사 엘지생활건강 Perfume composition
WO2017183744A1 (en) * 2016-04-20 2017-10-26 주식회사 엘지생활건강 Aroma composition
KR20190102406A (en) * 2018-02-26 2019-09-04 주식회사 엘지생활건강 Perfume composition for expressing the fragrance of Cymbidium cultiva'Aroma Pink'

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KR101881668B1 (en) * 2016-12-05 2018-07-24 주식회사 엘지생활건강 Perfume composition representing the fragrance of Lilium hansonii Leichtlin
KR102672909B1 (en) * 2018-10-01 2024-06-10 (주)아모레퍼시픽 Cosmetic composition for external application for skin comprising Palmarosa oil and aroma composition as an active ingredient

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KR200214224Y1 (en) * 2000-04-06 2001-02-15 신완우 Pillow having chrysanthemum or fagopyrum powder therein

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Publication number Priority date Publication date Assignee Title
KR20160097767A (en) * 2015-02-10 2016-08-18 주식회사 엘지생활건강 Perfume composition
WO2017183744A1 (en) * 2016-04-20 2017-10-26 주식회사 엘지생활건강 Aroma composition
KR20190102406A (en) * 2018-02-26 2019-09-04 주식회사 엘지생활건강 Perfume composition for expressing the fragrance of Cymbidium cultiva'Aroma Pink'

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