KR102394530B1 - Perfume composition for expressing the fragrance of Osmanthus insularis Koidz. - Google Patents

Perfume composition for expressing the fragrance of Osmanthus insularis Koidz. Download PDF

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KR102394530B1
KR102394530B1 KR1020150029547A KR20150029547A KR102394530B1 KR 102394530 B1 KR102394530 B1 KR 102394530B1 KR 1020150029547 A KR1020150029547 A KR 1020150029547A KR 20150029547 A KR20150029547 A KR 20150029547A KR 102394530 B1 KR102394530 B1 KR 102394530B1
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임소연
고승호
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(주)아모레퍼시픽
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • A61K36/63Oleaceae (Olive family), e.g. jasmine, lilac or ash tree

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Abstract

고상 마이크로 추출법(Solid Phase Micro Extraction, SPME법)에 의해 분석된 박달목서꽃의 향취성분과 달콤한 향취를 가지는 인공 합성물질인 메틸자스모네이트(Methyl jasmonate)를 유효성분으로 함유함으로써 박달목서꽃(Osmanthus insularis Koidz.)의 고유 향취를 재현하면서 뛰어난 기호성을 갖는 향료 조성물에 관한 것이다.Osmanthus insularis Koidz ( Osmanthus insularis Koidz), which contains methyl jasmonate, an artificial synthetic material having a sweet smell and the fragrance component analyzed by Solid Phase Micro Extraction (SPME method) as an active ingredient .) It relates to a perfume composition having excellent palatability while reproducing the unique scent of the .

Description

박달목서꽃의 향취를 재현한 향료 조성물{Perfume composition for expressing the fragrance of Osmanthus insularis Koidz.}Perfume composition for expressing the fragrance of Osmanthus insularis Koidz.

본 발명은 박달목서꽃(Osmanthus insularis Koidz.)의 향취를 재현한 향료 조성물에 관한 것이다.The present invention relates to a perfume composition that reproduces the scent of Osmanthus insularis Koidz.

박달목서는 제주도와 거문도에 분포하며 우리나라의 남해안 지방은 박달목서의 북쪽 한계선에 해당된다. 야생동식물보호법에 따라 멸종위기야생식물 Ⅱ급으로 지정되어 관리되고 있다. 박달목서는 상록교목으로서 털이 없고 가지는 회색이며 잔가지가 다소 편평하다. 키는 15m까지 자란다. 잎은 마주나고 넓은 타원모양 또는 계란형의 넓은 타원모양이며 끝이 뾰족하다. 잎의 길이는 7~15㎝, 너비 2~3㎝로서 가장자리가 밋밋하지만 어린 나무에는 끝이 뾰족한 톱니가 다소 있고 잎자루는 길이 1.5~2.5㎝이다. 꽃은 11~12월에 피며 백색이고 잎겨드랑이에서 속생하며, 소화경은 길이 7~10㎜이고 꽃받침잎은 3각형이며 톱니가 약간 있다. 열매는 타원모양이고 길이 15~20㎜로서 다음해 5월에 검게 익는다. Bakdalmokseo is distributed in Jeju-do and Geomundo, and the southern coast of Korea is the northern limit of Bakdalmokseo. According to the Wildlife Protection Act, it is designated and managed as an endangered wild plant class II. Bacchus is an evergreen arboreous tree without hairs, and its branches are gray, and its twigs are rather flat. It grows up to 15 m tall. The leaves are opposite, broad oval or oval, broad oval, and pointed at the tip. The length of the leaf is 7~15cm, the width is 2~3cm, the edge is flat, but young trees have some sharp saw teeth and the petiole is 1.5~2.5cm long. Flowers bloom in November~December, white, grow in the leaf axil, pedicel is 7~10㎜ long, sepals are triangular, and there are some saw teeth. Fruits are oval-shaped, 15-20 mm long, and ripen black in May of the following year.

목서는 향기 좋은 꽃을 피운다 하여 일반인들에게 널리 알려진 식물인데 반해 박달목서는 우리나라에 자생하고 있는 식물임에도 불구하고 향에 대한 인식과 과학적 연구가 미흡한 실정이다. 이에 따뜻하고 풍부한 박달목서꽃의 향기가 한국의 자연을 대표하는 향이 될 수 있다는 생각에 박달목서꽃의 향취에 관한 연구를 수행하였다.Moxa is a plant widely known to the general public because it produces fragrant flowers, whereas Bakdalmokseo is a plant that grows wild in Korea, but awareness of fragrance and scientific research are insufficient. Therefore, a study was conducted on the fragrance of Bakdalmokseo, thinking that the warm and rich scent of Bakdalmokseo flower could be a representative scent of Korea’s nature.

인터넷 블로그 http://blog.naver.com/dudfhr7878/120176770505Internet blog http://blog.naver.com/dudfhr7878/120176770505

이에, 본 발명자들은 살아있는 천연물의 향취물질을 분석하는데 효과적인 SPME법 (고상 마이크로 추출법(Solid Phase Micro Extraction)을 이용하여, 박달목서꽃의 향취를 재현하고자 하였다. 그러나 향취의 주성분만으로는 박달목서꽃의 향취를 재현할 수 없지만, 여기에 자스모네이트 (Methyl jasmonate)을 함께 사용하게 되면 한국적 박달목서꽃의 고유 향취를 재현할 수 있으며, 뛰어난 기호성을 나타냄을 발견하여 본 발명을 완성하게 되었다.Therefore, the present inventors tried to reproduce the scent of Baklava flowers by using the SPME method (Solid Phase Micro Extraction), which is effective in analyzing the scent substances of living natural products. However, when jasmonate (Methyl jasmonate) is used together, it is possible to reproduce the unique scent of the Korean Bakdal Moxae flower, and it was found that it exhibits excellent palatability, thereby completing the present invention.

따라서, 본 발명의 목적은 박달목서꽃의 고유 향취를 재현할 수 있고, 우수한 기호성을 갖는 향료 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a perfume composition that can reproduce the unique scent of Bakdal Moxa flower and has excellent palatability.

또한, 본 발명의 다른 목적은 상기 향료 조성물을 함유하는 피부 외용제를 제공하는 것이다.Another object of the present invention is to provide an external preparation for skin containing the fragrance composition.

상기한 목적을 달성하기 위하여, 본 발명은 박달목서꽃의 향취성분 및 메틸자스모네이트 (Methyl jasmonate)을 유효성분으로 함유하여 박달목서꽃의 향취를 재현한 향료 조성물을 제공한다. In order to achieve the above object, the present invention provides a perfume composition that reproduces the scent of B. dandelion flower by containing the perfume ingredient and methyl jasmonate (Methyl jasmonate) as active ingredients.

또한, 본 발명은 상기 박달목서꽃의 향취를 재현한 향료 조성물을 함유하는 피부외용제 조성물을 제공한다.In addition, the present invention provides a composition for external application to the skin containing a fragrance composition that reproduces the fragrance of the Bakdal Mokseo flower.

본 발명에 따른 향료 조성물은 박달목서꽃 향취를 재현하기 위한 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸1,5,7-옥타트리엔-3-올, 2-페닐알코올의 박달목서꽃 향취의 주요성분에 메틸자스모네이트를 더 함유함으로써, 박달목서꽃의 향취를 재현할 수 있고, 향취의 기호성도 개선할 수 있다.The perfume composition according to the present invention contains linalool oxide, linalool, anisaldehyde, 3,7-dimethyl 1,5,7-octatrien-3-ol, and 2-phenyl alcohol for reproducing the scent of rhododendron flowers. By further containing methyl jasmonate in the main component of the scent, the scent of Bakdal Moxa flower can be reproduced, and the palatability of the scent can be improved.

본 발명은 박달목서꽃의 향취 성분 및 메틸자스모네이트(Methyl jasmonate)를 필수성분으로서 함유하여 박달목서꽃의 향취를 재현한 향료 조성물을 제공한다The present invention provides a perfume composition that reproduces the scent of B. dandelion flower by containing the perfume component and methyl jasmonate as essential components.

이하, 본 발명을 더욱 구체적으로 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명에 따른 조성물은 박달목서꽃의 향취 성분에, 인공합성물질로서 메틸자스모네이트(Methyl jasmonate)를 필수성분으로 함유함으로써, 박달목서꽃의 고유향취를 재현할 수 있으며, 우수한 기호성을 나타낼 수 있다.The composition according to the present invention contains methyl jasmonate (Methyl jasmonate) as an artificial synthetic material as an essential component in the fragrance component of B. sagebrush, thereby reproducing the unique scent of B. magnolia flower and exhibiting excellent palatability.

본 발명의 일 실시상태에 있어서, 상기 박달목서꽃의 향취 성분은, 리날룰옥사이드(Linalool oxide), 리날룰(Linalool), 아니스 알데하이드(Anisaldehyde), 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol) 및 2-페닐에틸알코올(2-Phenylethyl alcohol)에서 선택되는 어느 하나 이상이다.In an exemplary embodiment of the present invention, the fragrance component of Bakdalmokseo flower is linalool oxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octane It is at least one selected from trien-3-ol (3,7-dimethyl-1,5,7-octatrien-3-ol) and 2-phenylethyl alcohol (2-Phenylethyl alcohol).

본 발명의 일 실시상태에 있어서, 상기 박달목서꽃의 향취 성분은, 리날룰옥사이드(Linalool oxide), 리날룰(Linalool), 아니스 알데하이드(Anisaldehyde), 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol) 및 2-페닐에틸알코올(2-Phenylethyl alcohol)이다.In an exemplary embodiment of the present invention, the fragrance component of Bakdalmokseo flower is linalool oxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octane trien-3-ol (3,7-dimethyl-1,5,7-octatrien-3-ol) and 2-phenylethyl alcohol (2-Phenylethyl alcohol).

본 발명의 일 실시상태에 있어서, 상기 향료 조성물은 리날룰옥사이드(Linalool oxide), 리날룰(Linalool), 아니스 알데하이드(Anisaldehyde), 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol) 및 2-페닐에틸알코올(2-Phenylethyl alcohol)의 함량의 합은 80~95중량%, 바람직하게는 90.1 중량%이다.In one embodiment of the present invention, the perfume composition is linalool oxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octatriene-3 The sum of the content of -ol (3,7-dimethyl-1,5,7-octatrien-3-ol) and 2-phenylethyl alcohol (2-Phenylethyl alcohol) is 80 to 95 wt%, preferably 90.1 wt% am.

본 발명의 일 실시상태에 있어서, 상기 향료 조성물은 노나날(Nonanal), 오시멘(Ocimene), 라일락 알코올(Lilac alcohol), 리모넨(Limonene), 제라니올(Geraniol), δ-데카락톤(δ-decalactone) 및 자스민 락톤(Jasmin lactone) 에서 선택되는 어느 하나 이상을 더 함유한다.In one embodiment of the present invention, the perfume composition is nonanal (Nonanal), ocimene (Ocimene), lilac alcohol (Lilac alcohol), limonene (Limonene), geraniol (Geraniol), δ-decalactone (δ) -decalactone) and jasmine lactone (Jasmin lactone) further contains any one or more selected from.

또한, 본 발명의 향료 조성물은 박달목서꽃의 고유 향취를 재현하여 박달목서꽃과의 향취 유사성을 높이고 우수한 기호성을 나타낼 수 있도록 하기 위하여, 상기 박달목서꽃의 향취 성분에 인공 합성물질로서 플로랄 허베이셔스 향(Floral herbaceous)을 가지는 메틸자스모네이트를 필수성분으로 사용한다.In addition, the perfume composition of the present invention reproduces the unique scent of Baklava flower to increase the similarity of smell with B. Baklava flower and to show excellent palatability. Methyl jasmonate with herbaceous) is used as an essential ingredient.

본 발명의 일 실시상태에 있어서, 상기 향료 조성물은 메틸자스모네이트를 조성물 총 중량에 대하여 1.5~3.0 중량%, 바람직하게는 2.0~3.0 중량%의 범위로 함유한다.In one embodiment of the present invention, the perfume composition contains methyl jasmonate in an amount of 1.5 to 3.0 wt%, preferably 2.0 to 3.0 wt%, based on the total weight of the composition.

본 발명의 일 실시상태에 있어서, 상기 향료 조성물은 조성물 총 중량에 대하여, 리날룰옥사이드(Linalool oxide)를 47.6~54.4 중량%, 바람직하게는 48.4~54.4 중량%, 더 바람직하게는 49.4~51.4 중량%, 리날룰(Linalool)을 20.1~23.3 중량%, 바람직하게는 20.3~23.3 중량%, 더 바람직하게는 20.3~22.3 중량%, 아니스알데하이드(Anisaldehyde)를 10.3~12.0 중량%, 바람직하게는 10.5~12.0 중량%, 더 바람직하게는 10.7~11.1 중량%, 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol)을 4~4.6 중량%, 바람직하게는 4.1~4.6 중량%, 더 바람직하게는 4.2~4.4 중량%, 2-페닐에틸알코올(2-Phenylethyl alcohol)을 3~3.4 중량%, 바람직하게는 3.1~3.4 중량%, 더 바람직하게는 3.15~3.25 중량%의 범위로 함유한다.In an exemplary embodiment of the present invention, the perfume composition contains 47.6 to 54.4% by weight of linalool oxide, preferably 48.4 to 54.4% by weight, more preferably 49.4 to 51.4% by weight, based on the total weight of the composition. %, 20.1 to 23.3% by weight of linalool, preferably 20.3 to 23.3% by weight, more preferably 20.3 to 22.3% by weight, 10.3 to 12.0% by weight of anisaldehyde, preferably 10.5 to 12.0 wt%, more preferably 10.7 to 11.1 wt%, 3,7-dimethyl-1,5,7-octatrien-3-ol (3,7-dimethyl-1,5,7-octatrien-3- ol) 4 to 4.6% by weight, preferably 4.1 to 4.6% by weight, more preferably 4.2 to 4.4% by weight, 2-phenylethyl alcohol (2-Phenylethyl alcohol) 3 to 3.4% by weight, preferably 3.1 -3.4% by weight, more preferably in the range of 3.15-3.25% by weight.

본 발명의 일 실시상태에 있어서, 상기 향료 조성물은 조성물 총 중량에 대하여 노나날(Nonanal)을 1.5~4.7 중량%, 바람직하게는 1.5~4.6 중량%, 더 바람직하게는 2.1~4.1 중량%, 오시멘(Ocimene)을 0.9~4.9 중량%, 바람직하게는 1.9~3.9 중량%, 라일락 알코올(Lilac alcohol)을 0.5~3 중량%, 바람직하게는 0.5~2.8 중량%, 더 바람직하게는 1.4~2.5 중량%, 리모넨(Limonene)을 0.7~2.4 중량%, 바람직하게는 1.0~2.2 중량%, 제라니올(Geraniol)을 0.08~0.3 중량%, 바람직하게는 0.08~0.25 중량%, 더 바람직하게는 0.1~0.25 중량%, δ-데카락톤(δ-decalactone)을 0.08~0.25 중량%, 바람직하게는 0.1~0.25 중량%의 범위로 함유한다. In an exemplary embodiment of the present invention, the perfume composition contains 1.5 to 4.7% by weight of nonanal, preferably 1.5 to 4.6% by weight, more preferably 2.1 to 4.1% by weight, oh, based on the total weight of the composition 0.9 to 4.9 wt% of cymene, preferably 1.9 to 3.9 wt%, 0.5 to 3 wt% of lilac alcohol, preferably 0.5 to 2.8 wt%, more preferably 1.4 to 2.5 wt% %, 0.7 to 2.4% by weight of Limonene, preferably 1.0 to 2.2% by weight, 0.08 to 0.3% by weight of Geraniol, preferably 0.08 to 0.25% by weight, more preferably 0.1 to 0.25% by weight, δ-decalactone (δ-decalactone) is contained in the range of 0.08 to 0.25% by weight, preferably 0.1 to 0.25% by weight.

박달목서꽃 향취를 재현하기 위한 주요 성분인 리날룰옥사이드, 리날룰, 아니스 알데하이드, 3,7-디메틸-1,5,7-옥타트리엔-3-올, 2-페닐에틸알코올, 메틸자스모네이트는 상기 범위를 벗어난 범위로 사용할 경우, 박달목서꽃과의 향취 유사성이 낮아지고, 향취의 기호성도 낮아지므로 바람직하지 않다. 그러나, 그 외의 부차적인 성분으로서 노나날, 오시멘, 라일락 알코올, 리모넨, 제라니올, δ-데카락톤, 자스민 락톤 성분들은 상기 범위 내에서 사용하는 것이 바람직하지만, 박달목서꽃의 향취에 크게 영향을 미치지 않기 때문에 박달목서꽃 향취를 재현하는데 영향을 미치지 않는 한, 상기 범위를 벗어나는 양으로도 함유될 수 있다.Linalool oxide, linalool, anise aldehyde, 3,7-dimethyl-1,5,7-octatrien-3-ol, 2-phenylethyl alcohol, methyl jasmonate, which are the main ingredients for reproducing the scent of Birchwood. When used in a range out of the above range, it is not preferable because the similarity of the scent to the B. magnolia flower and the palatability of the scent are also lowered. However, as other secondary ingredients, nonanal, ocimene, lilac alcohol, limonene, geraniol, δ-decalactone, and jasmine lactone components are preferably used within the above range, but they greatly affect the flavor of Birchwood. As long as it does not affect the reproduction of the scent of Bakdal Moxae flower, it may be contained in an amount outside the above range.

본 발명에 따른 피부 외용제는 전술한 본 발명의 향료 조성물을 함유한다. The external preparation for skin according to the present invention contains the above-described fragrance composition of the present invention.

상기 피부 외용제는 향수용, 화장용 또는 약용 (藥用)일 수 있으며, 상기 항료 조성물의 배합량은 당업계에 통상적인 기술에 따라, 목적하는 효과를 이루기 위해 적절하게 선택하여 배합할 수 있다.The external preparation for skin may be for perfume, cosmetic or medicinal use, and the blending amount of the perfume composition may be appropriately selected and blended to achieve the desired effect according to conventional techniques in the art.

상기 피부 외용제의 제형은 예를 들면, 연고, 로션, 가용화상, 현탁액, 에멀젼, 크림, 젤, 스프레이, 파프제, 경고제, 패치제 또는 물파스 등일 수 있지만 이들에만 한정되지 않고, 당업계에 주지된 어떠한 기제에도 배합될 수 있다.The formulation of the external preparation for skin may be, for example, ointment, lotion, solubilization, suspension, emulsion, cream, gel, spray, patch, warning agent, patch or water paste, but is not limited thereto, and is not limited thereto, and is well known in the art. It can be formulated with any base.

이하, 실시예를 통해 본 발명을 더욱 구체적으로 설명하지만, 본 발명이 이에 한정되지 않고, 본 발명의 다른 적용, 변형 등도 당업자에게 자명하다.Hereinafter, the present invention will be described in more detail through examples, but the present invention is not limited thereto, and other applications and modifications of the present invention will be apparent to those skilled in the art.

[참고예 1] SPME법을 이용한 박달목서꽃의 향취 분석[Reference Example 1] Fragrance analysis of Bak dahlia flower using SPME method

SPME법 (SUPELCO international, Vol.13, No.4, p.9-10)은 헤드 스페이스(Head Space)법의 일종이다.The SPME method (SUPELCO international, Vol.13, No.4, p.9-10) is a kind of headspace method.

추출과정에서 높은 열을 가해야 하고 처리 과정이 복잡하여 많은 시간이 소요되므로 본래의 향취와는 많은 차이가 있을 수 있는 박달목서꽃의 향취 성분을 화정유(Absolute) 형태로 만드는 용매추출법과 향취 성분을 정유(Essential oil)로 만드는 수증기증류법과 달리 SPME법은 기존의 추출법과는 달리 용매를 사용하지 않고, 전처리 또한 필요 없어, 신속하고 간편하게 향취 성분을 분석할 수 있다는 장점이 있다. Since high heat has to be applied during the extraction process and the processing process is complicated, which takes a lot of time, the solvent extraction method and fragrance ingredients that make the fragrance component of B. Unlike the steam distillation method made with essential oil, the SPME method does not use a solvent and does not require pre-treatment unlike the existing extraction method, so it has the advantage of being able to analyze the fragrance components quickly and conveniently.

향기가 강한 박달목서 한 그루를 골라 2시간동안 85㎛의 폴리아크릴레이트로 코팅된 화이버(Polyacrylate Fiber)에 향기성분을 흡착시켜 향기성분을 포집하였다. 제주특별자치도 제주시 한경면 용수리 절부암에서 3시간 동안 포집이 이루어졌다.Fragrance components were collected by selecting one tree with strong fragrance and adsorbing the fragrance component to a polyacrylate fiber coated with 85㎛ polyacrylate for 2 hours. The collection was carried out for 3 hours at Jeolbuam in Yongsu-ri, Hangyeong-myeon, Jeju-si, Jeju-do.

향취성분을 포집한 후, 화이버(Fiber)를 밀봉하고, 이를 GC-MS의 주입구에 옮겨 꽂은 다음, 2분간 탈착을 시키고, GC-MS 분석을 행하였다. GC-MS 분석조건은 다음과 같다.After collecting the odor component, the fiber was sealed, transferred to the GC-MS inlet, and then desorbed for 2 minutes, followed by GC-MS analysis. GC-MS analysis conditions are as follows.

SPME법은 특별한 전처리 없이 화이버(Fiber)에 흡착된 향취 성분들이 GS-MS 컬럼안으로 빠르게 탈착, 주입될 수 있어, 분석시간이 크게 단축될 수 있으므로, 박달목서꽃의 향취 성분을 분석하는데 유리하다.The SPME method is advantageous for analyzing the odor components of Baklava flower because the analysis time can be greatly shortened as the odor components adsorbed on the fiber can be quickly desorbed and injected into the GS-MS column without special pretreatment.

분석 조건analysis conditions

. 분석기기: HP 5890 II GC. Analyzer: HP 5890 II GC

. 검출기: HP 5972 MSD. Detector: HP 5972 MSD

. 컬럼(Column): DB-1(60m X 0.25mm X 0.25um). Column: DB-1 (60m X 0.25mm X 0.25um)

. 이동 기체(Carrier Gas): He. Carrier Gas: He

. 주입부 온도(Injection Temperature): 250 ℃. Injection Temperature: 250 ℃

. 검출부 온도(Detector Temperature): 280 ℃. Detector Temperature: 280 ℃

. 오븐 온도(Oven Temperature): 70℃~220℃(3℃/min) . Oven Temperature: 70℃~220℃(3℃/min)

. 이온화 전압(Ionization Voltage): 70eV. Ionization Voltage: 70 eV

. 탈착 시간: 2분. Desorption time: 2 minutes

그 결과, SPME법에 의해 분석된 박달목서꽃의 향취성분은 하기 표 1과 같다.As a result, the fragrance components of Bakdal-Mokseo flower analyzed by the SPME method are shown in Table 1 below.

향료명spice name 함량(%)content(%) 리날룰옥사이드linalool oxide 39.4239.42 리날룰linalul 16.6416.64 아니스알데하이드anise aldehyde 8.578.57 3,7-디메틸-1,5,7-옥타트리엔-3-올3,7-dimethyl-1,5,7-octatrien-3-ol 3.343.34 2-페닐에틸알코올 2-phenylethyl alcohol 2.482.48 노나날nonal 1.131.13 오시멘Oshimen 1.071.07 라일락 알코올 lilac alcohol 0.720.72 리모넨limonene 0.570.57 제라니올 geraniol 0.080.08 δ-데카락톤δ-decalactone 0.060.06 기타etc 25.9225.92 총함량total content 100100

상기 표 1에서 보여지는 바와 같이, 박달목서꽃은 2 리날룰옥사이드(Linalool oxide), 리날룰(Linalool), 아니스알데하이드(Anisaldehyde), 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol), 2-페닐에틸알코올(2-Phenylethyl alcohol)을 주요 향취성분으로 하고 있으며, 이들 주요 성분이 전체의 70.45 중량%를 차지하고 있음을 알 수 있다.As shown in Table 1 above, Bakdal-mokseo flower 2 linalool oxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octatriene-3 -ol (3,7-dimethyl-1,5,7-octatrien-3-ol) and 2-phenylethyl alcohol (2-Phenylethyl alcohol) are the main flavoring ingredients, and these main ingredients are 70.45% by weight of the total It can be seen that occupies

[시험예 1] 분석결과로 조성된 향료와 천연 박달목서꽃의 향취와의 비교관능평가 [Test Example 1] Comparative sensory evaluation between the fragrance prepared as a result of the analysis and the fragrance of natural Baklava flower

상기 분석된 결과를 토대로 새로이 조성한 하기 표 2의 조성을 갖는 조합향료(샘플 B)를 만들고, 이 항료와 천연 박달목서꽃의 향취 유사성을 관능평가를 통하여 검증하였다.Based on the results of the analysis, a freshly formulated fragrance (Sample B) having the composition shown in Table 2 below was prepared, and the similarity of smell between this fragrance and the natural Baklava flower was verified through sensory evaluation.

향료명spice name 함량(%)content(%) 리날룰옥사이드linalool oxide 39.4239.42 리날룰linalul 16.6416.64 아니스알데하이드anise aldehyde 8.578.57 3,7-디메틸-1,5,7-옥타트리엔-3-올3,7-dimethyl-1,5,7-octatrien-3-ol 3.343.34 2-페닐에틸알코올 2-phenylethyl alcohol 2.482.48 노나날nonal 1.131.13 오시멘Oshimen 1.071.07 라일락 알코올 lilac alcohol 0.720.72 리모넨limonene 0.570.57 제라니올 geraniol 0.080.08 δ-데카락톤δ-decalactone 0.060.06 DPG (DIPROPYLENE GLYCOL)DPG (DIPROPYLENE GLYCOL) 25.9225.92 총함량total content 100100

관능평가는 20~45세의 일반남녀 20명을 대상으로 하였으며, 박달목서꽃 화분의 샘플 A와, SPME법으로 재현한 조합향료의 샘플 B의 향취를 각각 맡아보도록 하고, 하기 표 3의 설문지에 응답하도록 함으로써, 샘플 A와 샘플 B의 향취 유사성(질문 1) 및 향취의 기호성(질문 2)을 조사하였다. 그 결과는 표 4에 나타내었다.The sensory evaluation was conducted on 20 normal men and women aged 20 to 45 years old, and they were asked to smell the scent of sample A of sagebrush flower pollen and sample B of the combination fragrance reproduced by SPME method, respectively, and responded to the questionnaire in Table 3 below. By doing so, the odor similarity (question 1) and taste preference (question 2) of sample A and sample B were investigated. The results are shown in Table 4.

설문지
(1) 질문 1: 샘플A와 샘플B의 향취가 얼마나 유사(비슷)한가?
1) 전혀 유사하지 않다.
2) 별로 유사하지 않다.
3) 그저 그렇다.
4) 어느 정도 유사하다.
5) 매우 유사하다.
(2) 질문 2: 샘플 B의 향취를 얼마나 좋아하는가?
1) 전혀 좋지 않다.
2) 별로 좋지 않다.
3) 그저 그렇다.
4) 약간 좋다.
5) 매우 좋다.
survey
(1) Question 1: How similar are the scents of Sample A and Sample B?
1) Not at all similar.
2) Not very similar.
3) Just so.
4) are somewhat similar.
5) Very similar.
(2) Question 2: How much do you like the smell of Sample B?
1) Not good at all.
2) Not very good.
3) Just so.
4) Slightly good.
5) Very good.

평가요원evaluator 질문 1 (유사성)Question 1 (Similarity) 질문 2 (기호성)Question 2 (symbolic) 1One 22 1One 22 22 33 33 33 33 44 33 22 55 33 22 66 1One 33 77 33 22 88 22 33 99 22 1 One 1010 33 33 1111 33 1One 1212 44 33 1313 33 1One 1414 33 33 1515 22 33 1616 22 22 1717 33 1One 1818 33 1One 1919 44 33 2020 33 33 평균Average 2.72.7 2.22.2

상기 표 4에서 보는 바와 같이, 조합향료인 샘플 B는 박달목서꽃 화분의 꽃 향취와 많은 차이가 있는 것으로 나타났으며, 기호성도 낮게 나타났다.As shown in Table 4, sample B, which is a combination fragrance, was found to have a lot of difference from the flower scent of sagebrush flower pollen, and showed low palatability.

[시험예 2] 전문 평가단에 의한 향취분석과 박달목서꽃과의 향취비교[Test Example 2] Fragrance analysis by a professional evaluation team and comparison of scent with Bakdalmokseo flower

상기 시험예 1에서 보는 바와 같이, SPME법에 의해 분석된 성분을 인공적으로 배합 조성한 향료 조성물이 박달목서꽃으로부터 직접 포집한 향취와 유사성이 없었다. As shown in Test Example 1, the fragrance composition artificially formulated with the components analyzed by the SPME method had no similarity to the fragrance directly collected from Baklava flower.

이에, 조향사로 구성된 전문 평가단은 박달목서꽃의 각각의 향취 성분들에 대하여 관능평가를 수행하였다. 그 결과, 박달목서꽃의 향취 성분들 중, 스윗 우디(Sweet woody)한 향취를 만들어내는 리날룰옥사이드, 플로랄 우디(Floral woody)한 향취를 만들어내는 리날룰, 스윗 플로랄(Sweet floral)한 향취를 만들어내는 아니스알데하이드, 캠퍼러스(Camphoreous)한 향취를 만들어내는 3,7-디메틸-1,5,7-옥타트리엔-3-올, 로지 플로랄(Rosey floral)한 향취를 만들어내는 2-페닐에틸알코올의 다섯 성분이 박달목서꽃의 고유향취를 만들어내는 주요성분임을 확인하였다.Accordingly, a professional evaluation team composed of perfumers performed a sensory evaluation on each fragrance component of Bakdalmokseo flower. As a result, among the fragrance components of Bakdal Moxae, linalool oxide, which creates a sweet woody fragrance, linalool, which creates a floral woody fragrance, and sweet floral fragrance were created. Anisaldehyde, 3,7-dimethyl-1,5,7-octatrien-3-ol, which produces a camphorous scent, and 2-phenylethyl alcohol, which produces a rosey floral scent It has been confirmed that the five components of .

[실시예 1] 주성분의 함량변화에 따른 새로운 조합향료의 제조[Example 1] Preparation of a new combination fragrance according to the change in the content of the main ingredient

상기 참고 실시예 3으로부터, 박달목서꽃의 독창적 향취의 주성분이 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸-1,5,7-옥타트리엔-3-올, 2-페닐에틸알코올임을 확인할 수 있었다. 따라서, 본 발명자들은 이들 다섯 성분을 함유하여 박달목서꽃향취를 그대로 나타내면서, 기호성이 좋은 향료를 제조하기 위해서 하기 #1 내지 #4의 새로운 조합 향료들을 만들었다.From the Reference Example 3, the main ingredients of the original scent of Bakdal Moxa flower were linalooxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octatrien-3-ol, and 2-phenylethyl alcohol. was able to confirm that Therefore, the present inventors made new combinations of fragrances #1 to #4 below in order to produce a fragrance with good palatability while containing these five ingredients as it is, while exhibiting the fragrance of Bakdal Mokseo flower.

조합향료 #1부터 #4는 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸-1,5,7-옥타트리엔-3-올 및 2-페닐에틸알코올의 함량의 합을 80~95중량%로 변화시켜 제조하였으며, 구체적인 조성은 하기 표 5에 나타내었다.Combination fragrances #1 to #4 consist of 80~ It was prepared by changing it to 95% by weight, and the specific composition is shown in Table 5 below.

향료명spice name #1#One #2#2 #3#3 #4#4 (80중량%)(80% by weight) (85중량%)(85% by weight) (90.1중량%)(90.1% by weight) (95중량%)(95% by weight) 리날룰옥사이드linalool oxide 44.844.8 47.647.6 50.450.4 53.253.2 리날룰linalul 18.918.9 20.120.1 21.321.3 22.422.4 아니스알데하이드anise aldehyde 9.79.7 10.310.3 10.910.9 11.611.6 3,7-디메틸-1,5,7-옥타트리엔-3-올3,7-Dimethyl-1,5,7-octatrien-3-ol 3.83.8 44 4.34.3 4.54.5 2-페닐에틸알코올2-phenylethyl alcohol 2.82.8 33 3.23.2 3.33.3 노나날nonal 6.26.2 4.74.7 3.13.1 1.61.6 오시멘Oshimen 5.95.9 4.44.4 2.92.9 1.51.5 라일락 알코올lilac alcohol 44 33 22 1One 리모넨limonene 3.23.2 2.42.4 1.61.6 0.70.7 제라니올geraniol 0.40.4 0.30.3 0.20.2 0.10.1 δ-데카락톤δ-decalactone 0.30.3 0.20.2 0.10.1 0.10.1 총 함량total content 100.0100.0 100.0100.0 100.0100.0 100.0100.0

[시험예 3] 상기 실시예 1에서 제조된 향료들의 관능평가[Test Example 3] Sensory evaluation of the perfumes prepared in Example 1

새로이 조합된 4가지의 향료에 대해, 박달목서꽃 향취와의 유사성 및 기호성을 참고 실시예 2와 동일한 방법의 관능평가에 의해 실시하였다. 한편, 두 개의 조합향료에 대한 비교관능평가를 실시한 후, 5분 동안의 휴식시간을 주어 후감각 마비현상이 없도록 하였다. 새로운 조합향료와 박달목서꽃의 향취 유사성 및 기호성에 관한 관능평가결과는 하기 표 6에 나타내었다.For the four newly combined fragrances, the similarity and palatability with the fragrance of Bakdal Moxae flower was carried out by sensory evaluation in the same manner as in Reference Example 2. On the other hand, after performing comparative sensory evaluation of the two combination fragrances, a rest period of 5 minutes was given so that there was no olfactory sensory paralysis. The sensory evaluation results regarding the similarity of scent and palatability of the new combination spice and Bakdalmokseo flower are shown in Table 6 below.

평가
요원
evaluation
agent
질문1 (유사성)Question 1 (similarity) 질문2 (기호성)Question 2 (Preference)
조합향료번호Combination Fragrance No. 조합향료번호Combination Fragrance No. #1#One #2#2 #3#3 #4#4 #1#One #2#2 #3#3 #4#4 1One 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 1.0 1.0 2.0 2.0 3.0 3.0 2.0 2.0 22 1.0 1.0 2.0 2.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 2.0 2.0 33 3.0 3.0 2.0 2.0 4.0 4.0 2.0 2.0 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 44 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 2.0 2.0 55 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 4.0 4.0 3.0 3.0 66 1.0 1.0 3.0 3.0 3.0 3.0 4.0 4.0 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 77 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 1.0 1.0 1.0 1.0 4.0 4.0 3.0 3.0 88 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 99 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 2.0 2.0 2.0 2.0 4.0 4.0 3.0 3.0 1010 2.0 2.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 1111 3.0 3.0 2.0 2.0 4.0 4.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 1212 1.0 1.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 1313 2.0 2.0 3.0 3.0 4.0 4.0 2.0 2.0 1.0 1.0 3.0 3.0 3.0 3.0 4.0 4.0 1414 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 1515 3.0 3.0 2.0 2.0 4.0 4.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 1616 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 1717 2.0 2.0 2.0 2.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0 3.0 1818 2.0 2.0 2.0 2.0 3.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0 2.0 2.0 4.0 4.0 1919 1.0 1.0 2.0 2.0 3.0 3.0 2.0 2.0 3.0 3.0 1.0 1.0 3.0 3.0 3.0 3.0 2020 2.0 2.0 2.0 2.0 4.0 4.0 2.0 2.0 1.0 1.0 1.0 1.0 2.0 2.0 3.0 3.0 평균Average 2.12.1 2.62.6 3.53.5 2.72.7 2.22.2 2.352.35 3.33.3 2.92.9

상기 표 6에서 보는 바와 같이, 주요 다섯 성분의 총함량이 90중량%를 차지하는 샘플 #3이 4개의 조합향료 중 가장 뛰어난 유사성과 기호성을 갖는 것으로 보여졌으나, 유사성과 기호성이 모두 기대에 미치지 못하는 것으로 나타났다.As shown in Table 6, sample #3, which accounts for 90% by weight of the total content of the five main ingredients, was shown to have the best similarity and palatability among the four combined fragrances, but both the similarity and palatability did not meet expectations. appear.

[실시예 2] 전문 평가단의 분석에 의한 향취 개선향료 제조[Example 2] Preparation of fragrance improvement fragrance by analysis of professional evaluation group

상기 표 6에서 박달목서꽃의 향취가 가장 유사한 것으로 나타난 샘플 #3의 향료의 유사성 및 기호성을 개선하기 위해서, 상기 샘플 #3에서와 주성분이 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸1,5,7-옥타트리엔-3-올, 2-페닐알코올을 90중량%의 함량으로 함유하고, 여기에 박달목서꽃 향기의 재현에 특유의 향을 갖게 만드는 메틸자스모네이트(Methyl jasmonate)를 사용하여 새로운 조합향료를 제조하였다. 이때, 메틸자스모네이트의 함량기준은 0.5중량%, 1중량%, 1.5중량%, 2중량% 및 2.5중량%, 3중량%, 3.5중량%의 함량으로 변화시켜가면서 첨가하고, 그 외 성분들은 메틸자스모네이트의 함량 변화에 따라 총 함량 100을 맞추기 위해 조절하였다. 이들 재조합 향료의 조성은 하기 표 7과 같다. In Table 6, in order to improve the similarity and palatability of the fragrance of Sample #3, which showed the most similar odor of Baklava flower, the main ingredients in Sample #3 were linalool oxide, linalool, anisaldehyde, 3,7-dimethyl Methyl jasmonate, which contains 1,5,7-octatrien-3-ol and 2-phenyl alcohol in an amount of 90% by weight, and gives a unique scent to the reproduction of the scent of B. was used to prepare a new combination fragrance. At this time, the content standard of methyl jasmonate is added while changing the content of 0.5% by weight, 1% by weight, 1.5% by weight, 2% by weight, 2.5% by weight, 3% by weight, and 3.5% by weight, and the other components are According to the change in the content of methyl jasmonate, it was adjusted to match the total content of 100. The compositions of these recombinant fragrances are shown in Table 7 below.

조합향료 번호Combination spice number #가#go #나#me #다#all #라#la #마#mind #바#bar #사#buy 향료명spice name 함량(%)content(%) 함량(%)content(%) 함량(%)content(%) 함량(%)content(%) 함량(%)content(%) 함량(%)content(%) 함량(%)content(%) 리날룰옥사이드linalool oxide 50.450.4 50.450.4 50.450.4 50.450.4 50.450.4 50.450.4 50.450.4 리날룰linalul 21.321.3 21.321.3 21.321.3 21.321.3 21.321.3 21.321.3 21.321.3 아니스알데하이드anise aldehyde 10.910.9 10.910.9 10.910.9 10.910.9 10.910.9 10.910.9 10.910.9 3,7-디메틸-1,5,7-옥타트리엔-3-올3,7-Dimethyl-1,5,7-octatrien-3-ol 4.34.3 4.34.3 4.34.3 4.34.3 4.34.3 4.34.3 4.34.3 2-페닐에틸알코올2-phenylethyl alcohol 3.23.2 3.23.2 3.23.2 3.23.2 3.23.2 3.23.2 3.23.2 노나날nonal 2.92.9 2.82.8 2.62.6 2.52.5 2.32.3 2.22.2 2.02.0 오시멘Oshimen 2.82.8 2.72.7 2.52.5 2.32.3 2.22.2 2.02.0 1.91.9 라일락 알코올lilac alcohol 1.91.9 1.81.8 1.71.7 1.61.6 1.51.5 1.41.4 1.31.3 리모넨limonene 1.41.4 1.31.3 1.31.3 1.21.2 1.11.1 1.11.1 1.01.0 제라니올geraniol 0.20.2 0.20.2 0.20.2 0.20.2 0.20.2 0.10.1 0.10.1 δ-데카락톤δ-decalactone 0.20.2 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 메틸자스모네이트methyl jasmonate 0.50.5 1One 1.51.5 22 2.52.5 33 3.53.5 총함량total content 100.0100.0 100.0100.0 100.0100.0 100.0100.0 100.0100.0 100.0100.0 100.0100.0

[시험예 4] 실시예 2에서 제조된 조합향료들의 관능평가[Test Example 4] Sensory evaluation of the combined fragrances prepared in Example 2

상기 실시예 2에서 조합된 #가, #나, #다, #라, #마, #바의 조합 향료들에 대해, 박달목서꽃의 향취 유사성 및 향취의 기호성을 상기 참고 시험예 1와 동일한 방법에 의해서 관능평가를 실시하였다. 두 개의 조합향료에 대한 비교관능평가를 실시한 후, 5분 동안의 휴식시간을 주어, 후감각 마비현상이 없도록 하였다. 새로운 조합향료와 박달목서꽃과의 향취 유사성 및 향취 기호성에 결과는 하기 표 8에 나타내었다.For the combined fragrances of #a, #na, #da, #ra, #ma, and #bar combined in Example 2, the similarity of the scent and the palatability of the scent of B. sensory evaluation was performed. After comparative sensory evaluation of the two combination fragrances, a rest period of 5 minutes was given to prevent olfactory sensory paralysis. The results of the similarity of smell and flavor palatability between the new combination perfume and Bakdalmokseo flower are shown in Table 8 below.

평가요원evaluator 질문1 (유사성)Question 1 (similarity) 질문2 (기호성)Question 2 (Preference) 조합향료번호Combination Fragrance No. 조합향료번호Combination Fragrance No. #가#go #나#me #다#all #라#la #마#mind #바#bar #사#buy #가#go #나#me #다#all #라#la #마#mind #바#bar #사#buy 1One 3.0 3.0 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 1.0 1.0 2.0 2.0 4.04.0 5.05.0 4.04.0 4.0 4.0 2.0 2.0 22 2.0 2.0 3.0 3.0 3.0 3.0 5.0 5.0 4.0 4.0 4.0 4.0 2.0 2.0 2.0 2.0 2.0 2.0 2.02.0 5.05.0 4.04.0 3.0 3.0 3.0 3.0 33 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 3.0 3.0 4.0 4.0 2.0 2.0 4.0 4.0 1.0 1.0 3.03.0 5.05.0 3.03.0 4.0 4.0 2.0 2.0 44 2.0 2.0 2.0 2.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 3.03.0 4.04.0 4.04.0 4.0 4.0 3.0 3.0 55 2.0 2.0 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.04.0 3.03.0 5.05.0 4.0 4.0 4.0 4.0 66 3.0 3.0 2.0 2.0 4.0 4.0 4.0 4.0 5.0 5.0 2.0 2.0 4.0 4.0 2.0 2.0 4.0 4.0 3.03.0 4.04.0 5.05.0 3.0 3.0 3.0 3.0 77 3.0 3.0 3.0 3.0 3.0 3.0 5.0 5.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 2.0 2.0 4.04.0 3.03.0 4.04.0 4.0 4.0 2.0 2.0 88 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 3.03.0 4.04.0 4.04.0 5.0 5.0 2.0 2.0 99 2.0 2.0 2.0 2.0 4.0 4.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 3.03.0 5.05.0 5.05.0 3.0 3.0 2.0 2.0 1010 3.0 3.0 2.0 2.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 2.0 2.0 4.04.0 4.04.0 4.04.0 4.0 4.0 3.0 3.0 1111 2.0 2.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 5.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 4.04.0 4.04.0 3.03.0 3.0 3.0 3.0 3.0 1212 2.0 2.0 4.0 4.0 4.0 4.0 5.0 5.0 5.0 5.0 3.0 3.0 2.0 2.0 2.0 2.0 4.0 4.0 4.04.0 3.03.0 3.03.0 5.0 5.0 3.0 3.0 1313 3.0 3.0 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 3.03.0 4.04.0 4.04.0 4.0 4.0 2.0 2.0 1414 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 4.0 5.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 4.04.0 5.05.0 4.04.0 3.0 3.0 2.0 2.0 1515 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 5.0 5.0 3.0 3.0 2.0 2.0 2.0 2.0 3.0 3.0 2.02.0 4.04.0 4.04.0 4.0 4.0 3.0 3.0 1616 2.0 2.0 2.0 2.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0 3.03.0 4.04.0 3.03.0 3.0 3.0 2.0 2.0 1717 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 5.0 5.0 5.0 5.0 3.0 3.0 4.0 4.0 3.0 3.0 3.03.0 5.05.0 3.03.0 3.0 3.0 3.0 3.0 1818 2.0 2.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.03.0 4.04.0 4.04.0 3.0 3.0 4.0 4.0 1919 2.0 2.0 4.0 4.0 3.0 3.0 5.0 5.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 4.04.0 5.05.0 3.03.0 4.0 4.0 3.0 3.0 2020 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 5.0 5.0 3.0 3.0 2.0 2.0 2.0 2.0 3.03.0 3.03.0 5.05.0 4.0 4.0 4.0 4.0 평균Average 2.42.4 2.752.75 3.63.6 4.34.3 4.04.0 3.653.65 2.92.9 2.552.55 2.62.6 3.33.3 4.154.15 3.93.9 3.73.7 2.752.75

상기 표 8에서 보는 바와 같이, 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸1,5,7-옥타트리엔-3-올, 2-페닐알코올의 박달목서꽃의 주요 향취성분에 메틸자스모네이트를 1.5 내지 3.0 중량%의 범위로 포함하는 #다, #라, #마, #바 의 경우에는 향취의 유사성 및 기호성이 높으며(평균 3.0 초과), 특히 메틸자스모네이트를 2.0 내지 3.0중량%의 양으로 함유할 경우에는 박달목서꽃과의 향취 유사성 및 향취 기호성이 매우 우수하여 박달목서꽃의 향취를 잘 재현할 수 있음을 확인할 수 있다.As shown in Table 8, methyl in the main flavor components of linalool oxide, linalool, anisaldehyde, 3,7-dimethyl 1,5,7-octatrien-3-ol, and 2-phenyl alcohol In the case of #da, #ra, #ma, and #bar containing jasmonate in an amount of 1.5 to 3.0% by weight, the similarity and palatability of the fragrance are high (average greater than 3.0), and in particular, 2.0 to 3.0 of methyljasmonate When it is contained in an amount of % by weight, it can be confirmed that the scent similarity and flavor palatability to Bakdal Moxa flower are very excellent, so that the scent of B.

한편, 메틸자스모네이트를 1.5중량% 미만 또는 3중량% 초과로 함유하면 오히려 향취의 유사성 및 기호성이 낮아짐을 알 수 있었다.On the other hand, it was found that when the methyl jasmonate was contained in an amount of less than 1.5% by weight or more than 3% by weight, the similarity and palatability of the scent were rather lowered.

[제형예][Formulation example]

상기에서와 같이 박달목서꽃의의 향취를 재현한 향료 조성물 (상기 표 7의 # 라)을 배합하여, 하기 표 9의 향수를 제조하였다. As described above, the perfume of Table 9 was prepared by blending the perfume composition that reproduced the scent of Bakdalmokseo flower (#d in Table 7 above).

박달목서꽃의 향취를 재현한 향료 조성물을 함유하는 향수Perfume containing a perfume composition that reproduces the scent of Bakdal Moxae flower 박달목서꽃 향취 재현 조합향료
알코올

색소
자외선차단제
Combination fragrance to reproduce the scent of Bakdalmokseo flower
Alcohol
water
pigment
sunscreen
15 중량%
83 중량%
2 중량%
적량
적량
15% by weight
83 wt%
2% by weight
appropriate amount
appropriate amount

Claims (11)

박달목서꽃의 주요 향취 성분 및 보조 향취 성분; 및 메틸자스모네이트(Methyl jasmonate)를 유효성분으로 함유하는 박달목서꽃의 향취를 재현한 향료 조성물로서,
상기 주요 향취 성분은 리날룰옥사이드(Linalool oxide), 리날룰(Linalool), 아니스알데하이드(Anisaldehyde), 3,7-디메틸-1,5,7-옥타트리엔-3-올(3,7-dimethyl-1,5,7-octatrien-3-ol) 및 2-페닐에틸알코올(2-Phenylethyl alcohol)이고,
상기 보조 향취 성분은 노나날(Nonanal), 오시멘(Ocimene), 라일락 알코올(Lilac alcohol), 리모넨(Limonene), 제라니올(Geraniol) 및 δ-데카락톤(δ-decalactone)이며,
상기 향료 조성물은 조성물의 총 중량에 대하여, 리날룰옥사이드를 47.6~54.4중량%로 함유하며, 리날룰을 20.1~23.3중량%로 함유하고, 아니스알데하이드를 10.3~12.0중량%로 함유하며, 3,7-디메틸-1,5,7-옥타트리엔-3-올을 4~4.6중량%로 함유하고, 2-페닐에틸알코올을 3~3.4중량%로 함유하며, 메틸자스모네이트를 1.5~3.0중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.
The main and auxiliary odor components of Bakdal Moxa flower; and methyl jasmonate as an active ingredient.
The main fragrance ingredient is linalool oxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octatrien-3-ol (3,7-dimethyl) -1,5,7-octatrien-3-ol) and 2-phenylethyl alcohol (2-Phenylethyl alcohol),
The auxiliary fragrance component is nonanal, ocimene, lilac alcohol, limonene, geraniol and δ-decalactone (δ-decalactone),
The perfume composition contains 47.6 to 54.4% by weight of linalool oxide, 20.1 to 23.3% by weight of linalool, and 10.3 to 12.0% by weight of anisaldehyde with respect to the total weight of the composition, 3, Contains 7-dimethyl-1,5,7-octatrien-3-ol in an amount of 4 to 4.6% by weight, 2-phenylethyl alcohol in an amount of 3 to 3.4% by weight, and methyl jasmonate in an amount of 1.5 to 3.0 A fragrance composition that reproduces the scent of Bakdal Moxae flower, characterized in that it is contained in weight %.
제1항에 있어서, 상기 주요 향취 성분 및 메틸자스모네이트의 중량비는 90.1 : 2~3인 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.According to claim 1, wherein the weight ratio of the main fragrance component and methyl jasmonate is 90.1: 2 to 3, characterized in that, the fragrance composition reproduces the fragrance of Bakdal Mokseo flower. 삭제delete 삭제delete 제1항에 있어서, 상기 향료 조성물은 조성물의 총 중량에 대하여, 리날룰옥사이드를 48.4~54.4중량%로 함유하며, 리날룰을 20.3~23.3중량%로 함유하고, 아니스알데하이드를 10.5~12.0중량%로 함유하며, 3,7-디메틸-1,5,7-옥타트리엔-3-올을 4.1~4.6중량%로 함유하고, 2-페닐에틸알코올을 3.1~3.4중량%로 함유하며, 메틸자스모네이트를 1.5~3.0중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.According to claim 1, wherein the perfume composition contains 48.4 to 54.4% by weight of linalool oxide, 20.3 to 23.3% by weight of linalool, and 10.5 to 12.0% by weight of anisaldehyde, based on the total weight of the composition. Contains 3,7-dimethyl-1,5,7-octatrien-3-ol in an amount of 4.1 to 4.6% by weight, 2-phenylethyl alcohol in an amount of 3.1 to 3.4% by weight, and methyl A perfume composition that reproduces the scent of Bakdal-mokseo flower, characterized in that it contains smonate in an amount of 1.5 to 3.0% by weight. 제5항 있어서, 상기 향료 조성물은 조성물의 총 중량에 대하여, 리날룰옥사이드를 49.4~51.4중량%로 함유하며, 리날룰을 20.3~22.3중량%로 함유하고, 아니스알데하이드를 10.7~11.1중량%로 함유하며, 3,7-디메틸-1,5,7-옥타트리엔-3-올을 4.2~4.4중량%로 함유하고, 2-페닐에틸알코올을 3.15~3.25중량%로 함유하며, 메틸자스모네이트를 2.0~3.0중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.The perfume composition according to claim 5, wherein the perfume composition contains 49.4 to 51.4% by weight of linalool oxide, 20.3 to 22.3% by weight of linalool, and 10.7 to 11.1% by weight of anisaldehyde, based on the total weight of the composition. Contains 3,7-dimethyl-1,5,7-octatrien-3-ol in an amount of 4.2 to 4.4 wt%, 2-phenylethyl alcohol in an amount of 3.15 to 3.25 wt%, methyljasmo A perfume composition that reproduces the scent of Bakdal-Mokseo flower, characterized in that it contains nate in an amount of 2.0 to 3.0% by weight. 제1항에 있어서, 상기 리날룰옥사이드, 리날룰, 아니스알데하이드, 3,7-디메틸-1,5,7-옥타트리엔-3-올 및 2-페닐에틸알코올의 함량의 합은 조성물의 총 중량에 대하여 85~95중량%인 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.According to claim 1, wherein the sum of the contents of linalooxide, linalool, anisaldehyde, 3,7-dimethyl-1,5,7-octatrien-3-ol and 2-phenylethyl alcohol is the total amount of the composition. A fragrance composition that reproduces the scent of Bakdal Mokseo flower, characterized in that it is 85 to 95% by weight based on the weight. 제1항에 있어서, 상기 향료 조성물은 조성물의 총 중량에 대하여, 노나날을 1.5~4.7중량%로 함유하며, 오시멘을 0.9~4.9중량%로 함유하고, 라일락 알코올을 0.5~3중량%로 함유하며, 리모넨을 0.7~2.4중량%로 함유하고, 제라니올을 0.08~0.3중량%로 함유하며, δ-데카락톤을 0.08~0.25중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.The fragrance composition according to claim 1, wherein the perfume composition contains 1.5 to 4.7% by weight of nonanal, 0.9 to 4.9% by weight of oshimen, and 0.5 to 3% by weight of lilac alcohol, based on the total weight of the composition. Contains limonene in an amount of 0.7 to 2.4% by weight, geraniol in an amount of 0.08 to 0.3% by weight, and δ-decalactone in an amount of 0.08 to 0.25% by weight. A recreated perfume composition. 제8항에 있어서, 상기 향료 조성물은 조성물의 총 중량에 대하여, 노나날을 2.1~4.1중량%로 함유하며, 오시멘을 1.9~3.9중량%로 함유하고, 라일락 알코올을 1.4~2.5중량%로 함유하며, 리모넨을 1.0~2.2중량%로 함유하고, 제라니올을 0.1~0.25중량%로 함유하며, δ-데카락톤을 0.1~0.25중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.The perfume composition according to claim 8, wherein the fragrance composition contains nonanal in an amount of 2.1 to 4.1% by weight, oximen in an amount of 1.9 to 3.9% by weight, and lilac alcohol in an amount of 1.4 to 2.5% by weight, based on the total weight of the composition. Contains limonene in an amount of 1.0 to 2.2% by weight, geraniol in an amount of 0.1 to 0.25% by weight, and δ-decalactone in an amount of 0.1 to 0.25% by weight. A recreated perfume composition. 제9항에 있어서, 상기 향료 조성물은 조성물의 총 중량에 대하여, 노나날을 2.2~2.5중량%로 함유하며, 오시멘을 2.0~2.3중량%로 함유하고, 라일락 알코올을 1.4~1.6중량%로 함유하며, 리모넨을 1.1~1.2중량%로 함유하고, 제라니올을 0.1~0.2중량%로 함유하며, δ-데카락톤을 0.1중량%로 함유하는 것을 특징으로 하는, 박달목서꽃의 향취를 재현한 향료 조성물.10. The method of claim 9, wherein the fragrance composition contains nonanal in an amount of 2.2 to 2.5% by weight, ocimene in an amount of 2.0 to 2.3% by weight, and lilac alcohol in an amount of 1.4 to 1.6% by weight, based on the total weight of the composition. It contains limonene in an amount of 1.1 to 1.2% by weight, geraniol in an amount of 0.1 to 0.2% by weight, and δ-decalactone in an amount of 0.1% by weight. perfume composition. 제1항, 제2항, 제5항, 제6항, 제7항, 제8항, 제9항 및 제10항 중 어느 한 항의 박달목서꽃의 향취를 재현한 향료 조성물을 함유하는 피부 외용제 조성물.Claims 1, 2, 5, 6, 7, 8, 9, and 10. A composition for external application for skin containing a perfume composition reproducing the scent of B. .
KR1020150029547A 2015-03-03 2015-03-03 Perfume composition for expressing the fragrance of Osmanthus insularis Koidz. KR102394530B1 (en)

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