KR101796154B1 - Perfume composition for expressing the fragrance of Freesia hybrida 'Shiny Gold' - Google Patents

Abstract

The present invention relates to a perfume composition capable of reproducing the fragrance of Phrygia shiny gold. The perfume composition according to the present invention is characterized in that a main flavor component of natural Freesia shiny gold is one kind selected from the group consisting of Bergamot oil, Citronellol, and Alpha hexyl cinnamic aldehyde By adding the above components, the similarity and satisfaction of the fragrance can be remarkably improved, and thus, fragrance compositions that reproduce the fragrance of Phrygia shiny gold can be effectively used.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a perfume composition for expressing fragrance of Freesia shiny gold,

The present invention relates to a fragrance composition capable of reproducing a fragrance of Phrygia shiny gold, and relates to a fragrance composition having improved similarity and satisfaction with fragrance inherent to Phrygia shiny gold.

Freisia, a spring messenger, is a typical flower with a particular appeal in the graduation and admission season. It is a cultivar loved by many people with its simple yet charming fragrance and beautiful figure. Freesia is a perennial plant with an iris. Scientific name is Freesia hybrida . South Africa is widely grown for ornamental purposes.

Alfalfa is fusiform, and when planted around September, it shoots soon, 5-6 leaves grow in winter, 8-12 leaves grow in buds. The flower stalk is 30-45cm, but the improvement is more than 60cm. The branch is split at the upper part, and the flower ear is bent at right angle and the flower runs in one line. The flower is like a funnel, its tip is divided into 6 pieces and spreads, it is yellowish white, but there is a purple line in the center of the outer petal. The calyx inside is yellow, with a triangular pattern of yellow, but there are many pure white colors in red color. There are various varieties with flower color such as white, pink, red, purple, etc., and flowers are bloomed from December when they are placed in a hotbed around November. When the leaves are dry in May, they are dried, stored and re-planted.

The Friisia shiny gold varieties were developed in 1998 by crossing Yvonne, a yellow-tender, Arizona-bearing yellow-bred double-blight. From 1999 to 2002, it underwent a four - year characterization test. In 2003, it was breed after the decision of the Rural Development Administration 's new selection committee. It is a thick yellow-colored double flower, it is a round-type large-sized flower, and its fragrance is strong. Shiny gold varieties won the prime minister's prize in the best varieties of Korea in 2013. By the early 2000s, Yvonne's market share was 99%, but Shiny Gold's market share rose from 3% in 2008 to 31.4% As a result, Yvonne's market share dropped to 39.0%.

Rural Development Administration Flower No.1 Development Shiny gold, a flower varietal, is known to have a beautiful flower and a better aroma than Yvonne because it is large and three-dimensional and has a clear yellow flower. Accordingly, it is required to develop a perfume composition having differentiated and new features by reproducing the fragrant fragrance of the Freesia shiny gold naturally.

The present inventors tried to reproduce the original fragrance of Friisia shiny gold by analyzing the main fragrance ingredient and content of Friya shiny gold. However, it is not possible to reproduce the fragrance inherent to the Friisian shiny gold only by the combination of the components and the analyzed content, and it is confirmed that the fragrance inherent to the Friisia shiny gold can be similarly reproduced by adding a new fragrance component to the fragrance , Thereby completing the present invention.

Accordingly, it is an object of the present invention to provide a fragrance composition which can reproduce the fragrance inherent in Friisia shiny gold and has excellent taste.

Another object of the present invention is to provide various uses such as the external preparation for skin, the cosmetic, the personal care product and the home care product of the perfume composition.

However, the technical problem to be solved by the present invention is not limited to the above-mentioned problems, and other matters not mentioned can be clearly understood by those skilled in the art from the following description.

As a means for solving the above-mentioned problems, the present invention relates to a process for the preparation of a compound of formula (I), wherein Linalool, Alpha terpineol, Ocimene Eucalyptol, Myrcene, D-limonene and containing at least one member selected from the group consisting of Bergamot oil, Citronellol, and Alpha hexyl cinnamic aldehyde, A fragrance composition recreating the fragrance is provided.

As another means for solving the above problems, the present invention provides an external preparation for skin comprising the above-mentioned perfume composition.

As another means for solving the above problems, the present invention provides a cosmetic comprising the perfume composition.

As another means for solving the above problems, the present invention provides a personal care product comprising the perfume composition.

As another means for solving the above problems, the present invention provides a home care product comprising the perfume composition.

According to the perfume composition of the present invention, at least one perfume composition selected from the group consisting of Bergamot oil, Citronellol, and Alpha hexyl cinnamic aldehyde is added to the fragrance ingredient combination of Freisia shiny gold. By adding the ingredient, it is possible to remarkably improve the similarity and the satisfaction of the fragrance, so that it can be usefully used as a perfume composition recreating the perfume shiny gold flavor.

Hereinafter, the present invention will be described in detail.

The present invention relates to a pharmaceutical composition comprising Linalool, Alpha terpineol, Ocimene Eucalyptol, Myrcene, and D-limonene, Wherein the fragrance composition contains at least one selected from the group consisting of Bergamot oil, Citronellol, and Alpha hexyl cinnamic aldehyde.

Generally, fragrance is extracted by extraction with a solvent, distillation using water vapor, etc. However, the above methods are not suitable for extracting fragrance components by heating, , And changes, and there are many differences from the characteristic features of the original substance. Headspace and SPME (Solid-Phase Micro Extraction) methods have been developed to overcome these disadvantages. These two methods do not require solvent pretreatment nor require a large amount of sample because they do not use solvents and can analyze the fragrance component with the sample itself, so that a good method to reproduce the original fragrance of the sample . In addition, the content of the fragrance ingredient of the Friisia shiny gold injected through the SPME can be analyzed by Gas Chromatograph-Mass spectrophotometry (GC-MS).

The present invention will be described in more detail on the basis of the fragrance ingredient and content of Phosphorus shiny gold obtained by such a perfume component analysis technique.

In one embodiment of the present invention, the fragrance composition recreating the fragrance of the present invention of Freesia shiny gold may include the main fragrance components of natural Freesia shiny gold, and more specifically, 60 to 70% by weight of linalool, 10 to 15% by weight of alpha terpineol, 10 to 15% by weight of ocimene, 0.5 to 1.5% by weight of eucalyptol, 0.5 to 1.5% by weight, and D-limonene in an amount of 0.5 to 1.5% by weight. However, the content may be out of the above range, so long as it does not affect the reproducibility of the fragrance of Phrygian shiny gold.

However, the main fragrance components of the natural frieze shiny gold can not reproduce the fragrance of the pharyngeal shiny gold well, and the fragrance of the fragrance is poor. Therefore, the total weight of the composition is selected from the group consisting of Bergamot oil, More preferably 1 to 4% by weight of at least one member selected from the group consisting of citronellol, alpha-hexyl cinnamic aldehyde and the like, more preferably Bergamot oil, 1 to 4% by weight of citronellol, 1 to 4% by weight of citronellol and 1 to 4% by weight of alpha hexyl cinnamic aldehyde, The content may be out of the above range.

On the other hand, the above-mentioned Linalil, alpha terpineol, ocimene, eucalyptol, myrcene, dymolimene, bergamot oil, citronerol, and alpha-hexyl cinnamic aldehyde can be obtained by using a commercially available product, . ≪ / RTI >

In addition, the perfume composition of the present invention may further include a flavor-imparting agent well known in the art in order to further improve the satisfaction of the fragrance of shiny pharyngeal shine gold. The content of the flavourinizing agent may be 0.1 to 10% by weight or 1 to 5% by weight based on the total weight of the composition, but is not limited thereto.

The perfume composition of the present invention may be provided in combination with an external preparation for skin or a cosmetic composition to the extent that the object of the present invention is not impaired.

The external preparation for skin may be an ointment, a lotion, a usable image, a suspension, an emulsion, a cream, a gel, a spray, a papermaking agent, a warning agent, a patch agent or a water paste. The cosmetic composition may be a basic cosmetic, a makeup cosmetic, Examples of the basic cosmetics include essences, lotions, creams, gels, lotions, packs, massage creams, milks, and the like; Examples of the makeup cosmetics include a foundation, a makeup base, and the like; Body cosmetics include, but are not limited to, soaps, liquid cleansers, bath salts, sunscreen creams, sun oils, and the like. However, the content of the active ingredient may vary depending on the formulation and purpose of the composition. For example, wash-off type cosmetics such as make-up remover, detergent and the like in which the active ingredient remains on the skin in a short period of time may be relatively high concentration, while cosmetics, milky lotions, creams, In the case of a leave-on type cosmetic product such as an essence, it may contain a lower concentration than a wash-off type cosmetic product.

The perfume composition of the present invention may be provided in combination with a personal care product or a home care product to the extent that the object of the present invention is not impaired.

The personal care product may be a hair product such as a shampoo, a rinse, a treatment, and a hair essence; Toothpaste, mouthwash and other oral products; A body wash, a bar diesel, a soap, and the like, and the home care product may be perfume or perfume; Laundry detergents such as fabric softener, kitchen detergent, and the like, but are not limited thereto. At this time, a perfume, a coloring agent, a bactericide, an antioxidant, an antiseptic, a moisturizer, a thickening agent, an inorganic salt, a synthetic polymer material and the like may be further added to the composition for improving physical properties.

Hereinafter, preferred embodiments of the present invention will be described in order to facilitate understanding of the present invention. However, the following examples are provided only for the purpose of easier understanding of the present invention, and the present invention is not limited by the following examples.

Example  One. Phrygia shiny  Analysis of aroma components of gold

 The volatile flavor components of Freesia shiny gold were extracted by SPME (solid-phase microextraction) method and analyzed by GC-MS (gas chromatography mass spectrometry). A 65μm PDMS / DVM SPME fiber was used to collect the fragrance components. First, the fiber was cleaned at 230 ° C for 30 minutes, and then the kit was attached at room temperature while adjusting the fiber length with the O-ring of the syringe. Then, the flower was sealed using a zipper bag, the fiber was carefully pierced, and the fragrance was extracted for about 2 hours. The fragrance-collected fiber was transferred to a GC-MSD inlet and desorbed for 1 minute and analyzed by GC-MS.

Specific analytical conditions for analyzing the kind and content of the fragrant ingredient of the collected pharyngeal shiny gold are as follows.

<Analysis condition>

Analytical Instruments: Agilent GC-7890 A / 5975C MSD

Detector: MSD

Column: VF-WAXms (60 m x 320 m x 0.5 m)

Injection temperature: 250 ° C

Detection temperature: 230 ℃

Oven temperature: 70 ° C (3 ° C / min) -> 170 ° C (5 ° C / min) -> 30 ° C

Column flow rate: 1.2 ml / min

Mobile phase gas: He

Injection amount: 0.5 μl

As a result, as shown in Table 1 below, the principal fragrance components of the Freesia shiny gold were linalool (65.51%), alpha terpineol (11.44%), ocimer (11.15%), eucalyptol (0.78%), and dimolimene (0.78%), which accounted for about 90.46% of the total fragrance components.

Example  2. Phrygia shiny  Preparation and Sensory Evaluation of Combination Spices of Gold Flavor Components

2-1. Phrygia shiny  Manufacture of fragrances combined with gold fragrant ingredients

Based on the fragrance component results of the Friisia shiny gold analyzed in the above Example 1, the fragrance ingredient combination of Freesia shiny gold fragrance having the composition shown in the following Table 2 was prepared.

2-2. natural Phrygia shiny  Sensory evaluation for comparison with the scent of gold

The sensory evaluation was performed in order to examine the similarity of the perfume shine gold fragrance ingredient perfume prepared in Example 2-1 and the natural freesia shiny gold perfume. Specifically, the sensory evaluation was carried out on 20 normal male and female adults aged 20 to 50 years. The fragrance components of the fragrance component of Freesia shiny gold manufactured in Example 2-1 and the fragrance of natural free-shiny shiny gold were evaluated , And by responding to the questionnaire shown in Table 3 below, the fragrance similarity (Question 1) and the taste preference (Q 2 and 3) of the fragrance ingredient combination of Freisia shiny gold fragrant ingredient and natural freesia shiny gold flower were examined.

As a result, as shown in Table 4 below, the fragrance similarity of the fragrance ingredient combination of Freisia shiny gold and natural Frisiaia shiny gold was not very similar to the average of 2.05 points, and the result was also 2.20 in average. From the above results, it can be seen that the fragrance of Friisia shiny gold can not be reproduced with only a simple combination of fragrance components of Friisia shiny gold.

Example  3. Phrygia shiny  Manufacture of fragrance to reproduce gold fragrance

When comparing the fragrance of the Freesia shiny gold fragrant ingredient combination fragrance produced in Example 2-1 and the natural freesia shiny gold fragrance by the sensory evaluation of the professional steerer, the combined fragrance had less citrus and floral feeling than the natural freesia shiny gold The result is that the fragrance is rough. In order to improve the rough feeling of the fragrance while adding a citrus and floral feeling, citrus notes of citrus notes, citronerol of rose floral notes, and alpha-hexyl cinnamic aldehyde of soft jasmine floral notes were added, Similarly, the formulations of Preparation Examples 1 to 5 were prepared.

Example  4. Natural Phrygia shiny  Sensory evaluation for comparison with the scent of gold

Sensory evaluation was performed on the similarity and preference degree of the fragrance between the products of Production Examples 1 to 5 and natural freesia shiny gold by the same method as in Example 2-2. Specifically, the flavor of the preparation example and the natural flavor of Freisia shiny gold were compared with each other, and after a comparison of one flavor, a rest time of about 5 minutes was given to avoid the olfactory paralysis phenomenon.

As a result, as shown in the following Table 6, similarity and preference of the fragrance were slightly increased in Production Example 2 in which citronellol (3% by weight) was added, while in the production example in which bergamot oil (3% by weight) 1, and alpha-hexyl cinnamic aldehyde (3% by weight) were added, the similarity and preference of the fragrance were significantly increased. Further, in Production Example 4 and Production Example 5 in which bergamot oil (2 or 3 wt%), citronell (2 or 3 wt%), and alpha-hexyl cinnamic aldehyde (3 wt%) were added, Was significantly increased. From the above results, it is preferable to add bergamot oil or alpha-hexyl cinnamic aldehyde when only a single ingredient is added to the combined fragrance of fragrance of Fresia shiny gold to reproduce the fragrance of Friisia shiny gold, It is possible to remarkably improve the reproducibility and the satisfaction of the fragrance.

Formulation Example  1. perfume manufacturing

A perfume composition containing a perfume composition having similarity to the fragrance of Phrygia shiny gold was prepared by the following composition.

Flavor of Production Example 4: 15 wt%

Alcohol: 82.3 wt%

Water 2: wt%

Pigment:

Sunscreen: good

Claims (8)

Wherein the composition comprises 60 to 70% by weight of linalool, 10 to 15% by weight of alpha terpineol, 10 to 15% by weight of ocimene, 0.5 to 15% by weight of eucalyptol, 1.5 to 1.5% by weight, Myrcene 0.5 to 1.5% by weight, and D-limonene 0.5 to 1.5% by weight,
The flavor of Freesia shiny gold, which contains 1 to 4 wt% each of at least one selected from the group consisting of Bergamot oil, Citronellol, and Alpha hexyl cinnamic aldehyde, .
delete delete The method according to claim 1,
1 to 4% by weight of Bergamot oil, 1 to 4% by weight of Citronellol and 1 to 4% by weight of Alpha hexyl cinnamic aldehyde based on the total weight of the composition &Lt; / RTI &gt;
7. An external preparation for skin comprising the perfume composition according to claim 1 or claim 4.
A cosmetic composition comprising the perfume composition according to any one of claims 1 to 4.
6. A personal care product, comprising a perfume composition according to any one of claims 1 to 4.
7. A home care product comprising a perfume composition according to any one of claims 1 to 4.