KR101669664B1 - Perfume composition for expressing the fragrance of achillea sibirica and skin external composition using the same - Google Patents

Abstract

The present invention relates to a perfume composition recreating the scent of milky lot and a composition for external application for skin containing the perfume composition.
The perfume composition of the present invention may contain at least one selected from the group consisting of Eucalyptol, Alpha-Pinene, Beta-Pinene, Camphor, Caryophyllene, Limonene, Phenylethyl Alcohol, Linalool and Eugenol as main fragrance components to reproduce the fragrance of natural crepe, and to improve the palatability by containing additional ingredients to give the main fragrance ingredient a feeling of being pure and clean , And the fragrance composition recreating the fragrance of the yarrow is applied to various bases.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a perfume composition,

The present invention relates to a perfume composition recreating the scent of milky lot and a composition for external application for skin containing the perfume composition. More particularly, the present invention relates to a perfume composition recreating the scent of milky lotion, And at least one member selected from the group consisting of cyclamenaldehyde, ethylinarurol, herdeion and hexyl cinnamic aldehyde is further added to the main fragrance component composed of eugenol to reproduce the crepe fragrance and improve the palatability of the fragrance And a skin external preparation containing the perfume composition.

It is a perennial herb that grows in the mountains and fields of each part of Korea. Yarrow has been widely known as a medicinal herb for the treatment of wounds from a long time ago. For example, the leaf is split like a scissors, so it is called the grasshopper grass, the edge of the leaf is serrated. When it is used as a medicine when it is bitten by a snake, it is also called a bacillus or a bacillus. It is called.

Growth environment of the yarrow grows in semi-shade or sunny spot, and rootstock grows sideways, and several buds gather, and the upper part has many hairs. The height is 50-100 cm, and the leaves are 6-10 cm long and 0.7-1.5 cm wide and pointed. There is no petiole, and the lower part wraps around the stem. The lamina are slightly deeply cracked like a comb, and there are sawtooths on the cut pieces. It is called sawtooth because the shape of the crack is like a saw blade.

The flower is bisexual, 0.7 ~ 0.9cm in diameter, and has a stem and a white head flower at the end of the branch. The involucre is round, slightly hairy, about 0.5㎝ in length and butterfly. The angle is long elliptical, lined with two lines and short on the outside. The length of the callus is from 0.35 to 0.45 cm, ranging from 5 to 7.

The fruit is achene, which runs around October to November. It has a length of about 0.3㎝ and a width of about 0.1㎝. Both ends are flat and have no hair.

Youngseon is used for food. Because it is hot and spicy, it should be well cooked after changing the water several times. The mature ones are used as a whole lot of noodle, pungent, sincere, and anti-inflammatory.

The inflorescence is the beginning (蓍 草). Also it is known as journaling call (一枝蒿), fifty seconds (蜈蚣草), 0 seconds (靈草), and also used the leaves and stems with herbs, mountain yarrow (Achillea There is sibirica . discoidea REGEL).

The harvest is picked when the flowers are bloomed, cut into small pieces before being dried, and sometimes used with green grass.

The active ingredients of the milfoil include oil in the crepe of the wood. Specific oil components include Chamazulene, Cineol, Luteolin, Achillein, Apigenin, Caffeic acid, and the like.

Such dust mites are effective for analgesia, gusty winds, bloodshed, and extinction, and are applied to diseases such as paralysis caused by custom, arthritis, bruises, and swelling.

As a method for reproducing the representative scent of milky water, a steam distillation method is economical and is used as a method capable of mass extraction.

However, since the steam distillation method exerts heat, the original flavor of the plant may be altered. As an alternative, the solvent extraction method is suitable for extracting the delicate floral fragrance because heat is not applied, but since a solvent such as hexane is used, a secondary reaction of the fragrance and the solvent may occur.

In addition, recently, a supercritical extraction method for extracting CO ₂ gas at low temperatures has been developed, and it has been reported that a high-purity, high-quality flavor can be obtained. However, supercritical extraction method has a disadvantage in that it is economically expensive.

Therefore, Solid Phase Micro Extraction (hereinafter referred to as SPME), which does not require any pretreatment without solvent and can analyze the fragrance quickly and easily, is suggested as a useful method for fragrance analysis.

Korean Patent Publication No. 2009-55190 discloses a fragrance composition having excellent palatability by analyzing the fragrance components of the magnolia seeds by the SPME method to reproduce the intrinsic fragrance of the magnolia seeds, Has been reported to be able to increase the demand for low-priced popular fragrances by reproducing the fragrance of the natural scent similar to the natural scent in the limited fragrance industry.

Korean Patent Publication No. 2010-49342 also discloses a lotion of lotus (Nelumbo nucifera) containing an essence ingredient of lotus collected by SPME method and hedione (hedione) which is an artificial synthetic material having a delicate flower scent as an active ingredient. Korean Patent Laid-Open Publication No. 2014-55344 discloses a perfume composition having excellent palatability while reproducing inherent fragrance. Beta-Phellandrene, Beta-Phellandrene, (D-Limonene) with Betaine, Beta-Pinene, Myrcene, Iso Bornylacetate, Alpha-Pinene, Camphene, A fragrance composition having excellent palatability while reproducing a fragrance inherent in a flower has been reported.

Each of the inventions provides a perfume composition for analyzing and reproducing the components of each plant by using the SPME method as a method for reproducing the fragrance inherent to the plant, but no composition for reproducing the fragrance of the gerbera has been reported.

Accordingly, the present inventors have made efforts to reproduce the scent of milky lotion by the SPME method. As a result, the present inventors have found that the main flavor component composed of eucalyptol, alpha-pinene, beta-pinene, camphor, cariophilene, limonene, phenylethyl alcohol, linarul, To thereby reproduce the fragrance of natural milky pofule and further contain an additional component in the main fragrance component to enhance the palatability of the fragrance to complete the present invention.

It is an object of the present invention to provide a perfume composition which can reproduce the fragrance of crepe yarn as it is and has excellent palatability.

The present invention relates to a pharmaceutical composition comprising Eucalyptol, Alpha-Pinene, Beta-Pinene, Camphor, Caryophyllene, Limonene, Phenylethyl Alcohol, , Linalool, and Eugenol. The perfume composition of the present invention is a perfume composition that reproduces the scent of the mulberry.

More specifically, the perfume composition comprises 15 to 20 wt% of eucalyptol, 10 to 15 wt% of alpha-pinene, 10 to 15 wt% of beta-pinene, 1 to 5 wt% of camphor, 15 to 20 wt% 5 to 10% by weight of phenylethyl alcohol, 1 to 5% by weight of phenylethyl alcohol, 1 to 5% by weight of linac, and 1 to 5% by weight of eugenol.
Further, the perfume composition of the present invention may further contain at least one or more selected from the group consisting of cyclic aldehyde, ethyl linol, hethion and hexyl cinnamic aldehyde, and more preferably, 5 to 10% by weight of cyclic aldehyde, 5 to 10% by weight of ethyl linoleate, and 5 to 10% by weight of heptane, but the present invention is not limited thereto.

delete

Accordingly, there is provided a composition for external application for skin containing a fragrance composition recreating the scent of a mildew of the present invention.

The perfume composition of the present invention contains the main fragrance component consisting of eucalyptol, alpha-pinene, beta-pinene, camphor, cariophilene, limonene, phenylethyl alcohol, linarul and eugenol to reproduce the fragrance of natural milky skin, The fragrance ingredient further contains at least one or more selected from the group consisting of cyclic aldehyde, ethyl rinolate, herdeon and hexyl cinnamic aldehyde to reproduce the crepe fragrance and improve the palatability of the fragrance.

Fig. 1 shows the result of analyzing the main fragrance ingredient of the crepe with GC-MS.

Hereinafter, the present invention will be described in detail.

The perfume composition according to embodiments of the present invention may be selected from the group consisting of Eucalyptol, Alpha-Pinene, Beta-Pinene, Camphor, Caryophyllene, Limonene, , Phenylethyl Alcohol, Linalool and Eugenol as main fragrance ingredients.

Fig. 1 shows the result of analyzing the main fragrance ingredient of the crepe with GC-MS.

The perfume composition of the present invention can reproduce fragrance of silk crepe in the case of a fragrance composition in which the above components are combined as a fragrance component of a creeping moth analyzed by the SPME method.

The fragrance composition capable of reproducing the mauve scent includes 15 to 20% by weight of eucalyptol,
10 to 15 wt% of par-pinene, 10 to 15 wt% of beta-pinene, 1 to 5 wt% of camphor, 5 to 20 wt% of caropilene, 5 to 10 wt% of limonene, 1 to 5 wt% of phenylethyl alcohol, 1 to 5% by weight of the rule, and 1 to 5% by weight of the eugenol.

The fragrance composition combined with the weight ratio described above can reproduce a soft silky crepe fragrance. When the fragrance composition is out of the above range, the similarity with the crepe fragrance is lowered and the palatability of the fragrance is lowered.

Further, the perfume composition of the present invention contains at least one or more selected from the group consisting of cyclamenaldehyde, ethylenicallyl, hediion and hexyl cinnamic aldehyde in addition to the main fragrance component, .

In a preferred embodiment of the present invention, when a mixed component of cyclamenaldehyde, ethylenal, and herbicide is contained, the fragrance exhibits excellent similarity and palatability to the intrinsic fragrance of the milky lotion, 5 to 10% by weight of aldehyde, 5 to 10% by weight of ethyl linolate, and 5 to 10% by weight of haze.
In addition to the above-mentioned cyclic aldehyde, ethylenearl and hendione components, hexyl cinnamic aldehyde may further be contained, wherein the mixing ratio is 5 to 10% by weight of cyclic aldehyde, 5 to 10% by weight of ethyl linoleate, 5 to 10 wt% and hexyl cinnamic aldehyde 1 to 5 wt%. In the case of a product containing a perfume composition composed of the above-mentioned mixed ingredients, a similarity of 3.33 and a palatability of 3.93 in the sensory evaluation with respect to the inflorescence intolerance are reproduced [not shown].

delete

When the above content range is satisfied, it is most similar to the original scent of the crepe and exhibits excellent palatability.

The fragrance composition reproduced by the present invention is collected by SPME-headspace method, the fragrance is adsorbed on the SPME fiber, and analyzed using a gas chromatography-mass spectrometer (GC / MSD) .

The SPME method is advantageous for analyzing the fragrance of a delicate flower because no secondary by-products due to heat can be obtained because the fragrance can be collected at room temperature without special pretreatment and analyzed within a short time.

According to the embodiments of the present invention, the fragrance was combined based on the fragrance component of the sawtooth, which was analyzed by the SPME-headspace method, and a sensory test was conducted in order to evaluate the palatability of the fragrance. As a result, It is possible to confirm the excellent palatability of the fragrance.

Accordingly, the present invention provides a composition for external application for skin containing, as an active ingredient, a perfume composition recreating the scent of a mildew.

Although the shower coron is described as a preferred example in the embodiment of the present invention, it may be formulated in a skin external base such as perfume, cosmetics and the like, and the blending amount may be suitably selected in accordance with the art in the art to achieve the desired effect .

In addition, the present invention relates to a composition for external application for skin, which comprises a perfume composition recreating a scarlet fragrance as an active ingredient, which can be used as an ointment, lotion, soluble image, suspension, emulsion, cream, gel, spray, papermaking, But it may also be incorporated in a medium known in the art.

Hereinafter, the present invention will be described in more detail with reference to Examples.

The present invention is intended to more specifically illustrate the present invention, and the scope of the present invention is not limited to these embodiments.

< Example  1 > Preparation of Combination Flavor Reproduced with Violet Flavor

In order to capture the fragrant and good fragrance of the yarrow, zipper bag was put on the straw mat flower in Yongin city, Gyeonggi province, and the fiber was fixed and the fragrance was collected for about 1 hour.

After capturing the fragrance components, the fiber was sealed and kept in a low temperature state and transferred to the laboratory for analysis. The fragrance adsorbed fiber was transferred to the inlet of GC-MSD and the flower was desorbed for 1 min and analyzed by GC-MS. GC-MS conditions are as follows.

The flavor components of the milfoil as analyzed by the SPME-headspace method are shown in Table 2 below.

According to the above Table 2, the main ingredients include eucalyptol, alpha-pinene, beta-pinene, camphor, cariophilene, limonene, phenylethyl alcohol, linarul and eugenol as main flavor components, &Lt; / RTI &gt; by weight.

< Comparative Example  1 > Preparation of Combination Flavor Reproduced with Violet Flavor

1. Manufacture of Combination Spices

The combined fragrance (Sample B) shown in the following Table 3 was made on the basis of the natural sawtooth (Sample A) and the result analyzed in Example 1 above, and the fragrance of the combined fragrance and natural crepe was verified through sensory evaluation.

2. Sensory evaluation of combination spices with natural scarf

Natural droppings (Sample A) and the combined fragrance (Sample B) blended in Comparative Example 1 were prepared and subjected to sensory evaluation on 15 normal male and female persons aged 20 to 45 years. Specifically, the fragrance samples were respectively handled by the fragrances, and responded to the questionnaire of Table 4 , and the fragrance similarity (Question 1) and the odor palatability (Question 2) of the samples A and B were examined.

At this time, for the reproducible combination fragrance (sample B), for the accurate sensory evaluation, it was diluted to a level similar to the intensity of the natural rosewood oil fragrance, The sensory evaluation results are shown in Table 5 below.

As can be seen from the results in Table 5, the combined fragrance (Sample B) of Comparative Example 1 had a similarity of not more than 3 points, so that there was a difference in natural crepe (Sample A) and flavor, . Thus, the fragrance of the combined fragrance (Sample B) blended in Comparative Example 1 had a low similarity with the natural fleece fragrance.

3. Comparison of the fragrance of natural creeping moth

Sensory evaluations were performed on the individual components of natural straw mats.

As a result, it was confirmed that among the fragrance components of natural milky pine, eucalyptol, alpha-pinene, beta-pinene, camphor, cariophilene, limonene, phenylethyl alcohol, linac, And it was possible to increase the reproducibility of the fragrance of the natural milky pofule based on the above main ingredients.

< Comparative Example  2-6> Manufacture of Combination Flavor Reproducing Papyrus Scent

1. Manufacture of Combination Spices

Ingredients analyzed in the crepe fragrance in Example 1 were compounded with the ingredients shown in Table 6 below to prepare a combined fragrance (Sample C to G). The combined fragrances (Samples C to G) were prepared by adjusting the total content of each combination fragrance to 60 to 80% by weight, while keeping the ratio of the nine major components that reproduce the intrinsic fragrance of natural creeping moth.

2. Sensory evaluation of combination spices with natural scarf

Natural droppings (Sample A) and the combined fragrances (Samples C to G) blended in the above Comparative Examples 2 to 6 were prepared and subjected to sensory evaluation on 15 normal male and female persons aged 20 to 45 years. Specifically, the fragrance samples were each hand soaked in the fragrance samples, and the comparative sensory evaluation was performed on the two fragrance fragrances, followed by a rest for 5 minutes to avoid post-sensory paralysis.

The sensory evaluation results of the flavor similarity and palatability of the natural comb sole and the combined fragrance (Samples C to G) blended in Comparative Examples 2 to 6 are shown in Table 7 below.

From the results of Table 7, it can be seen from the results of the similarity and palatability of natural milfoil that the combination fragrance of Comparative Example 5 in which the total content of the nine kinds of ingredients, which is the main component for reproducing the intrinsic fragrance of natural milfoil, is 75 wt% It looked. Nevertheless, even in the case of the combination fragrance of Comparative Example 5, it was confirmed that the similarity and palatability for reproducing the intrinsic fragrance of natural milfoil were as low as 2.93 and 2.87, respectively.

< Example  2-6> Manufacture of Combination Flavor Reproducing Papyrus Scent

1. Preparation of Combination Spices

In order to improve the similarity and palatability of the combined fragrance of Comparative Example 5 in which the fragrance of natural crepe is most similar in the results of Table 7, as shown in the following Table 8 , , Cyclamen aldehyde, ethylinaruler and hedidone to give a feeling of non-monotonous and clean. At this time, the concentration of the artificial synthetic material was changed from 19 to 25% by weight, while the ratio of cyclamen aldehyde, ethy linalool, and hedion was kept constant, . The other ingredients were adjusted to meet the total content of 100 wt%, depending on the content of these materials.

2. Sensory evaluation of combination spices with natural scarf

Natural droppings (Sample A) and the combined fragrances (Samples H to L) blended in Examples 2 to 6 were prepared and subjected to sensory evaluation on 15 normal male and female persons aged 20 to 45 years. Specifically, the fragrance samples were each hand soaked in the fragrance samples, and the comparative sensory evaluation was performed on the two fragrance fragrances, followed by a rest for 5 minutes to avoid post-sensory paralysis. The sensory evaluation results of the perfume compositions (samples H to L) blended in Examples 2 to 6 and the fragrance similarity and palatability of natural milky papules are shown in Table 9 below.

As can be seen in Table 9, excellent similarity and palatability were confirmed when cyclamenaldehyde, ethylinaruyl, and hedidone were contained in nine main components that reproduce the intrinsic fragrance of natural creeping moth, and in particular, cyclamenaldehyde , And the combined fragrance of Example 4 containing 22% by weight of ethyl linolurate and herdone, exhibited excellent similarity and palatability on average of 4.0 or more, so that the fragrance of natural milky pofule could be reproduced.

< Example  7> Shower cologne  Produce

A shower colong according to the composition of the following Table 10 was prepared containing the perfume composition combined with the composition of Example 4 above.

< Experimental Example  1> Shower cologne  Sensory evaluation

The sensory evaluation of the shower coron prepared in Example 7 was conducted on a general public. The sensory evaluation is then used to colognes of Example 7 for the general name of 15 men and women 25-45 years old, and to respond to the questionnaire of Table 11, and results thereof are illustrated in Table 12.

From the results of Table 12, it was confirmed that the shower coron prepared with the composition of Table 10 has similarity with the intrinsic fragrance of the crepe and shows excellent preference (average 4.0 or more).

As described above, the present invention relates to a composition containing a main scent component consisting of eucalyptol, alpha-pinene, beta-pinene, camphor, cariophilene, limonene, phenylethyl alcohol, linarul and eugenol, To provide a perfume composition.

The present invention further comprises at least one or more selected from the group consisting of cyclamenaldehyde, ethylinarurol, herdeion and hexyl cinnamic aldehyde in addition to the main fragrance component, Respectively.

Accordingly, the present invention can be formulated into an external skin base such as a shower cologne, perfume, cosmetics and the like, containing a perfume composition recreating the fragrance of natural milky poficle as an active ingredient, and can be used as an ointment, lotion, soluble image, suspension, emulsion, Gels, sprays, papermaking agents, warning agents, patching agents or water puffs.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is evident that many alternatives, modifications and variations will be apparent to those skilled in the art.

Claims (5)

A fragrance composition comprising an effective fragrance component of a milky lotus mixed with eucalyptol, alpha-pinene, beta-pinene, camphor, caropyrilene, limonene, phenylethyl alcohol, linarul and eugenol components,
Wherein the effective fragrance ingredient of the blended sawtooth has 15 to 20 wt% of eucalyptol, 10 to 15 wt% of alpha-pinene, 10 to 15 wt% of beta-pinene, 1 to 5 wt% of camphor, 15 to 20 wt% 5 to 10% by weight of limonene, 1 to 5% by weight of phenylethyl alcohol, 1 to 5% by weight of linacs and 1 to 5% by weight of eugenol,
A fragrance composition recited in which a mixture of cyclamic aldehyde (5 to 10 wt%), ethyl linolate (5 to 10 wt%), and hesidone (5 to 10 wt%) is contained. delete delete delete A composition for external application for skin containing the fragrance composition recreating the scarlet fragrance of claim 1.

Images