KR100927969B1 - Perfume composition that reproduces the scent of lilies using natural lily fragrance - Google Patents

Abstract

The present invention relates to a perfume composition reproducing a lily scent, and in detail, based on the component analyzed as a odor component of a lily by solid phase micro extraction (SPME) -headspace method (Linalool) , Geraniol, Phenyl ethyl alcohol, Benzyl acetate, Hedione, etc. may be appropriately combined, and lily fragrance extract is extracted from the lily flower through solvent extraction. The present invention relates to a fragrance composition having excellent palatability while reproducing the natural fragrance of lilies by using the purified natural lily fragrance.

As a result, by reproducing the fragrance of lilies similar to natural fragrances in the perfume industry, where the expensive demand by the limited supply of natural fragrance raw materials has been limited, it has the effect of contributing to the industrial development of the fragrance sector by increasing the demand for fragrances at low prices. It is expected.

Lily, lily, natural fragrance, fragrance composition

Description

Aromatic Composition Reproduced Fragrance of a Lily Using A Natural Lilies Flavoring}

The present invention relates to a fragrance composition for reproducing the scent of the lily ( Lilium longiflorum Thunb ).

About 100 species of lilies grow wild in Asia, Europe, and North America, and about 10 of them grow wild in Korea. Lilies have many varieties and varieties, and because of their variety of colors and fragrances, they are favored for both East and West. Especially, oriental lilies, which are popular in Japan, have recently been spotlighted as export trees.

Lily is a perennial plant that is cultivated all over the country. Its leaves are not petioles, lanceolate, 10-18cm long, 5-15mm wide, without hairs. Flowers bloom in May-June, with 2-3 side ends at the end of main stem, long tube, trumpet-shaped, and fragrant.

Natural distillation methods include steam distillation, solvent extraction, headspace, and solid phase micro extraction (hereinafter referred to as "SPME"). have.

Steam distillation has the advantage of being economical and can be extracted in large quantities. However, the original flavor of the plant can be altered due to the application of heat, and the solvent extraction method uses a solvent such as nucleic acid, which can result in a secondary reaction between the fragrance and the solvent. It is suitable for extracting the fragrance of delicate flowers because it is not added. The SPME method is useful for fragrance analysis because it does not use solvents, does not require pretreatment, and can be quickly and simply analyzed. Recently, the supercritical extraction method extracted at low temperature using CO ₂ gas has been developed to obtain a high-quality, high-quality fragrance, but there is a disadvantage in that the cost is expensive.

The inventors attempted to reproduce the scent of the lily using the SPME-headspace (headspace) method, which is effective for extracting the scent of the plant. Ocimene, Linalool, Geraniol, Phenyl ethyl alcohol and Benzyl acetate were found to be the main components of lily fragrance. The fragrance of lilies was reproduced using synthetic fragrances similar to the main ingredients of. However, as a result of sensory examination with lily fragrance steered with such synthetic fragrance, the natural feeling was less, and the actual lily fragrance could not be reproduced.

Thus, the present inventors have been able to reproduce the natural lily scent by adding a proper amount of lily scent extract obtained by solvent extraction from lilies in order to give more natural feeling to the flavor scented with a synthetic fragrance has come to complete the present invention.

It is therefore an object of the present invention to reproduce the intrinsic odor of lilies and to provide a perfume composition having a good odor. Another object of the present invention is to provide a perfume product (shower cologne) as a component of the fragrance composition, and to enable the cultivation of lilies to contribute to the increase of industrial activation in this field.

As described above, the fragrance composition according to the present invention is based on the fragrance component analyzed by the SPME-headspace method, Linalol, Geraniol, and Phenyl ethyl. Alcohol), benzyl acetate and Hedione are the main components of the lily scent, and by containing additional lily scent extract, it was possible to reproduce the lily scent and increase the preference of the scent.

In addition, the cultivation of the scented lily is activated by the present invention as well as the income of the lily cultivator can be increased according to the improvement of the added value, when developed as a special product is expected to attract tourists.

In the meantime, by reproducing the fragrance of lily which is the same as natural fragrance in the fragrance industry, where the expensive demand by limited natural fragrance raw material supply is limited, it is expected to increase the popular fragrance demand of low price and contribute greatly to the development of fragrance industry. do.

In order to achieve the above object, the present invention is a linalool (linalool), geraniol (geraniol), hedione (hedione), phenyl ethyl alcohol, benzyl acetate (benzyl acetate) and lily fragrance It provides a fragrance composition characterized in that it contains an extract.

It is the first time that the present invention extracts natural fragrance from a lily flower.

According to a preferred embodiment of the present invention, 10 to 15% by weight of the linarol, 15 to 20% by weight of the geraniol, 6 to 10% by weight of the hedione, 5 to the phenylethyl alcohol with respect to 100% by weight of the total composition 10% by weight, 5-10% by weight of the benzyl acetate and 3-5% by weight of the lily fragrance extract are provided.

In addition, 7-15 wt% citrononeol, 10-15 wt% musk tea, 1-3 wt% floral ozone, 1-5 wt% rialral, 2-5 wt% lismeral, 1-5 muscenon 3% by weight, 1 to 5% by weight ethylinalol, 2 to 5% by weight lemon south african oil, 5 to 7% by weight helvitolide, 3 to 5% by weight fluorosa and 0.1 to 1% by weight of neroliol It provides a fragrance composition characterized in that it contains.

The composition according to the present invention can reproduce the intrinsic fragrance of the lily by containing the lily fragrance extract extracted by the solvent extraction method as an essential component in the lily fragrance component analyzed by the headspace, it can exhibit excellent palatability.

Lily fragrance extract of the present invention is a component extracted from a lily flower using an extraction solvent selected from the group consisting of alcohol, ether, diethyl ether and nucleic acid, preferably a component extracted using a nucleic acid as an extraction solvent.

As the main ingredient that reproduces the scent of lilies, it is not preferable because the content of linarol, geraniol, hedione, phenylethyl alcohol, benzyl acetate, and lily scent extract is lower in similarity to the scent of lilies and lowers the palatability of the scent. not.

The composition according to the present invention mixed in the above range can be blended into perfume (shower cologne) and cosmetics (emulsion, cream, toner, etc.) and the blending amount can be appropriately selected and blended to achieve the desired effect and odor. .

SPME-headspace method was used as an analysis method for the lily odor component used in the present invention. In order to analyze the natural odor, the odor was adsorbed directly on the SPME fiber and analyzed using GC / MSD. This method extracts the fragrance at room temperature without special pretreatment and analyzes it in a short time, so there is no secondary by-product caused by heat, which is advantageous for analyzing the fragrance of delicate flowers.

In the present invention, the fragrance was combined based on the fragrance component of the lily analyzed by SPME-headspace method, and the sensory test was performed to determine the palatability of the fragrance.

Example 1.Fragrance Analysis of Lilies Using the SPME Headspace Method

In order to capture the fragrance component of the strong pink lily (Lurev), the flower was put on a zipper bag, the fibers (PDNS / DVB fiber) were fixed, and the incense was collected for about 1 hour. The collecting site is the lily festival in Taean-gun, Chungnam. The temperature was 28 ℃ and there was no wind.

After collecting the odor component, the fiber (Fiber) was sealed and stored in an ice box and transferred to a laboratory for analysis.

The fragrance adsorbed fiber (Fiber) was transferred to the inlet of GC-MSD, and then desorbed for 1 minute and subjected to GC-MS analysis. GC-MSD conditions are as follows.

Analysis condition Analyzer: AGILENT 6890/5973 GC / MSD Column: Innowax (60m * 0.32mm * 0.5㎛ Carrier gas: He Injection Temperature: 260 ℃ Oven Tempertature: 85 ℃ ~ 230 ℃ (2 ℃ / min) Desorption time: 1min

The fragrance components of lilies (Lureb) analyzed by SPME-headspace method are as follows.

ingredient Content (% by weight) Ocimene 11.25 Benzyl acetate 10.78 Phenylethyl alcohol 10.11 Linarol 7.56 Methylbenzoate 5.13 Geraniol 3.88 Eugenol 2.88 Creosol 2.70 Nonal 1.16 Mykene 0.29 Decanal 0.28 Ethylbenzoate 0.25 Methyl nonyl ketone 0.21 Etc 43.52 Total amount 100.00

As shown in Table 2, lilies are composed of acetonitrile, benzyl acetate, phenylethyl alcohol, linalol, methyl benzoate, geraniol and eugenol as main odorants, and these main components contain 51.59% by weight of the total. Doing.

Example 2. Perfume Combination Based on Analysis Results

Combination perfume (A) was made based on the analysis results. As shown in Reference Example 1, the lily contains a large amount of phenylethyl alcohol, and the actual scent also has a similar scent reminiscent of the pure rose natural scent. In consideration of the image of clear and clean lilies, we added lismeral, riral, citronol and floral ozone, flor irradiation, and parenal, which are used for the combination of lily of the valley. Lemon South African oil and ethyl rinarol were added to increase freshness and not monotonous. Helvetide and musk tea were used to give base notes a clean feeling.

Composition of Combination Fragrance (A) ingredient Content (% by weight) Linarol 14.8 Benzyl acetate 10.6 Tronelellol 10.6 Phenylethyl alcohol 4.0 Geraniol 16.0 Floral Ozone 1.1 Rural 5.3 Lismeral 2.9 Muskti 10.6 Mussenon 1.3 Freilsiol 0.3 Farenal 0.3 Lemon South African Oil 2.7 Ethylrinalol 4.0 Hedion 6.7 Helvetolide 5.3 Florosa 3.2 Neroliil 0.3 total 100

Example 3 Sensory Evaluation of Perfume Prepared Based on the Analysis

Shower cologne was prepared according to the composition of Table 4 using the combination perfume (A) combined according to the method of Example 2, and the sensory evaluation was carried out for the general public. The sensory evaluation was conducted on 15 men and women aged 25 to 45 years, using a shower cologne that reproduces the scent of lilies and responded to the questionnaire of Table 5 below. The results are shown in Table 6.

Shower cologne containing a fragrance composition that reproduces the scent of lilies (content: weight%) Combination Spices (A) 4 Alcohol 84 Purified water 9 Propylene glycol 3 Sunscreen Quantity Pigment Quantity

survey This shower cologne is a shower cologne that reproduces the smell of lilies. Sprinkle lightly over your body as you normally would with a shower cologne. Question 1) How similar do you think the smell of this shower cologne is to the lilies? ① Not at all similar. ② Not very similar. ③ Just like that. ④ Slightly similar. ⑤ Quite similar. Question 2) How much do you like the smell of this shower cologne? ① Not good at all. ② not very good. ③ Just like that. ④ Good. ⑤ Quite good. Question 3) If you don't like the smell, please briefly explain why.

rater Question 1) Question 2) One 2 3 2 2 4 3 One 3 4 2 3 5 2 3 6 4 4 7 2 2 8 2 3 9 2 4 10 2 3 11 2 5 12 3 2 13 2 One 14 2 4 15 3 2 Average 2.2 3.07

As shown in Table 6, the combination fragrance (A) that reproduced the lily scent was found to be different from the scent of the lily, and the preference was also not so high.

Example 4 Preparation and Sensory Evaluation of Fragrance-Enhancing Perfume Containing Lily Fragrance Extract

Sensory tests performed by a professional steeringman showed that the fragrance composition, which reproduced the lily scent, was coarse and irritating. Synthetic fragrance alone was not able to obtain the soft and rich aroma of natural lilies, so a combination perfume (B) was added to which the lily fragrance extract (Lily ab) in Table 7 was added. Lily extract was extracted by a method commonly known in the art using a nucleic acid as the extraction solvent. When more than 6% by weight of lily extract is added, the strength of the fragrance is too strong, the balance of the whole aroma is not balanced, and when used below 3% by weight, the fragrance of the lily did not survive well. When 4% by weight of lily extract was used, the balance, persistence, and diffusion of the overall aroma were improved and abundant lily aroma could be felt.

Combination Spices (B) Fragrance content Linarol 12 Benzyl acetate 10 Citronol 10 Phenylethyl acetate 4.0 Geraniol 16.0 Floral Ozone 1.1 Rural 5.3 Lismeral 2.9 Muskti 10.6 Mussenon 1.3 Freilsiol 0.3 Farenal 0.3 Lemon South African Oil 2.7 Ethylrinalol 4.0 Hedion 6.7 Helvetolide 5.3 Florosa 3.2 Neroliil 0.3 Lily aroma extract (Lily ab.) 4.0 total 100

Combination fragrance (B) containing lily fragrance extract was made and subjected to comparative sensory evaluation with the combination fragrance (A). As above, shower cologne was made to evaluate the scent. The survey results are shown below.

survey Try using shower cologne and answer the following survey.  Question 1) Which of A and B do you think has a stronger lily image? ① A ② B Question 2) How much do you like the smell of B? ① Not good at all. ② not very good. ③ Just like that. ④ Good. ⑤ Quite good.

rater Question 1) Question 2) One B 3 2 B 2 3 A 5 4 B 4 5 B 2 6 B 3 7 B 4 8 B 4 9 A 3 10 A 4 11 B 4 12 B 3 13 A 4 14 B 3 15 B 4 A: 4 / B: 11 3.46

As shown in the survey results, the combination perfume (B) with the addition of lily fragrance extract showed a stronger image of the lily and a higher preference for fragrance.

Claims (5)

Linalool 10-15 wt%, Geraniol 15-20 wt%, Hedione 6-10 wt%, Phenyl ethyl alcohol 5 -10 wt%, Benzyl Acetate (Benzyl acetate) containing 5 to 10% by weight and lily fragrance extract containing 3 to 5% by weight of the perfume composition to reproduce the smell of lilies. delete The fragrance composition of claim 1, wherein the lily fragrance extract is extracted from a lily flower using an extractant selected from the group consisting of alcohols, ethers, diethyl ether and nucleic acids. According to claim 1, wherein the ingredients are 7-15% citrononeol, 10-15% musk tea, 1-3% floral ozone, 1-5% lyral, 2-5% lismeral, 1 to 3 weight percent of musenone, 1 to 5 weight percent of ethylinalol, 2 to 5 weight percent of lemon south african oil, 5 to 7 weight percent of helbetolide, 3 to 5 weight percent of florosa and 0.1 to 1 weight of neroliol Perfume composition further comprises at least one component selected from the group consisting of%. A perfume product comprising the perfume composition according to any one of claims 1, 3 and 4.