JP2003300811A - Composition containing rosmarinic acid - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a composition emitting long-lasting fragrance, effective for improving the quality of hair or textile products and useful for the treatment of hair or textile products. <P>SOLUTION: The composition containing rosmarinic acid is produced by formulating rosmarinic acid with one or more kinds of perfumes selected from hydrocarbon-based, alcoholic, phenolic, phenol-ether-type, aldehyde-type, acetal- type, ketal-type, ketone-type, ether-type, acid-type, lactone-type, ester-type, nitrogen-containing, sulfur-containing, natural and formulated perfumes. <P>COPYRIGHT: (C)2004,JPO

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a rosmarinic acid-containing composition which is excellent in stability of scent and quality improvement of hair or fiber products, and is particularly suitable for treating hair or fiber products.

[0002]

BACKGROUND OF THE INVENTION Perfume ingredients have the effect of improving the degree of preference of various compositions, the effect of correcting unpleasant tastes and flavors, or the effect of reducing the mental burden on the user. It is used in various compositions such as foods, pharmaceuticals and cosmetics in order to improve the added value of the composition.

However, in general, the fragrance component is volatile,
It has high degradability and deterioration, and it is difficult to maintain a stable flavor for a long time in the composition.

In addition, tissues such as skin, hair, oral cavity, and respiratory organs, which are often exposed to the outside world, have physical factors such as impact, friction, and heating, and air pollutants such as dioxins, sulfur oxides, and nitrogen oxides. , Chemicals due to behavior such as drinking, smoking, medication, or external stimuli such as sunlight and ultraviolet rays are always in danger of damage.

In particular, hair is greatly damaged by external factors such as daily hair washing, hair makeup and ultraviolet rays. In addition, recently, damage such as hair color and bleaching has been increasing.

As a conventional technique, a hair cosmetic containing a polar solvent extract of a plant and a keratin or a keratin-decomposing derivative imparts a hair style-retaining formability and a good feel (Japanese Patent Laid-Open No. 59-157010). Gazette), α-hydroxycarboxylic acid, its inorganic and organic salts, citric acid, lactic acid, glycolic acid, tartaric acid, its inorganic and organic salts, lactose, glycolic acid, its inorganic and organic salts, Lactic acid having a high ratio of L-lactic acid, hair cosmetics in which inorganic salts and organic salts thereof are combined, or hair cosmetics in which those cosmetics are further combined with an ultraviolet absorber or a non-volatile silicone can prevent deterioration of hair damage. (Japanese Patent Laid-Open No. 11-5719), a shampoo composition containing a plant extract and a water-soluble chain polymer compound is supple for washing hair. , Having a function of imparting smoothness (Japanese Patent Application Laid-Open No. 59-187097), a hair setting agent composition containing a plant extract, a polymer compound for fixing hair and lecithin, and having a curl holding power for hair and after setting. Has a function of imparting a good feel (Japanese Patent Application Laid-Open No. 59-196811), and a hair cosmetic containing a polar solvent extract of perch and / or rosemary and collagen, has an effect of maintaining hair style formation, and an appropriate amount. And the effect of imparting good combability (JP-A-59-155307), and a hair cosmetic containing a plant extract and a non-volatile silicone has an effect of preventing damage to hair. That (Japanese Patent Laid-Open No. 8-231
No. 348) is known. Further, in order to prevent split ends and broken hair of hair, oil and silicones are blended to lubricate the surface of the hair and suppress friction due to brushing and the like (Japanese Patent Laid-Open Nos. 4-230615 and 5-7032).
No. 8, gazette) technology and blending glycol (Japanese Patent Laid-Open No. 7-
No. 118127), blending hydrolyzed keratin (JP-A-8-157342), and blending an amino acid (JP-A-59-181206) have been proposed. However, with these hair cosmetics,
The effect of preventing split ends is not sufficient, and the effect of improving the feel of damaged hair by repairing the hair surface is also insufficient. Further, a hair treatment agent containing Spanish rosmarinic oil has an effect of preventing hair loss (JP-A-60-
It is known that a composition containing the essence of a Lamiaceae plant has a function of normalizing dermal collagen bundles (Japanese Patent Laid-Open No. 10-330221).
However, none of them were effective.

The present invention has been made in view of the above circumstances, and includes a rosmarinic acid-containing composition having a flavoring scent, stability, and sustainability, as well as daily ultraviolet rays and ironing.
Hair by preventing heat of the dryer, especially keratin-containing fibers that have been chemically treated with bleach, hair color, hair bleach, perm, etc. Provided is a rosmarinic acid-containing composition which is excellent in the touch feeling and is particularly suitable for treating hair or textile products.

[0008]

Means for Solving the Problems and Modes for Carrying Out the Invention As a result of intensive studies to solve the above problems, the present invention provides a composition with good fragrance stability by using rosmarinic acid and a specific fragrance in combination. Also, by blending rosmarinic acid and a cationic surfactant, damage to hair or textiles (branches / cutting hairs) is prevented, and the surface of the hair or textiles is restored, so that the texture is remarkably improved. The inventors have found that they are improved and have completed the present invention.

That is, the present invention is based on rosmarinic acid and hydrocarbons, alcohols, phenols, phenol ethers, aldehydes, acetals, ketals, ketones, ethers, acids, lactones, esters. , Nitrogen-containing system, sulfur-containing system, natural system, and compound system 1
There is provided a rosmarinic acid-containing composition containing one or more fragrances, and a rosmarinic acid-containing composition for treating hair or textile products, which comprises rosmarinic acid and a cationic surfactant.

The following are known techniques for using rosmarinic acid. For example, rosmarinic acid and /
Alternatively, that the cosmetic containing lysine and / or arginine exhibits an ultraviolet ray-preventing effect (Japanese Patent Laid-Open No. 6-145034), and that the cosmetic containing rosmarinic acid and / or a water-soluble polymeric substance exhibits a skin beautiful effect (JP Sho 63-16261
1), cosmetics containing a Lamiaceae plant extract containing rosmarinic acid have a whitening effect (JP-A-7-18).
7989), a pharmaceutical medicinal plant composition containing Clematis radix containing rosmarinic acid, Trichosantes root and Brunella herba mixture extract has analgesic effect, chronic rheumatoid arthritis therapeutic effect, and peripheral blood circulation improving effect (special feature). (Kaihei 10-101572), and a composition for oral cavity containing rosmarinic acid or a rosmarinic acid derivative has an antibacterial effect (JP 2000-23).
It is known that a composition containing apigenin, chrysoeriol, luteolin and rosmarinic acid has a histamine release inhibitory effect (Japanese Patent Laid-Open No. 2000-86510). However, by combining rosmarinic acid and a fragrance, it is possible to make the fragrance excellent in stability, and by using rosmarinic acid and a cationic surfactant in combination, it is possible to significantly improve the feel of hair or textiles. Is not known about.

The present invention will be described in detail below. Rosmarinic acid used in the composition of the present invention is a substance represented by the following formula.

[0012]

[Chemical 1]

Rosmarinic acid is a mannose wax (Rosmarinus officin) which is an evergreen small shrub of the Lamiaceae family.
alis L. ) Is included in the plant group represented by.
Ginseng wax is used as an edible herb, and is known to have a pharmacological action such as an analgesic effect, an antitussive effect, and a diuretic effect, but the relationship between its medicinal effect and individual medicinal effect ingredients has not been completely clarified.

The rosmarinic acid of the present invention may be of any origin. For example, the mannose wax (Rosmarinus officin), which is the evergreen small shrub of the Lamiaceae family.
alis L. In addition to), it can be extracted from plants such as Lamiaceae, Purple family, Oleanderaceae, Seriaceae, and Gentianaceae, specifically, plants such as sage, aojiso, chili memphis, thyme, and nematodes. It can also be prepared by chemical organic synthesis. Although a pure compound of rosmarinic acid can be used in the present invention, it is not limited thereto, and cosmetics, detergents, pharmaceuticals,
It is also possible to use semi-purified or crude rosmarinic acid as long as it does not contain impurities unsuitable for quasi-drugs and foods.

When rosmarinic acid is extracted from a plant, plants that are naturally grown or cultivated can be used, but the plant is not limited to these, and recombinant plants obtained by gene recombination, callus, and hairy roots can be cultured. Cells and cultured tissues can also be used.

As the extraction site, a branch part, a leaf part, a root part, a seed part, a fruit part, a flower part and the like can be used.

As a method for producing plant-derived rosmarinic acid, a known method can be adopted. For example, mannen wax from 250 to
Extracted by milling to 500 μm or degreased with a low polar solvent such as hexane by hydrophilic solvent such as ethanol, methanol, hydrous ethanol, acetone, etc. by Soxhlet method or cooling filtration method etc. Get things. Then, after adding water, the organic solvent is distilled off, and water is further added to remove the resulting precipitate, or a method such as partitioning with a solvent such as hexane, ethyl acetate, methanol, and water is used to obtain a rosmarinic acid concentrated liquid. . Next, a method such as distillation under reduced pressure, washing with a low-polarity solvent, salt dissociation by pH adjustment, purification by a silicic acid column, a resin column, or high performance liquid chromatography can be used.

The composition of the present invention has the above-mentioned purified, semi-purified,
Or crude rosmarinic acid, as the amount of rosmarinic acid,
0.00001 to 50 mass% is blended, preferably 0.0001 to 30 mass%, more preferably 0.0.
01 to 5% by mass is blended. In particular, in the composition for treating hair or textiles, usually,
0.01 to 20% by mass, preferably 0.1 to 5% by mass,
More preferably, it is selected in the range of 0.1 to 2 mass%. If the blending amount is less than 0.01% by mass, the blending effect may not be sufficiently exhibited, and if the blending amount exceeds 20% by mass, the appearance of the composition may be impaired due to the generation of colored matters or precipitates. is there.

The first composition of the present invention uses a combination of rosmarinic acid and a specific fragrance, whereby the fragrance and stability can be improved. Examples of such a fragrance include the following.

The fragrances used in the composition of the present invention include hydrocarbons, alcohols, phenols and phenol ethers, aldehydes, acetals and ketals, ketones, ethers, acids, lactones, It is one or more kinds of fragrances selected from ester-based, nitrogen-containing, sulfur-containing, natural and compounded systems.

A list of perfume raw materials used as perfumes according to the invention can be found in various publications, for example "Perfume an.
d Flavor Chemicals ", Vol.
Iand II, Steffen Arctande
r, Allured Pub. Co. (1994) and "Synthetic Perfume Chemistry and Product Knowledge", Genichi Indo, Kagaku Kogyo Nipposha (1996) and "Perfume and F".
labor Materials of Nature
Origin ", Stephen Arctan
der, Allured Pub. Co. (1994)
And "Encyclopedia of fragrances", edited by the Japan Fragrance Association, Asakura Shoten (19
89) and "Perfumery Material
Performance V. 3.3 ", Boelen
s Aroma Chemical Information
Ion Service (1996) and "Flowe
r oils and Floral Compound
dsIn Perfumery ", Danute La
jaujis Anonis, Allured Pu
b. Co. (1993) and the like, each of which is incorporated by reference. Typical examples of the fragrances will be given below, but the fragrances are not limited to these.

The hydrocarbon compounds include ocimene, dihydromyrcene, farnesene, sedrene, α-pinene, β-pinene, limonene, dipentene, camphene,
Ferrandrene, terpinene, 3-calene, terpinolene, bisabolene, β-caryophyllene, kazinene, valencene, tsuyopsene, guaien, aloocimene, myrcene, longifolene, veldracin (1,3,5-undecatriene), p-cymene, 4- Isopropyl-
1-methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon terpene,
Bergamot terpene, peppermint terpene, spearmint terpene, lime terpene, vetiver terpene,
Rose wax, jasmine wax, limonene dimer, pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, icosan, henicosan, docosane, tricosan, tetracosane, pentacosan. , Hexacosan, heptacosan, octacosan, nonacosan, triacontane and the like.

Examples of alcohol compounds include 3-methyl-1-pentanol, geraniol, cedrol, citronellol, rosinol, nerol, dihydrolinalool, linalool, tetrahydrolinalool, dimethyloctanol, tetrahydromugol, mugol, myrcenol, dihydromyrcene. Nol, ocimenol, tetrahydromyrcenol, lavandulol, isodihydrolavandulol, hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), ethyllinalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla. Alcohol, 4-tunanol, 3-tunanol, farnesol, nerolidol, α-bisabolol, β-caryophyllene alcohol, sun Tallol, vetiverol, cedrenol, 3-l-menthoxypropane-1,2-diol, patchouli alcohol, dihydrocarbeol, phytol, isophytol, sclareol, carveol, menthol, ethyl alcohol, propyl alcohol, butanol, isoamyl alcohol, 1 -Heptanol, 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-
Ethylhexanol, 1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-
1-hexanol), 1-decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2-buten-1-ol), 2-methyl-3-buten-2-ol, β- Pentenol (1
-Penten-3-ol), leaf alcohol (cis)
-3-hexenol), trans-2-hexenol, trans-3-hexenol, cis-4-hexenol, 2,4-hexadiene-1-ol, matsutakeol (1-octen-3-ol), cis-6-.
Nonenol, cucumber alcohol (2,6-nonadienol), androl (1-nonen-3-ol), rosalva (9-decenol), 1-undecenol, undecabertol (4-methyl-3-decene-5)
-Ol), ocilol (3,7-dimethyl-7-methoxy-2-octanol), santalinol (2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2- Butene-1-ol), p, α-
Dimethylbenzyl alcohol, 2,2,6-trimethylcyclohexyl-3-hexanol, 1,2-pentanediol, benzyl alcohol, anise alcohol, β
-Phenylethyl alcohol, styralyl alcohol (1-phenyl-1-hydroxyethane), hydratropa alcohol, methyl β-phenylethyl alcohol,
α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-naphthol, furfuryl alcohol, 3-methyl-1-phenyl-3-pentanol,
Amylcinnamic alcohol, cinnamic alcohol, phenoxanol (3-methyl-5-phenylpentanol), 1,2-pentanediol, 2-ethylhexanol, dimethol (2,6-dimethylheptanol), 3,6 -Dimethyl-3-octanol, cohinol (3,4,5,6,6-pentamethyl-2-heptanol), brahamanol (methyltrimethylcyclopentenylbutanol), bacdanol (2-ethyl-4-).
(2,2,3-Trimethyl-3-cyclopentene-1-
Ill) -2-buten-1-ol), Thunderol (3
-Methyl-5- (2,2,3-trimethylcyclopent-3-en-yl) -pentan-2-ol), Sandalol (3-methyl-5- (2,2,3-trimethylcyclopenta- 3-en-1-yl) pentan-2-ol), cyclohexylethyl alcohol, apopachon (p-isopropylcyclohexanol), fluorolol (2,4-dimethyl-3-cyclohexene-1-methanol), pachone (p-tert). -Butylcyclohexanol), veldol (o-tert-butylcyclohexanol), mayol (p-isopropylcyclohexylmethanol), cyclomethylene citronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol), methylsande Flor (5'or 6'-methylno Born-5'-en-2
Yl) -2-methylpent-1-en-3-ol),
Timberol (2,2,6-trimethylcyclohexyl-3-hexanol), Polysanthol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-pentene-2 -Ol), hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), isopulegol, isocyclogeraniol, myrtenol, nopol (6,6-dimethylbicyclo [3.1.1] hept-2-ene- 2-Ethanol), Pinocarbeol, α-phenalkyl alcohol, borneol, isoborneol, patchhomint (2- (3,3-dimethylbicyclo [2.2.1] hept-2-ylidene) ethanol), camel (trimethyl) Norbornane methanol), dimethyl cyclomol, Santarex T ( Seo Kang Phil cyclohexanol), geranyl linalool, cumin alcohol, 2-
Methoxyphenylethyl alcohol, phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenylethyl alcohol, isobutylbenzylcarbinol, p-methylbenzylcarbinol, hydrocinnamic alcohol, centifold (1, 1-dimethyl-3-phenylpropanol-1), muguet alcohol (2,2-dimethyl-3)
-Phenyl propanol), phenyl hexanol, decahydro β-naphthol, AR-1 (3,6-dimethyloctane-3-ol), avitol (hydroabietyl alcohol), α-propylphenylethyl alcohol, p-methyldimethylbenzylcarbi. Examples thereof include nol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), fluorol (2-isobutyl-4-hydroxy-4-methyltetrahydropyran), propylene glycol, dipropylene glycol and hexylene glycol.

Examples of the phenol-based and phenol ether-based compounds are anisole, estragole, chabicol, anethole, cresol, carvacrol, and p.
-Cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-naphthol isobutyl ether, veratrol (1,2-dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxy Benzene, catechol,
Resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl-3 (3-methoxy-5-methylphenol), thymol, methylthymol, propenylguaetol (tr)
ans-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, m-ethylphenol, p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol), hydroquinone Dimethyl ether, resorcin dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyleugenol, methylisoeugenol, ethylisoeugenol, benzyleugenol, benzylisoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2
-Hydroxy-4-propenylbenzene), shogaol, zingerol, acetyleugenol, acetylisoeugenol safrole, isosaflor, diphenyl oxide, vetiver ether (tert-butylhydroquinone dimethyl ether) and the like.

Examples of the aldehyde compound include citronellal, citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, myrtenal, caryophyllene aldehyde, n-hexanal and 2-methylbutanal. , Isovaleraldehyde, n-valeraldehyde, acetaldehyde, n-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,
5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal,
2-methylundecanal, tridecanal, tetradecanal, 2-pentenal, cis-3-hexenal, trans-2-hexenal, trans-2-
Heptenal, 4-heptenal, trans-2-octenal, trans-2-nonenal, cis-6
-Nonenal, Melonal (2,6-dimethyl-5-heptenal), trans-4-decenal, cis-
4-decenal, trans-2-decenal, Grinal (2,5,6-trimethyl-4-heptenal),
10-undecenal, trans-2-undecenal, trans-2-dodecenal, mandarin aldehyde (3-dodecenal), trans-2-tridecenal, adxal (2,6,10-trimethyl-9)
-Undecen-1-al), 2,4-hexadienal, 2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4-decadienal, 2, 4-undecadienal, 2,4-dodecadienal, geraldehde (5,
9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadiene-1)
-Earl), oncidar (2,6,10-trimethyl-5,9-undecadienal), bergamar (α-
Methylene citronellal), camphorene aldehyde,
Cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxaldehyde), muguealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxy Acetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2.2.1] -5-heptene-2-carboxaldehyde), centenal (methoxydicyclopentadienecarboxaldehyde), dupicar (4-tricyclodecyl) Ridenbutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3)
-(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), setonal (trimethylcyclohexenemethylbutanal), inonal (2-methyl-4- (2,6,6-trimethyl) −
1 (2) -cyclohexenyl) -butenal), terestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p -Methylphenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmolandi (2
-Methyl-3- (4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2
-Methyl-3- (p-isopropylphenyl) -propionaldehyde), Florarozone (p-ethyl-α, α)
-Dimethylhydrocinnamic aldehyde), Suzral (p-isobutyl-α-methylhydrocinnamic aldehyde), cinnamic aldehyde, salicylaldehyde, anisaldehyde, o-methoxybenzaldehyde, o-methoxycinnamic aldehyde, canthoxal (2-methyl -3- (p-methoxyphenyl) -propanal), vanillin, ethylvanillin, methylvanillin (3,4-dimethoxybenzaldehyde), heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde) ), Phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrolein, lyral (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), bernaldehyde (1-methyl-4-)
(4-methylpentyl) -3-cyclohexenecarboxaldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), junipearl (4
(5) -Formyl-7,7,9-trimethylbicyclo [4.3.0] -nonene), vertoral (octahydro-4,7-methanoindenecarboxaldehyde), lilial (p-tert-butyl-α-). Methylhydrocinnamic aldehyde), Mefuranal (3-
Methyl-5-phenylvaleraldehyde), englandal (4-methyl-2-phenyl-2-pentenal),
Cocar (5-methyl-2-phenyl-2-hexenal), α-methylcinnamic aldehyde, α-butylcinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, formylethyltetramethyltetralin (6 -Ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,
3,4-tetrahydronaphthalene) and the like.

Examples of acetal-based and ketal-based compounds include magnolane (2,4-dimethyl-4,4a, 5,9).
b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl-5,5-)
Dimethyl-1,3-dioxane), indoflor (dihydroindenyl-2,4-dioxane), boasanbrenforte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal,
Leaf acetal (acetaldehyde ethylhexenyl acetal), acetaldehyde ethylhexyl acetal, citronellyl methyl acetal, erintar (acetaldehyde ethyl linalyl acetal), Bonarox (2,4-dioxane-3-methyl-7,10)
-Methanospiro [5.5] undecane), ephetal (acetaldehyde ethylphenyl acetal), acetaldehyde ethylisoeugenyl acetal, acetal R (acetaldehyde phenylethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentane) Diol acetal), spiroflor (3-ethyl-2,4-dioxaspiro [5.5] undecene-8-ene), ethyldimethyldioxaspiroundecene, herboxane (2-butyl-).
4,4,6-trimethyl-1,3-dioxane), caranal (2- (2,4-dimethylcyclohex-3-sen-1-yl) -5-methyl-5 (1-methylpropyl)
1,3-dioxane), hexanal dimethyl acetal, hexanal diethyl acetal, hexanal propylene glycol acetal, carotene (4,7-
Dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis
-3-Hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal, heptanal ethylene glycol acetal, 2-
Hexyl-5-methyl-1,3-dioxolane, 5-methyl-5-propyl-2- (1-methylbutyl) -1,
3-dioxane, octanal dimethyl acetal, octanal diethyl acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal,
2-methylundecanal dimethyl acetal, dodecanal dimethyl acetal, citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxy citronellal dimethyl acetal, hydroxy citronellal diethyl acetal, cis- 3-hexenal diethyl acetal, benzaldehyde dimethyl acetal, benzaldehyde diethyl acetal, benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenyl Acetaldehyde propylene glycol acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropaldehyde Dimethyl acetal, hydratropaldehyde aldehyde ethylene glycol acetal, osminal DMA (amylcinnamic aldehyde dimethyl acetal), osminal DE
A (amylcinnamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5-tetramethyl-4-isopropyl-1,3-dioxane), amber Sage (4,7-dihydro-2-isopentyl-
2-Methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonan (2-butyl-4-dioxaspiro [4.4] nonanone), Freiston (Ethyl-
2,4-dimethyl-1,3-dioxolane-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate) and the like can be mentioned.

Examples of the ketone compound include acetylcaryophyllene, carvone, pulegone, piperitenone, piperitone, menthone, sho brain, oxocedrane, isolongiforanone, nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, 2-nonanone, 3-nonanone, 2-undecanone, 2-tridecanone, methylisopropylketone, ethylisoamylketone, mesityloxide, butylideneacetone, methylheptadienone, methylheptenone , Dimethyloctenone, coabon (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranylacetone, farnesylacetone, acetoin, butyroin (5-hydroxy-4-octane Down), methyl lavender ketone (3
-Hydroxymethyl-2-nonane), diacetyl, 2,
3-pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclopentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2-n-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamone (2-butylidene-3,5,5 (3,3)
3,5) -Trimethylcyclopentanone), Sandex (3-methyl-5- (2,2,3-trimethyl-3-)
Cyclopentenyl) -3-penten-2-one), cyclotene, coronol (3,5-dimethyl-1,2-cyclopentadione), methylchorilone (3,4-dimethyl1,2-cyclopentadione), belldone ( 2-ter
t-butylcyclohexanone), p-tert-butylcyclohexanone, Hellback (3,3-dimethylcyclohexylmethylketone), frescomente (2-se)
c-butylcyclohexanone), Artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celery ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2-cyclohexanone) , Oribbon (p-tert-pentylcyclohexanone), Methylcyclocitron (2,3,5
-Trimethyl-4-cyclohexenyl-1-methylketone), Nerone (1- (p-menthen-6-yl) -1-)
Propane), vetiver (4-cyclohexyl-4-methyl-2-pentanone), havanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-).
2-acetonyl-4-methyl-tetrahydropyran),
Emoxiflon (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homoflor (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl-4-hydroxy. 2-Methyl-3 [2H] -furanone), Sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), Furaneol (2,5-dimethyl-4-hydroxy-3 [2]
H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, dibenzyl ketone, benzophenone, methylnaphthyl ketone,
4-Damascol (5-phenyl-5-methyl-3-hexanone), Bethicone (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandone (3- Methyl-4-phenyl-3-
Butene-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damacenone, damascon, isodamascon, α-dynascon (1- (5,5
-Dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2
-One and 4-3,5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one),
Ionone, pseudoionone, methylionone, methylyriton (3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allylionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one), plicaton (4-methyltricyclo [6.2]. .1.0 ^2.7] undecane-5-one), Okisosedoran, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo [5.3.1 ^1.7 .0 ^1.5] -8-undecene) ,
Verbenone (4,6,6-trimethyl- (1R) -bicyclohept-3-en-2-one), fencon, caron (7-methyl-3,5-dihydro-2H-benzodioxepin-3-one) , Trimofix O (2, 6,
10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), vittalide (acetyldimethyltetrahydrobenzindane), epiton (7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.
2.2] Oct-2-ene), Atrinone (4 (5)-
Acetyl-7,7,9 (7,7,9) -trimethylbicyclo [4.3.0] -1-nonene), cashmere (6,7-dihydro-1,1,2,3,3-pentamethyl-) 4 (5H) -indanone), muscone (3-methylcyclopentadecanone-1), musenone delta (3-methylpentadeca-4-enone), civetone (cycloheptadeca-9-en-1-one), exalton (Cyclopentadecanone), musk TM-II (cyclohexadecenone), phantolide (5-acetyl-1,1,2,2)
3,3,6-hexamethylindane), celestolide (4-acetyl-6-tert-butyl-1,1-dimethylindane), traseolide (5-acetyl-3-)
Isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,4)
7-hexamethyltetrahydronaphthalene), vitalide (acetyldimethyltetrahydrobenzindane),
Iso E Super (7-acetyl-1,2,3,3
4,5,6,7,8-octahydro-1,1,6,7-
Tetramethylnaphthalene), dihydrocarboxylic, diosphenol, zingerone and the like.

Examples of ether compounds include methylhexyl ether, decyl methyl ether, decyl vinyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, citronellyl ethyl ether, geranyl ethyl ether, α-terpinyl methyl ether, and Herbabert (3 , 3,5-Trimethylcyclohexyl ethyl ether), isobornyl methyl ether, tricyclodecenyl methyl ether, isoproxen (2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane), juniparome (methoxy) dimethyl tricyclo [5.2.1.0 ^2.6] decane), cyclododecyl methyl ether, Madorokkusu (1-methyl cyclododecyl methyl ether), Fizeoru (2-ethoxy -2,6,6-Trimethyl-9-
Methylenebicyclo [3.3.1] -nonane), cedramber (cedrol methyl ether), methylbenzyl ether, methylphenylethyl ether, ethyl 2-methoxybenzyl ether, allylphenylethyl ether, isoamylbenzyl ether, answer (isoamylphenylethyl) Ether), jacene (2-methyl-
2-butenyl phenyl ethyl ether), dibenzyl ether, cyclohexyl phenyl ether, myrooxide (ocimene epoxide), limonene oxide (p
-Mentha-8-ene-1,2-epoxide), rubofix (spiro [1,4-methanonaphthalene-2 (1
H), 2'-oxirane],-3,4,4a, 5,8,
8a-Hexahydro-3 ', 7-dimethyl and spiro [1,4-methanonaphthalene-2 (1H), 2'-
Oxirane], -3,4,4a, 5,8,8a-hexahydro-3 ', 6-dimethyl), trimethylcyclododecatriene epoxide, caryophyllene oxide, cedrene epoxide, isolongifolene epoxide, linalool oxide, citrooxide (2,2-Dimethyl-5 (1-methyl-1-propenyl) -tetrahydrofuran), Herboxoxide (5-isopropenyl-
2-methyl-2-vinyltetrahydrofuran), rosefuran (3-methyl-2- (3-methyl-2-butenyl) -furan), heptabelt (2-heptyltetrahydrofuran), mentofuran, theaspirane, oxybet (2- Oxaspiro [4,7] dodecane), Muscogen (3-oxabicyclo [10.3.0] -6-pentadecene), Cicamba (13-oxabicyclo [1])
0.3.0] Pentadecane), ambroxane (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.
1-b] furan), glycalva (3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1-b].
Franc), 1,8-cineole, 1,4-cineole,
Galaxolid (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-γ-2-benzopyran), rose oxide, nerol oxide, rimitol (2 , 2,6-Trimethyl-
6-vinyltetrahydropyran), dilan (2-butyl-4,6-dimethyldihydropyran), doremox (tetrahydro-4-methyl-2-phenyl-2H-pyran), ruvofluor (9-ethylidene-3-oxatricyclo). [6.2.1.0 ^2.7 ] undecane), hexahydroindenopyran and the like.

The acid compounds include gellan acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid, 2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, 3- Methylvaleric acid, hexanoic acid, isohexanoic acid, 2-hexanoic acid, 4-pentenoic acid, 2-methyl-
2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid,
Octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylenic acid, dodecanoic acid, myristic acid, palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid, lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, Three
-Phenylpropionic acid, vanillic acid, valine, abietic acid, sorbic acid and the like.

As the lactone compound, pentalide (cyclopentadecanolide), havanolide (oxacyclohexadecen-2-one), ambrettolide, cyclohexadecanolide, 10-oxahexadecanolide,
11-oxahexadecanolide, 12-oxahexadecanolide, ethylenedodecanedioate, γ-butyrolactone, γ-valerolactone, angelicalactone, γ
-Hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3-
Methyl-4-octanolide), γ-decalactone, γ-
Undecalactone, γ-dodecalactone, γ-jasmolactone, jasmine lactone, cis-jasmon lactone, lactojasmon (4-methyl-4-decanolide), jasmolactone (tetrahydro-6- (3-pentenyl) -2H- Pyran-2-one), menthalactone (3,6-dimethyl-5,6,7,7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undeca Lactone, δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactocatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone), coumarin, dihydrocoumarin, cyclohexyl lactone, 6-
Methylcoumarin, ε-decalactone, ε-dodecalactone and the like can be mentioned.

As the ester compound, ethyl formate,
Propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate, neryl formate, rosinyl formate, terpinyl formate, cerylyl formate, caryofelen formate, Afermate (α, 3,3-trimethylcyclohexanemethyl formate), oxyoctaline formate, benzyl formate, cinnamyl formate, phenylethyl formate, anisyl formate, eugenyl formate, decahydro-β-naphthyl formate, methyl acetate, ethyl acetate, acetic acid Propyl, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate, cis-3-hexenyl acetate, trans-2 acetate
-Hexenyl, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, dodecyl acetate, dimethylundecadienyl acetate, diacetyl, Diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, ocimenyl acetate, myrcenyl acetate, dihydromyrcenyl acetate, dimethyloctanyl acetate, linalyl acetate, citronellyl acetate, rosinyl acetate, geranyl acetate, acetic acid Neryl, tetrahydromugol acetate, ethyl linalyl acetate, lavandulyl acetate, isohydrolavanduryl acetate, nerolidol acetate, carbyl acetate, dihydrocarbyl acetate Le, acetate dihydro Kumi sulfonyl, terpinyl acetate, acetate isopulegol, menthyl acetate, acetic citryl acetate Miruteniru acetate Nopiru acetate fenchyl, bornyl acetate, isobornyl acetate, acetic cedryl, caryophyllene acetate, acetic Santariru,
Vetiveryl acetate, guaiac acetate, methyl cyclopentylidene acetate, cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amylcyclohexyl acetate, dihydroterpinyl acetate, cyclohexyl ethyl acetate, fluorolate (2,4-dimethyl-3-acetic acid acetate Cyclohexenylmethyl), rosamsk (acetic acid α, 3,3-
Trimethylcyclohexanemethyl), Vertenex (p-tert-butylcyclohexyl acetate), Verdox (o-tert-butylcyclohexyl acetate),
1-Ethynylcyclohexyl acetate, dihydroambulate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), miraldyl acetate (4 (3)-(4
-Methyl-3-pentenyl) -3-cyclohexenylmethyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styrylyl acetate, p-methylbenzyl acetate, acetic acid Anisyl, piperonyl acetate, acetyl vanillin, rosephenone, hydratropyl acetate, 2,4 acetate
-Dimethylbenzyl, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzylcarbyl acetate, phenylglycol diacetate, dimethylphenylethylcarbinyl acetate, phenylethylmethylmethylethylvinylacetate, veticolacetate (4-methyl-
4-phenyl-2-pentyl acetate), α-amylcinnamyl acetate, jasmalol (trans-decahydro-β-naphthyl acetate), furfuryl acetate, tetrahydrofurfuryl acetate, jasmal (3-pentyltetrahydropyranyl acetate), jasmeria (acetic acid) 5
-Methyl-3-butyltetrahydropyranyl), ethyl acetoacetate, gessate (2-hexyl acetoacetate ethyl), ethyl benzylacetoacetate, allyl cyclohexyl acetate, isopropyl cyclohexenyl acetate, ethyl propionate, propyl propionate, allyl propionate. , Butyl propionate, isobutyl propionate,
Isoamyl propionate, hexyl propionate, cis-3-hexenyl propionate, tra propionate
ns-2-hexenyl, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate, carbyl propionate, terpinyl propionate, menthyl propionate, bornyl propionate, isobornyl propionate, Tricyclodecenyl propionate, Benzyl propionate, Styralyl propionate, Anisyl propionate, Phenylethyl propionate, Cinnamyl propionate, Phenylpropyl propionate, Dimethylbenzylcarbionate propionate, Phenoxyethyl propionate, Propylene glycol propionate Dipropionate, allylcyclohexanepropionate, labdanax (3-hydroxy-3phenylpropionic acid) Le), furan acid isobutyl, methyl butyrate, ethyl butyrate, propyl butyrate, isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, pentyl butyrate, isoamyl butyrate, hexyl butyrate, heptyl butyrate, cis-3- hexenyl, butyric acid tran
s-2-hexenyl, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate,
Rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, dimethylbenzylcarbyl butyrate, tetrahydrofurfuryl butyrate, santalyl butyrate, methyl isobutyrate, ethyl isobutyrate, isobutyrate propyl , Isopropyl isobutyrate, butyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, hexyl isobutyrate,
Cis-3-hexenyl isobutyrate, 2,4-hexadienyl isobutyrate, isopentylate (1,3-dimethyl-3-butenyl isobutyrate), octyl isobutyrate, linalyl isobutyrate, citronellyl isobutyrate, rosinyl isobutyrate,
Geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate,
P-Cresyl isobutyrate, cinnamyl isobutyrate, phenylethyl isobutyrate, phenylpropyl isobutyrate, styrylyl isobutyrate, dimethylcarbinyl isobutyrate, dimethylphenylethylcarbinyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydroisobutyrate- β-naphthyl, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2-methylbutyl 2-methylbutyrate, sidorane (2-
(Hexyl methylbutyrate), cis-3-hexenyl 2-methylbutyrate, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, ethyl valerate, valeric acid Butyl, isobutyl valerate, amyl valerate, cis-valerate
3-hexenyl, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, propyl isovalerate, isopropyl isovalerate, allyl isovalerate, butyl isovalerate, isovaleric acid Isobutyl, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, cis-valerate
3-hexenyl, hexyl isovalerate, octyl isovalerate, linalyl isovalerate, citronellyl isovalerate,
Geranyl isovalerate, Menthyl isovalerate, Terpinyl isovalerate, Cyclohexyl isovalerate, Benzyl isovalerate, Phenylethyl isovalerate, Phenylpropyl isovalerate, Cinnamyl isovalerate, Manzanate (2
-Ethyl methyl valerate), phenyl salicylate, peranato (2-methyl valeric acid 2-methylpentyl ester), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, hexanoic acid Isobutyl, amyl hexanoate, isoamyl hexanoate, hexyl hexanoate, cis-3-hexenyl hexanoate, t hexanoate
rans-2-hexenyl, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, citronellyl hexanoate, benzyl hexanoate, methyl isohexanoate, methyl 2-hexenoate, t
ethyl trans-2-hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, ethyl 3-hydroxyhexanoate, ethyl 2-ethylhexanoate, mersat (3,5,5-trimethyl Ethyl hexanoate), berifuro (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, octyl heptanoate, methyl octanoate, ethyl octanoate,
Amyl octanoate, butyl octanoate, propyl octanoate, allyl octanoate, isoamyl octanoate, hexyl octanoate, heptyl octanoate, octyl octanoate, linalyl octanoate, benzyl octanoate, phenylethyl octanoate, p-cresyl octanoate , 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, bouvartate (methyl 2-nonenate), methyl 3-nonenate, methyl decanoate, ethyl decanoate, isopropyl decanoate, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienoate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylenate, isoamyl undecylenate, methyl dodecanoate, ethyl dodecanoate, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, ethyl oleate, methyl benzoate, ethyl benzoate, propyl benzoate, isopropyl benzoate, benzoic acid Allyl,
Isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, linalyl benzoate, geranyl benzoate, benzyl benzoate, phenylethyl benzoate, cinnamyl benzoate, methyl anisate, anise. Ethyl acid salt, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelica, butyl angelica, isobutyl angelica, isoamyl angelica, prenyl angelica, cis-3 angelica. -Hexenyl, 3-methylpentyl angelica, phenylethyl angelica, ethyl acrylate, phenylethyl methacrylate, ethyl crotonate,
Isobutyl crotonic acid, cyclohexyl crotonic acid, flutinato (4-methyl-pentan-2-ol-crotonate), pyroprunato (2-cyclopentyl-cyclopentyl crotonate), datilato (1-cyclohexylethyl crotonate), levulinate, levulinic acid Butyl, isoamyl levulinate, methyl lactate, ethyl lactate, amyl lactate, isobutyl lactate, cis-3-lactate
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelanate, ethyl cyclogellanate, ethylmethylphenylglycidate, fructate (ethyltricyclo [5.2.
1.0 ^2.6 ] Decan-2-ylcarboxylate), divescon (ethyl-2-ethyl-6,6-dimethyl-2)
-Cyclohexene-1-carboxylate and ethyl-2,3,6,6-tetramethyl-2-cyclohexenecarboxylate), ethyl safranate (ethyl dehydrocyclogeranate), allyl cyclohexylpropionate, cyclogalvanate (allyl cyclohexyl) Oxyacetate), calixol (ethyl-2-methyl-6-pentyl-4-oxocyclohex-2-enecarboxylate), tachrysate (methyl-1-methyl-3-cyclohexenecarboxylate), floramate (ethyl-2-). tert-butylcyclohexyl carbonate), jasmate cyclate (methylcyclooctyl carbonate), mahagonate (1-methyl-4)
-Isopropyl-2-carbomethoxybicyclo [2.
2.2] -Oct-5-ene), phenylethyl pivalate, methyl jasmonate, hedion (methyl dihydrojasmonate), belamos (methyl-3,6-dimethyl-β-resorsylate), methyl furancarboxylate, furan Ethyl carboxylate, propyl furan acrylate, methyl heptine carboxylate, ethyl heptine carboxylate,
Heptincarboxylate isoamyl, octylcarboxylate methyl, octynecarboxylate ethyl, decynecarboxylate methyl, glycomel (3- (bicyclo [2.2.1] hept-5-en-2-yl) -3 methyloxirane carboxylic acid Methyl ester), methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-1
6 (ethyl 3-methyl-3-phenylglycidate), aldehyde C-20 (ethyl p-methyl-β-phenylglycidate), ethyl methyl p-tolylglycidate, ethyl citronellyl oxalate, diethyl succinate, Dimethyl succinate, diethyl malonate, diethyl tartrate, diethyl adipate, diethyl sebacate, triethyl citrate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, methyl phenylacetate, ethyl phenylacetate, phenylacetate isopropyl, phenylacetate butyl , Phenyl phenylacetate, isobutyl phenylacetate, isoamyl phenylacetate, hexyl phenylacetate, phenylacetic acid c
is-3-hexenyl, citronellyl phenylacetate, rosinyl phenylacetate, geranyl phenylacetate, menthyl phenylacetate, benzyl phenylacetate, phenylethyl phenylacetate, p-cresyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, methyl cinnamate, Ethyl cinnamate, propyl cinnamate, isopropyl cinnamate, allyl cinnamate, isobutyl cinnamate,
Isoamyl cinnamate, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate,
Methyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, cilicylate ci
s-3-hexenyl, cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate, cyclopidene (methylcyclopentylideneacetate), avalin (methylabietate), hercoline (methyldihydroabietate), salicylate p
-Cresyl, allyl phenoxyacetate, ethyl phenylpropionate, ethylene brassielate, triacetin and the like.

As the nitrogen-containing compound, methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, N
-Methyl anthranilate, auranthiol (Schiff base of hydroxycitronellal-methyl anthranilate), mevantraal (methyl propylacetaldehyde-methyl anthranilate Schiff base), jasmentin (α-amylcinnamic aldehyde-methyl anthranil Schiff base), ligantral (methyl- (3,5-dimethyl-3-cyclohexen-1-yl) methylene anthranilate), indole, skatole, clonal (dodecanenitrile), tangerine (2-tridecenenitrile), Citralva (geranyl nitrile), citronellyl nitrile, lemonyl (3,7-dimethyl-2,6-nonadienitrile), cuminyl nitrile, cinnamalva (cinnamyl nitrile), trimethyl Amine, pyridine, 3-ethylpyridine, 2-acetylpyridine, 3-acetylpyridine, 2-isobutylpyridine, 3-isobutylpyridine, 2-n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4 -(1,4,8-
Trimethyl-3,7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p-methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-se
c-butylquinoline, 8-sec-butylquinoline, 6
(P) -tert-butylquinoline, 2-tert-butylquinoline, N-substituted-paramenthane-3-carboxamide, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3 , 5
-Trimethylpyrazine, 2-ethylpyrazine, 2-ethyl-3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2,3-diethyl-5
-Methylpyrazine, tetramethylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-isopropylpyrazine, 2
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-ethylpyrazine, methylthiomethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8)
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indole (Schiff base of indole-hydroxycitronellal),
2-methylbenzoxazole, decahydrocyclododecaxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), Gardamide (N-methyl-N-phenyl-2-methylbutyramide), Musk xylol, Musk ketone, Musk ambrette, Musk tibetan, Mosken, 2,6-lutidine, piperidine , 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine, capsaicin, nonanoic acid vanillylamide, quinine, perillartine (L-perilaldehyde α-anti-aldoxime), 2-isopropyl-4-methylthiazole , 2-isobutylthiazole and the like.

As the sulfur-containing compound, thiazole, 4
-Methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole, 2-isopropyl-4-methylthiazole, 4-
Methyl-5-vinylthiazole, 2-isobutylthiazole, sulfurol (4-methyl-5-thiazoleethanol), sulfuryl acetate (4-methyl-5-)
(Thiazole ethanol acetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole,
Benzothiazole, propyl mercaptan, hydrogen sulfide,
Isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomenthone) phenyl mercaptan, o-thiocresol, 2-ethylthiophenol,
2-naphthyl mercaptan, furfuryl mercaptan,
2-methyl-3-furanthiol, dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide,
Methylpropyl disulfide, methylpropyl trisulfide, propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio)
-1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), mint sulfide, dithiospirofuran,
Furfuryl methyl sulfide, 2-methyl-5-methylthiofuran, methylfurfuryl disulfide, furfuryl disulfide, thiophene, tetrahydrothiophene, 3-thiophene carboxaldehyde, 5-methyl-2-thiophene carboxaldehyde, tetrahydrothiophen-3-one , Trithioacetone, thioglycolic acid, methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropionic acid, pineapple mercaptan (methylmercaptomethylpropionate), 3
-Ethyl methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methylmethanethiosulfonate, allyl isothiocyanate, benzyl isothiocyanate, thirazine (2,4,6-trimethyl-4, 5-dihydro-
1,3,5-dithiazone), oxane (2-methyl-4)
-Propyl-1,3-oxathiane) and the like.

Examples of natural flavors include asaphetida resininoid, ajowan oil, star anise oil, abies oil, amyris oil, ambrette seed oil, ambergris tincture, ylang ylang oil, ylang ylang absolute, iris resinoid, iris absolute, Iris oil, wintergreen oil, elemioleoresin, elemiresinoid absolute, eremitinki, oakmoss concrete, oakmoss absolute, oakmoss resin, oakmoss resinoid, ocotia oil, osmanthus absolute, osmanthus concrete, opopanax resinoid, opopanax absolute , Opopanax oil, Olivanum resinoid, Olivanum absolute, Olivanum Yl, allspice oil, Olga Nam oil, oregano oil, oregano oleoresin, orange oil, orange flower absolute, orange flower concrete, Kanangaoiru,
Garjun balsam, garjun balsam oil, cascari rubber oil, castorium absolute, cassi absolute, cassiflower oil, cassia oil, gardenia absolute, carnations absolute, cabreuba oil, chamomile oil, cardamom oil, galbanum oil, galvanum resin, Galvanum Resinoid, Caraway Seed Oil, Carrot Seed Oil, Guayak Wood Oil, Guayak Resin, Guayak Concrete, Camphor Oil, Cubeba Oil, Cumin Oil, Cumin Absolute, Cumin Oleoresin, Clary Sage Oil, Grapefruit Oil, Clove Oil, Costas Oil, Copaiba Balsam, Copaiba Balsam Oil, Copaiba Balsamure Down, coriander oil, sassafras oil, sandalwood oil, Genet absolute, Shisooiru, citronella oil, jasmine oil, jasmine absolute, jasmine concrete, juniper berry oil, civet absolute, civet tincture, Jonquil absolute,
Agarwood oil, ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, styrax oil, styrax resinoid, spearmint oil, savory oil, sage oil, cedar oil, cedar leaf oil, geranium oil, celery seed oil , Thyme Oil, Taguette Oil, Tarragon Oil, Tuberose Absolute, Dill Oil, Tea Tree Oil, Trimos Absolute, True Balsam, Nutmeg Oil, Narcissus Absolute, Neroli Oil, Violet Leaf Absolute, Pine Oil, Pine Needle Oil, Basil Oil, Parsley leaf oil, parsley seed oil, parsley herb oil, patchouli oil, peppermint oil, vani Absolute, Honeysuckle Absolute, Palmarosa Oil, Valerian Oil, Bitter Orange Oil, Hyssop Oil, Hiba Oil, Hyacinth Absolute, Fennel Oil, Fig Guab Solut, Petit Glen Oil, Butch Oil, Bay Oil, Vetiver Oil, Penny Royal Oil, Pepper Oil, Peppermint Absolute , Peppermint oil, bergamot oil, peruvian balsam, benzoin tincture, benzoin resinoid, boad rose oil, borax oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil , Mill Resinoid, Mill Absolute, Mi Oil, musk absolute, musk root, eucalyptus oil, yuzu oil, mugwort oil, lime oil, labdanum oil, labdanum resinoid, lavender oil, lavender absolute, lavandin oil, lavandine absolute, linaloe oil, lemon oil, lemongrass oil, rose oil, Rose absolute,
Examples thereof include rose concrete, rosemary oil, lovage oil, laurel oil, laurel leaf oil, wormwood oil, musk, spirit cat scent, dragon scent, raccoon incense, musk and chibata.

As a mixed fragrance containing a combination of fragrance ingredients,
There are the following fragrance bases. Lemon tone, lime tone, orange tone, sweet orange tone, mandarin tone,
Citrus type base such as bergamot, petit gren, neroli, lemongrass, agemon, etc., fresh type base, apple, peach, strawberry, coconut, pineapple, raspberry, watermelon, grape Tone, mango tone, fruit mix tone, tropical fruit tone and other fruity type bases, rose tone, jasmine tone, muguet tone, lilac tone, carnation tone, hyacinth tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, violet tone , Iran-like, floral bouquet-like floral type base, cinnamon bark-like, cinnamon leaf-like, clove-like, pimento-berry-like, nutmeg-like, pepper-like, cardamom-like, coriander-like, cumin-like, etc. Wood, cedarwood, vetiver, sandalwood, guaiac wood, woodian bar, woody iris, and other woody type bases, smoky, quinoline, and other leather types, vanilla, tonka, honey, Pure balsam-like sweet type base, other butter flavor, milk flavor, aldehydick type base, amber type base, animal type base, anise type base, aromatic herbal type base, agar type base, aqua type base, camphor cineole Type base, green type base, seed type base, herb type base, pine type base, patchouli type base, balsamic type base, mint type base, musk type base Vinegar, Moss type base, lavender type base, linalool type base, and a resin-type base and the like.

Here, rosmarinic acid in the present invention is
It is widely known that it has an antioxidant effect. In the present invention, the antioxidant action of rosmarinic acid stabilizes the fragrance component having a double bond or a triple bond, which is unstable in structure and easily oxidized, and which has a double bond or a triple bond to stabilize the fragrance. Sex is improved. Further, rosmarinic acid in the present invention has a faint rosemary-like odor, and by this odor, citrus tone, floral tone, fruity tone, neroli tone, herb tone, spice tone,
It can accentuate musk amber, woody and sweet scents, improving scent and aroma lasting. Examples of the fragrances in which these effects are suitably exhibited include those shown below.

Hydrocarbon compounds include dihydromyrcene, α-pinene, β-pinene, limonene, myrcene and p.
-Symmen, etc.

For alcohol compounds, geraniol,
Citronellol, nerol, dihydrolinalool, linalool, mugol, dihydromyrcenol, ethyl linalool, terpineol, farnesol, vetiverol, patchouli alcohol, menthol, isoamyl alcohol, leaf alcohol (cis-3-hexenol), santalinol (2-methyl-). 4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Butene-1-ol), Sandalol (3-methyl-5)
-(2,2,3-Trimethylcyclopent-3-ene-
1-yl) pentan-2-ol), benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styrylyl alcohol (1-phenyl-1-hydroxyethane), amylcinnamic alcohol, bacdanol (2-ethyl-4-). (2,2,3-trimethyl-
3-cyclopenten-1-yl) -2-buten-1-ol), polysanthol (3,3-dimethyl-5-
(2,2,3-Trimethyl-3-cyclopentene-1-
Ill) -4-penten-2-ol), borneol,
Geranyl linalool, p-methylbenzylcarbinol, muguet alcohol (2,2-dimethyl-3-phenylpropanol) and the like can be mentioned.

Among the phenol type and phenol ether type compounds, estragal, chavicol, anethole, p-cresyl methyl ether, β-naphthol ethyl ether, β-naphthol methyl ether, eugenol, methyl eugenol, methyl isoeugenol,
Hinokitiol and the like can be mentioned.

Among the aldehyde compounds, citronellal, citral, hydroxycitronellal, acetaldehyde, cis-3-hexenal, trans-2
-Hexenal, Melonal (2,6-dimethyl-5-
Heptenal), 2,4-nonadienal, muguealdehyde (6,10-dimethyl-3-oxa-9-undecenal), tripral (dimethyltetrahydrobenzaldehyde), dupicar (4-tricyclodecylidenebutanal), miracaldehyde ( 4 (3)-
(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), benzaldehyde, phenylacetaldehyde, cyclamenaldehyde (2-methyl-3- (p-isopropylphenyl)-
Propionaldehyde), cinnamic aldehyde, anisaldehyde, vanillin, ethyl vanillin, heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde), lyral (4 (3)-(4-hydroxy- 4-methylpentyl)
-3-cyclohexene-1-carboxaldehyde),
Lilyal (p-tert-butyl-α-methylhydrocinnamic aldehyde), α-methylcinnamic aldehyde, α-hexylcinnamic aldehyde, n-
Examples include octanal, n-nonanal, 2-methylundecanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal and dodecanal.

In the acetal and ketal compounds,
Acetaldehyde diethyl acetal, caranal (2
-(2,4-Dimethylcyclohex-3-sen-1-yl) -5-methyl-5 (1-methylpropyl) 1,3-
Dioxane), osminal DEA (amylcinnamic aldehyde diethyl acetal), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate) and the like.

Among the ketone compounds, carvone, menthone, shabu brain, ethyl isoamyl ketone, methylheptenone, cis-jasmon, dihydrojasmon, maltol, ethylmaltol, benzophenone, methylnaphthylketone, raspberry ketone (4- (p-hydroxyphenyl)- 2-butanone), damascenone, damascone, ionone, methyl ionone, irone, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo [5.3.1 ^1.7 .0 ^1.5] -8-undecene) , Cashmeren (6,7-dihydro-1,1,2,3,3-
Pentamethyl-4 (5H) -indanone), muscone (3-methylcyclopentadecanone-1), musenone delta (3-methylpentadeca-4-enone), civetone (cycloheptadec-9-en-1-one) , Musk T
M-II (cyclohexadecenone), traseolide (5-acetyl-3-isopropyl-1,1,2,6-
Tetramethylindan), tonalide (6-acetyl-
1,1,2,4,4,7-hexamethyltetrahydronaphthalene), iso-E-super (7-acetyl-)
1,2,3,4,5,6,7,8-octahydro-1,
1,6,7-tetramethylnaphthalene) and the like.

Among the ether compounds, ambroxane (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-b] furan), 1,8-cineole, galaxolide (1,3,4,6,6). 7,8-hexahydro-
4,6,6,7,8,8-hexamethylcyclopenta-
(γ-2-benzopyran), rose oxide and the like.

Examples of acid compounds include acetic acid.

Lactone compounds include pentalide (cyclopentadecanolide), havanolide (oxacyclohexadecen-2-one), ambrettolide, cyclohexadecanolide, cis jasmon lactone, γ-nonalactone, γ-undeca lactone. Examples include lactone and coumarin.

Among the ester compounds, ethyl acetate, butyl acetate, isoamyl acetate, allylamyl glycolate,
Linalyl acetate, citronellyl acetate, geranyl acetate, terpinyl acetate, isobornyl acetate, belldox (acetic acid o
-Tert-butylcyclohexyl), benzyl acetate,
Phenylethyl acetate, styralyl acetate, rosephenone, cinnamyl acetate, dimethylbenzylcarbyl acetate, α-amylcinnamyl acetate, manzanate (ethyl 2-methylvalerate), ethyl oleate, methyl benzoate, ethyl safranate (ethyl dehydrocyclogela Nate), hedion (methyl dihydrojasmonate),
Examples thereof include diethyl phthalate, methyl salicylate, amyl salicylate, hexyl salicylate, benzyl salicylate, hercoline (methyldihydroabietate), ethylene brushlate, and benzyl propionate.

Among the nitrogen-containing compounds, methyl anthranilate, auranthiol (Schiff base of hydroxycitronellal-methyl anthranilate), indole,
Examples thereof include skatole, isobutylquinoline, pyrazine, musk ketone, pyridine and the like.

Examples of the sulfur-containing compound include limonene thiol.

Among natural flavors, star anise oil, ylang-ylang oil, iris oil, elemi oil, orange oil, orange flower absolute, cassia oil, chamomile oil, cardamom oil, clary sage oil, grapefruit oil, clove oil, coriander oil, sandalwood. Oil, citronella oil, jasmine absolute, spearmint oil, geranium oil, neroli oil, petitgrain oil, peppermint oil, bergamot oil,
Mandarin oil, eucalyptus oil, lime oil, lavender oil, lavandin oil, lemon oil, lemongrass oil, rose oil, rose absolute, rosemary oil and the like can be mentioned.

Furthermore, as the solvent for the fragrance, ethanol,
Acetine (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, deltil extra (isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), Carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aborin (dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnesene, dioctyl adipate, tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl abietate, avalin (methyl abietate), citroflex A-2 (acetyltriethyl citrate), citroflex A-4 (tributylacetyl citrate), citroflex No. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate),
Examples include polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like.

Of the above solvents, ethanol, ethylene glycol dibutyrate, hexylene glycol, methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), propylene glycol, dipropylene glycol DPG-FC (dipropylene glycol). Solvents for fragrances such as propylene glycol and 1,3-butylene glycol can be used to adjust the aroma potency.

The amount of these solvents used is 0.1 to 99% by mass, preferably 1 to 40% by mass, in the fragrance composition comprising the above fragrance and the solvent.

In the first composition of the present invention, such a fragrance composition is usually blended in an amount of 0.00001 to 50% by mass, preferably 0.0001 to 30% by mass. If the blending amount is less than 0.00001% by mass, a sufficient flavor may not be obtained, and if it exceeds 50% by mass, the flavor may be too strong and the quality of the composition may be deteriorated.

In the first composition of the present invention, the above fragrance is preferably supported between the layers of the swelling clay mineral from the viewpoint of exhibiting the effect of excellent flavor scenting, stability and durability. The swelling clay mineral is a kind of colloidal hydrous aluminum silicate having a three-layer structure, specifically, a natural or synthetic montmorillonite group such as montmorillonite, saponite, and hectorite (commercial products such as bee gum, kunipia, and laponite). , Bengel, etc.), sodium silicic mica, and synthetic mica known as lithium teniolite (commercially available Dimonite; Toby Industry Co., Ltd.)
Etc. These may be used alone or in appropriate combination of two or more.

In particular, an organically modified smectite clay mineral (commercially available product) obtained by dispersing and stirring a quaternary ammonium salt type cationic surfactant and / or a nonionic surfactant and then removing the low boiling point solvent. Then, Esben E, Esben W, Esben XL, Esben N-40
0: a detergent composition (shampoo, conditioner, conditioner, shampoo, rinse, etc.) which is washed by depositing a fragrance between the layers of Toyosyun Yoko Co., Ltd., Kraton AF, Kraton SO; Southern Clay Product Co., Ltd. When used in treatments, body soaps, hand soaps, soaps, facial cleansers, laundry detergents, bleaches, softeners, dishwashing detergents, bathroom detergents, toilet detergents, etc.) It is preferable in that it has an effect on.

The above fragrance is a swelling clay mineral 1 in a mass ratio.
To 0.1 to 20 and mixed and supported. Furthermore, the ratio of 0.5 to 15 is preferable. If it is less than 0.1, the mixture may become hard and may be difficult to handle. Further, when it exceeds 20, the carrying effect is not affected, and the effect of retaining the scent may not change. This supported material can be obtained by blending a predetermined amount of swelling clay mineral with a fragrance at 5 to 50 ° C. and stirring with a paddle or the like for 5 to 30 minutes.

Further, as an optional component for improving the viscosity and stability of the supported material, an oily component, a highly oily nonionic surfactant having an HLB of 16 or less, a silicone oil, a modified silicone emulsion and the like can be added.

The blending amount of the swelling clay mineral in the first composition of the present invention is not particularly limited and can be appropriately selected depending on the type, formulation of the composition, etc. It is desirable that the content be 0.001 to 20% by mass, preferably 0.005 to 10% by mass, based on the whole product. If the content is less than 0.001% by mass, the retention effect may not be sufficiently obtained, and if it exceeds 20% by weight, the retention effect may not change, and precipitates may occur.

The first composition of the present invention preferably contains a chelating agent from the viewpoint of stabilizing the composition containing a perfume ingredient. The chelating agent of the present invention generally means a compound having a chelating effect, for example, pyrophosphoric acid,
Condensed phosphoric acid such as polyphosphoric acid, oxycarboxylic acid such as citric acid and salts thereof, ethylenediaminetetraacetic acid (EDT
Examples thereof include polyaminocarboxylic acids and salts thereof such as A), porous inorganic substances such as zeolite, and clay minerals such as smectite and bentonite. Of these, oxycarboxylic acids such as citric acid are particularly preferable. When the chelating agent is added to the composition, it may be added as a free acid or a salt, and these can be used alone or in combination of two or more kinds.

The amount of the above chelating agent to be added is usually 0.0001 to 50% by mass, preferably 0.
It is desirable that 001 to 30 mass% be blended. If the blending amount is less than 0.0001% by mass, a sufficient stabilizing effect may not be obtained, and if the blending amount exceeds 50% by mass,
Precipitates may form.

The present invention also provides a second composition for treating hair or textiles, characterized by containing rosmarinic acid and a cationic surfactant. The combined use of rosmarinic acid and a cationic surfactant can remarkably improve the uncomfortable feel of the hair or fiber surface due to damage.

In the second composition for treating hair or textiles, the content of rosmarinic acid is not particularly limited, but usually 0.01 to 20 relative to the total composition.
%, Preferably 0.1 to 5% by mass, more preferably 0.1 to 2% by mass. Blending amount 0.01
If it is less than 20% by mass, the effect of preventing split ends and broken hair may not be sufficiently obtained, and if it exceeds 20% by mass, a good feeling in use may not be obtained.

Examples of the cationic surfactants include aliphatic amine salts (primary amine salt, secondary amine salt, tertiary amine salt, quaternary ammonium salt, hydroxyammonium salt, ether ammonium salt), and aromatic compounds. Group quaternary ammonium salts (benzalkonium salts, benzethonium salts,
Pyridinium salt), an amino acid-based cationic surfactant, a guanidine derivative or a salt thereof (4-guanidinobutyllauroamidoacetic acid, etc.), and the like, and these may be used alone or in appropriate combination of two or more. it can. These are specifically shown below.

[0064]

[Chemical 2]

[0065]

[Chemical 3]

[0066]

[Chemical 4]

[0067]

[Chemical 5]

[0068]

[Chemical 6]

[0069]

[Chemical 7]

[0070]

[Chemical 8]

[0071]

[Chemical 9]

[0072]

[Chemical 10]

[0073]

[Chemical 11]

In the above formula, R ¹ has 12 to 12 carbon atoms.
24, preferably 12 to 22 alkyl or alkenyl groups, wherein R ² , R ³ and R ⁴ each have 1 to 3 carbon atoms.
Alternatively, it represents 12 to 24, preferably 1 to 3 alkyl or alkenyl groups. R represents an alkyl group having 1 to 12 carbon atoms, preferably 1 to 6 carbon atoms. X represents an anion derived from a salt such as chloride, bromide, iodide, methylsulfate and ethylsulfate. Specific examples of R ¹ include alkyl or alkenyl groups such as lauryl, myristyl, palmityl, stearyl and oleyl.
Specific examples of ² , R ³ and R ⁴ include an alkyl group or an alkenyl group such as methyl, ethyl, stearyl, oleyl and the like, and the same alkyl group or alkenyl group as the above R ¹ .

The second composition of the present invention has an excellent effect of improving the quality of hair or fibers and can be suitably used for hair cosmetics, softening compositions and the like. In the case of hair cosmetics, the above cationic surfactant The content of the agent is not particularly limited, but is usually 0.01 to 5% by mass, preferably 0.1% by mass relative to the entire cosmetic.
It is selected in the range of 1 to 3% by mass, more preferably 0.1 to 2% by mass. If the blending amount is less than 0.01% by mass, the effect of improving the feel of hair may not be sufficiently obtained, and
If it exceeds 5% by mass, a good feeling in use may not be obtained in some cases. On the other hand, in the case of the softener composition, it is usually selected in the range of 0.1 to 20% by mass, preferably 1 to 15% by mass, and more preferably 2 to 10% by mass, based on the entire composition. If the blending amount is less than 0.1% by mass, the effect of improving the feel of the fiber may not be sufficiently obtained.
If it exceeds, good use feeling may not be obtained.

The second composition of the present invention contains a hydroxycarboxylic acid selected from gallic acid and its glycosides or gluconic acid and its derivatives from the viewpoint of improving the squeaky feeling of hair or textiles. preferable. Examples of hydroxycarboxylic acids include gallic acid and its glycosides, gluconic acid and its salts, and gluconic acids which are glycosides. These may be used alone or in appropriate combination of two or more. Examples of the salts include alkali metal salts such as sodium and potassium salts, ammonium salts, triethanolamine salts, transition metal salts and the like. Examples of glycosides include those obtained by glycosylating glucose, maltose, galactose and the like.

More specifically, the hydroxycarboxylic acid used in the present invention is, for example, gallic acid methyl ester-
3-Glucoside, gallic acid methyl ester-4-glucoside, gallic acid propyl ester-3-glucoside, gallic acid methyl ester-3-maltoside, gallic acid-3
-Glucoside, gallic acid-3-maltoside, gallic acid-
Gallic acid diacids such as octyl-3-maltoside, gallic acid-3-glucuronide, gallacturonide gallate, gallic acid methyl ester-3,5-diglucoside, gallic acid-3,4-diglucoside, gallic acid-3,5-diglucoside Examples thereof include gallic acid glycosides such as glycosides, and gluconic acids such as gluconic acid, zinc gluconate, copper gluconate, and iron gluconate. Of these, gallic acid-3,5-diglucoside is particularly preferable.

The method for producing the above-described diglycoside gallate is as follows:
Gallic acid or its ester and the like, and saccharides whose hydroxyl groups are partially or completely acetylated or whose anomeric positions are halogenated are, for example, BF ₃ .Et ₂ O, SnCl ₄ ,
The reaction is carried out in a solvent in the presence of an acid catalyst such as ZnCl ₂ to obtain a glucosylated product. If necessary, this is subjected to a deprotection reaction in the presence of an acid or alkali catalyst, and purified by extraction, column chromatography, etc. Thus, the manufacturing can be performed easily and efficiently.

When the composition of the present invention is used as a hair cosmetic, the content of the above-mentioned hydroxycarboxylic acids is not particularly limited, but is usually 0.01 to 1 with respect to the entire cosmetic.
A range of 0% by mass, preferably 0.1 to 5% by mass, more preferably 1 to 5% by mass is suitable. Blending amount 0.01
If it is less than 10% by mass, it may be difficult to obtain a sufficient touch improving effect, and if it exceeds 10% by mass, flaking may occur.

In the case of a composition for treating hair or textiles, the composition of the present invention is a conventional composition for treating hair or textiles, in addition to the above-mentioned components, within a range not impairing the object of the invention. Various commonly used additive components can be blended as desired. In this case, it is also effective to blend the above-mentioned flavor, swelling clay mineral, and chelating agent.

Examples of these additive components include nonionic surfactants such as polyoxyethylene alkyl ether and polyoxyethylene hydrogenated castor oil, amphoteric surfactants such as lauryldimethylaminoacetic acid betaine, hydroxyethyl cellulose and polyacrylic acid. Polymeric thickeners such as
Polyvinylpyrrolidone, set polymer resins such as alkyl resins, organic acids such as citric acid and glycolic acid and salts thereof,
Amino acids, protein hydrolysates, bactericides, UV absorbers, antioxidants, higher alcohols, silicone compounds such as methylpolysiloxane and amino-modified silicones and their derivatives, hydrocarbons, ester oils, colorants, solvents (ethanol, water) Etc.) and fatty acids.

These additive components may be used alone or in combination of two or more, and may be blended at an appropriate stage of composition preparation.

The formulation of the composition of the present invention is not particularly limited, and various forms such as liquid, cream, aerosol, pump spray type, spray type, foam, gel, wax and the like can be used. It can be prepared according to the usual method for each dosage form.

In this case, for example, liquefied petroleum gas, dimethyl ether, carbon dioxide gas, nitrogen gas and the like can be used as a propellant to be mixed when the composition of the present invention is made into a foam-forming aerosol type. Further, the preparation method may employ a usual method, specifically, the water-soluble component and the oil-soluble component in the above components are separately dissolved and mixed, and after these are mixed, a propellant is filled in a container and used. can do.

The composition of the present invention is excellent in fragrance and stability of a flavor component and can be applied to cosmetics, detergents, pharmaceuticals, quasi drugs, foods, and the quality of hair or fiber. It has an excellent effect of improving statically and can be suitably used for hair cosmetics, softening compositions and the like.

Particularly in the case of hair cosmetics, it can be widely used as an in-bath hair care agent and an out-bath hair care agent such as shampoo, conditioner, treatment, hair cream, hair gel, hair foam, hair water, hair wax, etc. By using the amount in accordance with the conventional method, split ends and broken hair of the hair are prevented, and the feel of the hair is improved.

[0087]

EXAMPLES The present invention will be specifically described below with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. The numerical value in each example is mass% unless otherwise specified.

[Preparation Example 1] Preparation of crude rosmarinic acid crude product A crude rosmarinic acid crude product was prepared from mannen wax by the following method. 1 per 100g dried leaves of mannen wax on filter paper
It was degreased by passing 00 mL of n-hexane and air-dried. Furthermore, 10 times the amount of 80 mass% ethanol was added to the dried leaves, and the mixture was stirred at 60 ° C. for 2 hours to obtain a crude extraction solution. After the ethanol content in the crude extraction solution was distilled off under reduced pressure, equal amounts of water and hexane were added, and the mixture was partitioned with a separating funnel to separate an aqueous phase fraction. Further, this fraction was desolvated with a rotary evaporator to obtain 8 g of a crude rosmarinic acid crude product.

[Preparation Example 2] Preparation of semi-purified product of rosmarinic acid The crude purified product of rosmarinic acid of Preparation Example 1 was dissolved in an appropriate amount of solvent and loaded onto a silicic acid column, and fractionated with chloroform: methanol = 10: 1. Was carried out and the highly polar fraction was collected. This fraction was desolvated with a rotary evaporator to 0.5.
g of rosmarinin semi-purified product was obtained.

Preparation Example 3 Preparation of Clay Mineral-Supporting Fragrance Composition Supported fragrance compositions 13 to 19 were prepared in the amounts shown in Table 1 below. The preparation method is to prepare the perfume ingredients in a 300 ml beaker at room temperature (about 25 ° C), and use the three-one motor (HED
(Manufactured by ION), the swelling clay mineral was gradually added at 10 g / min while stirring at 200 rpm. After the addition was completed, the mixture was stirred for 10 minutes to obtain a predetermined supported flavor.
The supported flavor thus obtained is blended so as to be uniformly dispersed in the composition of each example. The fragrances 13 to 17 will be described later.

[0091]

[Table 1]

[Example 1, Comparative Example 1] Fragrance development of composition Composition of fragrance 1 having the composition shown in Table 2 was prepared, and a composition having the composition shown in Table 3 was prepared. The mixture was placed in a cup and left at room temperature for one day with the lid on. The fragrance after that was evaluated by 5 panelists according to the following criteria, and the average points are shown in Table 3. As a result, the composition of the present invention exhibited a good scenting as compared with the control. Aroma sensory test Evaluation criteria 5: Very good 4: Fairly good 3: Normal 2: Fairly bad 1: Very bad

[0093]

[Table 2]

[0094]

[Table 3]

[Examples 2 and 3 and Comparative Example 2] Evaluation of flavor stability A fruit mix flavor having the following formulation was prepared and a juice having the composition shown in Table 4 was prepared. The flavor when stored for a month was judged by 5 panelists based on the following criteria and shown as an average point. The results are also shown in Table 4. Example 2 showed a good flavor stabilizing effect, and Example 3 showed an even better effect. Flavor stability evaluation standard 5: Almost no change is observed. 4: Slight change is observed 3: Change is observed 2: Significant change is observed 1: Significant change is observed Fruit mix flavor Burberry Strawberry flavor 40.0% Apple flavor 15.0% Melon flavor 17.0% Banana Flavor 10.0% Peach Flavor 5.0% Orange Oil 2.5% Raspberry Flavor 2.0% Pineapple Flavor 1.5% Grape Flavor 1.0% Tropical Fruit Flavor 1.5% Milk Flavor 1.0% Grapefruit Oil 0.5% Lemon oil 0.5% Rose oil 0.2% Solvent balance 100.0%

[0096]

[Table 4]

[Examples 4 to 7 and Comparative Examples 3 to 6] Aroma persistence test The rinse compositions shown in Tables 5 and 6 below were prepared to prepare composition 1
Apply g to a human hair bundle (length about 30 cm, weight about 10 g), apply it well with a comb, rinse in running water for 30 seconds, and then
It was air dried at 5 ° C. and 40% RH. The fragrance immediately after rinsing and the fragrance persistence after 8 hours were evaluated by the following criteria by 5 expert panels and shown as an average point. The evaluation result
It is also shown in Tables 5 and 6. In addition, in the example using the carrier fragrance, the fragrance was blended in the same amount (0.5%). Aroma stability evaluation standard 5: Strong scenting 4: Slight scenting 3: Normal scenting 2: Slightly scenting 1: Weak scenting

[0098]

[Table 5]

[0099]

[Table 6]

In Examples 4 and 5 containing rosmarinic acid,
As compared with Comparative Examples 3 and 4, a good scenting and flavor persistence were exhibited. In the case of using the supported flavor, a better scent and a long-lasting flavor were exhibited.

[Examples 8 to 11, Comparative Examples 7 to 10] Table 7
The composition having the composition shown in 1 above was prepared, and the split ends generation rate and the feel of the hair were evaluated by the following methods using the permed and bleached hair. The results are also shown in Table 7. Evaluation method (1) Branch hair occurrence rate Branches generated when each agent was applied to a hair bundle obtained by bundling 200 hairs damaged by perming and bleaching, dried, and brushed 5000 times immediately after drying and 1 week later. The number of hairs was counted, the split ends development index was calculated, and evaluation was performed based on the following evaluation criteria. The composition of the fragrance A in the table is shown in Table 8. Split hair occurrence rate (%) = (number of split ends / 200) × 100 Split ends occurrence index = (Split ends incidence after use / Split ends incidence before use) × 100 ◎: Split ends occurrence index is less than 40 ◯: Split hair generation index is 40 to 70 Δ: Split hair generation index is 71 to 90 ×: Split hair generation index is 91 or more (2) There are 20 panelists whose hair is damaged by touching hair color or perm. Using each agent, the feel of hair after use was compared with that before use, and evaluated based on the following evaluation criteria. ◎: 18 or more out of 20 respondents answered better after use ○: 12 out of 20 respondents answered better after use
17 people △: 4-1 out of 20 people answered that it was better after use
1 person x: Less than 4 out of 20 people answered that it was better after use

[0102]

[Table 7]

The composition of the fragrance composition A used in the above example is as follows.

[0104]

[Table 8]

[0105]

[Table 9]

[0106]

[Table 10]

[0107]

[Table 11]

[0108]

[Table 12]

[0109]

[Table 13]

[0110]

[Table 14]

[0111]

[Table 15]

[0112]

[Table 16]

[0113]

[Table 17]

[0114]

[Table 18]

[0115]

[Table 19]

[0116]

[Table 20]

[0117]

[Table 21]

[0118]

[Table 22]

Example 12 Liquid Toothpaste Precipitable Silica 20.0% Glycerin 25.0% Solbit 35.0% Xanthan Gum 0.20% Propylene Glycol 2.0% Sodium Lauryl Sulfate 1.5% Decaglyceryl Monolaurate 2 0.0% Fragrance 2 1.0% Sodium saccharin 0.1% Sodium fluoride 0.21% Mannose wax-derived crude rosmarinic acid (Preparation Example 1) 0.50% Dye, pH adjuster, Proper amount of purified water, balance 100.0%

[Example 13] Toothpaste Calcium carbonate 50.0% Glycerin 20.0% Carrageenan 0.50% Carboxymethyl cellulose 1.00% Lauryl diethanolamide 1.00% Sucrose monolaurate 2.00% Fragrance 3 0.50% Saccharin sodium 0.10% Mannose wax-derived crude purified rosmarinic acid (Preparation example 1) 0.50% Citric acid 0.50% pH adjuster Purified water Remainder total 100.0%

Example 14 Toothpaste Dicalcium Phosphate Dihydrate 50.0% Glycerin 20.0% Carboxymethyl Cellulose 2.0% Sodium Lauryl Sulfate 2.0% Perfume 1 1.0% Sodium Saccharin 0.1 % Sodium monofluorophosphate 0.7% Semi-refined rosmarinic acid derived from mannose wax (Preparation example 2) 0.1% pH adjuster Purified water Remainder 100.0%

Example 15 Toothpaste Aluminum Hydroxide 45.0% Sorbit 25.0% Gelling Silica 2.00% Carboxymethyl Cellulose 1.00% Sodium Lauryl Sulfate 2.00% Perfume 4 0.50% Palatinose 0.25% Sodium monofluorophosphate 0.70% Mannenose-derived semi-purified rosmarinic acid (Preparation Example 2) 0.10% Citric acid 0.05% pH adjuster Purified water Residual total 100.0%

[Example 16] Toothpaste Precipitable silica 25.0% Glycerin 25.0% Sorbit 25.0% Lauroyl polyglycerin ester 0.20% Polyoxyethylene sorbitan monolaurate 2.00% Sodium lauryl sulfate 1 .50% xylitol 8.00% fragrance 5 1.00% sodium saccharin 0.10% hinokitiol 0.20% sodium fluoride 0.21% mannem wax derived crude rosmarinic acid (Preparation Example 1) 0.50% arginine hydrochloride 1. 50% pH adjuster Suitable amount Purified water Balance 100.0%

[Example 17] Toothpaste Precipitable silica 25.0% Glycerin 25.0% Solbit 25.0% Lauroyl polyglycerin ester 0.20% Polyoxyethylene sorbitan monolaurate 2.00% Sodium lauryl sulfate 1 50% Xylitol 8.00% Tetrasodium pyrophosphate 3.00% Sodium tripolyphosphate 2.00% Fragrance 6 1.00% Sodium saccharin 0.10% Hinokitiol 0.20% Sodium fluoride 0.21% Mannenwax-derived crude purification Rosmarinic acid (Preparation Example 1) 0.50% Citric acid 0.50% pH adjuster Purified water Remainder 100.0%

Example 18 Liquid Toothpaste Precipitable Silica 20.0% Glycerin 25.0% Solbit 35.0% Xanthan Gum 0.20% Propylene Glycol 2.00% Sodium Lauryl Sulfate 1.50% Decaglyceryl Monolaurate 2 0.000 Fragrance 7 0.50% Saccharin sodium 0.10% Sodium fluoride 0.21% Mannen wax-derived semi-purified rosmarinic acid (Preparation Example 2) 0.10% Citric acid 0.50% pH adjuster Purified water Remainder total 100.0%

[Example 19] Oral ointment Liquid paraffin 15.0% Cetanol 10.0% Glycerin 20.0% Polyoxyethylene sorbitan fatty acid ester 5.00% Perfume 1 0.50% Saccharin sodium 0.02% Mannen wax derived Semi-purified rosmarinic acid (Preparation example 2) 0.10% Arginine hydrochloride 1.50% Purified water Residual total 100.0%

Example 20 Mouthwash Liquid Ethanol 20.0% Polyoxyethylene hydrogenated castor oil 0.30% Fragrance 2 Appropriate amount sodium saccharin 0.05% Sodium fluoride 0.021% Semi-purified rosmarinic acid derived from mannen wax (preparation example) 2) 0.10% dye, proper amount of pH adjuster, proper amount of purified water, balance 100.0%

Example 21 Mouthwash Tablet Sodium Bicarbonate 50.5% Citric Acid 15.0% Anhydrous Sodium Sulfate 12.0% Dibasic Sodium Phosphate 10.0% Polyethylene Glycol 3.00% Oleic Acid 10% Fragrance 4 0.50% Sodium monofluorophosphate 0.10% Mannenose-derived semi-refined rosmarinic acid (Preparation Example 2) 0.10% pH adjuster Purified water Remainder 100.0%

[Example 22] troche glucose 35.0% palatinose 35.0% gum arabic 6.0% fragrance 7 1.0% mannose wax-derived crude rosmarinic acid (Preparation Example 1) 0.1% purified water balance total 100.0%

[Example 23] Chewing gum Sugar 45.0% Gum base 20.0% Glucose 10.0% Syrup 16.0% Fragrance 6 0.5% Mannose wax-derived crude rosmarinic acid (Preparation Example 1) 0.1% Citric acid 0.1% pH adjuster Appropriate amount Purified water Residual total 100.0%

The compositions of the fragrance compositions 2 to 7 used in the above examples are as follows.

[0132]

[Table 23]

[Examples 24-26] Cream A cream having the following formulation was prepared according to a conventional method.

[0134]

[Table 24]

[Examples 27 to 30] Emulsion An emulsion having the following formulation was prepared according to a conventional method.

[0136]

[Table 25]

[0137]

[Table 26]

[0138]

[Table 27]

[Examples 31 to 33] Lotion A lotion having the following formulation was prepared according to a conventional method.

[0140]

[Table 28]

[Examples 34, 35] Body lotion A body lotion having the following formulation was prepared according to a conventional method.

[0142]

[Table 29]

[Examples 36 and 37] Gel A gel having the following formulation was prepared according to a conventional method.

[0144]

[Table 30]

[Example 38] Packing agent A pack formulation having the following formulation was prepared according to a conventional method.

[0146]

[Table 31]

[Examples 39 and 40] Spray type antiperspirants having the following formulations were prepared according to a conventional method.

[0148]

[Table 32]

[Examples 41 and 42] Roll-on type antiperspirant A roll-on type antiperspirant having the following formulation was prepared according to a conventional method.

[Table 33]

[Example 43] Juice Fructose Glucose syrup 16.0% 1/5 Concentrated orange juice 2.5% Citric acid 0.2% Mannose wax-derived crude rosmarinic acid (Preparation Example 1) 0.5% Ascorbic acid 0.1% Orange flavor 0.1% Palm oil carotene (Lion Oleochemical Co., Ltd.) 0.1% Water balance 100.0%

The fragrance compositions 8 to 12 used in the above examples
The composition of is as follows.

[0152]

[Table 34]

[0153]

[Table 35]

[0154]

[Table 36]

[0155]

[Table 37]

[0156]

[Table 38]

[0157]

[Table 39]

[0158]

[Table 40]

[0159]

[Table 41]

[0160]

[Table 42]

[0161]

[Table 43]

[0162]

[Table 44]

[0163]

[Table 45]

[0164]

[Table 46]

[0165]

[Table 47]

[0166]

[Table 48]

[0167]

[Table 49]

[0168]

[Table 50]

[0169]

[Table 51]

[0170]

[Table 52]

[0171]

[Table 53]

[0172]

[Table 54]

[0173]

[Table 55]

[0174]

[Table 56]

[Example 44] Hair gel The following hair gel was prepared according to a conventional method. Rosmarinic acid (Funakoshi Co., Ltd.) 0.5% Hexaglyceryl monoisostearate 5.0% Hydroxyethyl cellulose (* 1) 0.5% Quinceseed gum 0.3% Methylsiloxane-polyoxyethylene copolymer (* 2) 2.0% N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer (* 3) 2.0% polyoxyethylene hydrogenated castor oil (E O.40) 0.3% Dihydroxybenzophenone 0.1% Methylparaben 0.1% Triethanolamine 0.5% Perfume A 0.2% Ethanol 5.0% Purified water Residual total 100.0% * 1: SE -900 (manufactured by Daicel Chemical Co., Ltd.) * 2: KF-6004 (manufactured by Shin-Etsu Chemical Co., Ltd.) * 3: Yukaformer 510 Manufactured by Mitsubishi Chemical Corporation)

Example 45 Hair Wax The hair waxes shown below were prepared by a conventional method. Mannen wax-derived crude rosmarinic acid (Preparation Example 1) 1.0% Gallic acid-3,5-diglucoside 0.3% Decaglyceryl diisostearate 5.0% Carboxyvinyl polymer (* 1) 0.5% Xanthan gum 0.3 % Methylsiloxane-polyoxyethylene copolymer 2.0% Vaseline 3.0% Squalane 2.0% Candelilla wax 1.0% Polyoxyethylene octyldodecyl ether (EO25) 0.3% Polyoxy Propylene diglyceryl ether (P.O.9) 4.0% Dihydroxybenzophenone 0.1% Propylparaben 0.1% Methylparaben 0.3% Phenoxyethanol 0.5% Tetrasodium edetate 0.05% Triethanolamine 0. 5% fragrance A 0.2% purified water balance total 100.0% * 1 Carbopol 940 (manufactured by Goodrich)

Example 46 Hair Cream A hair cream having the following formulation was prepared according to a conventional method. Mannen wax-derived semi-refined rosmarinic acid (Preparation example 2) 0.3% Hydrolyzed silk liquid (* 1) 0.2% Hexaglyceryl tristearate 3.0% Alkyl-modified carboxyvinyl polymer (* 2) 0.4% Karaya gum 0.1% Methyl siloxane-polyoxyethylene copolymer 0.5% Methyl polysiloxane (100,000 mm ² / s) 5.0% Liquid paraffin 5.0% Paraffin wax (melting point 70 ° C) 3.0% Poly Oxyethylene hydrogenated castor oil (EO40) 2.0% 3-Methyl-1,3-butanediol 10.0% Dihydroxybenzophenone 0.1% Propylparaben 0.1% Methylparaben 0.3% Phenoxyethanol 0. 5% Coconut oil fatty acid sorbitan 2.0% Glycerin monostearate 1.0% Monostearic acid Propylene glycol 2.0% Triethanolamine 0.5% Perfume B 0.2% Purified water Remainder 100.0% * 1: Promote SILK700 SIG (manufactured by Seiwa Kasei) * 2: Carbopol 1342 (manufactured by Goodrich) )

Example 47 Hair Foam A hair foam having the following formulation was prepared according to a conventional method. Mannen wax-derived crude rosmarinic acid (Preparation Example 1) 2.0% N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer (* 1) 1.0 % Amino-modified silicone (* 2) 0.5% 3-Methyl-1,3-butanediol 2.0% Squalane 0.1% Stearyltrimethylammonium chloride 0.5% Methylparaben 0.3% Triethanolamine 0.1 % Fragrance A 0.1% Ethanol 20.0% Liquefied petroleum gas 7.0% Purified water Remainder total 100.0% * 1: Yucaformer 204WL (manufactured by Mitsubishi Chemical Corporation) * 2: SM8704C (manufactured by Toray Dow Corning Silicone)

[Example 48] Hair foam A hair foam shown below was prepared according to a conventional method. Rosmarinic acid (Funakoshi Co., Ltd.) 1.0% Methylpolysiloxane (30 mm ² / s) 5.0% Polyether-modified silicone (* 1) 0.5% 3-Methyl-1,3-butanediol 2. 0% Cationized cellulose 0.1% N-coconut oil fatty acid-L-glutamic acid 0.5% Polyoxyethylene hydrogenated castor oil (EO40) 0.4% Methylparaben 0.3% Citric acid 0.1% Fragrance A 0.1% ethanol 20.0% liquefied petroleum gas 7.0% purified water balance 100.0% * 1: SH200C-30cs (Toray Dow Corning Silicone)

[Example 49] Hair spray The hair spray shown below was prepared according to a conventional method. Semi-purified rosmarinic acid derived from mannose wax (Preparation example 2) 0.5% Vinylpyrrolidone (K30) 2.0% Polyglycerin fatty acid ester 3.0% Polyoxyethylene-modified silicone (* 1) 0.5% Polyoxyethylene hydrogenated castor oil (EO40) 0.5% Methylparaben 0.3% Fragrance B 0.1%The rest of ethanol 100.0% in total 50% of the above stock solution Liquefied petroleum gas 30%Dimethyl ether 20% 100.0% in total * 1: KF6011 (Shin-Etsu Silicone Co., Ltd.)

Example 50 Hair Water The following hair water was prepared according to a conventional method. Mannen wax-derived crude rosmarinic acid (Preparation Example 1) 1.0% Gluconic acid 1.0% Polyether-modified silicone (* 1) 0.5% 3-Methyl-1,3-butanediol 2.0% Stearyl trimethyl chloride Ammonium 0.5% Methyl polysiloxane 3.0% Polyoxyethylene lauryl ether 0.4% Lauryl dimethylamine oxide 0.2% Sodium pyrrolidonecarboxylate 1.0% Methylparaben 0.3% Sodium citrate 0.1% Hydroxy Methoxybenzophenone sulfonic acid 0.1% Perfume A 0.1% Ethanol 20.0% Purified water Balance 100.0% * 1: KF6012 (Shin-Etsu Chemical Co., Ltd.)

The fragrance compositions A and B used in the above examples
Is the composition shown above.

In Examples 44 to 50, the split ends generation rate and touch of hair were evaluated in the same manner as in Examples 8 to 11. As a result, the split ends generation rate was lowered and the touch of hair was improved. It was something.

[Examples 51 and 52] Shampoo Shampoos having the formulations shown below were prepared according to a conventional method.
The pH of shampoo is in the range of 3-7.5.

[0185]

[Table 57]

[0186]

[Table 58]

[0187]

[Table 59]

[Examples 53 to 55] Detergent The detergent having the following formulation was prepared according to a conventional method.

[0189]

[Table 60]

[Example 56] Cleaning pretreatment agent for clothes A washing pretreatment agent for clothes having the following formulation was prepared according to a conventional method. Sodium alkyl sulfate (C12-C14) 20% Soap 5% Sodium citrate 1% Tripolyphosphoric acid 1% Diethanolamine 2% Trialkylene glycol monobutyl ether 1% Rosmarinic acid (Funakoshi Co., Ltd.) 0.2% Perfume 14 0.2 % Purified water balance 100%

Incidentally, the fragrance compositions 13 and 1 used in the above examples
The composition of 4 is as follows.

[0192]

[Table 61]

[0193]

[Table 62]

[0194]

[Table 63]

[0195]

[Table 64]

[0196]

[Table 65]

[0197]

[Table 66]

[0198]

[Table 67]

[0199]

[Table 68]

[0200]

[Table 69]

[0201]

[Table 70]

[0202]

[Table 71]

[0203]

[Table 72]

[Examples 57-60] Rinse A rinse having the following formulation was prepared according to a conventional method.

[0205]

[Table 73]

[Examples 61 and 62] Softener A softener having the following formulation was prepared according to a conventional method.

[Table 74]

Incidentally, the fragrance compositions 15 and 1 used in the above examples
The composition of 6 is as follows.

[0208]

[Table 75]

[0209]

[Table 76]

[0210]

[Table 77]

[0211]

[Table 78]

[0212]

[Table 79]

[0213]

[Table 80]

[0214]

[Table 81]

[0215]

[Table 82]

[0216]

[Table 83]

[0217]

[Table 84]

[0218]

[Table 85]

[0219]

[Table 86]

[0220]

[Table 87]

[0221]

[Table 88]

[0222]

[Table 89]

[0223]

[Table 90]

[Example 63] Hair restorer A hair-growth agent having the following formulation was prepared according to a conventional method.

[0225]

[Table 91]

[Example 64] Bath salt A bath salt having the following formulation was prepared according to a conventional method.

[0227]

[Table 92]

[Example 65] Bath salt A bath salt having the following formulation was prepared according to a conventional method.

[0229]

[Table 93]

[Examples 66 and 67] Dishwashing agents A dishwashing agent having the following formulation was prepared according to a conventional method.

[0231]

[Table 94]

[Examples 68 and 69] Kitchen detergent A kitchen detergent having the following formulation was prepared according to a conventional method.

[0233]

[Table 95]

The composition of the fragrance composition 17 used in the above example is as follows.

[0235]

[Table 96]

[0236]

[Table 97]

[0237]

[Table 98]

[0238]

[Table 99]

[0239]

[Table 100]

[0240]

[Table 101]

[0241]

[Table 102]

[0242]

[Table 103]

[0243]

[Table 104]

[0244]

[Table 105]

[0245]

[Table 106]

[0246]

[Table 107]

[0247]

[Table 108]

[0248]

[Table 109]

[Examples 70 and 71] Bleach A bleaching agent having the following formulation was prepared according to a conventional method.

[0250]

[Table 110]

The composition of the fragrance composition 18 used in the above example is as follows.

[0252]

[Table 111]

[0253]

[Table 112]

[0254]

[Table 113]

[0255]

[Table 114]

[0256]

[Table 115]

[0257]

[Table 116]

[0258]

[Table 117]

[Examples 72, 73] Bleach A bleaching agent having the following formulation was prepared according to a conventional method.

[0260]

[Table 118]

The composition of the fragrance composition 19 used in the above example is as follows.

[0262]

[Table 119]

[0263]

[Table 120]

[0264]

[Table 121]

[0265]

[Table 122]

[0266]

[Table 123]

[0267]

[Table 124]

[0268]

[Table 125]

Example 74 Mouthwash A mouthwash having the following formulation was prepared according to a conventional method. Denatured ethanol 1.6% Polyoxyethylene hydrogenated castor oil 2.0% Citric acid 0.01% Trisodium citrate 0.3% Perfume 2 0.5% Ginseng wax-derived crude rosmarinic acid (Preparation Example 1) 0.5 % Hyaluronic acid 0.1% Laurolyl sarcosine sodium 0.1% Sodium fluoride 0.08% Glycerin 10.0% DL-Alanine 1.0% Purified water Residual total 100.0%

[Examples 75 and 76] Detergent for bathroom A bathroom detergent having the following formulation was prepared according to a conventional method.

[0271]

[Table 126]

[Examples 77, 78] Toilet detergent A toilet detergent having the following formulation was prepared according to a conventional method.

[0273]

[Table 127]

[Examples 79, 80] Body soap A body soap having the following formulation was prepared according to a conventional method.

[0275]

[Table 128]

[Examples 81, 82, 83] Bactericidal soap A sterilizing soap having the following formulation was prepared according to a conventional method.

[0277]

[Table 129]

[Examples 84, 85] Medicinal hand soap A medicated hand soap having the following formulation was prepared according to a conventional method.

[0279]

[Table 130]

[Examples 86 and 87] Gel-like cleansing agent A gel-like cleansing agent having the following formulation was prepared according to a conventional method.

[0281]

[Table 131]

[Examples 88, 89] Cream-type face wash A cream-type face wash having the following formulation was prepared according to a conventional method.

[0283]

[Table 132]

[0284]

According to the present invention, the stability of the scent is good,
Further, a composition excellent in improving the quality of hair or fiber products can be obtained and can be used for treating hair or fiber products.

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) A61K 7/075 A61K 7/075 4L031 7/08 7/08 4L033 7/16 7/16 7/32 7 / 32 7/50 7/50 C11B 9/00 C11B 9/00 A B C G H J L Q R S V X D06M 11/77 D06M 13/00 13/00 A23G 3/00 // A23G 3/00 3 / 30 3/30 A23L 2/02 B A23L 2/00 2/00 B 2/02 D06M 11/12 (72) Inventor Hiroshi Matsukawa 1-3-7 Honjo, Sumida-ku, Tokyo F-term within Lion Corporation (reference) 4B014 GB08 GB13 GK12 GL04 4B017 LC02 LK08 LL09 4B047 LB09 LG01 LG05 LG06 LG08 LG09 LG12 LG13 LG14 LG37 4C083 AA112 AA122 AB102 AB172 AB222 AB242 AB292 AB322 AB352 AB441 AB442 AC022 AC072 AC102 AC122 AC132 AC182 AC252 AC301 AC302 AC342 AC422 AC432 AC442 AC471 AC4 72 AC482 AC532 AC542 AC562 AC582 AC612 AC642 AC662 AC692 AC712 AC782 AC792 AC812 AC852 AC862 AD042 AD092 AD112 AD132 AD152 AD162 AD222 AD272 AD352 AD472 AD532 AD552 AD662 BB41 CC01 CC04 CC05 CC07 CC17 CC32 CC33 CC37 CC38 CC41 EE01 EE29 4H029 BA22 BA12 BA12 BA12 BA12 BA12 BA12 BA12 BA12 BA12 BA12 BA36 BA37 BA41 BA61 BC01 DA09 EA40 4L031 AA01 AA11 AB01 AB21 AB31 BA24 BA33 DA13 4L033 AA01 AA04 AB01 AB03 AB04 AC10 AC15 BA00 BA16

Claims (6)

[Claims] 1. Rosmarinic acid and hydrocarbon type, alcohol type, phenol type, phenol ether type, aldehyde type, acetal type, ketal type, ketone type, ether type, acid type, lactone type, ester type, nitrogen-containing type A rosmarinic acid-containing composition, characterized in that one or more kinds of fragrances selected from sulfur-containing, natural and blended systems are blended. 2. The composition according to claim 1, wherein the perfume is supported between layers of a swelling clay mineral. 3. The composition according to claim 1, further comprising a chelating agent. 4. A treatment for hair or a textile product.
4. The composition according to any one of 3 to 3. 5. A rosmarinic acid-containing composition for treating hair or textiles, which comprises rosmarinic acid and a cationic surfactant. 6. The composition according to claim 5, which contains a hydroxycarboxylic acid selected from gallic acid and its glycosides, and gluconic acid and its derivatives.