CN110157493A - 一种绿色环保的生物柴油及其制备方法 - Google Patents

一种绿色环保的生物柴油及其制备方法 Download PDF

Info

Publication number
CN110157493A
CN110157493A CN201810252599.6A CN201810252599A CN110157493A CN 110157493 A CN110157493 A CN 110157493A CN 201810252599 A CN201810252599 A CN 201810252599A CN 110157493 A CN110157493 A CN 110157493A
Authority
CN
China
Prior art keywords
parts
biodiesel
added
antioxidant
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810252599.6A
Other languages
English (en)
Inventor
闵韻书
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810252599.6A priority Critical patent/CN110157493A/zh
Publication of CN110157493A publication Critical patent/CN110157493A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1216—Inorganic compounds metal compounds, e.g. hydrides, carbides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1275—Inorganic compounds sulfur, tellurium, selenium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1283—Inorganic compounds phosphorus, arsenicum, antimonium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Fats And Perfumes (AREA)

Abstract

本发明公开了一种绿色环保的生物柴油及其制备方法，生物柴油组分按重量份数包括大豆油20‑40份、椰子油20‑50份、硅酸钠10‑20份、甲醇5‑15份、单硬脂酸甘油酯4‑12份、皂用脂肪酸5‑15份、纳米二氧化钛1‑4份、硫磷双辛基碱性锌盐6‑16份、抗氧化剂1‑5份、环已胺4‑10份、环烷酸5‑10份、邻苯二甲酸二乙酯8‑12份、过氧化锌2‑8份，本发明制备方法简单，制得得生物柴油环保性能好，具有优异的润滑性能号环保性能。

Description

一种绿色环保的生物柴油及其制备方法
技术领域
本发明涉及生物柴油制备技术领域，具体为一种绿色环保的生物柴油及其制备方法。
背景技术
生物柴油又称为生质柴油，是用未加工过的或者使用过的植物油以及动物脂肪通过不同的化学反应制备出来的一种被认为是环保的生质燃料。这种生物燃料可以像柴油一样使用。但环保性能比柴油好很多，硫含量低，二氧化硫和硫化物的排放低、生物柴油的生物降解性高达98％，降解速率是普通柴油的2倍，可大大减轻意外泄漏时对环境的污染。但是，目前生产生物柴油的配方和工艺较复杂，且环保性能差。
发明内容
本发明的目的在于提供一种绿色环保的生物柴油及其制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种绿色环保的生物柴油,生物柴油组分按重量份数包括大豆油20-40份、椰子油20-50份、硅酸钠10-20份、甲醇5-15份、单硬脂酸甘油酯4-12份、皂用脂肪酸5-15份、纳米二氧化钛1-4份、硫磷双辛基碱性锌盐6-16份、抗氧化剂1-5份、环已胺4-10份、环烷酸5-10份、邻苯二甲酸二乙酯8-12份、过氧化锌2-8份。
优选的，生物柴油组分优选的成分配比包括大豆油30份、椰子油35份、硅酸钠15份、甲醇10份、单硬脂酸甘油酯8份、皂用脂肪酸10份、纳米二氧化钛3份、硫磷双辛基碱性锌盐11份、抗氧化剂3份、环已胺7份、环烷酸8份、邻苯二甲酸二乙酯10份、过氧化锌5份。
优选的，所述抗氧化剂由20％偏亚硫酸钠、20％三聚磷酸钠、30％柠檬酸、10％吡喃葡糖基、20％甲基麦角甾组成。
优选的，其制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为200-400转/分，搅拌时间为12min-24min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为50℃-70℃，加热时间为10min-30min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
与现有技术相比，本发明的有益效果是：本发明制备方法简单，制得得生物柴油环保性能好，具有优异的润滑性能号环保性能；其中，添加的纳米二氧化钛、硫磷双辛基碱性锌盐能够起到防腐的作用，添加的抗氧化剂具有优异的抗氧化性能，有效的防止柴油氧化；此外，本发明采用的制备方法制作成本低，能够确保各组分材料充分混合，提高了柴油的活性。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供如下技术方案：一种绿色环保的生物柴油,生物柴油组分按重量份数包括大豆油20-40份、椰子油20-50份、硅酸钠10-20份、甲醇5-15份、单硬脂酸甘油酯4-12份、皂用脂肪酸5-15份、纳米二氧化钛1-4份、硫磷双辛基碱性锌盐6-16份、抗氧化剂1-5份、环已胺4-10份、环烷酸5-10份、邻苯二甲酸二乙酯8-12份、过氧化锌2-8份；其中，抗氧化剂由20％偏亚硫酸钠、20％三聚磷酸钠、30％柠檬酸、10％吡喃葡糖基、20％甲基麦角甾组成。
实施例一：
生物柴油组分按重量份数包括大豆油20份、椰子油20份、硅酸钠10份、甲醇5份、单硬脂酸甘油酯4份、皂用脂肪酸5份、纳米二氧化钛1份、硫磷双辛基碱性锌盐6份、抗氧化剂1份、环已胺4份、环烷酸5份、邻苯二甲酸二乙酯8份、过氧化锌2份。
本实施例的制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为200转/分，搅拌时间为12min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为50℃，加热时间为10min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
实施例二：
生物柴油组分按重量份数包括大豆油40份、椰子油50份、硅酸钠20份、甲醇15份、单硬脂酸甘油酯12份、皂用脂肪酸15份、纳米二氧化钛4份、硫磷双辛基碱性锌盐16份、抗氧化剂5份、环已胺10份、环烷酸10份、邻苯二甲酸二乙酯12份、过氧化锌8份。
本实施例的制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为400转/分，搅拌时间为24min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度70℃，加热时间为30min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
实施例三：
生物柴油组分按重量份数包括大豆油25份、椰子油25份、硅酸钠12份、甲醇6份、单硬脂酸甘油酯6份、皂用脂肪酸7份、纳米二氧化钛2份、硫磷双辛基碱性锌盐8份、抗氧化剂2份、环已胺5份、环烷酸6份、邻苯二甲酸二乙酯9份、过氧化锌3份。
本实施例的制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为250转/分，搅拌时间为14min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为55℃，加热时间为15min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
实施例四：
生物柴油组分按重量份数包括大豆油35份、椰子油45份、硅酸钠18份、甲醇13份、单硬脂酸甘油酯10份、皂用脂肪酸12份、纳米二氧化钛3份、硫磷双辛基碱性锌盐14份、抗氧化剂4份、环已胺9份、环烷酸9份、邻苯二甲酸二乙酯10份、过氧化锌7份。
本实施例的制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为350转/分，搅拌时间为20min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为65℃，加热时间为25min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
实施例五：
生物柴油组分按重量份数包括大豆油30份、椰子油35份、硅酸钠15份、甲醇10份、单硬脂酸甘油酯8份、皂用脂肪酸10份、纳米二氧化钛3份、硫磷双辛基碱性锌盐11份、抗氧化剂3份、环已胺7份、环烷酸8份、邻苯二甲酸二乙酯10份、过氧化锌5份。
本实施例的制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为300转/分，搅拌时间为18min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为60℃，加热时间为20min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
本发明制备方法简单，制得得生物柴油环保性能好，具有优异的润滑性能号环保性能；其中，添加的纳米二氧化钛、硫磷双辛基碱性锌盐能够起到防腐的作用，添加的抗氧化剂具有优异的抗氧化性能，有效的防止柴油氧化；此外，本发明采用的制备方法制作成本低，能够确保各组分材料充分混合，提高了柴油的活性。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (4)

1.一种绿色环保的生物柴油,其特征在于：生物柴油组分按重量份数包括大豆油20-40份、椰子油20-50份、硅酸钠10-20份、甲醇5-15份、单硬脂酸甘油酯4-12份、皂用脂肪酸5-15份、纳米二氧化钛1-4份、硫磷双辛基碱性锌盐6-16份、抗氧化剂1-5份、环已胺4-10份、环烷酸5-10份、邻苯二甲酸二乙酯8-12份、过氧化锌2-8份。
2.根据权利要求1所述的一种绿色环保的生物柴油,其特征在于：生物柴油组分优选的成分配比包括大豆油30份、椰子油35份、硅酸钠15份、甲醇10份、单硬脂酸甘油酯8份、皂用脂肪酸10份、纳米二氧化钛3份、硫磷双辛基碱性锌盐11份、抗氧化剂3份、环已胺7份、环烷酸8份、邻苯二甲酸二乙酯10份、过氧化锌5份。
3.根据权利要求1或2所述的一种绿色环保的生物柴油,其特征在于：所述抗氧化剂由20％偏亚硫酸钠、20％三聚磷酸钠、30％柠檬酸、10％吡喃葡糖基、20％甲基麦角甾组成。
4.实现权利要求1或2所述的一种绿色环保的生物柴油的制备方法,其特征在于：其制备方法包括以下步骤：
A、将大豆油、椰子油、硅酸钠、甲醇、单硬脂酸甘油酯、皂用脂肪酸混合后加入搅拌罐中低速搅拌，搅拌速率为200-400转/分，搅拌时间为12min-24min，得到混合物A；
B、将纳米二氧化钛、硫磷双辛基碱性锌盐、抗氧化剂、环已胺、环烷酸、邻苯二甲酸二乙酯、过氧化锌混合后加入反应釜中加热反应，加热温度为50℃-70℃，加热时间为10min-30min，之后缓慢冷却至室温，得到混合物B；
C、将混合物A加入混合物B中，之后加入混炼机中混炼，混炼温度为80℃，时间为30min，即得到生物柴油。
CN201810252599.6A 2018-03-26 2018-03-26 一种绿色环保的生物柴油及其制备方法 Pending CN110157493A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810252599.6A CN110157493A (zh) 2018-03-26 2018-03-26 一种绿色环保的生物柴油及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810252599.6A CN110157493A (zh) 2018-03-26 2018-03-26 一种绿色环保的生物柴油及其制备方法

Publications (1)

Publication Number Publication Date
CN110157493A true CN110157493A (zh) 2019-08-23

Family

ID=67636033

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810252599.6A Pending CN110157493A (zh) 2018-03-26 2018-03-26 一种绿色环保的生物柴油及其制备方法

Country Status (1)

Country Link
CN (1) CN110157493A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245269A (zh) * 2008-04-01 2008-08-20 李国钦 一种植物干馏制取生物柴油及其制备方法
CN102634386A (zh) * 2011-02-12 2012-08-15 湖南红宝科技开发有限公司 化合柴油
CN104232180A (zh) * 2014-10-17 2014-12-24 广西丰泰能源防爆科技有限公司 甲醇柴油
CN105950300A (zh) * 2016-06-28 2016-09-21 刘昱伶 生物柴油
CN107245379A (zh) * 2017-06-27 2017-10-13 合肥市老海新材料有限公司 一种高性能强稳定性生物合成柴油及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245269A (zh) * 2008-04-01 2008-08-20 李国钦 一种植物干馏制取生物柴油及其制备方法
CN102634386A (zh) * 2011-02-12 2012-08-15 湖南红宝科技开发有限公司 化合柴油
CN104232180A (zh) * 2014-10-17 2014-12-24 广西丰泰能源防爆科技有限公司 甲醇柴油
CN105950300A (zh) * 2016-06-28 2016-09-21 刘昱伶 生物柴油
CN107245379A (zh) * 2017-06-27 2017-10-13 合肥市老海新材料有限公司 一种高性能强稳定性生物合成柴油及其制备方法

Similar Documents

Publication Publication Date Title
CN101955854B (zh) 水基型飞机表面清洗剂及其制备方法
CN101947410A (zh) 石灰石粉活性激发剂
CN110157493A (zh) 一种绿色环保的生物柴油及其制备方法
CN102304408B (zh) 一种煤炭纳米助燃剂、制备方法及装置
CN101153149A (zh) 超强光催化降解抗菌环保涂料制备方法
CN103102808A (zh) 一种沥青氯丁橡胶涂料
CN102827665A (zh) 节煤脱硫助燃剂及其制备方法
CN103320207A (zh) 新型混凝土构件脱模剂的制备方法
CN104045487B (zh) 一种含有磷石膏的环保复合包膜肥料及其制备方法
CN102504896A (zh) 一种采用微生物菌剂制备乳化重油的方法
CN102876403A (zh) 新能源车用醇醚柴油
CN103627448B (zh) 一种液体清洁环保柴油及其制备方法
CN103571547A (zh) 一种制备乙醇-柴油混合燃料的方法
CN106700331A (zh) 一种pvc锌基热稳定剂
CN102899101A (zh) 甲醇汽油
CN103911185B (zh) 一种甲基汽油及其生产方法
CN106118796B (zh) 一种利用化工副产物制备煤基醇醚燃料助剂的方法
CN107164001A (zh) 一种复合乳化剂及其制备方法
CN106243420A (zh) 一种抗氧化橡胶材料
CN101328426B (zh) 一种乳化重油组合物
CN102134518B (zh) 沼浆混成燃料制备方法
CN108912458A (zh) 一种环保型超高分子量聚乙烯过滤材料的制备方法
CN103740416A (zh) 一种生物酶改性的环保型燃料
CN101838562B (zh) 一种调合型生物柴油及其制备方法
CN103333734A (zh) 新型混凝土模板脱模剂的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190823