KR102610348B1 - Perfume composition for reproducibly expressing the fragrance of Magnolia sieboldii K. Koch - Google Patents

Abstract

The present invention relates to a fragrance composition that reproduces the fragrance of fennel flowers, and more specifically, Benzyl alcohol and methyl trans-4-decenoate, which were analyzed as fragrance components of lanceolate flowers by SPME method. -decenoate), Methyl caprinate, Methyl caprylate, Methyl benzoate, etc. by adding benzaldehyde to a fragrance composition that reproduces the scent of the highly palatable fennel flower. It's about.
The fragrance composition according to the present invention contains benzaldehyde along with the main components of the scent of fennel flowers such as benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate, thereby enhancing the scent of turmeric flowers. It can be reproduced, and the palatability of the scent can also be improved.

Description

Perfume composition for reproducibly expressing the fragrance of Magnolia sieboldii K. Koch}

The present invention relates to a fragrance composition that reproduces the fragrance of fennel flowers, and more specifically, Benzyl alcohol and methyl trans-4-decenoate, which were analyzed as fragrance components of lanceolate flowers by SPME method. -decenoate), Methyl caprinate, Methyl caprylate, Methyl benzoate, etc. by adding benzaldehyde to a fragrance composition that reproduces the scent of the highly palatable fennel flower. It's about.

Magnolia sieboldii K. Koch is a small deciduous tree that grows wild throughout Korea. The growing environment is where water drains well and soil fertility is high. It is about 3 to 7 meters tall, and the leaves are 6 to 15 cm long and 5 to 10 cm wide. The surface is glossy and hairless, and the back side is grey-green with hairs along the veins. The flowers are white, 7 to 10 cm in diameter, and the anthers and stamens are red and have a strong scent.

The English name is 'Magnolia sieboldii K. Koch' , and it grows relatively commonly in mountain forests across the country, and is also called 'mountain magnolia', meaning 'magnolia that grows on the mountain'. In North Korea, it is called 'makran' and is designated as the national flower. Although it can be easily found in the mountains of Korea, not much is known about its scent, and despite its considerable value as a perfume, scientific research is lacking.

There can be several ways to reproduce the scent of hambac flowers. For example, common methods include a solvent extraction method that converts the fragrant components of the fennel flower into absolute oil and a steam distillation method that converts the fragrant components into essential oil. However, the above methods require high heat to be applied during the extraction process and the processing process is complicated and takes a lot of time, so there may be a significant difference from the original fragrance, and in the case of hamburger flowers, which are not numerous in number, sufficient raw materials cannot be supplied. It has limitations that make it difficult to do.

Recently, in order to compensate for these shortcomings, head space methods including SPME method (Solid Phase Micro Extraction; SUPELCO international, Vol.13, No.4, p.9-10) have been developed. It has been done. Unlike existing extraction methods, the headspace method does not use solvents and does not require pretreatment, so it has the advantage of being able to analyze odor components quickly and easily. On the other hand, fragrance components with high volatility are easy to analyze, but fragrance components with low volatility or high molecular weight also have the disadvantage of being difficult to analyze using this method.

Meanwhile, GC (Gas Chromatography) is a very useful instrumental analysis for qualitative and quantitative analysis of volatile substances, so it is widely used in the analysis of all fragrance components. However, while there are some fragrance components that have a very low threshold value and express a strong scent even at low concentrations, there are also volatile components that have a very high threshold value and cannot express scent even at high concentrations. Therefore, it cannot be said that the volatile components found quantitatively through GC are necessarily the main odor components of a specific substance. To solve this problem, the GC-O (Gas Chromatography Olfactometry, Guth H, Grosch W (1993) Lebensm Wiss U Technol, 196, 22-28) method has been developed and used. GC-O is a method of analyzing scent components through peaks in a chromatogram and at the same time smelling the scent directly to identify components that do not appear as peaks but actually produce scent.

Domestic Patent Application No. 2007-0037741

Therefore, the present inventors attempted to reproduce the scent of the fennel flower by using the SPME method, which is effective in analyzing scent substances in living natural products. It was not possible to reproduce the fragrance of the fennel flower using only the main components of the fragrance analyzed by the SPME method, but when benzaldehyde was used together, it was discovered that the unique scent of the fennel flower could be reproduced and that it showed excellent palatability, and the present invention was completed.

Therefore, the purpose of the present invention is to provide a fragrance composition that reproduces the unique scent of Hambac flower.

In addition, another object of the present invention is to provide a composition for external application to the skin containing the above-mentioned fragrance composition.

In order to achieve the above object, a fragrance composition that reproduces the fragrance of hamburger flowers containing fragrant components of hamburger flowers and benzaldehyde is provided.

The present invention also provides a composition for external application to the skin containing the above-described fragrance composition.

The fragrance composition according to the present invention contains benzaldehyde along with the main components of the scent of fennel flowers such as benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate, thereby enhancing the scent of turmeric flowers. It can be reproduced, and the palatability of the scent can also be improved.

Figure 1 is a photograph showing the process of sealing the fennel flower and adsorbing the scent component to polyacrylate coated fiber to capture the scent of the fennel flower.

Unless otherwise defined, all technical and scientific terms used in this specification have the same meaning as commonly understood by a person skilled in the art to which the present invention pertains. In general, the nomenclature used herein is well known and commonly used in the art.

The present invention relates to Benzyl alcohol, Methyl trans-4-decenoate, Methyl caprinate, Methyl caprylate, and It relates to a fragrance composition that reproduces the scent of fennel flower containing methyl benzoate and benzaldehyde as active ingredients.

In addition, the fragrance composition may further contain myrcene, phenyl ethyl alcohol, methyl laurate, Sabinene, and Hexanal. there is.

Hereinafter, the present invention will be described in more detail.

The composition according to the present invention contains benzaldehyde, an artificial synthetic substance, as an essential ingredient along with the fragrance component of hamburger flowers, so that it can reproduce the unique scent of hamburger flowers, increase the similarity in scent with actual hamburger flowers, and exhibit excellent palatability.

Benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, methyl benzoate, etc. can be used as the main ingredients among the fragrance ingredients of the fennel flower of the present invention, and myrcene as a secondary ingredient. , phenylethyl alcohol, methyl laurate, sabinene, hexanal, etc. can be used.

The fragrance composition according to the present invention contains 30 to 42% by weight of benzyl alcohol, preferably 30.7 to 36.7% by weight, and 4.7 to 14.7% by weight of methyl trans-4-decenoate, preferably 8% by weight, based on the total weight of the composition. ~14% by weight, 4.5~14.5% by weight of methyl caprinate, preferably 7~13% by weight, 3.7~13.7% by weight of methyl caprylate, preferably 6~12% by weight, 3.4~12% by weight of methyl benzoate. 13.4% by weight, preferably 5 to 11% by weight, myrcene at 3 to 9% by weight, phenylethyl alcohol at 2.5 to 8% by weight, methyl laurate at 2 to 7% by weight, and sabinene at 1.5 to 5% by weight. , it may contain hexanal in the range of 1 to 3.3% by weight, and benzaldehyde in the range of 1.2 to 5% by weight, preferably in the range of 2.7 to 3.9% by weight.

Benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, methyl benzoate, and benzaldehyde, which are the main ingredients for reproducing the scent of Hamburger flower, may cause harm to Hamburger flower if used outside the above range. This is undesirable because the similarity in scent decreases and the palatability of the scent also decreases. However, other secondary ingredients such as myrcene, phenylethyl alcohol, methyl laurate, sabinene, and hexanal are preferably used within the above range, but do not significantly affect the scent of hamburger flowers, so they It may be contained in amounts outside the above range as long as it does not affect reproduction.

Additionally, the present invention relates to a composition for external application to the skin containing the above-described fragrance composition. The fragrance composition according to the present invention includes perfume, softening lotion, astringent lotion, nourishing lotion, eye cream, nourishing cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence, shampoo, rinse, pack, ointment, lotion, It can be formulated in skin external bases including cosmetics such as soluble burns, suspension, emulsion, cream, gel, spray, patch, warning agent, patch, or water paste, but is not limited to these, and is not limited to any product well known in the art. It can also be formulated for external use. The mixing amount can be appropriately selected and mixed to achieve the desired effect according to techniques common in the art.

Additionally, the present invention relates to a fragrance article containing the above fragrance composition. The fragrance composition according to the present invention can be commercialized as a fragrance product by being included in air fresheners, deodorants, oils, gels, beads, plug-ins, etc., including diffusers, candles, room sprays, etc., but is not limited thereto.

Meanwhile, in the present invention, the SPME method can be used as an analysis method for the aroma components of Hambac flowers. The SPME method is advantageous for analyzing the highly volatile aroma components of the fennel flower because the aroma components adsorbed on the fiber can be quickly desorbed and injected into the GS-MS column without any special pretreatment, and the analysis time can be greatly shortened. . In addition, the SPME method is simple and easy to concentrate compared to existing pretreatment methods, is not limited by the form of the matrix, and does not use organic solvents, so it can significantly reduce sample contamination and by-product generation rates, thereby contributing to the results. It has the advantage of increasing credibility.

In the present invention, a combination fragrance was formulated based on the fragrance components of the fennel flower analyzed by the SPME method, and the similarity to the scent of the fennel flower and the palatability of the scent were tested through olfactory sensory tests. Sensory tests were conducted by professional perfumers and the general public, and the similarity to the scent of Hambac flower and the preference of the scent were evaluated through a survey.

Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not to be construed as limited by these examples. Accordingly, the actual scope of the present invention will be defined by the appended claims and their equivalents.

[Reference Example 1] Analysis of the fragrance of Hambac flowers using SPME method

After selecting a flower with a strong scent and sealing it as shown in Figure 1, the scent ingredient was captured by adsorbing it on 85㎛ polyacrylate-coated fiber for 2 hours. The capture was conducted for 3 hours in Pyeongchang-gun, Gangwon-do.

After collecting the scent components, the fiber was sealed, transferred to the inlet of the GC-MS, desorbed for 2 minutes, and GC-MS analysis was performed. GC-MS analysis conditions are as follows.

Analysis conditions

. Analytical instrument: HP 5890 II GC

. Detector: HP 5972 MSD

. Column: DB-1 (60m

. Carrier Gas: He

. Injection Temperature: 250 ℃

. Detector Temperature: 280 ℃

. Oven Temperature: 70℃~220℃ (3℃/min)

. Ionization Voltage: 70eV

. Desorption time: 2 minutes

As a result, the fragrance components of Hambac flower analyzed by SPME method were as shown in Table 1 below.

Fragrance name content(%) Benzyl alcohol 35.08 Methyl trans-4-decenoate 10.11 methyl caprinate 9.84 methyl caprylate 9.02 methyl benzoate 8.71 myrcene 4.11 phenyl ethyl alcohol 3.96 methyl laurate 3.16 Sabinen 2.53 Hexanal 1.72 etc 11.76 Total content 100.0

As shown in Table 1, the main aromatic components of Hambac flower include benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate, and these major components account for 72.76 of the total. It was confirmed that it accounted for % by weight.

[Test Example 1] Comparative sensory evaluation between the fragrance composition as a result of analysis and the natural hamburger flower fragrance

Based on the results analyzed in Reference Example 1, a newly prepared combination perfume (sample B) having the composition shown in Table 2 below was prepared, and the similarity in scent between this perfume and natural Hambac flower (sample A) was verified through sensory evaluation.

Fragrance name content(%) Benzyl alcohol 35.08 Methyl trans-4-decenoate 10.11 methyl caprinate 9.84 methyl caprylate 9.02 methyl benzoate 8.71 myrcene 4.11 phenyl ethyl alcohol 3.96 methyl laurate 3.16 Sabinen 2.53 Hexanal 1.72 DPG(solvent) 11.76 Total content 100.0

Sensory evaluation was conducted on 20 men and women aged 20 to 45. They were asked to smell the scent of sample A of the fragrance component collected directly from the fennel flower in Reference Example 1 above and sample B of the combined fragrance reproduced by the SPME method. And, by answering the questionnaire shown in Table 3 below, the similarity in scent (Question 1) and preference of scent (Question 2) between Sample A and Sample B were surveyed (evaluated) by scoring on a 7-point scale. The results are shown in Table 4 below.

survey

(1) Question 1: How similar are the scents of Sample A and Sample B?

Response: [1] Not similar at all---[3] So-so---[7] Very similar

(2) Question 2: How much do you like the scent of sample B?

Response: [1]Not good at all---[3]So-so---[7]Very good

evaluation agent Question 1 (Similarities) Question 2 (palatability) One 2 4 2 4 2 3 2 3 4 4 4 5 4 3 6 4 2 7 4 4 8 3 One 9 4 4 10 4 2 11 2 4 12 One 4 13 4 2 14 4 4 15 4 3 16 2 4 17 4 2 18 4 One 19 2 3 20 4 4 average 3.3 3.0

As shown in Table 4 above, as a result of evaluation on a 7-point scale, it was confirmed that Sample B, a combination fragrance, was significantly different from the scent of natural Hambac flowers and had low palatability.

[Test Example 2] Fragrance analysis by a professional evaluation group and comparison of scent with Hambac flower

As shown in Test Example 1, the fragrance composition artificially mixed with the ingredients analyzed by SPME method had very low similarity to the fragrance collected directly from the fennel flower.

Accordingly, a professional evaluation group consisting of perfumers performed a sensory evaluation of each fragrant component of the hambac flower. As a result, among the fragrant components of the fennel flower, benzyl alcohol, which produces a mild sweet scent, methyl trans-4-decenoate, which produces a fruity green scent, and winey fruity scent. Five ingredients, including methyl caprinate, which creates a fragrant scent, methyl caprylate, which creates a citrus fruity scent, and methyl benzoate, which creates a deep floral scent, create the unique scent of fennel flower. It was confirmed that it was the main ingredient.

[Example 1] Manufacture of new combination flavor according to changes in content of five main ingredients

From Test Example 2, it was confirmed that the main components of the unique fragrance of the fennel flower were composed of benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate. Therefore, the present inventors prepared new combination fragrances #1 to #4 as shown in Table 5 below in order to produce a fragrance that contains these five ingredients and has good palatability while retaining the fragrance of the lanceolate flower.

Combination fragrances #1 to #4 were manufactured by changing the total content of the five spices to 60-90% by weight while keeping the ratio of these five main ingredients constant (unit: weight%). The specific composition is shown in Table 5 below.

Fragrance name #One #2 #3 #4 (60% by weight) (70% by weight) (80% by weight) (90% by weight) Benzyl alcohol 28.9 33.7 38.6 43.4 Methyl trans-4-decenoate 8.3 9.7 11.1 12.5 methyl caprinate 8.1 9.5 10.8 12.2 methyl caprylate 7.4 8.7 9.9 11.2 methyl benzoate 7.2 8.4 9.6 10.8 myrcene 10.6 8 5.3 2.7 phenyl ethyl alcohol 10.2 7.7 5.1 2.5 methyl laurate 8.4 6.1 4.1 2 Sabinen 6.5 4.9 3.3 1.6 Hexanal 4.4 3.3 2.2 1.1 total content 100.0 100.0 100.0 100.0

[Test Example 3] Sensory evaluation of the fragrances prepared in Example 1 above

The four newly combined fragrances (#1 to #4) of Example 1 were subjected to sensory evaluation in the same manner as Test Example 1 to determine the similarity and palatability with the scent of fennel flower. Meanwhile, after conducting a comparative sensory evaluation of the two combined fragrances, a 5-minute break was given to prevent olfactory paralysis. The results of the sensory evaluation regarding the odor similarity and palatability of the new combination fragrance and Hambac flower are shown in Table 6 below.

evaluation
agent Question 1 (similarity) Question 2 (palatability) Combination flavor number Combination flavor number #One #2 #3 #4 #One #2 #3 #4 One 3.0 4.0 4.0 1.0 3.0 4.0 4.0 2.0 2 3.0 4.0 4.0 3.0 3.0 6.0 5.0 4.0 3 4.0 5.0 4.0 4.0 4.0 5.0 4.0 4.0 4 3.0 4.0 4.0 4.0 3.0 4.0 3.0 3.0 5 4.0 4.0 4.0 3.0 3.0 5.0 4.0 4.0 6 4.0 4.0 4.0 4.0 3.0 4.0 3.0 3.0 7 3.0 5.0 4.0 4.0 4.0 5.0 4.0 4.0 8 3.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 9 4.0 5.0 4.0 4.0 4.0 4.0 4.0 4.0 10 3.0 4.0 4.0 3.0 3.0 4.0 3.0 3.0 11 3.0 5.0 4.0 4.0 4.0 5.0 4.0 3.0 12 2.0 4.0 4.0 3.0 4.0 4.0 3.0 5.0 13 3.0 5.0 4.0 4.0 3.0 5.0 4.0 4.0 14 3.0 4.0 4.0 3.0 4.0 4.0 4.0 3.0 15 4.0 6.0 5.0 4.0 4.0 4.0 4.0 4.0 16 3.0 5.0 3.0 3.0 3.0 4.0 3.0 3.0 17 2.0 4.0 3.0 4.0 4.0 5.0 5.0 4.0 18 2.0 3.0 2.0 3.0 2.0 4.0 3.0 3.0 19 4.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 20 3.0 4.0 4.0 4.0 4.0 3.0 4.0 4.0 average 3.2 4.4 3.9 3.5 3.5 4.4 3.8 3.6

As shown in Table 6 above, as a result of evaluation on a 7-point scale, sample #2, which has a total content of 70% by weight of the five main ingredients among the aroma components of Hambac flower, was found to have the best similarity and preference among the four combined fragrances. It was shown. However, both similarity and preference were found to fall short of expectations.

[Example 2] Manufacture of fragrance improving fragrance according to analysis by professional evaluation team

In order to improve the similarity and palatability of the fragrance of sample #2, which was shown to be most similar to the fragrance of the fennel flower in Table 6, as shown in Table 7 below, benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, Methyl caprylate and methyl benzoate were maintained at a content of 70% by weight (same as sample #2 in Table 6), and benzaldehyde, an artificial synthetic substance, was further added to create a new combination of #A to #. Fragrance samples were prepared.

At this time, the content standard for benzaldehyde was set based on the judgment of a group of perfumer experts, and benzaldehyde was set at 0.9% by weight, 1.5% by weight, 2.1% by weight, 2.7% by weight, 3.3% by weight, 3.9% by weight, and 4.5% by weight. It was added while changing, and other ingredients were adjusted to adjust the total content to 100 according to the change in benzaldehyde content. The composition of these recombinant fragrances is shown in Table 7 below.

Combination flavor number #go #me #all #la #mind #bar #buy Fragrance name content(%) content(%) content(%) content(%) content(%) content(%) content(%) Benzyl alcohol 33.7 33.7 33.7 33.7 33.7 33.7 33.7 Methyl trans-4-decenoate 9.7 9.7 9.7 9.7 9.7 9.7 9.7 methyl caprinate 9.5 9.5 9.5 9.5 9.5 9.5 9.5 methyl caprylate 8.7 8.7 8.7 8.7 8.7 8.7 8.7 methyl benzoate 8.4 8.4 8.4 8.4 8.4 8.4 8.4 myrcene 7.9 7.8 7.7 7.6 7.5 7.4 7.3 phenyl ethyl alcohol 7.4 7.3 7.1 6.9 6.8 6.7 6.6 methyl laurate 6.0 5.9 5.8 5.7 5.5 5.4 5.3 Sabinen 4.7 4.6 4.5 4.4 4.3 4.1 4.0 Hexanal 3.1 2.9 2.8 2.7 2.6 2.5 2.3 Benzaldehyde 0.9 1.5 2.1 2.7 3.3 3.9 4.5 Total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[Comparative example] Manufacture of recombinant fragrance adding artificial synthetic substances other than benzaldehyde

The content of the five main fragrance ingredients was the same as in Example 2, and instead of adding benzaldehyde as an artificial synthetic substance, 3.3% by weight of Linalool or Geraniol, an artificial synthetic substance, was added. Samples #A and # were prepared with the compositions shown in Table 8 below.

Combination flavor number #ah #ruler Fragrance name content(%) content(%) Benzyl alcohol 33.7 33.7 Methyl trans-4-decenoate 9.7 9.7 methyl caprinate 9.5 9.5 methyl caprylate 8.7 8.7 methyl benzoate 8.4 8.4 myrcene 7.5 7.5 phenyl ethyl alcohol 6.8 6.8 methyl laurate 5.5 5.5 Sabinen 4.3 4.3 Hexanal 2.6 2.6 Linalool 3.3 - Geraniol - 3.3 Total content 100.0 100.0

[Test Example 4] Sensory evaluation of the combined fragrances prepared in Example 2 and Comparative Example

In order to determine the similarity of fragrance with the hamburger flower and the palatability of the fragrance of the seven combination fragrances (#A to #Sa) of Example 2 and the two combination fragrances of Comparative Example (#A, #A), Sensory evaluation was conducted in the same manner as Test Example 1 above. Meanwhile, after conducting a comparative sensory evaluation of the two combined fragrances, a 5-minute break was given to prevent olfactory paralysis. The sensory evaluation results for scent similarity and scent preference between the new combination fragrance and Hambac flower are shown in Tables 9 and 10 below.

evaluation agent Question 1 (similarity) Question 2 (palatability) Combination flavor number Combination flavor number #go #me #all #la #mind #bar #buy #go #me #all #la #mind #bar #buy One 4.0 5.0 5.0 5.0 4.0 4.0 4.0 3.0 4.0 4.0 5.0 6.0 5.0 3.0 2 3.0 5.0 5.0 6.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 3 4.0 4.0 4.0 5.0 5.0 5.0 4.0 4.0 5.0 5.0 5.0 6.0 5.0 4.0 4 4.0 4.0 4.0 5.0 5.0 4.0 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 5 5.0 5.0 5.0 6.0 5.0 5.0 5.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 6 4.0 4.0 4.0 5.0 5.0 4.0 4.0 5.0 5.0 5.0 4.0 4.0 5.0 4.0 7 4.0 4.0 5.0 4.0 6.0 5.0 5.0 4.0 4.0 5.0 4.0 5.0 6.0 4.0 8 4.0 5.0 5.0 5.0 5.0 4.0 4.0 4.0 5.0 4.0 5.0 5.0 4.0 4.0 9 3.0 3.0 4.0 4.0 5.0 5.0 4.0 3.0 4.0 4.0 4.0 5.0 5.0 3.0 10 4.0 4.0 4.0 5.0 5.0 5.0 4.0 4.0 5.0 4.0 5.0 6.0 5.0 4.0 11 3.0 5.0 5.0 5.0 5.0 6.0 5.0 3.0 4.0 5.0 4.0 5.0 4.0 4.0 12 4.0 4.0 5.0 5.0 6.0 5.0 4.0 5.0 4.0 5.0 5.0 6.0 5.0 4.0 13 3.0 5.0 5.0 5.0 6.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 14 4.0 4.0 4.0 6.0 6.0 5.0 4.0 4.0 4.0 5.0 6.0 6.0 5.0 5.0 15 5.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 5.0 4.0 5.0 5.0 4.0 4.0 16 4.0 5.0 5.0 5.0 5.0 6.0 4.0 4.0 4.0 4.0 4.0 5.0 5.0 5.0 17 3.0 4.0 4.0 5.0 6.0 5.0 3.0 3.0 4.0 5.0 6.0 5.0 4.0 5.0 18 5.0 4.0 5.0 5.0 5.0 6.0 4.0 4.0 5.0 4.0 6.0 6.0 4.0 4.0 19 4.0 4.0 4.0 4.0 5.0 5.0 4.0 4.0 5.0 5.0 5.0 5.0 4.0 4.0 20 3.0 4.0 5.0 5.0 6.0 5.0 4.0 4.0 4.0 4.0 4.0 5.0 4.0 4.0 average 3.9 4.3 4.6 5 5.2 4.9 4.1 3.9 4.4 4.4 4.8 5.2 4.6 4.0

evaluation agent
Question 1 (similarity) Question 2 (palatability) Combination flavor number Combination flavor number #ah #ruler #ah #ruler One 4.0 3.0 3.0 2.0 2 4.0 2.0 3.0 3.0 3 3.0 3.0 3.0 3.0 4 3.0 3.0 3.0 3.0 5 4.0 4.0 4.0 3.0 6 3.0 3.0 3.0 4.0 7 3.0 3.0 4.0 3.0 8 4.0 3.0 3.0 3.0 9 2.0 2.0 3.0 2.0 10 3.0 3.0 3.0 3.0 11 4.0 2.0 4.0 2.0 12 3.0 3.0 3.0 4.0 13 4.0 2.0 3.0 3.0 14 3.0 3.0 3.0 3.0 15 3.0 4.0 3.0 3.0 16 4.0 3.0 3.0 3.0 17 3.0 2.0 2.0 2.0 18 3.0 4.0 3.0 3.0 19 3.0 3.0 3.0 3.0 20 3.0 2.0 3.0 3.0 average 3.3 2.9 3.1 2.9

As shown in Table 9 above, as a result of evaluation on a 7-point scale, the main aromatic components of Hamburga flower, such as benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate, In the case of #na, #da, #la, #ma, and #bar containing benzaldehyde in the range of 1.5 to 3.9% by weight, it was confirmed that the similarity in fragrance and palatability were high (average score 4.3 to 5.2). In particular, in the case of #la, #hemp, and #bar, which contain benzaldehyde in the range of 2.7 to 3.9% by weight, it can be confirmed that the scent similarity and scent palatability with hamburger flowers are very excellent, and the scent of hamburger flowers can be well reproduced. There was (average score 4.6-5.2).

On the other hand, it was found that when benzaldehyde was contained in an amount of less than 1.5% by weight or more than 3.9% by weight, the similarity of fragrance and palatability were lowered.

In addition, as shown in Table 10 above, as a result of evaluation on a 7-point scale, when the artificial synthetic material contains 3.3% by weight of linalool or geraniol rather than benzaldehyde, the similarity and palatability are higher than those containing benzaldehyde. It was found that it was significantly lower than in the case of From this, it was confirmed that benzaldehyde is the most suitable artificial synthetic material that can maximize palatability while reproducing the scent of turmeric flowers.

[Formulation example]

As described above, a fragrance composition (#E in Table 7 above) having similarity to the scent of hambac flower was mixed to prepare the perfume shown in Table 11 below.

Perfume containing a fragrance composition that reproduces the scent of turmeric flowers Combination fragrance that reproduces the scent of Hambak flower
Alcohol
water
pigment
sunscreen 15% by weight
83% by weight
2% by weight
Appropriate amount
Appropriate amount

As the specific parts of the present invention have been described in detail above, it is clear to those skilled in the art that these specific techniques are merely preferred embodiments and do not limit the scope of the present invention. something to do. Accordingly, the substantial scope of the present invention will be defined by the appended claims and their equivalents.

Claims (8)

A fragrance composition that reproduces the fragrance of Hamburger flowers and contains benzaldehyde as an active ingredient,
The fragrance components of the hamburger flower include benzyl alcohol, methyl trans-4-decenoate, methyl caprinate, methyl caprylate, and methyl benzoate. It is composed of methyl benzoate,
A fragrance composition that reproduces the scent of hamburger flowers, characterized in that the benzaldehyde is contained in an amount of 1.5 to 3.9% by weight based on the total weight of the composition. The method of claim 1, wherein the fragrance composition further contains myrcene, phenyl ethyl alcohol, methyl laurate, Sabinene, and Hexanal. A fragrance composition that reproduces the characteristic scent of turmeric flowers. The method of claim 1, wherein the fragrance composition contains 30 to 42% by weight of benzyl alcohol, 4.7 to 14.7% by weight of methyl trans-4-decenoate, 4.5 to 14.5% by weight of methyl caprinate, and methyl caprylate, based on the total weight of the composition. A fragrance composition that reproduces the scent of Hambac flower, characterized in that it contains 3.7 to 13.7% by weight, and 3.4 to 13.4% by weight of methyl benzoate. The method of claim 2, wherein the fragrance composition contains 3 to 9% by weight of myrcene, 2.5 to 8% by weight of phenyl ethyl alcohol, 2 to 7% by weight of methyl laurate, 1.5 to 5% by weight of sabinene, and A fragrance composition that reproduces the scent of turmeric flowers, characterized in that it contains 1 to 3.3% by weight of hexanal. A composition for external application to the skin containing the fragrance composition of any one of claims 1 to 4. A fragrance article containing the fragrance composition of any one of claims 1 to 4. delete delete