KR102598797B1 - Perfume composition for reproducibly expressing the fragrance of Calanthe sieboldii Decne. ex Regel - Google Patents
Perfume composition for reproducibly expressing the fragrance of Calanthe sieboldii Decne. ex Regel Download PDFInfo
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- KR102598797B1 KR102598797B1 KR1020180124322A KR20180124322A KR102598797B1 KR 102598797 B1 KR102598797 B1 KR 102598797B1 KR 1020180124322 A KR1020180124322 A KR 1020180124322A KR 20180124322 A KR20180124322 A KR 20180124322A KR 102598797 B1 KR102598797 B1 KR 102598797B1
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- 239000003205 fragrance Substances 0.000 title claims abstract description 150
- 239000000203 mixture Substances 0.000 title claims abstract description 95
- 239000002304 perfume Substances 0.000 title description 5
- 241000983858 Calanthe striata var. sieboldii Species 0.000 title description 3
- 241000238562 Farfantepenaeus aztecus Species 0.000 claims abstract description 55
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 claims abstract description 41
- 241000233855 Orchidaceae Species 0.000 claims abstract description 40
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims abstract description 39
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 30
- OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 claims abstract description 30
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 30
- 229930008380 camphor Natural products 0.000 claims abstract description 30
- 229960000846 camphor Drugs 0.000 claims abstract description 30
- AGMLTHHZJKHNLS-YHQKBTMFSA-N (6z,9e)-heptadeca-6,9-diene Chemical compound CCCCCCC\C=C\C\C=C/CCCCC AGMLTHHZJKHNLS-YHQKBTMFSA-N 0.000 claims abstract description 24
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims abstract description 24
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims abstract description 24
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims abstract description 21
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 claims abstract description 21
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 claims abstract description 20
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 claims abstract description 19
- FQTLCLSUCSAZDY-SDNWHVSQSA-N (6E)-nerolidol Chemical compound CC(C)=CCC\C(C)=C\CCC(C)(O)C=C FQTLCLSUCSAZDY-SDNWHVSQSA-N 0.000 claims abstract description 19
- FQTLCLSUCSAZDY-SZGZABIGSA-N (E)-Nerolidol Natural products CC(C)=CCC\C(C)=C/CC[C@@](C)(O)C=C FQTLCLSUCSAZDY-SZGZABIGSA-N 0.000 claims abstract description 19
- ZLWGOLLBNDIBMM-UHFFFAOYSA-N trans-nerolidol Natural products CC(C)C(=C)C(O)CCC=C(/C)CCC=C(C)C ZLWGOLLBNDIBMM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005973 Carvone Substances 0.000 claims abstract description 12
- 239000004615 ingredient Substances 0.000 claims description 32
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 30
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 claims description 20
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 20
- QBCUUJGHWFKMDC-UHFFFAOYSA-N 3-Hydroxy-4-phenylbutan-2-one Chemical compound CC(=O)C(O)CC1=CC=CC=C1 QBCUUJGHWFKMDC-UHFFFAOYSA-N 0.000 claims description 18
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 18
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 18
- 229940095102 methyl benzoate Drugs 0.000 claims description 15
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 10
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 10
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 10
- NQFUSWIGRKFAHK-BDNRQGISSA-N alpha-Pinene epoxide Natural products C([C@@H]1O[C@@]11C)[C@@H]2C(C)(C)[C@H]1C2 NQFUSWIGRKFAHK-BDNRQGISSA-N 0.000 claims description 10
- 229930006723 alpha-pinene oxide Natural products 0.000 claims description 10
- 229930007744 linalool Natural products 0.000 claims description 10
- 125000003425 alpha-pinene oxide group Chemical group 0.000 claims description 9
- 229960001047 methyl salicylate Drugs 0.000 claims description 9
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 8
- CXENHBSYCFFKJS-LOQWIJHWSA-N (E,E)-alpha-farnesene Natural products CC(C)=CCC\C(C)=C/C\C=C(\C)C=C CXENHBSYCFFKJS-LOQWIJHWSA-N 0.000 claims description 3
- 241000238557 Decapoda Species 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 3
- ZLEFBGVPYZUUGI-UHFFFAOYSA-N methyl benzoate;2-methylbenzoic acid Chemical compound COC(=O)C1=CC=CC=C1.CC1=CC=CC=C1C(O)=O ZLEFBGVPYZUUGI-UHFFFAOYSA-N 0.000 claims description 2
- -1 2-butanone (3-hydroxy-4-phenyl-2-butanone) Chemical compound 0.000 claims 1
- PUGIWBCKLHQEFV-UHFFFAOYSA-N COC1=CC=C(C=C1)OC.C1(=CC=CC=C1)OC Chemical compound COC1=CC=C(C=C1)OC.C1(=CC=CC=C1)OC PUGIWBCKLHQEFV-UHFFFAOYSA-N 0.000 claims 1
- 229940067107 phenylethyl alcohol Drugs 0.000 claims 1
- 235000019629 palatability Nutrition 0.000 description 25
- 238000012360 testing method Methods 0.000 description 23
- 238000000034 method Methods 0.000 description 19
- 235000013601 eggs Nutrition 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 12
- 230000001953 sensory effect Effects 0.000 description 12
- 239000000796 flavoring agent Substances 0.000 description 10
- 235000019634 flavors Nutrition 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 238000002470 solid-phase micro-extraction Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000004817 gas chromatography Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- IAVREABSGIHHMO-UHFFFAOYSA-N meta-hydroxybenzaldehyde Natural products OC1=CC=CC(C=O)=C1 IAVREABSGIHHMO-UHFFFAOYSA-N 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- CXENHBSYCFFKJS-UHFFFAOYSA-N α-farnesene Chemical compound CC(C)=CCCC(C)=CCC=C(C)C=C CXENHBSYCFFKJS-UHFFFAOYSA-N 0.000 description 2
- CRDAMVZIKSXKFV-YFVJMOTDSA-N (2-trans,6-trans)-farnesol Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CO CRDAMVZIKSXKFV-YFVJMOTDSA-N 0.000 description 1
- JXBSHSBNOVLGHF-UHFFFAOYSA-N 10-cis-Dihydrofarnesen Natural products CC=C(C)CCC=C(C)CCC=C(C)C JXBSHSBNOVLGHF-UHFFFAOYSA-N 0.000 description 1
- NQFUSWIGRKFAHK-UHFFFAOYSA-N 2,3-epoxypinane Chemical compound CC12OC1CC1C(C)(C)C2C1 NQFUSWIGRKFAHK-UHFFFAOYSA-N 0.000 description 1
- NJESAXZANHETJV-UHFFFAOYSA-N 4-methylsalicylic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1 NJESAXZANHETJV-UHFFFAOYSA-N 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000021559 Dicerandra Species 0.000 description 1
- 241001094255 Elytraria Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000745768 Pluchea carolinensis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- FAMPSKZZVDUYOS-UHFFFAOYSA-N alpha-Caryophyllene Natural products CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 description 1
- JSNRRGGBADWTMC-UHFFFAOYSA-N alpha-farnesene Natural products CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229940117948 caryophyllene Drugs 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Abstract
본 명세서에는 금새우난의 향취를 재현한 향료 조성물이 개시된다. 상기 향료 조성물은 금새우난의 향취 성분 및 캠퍼를 포함하며, 상기 향취 성분은 6(Z),9(E)-헵타데카디엔, 트랜스-네롤리돌, 베타-카리오필렌, 알파-피넨, 메틸 벤조에이트, 1,4-다이메톡시벤젠, 트랜스-알파-파네신 및 카르본을 포함한다.Disclosed herein is a fragrance composition that reproduces the scent of golden shrimp orchids. The fragrance composition includes the fragrance components of golden shrimp orchid and camphor, and the fragrance components include 6(Z),9(E)-heptadecadiene, trans-nerolidol, beta-caryophyllene, alpha-pinene, and methyl benzo. ate, 1,4-dimethoxybenzene, trans-alpha-farnesine and carvone.
Description
본 명세서에는 금새우난의 향취를 재현한 향료 조성물이 개시된다.Disclosed herein is a fragrance composition that reproduces the scent of golden shrimp orchids.
금새우난의 향취를 재현하기 위한 방법으로는 여러 가지가 있을 수 있다. 예를 들면, 통상적인 방법으로 금새우난의 향취 성분을 화정유 (Absolute) 형태로 만드는 용매추출법과 향취 성분을 정유 (Essential oil)로 만드는 수증기증류법이 있다. 그러나, 상기 방법들은 추출 과정에서 높은 열을 가해야 하고 처리 과정이 복잡하여 많은 시간이 소요되므로 본래의 향취와는 많은 차이가 있을 수 있고, 개체수가 많지 않은 금새우난과 같은 경우에는 충분한 원료를 수급하기 힘들다는 한계를 가지고 있다.There are many ways to recreate the flavor of golden shrimp orchid. For example, common methods include a solvent extraction method to convert the fragrant components of golden shrimp orchids into essential oil (Absolute) and a steam distillation method to convert the fragrant components into essential oils (Essential oil). However, the above methods require high heat to be applied during the extraction process and the processing process is complicated and takes a lot of time, so there may be a significant difference from the original scent, and in the case of golden shrimp orchids, which do not have a large population, sufficient raw materials are required. It has limitations in that it is difficult to supply.
최근에는 이러한 단점을 보완하기 위해서, 고상 마이크로 추출법 (Solid Phase Micro Extraction)을 비롯하여 헤드 스페이스법 (Head Space)이 개발되었다. 헤드 스페이스법은 시료를 밀폐된 용기에 넣고 가열하여 휘발성 물질을 용기의 위쪽 공간에 모이게 하여 뽑아내는 방법으로, 실온에서 사람이 코로 맡을 수 있는 정도의 휘발성을 갖는 성분을 뽑아내고자 하는 경우에 바람직하다. 또한, 헤드 스페이스법은 기존의 추출법과는 달리 용매를 사용하지 않고 전처리 또한 필요 없어 신속하고 간편하게 향취 성분을 분석할 수 있는 장점이 있다. 다만, 휘발성이 좋은 향취 성분은 분석이 용이하지만, 휘발성이 낮거나 분자량이 큰 향취 성분들은 이 방법으로 분석이 쉽지 않다는 단점도 지니고 있다.Recently, in order to compensate for these shortcomings, head space methods including solid phase micro extraction have been developed. The headspace method is a method of extracting volatile substances by placing a sample in a sealed container and heating it to collect volatile substances in the upper space of the vessel. It is preferable when extracting components with a level of volatility that a person can smell through the nose at room temperature. . In addition, unlike existing extraction methods, the headspace method does not use solvents and does not require pretreatment, so it has the advantage of being able to analyze scent components quickly and easily. However, although highly volatile fragrance components are easy to analyze, fragrance components with low volatility or high molecular weight also have the disadvantage of being difficult to analyze using this method.
한편, GC (Gas Chromatography)는 휘발성 물질의 정성 및 정량 분석을 하는데 매우 유용한 기기 분석법이므로 모든 향취 성분 분석에 광범위하게 이용되고 있다. 하지만 향취 성분 중에는 역치값이 매우 낮아 저농도에서도 강하게 향을 발현하는 휘발성 성분이 존재하는 반면, 그 역치값이 매우 높아 고농도에서도 향을 발현하지 못하는 휘발성 성분도 존재한다. 따라서, 단순히 GC를 통해 정량적으로 주요하게 발견되는 휘발성 성분이 반드시 특정 물질의 주요 향취 성분이라고 말할 수는 없다. 이러한 문제점을 해결하기 위해, GC-O (Gas Chromatography Olfactometry)의 방법이 개발되어 사용되고 있다. GC-O는 향취 성분을 크로마토그램의 피크를 통해 분석하는 동시에 직접 향기를 맡으면서 피크로는 나타나지 않지만 실제로 향을 내는 성분을 동정하는 방법이다.Meanwhile, GC (Gas Chromatography) is a very useful instrumental analysis method for qualitative and quantitative analysis of volatile substances, so it is widely used in the analysis of all fragrance components. However, among fragrance components, there are volatile components that have a very low threshold value and express a strong scent even at low concentrations, while there are also volatile components that have a very high threshold value and cannot express scent even at high concentrations. Therefore, it cannot be said that the volatile components found quantitatively through GC are necessarily the main odor components of a specific substance. To solve these problems, the GC-O (Gas Chromatography Olfactometry) method has been developed and used. GC-O is a method of analyzing scent components through peaks in a chromatogram and at the same time smelling the scent directly to identify components that do not appear as peaks but actually produce scent.
일 측면에서, 본 명세서는 금새우난의 고유 향취를 재현한 향료 조성물을 제공하는 것을 목적으로 한다.In one aspect, the purpose of the present specification is to provide a fragrance composition that reproduces the unique scent of golden shrimp orchid.
다른 측면에서, 본 명세서는 상기 향료 조성물을 포함하는 피부 외용제 조성물 및 방향제 조성물을 제공하는 것을 목적으로 한다.In another aspect, the purpose of the present specification is to provide a composition for external application to the skin and a fragrance composition containing the fragrance composition.
일 측면에서, 본 명세서에 개시된 기술은 금새우난의 향취 성분 및 캠퍼 (camphor)를 유효성분으로 포함하는 금새우난의 향취를 재현한 향료 조성물을 제공한다.In one aspect, the technology disclosed in the present specification provides a fragrance composition that reproduces the fragrance of golden shrimp eggs, including the fragrant components of golden shrimp eggs and camphor as active ingredients.
예시적인 일 구현예에서, 상기 향취 성분은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene), 트랜스-네롤리돌 (trans-nerolidol), 베타-카리오필렌 (β-caryophyllene), 알파-피넨 (α-pinene), 메틸 벤조에이트 (methyl benzoate), 1,4-다이메톡시벤젠 (1,4-dimethoxybenzene), 트랜스-알파-파네신 (trans-α-farnesene) 및 카르본 (carvone)을 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance ingredient is 6(Z),9(E)-heptadecadiene, trans-nerolidol, beta- Caryophyllene (β-caryophyllene), alpha-pinene (α-pinene), methyl benzoate, 1,4-dimethoxybenzene, trans-alpha-farnesine (trans- It may contain α-farnesene) and carvone.
예시적인 일 구현예에서, 상기 향취 성분은 향료 조성물 전체 중량을 기준으로 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene)을 20 내지 28 중량%로 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance ingredient is 20 to 28% by weight of 6(Z),9(E)-heptadecadiene (6(Z),9(E)-heptadecadiene) based on the total weight of the fragrance composition. It may be included.
예시적인 일 구현예에서, 상기 향취 성분은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene) 20 내지 28 중량부에 대하여, 트랜스-네롤리돌 (trans-nerolidol) 14 내지 20 중량부, 베타-카리오필렌 (β-caryophyllene) 9 내지 15 중량부, 알파-피넨 (α-pinene) 7 내지 13 중량부, 메틸 벤조에이트 (methyl benzoate) 6 내지 10 중량부, 1,4-다이메톡시벤젠 (1,4-dimethoxybenzene) 4 내지 8 중량부, 트랜스-알파-파네신 (trans-α-farnesene) 4 내지 6 중량부 및 카르본 (carvone) 4 내지 6 중량부를 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance ingredient is 20 to 28 parts by weight of 6(Z),9(E)-heptadecadiene, trans-nerolidol ( trans-nerolidol) 14 to 20 parts by weight, beta-caryophyllene (β-caryophyllene) 9 to 15 parts by weight, alpha-pinene (α-pinene) 7 to 13 parts by weight, methyl benzoate (methyl benzoate) 6 to 10 parts by weight parts, 4 to 8 parts by weight of 1,4-dimethoxybenzene, 4 to 6 parts by weight of trans-α-farnesene, and 4 to 6 parts by weight of carvone. It may include parts by weight.
예시적인 일 구현예에서, 상기 캠퍼 (camphor)는 향료 조성물 전체 중량을 기준으로 1.5 내지 3.5 중량%로 포함되는 것일 수 있다.In an exemplary embodiment, the camphor may be included in an amount of 1.5 to 3.5% by weight based on the total weight of the fragrance composition.
예시적인 일 구현예에서, 상기 향료 조성물은 향취 성분 및 캠퍼 (camphor)를 85 내지 95 : 1.5 내지 3.5의 중량비로 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance composition may include a fragrance ingredient and camphor at a weight ratio of 85 to 95:1.5 to 3.5.
예시적인 일 구현예에서, 상기 향료 조성물은 메틸 살리실레이트 (methyl salicylate), 리날룰 (linalool), 알파-피넨 에폭사이드 (α-pinene epoxide), 메틸 헥사데카노에이트 (methyl hexadecanoate), 3-하이드록시-4-페닐-2-부타논 (3-hydroxy-4-phenyl-2-butanone), 벤즈알데하이드 (benzaldehyde) 및 2-페닐에틸 알콜 (2-phenylethyl alcohol)로 이루어진 군에서 선택되는 1 이상을 더 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance composition includes methyl salicylate, linalool, alpha-pinene epoxide, methyl hexadecanoate, 3- At least one selected from the group consisting of 3-hydroxy-4-phenyl-2-butanone, benzaldehyde, and 2-phenylethyl alcohol It may further include.
예시적인 일 구현예에서, 상기 향료 조성물은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene) 20 내지 28 중량부에 대하여, 1 내지 2 중량부의 메틸 살리실레이트 (methyl salicylate), 1 내지 1.5 중량부의 리날룰 (linalool), 1 내지 1.5 중량부의 알파-피넨 에폭사이드 (α-pinene epoxide), 0.8 내지 1.3 중량부의 메틸 헥사데카노에이트 (methyl hexadecanoate), 0.8 내지 1.2 중량부의 3-하이드록시-4-페닐-2-부타논 (3-hydroxy-4-phenyl-2-butanone), 0.7 내지 1 중량부의 벤즈알데하이드 (benzaldehyde) 및 0.5 내지 0.7 중량부의 2-페닐에틸 알콜 (2-phenylethyl alcohol)로 이루어진 군에서 선택되는 1 이상을 더 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance composition contains 1 to 2 parts by weight, based on 20 to 28 parts by weight of 6(Z),9(E)-heptadecadiene. Methyl salicylate, 1 to 1.5 parts by weight of linalool, 1 to 1.5 parts by weight of α-pinene epoxide, 0.8 to 1.3 parts by weight of methyl hexadecanoate ), 0.8 to 1.2 parts by weight of 3-hydroxy-4-phenyl-2-butanone, 0.7 to 1 part by weight of benzaldehyde and 0.5 to 0.7 parts by weight It may further include one or more selected from the group consisting of 2-phenylethyl alcohol.
다른 측면에서, 본 명세서에 개시된 기술은 상기 향료 조성물을 포함하는 피부 외용제 조성물을 제공한다.In another aspect, the technology disclosed herein provides a composition for external application to the skin containing the fragrance composition.
다른 측면에서, 본 명세서에 개시된 기술은 향료 조성물을 포함하는 방향제 조성물을 제공한다.In another aspect, the technology disclosed herein provides a fragrance composition comprising a fragrance composition.
일 측면에서, 본 명세서에 개시된 기술은 금새우난의 향취를 재현한 향료 조성물을 제공하는 효과가 있다.In one aspect, the technology disclosed in this specification has the effect of providing a fragrance composition that reproduces the scent of golden shrimp orchids.
다른 측면에서, 본 명세서에 개시된 기술은 상기 향료 조성물을 포함하는 피부 외용제 조성물 및 방향제 조성물을 제공하는 효과가 있다.In another aspect, the technology disclosed in the present specification has the effect of providing a skin external application composition and a fragrance composition including the fragrance composition.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
일 측면에서, 본 명세서에 개시된 기술은 금새우난의 향취 성분 및 캠퍼를 유효성분으로 포함하는 금새우난의 향취를 재현한 향료 조성물을 제공한다.In one aspect, the technology disclosed in the present specification provides a fragrance composition that reproduces the fragrance of golden shrimp eggs, including the fragrant components of golden shrimp eggs and camphor as active ingredients.
금새우난 (Calanthe sieboldii Decne. ex Regel)은 우리나라 남부 해안 지역과 제주도 서해안 일부 지역에서 자라는 난과식물이다. 상록성의 여러해살이풀이며, 높이는 20~50 ㎝이다. 헛비늘줄기가 매년 한 개씩 늘어나면서 마디가 많아져 염주 또는 새우의 등 모양을 이루고 수염 뿌리가 많이 달린다. 잎은 2~3개가 어긋나기하고 넓은 타원형이며, 잎맥을 따라 주름져 있고 가장자리는 물결 모양이다. 길이는 20~30 ㎝, 폭은 5~15 ㎝이다. 겨울에 땅 위로 나와 월동하고는 봄에 교체된다. 노란색의 꽃은 관상 가치가 매우 높아 남획 위협에 처해 있다. Calanthe sieboldii Decne. ex Regel) is an orchid plant that grows in the southern coastal area of Korea and some areas on the west coast of Jeju Island. It is an evergreen perennial herb with a height of 20 to 50 cm. As the scaly stem increases by one each year, the number of nodes increases, forming the shape of a beads or a shrimp's back, and many beard roots are attached. The leaves are alternately arranged in 2-3 pieces, have a wide oval shape, are wrinkled along the leaf veins, and have wavy edges. The length is 20-30 cm and the width is 5-15 cm. They come out onto the ground in winter, overwinter, and are replaced in spring. The yellow flowers have great ornamental value and are under threat of overexploitation.
본 명세서에 따른 향료 조성물은 주요 향취 성분으로 6(Z),9(E)-헵타데카디엔, 트랜스-네롤리돌, 베타-카리오필렌, 알파-피넨, 메틸 벤조에이트, 1,4-다이메톡시벤젠, 트랜스-알파-파네신 및 카르본을 포함한다.The fragrance composition according to the present specification contains 6(Z),9(E)-heptadecadiene, trans-nerolidol, beta-caryophyllene, alpha-pinene, methyl benzoate, and 1,4-dimethoxy as the main fragrance ingredients. Includes benzene, trans-alpha-farnesine and carvone.
본 명세서에 따른 향료 조성물은 6(Z),9(E)-헵타데카디엔, 트랜스-네롤리돌, 베타-카리오필렌, 알파-피넨, 메틸 벤조에이트, 1,4-다이메톡시벤젠, 트랜스-알파-파네신 및 카르본으로 구성된 금새우난의 향취 성분에 캠퍼를 첨가함으로써 천연 금새우난의 향취를 재현하고 향취의 기호성도 개선하는 효과가 있다.The fragrance composition according to the present specification includes 6(Z),9(E)-heptadecadiene, trans-nerolidol, beta-caryophyllene, alpha-pinene, methyl benzoate, 1,4-dimethoxybenzene, trans- By adding camphor to the fragrance component of golden shrimp eggs, which consists of alpha-farnesine and carbone, it has the effect of reproducing the scent of natural golden shrimp eggs and improving the palatability of the scent.
예시적인 일 구현예에서, 본 명세서에 따른 향료 조성물은 메틸 살리실레이트, 리날룰, 알파-피넨 에폭사이드, 메틸 헥사데카노에이트, 3-하이드록시-4-페닐-2-부타논, 벤즈알데하이드 및 2-페닐에틸 알콜로 이루어진 군에서 선택되는 1 이상의 보조 향취 성분을 더 포함하는 것일 수 있다.In one exemplary embodiment, the perfume composition according to the present disclosure includes methyl salicylate, linalool, alpha-pinene epoxide, methyl hexadecanoate, 3-hydroxy-4-phenyl-2-butanone, benzaldehyde And it may further include one or more auxiliary fragrance ingredients selected from the group consisting of 2-phenylethyl alcohol.
예시적인 일 구현예에서, 상기 향취 성분은 향료 조성물 전체 중량을 기준으로 6(Z),9(E)-헵타데카디엔을 20 내지 28 중량%, 22 내지 28 중량%, 22 내지 27 중량%, 22 내지 26 중량%, 22 내지 25 중량%, 22 내지 24 중량%, 23 내지 26 중량%, 24 내지 26 중량% 또는 24 내지 25 중량%로 포함하는 것이 금새우난과의 향취 유사성 및 향취 기호성 면에서 바람직할 수 있다.In an exemplary embodiment, the fragrance ingredient is 20 to 28% by weight, 22 to 28% by weight, 22 to 27% by weight of 6(Z),9(E)-heptadecadiene, based on the total weight of the fragrance composition. 22 to 26% by weight, 22 to 25% by weight, 22 to 24% by weight, 23 to 26% by weight, 24 to 26% by weight or 24 to 25% by weight is included in terms of flavor similarity and flavor preference with golden shrimp orchid. may be desirable.
예시적인 일 구현예에서, 상기 향취 성분은 6(Z),9(E)-헵타데카디엔 20 내지 28 중량부 또는 22 내지 28 중량부에 대하여, 트랜스-네롤리돌 14 내지 20 중량부, 베타-카리오필렌 9 내지 15 중량부, 알파-피넨 7 내지 13 중량부, 메틸 벤조에이트 6 내지 10 중량부, 1,4-다이메톡시벤젠 4 내지 8 중량부, 트랜스-알파-파네신 4 내지 6 중량부 및 카르본 4 내지 6 중량부를 포함하는 것일 수 있다.In an exemplary embodiment, the fragrance ingredient is 14 to 20 parts by weight of trans-nerolidol, beta- 9 to 15 parts by weight of caryophyllene, 7 to 13 parts by weight of alpha-pinene, 6 to 10 parts by weight of methyl benzoate, 4 to 8 parts by weight of 1,4-dimethoxybenzene, 4 to 6 parts by weight of trans-alpha-farnesine parts and 4 to 6 parts by weight of carvone.
예시적인 일 구현예에서, 상기 향취 성분은 6(Z),9(E)-헵타데카디엔 20 내지 28 중량부, 22 내지 28 중량부 또는 22 내지 25 중량부에 대하여, 트랜스-네롤리돌 16 내지 18 중량부 또는 17 내지 18 중량부, 베타-카리오필렌 11 내지 13 중량부 또는 12 내지 13 중량부, 알파-피넨 9 내지 11 중량부 또는 10 내지 11 중량부, 메틸 벤조에이트 7 내지 9 중량부 또는 8 내지 9 중량부, 1,4-다이메톡시벤젠 6 내지 7 중량부, 트랜스-알파-파네신 5 내지 6 중량부 및 카르본 5 내지 6 중량부를 포함하는 것이 바람직할 수 있다.In an exemplary embodiment, the fragrance ingredient is 16 to 16 parts by weight of trans-nerolidol, relative to 20 to 28 parts by weight, 22 to 28 parts by weight, or 22 to 25 parts by weight of 6(Z),9(E)-heptadecadiene. 18 parts by weight or 17 to 18 parts by weight, beta-caryophyllene 11 to 13 parts by weight or 12 to 13 parts by weight, alpha-pinene 9 to 11 parts by weight or 10 to 11 parts by weight, methyl benzoate 7 to 9 parts by weight or It may be preferable to include 8 to 9 parts by weight, 6 to 7 parts by weight of 1,4-dimethoxybenzene, 5 to 6 parts by weight of trans-alpha-farnesine, and 5 to 6 parts by weight of carvone.
예시적인 일 구현예에서, 상기 향료 조성물은 6(Z),9(E)-헵타데카디엔 20 내지 28 중량부 또는 22 내지 28 중량부에 대하여, 1 내지 2 중량부의 메틸 살리실레이트, 1 내지 1.5 중량부의 리날룰, 1 내지 1.5 중량부의 알파-피넨 에폭사이드, 0.8 내지 1.3 중량부의 메틸 헥사데카노에이트, 0.8 내지 1.2 중량부의 3-하이드록시-4-페닐-2-부타논, 0.7 내지 1 중량부의 벤즈알데하이드 및 0.5 내지 0.7 중량부의 2-페닐에틸 알콜로 이루어진 군에서 선택되는 1 이상의 보조 향취 성분을 더 포함하는 것일 수 있다. 상기 향료 조성물은 보조 향취 성분을 상기 범위로 포함하는 것이 바람직하지만, 금새우난의 향취를 재현하는 데에 크게 영향을 미치지 않으므로 금새우난 향취를 재현하는 데에 영향을 미치지 않는 한, 상기 범위를 벗어나는 양으로도 함유될 수 있다.In an exemplary embodiment, the fragrance composition contains 1 to 2 parts by weight of methyl salicylate, based on 20 to 28 parts by weight or 22 to 28 parts by weight of 6(Z),9(E)-heptadecadiene. 1.5 parts by weight linalool, 1 to 1.5 parts by weight alpha-pinene epoxide, 0.8 to 1.3 parts by weight methyl hexadecanoate, 0.8 to 1.2 parts by weight 3-hydroxy-4-phenyl-2-butanone, 0.7 to 1 part by weight It may further include one or more auxiliary fragrance ingredients selected from the group consisting of benzaldehyde and 0.5 to 0.7 parts by weight of 2-phenylethyl alcohol. The fragrance composition preferably contains an auxiliary fragrance component within the above range, but since it does not significantly affect the reproduction of the fragrance of golden shrimp orchids, the above range is limited as long as it does not affect the reproduction of the fragrance of golden shrimp orchids. It may also be contained in excessive amounts.
예시적인 일 구현예에서, 상기 캠퍼는 향료 조성물 전체 중량을 기준으로 1.5 내지 3.5 중량%로 포함되는 것일 수 있다. 다른 예시적인 일 구현예에서, 상기 캠퍼는 향료 조성물 전체 중량을 기준으로 1.5 중량% 이상, 1.6 중량% 이상, 1.7 중량% 이상, 1.8 중량% 이상, 1.9 중량% 이상, 2 중량% 이상, 2.1 중량% 이상, 2.2 중량% 이상, 2.3 중량% 이상, 2.4 중량% 이상 또는 2.5 중량% 이상으로 포함되고, 3.5 중량% 이하, 3.4 중량% 이하, 3.3 중량% 이하, 3.2 중량% 이하, 3.1 중량% 이하 또는 3.0 중량% 이하로 포함되는 것일 수 있다. 예컨대, 상기 캠퍼는 향료 조성물 전체 중량을 기준으로 1.5 내지 3.3 중량%, 2 내지 3 중량% 또는 2.5 내지 3 중량%로 포함되는 것이 바람직할 수 있다. 이에 따라, 상기 향료 조성물은 금새우난의 고유 향취를 재현하여 실제 금새우난과의 향취 유사성을 높이고 우수한 기호성을 제공하는 효과가 있다.In an exemplary embodiment, the camphor may be included in an amount of 1.5 to 3.5% by weight based on the total weight of the fragrance composition. In another exemplary embodiment, the camphor is present in an amount of at least 1.5% by weight, at least 1.6% by weight, at least 1.7% by weight, at least 1.8% by weight, at least 1.9% by weight, at least 2% by weight, and at least 2.1% by weight, based on the total weight of the fragrance composition. % or more, 2.2% by weight or more, 2.3% by weight or more, 2.4% by weight or more, or 2.5% by weight or more, and 3.5% by weight or less, 3.4% by weight or less, 3.3% by weight or less, 3.2% by weight or less, 3.1% by weight or less. Alternatively, it may be contained in an amount of 3.0% by weight or less. For example, the camphor may preferably be included in an amount of 1.5 to 3.3% by weight, 2 to 3% by weight, or 2.5 to 3% by weight based on the total weight of the fragrance composition. Accordingly, the flavor composition has the effect of reproducing the unique scent of golden shrimp orchids, increasing the similarity in scent with actual golden shrimp orchids, and providing excellent palatability.
예시적인 일 구현예에서, 상기 향료 조성물은 향취 성분 및 캠퍼를 85 내지 95 : 1.5 내지 3.5의 중량비로 포함하는 것일 수 있다. 바람직하게는, 상기 향료 조성물은 향취 성분 및 캠퍼를 88 내지 93 : 1.5 내지 3.5의 중량비 또는 90 내지 95 : 1.5 내지 3.5의 중량비로 포함하여 금새우난과의 향취 유사성 및 향취 기호성을 증가시키는 효과가 있다.In an exemplary embodiment, the fragrance composition may include fragrance ingredients and camphor at a weight ratio of 85 to 95:1.5 to 3.5. Preferably, the fragrance composition contains fragrance ingredients and camphor in a weight ratio of 88 to 93:1.5 to 3.5 or 90 to 95:1.5 to 3.5, so as to have the effect of increasing the fragrance similarity and fragrance palatability with Geumsaeuna orchid. there is.
다른 측면에서, 본 명세서에 개시된 기술은 상기 향료 조성물을 포함하는 피부 외용제 조성물을 제공한다.In another aspect, the technology disclosed herein provides a composition for external application to the skin containing the fragrance composition.
예시적인 일 구현예에서, 상기 피부 외용제는 피부 외부에서 도포되는 것이라면 어떠한 것이라도 포함될 수 있는 총칭으로서, 다양한 제형으로 제조될 수 있다. 예컨대, 상기 조성물은 연고, 에멀젼, 로션, 겔, 크림, 밤, 파우더, 페이스트, 스프레이, 현탁제, 유제, 패치제 등의 제형일 수 있으나, 이에 제한되는 것은 아니다.In an exemplary embodiment, the external skin agent is a general term that can include anything that is applied outside the skin, and can be prepared in various formulations. For example, the composition may be in the form of ointment, emulsion, lotion, gel, cream, balm, powder, paste, spray, suspension, emulsion, patch, etc., but is not limited thereto.
예시적인 일 구현예에서, 상기 피부 외용제 조성물은 화장료 조성물 또는 세정제 조성물인 것일 수 있다. 예컨대, 상기 피부 외용제 조성물은 화장품, 향수, 세정제 등으로 제형화될 수 있고, 당업계의 통상적인 기술에 따라 목적하는 효과를 이루기 위해 다른 성분들을 적절하게 선택하여 배합할 수 있다. 또한, 상기 향료 조성물의 배합량은 당업계의 통상적인 기술에 따라 목적하는 효과를 이루기 위해 적절하게 선택하여 배합할 수 있다.In an exemplary embodiment, the external skin composition may be a cosmetic composition or a cleanser composition. For example, the composition for external skin application can be formulated as a cosmetic, perfume, cleanser, etc., and other ingredients can be appropriately selected and mixed to achieve the desired effect according to conventional techniques in the art. In addition, the amount of the fragrance composition can be appropriately selected and mixed to achieve the desired effect according to common techniques in the art.
다른 측면에서, 본 명세서에 개시된 기술은 상기 향료 조성물을 포함하는 방향제 조성물을 제공한다.In another aspect, the technology disclosed herein provides a fragrance composition including the fragrance composition.
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것으로서, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되지 않는 것은 당업계에서 통상의 지식을 가진 자에게 있어서 자명할 것이다.Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not to be construed as limited by these examples.
시험예Test example 1. One. SPME법을SPME method 이용한 used 금새우난의Golden shrimp orchid 향취 성분 분석 Fragrance ingredient analysis
본 시험예에서는 SPME (Solid Phase Micro Extraction)법에 의해 금새우난의 향취 성분을 분석하였다. SPME법은 특별한 전처리 없이 화이버 (Fiber)에 흡착된 향취 성분들이 GS-MS 컬럼 안으로 빠르게 탈착, 주입될 수 있어 분석 시간이 크게 단축될 수 있으므로, 휘발성이 강한 금새우난의 향취 성분을 분석하는데 유리하다. 또한, SPME법은 기존의 전처리 방법에 비해 농축 방법이 간단하고 쉬우며 매트릭스의 형태에 구애받지 않고 유기용매를 사용하지 않기 때문에 시료의 오염 및 부산물의 발생률을 현저히 줄일 수 있어, 도출 결과에 대한 신빙성을 높일 수 있다는 장점이 있다.In this test example, the scent components of golden shrimp eggs were analyzed using the SPME (Solid Phase Micro Extraction) method. The SPME method is advantageous for analyzing the highly volatile scent components of golden shrimp orchids, as the analysis time can be greatly shortened as the scent components adsorbed on the fiber can be quickly desorbed and injected into the GS-MS column without any special pretreatment. do. In addition, the SPME method is simple and easy to concentrate compared to existing pretreatment methods, and because it is not limited by the type of matrix and does not use organic solvents, it can significantly reduce the incidence of sample contamination and by-products, increasing the reliability of the results. It has the advantage of being able to increase .
구체적으로, 향기가 강한 금새우난 (Calanthe sieboldii Decne. ex Regel)을 골라 화분을 채취한 후, 2시간 동안 85 ㎛의 폴리아크릴레이트로 코팅된 화이버 (Polyacrylate Fiber)에 향기 성분을 흡착시켜 향기 성분을 포집하였다. 3시간 동안 포집이 이루어졌다. 향취 성분을 포집한 후, 화이버 (Fiber)를 밀봉하고 이를 GC-MS의 주입구에 옮겨 꽂은 다음, 2분간 탈착시키고 GC-MS 분석을 수행하였다. GC-MS 분석 조건은 다음과 같다.Specifically, the pollen was collected from Calanthe sieboldii Decne. ex Regel, which has a strong scent, and then the scent ingredient was adsorbed on 85 ㎛ polyacrylate-coated fiber for 2 hours. was captured. Capture was carried out for 3 hours. After collecting the scent components, the fiber was sealed and transferred to the inlet of the GC-MS, then desorbed for 2 minutes and GC-MS analysis was performed. GC-MS analysis conditions are as follows.
GC-MS 분석 조건GC-MS analysis conditions
. 분석기기: HP 5890 II GC. Analytical instrument: HP 5890 II GC
. 검출기: HP 5972 MSD. Detector: HP 5972 MSD
. 컬럼 (Column): DB-1 (60m X 0.25mm X 0.25um). Column: DB-1 (60m
. 이동 기체 (Carrier Gas): He. Carrier Gas: He
. 주입부 온도 (Injection Temperature): 250 ℃. Injection Temperature: 250 ℃
. 검출부 온도 (Detector Temperature): 280 ℃. Detector Temperature: 280 ℃
. 오븐 온도 (Oven Temperature): 70 ℃ ~ 220 ℃ (3℃/min) . Oven Temperature: 70 ℃ ~ 220 ℃ (3℃/min)
. 이온화 전압 (Ionization Voltage): 70eV. Ionization Voltage: 70eV
. 탈착 시간: 2분. Desorption time: 2 minutes
SPME법에 의해 분석된 금새우난의 향취 성분은 표 1에 나타내었다.The odor components of golden shrimp eggs analyzed by SPME method are shown in Table 1.
상기 표 1에 나타난 바와 같이, 금새우난은 6(Z),9(E)-헵타데카디엔, 트랜스-네롤리돌, 베타-카리오필렌, 알파-피넨, 메틸 벤조에이트, 1,4-다이메톡시벤젠, 트랜스-알파-파네신 및 카르본을 주요 향취 성분으로 하고 있으며, 이들 주요 성분이 전체의 67.17 중량%를 차지하고 있음을 확인하였다.As shown in Table 1, golden shrimp eggs include 6(Z),9(E)-heptadecadiene, trans-nerolidol, beta-caryophyllene, alpha-pinene, methyl benzoate, and 1,4-dime. It was confirmed that oxybenzene, trans-alpha-farnesine, and carvone were the main fragrance ingredients, and that these main ingredients accounted for 67.17% by weight of the total.
시험예 2. 전문 평가단에 의한 향취 성분 분석Test Example 2. Analysis of fragrance components by professional evaluation team
상기 시험예 1에서 분석된 금새우난의 향취 성분들에 대하여 조향사로 구성된 전문 평가단을 대상으로 관능 평가를 수행하였다. Sensory evaluation was performed on the fragrance components of the golden shrimp orchids analyzed in Test Example 1 by a professional evaluation group consisting of perfumers.
그 결과, 금새우난의 향취 성분들 중 플로럴 (floral)한 향취를 만들어 내는 6(Z),9(E)-헵타데카디엔, 플로럴 그린 (floral green)한 향취를 만들어 내는 트랜스-네롤리돌, 우디 스파이시 (woody spicy)한 향취를 만들어 내는 베타-카리오필렌, 허벌 (herbal)한 향취를 만들어 내는 알파-피넨, 아로마틱 스윗 (aromatic sweet)한 향취를 만들어 내는 메틸 벤조에이트, 스윗 플로럴 (sweet floral)한 향취를 만들어 내는 1,4-다이메톡시벤젠, 우디 시트러스 (woody citrus)한 향취를 만들어 내는 트랜스-알파-파네신, 스윗 민티 (sweet minty)한 향취를 만들어 내는 카르본의 여덟 성분이 금새우난의 고유 향취를 만들어 내는 주요 성분임을 확인하였다.As a result, among the fragrance components of golden shrimp orchid, 6(Z),9(E)-heptadecadiene, which produces a floral fragrance, trans-nerolidol, which produces a floral green fragrance, Beta-caryophyllene, which creates a woody spicy scent, alpha-pinene, which creates a herbal scent, methyl benzoate, which creates an aromatic sweet scent, and sweet floral. The eight ingredients of 1,4-dimethoxybenzene, which creates a strong scent, trans-alpha-farnesin, which creates a woody citrus scent, and carvone, which creates a sweet minty scent, are gold. It was confirmed that it is the main ingredient that creates the unique flavor of shrimp naan.
시험예Test example 3. 향취 성분 함량 변화에 따른 향료 조성물의 관능 평가 비교 3. Comparison of sensory evaluation of fragrance compositions according to changes in fragrance ingredient content
상기 시험예 2의 분석을 토대로, 여덟 성분의 주요 향취 성분을 포함하여 금새우난의 향취를 그대로 나타내면서 기호성이 좋은 향료를 제조하기 위해서 하기 표 2에 나타난 바와 같이 #1 내지 #4의 향료 조성물을 제조하였다. 향료 조성물 #1 내지 #4는 이들 여덟 가지 주요 향취 성분의 총 함량을 80~95 중량%로 변화시켜 제조하였다 (단위: 중량%). Based on the analysis of Test Example 2, in order to produce a fragrance with good palatability while retaining the fragrance of golden shrimp orchids including the eight main fragrance components, the fragrance compositions #1 to #4 were used as shown in Table 2 below. Manufactured. Fragrance compositions #1 to #4 were prepared by varying the total content of these eight major fragrance ingredients to 80 to 95% by weight (unit: weight%).
상기 제조한 #1 내지 #4의 향료 조성물에 대해 천연 금새우난 고유 향취와의 유사성 및 향취의 기호성을 후각 관능 검사를 통해 평가하였다.The fragrance compositions #1 to #4 prepared above were evaluated through an olfactory sensory test for similarity to the unique fragrance of natural golden shrimp orchids and palatability of the fragrance.
관능 검사는 20~45세의 일반 남녀 20명을 대상으로 하였으며, 상기 시험예 1에서 천연 금새우난 화분으로부터 직접 포집된 향취 (샘플 A)와, 시험 대상 향료 조성물의 향취 (샘플 B)를 각각 맡아보도록 하고, 하기 표 3의 설문지에 응답하도록 함으로써, 샘플 A와 샘플 B의 향취 유사성 (질문 1) 및 향취 기호성 (질문 2)을 조사하였다. 그 결과는 하기 표 4에 나타내었다. 한편, 두 개의 향료 조성물에 대한 비교 관능 평가를 실시한 후, 5분 동안의 휴식 시간을 주어 후감각 마비 현상이 없도록 하였다.The sensory test was conducted on 20 men and women aged 20 to 45 years. In Test Example 1, the scent collected directly from the natural golden shrimp orchid pollen (sample A) and the scent of the fragrance composition to be tested (sample B) were tested, respectively. The scent similarity (Question 1) and scent preference (Question 2) between Sample A and Sample B were investigated by having them smell it and answer the questionnaire in Table 3 below. The results are shown in Table 4 below. Meanwhile, after conducting a comparative sensory evaluation of the two fragrance compositions, a 5-minute break was given to prevent olfactory paralysis.
(1) 질문 1: 샘플 A와 샘플 B의 향취가 얼마나 유사(비슷)한가?
1) 전혀 유사하지 않다.
2) 별로 유사하지 않다.
3) 그저 그렇다.
4) 어느 정도 유사하다.
5) 매우 유사하다.
(2) 질문 2: 샘플 B의 향취를 얼마나 좋아하는가?
1) 전혀 좋지 않다.
2) 별로 좋지 않다.
3) 그저 그렇다.
4) 약간 좋다.
5) 매우 좋다. survey
(1) Question 1: How similar are the scents of Sample A and Sample B?
1) They are not similar at all.
2) Not very similar.
3) That's just the way it is.
4) Somewhat similar.
5) Very similar.
(2) Question 2: How much do you like the scent of sample B?
1) Not good at all.
2) Not very good.
3) That's just the way it is.
4) Somewhat good.
5) Very good.
표 4에서 보는 바와 같이, 금새우난 향취 성분 중 주요 여덟 성분의 총 함량이 향료 조성물의 90 중량%를 차지하는 #3이 4개의 향료 조성물 중 가장 뛰어난 유사성과 기호성을 갖는 것으로 나타났다. As shown in Table 4, #3, which accounts for 90% by weight of the fragrance composition with a total content of eight major ingredients among the fragrant ingredients, was found to have the best similarity and palatability among the four fragrance compositions.
시험예 4. 인공 합성 물질 첨가에 따른 향료 조성물의 관능 평가 비교Test Example 4. Comparison of sensory evaluation of fragrance compositions according to the addition of artificial synthetic substances
상기 시험예 3에서 금새우난의 고유 향취와 가장 유사한 것으로 나타난 향료 조성물 #3의 유사성 및 기호성을 개선하기 위해서, 하기 표 5에 나타난 바와 같이, 주요 향취 성분으로 6(Z),9(E)-헵타데카디엔, 트랜스-네롤리돌, 베타-카리오필렌, 알파-피넨, 메틸 벤조에이트, 1,4-다이메톡시벤젠, 트랜스-알파-파네신 및 카르본을 90 중량%의 함량으로 유지하고 (표 3의 #3과 동일), 여기에 인공 합성 물질인 캠퍼를 더 첨가하여 #5 내지 #11의 향료 조성물을 제조하였다 (단위: 중량%). 이때, 캠퍼를 0.5 중량%, 1.0 중량%, 1.5 중량%, 2.0 중량%, 2.5 중량%, 3.0 중량%, 3.5 중량%의 함량으로 변화시켜 가면서 첨가하였고, 그 외 성분들은 캠퍼의 함량 변화에 따라 총 함량 100 중량%를 맞추기 위해 조절하였다.In order to improve the similarity and palatability of fragrance composition #3, which was shown to be most similar to the unique fragrance of golden shrimp orchid in Test Example 3, 6(Z) and 9(E) were used as the main fragrance ingredients, as shown in Table 5 below. -Heptadecadiene, trans-nerolidol, beta-caryophyllene, alpha-pinene, methyl benzoate, 1,4-dimethoxybenzene, trans-alpha-farnesine and carvone are maintained at a content of 90% by weight; (Same as #3 in Table 3), and camphor, an artificial synthetic substance, was further added to prepare fragrance compositions #5 to #11 (unit: weight%). At this time, camphor was added in varying amounts of 0.5 wt%, 1.0 wt%, 1.5 wt%, 2.0 wt%, 2.5 wt%, 3.0 wt%, and 3.5 wt%, and other ingredients were added according to the change in camphor content. It was adjusted to achieve a total content of 100% by weight.
상기 #5 내지 #11의 향료 조성물에 대해 상기 시험예 3과 동일한 방법으로 천연 금새우난 고유 향취와의 유사성 및 향취의 기호성을 후각 관능 검사를 통해 평가하여 하기 표 6에 나타내었다.The fragrance compositions #5 to #11 were evaluated through an olfactory sensory test for similarity to the unique fragrance of natural golden shrimp orchids and palatability of the fragrance in the same manner as in Test Example 3, and are shown in Table 6 below.
상기 표 6에 나타난 바와 같이, 금새우난의 주요 향취 성분에 캠퍼를 1.5 내지 3.0 중량%의 범위로 함유하는 #7, #8, #9, #10의 경우에는 향취 유사성 및 기호성이 높은 것을 확인할 수 있었다. 특히, 캠퍼를 2.0 내지 3.0 중량%의 범위로 함유하는 #8, #9, #10의 경우에는 금새우난과의 향취 유사성 및 향취 기호성이 매우 우수하여 금새우난의 향취를 잘 재현할 수 있음을 확인할 수 있었다. 아울러, 캠퍼를 1 중량% 이하 또는 3.5 중량%를 초과하여 함유하면 오히려 향취의 유사성 및 기호성이 낮아짐을 알 수 있었다.As shown in Table 6 above, in the case of #7, #8, #9, and #10, which contain camphor in the range of 1.5 to 3.0% by weight as the main scent component of Geumsaeunnan, it was confirmed that the scent similarity and palatability were high. I was able to. In particular, in the case of #8, #9, and #10, which contain camphor in the range of 2.0 to 3.0% by weight, the scent similarity and flavor preference with golden shrimp orchids are very excellent, and the scent of golden shrimp eggs can be well reproduced. was able to confirm. In addition, it was found that if camphor was contained in an amount of 1% by weight or less or more than 3.5% by weight, the similarity of fragrance and palatability were lowered.
이에 따라, 상기 시험예 1에서 분석된 금새우난의 향취 성분만으로는 금새우난의 향취를 재현하는 데에 한계가 있었으나, 금새우난의 향취 성분에 캠퍼를 첨가하여 함께 사용하는 경우 금새우난의 고유 향취를 재현하고 더욱 우수한 기호성을 제공할 수 있음을 확인하였다.Accordingly, there was a limit to reproducing the scent of golden shrimp eggs using only the scent components of golden shrimp eggs analyzed in Test Example 1, but when camphor was added to the scent components of golden shrimp eggs and used together, the scent of golden shrimp eggs was increased. It was confirmed that it can reproduce the unique scent and provide better palatability.
또한, 캠퍼 이외 다른 인공 합성 물질을 첨가하여 향료 조성물을 제조하여 첨가 물질의 종류에 따른 향취 유사성 및 기호성을 비교 평가하였다. 첨가 물질로 하이드록시시트로넬랄 (hydroxycitronellal) 또는 노나날 (nonanal)을 사용하여 표 7의 조성 (중량%)에 따라 #12 및 #13의 향료 조성물을 제조하였으며, 이의 천연 금새우난 고유 향취와의 유사성 및 향취의 기호성을 후각 관능 검사를 통해 평가하였다. 상기 시험예 3과 동일한 방법으로 평가하였으며, 그 결과는 하기 표 8에 나타내었다.In addition, a fragrance composition was prepared by adding artificial synthetic substances other than camphor, and the similarity and palatability of the fragrance according to the type of added substance was compared and evaluated. Fragrance compositions #12 and #13 were prepared according to the composition (% by weight) in Table 7 using hydroxycitronellal or nonanal as an additive, and their natural golden shrimp orchid unique fragrance and The similarity and palatability of fragrances were evaluated through olfactory sensory tests. Evaluation was performed in the same manner as in Test Example 3, and the results are shown in Table 8 below.
상기 표 8에 나타난 바와 같이, 인공 합성 물질로서 캠퍼가 아닌 다른 물질을 3.0 중량%로 함유하는 경우, 향취 유사성 및 기호성이 캠퍼를 함유하는 향료 조성물 대비 현저하게 낮아짐을 알 수 있었다. 이로부터 금새우난의 향취를 재현하면서 기호성을 극대화시킬 수 있는 인공 합성 물질로 캠퍼가 가장 적합함을 알 수 있었다.As shown in Table 8, when an artificial synthetic material other than camphor was contained at 3.0% by weight, it was found that the scent similarity and palatability were significantly lowered compared to the fragrance composition containing camphor. From this, it was found that camphor is the most suitable artificial synthetic material that can reproduce the scent of golden shrimp orchid while maximizing palatability.
시험예 5. 주요 향취 성분 및 인공 합성 물질로만 이루어진 향료 조성물의 관능 평가Test Example 5. Sensory evaluation of a fragrance composition consisting only of major fragrance ingredients and artificial synthetic substances
상기 시험예 4에서 금새우난과의 향취 유사성 및 기호성이 높았던 #8, #9 및 #10의 향료 조성물에서, 부차적인 향취 성분들을 제외하고 주요 향취 성분과 캠퍼로만 이루어진 향료 조성물을 제조하여 향취 유사성 및 기호성을 후각 관능 검사를 통해 평가하였다. 인공 합성 물질인 캠퍼의 함량을 달리하여 하기 표 9의 조성 (중량%)에 따라 #13 내지 #16의 향료 조성물을 제조하였으며, 상기 시험예 3과 동일한 방법으로 천연 금새우난 고유 향취와의 유사성 및 향취의 기호성을 평가하였다.In the fragrance compositions #8, #9, and #10, which had high scent similarity and preference with golden shrimp orchid in Test Example 4, a fragrance composition consisting of only the main fragrance ingredients and camphor was prepared, excluding secondary fragrance ingredients, to obtain fragrance similarity. and palatability were evaluated through olfactory sensory tests. Fragrance compositions #13 to #16 were prepared according to the composition (% by weight) in Table 9 below by varying the content of camphor, an artificial synthetic substance, and similar to the unique scent of natural golden shrimp eggs in the same manner as Test Example 3. and the palatability of the fragrance was evaluated.
그 결과, 천연 금새우난 고유 향취와의 유사성이 #13은 평균 3.6, #14는 평균 3.7, #15는 평균 3.7, #16은 평균 3.8, 기호성이 #13은 평균 3.75, #14는 평균 3.8, #15는 평균 3.8, #16은 평균 3.85인 것으로 나타나, 부차적인 향취 성분이 제외되더라도 주요 향취 성분과 캠퍼 성분에 의해 금새우난과의 향취 유사성 및 기호성이 높게 유지될 수 있음을 확인할 수 있었다.As a result, similarity to the unique scent of natural golden shrimp naan was 3.6 on average for #13, 3.7 on average for #14, 3.7 on average for #15, 3.8 on average for #16, and 3.75 on average for #13 and 3.8 on average for #14. , #15 showed an average of 3.8, and #16 had an average of 3.85. It was confirmed that even if the secondary fragrance components are excluded, the similarity in flavor and palatability with Geumsaeunanan can be maintained high by the main flavor components and camphor components. .
시험예 6. 6(Z),9(E)-헵타데카디엔 함량 변화에 따른 향료 조성물의 관능 평가 비교Test Example 6. Comparison of sensory evaluation of fragrance compositions according to changes in 6(Z),9(E)-heptadecadiene content
금새우난의 주요 향취 성분과 캠퍼 성분을 포함하는 향료 조성물에서, 6(Z),9(E)-헵타데카디엔의 함량을 달리하여 하기 표 10의 조성 (중량%)에 따라 #17 내지 #21의 향료 조성물을 제조한 다음, 향취 유사성 및 기호성을 후각 관능 검사를 통해 평가하였다. 상기 시험예 3과 동일한 방법으로 천연 금새우난 고유 향취와의 유사성 및 향취의 기호성을 평가하였다.In a fragrance composition containing the main fragrance component and camphor component of golden shrimp orchid, the content of 6(Z),9(E)-heptadecadiene is varied to #17 to # according to the composition (% by weight) in Table 10 below. After preparing the fragrance composition of 21, the scent similarity and palatability were evaluated through an olfactory sensory test. The similarity with the unique scent of natural golden shrimp orchids and the palatability of the scent were evaluated in the same manner as Test Example 3 above.
그 결과, 천연 금새우난 고유 향취와의 유사성이 #17은 평균 2.7, #18은 평균 2.8, #19는 평균 3.8, #20은 평균 3.7, #21은 평균 2.9, 기호성이 #17은 평균 2.7, #18은 평균 2.7, #19은 평균 3.8, #20은 평균 3.7, #21은 평균 2.7인 것으로 나타나, 6(Z),9(E)-헵타데카디엔의 함량이 22 내지 28 중량%인 것이 금새우난과의 향취 유사성 및 기호성 면에서 바람직함을 확인하였고, 6(Z),9(E)-헵타데카디엔의 함량이 낮거나 높아지면 금새우난과의 향취 유사성 및 기호성이 현저하게 낮아짐을 확인할 수 있었다.As a result, the similarity with the unique scent of natural golden shrimp was 2.7 on average for #17, 2.8 on average for #18, 3.8 on average for #19, 3.7 on average for #20, 2.9 on average for #21, and 2.7 on average for #17. , #18 was found to be an average of 2.7, #19 was an average of 3.8, #20 was an average of 3.7, and #21 was an average of 2.7, with a content of 6(Z),9(E)-heptadecadiene of 22 to 28% by weight. It was confirmed that this is preferable in terms of flavor similarity and palatability with golden shrimp orchids, and when the content of 6(Z),9(E)-heptadecadiene is low or high, the flavor similarity and palatability with golden shrimp orchids significantly decreases. It was confirmed that it was lowered.
본 명세서의 일 측면에 따른 조성물의 제형예를 아래에서 설명하나, 다른 여러 가지 제형으로도 응용 가능하며, 이는 본 발명을 한정하고자 함이 아닌 단지 구체적으로 설명하고자 함이다.A formulation example of the composition according to one aspect of the present specification is described below, but it can be applied to various other formulations, and this is not intended to limit the present invention, but is only intended to provide a detailed description.
제형예Formulation example 1. 향수 1. Perfume
상기 #10의 향료 조성물 15 중량%를 통상의 방법에 따라 알코올 81 중량%, 물 2 중량%, 색소 적량 및 자외선 차단제 적량과 배합하여 금새우난의 향취를 재현한 향료 조성물을 포함하는 향수를 제조하였다.15% by weight of the fragrance composition of #10 is mixed with 81% by weight of alcohol, 2% by weight of water, an appropriate amount of pigment, and an appropriate amount of sunscreen according to a conventional method to prepare a perfume containing a fragrance composition that reproduces the scent of golden shrimp orchids. did.
이상, 본 발명 내용의 특정한 부분을 상세히 기술하였는바, 당업계의 통상의 지식을 가진 자에게 있어서, 이러한 구체적인 기술은 단지 바람직한 실시 태양일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의해 정의된다고 할 것이다.As above, specific parts of the present invention have been described in detail, and for those skilled in the art, it is clear that these specific techniques are merely preferred embodiments and do not limit the scope of the present invention. It will be obvious. Accordingly, the actual scope of the present invention will be defined by the appended claims and their equivalents.
Claims (10)
상기 향취 성분은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene), 트랜스-네롤리돌 (trans-nerolidol), 베타-카리오필렌 (β-caryophyllene), 알파-피넨 (α-pinene), 메틸 벤조에이트 (methyl benzoate), 1,4-다이메톡시벤젠 (1,4-dimethoxybenzene), 트랜스-알파-파네신 (trans-α-farnesene) 및 카르본 (carvone)을 포함하고,
상기 향취 성분은 향료 조성물 전체 중량을 기준으로 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene)을 22 내지 28 중량%로 포함하고,
상기 향취 성분 및 캠퍼 (camphor)는 항료 조성물 전체 중량을 기준으로 85 내지 95 중량% 및 1.5 내지 3.5 중량%로 포함되는 금새우난의 향취를 재현한 향료 조성물.
Contains fragrant components of golden shrimp orchid and camphor as active ingredients,
The fragrance ingredients include 6(Z),9(E)-heptadecadiene, trans-nerolidol, and beta-caryophyllene. , alpha-pinene, methyl benzoate, 1,4-dimethoxybenzene, trans-α-farnesene and carvone. Contains (carvone),
The fragrance ingredient includes 22 to 28% by weight of 6(Z),9(E)-heptadecadiene (6(Z),9(E)-heptadecadiene) based on the total weight of the fragrance composition,
A fragrance composition that reproduces the fragrance of golden shrimp orchids, wherein the fragrance ingredient and camphor are contained in an amount of 85 to 95% by weight and 1.5 to 3.5% by weight based on the total weight of the fragrance composition.
상기 향취 성분은 향료 조성물 전체 중량을 기준으로 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene)을 22 내지 25 중량%로 포함하는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
The fragrance ingredient contains 22 to 25% by weight of 6(Z),9(E)-heptadecadiene (6(Z),9(E)-heptadecadiene) based on the total weight of the fragrance composition. A fragrance composition that reproduces the scent of shrimp naan.
상기 향취 성분은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene) 22 내지 28 중량부에 대하여, 트랜스-네롤리돌 (trans-nerolidol) 14 내지 20 중량부, 베타-카리오필렌 (β-caryophyllene) 9 내지 15 중량부, 알파-피넨 (α-pinene) 7 내지 13 중량부, 메틸 벤조에이트 (methyl benzoate) 6 내지 10 중량부, 1,4-다이메톡시벤젠 (1,4-dimethoxybenzene) 4 내지 8 중량부, 트랜스-알파-파네신 (trans-α-farnesene) 4 내지 6 중량부 및 카르본 (carvone) 4 내지 6 중량부를 포함하는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
The fragrance ingredient is 14 to 20 parts by weight of trans-nerolidol, based on 22 to 28 parts by weight of 6(Z),9(E)-heptadecadiene. Parts by weight, beta-caryophyllene (β-caryophyllene) 9 to 15 parts by weight, alpha-pinene (α-pinene) 7 to 13 parts by weight, methyl benzoate (methyl benzoate) 6 to 10 parts by weight, 1,4-di Containing 4 to 8 parts by weight of methoxybenzene (1,4-dimethoxybenzene), 4 to 6 parts by weight of trans-α-farnesene, and 4 to 6 parts by weight of carvone, A fragrance composition that reproduces the scent of golden shrimp orchid.
상기 캠퍼 (camphor)는 향료 조성물 전체 중량을 기준으로 2 내지 3 중량%로 포함되는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
A fragrance composition that reproduces the scent of golden shrimp orchids, wherein the camphor is contained in an amount of 2 to 3% by weight based on the total weight of the fragrance composition.
상기 향취 성분 및 캠퍼 (camphor)는 항료 조성물 전체 중량을 기준으로 90 내지 95 중량% 및 2 내지 3 중량%로 포함되는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
A fragrance composition that reproduces the fragrance of golden shrimp orchids, wherein the fragrance ingredient and camphor are contained in an amount of 90 to 95% by weight and 2 to 3% by weight based on the total weight of the fragrance composition.
상기 향료 조성물은 메틸 살리실레이트 (methyl salicylate), 리날룰 (linalool), 알파-피넨 에폭사이드 (α-pinene epoxide), 메틸 헥사데카노에이트 (methyl hexadecanoate), 3-하이드록시-4-페닐-2-부타논 (3-hydroxy-4-phenyl-2-butanone), 벤즈알데하이드 (benzaldehyde) 및 2-페닐에틸 알콜 (2-phenylethyl alcohol)로 이루어진 군에서 선택되는 1 이상을 더 포함하는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
The fragrance composition includes methyl salicylate, linalool, alpha-pinene epoxide, methyl hexadecanoate, 3-hydroxy-4-phenyl- It further contains at least one selected from the group consisting of 2-butanone (3-hydroxy-4-phenyl-2-butanone), benzaldehyde and 2-phenylethyl alcohol, A fragrance composition that reproduces the scent of golden shrimp orchid.
상기 향료 조성물은 6(Z),9(E)-헵타데카디엔 (6(Z),9(E)-heptadecadiene) 22 내지 28 중량부에 대하여, 1 내지 2 중량부의 메틸 살리실레이트 (methyl salicylate), 1 내지 1.5 중량부의 리날룰 (linalool), 1 내지 1.5 중량부의 알파-피넨 에폭사이드 (α-pinene epoxide), 0.8 내지 1.3 중량부의 메틸 헥사데카노에이트 (methyl hexadecanoate), 0.8 내지 1.2 중량부의 3-하이드록시-4-페닐-2-부타논 (3-hydroxy-4-phenyl-2-butanone), 0.7 내지 1 중량부의 벤즈알데하이드 (benzaldehyde) 및 0.5 내지 0.7 중량부의 2-페닐에틸 알콜 (2-phenylethyl alcohol)로 이루어진 군에서 선택되는 1 이상을 더 포함하는 것인, 금새우난의 향취를 재현한 향료 조성물.
According to clause 1,
The fragrance composition contains 1 to 2 parts by weight of methyl salicylate based on 22 to 28 parts by weight of 6(Z),9(E)-heptadecadiene. ), 1 to 1.5 parts by weight of linalool, 1 to 1.5 parts by weight of alpha-pinene epoxide, 0.8 to 1.3 parts by weight of methyl hexadecanoate, 0.8 to 1.2 parts by weight 3-hydroxy-4-phenyl-2-butanone, 0.7 to 1 part by weight of benzaldehyde and 0.5 to 0.7 parts by weight of 2-phenylethyl alcohol (2 A fragrance composition that reproduces the scent of golden shrimp orchids, further comprising one or more selected from the group consisting of -phenylethyl alcohol).
A composition for external application to the skin comprising the fragrance composition of any one of claims 1, 3 to 8.
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