KR101877624B1 - Perfume composition representing the fragrance of Coelogyne nitida - Google Patents

Abstract

The present invention relates to coelogyne The present invention relates to a perfume composition that reproduces the fragrance of a flower of the order Ninetida. And a flavor composition recreating the fragrance of a celluloliginitida flower comprising, as an active ingredient, at least one component selected from the group consisting of citronellol, hedione, and galaxolide . The composition of the present invention can be used as a perfume composition, a home care product and a personal care product containing the perfume composition because of its high degree of similarity with the intrinsic fragrance of Celogeninida flowers and satisfactory perfume.

Description

(Perfume composition representing the fragrance of Coelogyne nitida) < RTI ID = 0.0 >

The present invention relates to coelogyne The present invention relates to a perfume composition that reproduces the fragrance of a flower of the order Ninetida. And a flavor composition recreating the fragrance of a celluloliginitida flower comprising, as an active ingredient, at least one component selected from the group consisting of citronellol, hedione, and galaxolide . The present invention also relates to a home care product and a personal care product comprising the perfume composition

75% of all eggs and plants have a fragrance. There are various kinds of fragrance, so you can have all kinds of sweet flowers such as Laeliocattleya Angel Love, Laelia anceps, Lilac. In C. maxima , known as Ecuador's most beautiful tree, it is known that it can scent Heliotrope, a kind of herb, and sweet pea, a garden pea flower. There is also a strong emanation of complex incense like lycra, magnolia, gardenia, vanilla, honey, etc., like Encyclia fragrans, and some people like the Phalaenopsis Mini Mark, Some are perceived as fleeting but some feel like they have no fragrance at all. Maxillaria tenuifolia has a very strong smell of coconut or crayon, which is also called 'cococnut orchid'. Regarding the scent of eggs, there is a false prejudice that scent is not produced in the ovary where the subtropical region originates from the tropics. Since ancient times, Korea has been cultivating mainly Chinese cryogenic Cymbidium with good fragrance. On the other hand, this prejudice was born out of the fact that the most common cultivated cultivars in Korea were the low temperature Cymbidium and Denphala (Den phalaenopsis), which are not very strong in flavor. However, there are many fragrance in Korean Chunran and Japanese Chunran, among oriental cultivars. On the other hand, Zygopetalum, Brazavola, and Cattleya, which are classified as Yangran,

Among the other eggs, a typical egg with a smell is the Coelogyne , and the flower is beautiful and sweet.

On the other hand, Coelogyne is a half-sized Cymbidium , which is about half the size of a Cymbidium, and leaves one or two leaves to the government of an egg-shaped bulb, and in the late spring the bird's eyes are created at the donation of the bulb. Is a finished plant. The flower buds are formed after the completion of the new bulb, which should be responded to for about two weeks at low temperatures. It does not grow in winter, but blooms around May in origin. The peduncle has an upright shape and a sewer shape. The bud is gathered in a spike shape. The flower size is usually about 3 centimeters. There are no colorful flowers such as red or pink, and they are yellowish brown, white, greenish yellow, and bloom for 3 ~ 4 weeks after flowering.

Cellulasechnitida flowers have their own distinctive scent, but with conventional solvent extraction or steam distillation methods, loss of flavor due to heat is inevitable, and there are many differences from the original scent of flowers. Accordingly, there has been a demand for the development of a perfume composition that is differentiated and has new characteristics by artificially reproducing the cellulase flower of the zinitidas in a natural state.

Under these backgrounds, the present inventors analyzed the fragrance component and content of the Celogeninida flowers in order to reproduce the differentiated fragrance inherent to the Celoginitida flowers, and when the analyzed components were artificially mixed with the analyzed contents It was found that it was difficult to obtain a fragrance similar to the original fragrance and it was found that by adding a new fragrance ingredient which does not exist in the natural state of the cellulasechnitida flowers, the fragrance of the cellulasechnitida flowers can be reproduced almost similarly Thus completing the present invention.

Korean Patent Publication No. 10-2004-0021689

It is an object of the present invention to provide a method for the production of coelogyne nitida ) fragrance components of flowers; And a fragrance composition recreating the fragrance of a cellulosinitida flower comprising, as an active ingredient, at least one component selected from the group consisting of citronellol, hedione, and galaxolide will be.

Another object of the present invention is to provide a home care product comprising the perfume composition.

It is still another object of the present invention to provide a personal care product comprising the perfume composition.

SUMMARY OF THE INVENTION In order to solve the above problems and to achieve the object of the present invention, the present invention provides a method for producing Coelogyne nitida ) fragrance components of flowers; The present invention provides a fragrance composition recreating the fragrance of cellulasechnida flowers comprising at least one component selected from the group consisting of citronellol, hedione, and galaxolide as an active ingredient .

In the present invention, " Coelogyne " nitida ") is a species of the cellulina that lives in the Himalayan region of India and Southeast Asia. It requires a rest period during the winter and is sufficient to prevent the hut scales from shrinking from low temperatures and high sunlight during the rest period Only a small amount of nutrients and water are needed. These conditions have been reported to help to bloom in the spring.

In the present invention, "fragrance" refers to an odor that enters the nose as a fragrant but slightly pungent odor. The fragrance of the present invention is a fragrance of celloginitida flowers, which means a sweet fragrance.

In the present invention, the term "fragrance" is an organic substance having a strong aroma added to add flavor to cosmetics, food products, and the like, and has excellent volatility at room temperature. Spices can be roughly classified into natural fragrance obtained from roses, lemons, etc., isolated fragrance separated and purified from raw materials such as low-priced natural fragrance and coal tar, and synthetic fragrance synthesized through chemical reaction. It is also called artificial fragrance by combining isolated flavor and synthetic flavor. By application, cosmetics can be divided into fragrances and food fragrances. Cosmetics fragrance is aimed only at fragrance, but food fragrance is mainly flavor with flavor. The perfume composition of the present invention is a perfume composition for reproducing the fragrance of cellulasechnida flowers, which comprises citronellol, hedione and / or galaxolide in the fragrance component of the cellulidinatin flower, (Table 9). It was confirmed that the fragrance and similarity of the flowers of Seljigninida flowers were excellent.

In the present invention, the fragrance component of the Celogeninida flower is collectively referred to as the component analyzed by collecting the fragrance of the Celoginita flower. Generally, fragrance is extracted by extraction with a solvent, distillation using water vapor, etc. However, the above methods are not suitable for extracting fragrance components by heating, , And the like, and there are many differences from the perfume characteristics of the original material. In addition, it is difficult to apply natural monuments such as spruce trees easily. Headspace and SPME (solid-phase microextraction) methods have been developed to overcome these disadvantages. These two methods do not require any pretreatment of the sample without solvent and do not require a large amount of sample, and can analyze the fragrance component with the sample itself so that it can reproduce the original fragrance of the sample Method.

In the present invention, the fragrance component of the Celogeninida flower may be selected from the group consisting of limonene, phenylethyl alcohol, methyl anthranilate, benzyl acetate and anethole (anethol) as a main component, and other additional components may include benzaldehyde, L-carvone, methyl salicylate, phenyl acetic aldehyde ), Para-cymene, phenylethyl acetate and L-menthone.

The limonene is one kind of hydrocarbons belonging to terpenes, which is also called 1,8-p-mentadiene, and has a similar aroma to oranges and is used as a raw material for perfumes. D-limonene, which is one of the optical isomers, is contained in about 90% of the main component of orange oil, and is also contained in plant essential oils such as lemon oil, lime oil, and bergamot oil, and is widely distributed in plants. L-limonene, another optical isomer, is contained in the oils of pine and other plants, such as spearmint oil and turpentine oil, as well as peppermint oil. The phenylethyl alcohol is an organic compound also called 2-phenylethanol, which is a colorless liquid widely present in nature, and has pleasant floral scent and is used as a raw material for fragrance. The methylanthranilate is an ester of anthranilic acid, also called methyl 2-aminobenzoate or carbomethoxyaniline, which occurs naturally in grapes and is used to produce grape flavors. Benzyl acetate is a colorless liquid synthesized from benzyl alcohol and acetic acid. It is contained in jasmine, gardenia, ylang-ylang oil, and gives a fragrance belonging to the floral family. The anethole is an aromatic compound having a benzene ring, and is present in convention oil, anise oil, fennel oil and the like, and is used as a fragrance such as confectionery, beverage or the like, or as an aroma, a raw food or an expectorant.

In one embodiment of the present invention, the fragrance components of the flowers of the Celenosinetida were analyzed using a headspace method. As a result, limonene, phenylethyl alcohol, , Methyl anthranilate, benzyl acetate, and anethole were identified. As other odor components, benzaldehyde, L-carboxy, methyl salicylate, phenylacetic aldehyde, para-cymene, phenyl ethyl acetate and L- (Table 1 and Table 2).

The perfume composition of the present invention further comprises citronellol, hedione, and / or galaxolide in the fragrance component of the cellosinitida flower, so that the fragrance of celloginitida flowers Can be reproduced. In particular, the perfume composition of the present invention may contain galactolide in the fragrance component of the cellosynnitida flower, and more specifically, the fragrance composition of the present invention may contain galactolide in the fragrance component of the cellosynintida flower It necessarily contains galactoside, and may additionally contain citronellol or hedione. In one embodiment of the present invention, it was confirmed that the fragrance added with galactolide to the fragrance component of the Celigninida flower was most excellent in similarity and satisfaction with the fragrance of the Celoginitida flower (Table 9).

The citronellol is a colorless, transparent monoterpenic alcohol having a sweet rose-like sensation detected in a plant essential oil, and is present in Java, sitronelal oil, geranium oil, rose oil and the like, and is made by reducing d-citronellal. Further, It is used in pineapple, citrus flavor, rose flavor, honey flavor and is widely used for combination of rose oil, perfume, cosmetics and soap. The hedione is a kind of ester, which is a diffusible perfume, and is also called methyl dihydrojasmonate. In addition, a jasmine-like flavor is produced, and a racemic mixture has a floral-like aroma and a citrus-like aroma. The garaxalide is a synthetic sweet fragrant musk fragrant ingredient used in perfumes, also called hexahydrohexamethyl cyclopentabenzopyran (HCCB). In addition, the galactolide was first synthesized in 1965 as one of the musk components used to add the musk fragrance.

In one embodiment of the present invention, in the case of a flavor obtained by adding citronellol, hedione and / or galactaride to the flavor component of the Celigninida flower, the degree of similarity and satisfaction with the flavor of the Celoginita flower is excellent (Table 9).

Specifically, the present invention provides a fragrance composition recreating the fragrance of cellulasechnida flowers containing the following ingredients.

Specifically, the perfume composition comprises 20 to 60% by weight of limonene, 10 to 30% by weight of phenylethyl alcohol, 0.1 to 5% by weight of methyl anthranilate, 0.1 to 5% by weight of benzyl acetate, The total content of the five components may be 40 to 90% by weight based on 100% by weight of the total composition, and more specifically, the total content of the five kinds of components The total content of the components may be from 50 to 80% by weight based on 100% by weight of the total composition.

The perfume composition may further comprise 0.1 to 10% by weight of benzaldehyde, 0.1 to 15% by weight of L-carboxy, 0.1 to 15% by weight of methyl salicylate, 0.1 to 30% by weight of phenylacetic aldehyde, 0.1 to 10% by weight of para-cymene, 0.1 to 30% by weight of phenyl ethyl acetate, and 0.1 to 10% by weight of L-mentone.

In addition, the perfume composition may include 1 to 30% by weight of citronellol, 1 to 20% by weight of heddone, and 1 to 20% by weight of galactolide, based on 100% by weight of the whole composition.

In another aspect of the present invention, there is provided a home care product comprising the perfume composition.

For the purposes of the present invention, "home care products" are intended to refer to products used for household cleaning (e.g., hard surface cleaners, manual and automatic dish care, toilet cleaners and sanitizers, (For example, detergents, fabric softeners, pretreatment stain removers), directional compounds to remove odors or, in some cases, be used as a perfume substitute. , And the like, but the present invention is not limited thereto, and can be applied to all the home care compositions into which the perfume is injected. Specifically, the home care products include laundry detergents, laundry detergent additives, laundry bars, fabric softeners, kitchen detergents, wood and furniture polishes, floor polishes, bath and tile cleaners, toilet cleaners, hard surface cleaners, window cleaners, anti- But are not limited to, cleaners, auto-dishwashing agents and sheeting agents, carpet cleaners, prewash spotters, rust stain cleaners, descalers, deodorants and perfumes.

Products for use in the home care products of the present invention, such as laundry products, may be, but are not limited to, a textile care product comprising the perfume composition and a cationic polymer, an amphoteric surfactant, or a mixture thereof. The cationic polymer used in the textile care product may be selected from the group consisting of cationic guar, cationic cellulose, dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, PVP-dimethylaminoethyl methacrylate copolymer, Dimethyl diallylammonium chloride copolymer, acrylamide-dimethylaminoethyl methacrylate methyl chloride copolymer, trimethylaminoethyl methacrylate polymer, and the like, but is not limited thereto. The amphoteric surfactant used in the textile care product is selected from the group consisting of alkylamidopropyl betaine, alkyldimethylbetaine, alkylmonoamphoacetate, cocoamphocarboxy glycinate, sarcosinate and alkylamphodiacetate, and the like. Any one or more may be used, but are not limited to.

While the home care products of the present invention, such as those for use in such laundry products, require several cleaning additives, certain simple formulations, such as bleach additives, may require only oxygen bleaching agents and surfactants. The cleaning adjunct may include builders, enzymes, bleaches, bleach activators, catalytic materials, and the like. Specifically, the cleaning adjunct may be selected from the group consisting of a foam promoter, a foam inhibitor (defoamer), a dispersant polymer, a color speckle, a silver care agent, an antioxidant and / or an anticorrosive, a dye, a filler, a bactericide, May contain various active or specialized substances such as stabilizers, stabilizers, enzyme stabilizers, pro-peptides, antioxidants, solubilizers, carriers, processing aids and pigments and in the case of liquid formulations, solvents, chelating agents, Antioxidants, perfumes, processing aids, and other fabric care agents, surfaces, and skin care agents, which may be included in the compositions of the present invention.

The home care product of the present invention, such as a perfume, may be a volatile perfume composition comprising the gel or solidified inventive perfume composition of the present invention and may be a liquid perfume composition comprising the perfume composition of the present invention prepared in liquid form have. In addition, the perfume composition may contain 0.001 to 30% by weight, specifically 1 to 30% by weight, more specifically 1 to 10% by weight, of the perfume composition of the present invention in the weight of the total product. When the perfume composition is added in an amount of less than 0.001% by weight, the fragrance is difficult to be appreciated because the fragrance is very low. When the perfume composition is added in an amount of more than 30% by weight, the fragrance becomes too strong for use as a fragrance. When the perfume composition of the present invention is used as a fragrance additive, the composition can be added as it is or mixed with optional ingredients useful in a flavoring or fragrance. In particular, they may be mixed with one or more of the natural extracts used in the field of a wide variety of natural, synthetic, synthetic chemicals, natural fragrances, flavors, flavors or fragrances. Additionally, the perfume may include one or more ingredients or excipients commonly used with flavors and fragrances, such as carrier materials, thickeners, flavor enhancers and other adjuvants commonly known and used in the art have.

In another aspect of the present invention, there is provided a personal care product comprising the perfume composition.

In the present invention, "personal care product" is intended to encompass all types of cosmetic products, including cosmetics, hair care products, toiletries, cosmeceuticals, beauty aids, , Personal hygiene and cleansing products, but are not limited thereto, and can be applied to personal care compositions into which perfumes are injected. Specifically, the present invention relates to a cosmetic composition comprising a composition selected from the group consisting of deodorant, antiperspirant, spray, stick and roll-on product, shaving preparation, skin lotion, Nail polish remover, nail cream and lotion, exfoliant, sunscreen, insect repellent, anti-aging agent, lipstick, foundation, face powder, eyeliner , Eye shadow, blushes, makeup, mascara, moisturizing preparation, body and hand preparation, skin care preparation, face and neck preparation, tonic, dressing, hair grooming aid, aerosol fixative, fragrance preparation, aftershave, - up formulation, soft focus preparations, night and day skin care preparations, non-pigmented hair preparations, tanning preparations, synthetic and non-synthetic soap bars, Makeup remover, facial cleanser, cold cream, sunscreen, mousse, spritz, shampoo, shampoo, baby shampoo, baby shampoo, shaving cream, squeegee, nose strip, personal care nonwovens, baby shampoo, baby conditioner, Face masks and muds, face masks, colognes and lotions, hair cuticle coats, shower gels, face and bodywashes, personal care rinse-offs, gels, foam baths, scrubbing cleansers, astringents, nail conditioners, eye shadow sticks, Hair brush, lip balm, lip gloss, hair care pump spray and other non-aerosol sprays, hair-freeze-control gel, hair rib-in conditioner, hair pomade, hair detergent, hair fixative, hair bleach, skin Lotions, pre-shave and pre-electric shave, anhydrous creams and lotions, oil / water, water / type, multiple macros Microemulsions, water-resistant creams and lotions, acne skin preparations, mouthwashes, massage oils, toothpastes, clear gels and sticks, ointment bases, local wound healing agents, aerosol talc, barrier sprays, vitamins and antioxidants, herbal extracts, Hair styling aids, hair-, eye-, nail- and skin-soft products, emit control personal care products, hair conditioning mists, skin care moisturizing mist, skin wipes, pores But are not limited to, skin wipes, pore cleansers, Blemish Reductors, skin exfoliators, skin removers, skin towelette and cloth, depilatories, personal care lubricants and nail coloring aids.

The personal care products of the present invention, such as cosmetics, can be used as a solution, an external ointment, a cream, a foam, a nutritional lotion, a softening longevity pack, a pack, a flexible water, a milky lotion, a makeup base, an essence, But may be formulated as a suspension, emulsion, paste, gel, lotion, powder, soap, surfactant-containing cleansing, oil, powder foundation, emulsion foundation, wax foundation, patch, But is not limited thereto.

The cosmetics of the present invention may further comprise at least one cosmetically acceptable carrier to be incorporated in cosmetics for general skin, and examples thereof include oil, water, a surfactant, a humectant, a lower alcohol, a thickener, a chelate Coloring matters, preservatives, fragrances, and the like may be appropriately compounded, but the present invention is not limited thereto. The cosmetically acceptable carrier included in the cosmetic of the present invention varies depending on the formulation.

When the formulation of the present invention is an ointment, a paste, a cream or a gel, the carrier component may be an animal oil, a vegetable oil, a wax, a paraffin, a starch, a tracer, a cellulose derivative, polyethylene glycol, silicone, bentonite, silica, talc, zinc oxide Mixtures of these may be used.

When the formulation of the present invention is a powder or a spray, lactose, talc, silica, aluminum hydroxide, calcium silicate, polyamide powder or a mixture thereof may be used as the carrier component, Propellants such as fluorohydrocarbons, propane / butane or dimethyl ether.

When the formulation of the present invention is a solution or emulsion, a solvent, a dissolving agent or an emulsifying agent is used as a carrier component, and examples thereof include water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzyl benzoate, 1,3-butyl glycol oil may be used, in particular fatty acid esters of cottonseed oil, peanut oil, corn oil, olive oil, castor oil and sesame oil, glycerol aliphatic esters, polyethylene glycols or sorbitan may be used have.

When the formulation of the present invention is a suspension, a carrier such as water, a liquid diluent such as ethanol or propylene glycol, a suspension such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester, Crystalline cellulose, aluminum metahydroxide, bentonite, agar or tracant, etc. may be used.

When the formulation of the present invention is a soap, an alkali metal salt of a fatty acid, a fatty acid hemiester salt, a fatty acid protein hydrolizate, isethionate, a lanolin derivative, an aliphatic alcohol, a vegetable oil, glycerol, .

In the cosmetic of the present invention, the content of the perfume composition may vary depending on the formulation. For example, wash-off type cosmetics, such as make-up removers, detergents, and the like, where the active ingredient remains on the skin in a short period of time, may be relatively high concentrations. On the other hand, in the case of leave-on type cosmetics such as lotion, cream, essence and the like in which the active ingredient remains on the skin for a long period of time, the concentration may be lower than that of the wash-off type cosmetics.

The personal care products of the present invention, for example, hair care products, can be used as a shampoo (including complex shampoos such as two-in-one conditioning shampoos), hair conditioners, rinses after shampooing, hair dyeing, But are not limited to, styling agents (including setting aids such as gels and sprays, and grooming adjuvants such as pomades, conditioners, permanent liquids, and relaxants), and hair smoothing products. The hair care product may include, but is not limited to, the perfume composition of the present invention and any one or more selected from the group consisting of a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, and a cationic polymer. The cationic surfactant used in the hair care product may be at least one selected from the group consisting of cetrimonium chloride, stearamidopropyldimethylamine, dicetyldimethylammonium chloride and ester quatro. It does not. The amphoteric surfactant used in the hair care product may be at least one selected from the group consisting of cocamidopropyl betaine, cocoamphocarboxy glycinate and coco amphocarboxy propionate, but is not limited thereto. The nonionic surfactant used in the hair care product may be at least one selected from the group consisting of lauryl acid diethanolamide, coconut fatty acid diethanolamide, coconut fatty acid monoethanolamide, lauryldimethylamine oxide and palm oil alkyldimethylamine oxide May be used, but is not limited thereto. The cationic polymer used in hair care products is a natural cationic polymer group consisting of guar hydroxypropyl trimonium chloride, hydroxypropyl guar hydroxypropyl trimonium chloride and quaternary hydroxyethyl cellulose; And a synthetic cationic polymer group consisting of dimethyldiallylammonium chloride polymer, acrylamide dimethyl allylammonium chloride copolymer and polyvinyl pyrrolidone dimethyl amino ethyl methacrylate copolymer, may be used. It is not limited. The hair dye may be a hair dye containing the perfume composition of the present invention, a precursor and a coupler, but is not limited thereto.

The personal care products of the present invention, such as body care products, may be used as a single component or as a single component for bath and shower additives, fragrance and flavor containing preparations, hair care products, deodorants and depot preparations, decorative preparations, Can be used in combination with a stabilizer. The body care product may be a body oil, a body lotion, a body gel, a treatment cream, a skin protective ointment, a shaving preparation such as a shaving foam or gel, a skin powder such as a baby powder, a moisturizing gel, a moisturizing spray, Sprays, cellulite gels, and peeling agents. Suitable bath and shower additives include shower gel, bath-salt, bubble bath and soap. Formulations containing fragrant and flavor substances include perfumes, lotions and shaving lotions (aftershave formulations). The body care product may be in the form of a cream, ointment, paste, foam, gel, lotion, powder, makeup, spray, stick or aerosol, but is not limited thereto. The body care product may also include, but is not limited to, a stabilizing mixture, and optionally additional UV absorbers, sterically hindered amines, complexing agents, and phenolic or non-phenolic antioxidants.

The present invention relates to a composition for reproducing the fragrance of Celogeninida flowers, and it has been confirmed through sensory evaluation that the degree of similarity with the intrinsic fragrance of the Celoginaniuma flower is high and the satisfaction of the fragrance is excellent. As a result, Can be advantageously used as a home care product and a personal care product containing a perfume composition.

Hereinafter, the present invention will be described in detail with reference to Examples and Experimental Examples. However, the following Examples and Experimental Examples are merely illustrative of the present invention, and the present invention is not limited to the following Examples and Experimental Examples.

Experimental Example  One. Headspace method  Used Cellogine Nitida  Analysis of fragrance components of flowers

The headspace analysis method is a method capable of collecting sample fragrance as it is in a natural state. In the present invention, the headspace analysis method was used and the following component analysis was performed using the method described in the literature. A hermetically sealed wrap was placed on the flower portion of the cellogeninida and the circulating air was passed through the tenax column while the outside air was forcibly circulated by the power device to collect the fragrance ingredient.

The tenax column, in which the odor was collected, was connected to a gas chromatographic analyzer to analyze the type and content of the collected fragrance. The results are shown in Table 1 below.

<Analysis condition>

Analytical Instruments: Hewlett Packard 6890

Detector: FID

Column: HP-20M 0.2 mm ID x 25 m

Injection temperature: 250 ° C

Detector temperature: 250 ° C

Oven temperature: 55 占 폚 (0 minutes) to 215 占 폚 (40 minutes), 4.0 占 폚 / min

Split Ratio: 30: 1

Mobile phase gas: helium 18 cm / sec

Injection amount: 0.3 ml

Analysis of the fragrance component of celloginitida flowers Perfume name weight (%) ANETHOL 4.3 Benzyl acetate (BENZYL ACETATE) 0.8 D-LIMONENE 46.1 METHYL ANTHRANILATE 0.7 PHENYLETHYL ALCOHOL 23.1 Benzaldehyde (BENZALDEHYDE) 1.4  L-Carbon (L-CARVONE) 3.2 L-Mentone 0.8 Methyl salicylate (METHYL SALICYLATE) 4.2 PARA-CYMENE 3.3 PHENYL ACETIC ALDEHYDE 6.2 Phenyl ethyl acetate (PHENYLETHYL ACETATE) 0.5 Other 5.4 total 100.0

In addition, the fragrance industry proprietor 6 analyzed the cellulasechnitida flowers and the sensory evaluation of the actual flower fragrance, and selected 5 major fragrance components of the cellulase flower flower, and the selected fragrance components were O And more than half of them were selected as main ingredients. The results are shown in Table 2 below.

Perfume name Aroma A B C D E F ANETHOL O O O O O O Benzyl acetate (BENZYL ACETATE) O O O O D-LIMONENE O O O O O O METHYL ANTHRANILATE O O O O PHENYLETHYL ALCOHOL O O O O O O Benzaldehyde (BENZALDEHYDE) O  L-Carbon (L-CARVONE) L-Mentone Methyl salicylate (METHYL SALICYLATE) O PARA-CYMENE PHENYL ACETIC ALDEHYDE O O Phenyl ethyl acetate (PHENYLETHYL ACETATE)

As a result of the analysis, the perfume industry was selected based on the fragrance intensity of six seedlings, not the content, but the cellulases and flowers, and the major fragrance components of the cellulogeninida flowers were limonene, phenylethyl alcohol, methyl anthranilate, benzyl acetate, It was toll.

Experimental Example  2. Cellogine Nitida  Manufacture and comparison analysis of fragrance for reproduction of flower fragrance

Based on the cellulase DNA flower component (Table 1) analyzed in Experimental Example 1, the fragrance for reproducing the fragrance of cellulasechnida flowers having the composition and contents shown in Table 3 was prepared. Then, comparative analysis was carried out by the following process for the fragrance of celloginitida flower of Table 1 and the fragrance of fragrance reproduction of celloginitida flower of Table 3 below.

The sensory evaluation subjects were selected from six perfume industry steers and comparative analysis was performed with respect to the fragrance of celloginitida flowers of Table 1 and the fragrance reproducibility of fragrances of celloginitida flowers of Table 3 below.

Celogeninida Flower fragrance Flavor Reproduction fragrance Perfume name weight (%) ANETHOL 4.3 Benzyl acetate (BENZYL ACETATE) 0.8 D-LIMONENE 46.1 METHYL ANTHRANILATE 0.7 PHENYLETHYL ALCOHOL 23.1 Benzaldehyde (BENZALDEHYDE) 1.4  L-Carbon (L-CARVONE) 3.2 L-Mentone 0.8 Methyl salicylate (METHYL SALICYLATE) 4.2 PARA-CYMENE 3.3 PHENYL ACETIC ALDEHYDE 6.2 Phenyl ethyl acetate (PHENYLETHYL ACETATE) 0.5 Other 5.4 total 100.0

As a result of the analysis, it was found that the fragrance reproduced from the fragrance of cellulasechninida flowers combined with the fragrance of the cellulasechnida flowers of Table 1, which was combined according to Table 3, was low and the fragrance reproduction perfume of cellulasechnida flowers of Table 3 The satisfaction of the incense was evaluated to be a little insufficient level. As a result, it was judged that it is impossible to reproduce the fragrance of celloginitida flowers only by the headspace analysis result. Therefore, it was confirmed that it is desirable to reproduce the fragrance of cellulidinitida flowers by adding a new fragrance ingredient based on the head space result.

Experimental Example  3. Various combinations of Cellogine Nitida  Fragrance

<3-1> Cellogine Nitida  Manufacture of fragrance reproduce fragrance of flowers

From the above Experimental Example 1, it can be confirmed that the main component of the fragrance in which the sweet and soft honey notes of the cellosinitida flowers are deeply felt is limonene, phenylethyl alcohol, methyl anthranilate, benzyl acetate and anethole. Accordingly, the present inventors adjusted the content of the above five main components and newly combined the reproducible fragrance of the cellulase crustacea to prepare a fragrance for reproducing the fragrance of the cellulase crustacea. The control sample is the fragrance reproduction perfume (STD) of the cellulasechnitida flower prepared in Experimental Example 2.

Specifically, Comparative Examples 1 to 4 were prepared by keeping the ratio of the five main components constant and changing the total content of the five main components to 60 to 90% by weight. Specific compositions are shown in Table 4 below.

Composition table of fragrance reproduce fragrance of cellojeneitida flower (unit:% by weight) Perfume name STD Comparative Example  One Comparative Example  2 Comparative Example  3 Comparative Example  4 Perfume name (Content:% by weight) 75% 90% 80% 70% 60% Anethole 4.3 5.2 4.6 4.0 3.4 Benzyl acetate 0.8 1.0 0.9 0.7 0.6 D-limonene 46.1 55.3 49.2 43.0 36.9 Methyl anthranilate 0.7 0.8 0.7 0.7 0.6 Phenylethyl alcohol 23.1 27.7 24.6 21.6 18.5 Benzaldehyde 1.4 0.6 1.1 1.7 2.2  L-Carbon 3.2 1.3 2.6 3.8 5.1 L-menton 0.8 0.3 0.6 1.0 1.3 Methyl salicylate 4.2 1.7 3.4 5.0 6.7 Para-cymen 3.3 1.3 2.6 4.0 5.3 Phenylacetic aldehyde 6.2 2.5 5.0 7.4 9.9 Phenyl ethyl acetate 0.5 0.2 0.4 0.6 0.8 DPG (dipropylene glycol) 5.4 2.2 4.3 6.5 8.6 total 100.0 100.0 100.0 100.0 100.0

<3-2> Cellogine Nitida  Sensory Evaluation of Flavor Reproducing Flavor of Flower

The sensory evaluation of the similarity and preference with the fragrance of the cellulasechnitida flower of the fragrance of the fragrance reproduced from the cellulase crustacean flower prepared in the above Experimental Example <3-1> was performed. The sensory evaluation subjects were 20 normal healthy men and women aged 20 ~ 35 years. The similarity of each of the fragrance reproducible fragrances of the cellulase crustacea flowers of Comparative Example 1 to Comparative Examples 1 to 4 was evaluated by the 5-point rating method according to the following Table 5, and the satisfaction was evaluated in accordance with Table 6 The evaluation results are shown in Table 7 below. &Lt; tb &gt;&lt; TABLE &gt; The evaluation room and the sample preparation room were separated so that the evaluator had no prior knowledge of the sample.

5-point Rating Method for Similarity score Similarity One Very different 2 a little bit different 3 so so 4 A little similar 5 Very similar

Five-point rating method for satisfaction score satisfaction One Not very good 2 It's not good. 3 so so 4 A little good 5 very good

Evaluation results - similarity and satisfaction rater Similarity satisfaction number age gender STD Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 STD Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 One 25 female 2 2 3 2 2 2 2 2 2 2 2 27 female 2 3 3 3 2 2 2 2 2 2 3 28 female 3 3 3 3 2 One 2 3 2 2 4 35 female One 2 4 2 2 One 2 3 2 One 5 34 female One One 3 2 3 One 2 3 2 2 6 32 female 2 2 3 2 3 One 2 3 3 3 7 28 female 2 2 4 2 2 One 2 2 One 2 8 29 female 3 3 4 3 3 2 2 3 2 2 9 30 female 2 3 3 2 3 2 3 3 2 2 10 31 female One 2 3 2 3 One One 3 2 2 11 31 female 2 2 3 2 2 One One 3 2 2 12 32 south 2 3 4 3 2 2 One 2 2 2 13 26 south 2 3 3 3 2 One One 2 3 3 14 25 south 2 2 3 3 2 2 One 2 One One 15 25 south One One 3 2 2 One One 2 One One 16 28 south One One 3 2 3 One 2 3 One 3 17 29 south One One 2 2 3 One 2 3 2 One 18 30 south 2 2 3 3 2 2 2 3 2 One 19 25 south One One 2 2 One One One 2 2 2 20 27 south One 2 2 2 One 2 One 2 2 2 Average 28.9 1.7 2.1 3.1 2.4 2.3 1.4 1.7 2.6 1.9 1.9

The average age of the subjects was 35.9 years old, 5 men and 15 women.

As a result of the similarity and satisfaction evaluation, as shown in Table 7, the flavor reproduction perfume (STD) of the Celjinnitida flower of Experimental Example 2 showed a very low degree of similarity, and the content of the five main components was 80% Of Comparative Examples 2 and 3 have the highest degree of similarity and satisfaction among the four combinations, but there is a limit.

Experimental Example  4. Added a new fragrance ingredient Cellogine Nitida  Fragrance

<4-1> Cellogine Nitida  Manufacture of fragrances to improve fragrance of flowers

In order to improve the similarity and the satisfaction of the perfume of Comparative Example 2, in which the cellosynnitida flowers and the fragrance were most similar in Experimental Example 3, fragrance improving fragrance of celloginitida flowers with new fragrance components was prepared.

Specifically, a new combination of improving fragrances was prepared by using 80 to 90% by weight of the perfume of Comparative Example 2, and using artificial synthetic substances such as citronellol, hedione and galactaride. The contents of citronellol, hesidone and galactolide were determined according to the judgment of the professional group of the rootstocks, and they were added in such a manner that the total content of the three components was changed to 10 to 20% by weight, The content was adjusted to meet the total content of 100% by weight. The compositions of the improved fragrances of the new combination are shown in Table 8 below.

Composition table of fresh perfume composition (unit:% by weight) Improve fragrance number Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Anethole 4.6 4.1 4.1 4.1 3.7 3.7 3.7 3.2 Benzyl acetate 0.9 0.8 0.8 0.8 0.7 0.7 0.7 0.6 D-limonene 49.2 44.3 44.3 44.3 39.3 39.4 39.4 34.4 Methyl anthranilate 0.7 0.7 0.7 0.7 0.6 0.6 0.6 0.5 Phenylethyl alcohol 24.6 22.2 22.2 22.2 19.7 19.7 19.7 17.2 Benzaldehyde 1.1 1.0 1.0 1.0 0.9 1.2 1.2 0.8  L-Carbon 2.6 2.3 2.3 2.3 2.0 2.1 2.1 1.8 L-menton 0.6 0.6 0.6 0.6 0.5 0.5 0.5 0.4 Methyl salicylate 3.4 3.0 3.0 3.0 2.7 2.7 2.7 2.4 Para-cymen 2.6 2.4 2.4 2.4 2.1 2.1 2.1 1.8 Phenylacetic aldehyde 5.0 4.5 4.5 4.5 4.0 4.0 4.0 3.5 Phenyl ethyl acetate 0.4 0.4 0.4 0.4 0.3 0.3 0.3 0.3 Citronellol - 10 10 10 10 Hedione - 10 10 10 5 Galaxy Ride - 10 10 10 5 DPG 4.3 3.9 3.9 3.9 3.5 3.1 3.1 3.0 total 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0

<4-2> Cellogine Nitida  Sensory evaluation of fragrance improving fragrance of flowers

The sensory evaluation of the similarity and preference of the fragrance of cellulasechnitida flowers prepared in Experimental Example <4-1> to the fragrance of cellulasechnida flowers was performed. The sensory evaluation subjects were 20 normal healthy men and women aged 20 ~ 35 years. The similarity of each of the fragrance improving fragrances of Cellinineida flowers of Comparative Example 2 and Examples 1 to 7 was evaluated by the 5-point rating method according to Table 4. The degree of satisfaction was evaluated in accordance with Table 5 The evaluation results are shown in Table 9 below. &Lt; tb &gt;&lt; TABLE &gt; The evaluation room and the sample preparation room were separated so that the evaluator had no prior knowledge of the sample.

Evaluation results - similarity and satisfaction
number Similarity satisfaction Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 One 3 3 3 5 4 5 5 5 2 3 3 5 4 5 4 5 2 3 3 3 4 3 3 4 4 2 3 4 3 4 4 4 4 3 3 3 4 4 4 5 4 5 3 3 4 3 3 4 3 5 4 4 4 3 4 3 4 3 4 3 3 3 5 4 4 5 5 5 3 3 4 4 3 5 4 5 3 3 4 4 4 5 4 5 6 3 4 4 3 4 4 5 5 3 3 3 3 3 4 5 4 7 4 3 4 4 4 5 5 5 2 4 4 4 3 3 4 5 8 4 4 4 4 3 4 5 4 3 3 4 3 5 4 5 4 9 3 3 4 4 3 3 4 5 3 3 3 4 4 4 5 4 10 3 4 3 4 4 5 5 4 3 3 4 3 4 4 4 4 11 3 4 4 4 4 4 4 4 3 3 3 4 4 4 4 5 12 4 4 3 4 4 4 5 5 2 3 3 4 4 3 4 5 13 3 3 3 3 3 4 5 5 2 4 3 4 3 4 3 4 14 3 4 4 4 4 3 4 5 2 3 3 5 3 4 4 5 15 3 4 4 5 3 5 4 5 2 4 4 4 3 4 5 5 16 3 4 3 4 4 4 4 4 3 4 4 4 4 4 5 5 17 2 4 3 3 3 3 4 5 3 4 4 5 2 4 5 5 18 3 3 3 3 3 4 4 4 3 4 4 4 3 3 4 5 19 2 4 3 5 4 4 5 5 2 3 3 4 3 4 3 4 20 2 3 4 5 4 4 4 5 2 3 3 4 4 4 4 5 Average 3.1 3.6 3.5 4.0 3.6 4.1 4.4 4.7 2.6 3.3 3.5 4.0 3.6 4.0 4.2 4.7

The subjects were evaluated in the same manner as in Experimental Example 3.

As a result of the similarity evaluation, as shown in Table 9, the comparative example 2 in which only the main components of the C. sinensis flower was combined showed a level of similarity of 3.1. In addition, in the case of the above-mentioned Examples 1 to 7 in which citronellol, hedione and / or galactaride were mixed in Comparative Example 2, the degree of similarity was evaluated to increase. In particular, it was confirmed that the similarity of Example 3 and Examples 5 to 7 in which the galactolide was additionally mixed in Comparative Example 2 was greatly increased, and it was confirmed that galactolide was a major component of the reproduction of the fragrance of the cellulasechnida flower . Further, it is considered that the degree of similarity of Example 7 in which both citronellol, hedione, and galactolide are further mixed is the greatest increase. It was confirmed that a mixture of the above three components had a higher degree of similarity.

As a result of the satisfaction evaluation, as shown in Table 9, the comparative example 2 showed low perfume satisfaction. In addition, in Examples 1 to 7 in which citronellol, hedione and / or galactaride were mixed in Comparative Example 2, the satisfaction of flavor was increased. Particularly, satisfaction with Example 3 and Examples 5 to 7 in which galactolide was additionally mixed in Comparative Example 2 was greatly increased, and it was confirmed that galactolide was a major component in the reproduction of the fragrance of celloginenitida flower . Furthermore, the satisfaction level of Example 7 in which both citronellol, hedione and galactolide were mixed together was the greatest increase. It was confirmed that the combination of the above three components excellently satisfied the perfume.

Thus, the satisfaction of flavor similarity and flavor of the Celogeninida flowers of a composition comprising citronellol, hedione and / or galaxolide, in addition to the flavor components of the Celigninida flowers, It was confirmed that the composition can be used as a home care product and a personal care product as a perfume composition recreating the fragrance of cellulidinitida flowers.

Claims (8)

60 to 90% by weight, based on the whole perfume composition, of a fragrance component of a Coelogyne nitida flower; And 1 to 20% by weight of at least one component selected from the group consisting of citronellol, hedione and galaxolide as an active ingredient. &Lt; / RTI &gt;
The fragrance component of the Celigninida flowers includes limonene, phenylethyl alcohol, methyl anthranilate, benzyl acetate, and anethol. , Perfume composition.
delete The composition of claim 1, wherein the composition is selected from the group consisting of benzaldehyde, L-carvone, methyl salicylate, phenyl acetic aldehyde, para- wherein the perfume composition further comprises at least one component selected from the group consisting of cymene, phenylethyl acetate and L-menthone.
The perfume composition of claim 1, wherein the perfume composition comprises 20 to 60 wt% limonene, 10 to 30 wt% phenylethyl alcohol, 0.1 to 5 wt% methyl anthranilate, 0.1 to 5 wt% Of benzyl acetate, and 1 to 10 wt% of anethole.
The perfume composition of claim 3, wherein the perfume composition comprises from 0.1 to 10% by weight of benzaldehyde, from 0.1 to 15% by weight of L-carboxy, from 0.1 to 15% by weight of methyl salicylate, from 0.1 to 30% The composition of claim 1, wherein the perfume composition comprises 0.1 to 10% by weight of phenylacetic aldehyde, 0.1 to 10% by weight of para-cymene, 0.1 to 30% by weight of phenylethyl acetate and 0.1 to 10% .
The perfume composition of claim 1, wherein the perfume composition comprises 1 to 20% by weight of citronellol, 1 to 20% by weight of heddione, and 1 to 20% by weight of galactaride, based on the total perfume composition Composition.
7. A home care product comprising a perfume composition according to any one of claims 1 and 6 to 6.
6. A personal care product comprising a perfume composition according to any one of claims 1 and 6 to 6.