KR20170110902A

KR20170110902A - Perfume composition

Info

Publication number: KR20170110902A
Application number: KR1020160035289A
Authority: KR
Inventors: 이지민; 김후덕
Original assignee: 주식회사 엘지생활건강
Priority date: 2016-03-24
Filing date: 2016-03-24
Publication date: 2017-10-12

Abstract

The present disclosure relates to citrus flower fragrance ingredients; And an artificial flavor component. The present invention also relates to a flavor composition recreating a citron flower scent.

Description

Perfume composition {PERFUME COMPOSITION}

The present specification relates to a perfume composition capable of reproducing a citron flower component.

Citron junos (Citron junos) is an evergreen shrub with mosquito, and is native to Korea, China, and Japan. In Korea, it grows in southern regions of Goheung, Wando, Gyeongnam, Geoje, Namhae and Tongyeong in Korea. The height of citron is about 4m high and has pointed thorns on branches. Leaves are alternate and long ovate, with dull serrate on edge, wing on petiole.

Flowers are bisexual and bloom in May to June, with one on the axilla. There are 5 calyxes and petals, 20 of which are merged together or divided into five.

The kind of citron, the citron of citron, is the citron, the celadon, and the fenugreek, and it has a spherical shape with a diameter of 4 ~ 7cm and ripen in September ~ October. Its color is bright yellow and its surface is rugged and fragrant. The Korean is the thickest, the shell is thick, and the breeding is by seeding or grafting.

Citron flowers have their own differentiated fragrance, but fruit is widely used commercially, so there is a limit to using the fragrance on an industrial scale in its natural state.

Therefore, it is required to develop a perfume composition having a unique characteristic of oriental varieties by artificially reproducing and reproducing the natural citron flower fragrance.

Korean Patent Publication No. 2004-0031023

The present specification reproduces the inherent fragrance of citron flowers and provides a perfume composition having excellent palatability.

According to one embodiment of the present disclosure, citron floral component; And an artificial flavor component, wherein the artificial flavor component is selected from the group consisting of Methyl Anthranilate, Citronellyl Nitrile, Methyl Pamplemousse, Ylang ylang flower Oil ) And petitgrain oil. The present invention also provides a perfume composition comprising:

According to an embodiment of the present invention, there is provided an external preparation for skin comprising the perfume composition.

According to one embodiment of the present disclosure, there is provided a personal care product comprising the perfume composition.

According to one embodiment of the present disclosure, there is provided a home care product comprising the perfume composition.

The perfume composition according to one embodiment of the present invention can reproduce the citron flower fragrance without damaging the citron flower.

In addition, the perfume composition according to one embodiment of the present disclosure has a high degree of similarity and / or high satisfaction with the citron flower fragrance.

Hereinafter, the present invention will be described in more detail.

Whenever a component is referred to as "comprising ", it is to be understood that the component may include other components as well, without departing from the scope of the present invention.

According to one embodiment of the present invention, the citron flower fragrance ingredient is a natural component of citron flower.

According to one embodiment of the present disclosure, the citron flower component is selected from the group consisting of Limonene, Linalool, Phenylacetaldehyde, Geraniol, cis-Jasmone and Indole ).

Limonene, Linalool, Phenylacetaldehyde, Geraniol, cis-Jasmone and Indole are the flavor components of citron flowers. However, in the case of containing only the above-described citron flower component, it is impossible to reproduce the original citron flower fragrance.

The perfume composition according to one embodiment of the present invention may contain at least one component selected from the group consisting of Methyl Anthranilate, Citronellyl Nitrile, Methyl Pamplemousse, Ylang ylang flower oil, and petitgrain oil. The flavor of the citron flower can be reproduced, and the flavor of the citron flower can be reproduced and excellent palatability can be obtained.

Generally, as a method of collecting the fragrance, extraction using distillation using a solvent, distillation using steam, and the like are used, but in the process of extracting the fragrance component, the disappearance of the fragrance component by heating, , And changes, and there are many differences from the characteristic features of the raw materials. Headspace and solid phase microextraction (SPME) methods have been developed to overcome these drawbacks. These two methods can be used to analyze the fragrance components with the conventional method and the sample itself, which is a good way to reproduce the fragrance of the living state of the sample.

In one embodiment of the present invention, the citron flower component can be analyzed and / or collected using a headspace method, but the method is not limited thereto.

According to one embodiment of the present disclosure, the content of the citron flower component is 61.3 to 89 wt% based on the total weight of the perfume composition,

The content of the artificial flavor component is 11 to 38.7% by weight based on the total weight of the perfume composition.

According to one embodiment of the present disclosure, the citron flower component is selected from the group consisting of Limonene, Linalool, Phenylacetaldehyde, Geraniol, cis-Jasmone and Indole ),

The artificial flavor component may be selected from the group consisting of Methyl Anthranilate, Citronellyl Nitrile, Methyl Pamplemousse, Ylang ylang flower Oil and Petitgrain Oil ),

The content of limonene is 20 to 28% by weight, the content of linalool is 16 to 22% by weight and the content of phenylacetaldehyde is 11 to 30% by weight based on the total weight of the perfume composition. The content of geraniol is from 11 to 15% by weight, the content of cis-Jasmone is from 3 to 7% by weight, the content of indole is from 0.3 to 2% by weight, , The content of methyl anthranilate is 4 to 12% by weight, the content of citronellyl nitrile is 4 to 12% by weight, the content of methylpolyamphos is 2 To 7% by weight, the content of ylang ylang flower oil is 0.7 to 5.2% by weight, and the content of petitgrain oil is 0.3 to 2.5% by weight.

In the present specification, the citron flower fragrance ingredient and artificial flavor ingredient may be manufactured using commercially available products, separated from plants or synthesized, but not limited thereto.

Further, according to one embodiment of the present disclosure, the perfume composition may further include a solvent.

Based on the total weight of the perfume composition, 0 to 50% by weight of the solvent.

The solvent may be a solvent used in the art. Examples of the solvent include dipropylene glycol, isopropyl myristate, and the like.

According to an embodiment of the present invention, there is also provided a cosmetic comprising the perfume composition.

Examples of the cosmetics include basic cosmetics, makeup cosmetics, facial cleansing products, and the like. There are no particular restrictions on the formulations, and examples of the cosmetics may include gels, lotions, ampoules, milks, oils, ointments, patches, sprays, It may be one selected formulation.

The basic cosmetic products include, but are not limited to, lotions, creams, essences, gels, lotions, packs, nutritional creams, massage creams, milky lotions, sunscreen creams, sun oils and the like.

The makeup cosmetic products include, but are not limited to, foundation, makeup base, lipstick, eye shadow, eyeliner, mascara, eyebrow pencil and the like.

The facial cleansing products include, but are not limited to, cleansing creams, cleansing foams, cleansing waters, and cleansing oils.

Examples of the personal care products include hair products such as shampoos, conditioners, waxes, gels, mousses, hair treatments and hair essences; Toothpaste, mouthwash and other oral products; Skin cleansing agents such as soaps, body cleansers and bath salts; Skin moisturizers such as body creams and body lotions; Perfume, and the like.

The home care product may include a perfume; And detergents such as a liquid detergent, a kitchen detergent, a laundry detergent, a fabric softener, a bathroom detergent, and a fiber deodorant.

According to one embodiment of the present invention, the composition may further contain, in accordance with the formulation, additives commonly used in the art such as perfumes, coloring matters, bactericides, antioxidants, preservatives, moisturizers, thickeners, inorganic salts, .

The content of the active ingredient may vary depending on the formulation and purpose. For example, wash-off type cosmetics such as make-up removers, detergents and the like where the active ingredients stay on the skin in a short period of time may be relatively high concentrations. On the other hand, in the case of leave-on type cosmetics such as lotion, cream, essence and the like in which the active ingredient remains on the skin for a long period of time, the concentration may be lower than that of the wash-off type cosmetics.

The cosmetic, personal care, and home care products may be included within the scope of not impairing the object of the present invention, and are not limited to the contents and formulations included. By selecting the above-mentioned additives, Can be selected and manufactured.

Hereinafter, the present invention will be described in detail by way of examples with reference to the drawings. However, the embodiments according to the present disclosure can be modified in various other forms, and the scope of the present specification is not construed as being limited to the embodiments described below. Embodiments of the present disclosure are provided to more fully describe the present disclosure to those of ordinary skill in the art.

Experimental Example 1: Analysis of fragrance components of citron flowers using headspace method

The headspace analysis method is a method in which a sample fragrance ingredient can be sampled as it is in a natural state. In this specification, headspace analysis is used for analyzing the fragrance component of citron flower, and component analysis is performed using the method described in the literature Respectively. A sealed rappel was placed on the citron flower part, and circulated air was passed through the tenax column while forced circulation of the outside air was performed with a power device to capture the fragrance component. The analysis results of the fragrance components of citron flowers are shown in Table 1 below.

Analytical Instruments: Hewlett Packard 6890

Detector: FID

Column: HP-20M 0.2mm ID X 25m

Injection temperature: 250 ° C

Detector temperature: 250 ° C

Oven temperature: 55 占 폚 (0 minutes) to 215 占 폚 (40 minutes), 4.0 占 폚 / min

Split Ratio: 30: 1

Mobile phase gas: helium 18 cm / sec

Injection amount: 0.3ml

Perfume name weight% Limonene 24.66 Linerul 18.72 Phenylacetaldehyde 14.20 Zerrani 14.11 Jason 5.39 Indole 0.97 Other 21.95 total 100.00

As a result of the analysis, it was confirmed that the fragrance components of natural citron flowers were 24.66% by weight of limonene, 18.72% by weight of linalool, 14.2% by weight of phenylacetaldehyde, 14.11% by weight of geraniol, 5.39% by weight of jasmone and 0.97% Respectively. Further, it was confirmed that the total amount of the above components was about 78.05% by weight based on the whole of the natural citron flower component.

Experimental Example 2: Analysis of description of fragrance components and reproducible fragrance of citron flower

Representative fragrances composed of the citron flower component in Table 1 and the combination of the following Table 2 analyzed in Experimental Example 1 were analyzed by the following process.

The sensory evaluation subjects were selected five professional irrigation experts engaged in the fragrance industry, and descriptive analysis was performed on the natural citron flower fragrance and reproduction perfume respectively.

Perfume name weight% Limonene 24.66 Linerul 18.72 Phenylacetaldehyde 14.20 Zerrani 14.11 Jason 5.39 Indole 0.97 Dipropylene glycol 21.95 total 100.00

As a result of the analysis, Experimental Example 1 and Experimental Example 2 show differences in the presence or absence of other indipropylene glycol, and the similarity between the combined fragrance and the citron flower component in Table 1 is low, Satisfaction of the fragrance was evaluated to be a little insufficient level.

Therefore, it was judged that it is impossible to reproduce the smell of citron flowers only by the headspace analysis result. Therefore, it was confirmed that it is preferable to reproduce the citron scent by adding a new perfume ingredient based on the head space result.

Experimental Example 2: Preparation of perfume composition

The citrus flower scent is a scent of citrus-like incense and floral scent like citron, and it is a new feature scent different from the traditional scent of flowers. Accordingly, the artificial fragrance component of methylanthranilate, citronellynitrile, methylpamplemos, ylang ylang flower oil, and petitgrain oil having these characteristics is further applied, and limonene, linalool, phenylacetaldehyde, And perfume compositions of Comparative Examples 1 to 3 and Examples 1 to 6 were prepared as shown in Table 3 by adding a main ingredient of citron blossom such as alum, jasmone and indole.

Perfume name Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Limonene 24.66 24.0 22 24.7 27.0 20.0 25.0 22.0 23.5 Linerul 18.72 19.0 20 18.7 15.5 19.5 17.5 18.5 19.2 Phenylacetaldehyde 14.20 14.2 14.0 14.2 10.2 12.3 16.5 13.5 13.8 Zerrani 14.11 14.0 12.0 14.0 12.0 15.0 13.8 10.3 13.1 Jason 5.39 5.5 6.0 5.5 7 6.0 4.0 4.5 4.4 Indole 0.97 1.0 1.0 1.0 1.5 0.8 1.1 1.0 0.9 Methylanthranilate - - - 5.0 - 10.0 8.0 6.0 8.8 Citronellyl nitrile - - - 5.0 8.0 - 10 9.0 8.3 Methyl palm Flemos - - - 3.0 5.0 3.0 - 3.0 4.5 Ylang Ylang flower oil - - - - 5.0 3.0 2.0 3.0 2.4 Petit Grain Oil - - - - 3.0 2.0 0.5 1.5 1.1 Dipropylene glycol 21.95 22.3 25.0 8.9 5.8 8.4 1.6 7.7 - total 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0

(Unit: wt%)

Experimental Example 4: Evaluation of perfume similarity of perfume composition

The sensory evaluation of the similarity of the citron flower scent was carried out on 20 healthy male and female 20 to 35 year olds. The average age of the subjects was 27.6 years old, 9 men and 11 women. The similarity was evaluated by the five-point scale method for the perfume compositions prepared in Comparative Examples 1 to 3 and Examples 1 to 6 with the questionnaire of Table 4 below.

The evaluation room and the sample preparation room were separated so that the evaluator had no prior knowledge of the sample.

The results of similarity evaluation of citron blossom of Comparative Examples 1 to 3 and Examples 1 to 6 are shown in Table 5 below.

score Similarity One Very different 2 a little bit different 3 so so 4 A little similar 5 Very similar

number age gender Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 One 21 female One One 2 2 2 3 3 4 4 2 28 female 2 2 2 2 3 4 4 4 4 3 26 south 2 One One 2 2 3 2 3 5 4 23 south One 2 2 3 3 3 3 4 5 5 22 female One 2 2 3 3 4 3 5 5 6 22 female 2 One 2 2 4 3 3 4 3 7 29 south One 2 2 2 3 3 4 4 5 8 24 female 2 One One 2 3 4 3 3 3 9 33 female One 2 2 3 3 4 3 3 5 10 27 south 2 2 2 3 3 2 3 4 5 11 22 female 2 2 2 2 4 4 4 5 4 12 25 female One One One 2 3 4 4 3 3 13 28 south 2 2 One 2 2 4 3 4 4 14 31 south 2 2 2 3 3 4 4 4 3 15 32 south One 2 2 3 2 3 3 4 5 16 33 female One 2 2 3 3 3 3 5 5 17 24 female One One 2 3 2 4 4 4 4 18 29 female 2 2 One 2 3 2 3 5 5 19 35 south One One 2 2 3 3 3 4 4 20 34 south One 2 2 3 4 4 3 3 5 Average 27.6 1.45 1.65 1.75 2.45 2.90 3.40 3.25 3.95 4.30

As a result of the above Table 5, the Comparative Example 1 was prepared according to the main ingredient and content of the fragrance of the naturally occurring citron flowers analyzed in Experimental Example 1, and showed a very low degree of similarity. In Comparative Examples 2 and 3, The composition was the same as that of Comparative Example 1, but the content was adjusted, and the similarity degree of the fragrance slightly increased.

On the other hand, it has been found that it is composed of methyl anthranilate, citronellyl nitrile, methyl pamplemousse, ylang ylang flower oil and petitgrain oil Examples 1 to 6 containing at least one artificial flavor component selected from the group were evaluated to have increased similarity.

In particular, it is possible to use artificial flowers such as Methyl Anthranilate, Citronellyl Nitrile, Methyl Pamplemousse, Ylang ylang flower Oil and Petitgrain Oil It was confirmed that the degree of similarity was the highest in Examples 5 and 6 in which the perfume ingredients were mixed.

Experimental Example 5: Evaluation of fragrance composition perfume

The sensory evaluation of the satisfaction of the citron blossom aroma was performed on 20 healthy male and female 20 to 35 year olds. The average age of the subjects was 27.6 years old, 9 men and 11 women. The evaluation of the satisfaction was made by the five-point scale method for the perfume compositions prepared in Comparative Examples 1 to 3 and Examples 1 to 6 with the questionnaire of Table 6 below.

The results of Satisfaction satisfaction evaluation of citron flowers of Comparative Examples 1 to 3 and Examples 1 to 6 are shown in Table 7 below.

score satisfaction One Not very good 2 It's not good. 3 so so 4 A little good 5 very good

number age gender Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 One 21 female 2 2 3 3 3 3 4 5 5 2 28 female 2 2 3 3 3 4 4 4 4 3 26 south 2 One 2 2 2 3 2 4 4 4 23 south 2 2 2 3 3 4 3 4 5 5 22 female One 2 3 4 3 4 3 5 5 6 22 female 2 One 2 4 5 4 4 4 3 7 29 south One 2 2 2 3 3 4 4 5 8 24 female 2 2 One 2 3 4 3 3 3 9 33 female One 2 3 4 3 4 4 3 5 10 27 south 2 3 3 3 4 3 3 4 5 11 22 female 2 3 2 3 4 4 4 4 4 12 25 female One One One 3 3 3 4 3 3 13 28 south 2 2 One 3 3 4 3 4 5 14 31 south 2 3 3 3 3 3 3 4 3 15 32 south One 2 2 3 2 3 3 5 5 16 33 female One 2 2 3 3 3 3 5 5 17 24 female 2 One 3 4 3 4 4 4 4 18 29 female 2 One One 2 3 2 3 4 5 19 35 south 2 One 2 3 4 3 3 5 5 20 34 south One 2 3 4 4 4 4 3 4 Average 27.6 1.65 1.85 2.20 3.05 3.20 3.45 3.40 4.05 4.35

As a result of the above Table 7, the Comparative Example 1 was prepared according to the main ingredient and content of the fragrance of the naturally occurring citron flowers analyzed in Experimental Example 1, and showed very low satisfaction, and Comparative Examples 2 and 3 The composition of Example 1 was the same, but the content was controlled, and the satisfaction of Comparative Examples 2 and 3 was also below the average.

On the other hand, it has been found that it is composed of methyl anthranilate, citronellyl nitrile, methyl pamplemousse, ylang ylang flower oil and petitgrain oil Examples 1 to 6 containing one or more artificial flavor components selected from the group were evaluated to have increased satisfaction.

Particularly, a mixture of methyl anthranilate, citronellyl nitrile, methyl pamplemousse, ylang ylang flower oil and petitgrain oil In the case of Examples 5 and 6, it was confirmed that the satisfaction was the greatest.

As a result of the above Tables 5 and 7, it was confirmed that the citron flower fragrance ingredient was added with methyl anthranilate, citronellyl nitrile, methyl pamplemousse, ylang ylang flower Oil and petitgrain oil, it was confirmed that the fragrance unique to the citron flower and the high similarity and satisfaction were improved.

Claims

Citron flower fragrance ingredient; And an artificial flavor component,
The artificial flavor component may be selected from the group consisting of Methyl Anthranilate, Citronellyl Nitrile, Methyl Pamplemousse, Ylang ylang flower Oil and Petitgrain Oil ). &Lt; / RTI >

The method according to claim 1,
Wherein the citron floral fragrance component comprises Limonene, Linalool, Phenylacetaldehyde, Geraniol, cis-Jasmone and Indole.

The method according to claim 1,
Wherein the content of the citron flower component is 61.3 to 89 wt% based on the total weight of the perfume composition,
Wherein the content of the artificial flavor component is from 11 to 38.7% by weight based on the total weight of the perfume composition.

Citron flower fragrance ingredient; And an artificial flavor component,
Wherein the artificial flavor component comprises 4 to 12% by weight of methyl anthranilate, 4 to 12% by weight of citronellyl nitrile, 4 to 12% by weight of methyl ethyl palmitate, 2 to 7% by weight of Pamplemousse, 0.7 to 5.2% by weight of ylang ylang flower oil and 0.3 to 2.5% by weight of Petitgrain Oil,
Wherein the fragrance composition comprises 20 to 28% by weight of limonene, 16 to 22% by weight of linalool, 11 to 15% by weight of phenylacetaldehyde, From 11 to 15% by weight of geraniol, from 3 to 7% by weight of cis-Jasmone and from 0.3 to 2% by weight of indole.

A cosmetic comprising the perfume composition according to any one of claims 1 to 4.

A personal care product comprising a perfume composition according to any one of claims 1 to 4.

A home care product comprising a perfume composition according to any one of claims 1 to 4.