JP4243867B2 - Rosmarinic acid-containing composition - Google Patents

Description

  The present invention relates to a rosmarinic acid-containing composition that is excellent in stability of fragrance and quality of hair or textile products, and is particularly suitable for treating hair or textile products.

  The fragrance ingredient has an effect of improving the degree of preference of various compositions, an unpleasant taste, an effect of correcting flavor, or an effect of reducing the mental burden of the user, etc., in order to improve the added value of the composition It is used in various compositions such as foods, pharmaceuticals, and cosmetics.

  However, in general, a fragrance component has high volatility, degradability, and alteration, and it is difficult to maintain a stable flavor for a long period of time in the composition.

  In addition, tissues such as skin, hair, oral cavity, respiratory organs, etc. that are generally in contact with the outside world are subject to physical factors such as blow, friction, heating, air pollutants such as dioxins, sulfur oxides, nitrogen oxides, drinking, It is always at risk of damage due to chemical components caused by behavior such as smoking and medication, or external stimuli such as sunlight and ultraviolet rays.

  In particular, the hair is damaged a lot by external factors such as daily hair washing, hair makeup and ultraviolet rays. Recently, damage due to hair coloring, bleaching, etc. has also increased.

As a conventional technique, a hair cosmetic composition containing a plant polar solvent extract and keratin or a keratin-degrading derivative imparts hair style retention and good feel (Patent Document 1: Japanese Patent Laid-Open No. S59-59). 157010 publication), α-hydroxycarboxylic acid, inorganic salts and organic salts thereof, citric acid, lactic acid, glycolic acid, tartaric acid, inorganic salts and organic salts thereof, lactose, glycolic acid, inorganic salts and organic salts thereof. Hair cosmetics combining a salt, lactic acid with a high L-lactic acid ratio, inorganic salts and organic salts thereof, or hair cosmetics further combining UV cosmetics or non-volatile silicones with these cosmetics prevent hair damage deterioration. Swelling composition (see Patent Document 2: Japanese Patent Application Laid-Open No. 11-5719), shampoo composition containing plant extract and water-soluble chain polymer compound A hair setting agent that has a function of imparting suppleness and smoothness to the shampooed hair (Patent Document 3: Japanese Patent Application Laid-Open No. 59-187097), a plant extract, a polymer compound for fixing hair, and lecithin The composition has an effect of imparting curl retention of hair and a good feel after setting (see Patent Document 4: JP-A-59-19681), polar solvent extract of perch and / or rosemary, and A hair cosmetic containing collagen has an effect of imparting hair style formation retention effect, moderate touch and good combing property (see Patent Document 5: JP-A-59-155307), plant extract And hair cosmetics containing non-volatile silicones have the effect of preventing hair damage (Patent Document 6: Japanese Patent Laid-Open No. 8-231348) (See news). In addition, in order to prevent hair splits and breaks, oil and silicones are blended to smooth the hair surface and suppress friction caused by brushing or the like (Patent Document 7: JP-A-4-230615, Patent Document 8: Japanese Patent Application Laid-Open No. 5-70328) Technology, blending glycol (Patent Document 9: Japanese Patent Application Laid-Open No. 7-118127), hydrolyzed keratin (Patent Document 10: Japanese Patent Application Laid-Open No. 8-157342) And a technique of blending an amino acid (see Patent Document 11: Japanese Patent Laid-Open No. 59-181206) has been proposed. However, these hair cosmetics are not sufficient in the effect of preventing split ends, and the effect of improving the touch of damaged hair by repairing the hair surface is insufficient.
Furthermore, the hair treatment agent containing Spanish rosmarin oil has an effect of preventing hair loss (see Patent Document 12: Japanese Patent Laid-Open No. 60-500619), and the composition containing the essence of Lamiaceae plants is normal in dermal collagen bundles. It has been known that it has an effect of oxidization (see Patent Document 13: JP-A-10-330221). However, none of the effects was sufficient.

JP 59-157010 A Japanese Patent Laid-Open No. 11-5719 JP 59-187097 A JP 59-1996811 A JP 59-155307 A JP-A-8-231348 JP-A-4-230615 Japanese Patent Laid-Open No. 5-70328 Japanese Patent Laid-Open No. 7-118127 JP-A-8-157342 JP 59-181206 A JP-A-60-500619 Japanese Patent Laid-Open No. 10-330221 JP-A-6-145034 JP 63-162611 A Japanese Patent Laid-Open No. 7-18789 Japanese Patent Laid-Open No. 10-101572 JP 2000-239136 A JP 2000-86510 A

  The present invention has been made in view of the above circumstances, and includes a rosmarinic acid-containing composition having a fragrant flavor, stability and sustainability, as well as daily ultraviolet rays and the heat of an iron / dryer, especially bleaching agents and hair colors.・ Prevents damage to fibers containing keratin that has undergone chemical treatment such as hair bleaching and perm, especially splitting and cutting of hair, and improves hair feel by repairing the hair surface, especially hair or A rosmarinic acid-containing composition suitable for treating textile products is provided.

  As a result of intensive studies to solve the above-mentioned problems, the present invention provides a composition having good fragrance stability by using rosmarinic acid and a specific fragrance, and also contains rosmarinic acid and a cationic surfactant. By doing so, it was found that the hair or the textile product was prevented from being damaged (split hairs or broken hairs), and the surface of the hair or the textile product was repaired to significantly improve the touch, and the present invention was made.

That is, the present invention provides the following rosmarinic acid-containing composition.
[1]. A rosmarinic acid-containing composition for hair treatment, comprising rosmarinic acid, a cationic surfactant, and a gallic acid glycosylated product, and treated with hair color, hair bleach or perm.
[2]. The content of rosmarinic acid is 0.01 to 20% by mass, the content of the cationic surfactant is 0.01 to 5% by mass, and the content of the gallic acid glycoside is 0.01 to 10% by mass. The rosmarinic acid-containing composition according to claim 1.

  ADVANTAGE OF THE INVENTION According to this invention, the composition excellent in the quality improvement of hair or textiles is obtained, and it can utilize for hair or textiles processing.

Here, the following is known as a technique using rosmarinic acid.
For example, cosmetics containing rosmarinic acid and / or lysine and / or arginine exhibit an ultraviolet protection effect (see Patent Document 14: JP-A-6-145034), and contain rosmarinic acid and / or a water-soluble polymer substance. The cosmetic exhibits a skin beautifying effect (see Patent Document 15: Japanese Patent Laid-Open No. 63-162611), and the cosmetic containing a Lamiaceae plant extract containing rosmarinic acid has a whitening effect (Patent Document 16: Special) No. 7-187989), a medicinal plant composition containing a mixed solution of clematisradix containing rosmarinic acid, tricho santes root and Brunella herba has analgesic effect, chronic rheumatoid arthritis therapeutic effect, peripheral blood circulation improving effect Having (see Patent Document 17: JP-A-10-101572), rosmarinic acid or ross An oral composition containing a phosphoric acid derivative has an antibacterial effect (see Patent Document 18: JP 2000-239136 A), and a composition containing apigenin, chrysoeriol, luteolin and rosmarinic acid has an inhibitory action on histamine release. It is known (see Patent Document 19: Japanese Patent Laid-Open No. 2000-86510). However, by combining rosmarinic acid and a fragrance, it should have excellent scent stability, and by using rosmarinic acid and a cationic surfactant in combination, the touch of hair or textile products should be significantly improved. Is not known about.

  Hereinafter, the present invention will be described in detail. The rosmarinic acid used in the composition of the present invention is a substance represented by the following formula.

  Rosmarinic acid is contained in a plant group represented by rosmarinus officinalis L., which is an evergreen small shrub of the family Lamiaceae. Mannen wax is used as an edible herb and has other pharmacological effects such as analgesic effect, antitussive effect, diuretic effect, etc., but the relationship between its medicinal properties and individual medicinal properties has not been completely clarified.

  The rosmarinic acid of the present invention can be used from any source. For example, in addition to Mannenro (Rosmarinus officinalis L.) which is an evergreen small shrub of the family Lamiaceae, plants of Lamiaceae, Murasaceae, Oleanderaceae, Apiaceae, Gentianaceae, specifically, sage, ajizo, chimmentoso, thyme, enema, etc. Can be extracted from plants. It can also be prepared by chemical organic synthesis. In the present invention, a pure compound of rosmarinic acid can be used, but it is not limited to this, and it is semi-purified as long as it does not contain impurities inappropriate for cosmetics, detergents, pharmaceuticals, quasi drugs, and foods. Alternatively, crude rosmarinic acid can also be used.

  When extracting rosmarinic acid from a plant, the plant can be a native or cultivated plant, but is not limited thereto, and is a recombinant plant obtained by genetic recombination, a cultured cell such as a callus or a hairy root, a culture Tissues can also be used.

  Moreover, a branch part, a leaf part, a root part, a seed part, a fruit part, a flower part, etc. can be used for an extraction site | part.

  A well-known method can be employ | adopted for the manufacturing method of the rosmarinic acid derived from a plant. For example, mannen wax pulverized to 250 to 500 μm, or those degreased with a low polarity solvent such as hexane using a hydrophilic solvent, specifically ethanol, methanol, hydrous ethanol, acetone or the like, or the Soxhlet method or An extract is obtained by a cooling filtration method or the like. Next, after adding water, the organic solvent is distilled off, and further rosmarinic acid concentrate is obtained using a method such as removal of the precipitate formed by adding water or partitioning with a solvent such as hexane, ethyl acetate, methanol, water, etc. . Then, the concentrated solution can be distilled under reduced pressure, washed with a low-polarity solvent, salt dissociation by adjusting pH, purified by silicic acid column, resin column, high performance liquid chromatography, or the like.

  In the composition of the present invention, the above-mentioned purified, semi-purified or crude rosmarinic acid is blended in an amount of rosmarinic acid of 0.00001 to 50% by mass, preferably 0.0001 to 30% by mass, Preferably 0.001-5 mass% is mix | blended. In particular, in the composition for treating hair or textile products, it is usually 0.01 to 20% by mass, preferably 0.1 to 5% by mass, more preferably 0.1 to 2% by mass with respect to the entire composition. % Is selected. When the blending amount is less than 0.01% by mass, the blending effect may not be sufficiently exhibited. When the blending amount exceeds 20% by mass, the appearance of the composition such as generation of colored substances and precipitates may be lost. is there.

  The 1st composition of this invention uses rosmarinic acid and a specific fragrance | flavor together, By this, fragrance standing and stability can be improved. The following are mentioned as such a fragrance | flavor.

  The perfume used in the composition of the present invention is hydrocarbon, alcohol, phenol and phenol ether, aldehyde, acetal and ketal, ketone, ether, acid, lactone, ester, It is 1 type, or 2 or more types of fragrance | flavors chosen from a nitrogen-containing type | system | group, a sulfur containing type | system | group, a natural type | system | group, and a preparation system.

  A list of perfume ingredients used as perfumes in the present invention can be found in various publications such as “Perfume and Flavor Chemicals”, Vol. Iand II, Steffen Arctander, Allured Pub. Co. (1994) and “Synthetic fragrance chemistry and product knowledge”, Motoichi Into, Chemical Industry Daily (1996) and “Perfume and Flavor Materials of Natural Origin”, Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V3.3", Boelens Aroma Chemical Information Service (1996) and "Flower oil". , Danute Lajaujis Anonis, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference. Although the typical example of a fragrance | flavor is given to the following, it is not limited to these.

  Examples of the hydrocarbon compounds include osymene, dihydromyrcene, farnesene, cedrene, α-pinene, β-pinene, limonene, dipentene, camphene, ferrandrene, terpinene, 3-carene, terpinolene, bisabolen, β-caryophyllene, kazinene, Valensen, Tuopsen, Guayen, Allocymene, Myrcene, Longifolene, Verdracine (1,3,5-undecatriene), p-cymene, 4-isopropyl-1-methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon Terpenes, bergamot terpenes, peppermint terpenes, spearmint terpenes, lime terpenes, vetiver terpenes, rose wax, jasmine wax, limonene dimer, pentane, hexane, heptane Octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, icosane, heikosan, docosan, tricosan, tetracosan, pentacosan, hexacosan, heptacosan, octacosan, nonacosan, triacontane, etc. .

  Examples of alcohol compounds include 3-methyl-1-pentanol, geraniol, cedrol, citronellol, rosinol, nerol, dihydrolinalol, linalool, tetrahydrolinalol, dimethyloctanol, tetrahydromumol, mugol, mircenol, dihydromyrsenol, osimenol , Tetrahydromyrsenol, lavandulol, isodihydrolavandulol, hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), ethyl linalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla alcohol, 4 -Tuanol, 3-tanol, farnesol, nerolidol, α-bisabolol, β-caryophyllene alcohol, santalol, Tiberol, cedrenol, 3-l-menthoxypropane-1,2-diol, patchouli alcohol, dihydrocarbeole, phytol, isophytol, sclareol, carveol, menthol, ethyl alcohol, propyl alcohol, butanol, isoamyl alcohol, 1-heptanol 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-ethylhexanol, 1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-1-hexanol) 1-decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2-buten-1-ol), 2-methyl-3-buten-2-ol, β-pentenol (1 Penten-3-ol), leaf alcohol (cis-3-hexenol), trans-2-hexenol, trans-3-hexenol, cis-4-hexenol, 2,4-hexadien-1-ol, Matsutakeol (1- Octen-3-ol), cis-6-nonenol, cucumbar alcohol (2,6-nonadienol), androl (1-nonen-3-ol), Rosalba (9-decenol), 1-undecenol, undecabel Tolu (4-methyl-3-decen-5-ol), osirole (3,7-dimethyl-7-methoxy-2-octanol), santalinol (2-methyl-4- (2,2,3-trimethyl-) 3-cyclopenten-1-yl) -2-buten-1-ol), p, α-dimethylbenzyl alcohol 2,2,6-trimethylcyclohexyl-3-hexanol, 1,2-pentanediol, benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styryl alcohol (1-phenyl-1-hydroxyethane), hydratropa Alcohol, methyl β-phenylethyl alcohol, α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-naphthol, furfuryl alcohol, 3-methyl-1-phenyl-3-pentanol, amyl cinnamic alcohol, cinnamic alcohol Phenoxanol (3-methyl-5-phenylpentanol), 1,2-pentanediol, 2-ethylhexanol, dimethylol (2,6-dimethylheptanol), 3,6-dimethyl-3-octanol, coffee Nord (3,4,5,6,6-pentamethyl-2-heptanol), Brahamanol (methyltrimethylcyclopentenylbutanol), Bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1) -Yl) -2-buten-1-ol), sandalol (3-methyl-5- (2,2,3-trimethylcyclopent-3-en-yl) -pentan-2-ol), sandalol ( 3-methyl-5- (2,2,3-trimethylcyclopent-3-en-1-yl) pentan-2-ol), cyclohexyl ethyl alcohol, apopathion (p-isopropylcyclohexanol), floralol (2,4 -Dimethyl-3-cyclohexene-1-methanol), pacheon (p-tert-butylcyclohexanol), Rudol (o-tert-butylcyclohexanol), Mayol (p-isopropylcyclohexylmethanol), cyclomethylenecitronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol), methyl sandefurol (5'or6 ' -Methylnorborn-5'-en-2-yl) -2-methylpent-1-en-3-ol), tingerol (2,2,6-trimethylcyclohexyl-3-hexanol), polysanthol (3,3 -Dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), isopulegol, Isocyclogeraniol, myrtenol, nopol ( , 6-dimethylbicyclo [3.1.1] hept-2-ene-2-ethanol), pinocarbeveol, α-fenkyl alcohol, borneol, isoborneol, pachomint (2- (3,3-dimethylbicyclo [ 2.2.1] Hept-2-ylidene) ethanol), kamechol (trimethylnorbornanemethanol), dimethylcyclomol, santarex T (isocamphylcyclohexanol), geranyl linalool, cumin alcohol, 2-methoxyphenylethyl alcohol, Phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenylethyl alcohol, isobutylbenzyl carbinol, p-methylbenzyl carbinol, hydrosynamic alcohol, centifold (1,1 -Dimethyl-3-phenylpropanol-1), muget alcohol (2,2-dimethyl-3-phenylpropanol), phenylhexanol, decahydro β-naphthol, AR-1 (3,6-dimethyloctane-3-ol) , Abitol (hydroabietyl alcohol), α-propylphenylethyl alcohol, p-methyldimethylbenzyl carbinol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), furolol (2-isobutyl-4-hydroxy-4-methyl) Tetrahydropyran), propylene glycol, dipropylene glycol, hexylene glycol and the like.

  Examples of phenolic and phenolic ether compounds include anisole, estragole, chabicol, anethole, cresol, carvacrol, p-cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-naphthol. Isobutyl ether, veratrol (1,2-dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxybenzene, catechol, resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl 3 ( 3-methoxy-5-methylphenol), thymol, methylthymol, propenyl guaetol (trans-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, -Ethylphenol, p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol), hydroquinone dimethyl ether, resorcin dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyl eugenol, methylisoeugenol, ethylisoeugenol , Benzyleugenol, benzylisoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2-hydroxy-4-propenylbenzene), shogaol, gingerol, acetyleugenol, acetylisoeugenol safrole, isosafrole, diphenyl oxide, vetiver ether (Tert-butyl hydroquinone dimethyl ether) and the like.

  Examples of aldehyde compounds include citronellal, citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, myrtenal, caryophyllaldehyde, n-hexanal, 2-methylbutanal, isovaler Aldehyde, n-valeraldehyde, acetaldehyde, n-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal 2-methylundecanal, tridecanal, tetradecanal, 2-pentenal, cis-3-hexenal, trans-2-hexenal, trans-2-heptenal, 4-heptenal, t ans-2-octenal, trans-2-nonenal, cis-6-nonenal, meronal (2,6-dimethyl-5-heptenal), trans-4-decenal, cis-4-decenal, trans-2-decenal, grinal (2,5,6-trimethyl-4-heptenal), 10-undecenal, trans-2-undecenal, trans-2-dodecenal, mandarinaldehyde (3-dodecenal), trans-2-tridecenal, adxal (2,6,6) 10-trimethyl-9-undecene-1-al), 2,4-hexadienal, 2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4 -Decadienal, 2,4-Undecadiena 2,4-dodecadienal, geraldaldehyde (5,9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadien-1-al), oncidar (2,6,6) 10-trimethyl-5,9-undecadienal), Bergamar (α-methylenecitronellal), camphorene aldehyde, cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3- Cyclohexadiene-1-carboxaldehyde), mugealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxyacetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2.2.1] ] -5-heptene-2-carbo Cialdehyde), centenal (methoxydicyclopentadiene carboxaldehyde), dupical (4-tricyclodecylidenebutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3 )-(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), Setneral (trimethylcyclohexenemethylbutanal), Inonal (2-methyl-4- (2,6,6-) Trimethyl-1 (2) -cyclohexenyl) -butenal), telestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde , P Methylphenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmolandi (2-methyl-3 -(4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2-methyl-3- (p-isopropylphenyl) -propionaldehyde), florarozone (p- Ethyl-α, α-dimethylhydrocinnamic aldehyde), suzaral (p-isobutyl-α-methylhydrocinnamic aldehyde), cinnamaldehyde, salicylaldehyde, ani Aldehyde, o-methoxybenzaldehyde, o-methoxycinnamic aldehyde, cantoxal (2-methyl-3- (p-methoxyphenyl) -propanal), vanillin, ethyl vanillin, methyl vanillin (3,4-dimethoxybenzaldehyde), helio Tropine, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde), phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-hydroxymethyl-2-furfural, furylacrolein, rilal (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), Bernaldehyde (1-methyl-4- (4-methylpentyl) -3-silane Chlorhexene carboxaldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexene carboxaldehyde), junipal (4 (5) -formyl-7,7,9-trimethyl) Bicyclo [4.3.0] -nonene), vertoral (octahydro-4,7-methanoindenecarboxaldehyde), lyial (p-tert-butyl-α-methylhydrocinnamic aldehyde), mefranal (3-methyl- 5-phenyl valeraldehyde), eglantal (4-methyl-2-phenyl-2-pentenal), cocarl (5-methyl-2-phenyl-2-hexenal), α-methyl cinnamic aldehyde, α-butyl cinnamic aldehyde , Α-amylcinnamic aldehyde, α -Hexylcinnamic aldehyde, formylethyltetramethyltetralin (6-ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene) and the like.

  Examples of acetal compounds and ketal compounds include magnolan (2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl-5, 5-dimethyl-1,3-dioxane), indofur (dihydroindenyl-2,4-dioxane), boasambrene forte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal, leaf acetal (acetaldehyde ethyl hexenyl acetal), Acetaldehyde ethylhexyl acetal, citronellyl methyl acetal, erintal (acetaldehyde ethyl linalyl acetal), Bonalox (2,4-dioxane-3-methyl-7,10-methanospiro [5.5] unde ), Ephethal (acetaldehyde ethyl phenylacetal), acetaldehyde ethyl isoeugenyl acetal, acetal R (acetaldehyde phenylethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentanediol acetal), spirofurol ( 3-ethyl-2,4-dioxaspiro [5.5] undecene-8-ene), ethyldimethyldioxaspiroundecene, herboxan (2-butyl-4,4,6-trimethyl-1,3-dioxane), Caranal (2- (2,4-dimethylcyclohex-3-en-1-yl) -5-methyl-5 (1-methylpropyl) 1,3-dioxane), hexanal dimethyl acetal, hexanal diethyl acetal, hexanalp Pyrene glycol acetal, carotene (4,7-dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis-3-hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal , Heptanal ethylene glycol acetal, 2-hexyl-5-methyl-1,3-dioxolane, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane, octanal dimethyl acetal, octanal Diethyl acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal, 2-methylundecanal dimethyl acetal, dodecanal dimethyl acetal , Citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxy citronellal dimethyl acetal, hydroxy citronellal diethyl acetal, cis-3-hexenal diethyl acetal, benzaldehyde dimethyl acetal, Benzaldehyde diethyl acetal, benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetaldehyde propylene glycol acetal, phenylacetoaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropaldehyde dimethyl acetal, hydratropa Aldehyde ethylene glycol acetal, osminal DMA (amylcinnamic aldehyde dimethyl acetal), osminal DEA (amylcinnamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5) 5-tetramethyl-4-isopropyl-1,3-dioxane), amber Sage (4,7-dihydro-2-isopentyl-2-methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonane (2-butyl- 4-dioxaspiro [4.4] nonanone), Freyston (ethyl-2,4-dimethyl-1,3-dioxolane-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate) Etc.

Examples of the ketone compounds include acetyl caryophyllene, carvone, pregon, piperithenone, piperiton, menthone, show brain, oxocedrane, isolongifolanone, nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone. 2-octanone, 3-octanone, 2-nonanone, 3-nonanone, 2-undecanone, 2-tridecanone, methyl isopropyl ketone, ethyl isoamyl ketone, mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctene Non, coabon (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranyl acetone, farnesyl acetone, acetoin, butyroin (5-hydroxy-4-octanone), methy Lavender ketone (3-hydroxymethyl-2-nonane), diacetyl, 2,3-pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amyl Cyclopentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2-n-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamon (2-butylidene- 3,5,5 (3,3,5) -trimethylcyclopentanone), sandex (3-methyl-5- (2,2,3-trimethyl-3-cyclopentenyl) -3-penten-2-one ), Cycloten, coronol (3,5-dimethyl-1,2 Cyclopentadione), methylcholylone (3,4-dimethyl 1,2-cyclopentadione), verdon (2-tert-butylcyclohexanone), p-tert-butylcyclohexanone, Hellbach (3,3-dimethylcyclohexylmethyl ketone), Frescomente (2-sec-butylcyclohexanone), artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celly ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl) -2-cyclohexanone), olibon (p-tert-pentylcyclohexanone), methylcyclocitron (2,3,5-trimethyl-4-cyclohexenyl-1-methylketone), neron (1- (p-menten-6-yl) ) -1-propane), Vetival (4-cyclohexyl-4-methyl-2-pentanone), habanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-2-acetonyl-4-methyl-) Tetrahydropyran), emoxifuron (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homofurol (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl -4-hydroxy-2-methyl-3 [2H] -furanone), sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), furaneol (2,5-dimethyl-4-hydroxy-3) [2H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5 Methylfuran, 2-acetylfuran, methyltetrahydrofuranone, dibenzylketone, benzophenone, methylnaphthylketone, 4-damascol (5-phenyl-5-methyl-3-hexanone), ethicon (4-methyl-4-phenyl-2) -Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandone (3- Methyl-4-phenyl-3-buten-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damasenone, damascone, isodamascone, α-dynascone (1- (5,5 Dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one and 4-3 , 5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one), ionone, pseudoionone, methylionone, methyliriton (3-methyl-4- (2,4,6-trimethyl-3- Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allyl ionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH (2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzo Run 2-one), Purikaton (4-methyl-tricyclo [6.2.1.0 ^2.7] undecane-5-one), Okisosedoran, belt fix (9-acetyl -2,6,6,8- tetramethyl Tricyclo [5.3.1 ^1.7 . 0 ^1.5] -8-undecene), verbenone (4,6,6-trimethyl - (1R) - Bishikuroheputo-3-en-2-one), fenchone, Charon (7-methyl-3,5-dihydro -2H- Benzodioxepin-3-one), trimofix O (2,6,10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), bitalide (acetyldimethyltetrahydrobenzindane), epiton (7 ( 8) -Acetyl-5-isopropyl-2-methylbicyclo [2.2.2] oct-2-ene), atrinone (4 (5) -acetyl-7,7,9 (7,7,9) -trimethyl Bicyclo [4.3.0] -1-nonene), cachemelan (6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H) -indanone), muscone (3- Tilcyclopentadecanone-1), musenone delta (3-methylpentadec-4-enone), civeton (cycloheptadec-9-en-1-one), exetalton (cyclopentadecanone), musk TM-II ( Cyclohexadecenone), fantolide (5-acetyl-1,1,2,3,3,6-hexamethylindane), celestorido (4-acetyl-6-tert-butyl-1,1-dimethylindane), traseolide ( 5-acetyl-3-isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,7-hexamethyltetrahydronaphthalene), bitalide (acetyldimethyltetrahydro) Benzindan), iso-e super (7-acetyl-1,2,3,4,5,6,7,8) -Octahydro-1,1,6,7-tetramethylnaphthalene), dihydrocarbon, diosphenol, gingerone and the like.

Examples of ether compounds include methyl hexyl ether, decyl methyl ether, decyl vinyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, citronellyl ethyl ether, geranyl ethyl ether, α-terpinyl methyl ether, Herbabert (3, 3, 5-trimethylcyclohexyl ethyl ether), isobornyl methyl ether, tricyclodecenyl methyl ether, isoproxen (2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane), juniparome (methoxydimethyltricyclo [5.2.1.0 ^2.6 ] decane), cyclododecyl methyl ether, Madrox (1-methylcyclododecyl methyl ether), fizeol (2-ethoxy-2,6,6) -Trimethyl-9-methylenebicyclo [3.3.1] -nonane), cedlum bar (cedrol methyl ether), methyl benzyl ether, methyl phenyl ethyl ether, ethyl 2-methoxy benzyl ether, allyl phenyl ethyl ether, isoamyl benzyl ether, Answer (isoamyl phenyl ethyl ether), jacene (2-methyl-2-butenyl phenyl ethyl ether), dibenzyl ether, cyclohexyl phenyl ether, mirooxide (oxime epoxide), limonene oxide (p-menta-8-ene-1) , 2-epoxide), rubofix (spiro [1,4-methanonaphthalene-2 (1H), 2′-oxirane], − 3,4,4a, 5,8,8a-hexahydro-3 ′, 7-dimethyl and Spiro [1 , 4-methanonaphthalene-2 (1H), 2′-oxirane], 3,4,4a, 5,8,8a-hexahydro-3 ′, 6-dimethyl), trimethylcyclododecatriene epoxide, caryophyllene oxide, ce Drain epoxide, isolongifolene epoxide, linalool oxide, citrooxide (2,2-dimethyl-5 (1-methyl-1-propenyl) -tetrahydrofuran), herboxoxide (5-isopropenyl-2-methyl-2-vinyl) Tetrahydrofuran), rose furan (3-methyl-2- (3-methyl-2-butenyl) -furan), heptabel (2-heptyltetrahydrofuran), mentfuran, theaspirane, oxybet (2-oxaspiro [4,7] dodecane) ), Muskogen (3-oxabicyclo [1 .3.0] -6-pentadecene), cyclamber (13-oxabicyclo [10.3.0] pentadecane), ambroxan (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-b] Furan), glycalva (3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1-b] furan), 1,8-cineol, 1,4-cineol, galaxolide (1,3,4,6) , 7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-γ-2-benzopyran), rose oxide, nerol oxide, limetole (2,2,6-trimethyl-6- Vinyltetrahydropyran), dirane (2-butyl-4,6-dimethyldihydropyran), dremox (tetrahydro-4-methyl-2-phenyl-2H-) Lan), Rubofuroa (9 ethylidene-3-oxatricyclo [6.2.1.0 ^2.7] undecane), hexahydroisochromeno indeno-pyran, and the like.

  Examples of the acid compounds include geranic acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid, 2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, and 3-methylvaleric acid. , Hexanoic acid, isohexanoic acid, 2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid, octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylene Acid, dodecanoic acid, myristic acid, palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid, lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylpropionic acid, vanillic acid, valine, abietic acid, sorbine An acid etc. are mentioned.

  Lactone compounds include pentalide (cyclopentadecanolide), habanolide (oxacyclohexadecen-2-one), ambletide, cyclohexadecanolide, 10-oxahexadecanolide, and 11-oxahexadecanolide. 12-oxahexadecanolide, ethylenedodecandioate, γ-butyrolactone, γ-valerolactone, angelicalactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3 -Methyl-4-octanolide), [gamma] -decalactone, [gamma] -undecalactone, [gamma] -dodecalactone, [gamma] -jasmolactone, jasmine lactone, cisjasmon lactone, lacto jasmon (4-methyl-4-decanolide), jasmo Lactone (tetrahydro-6 (3-pentenyl) -2H-pyran-2-one), mentalactone (3,6-dimethyl-5,6,7,7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide Butylidenephthalide, δ-hexalactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2 Decenolactone, δ-undecalactone, δ-dodecalactone, δ-tridecalactone, δ-tetradecalactone, lactoscatone (decahydro-4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid- δ-lactone), coumarin, dihydrocoumarin, cyclohexyl lactone, 6-methylcoumarin, ε-deca Examples include lactone and ε-dodecalactone.

Examples of ester compounds include ethyl formate, propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate, neryl formate, rosinyl formate, formic acid Terpinyl, Cedryl formate, Cariopherene formate, Afermate (α, 3,3-trimethylcyclohexanemethyl formate), Oxyoctaline formate, Benzyl formate, Cinnamyl formate, Phenylethyl formate, Anisyl formate, Eugenyl formate, Decahydro formate-β- Naphthyl, methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate, cis-3-hexenyl acetate, Trans-2-hexenyl acetate, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, dodecyl acetate, dimethylundecadi acetate Enyl, diacetyl, diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, osmenyl acetate, mircenyl acetate, dihydromyrsenyl acetate, dimethyloctanyl acetate, linalyl acetate, citronellyl acetate, rosinyl acetate, Geranyl acetate, neryl acetate, tetrahydromugol acetate, ethyl linalyl acetate, lavandulyl acetate, isohydrolavandulyl acetate, nerolidol acetate, carbyl acetate Dihydrocarbyl acetate, dihydrocuminyl acetate, terpinyl acetate, isopulegol acetate, menthyl acetate, citryl acetate, mirtenyl acetate, nopyru acetate, fenkyl acetate, bornyl acetate, isobornyl acetate, cedolyl acetate, caryophyllene acetate, santalylacetate, vetiberyl acetate, guaiac , Methyl cyclopentylidene acetate, cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amylcyclohexyl acetate, dihydroterpinyl acetate, cyclohexylethyl acetate, fluorolate (2,4-dimethyl-3-cyclohexenylmethyl acetate), Rosamusk (α, 3,3-trimethylcyclohexanemethyl acetate), Vertenex (p-tert-butylcyclohexyl acetate), Verdox (o-tert-butyl acetate) Tilcyclohexyl), 1-ethynylcyclohexyl acetate, dihydroambrate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), miraldyl acetate (4 (3)-(4-methyl-3-pentenyl) -3- Cyclohexenyl methyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styryl acetate, p-methylbenzyl acetate, anisyl acetate, piperonyl acetate, acetyl vanillin, rosephenone Hydratropyl acetate, 2,4-dimethylbenzyl acetate, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzyl carvinyl acetate, phenyl glycol diacetate, dimethylphenylethyl carvinyl acetate, phenyl ethyl acetate Ruethylcarbinyl, beticol acetate (4-methyl-4-phenyl-2-pentyl acetate), α-amylcinnamyl acetate, jasmalol (trans-decahydro-β-naphthyl acetate), furfuryl acetate, tetrahydrofurfuryl acetate, jasmar (3-pentyltetrahydropyranyl acetate), jasmeria (5-methyl-3-butyltetrahydropyranyl acetate), ethyl acetoacetate, jessate (ethyl 2-hexylacetoacetate), ethyl benzylacetoacetate, allyl cyclohexylacetate, cyclohexenyl Isopropyl acetate, ethyl propionate, propyl propionate, allyl propionate, butyl propionate, isobutyl propionate, isoamyl propionate, hexyl propionate, cioni propionate -3-hexenyl, trans-2-hexenyl propionate, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate, carbyl propionate, terpinyl propionate, menthyl propionate, propionate Boronyl acid, Isobornyl propionate, Tricyclodecenyl propionate, Benzyl propionate, Styraryl propionate, Anisyl propionate, Phenyl ethyl propionate, Cinnamyl propionate, Phenyl propyl propionate, Dimethyl benzyl carvinyl propionate, Propionic acid Phenoxyethyl, propylene glycol propionate dipropionate, allylcyclohexane propionate, Rabdanax (3 Hydroxy-3-phenylpropionate ethyl), isobutyl furanpropionate, methyl butyrate, ethyl butyrate, propyl butyrate, isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, amyl butyrate, isoamyl butyrate, hexyl butyrate, heptyl butyrate, cis-butyrate 3-hexenyl, trans-2-hexenyl butyrate, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate, rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, Dimethylbenzyl carvinyl butyrate, tetrahydrofurfuryl butyrate, santalyl butyrate, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, butyl isobutyrate, isobutyric acid Sobutyl, isoamyl isobutyrate, hexyl isobutyrate, cis-3-hexenyl isobutyrate, 2,4-hexadienyl isobutyrate, isopentylate (1,3-dimethyl-3-butenyl isobutyrate), octyl isobutyrate, linalyl isobutyrate Citronellyl isobutyrate, rosinyl isobutyrate, geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate, p-cresyl isobutyrate, cinnamyl isobutyrate, phenylethyl isobutyrate, isobutyric acid Phenylpropyl, styrylyl isobutyrate, dimethylcarbyl isobutyrate, dimethylphenylethylcarbyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydro-β-naphthyl isobutyrate, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2 -Methylbutyric acid- Methyl butyl, cidolane (hexyl 2-methylbutyrate), cis-3-hexenyl 2-methylbutyrate, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, Ethyl valerate, butyl valerate, isobutyl valerate, amyl valerate, cis-3-hexenyl valerate, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, isovaleric acid Propyl, isopropyl isovalerate, allyl isovalerate, butyl isovalerate, isobutyl isovalerate, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, cis-3-hexenyl isovalerate, isoyoshi Hexyl herbate, octyl isovalerate, linalyl isovalerate, citroisovalerate Neryl, geranyl isovalerate, menthyl isovalerate, terpinyl isovalerate, cyclohexyl isovalerate, benzyl isovalerate, phenylethyl isovalerate, phenylpropyl isovalerate, cinnamyl isovalerate, manzanate (2-methyl valerate) Ethyl herbate), phenyl salicylate, peranato (2-methylpentyl ester of 2-methylvaleric acid), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, isobutyl hexanoate, hexane Amyl acid, isoamyl hexanoate, hexyl hexanoate, cis-3-hexenyl hexanoate, trans-2-hexenyl hexanoate, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, Citronellyl sanate, benzyl hexanoate, methyl isohexanoate, methyl 2-hexenoate, ethyl trans-2-hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, 3-hydroxyhexanoic acid Ethyl, ethyl 2-ethylhexanoate, mersat (ethyl 3,5,5-trimethylhexanoate), beliflo (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, Octyl heptanoate, methyl octoate, ethyl octoate, amyl octoate, butyl octoate, propyl octoate, allyl octoate, isoamyl octoate, hexyl octoate, heptyl octoate, octyl octoate, linalyl octoate, o Benzyl tanoate, phenylethyl octoate, p-cresyl octoate, ethyl 2-octenoate, methyl nonanoate, ethyl nonanoate, phenylethyl nonanoate, bouvartate (methyl 2-nonenoate), methyl 3-nonenoate, decane Methyl acid, ethyl decanoate, isopropyl decanoate, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, ethyl 2,4-decadienoate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylenate, undecylene Isoamyl acid, methyl dodecanoate, ethyl dodecanoate, butyl dodecanoate, isoamyl dodecanoate, ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, olei Ethyl acetate, methyl benzoate, ethyl benzoate, propyl benzoate, isopropyl benzoate, allyl benzoate, isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, benzoic acid Linalyl, geranyl benzoate, benzyl benzoate, phenylethyl benzoate, cinnamyl benzoate, methyl anisate, ethyl anisate, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, tigulin Cis-3-hexenyl acid, citronellyl tiglate, geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelate, butyl angelate, isobutyl angelate, isoamyl angelate, Angelic acid prenyl, angelic acid cis-3-hexenyl, angelic acid 3-methylpentyl, angelic acid phenylethyl, ethyl acrylate, phenyl ethyl methacrylate, ethyl crotonate, isobutyl crotonate, cyclohexyl crotonate, flutinato (4-methyl -Pentan-2-ol-crotonate), pyropurnato (2-cyclopentyl-cyclopentylcrotonate), dachirat (1-cyclohexylethylcrotonate), ethyl levulinate, butyl levulinate, isoamyl levulinate, methyl lactate, ethyl lactate, lactic acid Amyl, isobutyl lactate, cis-3-hexenyl lactate, butyryl butyl lactate, ethyl pyruvate, methyl gellanate, ethyl gellanate, methyl cyclogellanate, ethyl cyclogellanate, ethyl Le phenylglycidates, Furuteto (ethyl tricyclo [5.2.1.0 ^2.6] decan-2-yl-carboxylate), Jibesukon (ethyl-2-ethyl-6,6-dimethyl-2-cyclohexen-1-carboxy And ethyl-2,3,6,6-tetramethyl-2-cyclohexenecarboxylate), ethyl safranate (ethyl dehydrocyclogeranate), allyl cyclohexylpropionate, cyclogalvanate (allylcyclohexyloxyacetate), calixol ( Ethyl-2-methyl-6-pentyl-4-oxocyclohexyl-2-enecarboxylate), tacrisate (methyl-1-methyl-3-cyclohexenecarboxylate), floramate (ethyl-2-tert-butylcyclohexylcarboxy) ), Jasma cyclate (methylcyclooctyl carbonate), mahagonate (1-methyl-4-isopropyl-2-carbomethoxybicyclo [2.2.2] -oct-5-ene), phenylethyl pivalate, Methyl jasmonate, hedion (methyl dihydrojasmonate), veramos (methyl-3,6-dimethyl-β-resorcylate), methyl furan carboxylate, ethyl furan carboxylate, propyl furan acrylate, methyl heptine carboxylate, heptin Ethyl carboxylate, isoamyl heptine carboxylate, methyl octynecarboxylate, ethyl octynecarboxylate, methyl decynecarboxylate, glycomer (3- (bicyclo [2.2.1] hept-5-en-2-yl) -3 Methyl Este of Methyloxirane Carboxyacid ), Methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-16 (ethyl 3-methyl-3-phenylglycidate), aldehyde C-20 (ethyl p-methyl-β-phenylglycidate) , Methyl p-tolylglycidate, ethyl citronellyl oxalate, diethyl succinate, dimethyl succinate, diethyl malonate, diethyl tartrate, diethyl adipate, diethyl sebacate, triethyl citrate, dimethyl phthalate, diethyl phthalate, phthalate Dibutyl acid, methyl phenylacetate, ethyl phenylacetate, isopropyl phenylacetate, butyl phenylacetate, propylphenylacetate, isobutyl phenylacetate, isoamyl phenylacetate, hexylphenylacetate, cis-3-hexenyl phenylacetate, citrone phenylacetate Rosinyl phenylacetate, geranyl phenylacetate, menthyl phenylacetate, benzyl phenylacetate, phenylethyl phenylacetate, p-cresyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, methyl cinnamate, ethyl cinnamate, cinnamic acid Propyl, isopropyl cinnamate, allyl cinnamate, isobutyl cinnamate, isoamyl cinnamate, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, salicylic acid Butyl, isobutyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, cis-3-hexenyl salicylate, cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate Cyclopyden (methylcyclopentylidene acetate), avalin (methyl abieticate), hercoline (methyldihydroabietate), p-cresyl salicylate, allyl phenoxyacetate, ethyl phenylpropionate, ethylene brushate, triacetin and the like.

  Nitrogen-containing compounds include methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, methyl N-methylanthranylate, auranthiol (hydroxycitronone). Lahr-methylanthranilate Schiff base), mevantral (methylpropylacetaldehyde-methyl anthranilate Schiff base), jasmentin (α-amylcinnamic aldehyde-methyl anthranilate Schiff base), ligantoral (methyl- (3,5 -Dimethyl-3-cyclohexen-1-yl) methyleneanthranilate), indole, skatole, clonal (dodecanenitrile), tangenyl (2-tridecene) Thryl), citralba (geranyl nitrile), citronellyl nitrile, lemonyl (3,7-dimethyl-2,6-nonadinitrile), cuminyl nitrile, cinnamalva (cinnamyl nitrile), trimethylamine, pyridine, 3-ethylpyridine, 2- Acetylpyridine, 3-acetylpyridine, 2-isobutylpyridine, 3-isobutylpyridine, 2-n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4- (1,4,8-trimethyl-3 , 7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p-methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, 6 (p) -Tert-butylquinoline, 2-tert-butylquinoline, N-substituted-paramentane-3-carboxamide, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5- Trimethylpyrazine, 2-ethylpyrazine, 2-ethyl-3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2 , 3-Diethyl-5-methylpyrazine, tetramethylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3- Isopropylpyrazine, 2-isobutyl-3-methoxypyrazine, 2-acetylpyrazine, 2-acetyl- -Ethylpyrazine, methylthiomethylpyrazine, corylonepyrazine (5-methyl-6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8-tetrahydroquinoxaline), 1-methyl Pyrrole, 2-acetylpyrrole, pyrrolidine, indolene (Schiff base of indole-hydroxycitronellal), 2-methylbenzoxazole, decahydrocyclododecoxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2 .1] Octane-8-one, 1,5-dimethyl-, oxime), gardamide (N-methyl-N-phenyl-2-methylbutyramide), muskoxylol, musk ketone, musk ambullet, musk civeten, mosken, 2 , 6- Tidine, piperidine, 2- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, 2- (2-pinen-10-ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine , Capsaicin, nonanoic acid vanillylamide, quinine, perilartin (L-perilaldehyde α-anti-aldoxime), 2-isopropyl-4-methylthiazole, 2-isobutylthiazole and the like.

  Examples of sulfur-containing compounds include thiazole, 4-methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole, 2-isopropyl-4-methylthiazole, 4-methyl-5-vinylthiazole. 2-isobutylthiazole, sulfuryl (4-methyl-5-thiazole ethanol), sulfuryl acetate (4-methyl-5-thiazole ethanol acetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole, Benzothiazole, propyl mercaptan, hydrogen sulfide, isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomentone) Enyl mercaptan, o-thiocresol, 2-ethylthiophenol, 2-naphthyl mercaptan, furfuryl mercaptan, 2-methyl-3-furanthiol, dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide, methylpropyl disulfide, methylpropyl trisulfide , Propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio) -1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), Mint sulfide, dithiospirofurofuran, furfuryl methyl sulfide, 2-methyl-5-methylthiofuran, methyl furfuryl disulfide, furfuryl Disulfide, thiophene, tetrahydrothiophene, 3-thiophenecarboxaldehyde, 5-methyl-2-thiophenecarboxaldehyde, tetrahydrothiophene-3-one, trithioacetone, thioglycolic acid, methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropion Acid, pineapple mercaptan (methyl mercaptomethylpropionate), ethyl 3-methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methylmethanethiosulfonate, allyl isothiocyanate, isothiocyanic acid Benzyl, thiaridine (2,4,6-trimethyl-4,5-dihydro-1,3,5-dithiazone), oxane (2-methyl-4-propyl-1,3-oxy) Satian) and the like.

  Natural fragrances include Asafetida Resinoid, Ajowan Oil, Star Anise Oil, Abies Oil, Amiris Oil, Ambret Seed Oil, Ambergris Tincture, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Winter Green Oil, Elemioreoresin, Elemi Resinoid Absolute, Elemi Tinch, Oak Moss Concrete, Oak Mos Absolute, Oak Mos Resin, Oak Moth Resinoid, Ocotia Oil, Ottoman Sus Absolute, Otto Manus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopa NAX OIL, ORIBANAM RESINNOID, ORIBANUM ABSOLUTE, ORIBANUM OIL, OH Spice oil, origanum oil, oregano oil, oregano oleoresin, orange oil, orange flower absolute, orange flower concrete, cananga oil, garjun balsam oil, gajun balsam oil, cascari bark oil, castrium absolute, cassie absolute, cassie Flower oil, cassia oil, gardenia absolute, carnation absolute, cabruba oil, camomil oil, cardamom oil, galvanum oil, galvanum resin, galvanum resinoid, caraway seed oil, carrot seed oil, guaiac wood oil, guaiac resin, guava Yak concrete, camphor oil, kubeba oil, cumin oil, cumin abu Lute, Cumin Oleoresin, Clarisage Oil, Grapefruit Oil, Clove Oil, Costas Oil, Copaiba Balsam, Copaiba Balsam Oil, Copaiba Balsam Resin, Coriander Oil, Sassafras Oil, Sandalwood Oil, Geneva Absolute, Perilla Oil, Citronella Oil, Jasmine Oil , Jasmine absolute, jasmine concrete, juniper berry oil, civet absolute, civet tincture, jonquil absolute, agarwood oil, ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, stylax oil, stylax resinoid, spearmint oil , Savory oil, sage oil, cedar oil, se Darleaf Oil, Geranium Oil, Celery Seed Oil, Thyme Oil, Tagget Oil, Tarragon Oil, Tuberose Absolute, Dill Oil, Tea Tree Oil, Torimos Absolute, Truval Sam, Nutmeg Oil, Narcissus Absolute, Neroli Oil, Violet Leaf Absolute, Pine oil, pine needle oil, basil oil, parsley leaf oil, parsley seed oil, parsley herb oil, patchouli oil, mint oil, vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, Hyacinth absolute, fennel oil, fig absolute, petit glen oil, bush Chu Oil, Bay Oil, Vetiver Oil, Penny Royal Oil, Pepper Oil, Peppermint Absolute, Peppermint Oil, Bergamot Oil, Peru Balsam, Benzoin Tincture, Benzoin Resinoids, Boadrose Oil, Pepper Oil, Hop Oil, Hop Concrete, Hop Absolute, Marjoram Oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, mil resinoid, mil absolute, mill oil, musk absolute, mustinki, eucalyptus oil, yuzu oil, mugwort oil, lime oil, labdanum oil, labdanum resinoid, lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute Oil, linaloe oil, lemon oil, lemongrass oil, rose oil, rose absolute, rose concrete, rosemary oil, lobe oil, laurel oil, laurel leaf oil, wormwood oil, musk, ghost cat incense, dragon perfume, marine incense , Musk, chibata and the like.

  Examples of blended fragrances that combine fragrance ingredients include the following incense-based bases. Lemon-like, lime-like, orange-like, sweet orange-like, mandarin-like, bergamot-like citrus-type base, petit-gren-like, neroli-like, lemongrass-like, aggluten-like, fresh-type base, apple-like, peach-like, strawberry Tone, coconut tone, pineapple tone, raspberry tone, water melon tone, grape tone, mango tone, fruit mix tone, tropical fruit tone and other fruity type base, rose tone, jasmine tone, mugue tone, lilac tone, carnation tone, hyacinth Tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, violet tone, Iranian tone, floral bouquet tone and other floral type bases, cinnamon bark tone, cinnamon leaf tone, clove tone, pimentoberry tone, nutmeg tone, pep -Tone, cardamom tone, coriander tone, cumin tone, etc., spicy type bass, cedarwood tone, vetiver tone, sandalwood tone, guaiac wood tone, woody bar tone, woody iris tone, woody type bass, smoky tone, quinoline tone Leather type such as vanilla, tonka, honey, pure balsam, etc., butter flavor, milk flavor, aldehydic type base, amber type base, animal type base, anise type base, aromatic Herbal type base, agar type base, aqua type base, camphor cineole type base, green type base, seed type base, herb type base, pine type base, patchouli type base Vinegar, balsamic type base, mint type base, musk type base, Moss type base, lavender type base, linalool type base, and a resin-type base and the like.

  Here, rosmarinic acid in the present invention is widely known to have an antioxidant effect. In the present invention, this antioxidant activity of rosmarinic acid stabilizes aldehyde compounds and ketone compounds that are unstable in structure and easily oxidized, and fragrance components having double bonds or triple bonds are stabilized. Improved. In addition, the rosmarinic acid in the present invention has a rosemary-like fragrance, and this citrus tone, floral tone, fruity tone, neroli tone, herbal tone, spice tone, musk umber tone, woody tone, sweet The fragrance of the tone can be emphasized, and the fragrance and fragrance sustainability are improved. Examples of the fragrances that suitably exhibit these effects include those shown below.

  Examples of the hydrocarbon compound include dihydromyrcene, α-pinene, β-pinene, limonene, myrcene, p-cymene and the like.

  Among alcohol compounds, geraniol, citronellol, nerol, dihydrolinalol, linalool, mugor, dihydromyrsenol, ethyl linalool, terpineol, farnesol, vetiverol, patchoulial alcohol, menthol, isoamyl alcohol, leaf alcohol (cis-3-hexenol), Santalinol (2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), sandalol (3-methyl-5- (2,2, 3-trimethylcyclopent-3-en-1-yl) pentan-2-ol), benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styryl alcohol (1-phenyl-1-hydroxyethane), amylcinnamic Lucol, vacudanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), polysanthol (3,3-dimethyl-5- (2 , 2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), borneol, geranyl linalool, p-methylbenzyl carbinol, muget alcohol (2,2-dimethyl-3-phenyl) Propanol) and the like.

  Examples of phenolic compounds and phenolic ether compounds include estragole, chavicol, anethole, p-cresyl methyl ether, β-naphthol ethyl ether, β-naphthol methyl ether, eugenol, methyl eugenol, methyl isoeugenol, hinokitiol and the like.

  Among the aldehyde compounds, citronellal, citral, hydroxycitronellal, acetaldehyde, cis-3-hexenal, trans-2-hexenal, meronal (2,6-dimethyl-5-heptenal), 2,4-nonadienal, mugealdehyde ( 6,10-dimethyl-3-oxa-9-undecenal), tripral (dimethyltetrahydrobenzaldehyde), dupical (4-tricyclodecylidenebutanal), mylacaldehyde (4 (3)-(4-methyl-3- Penten-1-yl) -3-cyclohexene-1-carboxaldehyde), benzaldehyde, phenylacetaldehyde, cyclamenaldehyde (2-methyl-3- (p-isopropylphenyl) -propionaldehyde), cinna Lacaldehyde, anisaldehyde, vanillin, ethyl vanillin, heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde), laral (4 (3)-(4-hydroxy-4-methylpentyl)- 3-cyclohexene-1-carboxaldehyde), lyial (p-tert-butyl-α-methylhydrocinnamic aldehyde), α-methylcinamic aldehyde, α-hexylcinnamic aldehyde, n-octanal, n-nonanal, 2 -Methylundecanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal and the like.

  For acetal and ketal compounds, acetaldehyde diethyl acetal, caranal (2- (2,4-dimethylcyclohex-3-sen-1-yl) -5-methyl-5 (1-methylpropyl) 1,3-dioxane) Osminal DEA (amylcinnamic aldehyde diethyl acetal), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate), and the like.

Among the ketone compounds, carvone, menthone, show brain, ethyl isoamyl ketone, methyl heptenone, cis-jasmon, dihydrojasmon, maltol, ethyl maltol, benzophenone, methyl naphthyl ketone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone ), damascenone, damascone, ionone, methyl ionone, irone, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo [5.3.1 ^1.7 .0 ^1.5] -8-undecene), Kashumeran ( 6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H) -indanone), Muscon (3-methylcyclopentadecanone-1), Musenon delta (3-methylpentadec-4-enone) ), Civeton (cycloheptadec-9-ene-1 -One), musk TM-II (cyclohexadecenone), traceolide (5-acetyl-3-isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4) , 4,7-hexamethyltetrahydronaphthalene), iso-e-super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene) ) And the like.

  Among the ether compounds, ambroxane (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-b] furan), 1,8-cineol, galaxolide (1,3,4,6,7,8) -Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-γ-2-benzopyran), rose oxide and the like.

  An acetic acid is mentioned in an acid type compound.

  Among the lactone compounds, pentalide (cyclopentadecanolide), habanolide (oxacyclohexadecen-2-one), ambletide, cyclohexadecanolide, cis jasmon lactone, γ-nonalactone, γ-undecalactone, coumarin Etc.

  For ester compounds, ethyl acetate, butyl acetate, isoamyl acetate, allyl amyl glycolate, linalyl acetate, citronellyl acetate, geranyl acetate, terpinyl acetate, isobornyl acetate, verdox (o-tert-butylcyclohexyl acetate), benzyl acetate, acetic acid Phenylethyl, styrylyl acetate, rosephenone, cinnamyl acetate, dimethylbenzylcarbvinyl acetate, α-amylcinnamyl acetate, manzanate (ethyl 2-methylvalerate), ethyl oleate, methyl benzoate, ethyl safranate (ethyl dehydrocyclogeranate) ), Hedion (methyl dihydrojasmonate), diethyl phthalate, methyl salicylate, amyl salicylate, hexyl salicylate, benzyl salicylate, hercoline (methyldihydroabietate) , Ethylene brassylate, and benzyl propionate.

  Examples of nitrogen-containing compounds include methyl anthranilate, auranthiol (Schiff base of hydroxycitronellal-methylanthranilate), indole, skatole, isobutylquinoline, pyrazine, musk ketone, pyridine and the like.

  In the sulfur-containing compound, limonene thiol is exemplified.

  Natural flavors include Star Anise Oil, Ylang Ylang Oil, Iris Oil, Elemi Oil, Orange Oil, Orange Flower Absolute, Cassia Oil, Camomile Oil, Cardamom Oil, Clarisage Oil, Grapefruit Oil, Clove Oil, Sandalwood Oil, Citronella Oil, jasmine absolute, spearmint oil, geranium oil, neroli oil, petitgren oil, peppermint oil, bergamot oil, mandarin oil, eucalyptus oil, lime oil, lavender oil, lavandine oil, lemon oil, lemongrass oil, rose oil, rose absolute , Rosemary oil and the like.

  In addition, as perfume solvents, ethanol, acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, delchile extra (isopropyl myristate) , Methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aboline (dimethyl phthalate), deltyl prime (Isopropyl palmitate), dipropylene glycol DPG-FC (dipropylene glycol), farnesene, dioctyl adipate, tri Tyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate, cetyl acetate (hexadecyl acetate), ethyl abiate, avaline (methyl abietate), citroflex A-2 (Acetyl triethyl citrate), citroflex A-4 (tributyl acetyl citrate), citroflex no. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate), polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like.

  Among the above solvents, ethanol, ethylene glycol dibutyrate, hexylene glycol, methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), propylene glycol, dipropylene glycol DPG-FC (dipropylene glycol), propylene glycol Perfume solvents such as 1,3-butylene glycol can be used to adjust the aroma titer.

  The amount of these solvents used is 0.1 to 99% by mass, preferably 1 to 40% by mass, in the fragrance and the fragrance composition comprising the solvent.

  Such a fragrance composition is usually blended in the first composition of the present invention in an amount of 0.00001 to 50% by mass, preferably 0.0001 to 30% by mass. If the blending amount is less than 0.00001% by mass, sufficient flavor may not be obtained, and if it exceeds 50% by mass, the flavor is too strong and the quality of the composition may be deteriorated.

  The first composition of the present invention preferably supports the above-mentioned fragrance between layers of swellable clay minerals from the viewpoint of exhibiting an effect of excellent flavor fragrance, stability and sustainability. The swellable clay mineral is a kind of colloidal hydrous aluminum silicate having a three-layer structure. Specifically, natural or synthetic montmorillonite groups such as montmorillonite, saponite, and hectorite (commercially available products are bee gum, kunipia, laponite. , Bengel, etc.), sodium silicic mica, and synthetic mica known under the name of lithium teniolite (commercially available products such as Daimonite; Toby Industries Co., Ltd.). These can be used individually by 1 type or in combination of 2 or more types.

  In particular, an organically modified smectite clay mineral obtained by dispersing and stirring a quaternary ammonium salt type cationic surfactant and / or a nonionic surfactant and then removing a low boiling point solvent (Esben E in the commercial product). , Sven W, Sben XL, Sven N-400; manufactured by Toyoshun Yoko Co., Ltd., Clayton AF, Clayton SO; manufactured by Southern Clay Product Co., Ltd.) Formulated in detergent compositions (shampoos, rinses, conditioners, treatments, body soaps, hand soaps, soaps, facial cleansers, laundry detergents, bleaches, softeners, dishwashing detergents, bathroom detergents, toilet detergents, etc.) It is preferable in that it has an effect on the retention of the scent after washing.

  The said fragrance | flavor is mix | blended and carried in the ratio of 0.1-20 with respect to the swellable clay mineral 1 by mass ratio. Furthermore, the ratio of 0.5-15 is preferable. If it is less than 0.1, the mixture becomes hard and handling may be difficult. Moreover, even if it exceeds 20, the carrying effect is not affected, and the effect of scent retention may not change. This carrier can be obtained by blending a predetermined amount of swellable clay mineral with a perfume at 5 to 50 ° C. and stirring with a paddle or the like for 5 to 30 minutes.

  Furthermore, as an optional component for improving the viscosity and stability of the support, an oily component, a highly ionic nonionic surfactant having an HLB of 16 or less, silicone oil, a modified silicone emulsion, and the like can be added.

  The blending amount of the swellable clay mineral in the first composition of the present invention is not particularly limited and can be appropriately selected depending on the type, the dosage form of the composition, etc. On the other hand, it is desired to be 0.001 to 20% by mass, preferably 0.005 to 10% by mass. When the blending amount is less than 0.001% by mass, the retention effect may not be sufficiently obtained, and when it exceeds 20% by mass, the retention effect may not be changed, and a precipitate may be generated.

  It is preferable to mix | blend a chelating agent with the 1st composition of this invention from the point of the composition stabilization containing a fragrance | flavor component. The chelating agent of the present invention generally means a compound having a chelating effect, for example, condensed phosphoric acid such as pyrophosphoric acid and polyphosphoric acid, oxycarboxylic acid such as citric acid and salts thereof, ethylenediaminetetraacetic acid (EDTA) and the like. Examples thereof include polyaminocarboxylic acids and salts thereof, porous inorganic materials such as zeolite, and clay minerals such as smectite and bentonite. Of these, oxycarboxylic acids such as citric acid are particularly preferred. Moreover, when mix | blending a chelating agent with a composition, you may mix | blend as a free acid and may mix | blend as a salt, and these can be used individually by 1 type or in combination of 2 or more types.

  The compounding amount of the chelating agent is usually 0.0001 to 50% by mass, preferably 0.001 to 30% by mass, based on the entire composition. When the blending amount is less than 0.0001% by mass, a sufficient stabilizing effect may not be obtained, and when the blending amount exceeds 50% by mass, precipitates may be generated.

  Moreover, this invention provides the 2nd composition for hair or textiles processing characterized by mix | blending rosmarinic acid, a cationic surfactant, and a gallic acid glycoside. By using a combination of rosmarinic acid and a cationic surfactant, it is possible to remarkably improve the poor touch of the hair or fiber surface due to damage.

  In the second composition for treating hair or textile products, the content of the rosmarinic acid is not particularly limited, but is usually 0.01 to 20% by mass, preferably 0.1%, based on the entire composition. It is selected in a range of ˜5% by mass, more preferably 0.1 to 2% by mass. When the blending amount is less than 0.01% by mass, the effect of preventing split ends and hair breakage may not be sufficiently obtained, and when it exceeds 20% by mass, a good feeling of use may not be obtained. is there.

  Examples of the cationic surfactant include aliphatic amine salts (primary amine salts, secondary amine salts, tertiary amine salts, quaternary ammonium salts, hydroxyammonium salts, ether ammonium salts), aromatic quaternary salts. Quaternary ammonium salts (benzalkonium salts, benzethonium salts, pyridinium salts), amino acid-based cationic surfactants, guanidine derivatives or salts thereof (such as 4-guanidinobutyllauramide acetic acid), and the like. Or 2 or more types can be used in appropriate combination. These are specifically shown below.

Here, in the above formula, R ¹ represents an alkyl group or alkenyl group having 12 to 24 carbon atoms, preferably 12 to 22 carbon atoms, and R ² , R ³ and R ⁴ each have 1 to 3 or 12 carbon atoms. 24, preferably 1 to 3 alkyl or alkenyl groups. R represents an alkyl group having 1 to 12 carbon atoms, preferably 1 to 6 carbon atoms. X represents an anion derived from a salt such as chloride, bromide, iodide, methyl sulfate, ethyl sulfate and the like. Specific examples of R ¹ include alkyl groups or alkenyl groups such as lauryl, myristyl, palmityl, stearyl, and oleyl. Specific examples of R ² , R ³ , and R ⁴ include methyl, ethyl, Examples thereof include alkyl groups or alkenyl groups such as stearyl and oleyl, and the same alkyl groups or alkenyl groups as those described above for R ¹ .

  The second composition of the present invention is excellent in the effect of improving the quality of hair or fibers, and can be suitably used for hair cosmetics, flexible compositions, etc., but in the case of hair cosmetics, it contains the above cationic surfactant. The amount is not particularly limited, but is usually selected in the range of 0.01 to 5% by mass, preferably 0.1 to 3% by mass, more preferably 0.1 to 2% by mass with respect to the entire cosmetic. . When the blending amount is less than 0.01% by mass, the effect of improving the hair touch may not be sufficiently obtained, and when it exceeds 5% by mass, a good feeling in use may not be obtained. On the other hand, in the case of a softening agent composition, it is normally selected in the range of 0.1 to 20% by mass, preferably 1 to 15% by mass, and more preferably 2 to 10% by mass with respect to the entire composition. If the blending amount is less than 0.1% by mass, the effect of improving the fiber touch may not be sufficiently obtained, and if it exceeds 20% by mass, a good feeling in use may not be obtained.

  The second composition of the present invention preferably contains hydroxycarboxylic acids selected from gallic acid and its glycosylated products or gluconic acid and its derivatives from the viewpoint of improving the squeaky feeling of hair or textile products. Examples of hydroxycarboxylic acids include gallic acid and its glycosylated products, gluconic acid and its salts, or gluconic acids that are glycosylated. These can be used individually by 1 type or in combination of 2 or more types. Examples of the salts include alkali metal salts such as sodium and potassium salts, ammonium salts, triethanolamine salts, transition metal salts and the like. Examples of glycosides include those obtained by glycosylation of glucose, maltose, galactose and the like.

  More specifically, as hydroxycarboxylic acid used in the present invention, for example, gallic acid methyl ester-3-glucoside, gallic acid methyl ester-4-glucoside, gallic acid propyl ester-3-glucoside, gallic acid methyl ester-3- Maltoside, gallic acid-3-glucoside, gallic acid-3-maltoside, gallic acid-octyl-3-maltoside, gallic acid-3-glucuronide, gallic acid galacturonide, gallic acid methyl ester-3,5-diglucoside, gallic acid- Examples include gallic acid glycosides such as 3,4-diglucoside, gallic acid-3,5-diglucoside, and the like, and gluconic acids such as gluconic acid, zinc gluconate, copper gluconate, and iron gluconate. It is done. Of these, gallic acid-3,5-diglucoside is particularly preferred.

The method for producing the gallic acid diglycoside includes gallic acid or an ester thereof, a saccharide having a partially or completely acetylated hydroxyl group or a saccharide having an anomeric halogenated, such as BF ₃ · Et. Reaction in a solvent in the presence of an acid catalyst such as ₂ O, SnCl ₄ or ZnCl ₂ gives a glucosylated product. If necessary, this is subjected to a deprotection reaction in the presence of an acid or alkali catalyst, followed by extraction, column chromatography. It can be easily and efficiently produced by purifying by graphy or the like.

  When the composition of the present invention is a hair cosmetic, the content of the hydroxycarboxylic acids is not particularly limited, but is usually 0.01 to 10% by mass, preferably 0.1 to 10% by mass with respect to the entire cosmetic. The range of 5% by mass, more preferably 1-5% by mass is suitable. When the blending amount is less than 0.01% by mass, it may be difficult to obtain a sufficient touch improving effect, and when it exceeds 10% by mass, flaking may occur.

  In the case of a composition for treating hair or textile products, the composition of the present invention is commonly used in conventional compositions for treating hair or textile products, in addition to the aforementioned components, as long as the object of the invention is not impaired. Various additive components can be blended as desired. In this case, it is also effective to blend the above-described fragrance, swellable clay mineral, and chelating agent.

  These additive components include, for example, nonionic surfactants such as polyoxyethylene alkyl ether and polyoxyethylene hydrogenated castor oil, amphoteric surfactants such as lauryldimethylaminoacetic acid betaine, hydroxyethyl cellulose, polyacrylic acid and the like. Molecular thickeners, polyvinyl pyrrolidone, set polymer resins such as alkyl resins, organic acids such as citric acid and glycolic acid and their salts, amino acids, protein hydrolysates, bactericides, UV absorbers, antioxidants, higher alcohols And silicone compounds such as methylpolysiloxane and amino-modified silicone and derivatives thereof, hydrocarbons, ester oils, colorants, solvents (ethanol, water, etc.), fatty acids and the like.

  These additive components may be used singly or in combination of two or more, and may be blended at an appropriate stage of the composition preparation.

  The composition of the present invention is not particularly limited in its dosage form, and is adjusted to various shapes such as liquid, cream, aerosol, pump spray type, spray type, foam, gel, and wax. And can be prepared according to conventional methods for each dosage form.

  In this case, for example, liquefied petroleum gas, dimethyl ether, carbon dioxide gas, nitrogen gas or the like can be used as a propellant to be blended when the composition of the present invention is made into a foam-generating aerosol type. Furthermore, the usual method can be adopted as the preparation method. Specifically, the water-soluble component and the oil-soluble component in the above components are separately dissolved and mixed, and after mixing these, the propellant is filled in a container and used. can do.

  The composition of the present invention is excellent in the effect of improving the quality of hair or fibers, and can be suitably used for hair cosmetics, flexible compositions and the like.

  Especially in the case of hair cosmetics, it can be widely used as in bath hair care agents and out bath hair care agents such as shampoos, rinses, treatments, hair creams, hair gels, hair foams, hair waters, hair waxes, etc. By using it according to the law, it prevents hair splits and hairs and improves the feel of the hair.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example. In addition, the numerical value in each example shall be the mass% unless there is particular description.

[Preparation Example 1] Preparation of rosmarinic acid crude purified product A rosmarinic acid crude purified product was prepared from mannen wax by the following method.
100 g of n-hexane was passed through 100 g of dried Mannenrou leaves on the filter paper and degreased and air-dried. Furthermore, 10 times amount 80 mass% ethanol was added with respect to this dry leaf, and it stirred at 60 degreeC for 2 hours, and obtained the crude extraction solution. After distilling off the ethanol in the crude extract under reduced pressure, an equal amount of water and hexane were added, and the aqueous phase fraction was separated by partitioning with a separatory funnel. Further, the solvent was removed from the fraction with a rotary evaporator to obtain 8 g of a crude product of rosmarinic acid.

[Preparation Example 2] Preparation of rosmarin semi-purified product The rosmarinic acid crude product of Preparation Example 1 was dissolved in an appropriate amount of solvent, loaded onto a silicic acid column, and fractionated with chloroform: methanol = 10: 1. The highly polar fraction was collected. This fraction was desolvated with a rotary evaporator to obtain 0.5 g of a rosmarin semi-purified product.

[Preparation Example 3] Preparation of clay mineral-supported fragrance composition Supported fragrance compositions 13 to 19 were prepared in the amounts shown in Table 1 below. In the preparation method, a fragrance component is prepared in a 300 ml beaker at room temperature (about 25 ° C.), and a swellable clay mineral is gradually added at 10 g / min while stirring at 200 rpm with a three-one motor (manufactured by HEDION). did. After completion of the addition, the mixture was further stirred for 10 minutes to obtain a predetermined supported fragrance. The obtained supported fragrance is blended so as to be uniformly dispersed in the composition of each example. In addition, the fragrance | flavors 13-19 are mentioned later.

[Reference Example 1, Comparative Example 1] Sensory evaluation of fragrance of composition A fragrance 1 having the composition shown in Table 2 was prepared, a composition having the composition shown in Table 3 was prepared, and this composition was put in a cup for sensory evaluation. The sample was allowed to stand at room temperature for a whole day and night with the lid covered, and the subsequent fragrance evaluation was evaluated by five panelists according to the following criteria. As a result, the composition of the present invention showed a better scent compared to the control.
Evaluation criteria for fragrance sensory test 5: Very good 4: Slightly good 3: Normal 2: Slightly bad 1: Very bad

[Reference Examples 2, 3, Comparative Example 2] Evaluation of flavor stability A fruit mix flavor having the following formulation was prepared, juices having the composition shown in Table 4 were prepared, and stored at 40 ° C. for 1 month immediately after pasteurization at low temperature. The flavor at the time was determined by five panelists according to the following criteria and indicated by an average score. The results are shown in Table 4. Reference Example 2 showed a good flavor stabilization effect, and Reference Example 3 showed a better effect.
Flavor stability evaluation criteria 5: Almost no change is observed.
4: A slight change is observed 3: A change is observed 2: A considerable change is observed 1: A significant change is observed
Fruit mix flavor <br/> Strawberry flavor 40.0%
Apple flavor 15.0%
Melon flavor 17.0%
Banana flavor 10.0%
Peach flavor 5.0%
Orange oil 2.5%
Raspberry flavor 2.0%
Pineapple flavor 1.5%
Grape flavor 1.0%
Tropical fruit flavor 1.5%
Milk flavor 1.0%
Grapefruit oil 0.5%
Lemon oil 0.5%
Rose oil 0.2%
Solvent balance Total 100.0%

[Reference Examples 4 to 7, Comparative Examples 3 to 6] Aroma persistence test The rinse compositions described in Tables 5 and 6 below were prepared, and 1 g of the composition was used as a human hair bundle (length of about 30 cm, weight of about 10 g). Then, the sample was thoroughly blended with a comb, rinsed in running water for 30 seconds, and then air-dried at 25 ° C. and 40% RH. The fragrance immediately after rinsing and the fragrance persistence after the lapse of 8 hours were evaluated according to the following criteria by five specialist panels, and indicated by an average score. The evaluation results are shown in Tables 5 and 6. In addition, the example using a carrying | supporting fragrance | flavor was mix | blended so that the compounding quantity of a fragrance | flavor might become the same (0.5%).
Evaluation standard for aroma stability 5: Strong fragrance 4: Slightly strong fragrance 3: Normal fragrance 2: Slightly weak fragrance 1: Weak fragrance

  Reference Examples 4 and 5 containing rosmarinic acid showed better fragrance and flavor sustainability than Comparative Examples 3 and 4. When the supported fragrance was used, a better fragrance and flavor persistence were exhibited.

[Example 1, Reference Examples 8 and 9, Comparative Examples 7 to 10]
A composition having the composition shown in Table 7 was prepared, and the occurrence of split ends and the touch were evaluated by the following methods using hair subjected to perm and bleach treatment. The results are also shown in Table 7.
Evaluation method (1) Rate of occurrence of split ends Each agent was applied to a bundle of hair bundled with 200 hairs damaged by perm and bleach treatment, dried, and the branches generated when brushing was performed 5000 times immediately after drying and after 1 week. The number of hairs was counted, the split end index was calculated, and evaluated based on the following evaluation criteria. In addition, Table 8 shows the composition of the fragrance A in the table.
Rate of occurrence of split ends (%) = (number of split ends / 200) × 100
Split end index = (rate of split ends after use / rate of split ends before use) x 100
◎: Split hair generation index is less than 40 ○: Split hair generation index is 40 to 70
Δ: Split end index is 71 to 90
×: Split hair generation index is 91 or more (2) Touch 20 panelists who have damaged hair by hair color and perm use each agent, compare the touch of hair after use with before use, Evaluation was performed based on the following evaluation criteria.
◎: 18 or more out of 20 people answered that the use was better ○: 12-17 people out of 20 answered that the use was better Δ: Answered that the use was better Things are 4-11 out of 20 people ×: Less than 4 out of 20 people answered better after use

  In addition, the composition of the fragrance composition A used in the above example is as follows.

[Reference Example 10] Hair Gel The following hair gel was prepared according to a conventional method.
Rosmarinic acid (Funakoshi Co., Ltd.) 0.5%
Hexaglyceryl monoisostearate 5.0%
Hydroxyethyl cellulose (* 1) 0.5%
Quince seed gum 0.3%
Methylsiloxane / polyoxyethylene copolymer (* 2) 2.0%
N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine
Methacrylic acid alkyl ester copolymer (* 3) 2.0%
Polyoxyethylene hydrogenated castor oil (EO40) 0.3%
Dihydroxybenzophenone 0.1%
Methylparaben 0.1%
Triethanolamine 0.5%
Fragrance A 0.2%
Ethanol 5.0%
Purified water balance
Total 100.0%
* 1: SE-900 (manufactured by Daicel Chemical Industries)
* 2: KF-6004 (manufactured by Shin-Etsu Chemical)
* 3: Yuka Former 510 (Mitsubishi Chemical Corporation)

[Reference Example 11] Hair wax The following hair wax was prepared according to a conventional method.
Crude rosmarinic acid derived from mannen wax (Preparation Example 1) 1.0%
Gallic acid-3,5-diglucoside 0.3%
Decaglyceryl diisostearate 5.0%
Carboxy vinyl polymer (* 1) 0.5%
Xanthan gum 0.3%
Methylsiloxane / polyoxyethylene copolymer 2.0%
Vaseline 3.0%
Squalane 2.0%
Candelilla wax 1.0%
Polyoxyethylene octyldodecyl ether (EO 25) 0.3%
Polyoxypropylene diglyceryl ether (P.O.9) 4.0%
Dihydroxybenzophenone 0.1%
Propylparaben 0.1%
Methylparaben 0.3%
Phenoxyethanol 0.5%
Edetate tetrasodium 0.05%
Triethanolamine 0.5%
Fragrance A 0.2%
Purified water balance
Total 100.0%
* 1: Carbopol 940 (Goodrich)

[Reference Example 12] Hair Cream A hair cream having the following formulation was prepared according to a conventional method.
Mannen wax-derived semi-purified rosmarinic acid (Preparation Example 2) 0.3%
Hydrolyzed silk solution (* 1) 0.2%
Hexaglyceryl tristearate 3.0%
Alkyl-modified carboxyvinyl polymer (* 2) 0.4%
Karaya gum 0.1%
Methylsiloxane / polyoxyethylene copolymer 0.5%
Methyl polysiloxane (100,000 mm ² / s) 5.0%
Liquid paraffin 5.0%
Paraffin wax (melting point 70 ° C) 3.0%
Polyoxyethylene hydrogenated castor oil (EO40) 2.0%
3-methyl-1,3-butanediol 10.0%
Dihydroxybenzophenone 0.1%
Propylparaben 0.1%
Methylparaben 0.3%
Phenoxyethanol 0.5%
Palm oil fatty acid sorbitan 2.0%
Glycerol monostearate 1.0%
Propylene glycol monostearate 2.0%
Triethanolamine 0.5%
Fragrance B 0.2%
Purified water balance
Total 100.0%
* 1: Promois SILK700SIG (manufactured by Seiwa Kasei Co., Ltd.)
* 2: Carbopol 1342 (Goodrich)

[Reference Example 13] Hair Foam A hair foam having the formulation shown below was prepared according to a conventional method.
Crude rosmarinic acid derived from mannen wax (Preparation Example 1) 2.0%
N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-
Methylcarboxybetaine / methacrylic acid alkyl ester copolymer (* 1) 1.0%
Amino-modified silicone (* 2) 0.5%
3-methyl-1,3-butanediol 2.0%
Squalane 0.1%
Stearyltrimethylammonium chloride 0.5%
Methylparaben 0.3%
Triethanolamine 0.1%
Fragrance A 0.1%
Ethanol 20.0%
Liquefied petroleum gas 7.0%
Purified water balance
Total 100.0%
* 1: Yuka Former 204WL (Mitsubishi Chemical Corporation)
* 2: SM8704C (manufactured by Toray Dow Corning Silicone)

[Reference Example 14] Hair foam The following hair foam was prepared according to a conventional method.
Rosmarinic acid (Funakoshi Co., Ltd.) 1.0%
Methyl polysiloxane (30mm ² / s) 5.0%
Polyether-modified silicone (* 1) 0.5%
3-methyl-1,3-butanediol 2.0%
Cationized cellulose 0.1%
N-coconut oil fatty acid-L-glutamic acid 0.5%
Polyoxyethylene hydrogenated castor oil (EO40) 0.4%
Methylparaben 0.3%
Citric acid 0.1%
Fragrance A 0.1%
Ethanol 20.0%
Liquefied petroleum gas 7.0%
Purified water balance
Total 100.0%
* 1: SH200C-30cs (Toray Dow Corning Silicone)

[Reference Example 15] Hair spray The hair spray shown below was prepared according to a conventional method.
Mannen wax derived semi-purified rosmarinic acid (Preparation Example 2) 0.5%
Vinylpyrrolidone (K30) 2.0%
Polyglycerin fatty acid ester 3.0%
Polyoxyethylene-modified silicone (* 1) 0.5%
Polyoxyethylene hydrogenated castor oil (EO40) 0.5%
Methylparaben 0.3%
Fragrance B 0.1%
Ethanol remainder
Total 100.0%
50% of the above stock solution
Liquefied petroleum gas 30%
Dimethyl ether 20%
Total 100.0%
* 1: KF6011 (manufactured by Shin-Etsu Silicone)

[Reference Example 16] Hair Water Hair water shown below was prepared according to a conventional method.
Crude rosmarinic acid derived from mannen wax (Preparation Example 1) 1.0%
Gluconic acid 1.0%
Polyether-modified silicone (* 1) 0.5%
3-methyl-1,3-butanediol 2.0%
Stearyltrimethylammonium chloride 0.5%
Methyl polysiloxane 3.0%
Polyoxyethylene lauryl ether 0.4%
Lauryldimethylamine oxide 0.2%
Sodium pyrrolidonecarboxylate 1.0%
Methylparaben 0.3%
Sodium citrate 0.1%
Hydroxymethoxybenzophenonesulfonic acid 0.1%
Fragrance A 0.1%
Ethanol 20.0%
Purified water balance
Total 100.0%
* 1: KF6012 (Shin-Etsu Chemical Co., Ltd.)

  In addition, the fragrance | flavor composition A and B used in the said example is a composition shown above.

  Also in the above Reference Examples 10 to 16, when the occurrence of split ends and the touch of hair were evaluated in the same manner as in Example 1 and Reference Examples 8 and 9, the split ends were reduced and the touch of hair was improved. It was to be done.

[Reference Examples 17 and 18] Shampoos Shampoos having the formulations shown below were prepared according to a conventional method. The pH of the shampoo is in the range of 3 to 7.5.

[Reference Examples 19 to 21] Cleaning agents Cleaning agents having the following formulations were prepared according to a conventional method.

[Reference Example 22] Clothing pretreatment agent for clothing A pretreatment agent for clothing of the following formulation was prepared according to a conventional method.
Sodium alkyl sulfate (C12-C14) 20%
Soap 5%
Sodium citrate 1%
Tripolyphosphoric acid 1%
Diethanolamine 2%
Trialkylene glycol monobutyl ether 1%
Rosmarinic acid (Funakoshi Co., Ltd.) 0.2%
Fragrance 14 0.2%
Purified water balance
Total 100%

  In addition, the composition of the fragrance | flavor compositions 13 and 14 used in the said example is as follows.

[Reference Examples 23 to 26] Rinse A rinse of the following formulation was prepared according to a conventional method.

[Reference Examples 27 and 28] Softener A softener having the formulation shown below was prepared according to a conventional method.

  In addition, the composition of the fragrance | flavor compositions 15 and 16 used in the said example is as follows.

[Reference Example 29] Hair growth material A hair growth material having the formulation shown below was prepared according to a conventional method.

  The composition of the fragrance composition 12 used in the above example is as follows.

[Reference Examples 30 and 31] Bleaching agents Bleaching agents having the following formulation were prepared according to a conventional method.

  In addition, the composition of the fragrance composition 18 used in the above example is as follows.

[Reference Examples 32 and 33] Bleaching agents Bleaching agents having the formulations shown below were prepared according to a conventional method.

  The composition of the fragrance composition 19 used in the above example is as follows.

Claims (2)

  A rosmarinic acid-containing composition for hair treatment that has been treated with hair color, hair bleach or perm, comprising rosmarinic acid, a cationic surfactant, and a gallic acid glycosylated product.   The content of rosmarinic acid is 0.01 to 20% by mass, the content of the cationic surfactant is 0.01 to 5% by mass, and the content of the gallic acid glycoside is 0.01 to 10% by mass. The rosmarinic acid-containing composition according to claim 1.