JP2019147942A - Aroma composition reproducing cymbidium aroma pink flavor - Google Patents
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Abstract
Description
本発明は、シンビジウムアロマピンクの香りを再現し得る香料組成物に関するもので、シンビジウムアロマピンク固有の香りとの類似性及び満足度が改善された香料組成物に関する。 The present invention relates to a fragrance composition capable of reproducing the scent of cymbidium aroma pink, and relates to a fragrance composition having improved similarity and satisfaction with the scent unique to cymbidium aroma pink.
シンビジウム（Ｃｙｍｂｉｄｉｕｍ）は、西洋ランの一種であって、春から秋まで育ち、冬には生育が止まる。シンビジウムという名前は、船を意味するラテン語「ｃｙｍｂａ」から起因した。つぼみが大きく丸くてまるで水の上に浮かんでいる船を連想させるという意味で名前が付けられた。大きい花と絢爛たる色彩を誇るシンビジウムは、根を地に下ろす地生ランであって、亜熱帯気候のアジア地域（インド北部、中国、日本、マレーシア、フィリピン、ボルネオ及びヒマラヤ山岳地帯）とオーストラリア北部に自生することが知られている。種によって約６０〜９０ｃｍまで育ち、約５〜１０ｃｍサイズの花がつく。一回に１５個以上の花が咲き、花色は、白色、緑色、黄緑色、黄色、茶色、ピンク、赤色、黒色に至るまで多様である。 Cymbidium is a type of Western orchid that grows from spring to autumn and stops growing in winter. The name cymbidium was derived from the Latin word “cymba” meaning ship. The name was given in the sense that the buds are large and round, reminiscent of a ship floating on the water. Cymbidium, boasting large flowers and dark colors, is a terrestrial orchid rooted in the subtropical climate of Asia (North India, China, Japan, Malaysia, Philippines, Borneo and Himalayan Mountains) and northern Australia. It is known to grow naturally. It grows up to about 60-90 cm depending on the seed, and has about 5-10 cm size flowers. More than 15 flowers bloom at a time, and the flower color varies from white, green, yellowish green, yellow, brown, pink, red, black.
シンビジウムは、イギリスのビクトリア女王時期から人気のあるランになった。夏には花を咲かせにくいが、冬にはよく開花するので卒業式や入学式で花束でたくさん用いられる。また、礼服に飾りで用いるコルサージュを作るためにもたくさん用いられる。このように活用度が多様なシンビジウムは、ラン市場で独歩的な位相を占め、大韓民国で胡蝶蘭（ファレノプシス）とともに売上高を基準として６０％の市場を占めている。 Cymbidium has become a popular run since the Queen Victoria period in England. It is difficult to bloom in summer, but often blooms in winter, so it is often used in bouquets at graduation and entrance ceremonies. It is also used in many ways to make corsages that can be used as ornaments for dress. Cymbidium, which is used in various ways, occupies a monopolistic phase in the orchid market, and occupies 60% of the market in Korea along with Phalaenopsis.
シンビジウムのアロマピンクの品種は、ラッキーレインボーラパンホット（ＬｕｃｋｙＲａｉｎｂｏｗ‘Ｌａｐｉｎ Ｈｏｔ’）とエブレネウム（Ｅｂｕｒｎｅｕｍ）を交配して２００１年から２０１０年まで系統的に養成及び選抜された後、２０１１年から２０１６年まで特性検定を経て品種化された。白色に花房の一部が淡いピンクをたたえ、盾板の中が黄色をたたえているため、全体的に派手な感じを与える中型種として、花数は少ないが、シンビジウムエブレネウム原種の香り特性を一部有している。花サイズは小さく丸い花形を有する。３月頃に開花する晩生種であり、施設栽培作物として施設内の温度が１５℃の範囲であれば、全国とこでも栽培ができる。エブレネウムと比較して花が美しく香りもさらにすぐれたものとして知られている。そして、シンビジウムアロマピンクの香りをそのまま再現することにより差別化された新しい特徴を有する香り組成物の開発が求められている。 Cymbidium aroma pink varieties were systematically trained and selected from 2001 to 2010 by crossing LuckyRainbow 'Lappin Hot' and Ebreneum, and from 2011 to 2016 It was cultivated through a characteristic test. The white floret has a light pink color and the shield plate has a yellow color. It has a part. The flower size has a small round flower shape. It is a late-flowering species that blooms around March and can be cultivated anywhere in the country as long as the temperature in the facility is in the range of 15 ° C. as a cultivated crop. Compared to Ebreneum, it is known for its beautiful flowers and even better fragrance. And development of the fragrance composition which has the new characteristic differentiated by reproducing the scent of Cymbidium aroma pink as it is is calculated | required.
本発明の発明者らは、シンビジウムアロマピンクの主要香り成分及び含量を分析してシンビジウムアロマピンクの本来の香りを再現しようとした。ただし、上記分析された成分及び含量の組合せのみではシンビジウムアロマピンク固有の香りを再現することが不可能であるため、上記香料に新しい香り成分を添加することによってシンビジウムアロマピンク固有の香りを類似に再現し得ることを確認して、本発明を完成した。 The inventors of the present invention tried to reproduce the original scent of cymbidium aroma pink by analyzing the main scent components and content of cymbidium aroma pink. However, since it is impossible to reproduce the scent unique to Cymbidium Aroma Pink only by the combination of the analyzed components and contents, the scent unique to Cymbidium Aroma Pink can be made similar by adding a new scent component to the above fragrance. After confirming that it can be reproduced, the present invention has been completed.
さて、本発明の目的は、シンビジウムアロマピンク固有の香りを再現し得、優れた選好度を有する香料組成物を提供することにある。 Now, an object of the present invention is to provide a fragrance composition that can reproduce the scent unique to Cymbidium Aroma Pink and has excellent preference.
また、本発明の他の目的は、前記香料組成物を適用した化粧料、香り用製品、皮膚外用剤、パーソナルケア製品及びホームケア製品などを提供することにある。 Another object of the present invention is to provide cosmetics, fragrance products, external preparations for skin, personal care products, home care products, and the like to which the fragrance composition is applied.
本発明は、リナロール（Ｌｉｎａｌｏｏｌ）、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）、オシメン（Ｏｃｉｍｅｎｅ）、ミルセン（Ｍｙｒｃｅｎｅ）、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）及びβ−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）を含有し、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上を含む、シンビジウムアロマピンクの香りを再現した香料組成物を提供する。 The present invention relates to linalool, alpha-farnesene, methyl benzoate, oximene, myrcene, palmitic acid and beta-caryophylene. And a fragrance composition that reproduces the scent of cymbidium aroma pink, comprising at least one selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde.
また、本発明は、前述した香料組成物を含む化粧料、香り用製品、皮膚外用剤、パーソナルケア製品及びホームケア製品を提供する。 The present invention also provides cosmetics, fragrance products, external preparations for skin, personal care products, and home care products containing the above-described fragrance composition.
本発明では、シンビジウムアロマピンクの香り成分の組合せ香料にフロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上の成分を添加することで、香りの類似性及び満足度を著しく改善させ得る。これによって、本発明の組成物は、シンビジウムアロマピンクの香りを再現した香料組成物として有用に用いられる。 In the present invention, the fragrance is obtained by adding one or more components selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde to the combination fragrance of the symbidium aroma pink scent component. Similarity and satisfaction can be significantly improved. Thus, the composition of the present invention is usefully used as a fragrance composition that reproduces the scent of cymbidium aroma pink.
以下、本発明による香料組成物をより詳細に説明する。 Hereinafter, the fragrance composition according to the present invention will be described in more detail.
本発明は、リナロール（Ｌｉｎａｌｏｏｌ）、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）、オシメン（Ｏｃｉｍｅｎｅ）、ミルセン（Ｍｙｒｃｅｎｅ）、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）及びβ−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）を含有し、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上を含む、シンビジウムアロマピンクの香りを再現した香料組成物に関する。 The present invention relates to linalool, alpha-farnesene, methyl benzoate, oximene, myrcene, palmitic acid and beta-caryophylene. And a fragrance composition that reproduces the scent of cymbidium aroma pink, comprising at least one selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde.
一般に、香りを採取する方法として、溶媒を用いた溶媒抽出法（ｅｘｔｒａｃｔｉｏｎ）、水蒸気を用いる水蒸気蒸溜法（ｓｔｅａｍ ｄｉｓｔｉｌｌａｔｉｏｎ）などの方法が用いられる。しかし、このような方法では、香り成分を抽出する過程で加熱、減圧などによって香り成分が消失されるか変化されて、元物質が有する香りとの間に差異が発生することになる。 In general, as a method for collecting aroma, a method such as a solvent extraction method using a solvent or a steam distillation method using water vapor is used. However, in such a method, in the process of extracting the scent component, the scent component is lost or changed by heating, decompression or the like, and a difference is generated between the scent of the original substance.
このような短所を克服するために、ＳＰＭＥ（Ｓｏｌｉｄ−Ｐｈａｓｅ ＭｉｃｒｏＥｘｔｒａｃｔｉｏｎ）法とヘッドスペース（Ｈｅａｄｓｐａｃｅ）法などが開発された。上記方法は、追加的な前処理技術や溶媒を使用せず、簡便に揮発性有機化合物をファイバー（ｆｉｂｅｒ）に吸着させて濃縮する方式であって、加熱や減圧が不必要であるため試料本来の香りを再現し得るよい方法と言える。また、ＳＰＭＥ法は、分析しようとする発散された香りを外部空気から遮断させた状態で、香りを吸着するファイバー（Ｆｉｂｅｒ）を位置させて香り成分を吸着した後、吸着された香り物質をガスクロマトグラフィ−質量分析法（Ｇａｓ Ｃｈｒｏｍａｔｏｇｒａｐｈ−Ｍａｓｓ ｓｐｅｃｔｒｏｐｈｏｔｏｍｅｔｒｙ、ＧＣ−ＭＳ）を通じて定量分析する。前記ガスクロマトグラフィ−質量分析（ＧＣ−ＭＳ）法は、揮発性物質の含量分析に主に用いられる分析装置である。ＧＣ−ＭＳは、前記ＳＰＭＥを通じて注入された試料中のさまざまな化合物をガスクロマトグラフィー（ＧＣ）で分離した後、流入される物質の原子量を測定することで（ＭＳ）、前記化合物の含量を分析し得る。このような分析方法によって、再現しようとする香りの構成成分とその含量を測定することができる。 In order to overcome these disadvantages, an SPME (Solid-Phase Micro Extraction) method and a headspace method have been developed. The above method is a method in which a volatile organic compound is simply adsorbed on a fiber and concentrated without using any additional pretreatment technique or solvent, and heating and decompression are unnecessary, so that the sample itself is not used. It can be said that it is a good method that can reproduce the scent. In the SPME method, a scent component is adsorbed by locating a fiber (Fiber) that adsorbs a scent while the scent to be analyzed is blocked from external air, and then the adsorbed scent substance is gasified. Quantitative analysis is performed through chromatography-mass spectrometry (Gas Chromatograph-Mass spectrophotometry, GC-MS). The gas chromatography-mass spectrometry (GC-MS) method is an analyzer mainly used for content analysis of volatile substances. GC-MS separates various compounds in the sample injected through the SPME by gas chromatography (GC), and then analyzes the content of the compound by measuring the atomic weight of the inflowing substance (MS). Can do. By such an analysis method, it is possible to measure the constituents and the content of the scent to be reproduced.
一つの具体例では、上述した香り成分の分析技術により得られたシンビジウムアロマピンクの香り成分は、主要香り成分として、リナロール（Ｌｉｎａｌｏｏｌ）、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）、オシメン（Ｏｃｉｍｅｎｅ）、ミルセン（Ｍｙｒｃｅｎｅ）、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）及びβ−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）を含有する。 In one specific example, the scent component of cymbidium aroma pink obtained by the above-described scent component analysis technology includes linalool, α-farnesene, and methyl benzoate as main scent components. , Ocimene, Myrcene, Palmitic acid and beta-Caryophyllene.
しかし、前記シンビジウムアロマピンクの主要香り成分のみではシンビジウムアロマピンクの香りをまともに再現できないので、香りの嗜好度が下がる。したがって、本発明では、前記シンビジウムアロマピンクの主要香り成分に、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上の香り成分を追加して香りの再現性を高めることができる。 However, since the scent of Cymbidium Aroma Pink cannot be accurately reproduced with only the main scent component of the Cymbidium Aroma Pink, the preference of the scent is lowered. Therefore, in the present invention, one or more scent components selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde are added to the main scent component of the Cymbidium aroma pink. The reproducibility of the scent can be enhanced.
したがって、本発明によるシンビジウムアロマピンクの香りを再現した香料組成物は、天然シンビジウムアロマピンクの主要香り成分、すなわち、リナロール（Ｌｉｎａｌｏｏｌ）、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）、オシメン（Ｏｃｉｍｅｎｅ）、ミルセン（Ｍｙｒｃｅｎｅ）、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）及びβ−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）と、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上の香り成分とを含む。 Therefore, the fragrance composition reproducing the scent of cymbidium aroma pink according to the present invention is a main scent component of natural cymbidium aroma pink, that is, linalool, α-farnesene, methyl benzoate, Selected from the group consisting of Ocimene, Myrcene, Palmitic acid and β-Caryophyllene, Florosa, Hedione and Muguet Aldehyde One or more scent ingredients.
一つの具体例では、シンビジウムアロマピンクの主要香り成分として、組成物の全体重量に対して、リナロール（Ｌｉｎａｌｏｏｌ）２５〜３５重量％、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）２０〜２５重量％、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）１〜５重量％、オシメン（Ｏｃｉｍｅｎｅ）１〜５重量％、ミルセン（Ｍｙｒｃｅｎｅ）１〜５重量％、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）１〜３重量％及びβ−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）０．１〜２重量％を含有し得る。 In one embodiment, the main scent component of cymbidium aroma pink is 25-35% by weight of linalool, 20-25% by weight of alpha-farnesene, methyl benzoate, based on the total weight of the composition. (Methyl benzoate) 1 to 5% by weight, Ocimene 1 to 5% by weight, Myrcene 1 to 5% by weight, Palmitic acid 1 to 3% by weight, and beta-Caryophyllene It may contain from 0.1 to 2% by weight.
また、一つの具体例では、シンビジウムアロマピンクの主要香り成分とともに含まれる香り成分、すなわち、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上を、組成物の全体重量に対して１〜２０重量％、具体的には、３〜１６重量％の量で含有し得る。 In one specific example, the scent component contained together with the main scent component of cymbidium aroma pink, that is, one or more selected from the group consisting of Florosa, Hedione and Muguet Aldehyde In an amount of 1 to 20% by weight, specifically 3 to 16% by weight, based on the total weight of the composition.
本発明では、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）を一緒に用い得る。また、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）を全て含み得、この場合、組成物の全体重量に対して、フロローサ（Ｆｌｏｒｏｓａ）１〜５重量％、へディオン（Ｈｅｄｉｏｎｅ）０．１〜５重量％及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）０．１〜１０重量％の量で含有し得る。 In the present invention, Hedione and Muguet Aldehyde can be used together. It may also contain all of Florosa, Hedione, and Muguet Aldehyde, in which case 1 to 5% by weight of Florosa, based on the total weight of the composition, Hedione ) 0.1-5% by weight and Muguet Aldehyde 0.1-10% by weight.
本発明の香料組成物に含まれるリナロール（Ｌｉｎａｌｏｏｌ）、α−ファルネセン（ａｌｐｈａ−Ｆａｒｎｅｓｅｎｅ）、メチルベンゾエート（Ｍｅｔｈｙｌ ｂｅｎｚｏａｔｅ）、オシメン（Ｏｃｉｍｅｎｅ）、ミルセン（Ｍｙｒｃｅｎｅ）、パルミチン酸（Ｐａｌｍｉｔｉｃ ａｃｉｄ）、β−カリオフィレン（ｂｅｔａ−Ｃａｒｙｏｐｈｙｌｌｅｎｅ）、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）は、市販品を用いるか、あるいは植物から分離、反合成又は合成を通じて製造されたものを用いることができる。 Linalol, α-farnesene, methyl benzoate, oximeene, myrcene, myrcene, palmitic acid, β-caryophyllene included in the fragrance composition of the present invention (Beta-Caryophyllene), Florosa, Hedione, and Mugealdehyde (Muguet Aldehyde) may be commercially available products, or those produced through separation, anti-synthesis or synthesis from plants. .
また、本発明の香料組成物は、シンビジウムアロマピンクの香り満足度をより向上させるために当業界で広く知られている香可溶化剤をさらに含み得る。前記香可溶化剤の含量は、前記組成物の全体重量に対して、０．１〜１０重量％、具体的には、１〜５重量％であってもよい。 In addition, the fragrance composition of the present invention may further include a fragrance solubilizing agent widely known in the art for further improving the scent satisfaction of Cymbidium aroma pink. The content of the fragrance solubilizer may be 0.1 to 10% by weight, specifically 1 to 5% by weight, based on the total weight of the composition.
本発明の香料組成物は、本発明の目的を阻害しない範囲で化粧料又は皮膚外用剤に配合して提供し得る。 The fragrance composition of the present invention can be provided by being blended with a cosmetic or an external preparation for skin as long as the object of the present invention is not impaired.
前記化粧料は、基礎化粧品、メイクアップ化粧品及びボディー化粧品などであって、これらに制限されるものではないが、前記基礎化粧品の例としては、エッセンス、ローション、クリーム、ジェル、化粧水、パック、マッサージクリーム、乳液などがあり；前記メイクアップ化粧品としては、ファウンデーション、メイクアップベースなどがあり；ボディー化粧品としは、石鹸、液体洗浄剤、入浴剤、サンスクリーンクリーム、サンオイルなどがあり得る。皮膚外用剤は、軟膏、ローション、可溶化状、懸濁液、エマルジョン、クリーム、ジェル、スプレー、パフ剤、硬膏剤、パッチ剤又はパスタ剤などであってもよい。前記組成物は、剤形及び目的によって有効成分の含量は様々である。例えば、有効成分が短期間内に皮膚にとどまることとなるメイクアップ除去剤、洗浄剤などのようなウォッシュ−オフ（ｗａｓｈ−ｏｆｆ）タイプの化粧品は、比較的高い濃度であってもよいが、有効成分が長期間の間皮膚にとどまることとなる化粧水、乳液、クリーム、エッセンスなどのリーブ−オン（ｌｅａｖｅ−ｏｎ）タイプの化粧品の場合には、ウォッシュ−オフタイプの化粧品に比べて低い濃度を含んでいてよい。 The cosmetics are basic cosmetics, makeup cosmetics, body cosmetics and the like, and are not limited thereto. Examples of the basic cosmetics include essence, lotion, cream, gel, lotion, pack, Examples of the makeup cosmetics include foundations and makeup bases; examples of the body cosmetics include soaps, liquid detergents, bathing agents, sunscreen creams, sun oils, and the like. The external preparation for skin may be an ointment, lotion, solubilized form, suspension, emulsion, cream, gel, spray, puff, plaster, patch or pasta. The content of the active ingredient varies depending on the dosage form and purpose. For example, wash-off type cosmetics such as makeup removers, cleaning agents, etc., where the active ingredient will remain on the skin within a short period of time, may be at relatively high concentrations, In the case of leave-on type cosmetics such as lotions, emulsions, creams and essences where the active ingredient remains on the skin for a long period of time, the concentration is lower than that of wash-off type cosmetics. May be included.
また、本発明の香料組成物は、本発明の目的を阻害しない範囲で香り用物品に配合されて提供され得る。具体的に、本発明の香料組成物は、香り剤、脱臭剤、ディフューザ、キャンドル、油類、ジェル、玉、プラグインなどに含有させることによって、香り用物品として提供され得る。 Moreover, the fragrance | flavor composition of this invention can be mix | blended and provided with the article for fragrances in the range which does not inhibit the objective of this invention. Specifically, the fragrance composition of the present invention can be provided as a scented article by containing it in a fragrance, a deodorant, a diffuser, a candle, oils, a gel, a ball, a plug-in or the like.
また、本発明の香料組成物は、本発明の目的を阻害しない範囲で、パーソナルケア製品又はホームケア製品に配合して提供し得る。 Moreover, the fragrance | flavor composition of this invention can mix | blend and provide to a personal care product or a home care product in the range which does not inhibit the objective of this invention.
前記パーソナルケア製品は、シャンプー、リンス、トリートメント、ヘアエッセンスなどのヘアー製品；歯磨き粉、うがい液などの口腔製品；ボディーウォッシュ、ボディージェル、石鹸などの皮膚洗浄剤などであってもよく、前記ホームケア製品は、香水などの香り剤；纎維柔軟剤、キッチン洗剤などの洗濯洗剤類などであってもよいが、これらに制限されるものではない。 The personal care product may be a hair product such as shampoo, rinse, treatment or hair essence; an oral product such as toothpaste or gargle; a skin cleanser such as body wash, body gel or soap; The product may be a fragrance such as perfume; a fiber softener, laundry detergent such as kitchen detergent, but is not limited thereto.
以下、本発明の理解を助けるために実施例を挙げて詳細に説明する。しかし、本発明による実施例は様々な他の形態に変形され得、本発明の範囲が下記実施例に限定されることと解釈されるべきではない。 Hereinafter, in order to help understanding of the present invention, examples will be described in detail. However, the examples according to the present invention may be modified in various other forms, and the scope of the present invention should not be construed to be limited to the following examples.
＜実施例＞
１．シンビジウムアロマピンクの香り成分の分析
シンビジウムアロマピンクの香り成分及び含量を分析するために、固体相微細抽出法（Ｓｏｌｉｄ Ｐｈａｓｅ Ｍｉｃｒｏ Ｅｘｔｒａｃｔｉｏｎ、ＳＰＭＥ）で香り成分を抽出した後、ガスクロマトグラフィー質量分析法（Ｇａｓ Ｃｈｒｏｍａｔｏｇｒａｐｈ−Ｍａｓｓ ｓｐｅｃｔｒｏｐｈｏｔｏｍｅｔｒｙ、ＧＣ−ＭＳ）で分析した。
<Example>
1. Analysis of scent component of cymbidium aroma pink In order to analyze the scent component and content of cymbidium aroma pink, after extracting the scent component by solid phase micro extraction (SPME), gas chromatography mass spectrometry ( Gas Chromatography-Mass spectrophotometry (GC-MS).
シンビジウムアロマピンクの生花から香り発散が一番よく行われるつぼみ周辺を外気と遮断されるようにテドラーバック（Ｔｅｄｌｅｒ ｂａｇ）で密封してＳＰＭＥ専用シリンジ（ｓｙｒｉｎｇｅ)をさして６０分間香り成分を捕集した。香り成分が吸着されたシリンジ（ｓｙｒｉｎｇｅ）をガスクロマトグラフィー分析装置に連結して吸着された香り成分の種類と含量を分析した。 The buds where fragrance divergence was most frequently performed from fresh flowers of Cymbidium aroma pink were sealed with a tedler bag so as to be blocked from the outside air, and a SPME dedicated syringe (syringe) was inserted to collect scent components for 60 minutes. The type and content of the adsorbed scent component were analyzed by connecting a syringe on which the scent component was adsorbed to a gas chromatography analyzer.
このとき、捕集されたシンビジウムアロマピンクの香り成分の種類と含量を分析するための分析条件は下記の通りである。 At this time, the analysis conditions for analyzing the type and content of the scent component of the collected cymbidium aroma pink are as follows.
＜分析条件＞
分析機器：Ａｇｉｌｅｎｔ ６８９０ ＧＣ／５９７５ ＭＳＤ
検出器：ＭＳＤ
コラム：ＤＢ−ＷＡＸ ６０ｍ×２５０μ×０．２５μｍ
注入部の温度：２３０℃
検出部の温度：２３０℃
オーブン温度：５０℃（５分）〜２３０℃（２０分）、３．０℃／分
スプリット比：２０：１
移動相気体：Ｈｅ
注入量：０．５μｌ
<Analysis conditions>
Analytical instrument: Agilent 6890 GC / 5975 MSD
Detector: MSD
Column: DB-WAX 60m × 250μ × 0.25μm
Injection section temperature: 230 ° C
Detector temperature: 230 ° C
Oven temperature: 50 ° C. (5 minutes) to 230 ° C. (20 minutes), 3.0 ° C./minute Split ratio: 20: 1
Mobile phase gas: He
Injection volume: 0.5 μl
分析結果を下記表１に示した。 The analysis results are shown in Table 1 below.
２．シンビジウムアロマピンクの再現香料の製造及び官能評価
（１）実施例１〜６及び比較例１
下記表２の組成によって、各成分を均一に混合して香料組成物を製造した。
2. Production and sensory evaluation of regenerated fragrance of Cymbidium aroma pink (1) Examples 1-6 and Comparative Example 1
Each component was uniformly mixed according to the composition shown in Table 2 to produce a fragrance composition.
（２）実験例１．官能評価
実施例１〜６及び比較例１で製造された香料組成物に対して、シンビジウムアロマピンクの香りとの類似性及び選好度に対する官能評価を実施した。官能評価の対象者は、２７〜５０才の身体が元気な一般男女２０人を対象とし、男４人、女１６人であった。
(2) Experimental Example 1. Sensory evaluation The sensory evaluation with respect to the similarity and preference with the scent of Cymbidium aroma pink was implemented with respect to the fragrance | flavor composition manufactured in Examples 1-6 and Comparative Example 1. The subjects of sensory evaluation were 20 men and women who were healthy with a body of 27 to 50 years old, and were 4 men and 16 women.
類似性に対する評価は、５点評価法で評価し、選好度に対する評価も５点評点法で評価した。評価室と試料準備室を分離して評価者が試料の事前認知のないようにした。 Evaluation for similarity was evaluated by a five-point evaluation method, and evaluation for preference was also evaluated by a five-point evaluation method. The evaluation room and the sample preparation room were separated so that the evaluator did not recognize the sample in advance.
＜類似度＞
１点：シンビジウムアロマピンクの香りと非常に異なる。
２点：シンビジウムアロマピンクの香りと少し異なる。
３点：シンビジウムアロマピンクの香りとまあまあである。
４点：シンビジウムアロマピンクの香りと少し似ている。
５点：シンビジウムアロマピンクの香りと非常に似ている。
<Similarity>
1 point: Very different from the scent of Cymbidium Aroma Pink.
2 points: Slightly different from the scent of Cymbidium Aroma Pink.
3 points: Cymbidium aroma pink scent and so on.
4 points: A little like the scent of Cymbidium Aroma Pink.
5 points: Very similar to the scent of Cymbidium Aroma Pink.
＜選好度＞
１点：非常に良くない。
２点：少し良くない。
３点：まあまあである。
４点：少し良い。
５点：非常に良い。
<Preference>
1 point: Not very good.
2 points: not good.
3 points: OK.
4 points: A little good.
5 points: Very good.
前記類似度及び選好度の結果を、それぞれ下記表３及び表４に示した。 The results of the similarity and preference are shown in Tables 3 and 4 below, respectively.
類似度に関して、比較例１は、分析された天然に存在するシンビジウムアロマピンクの主要香り成分及び含量に従って製造された香料組成物であるが、天然シンビジウムアロマピンクの本来の香りとは非常に低い類似度を示した。 Regarding similarity, Comparative Example 1 is a fragrance composition produced according to the analyzed natural symbidium aroma pink main scent components and content, but very similar to the original scent of natural cymbidium aroma pink. Showed the degree.
一方、実施例１〜実施例６のように、主要香り成分とともに、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上の香り成分を追加すると、香り類似度の評価が高くなることが確認された。特に、上記３種の香り成分を一緒に混用すると、シンビジウムアロマピンクの本来の香りにさらに類似することが確認できる。 On the other hand, as in Examples 1 to 6, one or more scent components selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde are added together with the main scent component. Then, it was confirmed that evaluation of scent similarity becomes high. In particular, when the above three scent components are mixed together, it can be confirmed that the scent of cymbidium aroma pink is more similar to the original scent.
また、選好度に関して、天然に存在するシンビジウムアロマピンクの主要香り成分及び含量に従って製造された比較例１の香料組成物は、香りの面で非常に低い選好度を示した。 Moreover, regarding the preference, the fragrance composition of Comparative Example 1 manufactured according to the main scent component and content of cymbidium aroma pink existing in nature showed a very low preference in terms of fragrance.
一方、フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上の香り成分を追加した実施例１〜実施例６の香料組成物は、比較例に比べて香り選好度の評価が高くなることが確認された。特に、上記３種の香り成分を一緒に混用すると、選好度に最も優れることが確認できた。 On the other hand, the fragrance compositions of Examples 1 to 6 to which one or more scent components selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde are added are comparative examples. It was confirmed that the evaluation of the scent preference was higher than that. In particular, it was confirmed that when the above three fragrance components were mixed together, the preference was most excellent.
Claims (5)
フロローサ（Ｆｌｏｒｏｓａ）、へディオン（Ｈｅｄｉｏｎｅ）及びミュゲアルデヒド（Ｍｕｇｕｅｔ Ａｌｄｅｈｙｄｅ）からなる群より選択された一つ以上を含むことを特徴とする、シンビジウムアロマピンクの香りを再現した香料組成物。 Linalool, alpha-farnesene, methyl benzoate, ocimene, myrcene, palmitic acid and beta-caryophylene (beta-carneophyl)
A fragrance composition that reproduces the scent of cymbidium aroma pink, comprising at least one selected from the group consisting of Florosa, Hedione, and Muguet Aldehyde.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020180022756A KR102104269B1 (en) | 2018-02-26 | 2018-02-26 | Perfume composition for expressing the fragrance of Cymbidium cultiva'Aroma Pink' |
| KR10-2018-0022756 | 2018-02-26 |
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| JPH07308370A (en) * | 1994-05-16 | 1995-11-28 | Kanebo Ltd | Perfume composition for spraying |
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| JPH11269482A (en) * | 1998-03-24 | 1999-10-05 | Shiseido Co Ltd | Orchid-like perfume composition |
| JP3821222B2 (en) * | 2002-04-05 | 2006-09-13 | ライオン株式会社 | Rosmarinic acid-containing composition |
| KR101064067B1 (en) * | 2008-10-28 | 2011-09-08 | (주)아모레퍼시픽 | Perfume composition which reproduced scent of silk flower |
| KR101790180B1 (en) * | 2010-11-17 | 2017-10-27 | (주)아모레퍼시픽 | Perfume composition for expressing the fragrance of Dictamus dasycarpus and the composition for skin external application containing the same |
| KR101770682B1 (en) * | 2011-03-24 | 2017-09-05 | (주)아모레퍼시픽 | Perfume composition for expressing the fragrance of chrysanthemum indicum and the composition for skin external application containing the same |
| KR101236020B1 (en) * | 2011-06-14 | 2013-02-21 | 한국콜마주식회사 | Perfume composition and composition for external application to skin |
| KR102085097B1 (en) * | 2014-09-04 | 2020-03-05 | 주식회사 엘지생활건강 | Perfume compositin |
| KR101614066B1 (en) * | 2014-10-14 | 2016-04-20 | (주)더페이스샵 | Perfume composition for expressing the fragrance of Citrus reticulate |
| US9796945B2 (en) * | 2015-02-02 | 2017-10-24 | Johnson & Johnson Consumer Inc. | Perfume compositions |
| KR102406007B1 (en) * | 2015-02-06 | 2022-06-08 | (주)아모레퍼시픽 | Perfume composition for expressing the fragrance of Citrus |
| KR102428986B1 (en) * | 2016-04-29 | 2022-08-04 | (주)아모레퍼시픽 | Perfume composition for reproducibly expressing the fragrance of Nelumbo nucifera Gaertner |
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| JPH07308370A (en) * | 1994-05-16 | 1995-11-28 | Kanebo Ltd | Perfume composition for spraying |
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| 印藤 元一, 合成香料 化学と商品知識, JPN6022044870, 1996, pages 167 - 246, ISSN: 0004908118 * |
| 農業経済新聞, JPN6022044869, 15 January 2018 (2018-01-15), ISSN: 0004908117 * |
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| CN110194990B (en) | 2023-08-22 |
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