KR101737998B1 - Perfume composition for expressing the fragrance of Chrysanthemum boreale - Google Patents

Abstract

It contains gamma-terpinene, which is an artificial synthetic material with herbal and citrus scent, as an active ingredient. A fragrance composition having excellent palatability while reproducing the intrinsic fragrance of Chrysanthemum boreale is disclosed.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a perfume composition for expressing the fragrance of Chrysanthemum boreale,

The present invention relates to perfume compositions having excellent palatability while reproducing the intrinsic fragrance of Chrysanthemum boreale.

The country is a perennial plant belonging to the dicotyledonous plants of the dicotyledonous plants. It is native to the mountainous regions of Korea, Japan, and northern China. The whole plant has white hairs and the height grows about 1m. Leaves are alternate phyllotaxis and leaf edges are split like feathers. Flowers bloom in October to November in yellow. Head flower is about 1.5cm long and hangs like a mountain type at the end of branches and trunks. The involucre is about 4mm in length, and the crest angle is 3-4 lines. The outer piece is a stripe or a narrow oval shape. The corolla is tubular and the end is divided into 5 branches. The yellow flowers are beautiful and the fragrance is good. It is suitable for planting in the yard, soaking the liquor and boiling the young leaves and eating them as herbs. Flowers are used for calming, detoxifying, and eliminating headaches and dizziness.

There are many ways to reproduce the fragrance of this country. For example, there are solvent extraction methods in which the fragrance components of flowers are made into an absolute form using a solvent, and steam distillation methods in which fragrance components are made into essential oils in a conventional manner. However, since the above methods require high heat during the extraction process, and the processing is complicated and takes a long time, there may be many differences from the original fragrance of flowers.

To overcome these drawbacks, Solid Phase Micro Extraction (SPME) was developed. The SPME method is described in the paper (SUPELCO international, Vol.13, No.4, pages 9-10), which is incorporated herein by reference in its entirety. Unlike the conventional extraction method, the SPME method does not use a solvent and does not require a pretreatment, and thus it is possible to analyze the fragrance ingredient quickly and easily.

Accordingly, the present inventors tried to reproduce the fragrance of the country of origin by using the SPME method which is effective in analyzing the fragrance material of a flower which actually blooms. As a result, alpha-thujone, beta-thujone, camphor, sabinene, p-cymene, etc., And tried to reproduce the fragrance of the country by using it. However, the inventors of the present invention have conducted a sensory test and found that these ingredients alone can not reproduce the fragrance of the country of origin.

Accordingly, the inventors of the present invention conducted research to reproduce the fragrance of the country of origin, and as a result, they found that alpha-thujone, beta-thujone, camphor, sabinene, (p-cymene) and gamma-terpinene, which is a characteristic fragrance ingredient for realizing the Korean national flavor, can be reproduced with the composition of the country of origin as an essential ingredient , Indicating excellent palatability, and completed the present invention.

Accordingly, an object of the present invention is to provide a perfume composition having excellent palatability while reproducing the inherent fragrance of the country of origin.

Another object of the present invention is to provide a composition for external application for skin comprising the above-mentioned perfume composition as a constituent component.

In order to attain the above object, the present invention provides a fragrance composition recreating the fragrance of an acidic country containing gamma-terpinene as an active ingredient and a flavor component of a country of origin.

The present invention also provides a composition for external application for skin containing a fragrance composition recreating the fragrance of the above-mentioned acid of the acid.

The perfume composition according to the present invention is composed of alpha-thujone, beta-thujone, camphor and sabinene as main components for reproducing the acid scent analyzed by the SPME method. , Gamma-terpinene is contained in the main component of the fragrance of p-cymene, and thus it is possible to reproduce the fragrance of the country of origin and to improve the palatability of the fragrance.

In the present invention, the SPME method is used as an analysis method for the fragrance component of the acidic country. The SPME method is advantageous for analyzing the fragrance components of the volatile SOBs because the fractions adsorbed on the fibers can be rapidly desorbed and injected into the GS-MS columns without any special pretreatment and the analysis time can be greatly shortened . In the present invention, based on the fragrance components of the country of origin of PyeongChang, Gangwon Province analyzed by SPME method, a combined fragrance was prepared, and the similarity with the fragrance of the acid fragrance and the taste of the fragrance were performed through the olfactory sensory test. The sensory evaluation was conducted by a professional irrigation and general person, and the similarity with the scent of the country and the palatability of the flavor were evaluated through questionnaires.

As a result of analyzing the flavor components of the country of origin through the SPME method, the flavor components of the country of origin were alpha-thujone, beta-thujone, camphor, sabinene, P-cymene and secondary constituents alpha-phellandrene, beta-phellandrene, benzaldehyde, and sabinol. have.

Based on the results of this analysis, it is found that the fragrance ingredients of the acidic countries of alpha-thujone, beta-thujone, camphor, sabinene and para A gamma-terpinene, which is a component for realizing a Korean native-acid flavor, is added to a p-cymene, thereby providing a composition reproducing the inherent fragrance of an acidic country having excellent palatability.

The perfume composition according to the present invention may be used in combination with other perfume compositions such as alpha-thujone, beta-thujone, camphor, sabinene, p-cymene and gamma- (gamma-terpinene) as an active ingredient.

In addition, the perfume composition may further contain alpha-phellandrene, beta-phellandrene, benzaldehyde and sabinol.

The perfume composition according to the present invention is characterized in that it contains alpha-thujone in an amount of 50.0 to 65.0% by weight, beta-thujone in an amount of 10.0 to 20.0% by weight, camphor in an amount of 4.4% By weight, 10.4% by weight, sabinene by 3.8 to 9.5% by weight, para-cymene by 3.1 to 7.4% by weight, alpha-phellandrene by 3.9 to 7.9% by weight, 3.3 to 6.3% by weight of beta-phellandrene, 2.0 to 3.8% by weight of benzaldehyde and 0.9 to 2.7% by weight of sabinol. Also, it contains gamma-terpinene in a range of 2.0 to 6.0 wt%. The main ingredients for reproducing the acid scent are alpha-thujone, beta-thujone, camphor, sabinene, p-cymene, gamma- When gamma-terpinene is used in a range outside the above-described range, the similarity of the fragrance with the country of origin is lowered, and the palatability of the fragrance is also lowered. However, the other components are preferably used within the above-mentioned range, but they do not greatly affect the fragrance of the country of origin, so they may be contained in an amount outside the above range as long as they do not affect the reproduction of the fragrance of the country fragrance.

The composition according to the present invention, which is mixed in the above-described range, may be formulated into a skin external-use base such as perfume, cosmetics, etc., and the blending amount may be appropriately selected and blended according to the conventional art have.

Such external application substrates include, but are not limited to, ointments, lotions, soluble images, suspensions, emulsions, creams, gels, sprays, papings, Can be incorporated into any given base.

Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto, and other applications, modifications and the like of the present invention will be apparent to those skilled in the art.

[ Example ]

[ Reference Example  One] SPME Analysis of the flavor of the country by using the law

The fragrance component was collected by adsorbing the fragrance component to a polyacrylate fiber coated with 85 탆 of polyacrylate for 2 hours. The collection site was collected for 3 hours at Chinbu-myeon, Pyeongchang-gun, Gangwon-do, South Korea.

After capturing the fragrance components, the fiber was sealed, transferred to the inlet of the GC-MS, desorbed for 2 minutes, and subjected to GC-MS analysis. GC-MS analysis conditions are as follows.

Analysis condition

. Analytical instrument: HP 5890 II GC. Detector: HP 5972 MSD

. Column: DB-1 (60 mx 0.25 mm x 0.25 m). Mobile phase gas: He

. Injection temperature: 250 ℃. Detector temperature: 280 ° C

. Oven temperature: 70 캜 to 220 캜 (3 캜 / min). Ionization voltage: 70 eV

. Removal time: 2 minutes

As a result, the flavor components of the acidic rice analyzed by the SPME method are shown in Table 1 below.

Flavor Name Content (% by weight) Alpha-thujone 57.62 Beta-thujone < / RTI > 15.26 Camphor 6.56 Sabinene 6.23 P-cymene < / RTI > 4.48 Alpha-phellandrene < / RTI > 1.45 Beta-phellandrene < / RTI > 1.27 Benzaldehyde < / RTI > 1.16 Sabinol 0.66 Other 5.31 Total content 100.00

As can be seen in Table 1, the country of origin is dominated by alpha-thujone, beta-thujone, camphor, sabinene, p-cymene, And 90.15% by weight of the total of these main components. In this Reference Example 1, a sample of the fragrance component directly collected from the country of origin was designated as Sample A.

[ Test Example  1] The results of the analysis showed that the fragrance Comparative sensory evaluation

Based on the results of the analysis, a newly prepared combined fragrance (Sample B) having the composition shown in the following Table 2 was prepared, and the fragrance similarity of the fragrance and the name of the country designated as Sample A was verified through sensory evaluation.

Flavor Name Content (% by weight) Alpha-thujone 57.62 Beta-thujone < / RTI > 15.26 Camphor 6.56 Sabinene 6.23 P-cymene < / RTI > 4.48 Alpha-phellandrene < / RTI > 1.45 Beta-phellandrene < / RTI > 1.27 Benzaldehyde < / RTI > 1.16 Sabinol 0.66 Dipropyleneglycol 5.31 Total content 100.00

The sensory evaluation was carried out on 20 normal male and female twenties between 20 and 40 years old. Sample fractions of sample fragrance A and fragrant fragrance analyzed by SPME were artificially blended and reproduced, (Question 1) and sample palatability (Question 2) of Sample A and Sample B by responding to the questionnaire of Table 3 below. The results are shown in Table 4 below.

survey
(1) Question 1: How similar is sample A to sample B?
1) It is not at all similar.
2) Not very similar.
3) Just so.
4) Somewhat similar.
5) Very similar.

(2) Question 2: How much do you like the smell of Sample B?
1) Not at all good.
2) Not very good.
3) Just so.
4) Somewhat good.
5) Very good.

Rating agent Question 1 (similarity) Question 2 (palatability) One 3.0 1.0 2 3.0 3.0 3 2.0 3.0 4 3.0 2.0 5 2.0 2.0 6 1.0 3.0 7 2.0 3.0 8 1.0 2.0 9 2.0 2.0 10 2.0 2.0 11 2.0 2.0 12 2.0 3.0 13 3.0 2.0 14 2.0 2.0 15 1.0 2.0 16 1.0 2.0 17 3.0 2.0 18 2.0 3.0 19 2.0 1.0 20 2.0 2.0 Average 2.05 2.2

As shown in Table 4, the sample B of the combination fragrance was much different from the flower fragrance of the country, and the palatability was also low.

[ Test Example  2] Flavor analysis and  With the country of origin Odor comparison

As shown in the above Test Example 1, there was no similarity to the fragrance composition in which the fragrance composition prepared by artificially blending the components analyzed by the SPME method was directly collected from the country of origin.

Therefore, the expert team composed of the irrigation companies performed sensory evaluation on each of the fragrance components of the country. Among the aroma components of the country, alpha-thujone, beta-thujone, camphor, sabinene, and p-cymene were found in the country Which is a major component of the fragrance.

[ Example  1] Production of new combination fragrance according to changes of main ingredient content

From the above Test Example 2, it can be seen that the main ingredient of the original scent of the country of origin is alpha-thujone, beta-thujone, camphor, sabinene and p-cymene. . Therefore, the present inventors made the new combination fragrances of the following # 1 to # 4 in order to prepare fragrance having good taste while showing the fragrance of the country of origin by containing these five ingredients.

Combination fragrances # 1 to # 4 were prepared by varying the total content of the five fragrances to 60 to 90% by weight while maintaining the ratio of these five ingredients constant (see Table 5).

[ Test Example  3] Example  Sensory evaluation of flavors prepared in 1

The similarity and palatability to the four fragrances of the freshly combined Example 1 were compared with those of the acid fruity fragrance by the sensory evaluation in the same manner as in Test Example 1. [ On the other hand, after performing the comparative sensory evaluation on the two combined flavorings, a resting time of 5 minutes was given to avoid post-sensory paralysis. The sensory evaluation results of the new combination fragrance and the fragrance similarity and palatability of the country are shown in Table 6 below.

evaluation
agent Question 1 (similarity) Question 2 (palatability) Combination Spice Number Combination Spice Number #One #2 # 3 #4 #One #2 # 3 #4 One 1.0 3.0 3.0 3.0 2.0 3.0 4.0 3.0 2 2.0 3.0 4.0 3.0 2.0 3.0 2.0 3.0 3 3.0 3.0 3.0 4.0 3.0 3.0 4.0 3.0 4 2.0 2.0 3.0 3.0 2.0 2.0 3.0 3.0 5 2.0 3.0 2.0 3.0 2.0 3.0 3.0 3.0 6 1.0 2.0 4.0 3.0 1.0 2.0 3.0 4.0 7 2.0 3.0 4.0 4.0 2.0 3.0 3.0 2.0 8 2.0 2.0 3.0 3.0 2.0 2.0 3.0 3.0 9 3.0 3.0 4.0 3.0 3.0 3.0 3.0 3.0 10 2.0 2.0 2.0 3.0 2.0 2.0 3.0 3.0 11 2.0 2.0 3.0 4.0 2.0 2.0 4.0 3.0 12 3.0 3.0 4.0 3.0 3.0 3.0 3.0 3.0 13 2.0 3.0 3.0 2.0 2.0 3.0 4.0 4.0 14 3.0 2.0 4.0 3.0 3.0 2.0 3.0 3.0 15 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 16 2.0 2.0 3.0 4.0 2.0 2.0 3.0 4.0 17 2.0 3.0 3.0 3.0 2.0 3.0 4.0 3.0 18 1.0 1.0 3.0 3.0 1.0 1.0 3.0 2.0 19 2.0 3.0 4.0 3.0 2.0 3.0 4.0 3.0 20 2.0 3.0 3.0 2.0 2.0 3.0 4.0 2.0 Average 2.1 2.6 3.3 3.1 2.2 2.6 3.3 3.0

As shown in Table 6 above, Sample # 3, in which the total content of the five major components occupied 80% by weight, was found to have the highest similarity and palatability among the four combined flavors, but the similarity and palatability were not all satisfied Respectively.

[ Example  2] Improvement of fragrance by analysis of professional evaluation team Manufacture of perfume

Beta-thujone, beta-thujone, and beta-thujone as in Sample # 3, in order to improve the similarity and palatability of the fragrance of Sample # 3, A total of 80% by weight of camphor, sabinene and p-cymene was contained and a new combination of gamma-terpinene (artificial synthetic material) To prepare a perfume. The content of the artificial synthetic material gamma-terpinene was varied while changing the contents to 1.0 wt%, 1.5 wt%, 2.0 wt%, 2.5 wt%, 3.0 wt% and 3.5 wt% It was adjusted to a total content of 100 according to the change of the content of the substance. The composition of these recombinant perfumes is shown in Table 7 below.

[ Test Example  4] Example  Sensory evaluation of the combination fragrances prepared in 2

The perfume similarity and palatability of the six countries (#, #, #, #, #, # bar) in Example 2 were measured for sensory evaluation in the same manner as in Test Example 1 Lt; / RTI > On the other hand, after performing the comparative sensory evaluation on the two combined flavorings, a resting time of 5 minutes was given to prevent the post sensory paralysis phenomenon. The sensory evaluation results of the new combination fragrance and the similarity and palatability of fragrance with the country of origin are shown in Table 8 below.

evaluation
agent Question 1 (similarity) Question 2 (palatability) Combination Spice Number Combination Spice Number #end #I #All #la #hemp #bar #end #I #All #la #hemp #bar One 4.0 3.0 4.0 5.0 4.0 3.0 2.0 4.0 4.0 3.0 4.0 4.0 2 4.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 3.0 3 4.0 3.0 4.0 4.0 4.0 4.0 3.0 4.0 3.0 4.0 4.0 3.0 4 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0 3.0 3.0 5 3.0 4.0 3.0 4.0 3.0 3.0 3.0 4.0 3.0 3.0 4.0 3.0 6 3.0 3.0 3.0 4.0 4.0 3.0 4.0 4.0 4.0 5.0 3.0 2.0 7 3.0 3.0 4.0 5.0 3.0 4.0 3.0 3.0 3.0 5.0 4.0 3.0 8 3.0 4.0 4.0 4.0 3.0 4.0 3.0 4.0 3.0 4.0 3.0 3.0 9 3.0 2.0 3.0 5.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 10 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 11 3.0 3.0 4.0 4.0 4.0 3.0 4.0 4.0 3.0 4.0 4.0 3.0 12 3.0 4.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 13 4.0 4.0 4.0 4.0 4.0 3.0 4.0 3.0 3.0 4.0 3.0 4.0 14 3.0 3.0 3.0 4.0 3.0 4.0 3.0 4.0 3.0 3.0 3.0 4.0 15 3.0 3.0 3.0 5.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 16 3.0 4.0 3.0 5.0 3.0 3.0 4.0 4.0 3.0 5.0 4.0 4.0 17 3.0 3.0 4.0 5.0 4.0 4.0 2.0 3.0 4.0 5.0 3.0 4.0 18 2.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 19 3.0 3.0 3.0 3.0 3.0 4.0 3.0 4.0 3.0 5.0 3.0 3.0 20 2.0 4.0 3.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 4.0 Average 3.1 3.4 3.5 4.2 3.6 3.4 3.2 3.6 3.5 4.0 3.5 3.4

As can be seen from Table 8 above, it is possible to use a variety of phytoplankton such as alpha-thujone, beta-thujone, camphor, sabinene, p-cymene, When 4 weight% of gamma-terpinene was contained in the main fragrance ingredient, it was confirmed that fragrance of the country of origin can be best reproduced and excellent similarity and palatability are exhibited.

[ Manufacturing example ]

The fragrance composition (# a) having similarity to the fragrance of the country of origin as described above was blended to produce the perfume of Table 9 below.

(Content:% by weight) containing the perfume composition reproducing the fragrance of the country of origin, Spices reproduce fragrance
Alcohol
water
Pigment
Sunscreen 15
To 80
Suitable amount
Suitable amount
Suitable amount

Claims (6)

A fragrance composition recreating the fragrance of a country of origin containing an odor component of a country and gamma-terpinene as an active ingredient,
The fragrance components of the acid bacterium are alpha-thujone, beta-thujone, camphor, sabinene and p-cymene,
The fragrance composition may contain alpha-thujone of 47.0 to 57.0 wt%, beta-thujone of 10.0 to 16.0 wt%, camphor of 3.4 to 7.4 wt% based on the total weight of the composition, wherein the perfume composition comprises 2.8 to 6.5% by weight of at least one flavorant selected from the group consisting of flavin, sabinene, p-cymene, and gamma-terpinene in an amount of 2.4 to 5.4% by weight and gamma-terpinene in an amount of 2.0 to 6.0% by weight. delete The composition according to claim 1, further comprising alpha-phellandrene, beta-phellandrene, benzaldehyde and sabinol in the composition Perfume composition. delete The perfume composition of claim 3, wherein the perfume composition comprises from 3.9 to 7.9 wt% alpha-phellandrene, from 3.3 to 6.3 wt% beta-phellandrene, from benzaldehyde benzaldehyde in an amount of 2.0 to 3.8% by weight and sabinol in an amount of 0.9 to 2.7% by weight. The composition for external application for skin, which comprises the perfume composition of any one of claims 1, 3 and 5.