CN109957220A - 一种金属板覆膜用的pet薄膜料 - Google Patents

一种金属板覆膜用的pet薄膜料 Download PDF

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CN109957220A
CN109957220A CN201711499986.1A CN201711499986A CN109957220A CN 109957220 A CN109957220 A CN 109957220A CN 201711499986 A CN201711499986 A CN 201711499986A CN 109957220 A CN109957220 A CN 109957220A
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metal plate
antioxidant
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film material
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何永娜
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Tianjin Grace Technology Co Ltd
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    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
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    • C08J2405/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • C08J2405/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/16—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
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Abstract

本发明公开的一种金属板覆膜用的PET薄膜料，它包括以下重量组分：PET：100份；EVA：10‑15份；玻璃纤维：5‑10份；甲基丙烯酸甲酯：4‑7份；硅微粉：3‑5份；聚碳硅烷：1‑4份；石墨粉：2‑5份：氧化镍：4‑5份；氢氧化镁：7‑12份；聚乳酸：3‑5份；壳聚糖：6‑8份；聚异丁烯基丁二酰亚胺：2‑3份：硅烷偶联剂：1‑4份；抗冲击改性剂：4‑7份；抗氧化剂：1‑2份；稳定剂：1‑2份；抗静电剂：0.5‑1.5份；增塑剂：4‑7份；钛白粉：2‑4份；石蜡：1‑3份，所述硅烷偶联剂为3‑氨丙基三乙氧基硅烷，所述抗冲击改性剂为甲基丙烯酸酯‑丁二烯一苯乙烯共聚物，所述抗氧化剂为抗氧剂DNP。

Description

一种金属板覆膜用的PET薄膜料
技术领域
本发明涉及涉及一种金属板覆膜用的PET薄膜料。
背景技术
金属板覆膜技术是把塑料膜和金属板通过高温热压，将膜贴在金属板上的加工技术。覆膜技术在1977年诞生于日本，最初用于制罐，可代替内涂、外涂技术，到现在为止已发展到了建材内装、家电外壳、船舶内装等多种领域，PET，聚对苯二甲酸乙二醇酯，是一种环保型工程塑料，由于其具有较好的物理机械性能、耐油性能等，因此，被广泛的应用于覆膜铁行业，随着社会的不断进步，人们对覆膜铁的质量要求越来越高，而其表面复合的薄膜质量也是影响覆膜铁质量的一个关键因素。由于覆膜铁的广泛应用，因此，对塑料薄膜的应用性能要求也越来越多，对其防腐蚀性、耐高温性、阻燃性、抗菌性等性能的要求也越发的明显。而目前，市场上的PET塑料薄膜，其性能方面还存在一些缺陷，为了适应市。
发明内容
本发明所要解决的技术问题是提供一种金属板覆膜用的PET薄膜料，它包括以下重量组分：PET：100份；EVA：10-15份；玻璃纤维：5-10份；甲基丙烯酸甲酯：4-7份；硅微粉：3-5份；聚碳硅烷：1-4份；石墨粉：2-5份：氧化镍：4-5份；氢氧化镁：7-12份；聚乳酸：3-5份；壳聚糖：6-8份；聚异丁烯基丁二酰亚胺：2-3份：硅烷偶联剂：1-4份；抗冲击改性剂：4-7份；抗氧化剂：1-2份；稳定剂：1-2份；抗静电剂：0.5-1.5份；增塑剂：4-7份；钛白粉：2-4份；石蜡：1-3份，所述硅烷偶联剂为3-氨丙基三乙氧基硅烷，所述抗冲击改性剂为甲基丙烯酸酯-丁二烯一苯乙烯共聚物，所述抗氧化剂为抗氧剂DNP。
优选的，所述稳定剂为钙锌复合稳定剂与季戊四醇重量组份比例为2∶3的混合物。
优选的，所述抗静电剂为乙氧基化C12叔烷基胺。
优选的，所述增塑剂为癸二酸二辛酯。
本发明具有的优点和积极效果是：本发明的PET塑料薄膜料，以PET为主料，同时加入了玻璃纤维、壳聚糖、阻燃剂、聚碳硅烷等试剂，使得产品的阻燃性、耐高温性、抗菌性、防腐蚀性等综合性能优越，采用该材料制备出的PET塑料薄膜可以广泛的应用于覆膜铁生产中，加入了聚乳酸和钛白粉，可以增强产品的抗紫外线性能，加入了抗氧化剂可以防止产品因氧化而老化；加入了硅微粉，增强了产品的耐低温性。
具体实施方式
下面结合实施例对本发明的具体实施方式作进一步描述，以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
本实施方式的一种金属板覆膜用的PET薄膜料，它包括以下重量组分：PET：100份；EVA：10份；玻璃纤维：5份；甲基丙烯酸甲酯：4份；硅微粉：3份；聚碳硅烷：1份；石墨粉：2份：氧化镍：4份；氢氧化镁：7份；聚乳酸：3份；壳聚糖：6份；聚异丁烯基丁二酰亚胺：2份：硅烷偶联剂：1份；抗冲击改性剂：4份；抗氧化剂：1份；稳定剂：1份；抗静电剂：0.5份；增塑剂：4份；钛白粉：2份；石蜡：1份，所述硅烷偶联剂为3-氨丙基三乙氧基硅烷，所述抗冲击改性剂为甲基丙烯酸酯-丁二烯一苯乙烯共聚物，所述抗氧化剂为抗氧剂DNP。
优选的，所述稳定剂为钙锌复合稳定剂与季戊四醇重量组份比例为2∶3的混合物。
优选的，所述抗静电剂为乙氧基化C12叔烷基胺。
优选的，所述增塑剂为癸二酸二辛酯。
本发明具有的优点和积极效果是：本发明的PET塑料薄膜料，以PET为主料，同时加入了玻璃纤维、壳聚糖、阻燃剂、聚碳硅烷等试剂，使得产品的阻燃性、耐高温性、抗菌性、防腐蚀性等综合性能优越，采用该材料制备出的PET塑料薄膜可以广泛的应用于覆膜铁生产中，加入了聚乳酸和钛白粉，可以增强产品的抗紫外线性能，加入了抗氧化剂可以防止产品因氧化而老化；加入了硅微粉，增强了产品的耐低温性。
以上对本发明的一个实施例进行了详细说明，但所述内容仅为本发明的较佳实施例，不能被认为用于限定本发明的实施范围。凡依本发明申请范围所作的均等变化与改进等，均应仍归属于本发明的专利涵盖范围之内。

Claims (4)

1.一种金属板覆膜用的PET薄膜料，其特征在于：它包括以下重量组分：PET：100份；EVA：10-15份；玻璃纤维：5-10份；甲基丙烯酸甲酯：4-7份；硅微粉：3-5份；聚碳硅烷：1-4份；石墨粉：2-5份：氧化镍：4-5份；氢氧化镁：7-12份；聚乳酸：3-5份；壳聚糖：6-8份；聚异丁烯基丁二酰亚胺：2-3份：硅烷偶联剂：1-4份；抗冲击改性剂：4-7份；抗氧化剂：1-2份；稳定剂：1-2份；抗静电剂：0.5-1.5份；增塑剂：4-7份；钛白粉：2-4份；石蜡：1-3份，所述硅烷偶联剂为3-氨丙基三乙氧基硅烷，所述抗冲击改性剂为甲基丙烯酸酯-丁二烯一苯乙烯共聚物，所述抗氧化剂为抗氧剂DNP。
2.根据权利要求1所述的一种金属板覆膜用的PET薄膜料，其特征在于：所述稳定剂为钙锌复合稳定剂与季戊四醇重量组份比例为2∶3的混合物。
3.根据权利要求1所述的一种金属板覆膜用的PET薄膜料，其特征在于：所述抗静电剂为乙氧基化C12叔烷基胺。
4.根据权利要求1所述的一种金属板覆膜用的PET薄膜料，其特征在于：所述增塑剂为癸二酸二辛酯。
CN201711499986.1A 2017-12-26 2017-12-26 一种金属板覆膜用的pet薄膜料 Pending CN109957220A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111993752A (zh) * 2020-08-26 2020-11-27 广东毅科新材料有限公司 一种木制品复合膜生产制备工艺

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111993752A (zh) * 2020-08-26 2020-11-27 广东毅科新材料有限公司 一种木制品复合膜生产制备工艺

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Application publication date: 20190702