CN109847572A - A kind of microorganism bubble liquid and its preparation method and application - Google Patents

A kind of microorganism bubble liquid and its preparation method and application Download PDF

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Publication number
CN109847572A
CN109847572A CN201811580524.7A CN201811580524A CN109847572A CN 109847572 A CN109847572 A CN 109847572A CN 201811580524 A CN201811580524 A CN 201811580524A CN 109847572 A CN109847572 A CN 109847572A
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Prior art keywords
microorganism
bubble
bubble liquid
liquid
variety
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CN201811580524.7A
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Chinese (zh)
Inventor
蔡峰
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Shenzhen Huanbao Chemical Technology Co ltd
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Shenzhen Huanbao Chemical Technology Co ltd
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Priority to CN201811580524.7A priority Critical patent/CN109847572A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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Abstract

The invention discloses a kind of microorganism bubble liquid and its preparation method and application, the microorganism bubble liquid flocks together foaming agent, moisturizer, bubble film forming agent, plant extract agent, strain etc., to merge three kinds of solvent adsorption method, microbial degradation method and plant deodorization method waste gas processing methods, different strains is selected furthermore according to different situations, some poisonous and harmful positions in water can be handled simultaneously, to realize the processing to waste water and gas.

Description

A kind of microorganism bubble liquid and its preparation method and application
Technical field
The present invention relates to field of environment protection more particularly to a kind of microorganism bubble liquid and its preparation method and application.
Background technique
Existing spray painting oil spout factory, printing house, garbage transfer station, hardware plastic cement factory, rubber plant, automobile factory etc. are produced useless Gas mostly uses active carbon adsorption, photocatalytic method, plasma method, solvent absorption etc. to be handled;These processing methods are suitable With range, investment cost, operating cost, removal effect, energy consumption, security risk, there can be respective advantage and disadvantage in terms of operational readiness, But on the whole, or there are many deficiencies place, such as active carbon adsorption effect is good, but it is more to regenerate auxiliary device;Light It is few to be catalyzed auxiliary device, but it is costly, and solvent absorption expense is low, but poor processing effect.
Summary of the invention
Shortcoming present in view of the above technology, the present invention provide a kind of microorganism bubble liquid and preparation method thereof, Exhaust gas, waste liquid are handled using microorganism, with applied widely, cost of investment is low, exhaust gas removal effect is good, safety The advantages that high.
To achieve the above object, the present invention provides a kind of microorganism bubble liquid, which is characterized in that according to weight percent Meter, each component are as follows:
Foaming agent: 1.6-20%;
Moisturizer: 1-5%;
Bubble film forming agent: 1-10%;
Nutriment: 0.2-5.5%;
Plant extraction liquid 35-50%;
Active bacteria 0.01-0.5%;
Deionized water 26.5-50%.
Preferably, in percentage by weight, the component of optimal practical range is as follows:
Foaming agent: 4-5%;
Moisturizer: 2-3%;
Bubble film forming agent: 1-3%;
Nutriment: 0.7-1.3%;
Plant extraction liquid: 40.2-48%;
Active bacteria: 0.1-0.5%;
Deionized water: 35-50%.
Preferably, the foaming agent is polyoxyethylene fatty alkyl ether sulfonate, neopelex, dodecyl Sodium sulphate, coconut oleoyl amine DEA, coconut oleoyl amine MEA, dodecyldimethylamine oxide, Cocoamidopropyl betaine, dodecane Base dimethyl betaine, α-one of sodium olefin sulfonate and alkyl glucoside or a variety of mixing.
Preferably, the moisturizer is one of glycerol, propylene glycol, polyethylene glycol and D-sorbite or a variety of mixed It closes.
Preferably, the bubble film forming agent is polyvinyl alcohol, polyethylene glycol oxide, hydroxyethyl cellulose, hydroxypropyl methyl One of cellulose and sodium carboxymethylcellulose or a variety of mixing.
Preferably, the nutriment includes one of albumen powder, sucrose and fructose or a variety of mixing
Preferably, it is characterized in that, the plant extraction liquid be ginger active extract, it is garlic active extract, green Tea active extract, dark green tea active extract, pomelo peel active extract, lemon active extract, sweet orange active extract, eucalyptus One of leaf oil, camphor tree leaf oil or a variety of mixing.
Preferably, the active bacteria be one of methane backeria, actinomyces, vulcanization bacterium, nitrifier and saccharomycete or A variety of mixing.
The invention also discloses a kind of preparation methods of microorganism bubble liquid, are applied to described in any item microorganisms above Bubble liquid, comprising the following steps:
S1: under normal temperature and pressure, deionized water being added in agitator tank, and foaming agent is then added and is stirred, until completely Dissolution;
S2: and then moisturizer, bubble film forming agent, sucrose, albumen powder, plant extract agent are added to agitator tank and stirred It mixes, until being uniformly mixed;
S3: then access active bacteria is slowly stirred and stands after twenty minutes, obtains translucent microorganism bubble liquid.
The invention also discloses a kind of applications of microorganism bubble liquid, after the above method obtains microorganism bubble liquid, Bubble liquid is added in big gun machine processed, production obtains the microorganism bubble of diameter 5nm-100cm, then by the microorganism bubble Enter exhaust gas waste water engineering by airflow circulating, air-flow and water flow is followed to move together.
The beneficial effects of the present invention are: the present invention has merged solvent adsorption method, microbial degradation method, plant deodorization method first Three kinds of processing methods, greatly enhance treatment effect;Secondly, bubble surface area is big, it is identical compared with solvent absorption The solvent of quality, bubble are contacted than directly carrying out atomizing spray with solvent with the effective of exhaust gas with effective contact area of exhaust gas Area is much bigger, and assimilation effect is relatively more preferable;Then, after bubbles burst enter wastewater disposal basin in, microorganism therein also therewith into Entering into pond, microorganism can continue the organic matter in Decomposition Wastewater, so that the COD content of waste water is reduced, it can to exhaust gas and waste water To reach treatment effect simultaneously;Finally, investment cost is low, operational degree is simple.
Specific embodiment
In order to more clearly state the present invention, the present invention is further described combined with specific embodiments below, especially It states, embodiment cited by the present invention is only specific embodiment, does not represent whole embodiments of the invention, this field Technical staff use other compositions, but the technical effect reached is same as the present application, all should belong to the protection model of the application It encloses.
The main function of each ingredient is as follows in the present invention:
Foaming agent: the surface tension of liquid can be effectively reduced in foaming agent surface-active with higher, and on liquid film surface Electric double layer arranges and surrounds air, forms bubble, then laughed at oneself foam by multiple single isolated bubbles.
Moisturizer: enhance the toughness of bubble, be not easily broken it.
Plant extract agent: for different plants, taking different extracting modes, and garlic or ginger are cleaned and used after draining After flash extracter processing, 90% methanol or ethanol solution of 6 times of volumes is added, handles 1-3 minutes, after separation of solid and liquid, recycling Methanol or ethanol solution, concentration are recycled molten so that extract is in paste, then is saturated with water n-butanol and extracts 3 times to extract After agent, extract is concentrated in vacuo drying, obtains garlic, ginger or aloe extract;By green tea, dark green tea or lemon, pomelo peel, Sweet orange, which is cleaned to drain to be placed in micronizer, carries out CO2 supercritical extract after crushing, fluid extraction pressure is 30-50MPa, 30-40 DEG C of extraction temperature, CO2 fluid flow is 750-850L/h, and extraction time 3-5h obtains corresponding extract;Folium eucalypti and Camphortree leaf crushes after cleaning, and using steam distillation, circulation extracts separation, until being distilled out of by separation combination, flow back drop Stop heating when middle no oil droplet, obtains corresponding eucalyptus oil or camphor tree liquid oil;It dissolves, obtains corresponding by extract obtained Vegetable active extracting solution.
The present invention mainly utilizes the very high functional compounds of reactivity and terpenoid in plant extraction liquid, such as Use the allicin in garlic;Gingerol and salad oil in ginger extract;Citral and limonene in lemon extract, Limonene in green tea or tea polyphenols and pomelo peel extracting solution in dark green tea extracting solution;Folium eucalypti in eucalyptus oil and camphor tree leaf oil Element and camphor;These compounds form diameter very little but highly active molecule after bubbles burst, in these molecules and exhaust gas Odor molecules collide and the chemical bond that destroys in odor molecules promotes its decomposition, and using similar compatibility absorb and Dissolution;Also with acidic oxides such as carbon, nitrogen, sulphur in exhaust gas neutralization reaction occurs for alkaloid in plant extraction liquid,
Nutriment: generally glucose and albumen powder provide required nutritional ingredient for active bacteria initial stage proliferation.
Active bacteria: actinomyces are Gram-positive strains, belong to prokaryotes monoid, actinomyces for steroid transformation, Hydro carbons fermentation and sewage treatment etc.;Methane backeria belongs to prokaryotes, by passing through fermentation using carbon compound as receptor Debirs are converted methane by effect;Hydrogen sulfide and sulfur-containing amino acid etc. are eventually formed sulfuric acid by oxidation of sulfide-oxidizing enzyme or so Salt;Nitrobacter is in one kind of self-operation microorganism, by nitrobacteria, can effectively reduce the content of ammonia nitrogen in waste water;Yeast Carbohydrate breakdown can be alcohol and carbon dioxide by bacterium, be a kind of natural leavening.
Embodiment one:
By deionized water 487g, fatty alcohol vinethene sodium sulfonate 15g, lauryl sodium sulfate 20g, coconut oleoyl amine DEA5g It is added in agitator tank, turn on agitator is stirred to all raw materials using the rate of 400r/min and is all completely dissolved, then by glycerol 20g, propylene glycol 10g, polyvinyl alcohol 15g, sucrose 5g, albumen powder 2g, green tea extractive liquor 110g, ginger extract 200g, dark green tea Agitator tank is added in extracting solution 110g, is slowly stirred after twenty minutes, and access vulcanization strain 0.5g then heats to 70 degrees Celsius, training Cooling processing is carried out after supporting 3 hours, temperature is reduced to 25 degrees centigrades, access nitrifies strain 0.2g, after culture 2 hours again Barms 0.3g is accessed, after being warming up to 37 degrees Celsius of closings cultures 3 hours, obtains 1000g microorganism bubble liquid.
Embodiment two:
By deionized water 495g, polyoxyethylene fatty alkyl ether sulfonate 30g, lauryl sodium sulfate 10g, coconut oleoyl amine DEA10g is added in agitator tank, and turn on agitator is stirred to all raw materials using the rate of 400r/min and all dissolved, then by mountain Pears sugar alcohol 10g, glycerol 10g, hydroxyethyl cellulose 10g, polyvinyl alcohol 10g, sucrose 10g, albumen powder 3g, lemon extract 200g, eucalyptus oil 200g are slowly stirred access unwrapping wire strain 1g, methane strain 1g after twenty minutes, agitator tank are added, then carries out Heating treatment is sealed, 37 degrees centigrades are raised the temperature to, after cultivating 5-8 hour, standing obtains 1000g bacterial gas Steep liquid.
Real-time example three:
By deionized water 402g, polyoxyethylene fatty alkyl ether sulfonate 20g, lauryl sodium sulfate 20g, coconut oleoyl amine DEA5g is added in agitator tank, and turn on agitator is stirred to all raw materials using the rate of 400r/min and is all completely dissolved, then It is raw by polyethylene glycol 10g, glycerol 10g, propylene glycol 10g, polyvinyl alcohol 30g, sucrose 5g, albumen powder 3g, green tea extractive liquor 200g Agitator tank is added in ginger extracting solution 200g, pomelo peel extracting solution 80g, and stirring is stood after twenty minutes, and access vulcanization strain 1g is warming up to 70 degrees Celsius, temperature is reduced to 25 degrees centigrades after 2 hours, and access nitrification strain 2g after culture 3 hours, then accesses ferment Female strain 1g and methane strain 1g, is sealed heating, raises the temperature to 37 degrees centigrades, and it is micro- to obtain 1000g after 3 hours Biological bubble liquid.
The microorganism bubble liquid obtained in above-described embodiment is added in big gun machine processed, production obtains diameter 5nm-100cm Microorganism bubble, microorganism bubble is then entered into exhaust gas waste water engineering by airflow circulating, follows air-flow and water flow together Movement, the specific diameter of the bubble of microorganism according to the degree of exhaust gas waste water can unrestricted choice, if in waste water and gas pollutant compared with Microorganism bubbles that are more, selecting diameter small;If pollutant is less, with regard to the microorganism bubble for selecting to be relatively large in diameter.
When exhaust gas enters in environment-friendly engineering, exhaust gas is wrapped in microorganism bubble, is wrapped up in each microorganism bubble Have an a large amount of exhaust emission, when pollution molecule is handled by microorganism bubble, due to microorganism bubble have certain viscosity and Hardness, when being moved with exhaust gas contact, while and other microorganism bubble hits after blow, the microorganism bubble after blowing, Automatically drop to environment-friendly engineering or device bottom, under suitable environment microbial growth effectively decompose VOC, ammonia, hydrogen sulfide, COD, total phosphorus, phosphate and ammonia-nitrogen content in benzene, dimethylbenzene, non-methane total hydrocarbons and waste water, selectivity add active bacteria, Plant extraction liquid in microorganism bubble passes through a series of physical such as various polymerizations, substitution, displacement, absorption and decomposition or chemistry instead Odorous gas molecule should be removed.
Shown in the following table of the treatment effect of embodiment 1-3:
From in above data it can be seen that with plant extract liquid hold-up in microorganism bubble liquid increase, VOC (is waved Hair property organic matter), dust, ammonia, hydrogen sulfide, benzene, the removal effect of dimethylbenzene and non-methane total hydrocarbons it is better, with heating bubble liquid The increase of middle active bacteria content, it is higher to the removal rate of COD (COD), total phosphorus and ammonia nitrogen.
Disclosed above is only several specific embodiments of the invention, but the present invention is not limited to this, any ability What the technical staff in domain can think variation should all fall into protection scope of the present invention.

Claims (10)

1. a kind of microorganism bubble liquid, which is characterized in that in percentage by weight, each component is as follows:
Foaming agent: 1.6-20%;
Moisturizer: 1-5%;
Bubble film forming agent: 1-10%;
Nutriment: 0.2-5.5%;
Plant extraction liquid 35-50%;
Active bacteria 0.01-0.5%;
Deionized water 26.5-50%.
2. microorganism bubble liquid according to claim 1, which is characterized in that in percentage by weight, optimal implementation model The component enclosed is as follows:
Foaming agent: 4-5%;
Moisturizer: 2-3%;
Bubble film forming agent: 1-3%;
Nutriment: 0.7-1.3%;
Plant extraction liquid: 40.2-48%;
Active bacteria: 0.1-0.5%;
Deionized water: 35-50%.
3. microorganism bubble liquid according to claim 1, which is characterized in that the foaming agent is fatty alcohol polyoxyethylene ether Sodium sulfonate, neopelex, lauryl sodium sulfate, coconut oleoyl amine DEA, coconut oleoyl amine MEA, dodecyl dimethyl Amine oxide, Cocoamidopropyl betaine, dodecyldimethylammonium hydroxide inner salt, one in α-sodium olefin sulfonate and alkyl glucoside Kind or a variety of mixing.
4. microorganism bubble liquid according to claim 1, which is characterized in that the moisturizer is glycerol, propylene glycol, poly- second One of two pure and mild D-sorbites or a variety of mixing.
5. microorganism bubble liquid according to claim 1, which is characterized in that the bubble film forming agent is polyvinyl alcohol, gathers One of ethylene oxide, hydroxyethyl cellulose, hydroxypropyl methyl cellulose and sodium carboxymethylcellulose or a variety of mixing.
6. microorganism bubble liquid according to claim 1, which is characterized in that the nutriment includes albumen powder, sucrose With one of fructose or a variety of mixing.
7. microorganism bubble liquid according to claim 1, which is characterized in that the plant extraction liquid is the extraction of ginger activity Liquid, garlic active extract, green tea active extract, dark green tea active extract, pomelo peel active extract, lemon activity are extracted One of liquid, sweet orange active extract, eucalyptus oil, camphor tree leaf oil or a variety of mixing.
8. microorganism bubble liquid according to claim 1, which is characterized in that the active bacteria be methane backeria, actinomyces, Vulcanize one of bacterium, nitrifier and saccharomycete or a variety of mixing.
9. a kind of preparation method of microorganism bubble liquid is applied to the described in any item microorganism bubble liquid of claim 1-8, It is characterized in that, comprising the following steps:
S1: under normal temperature and pressure, deionized water being added in agitator tank, and foaming agent is then added and is stirred, until being completely dissolved;
S2: and then moisturizer, bubble film forming agent, sucrose, albumen powder, plant extract agent are added to agitator tank and be stirred, directly Extremely it is uniformly mixed;
S3: then access active bacteria is slowly stirred and stands after twenty minutes, obtains translucent microorganism bubble liquid.
10. a kind of application of microorganism bubble liquid, which is characterized in that obtain microorganism bubble liquid by method for claim 9 Afterwards, bubble liquid is added in big gun machine processed, production obtains the microorganism bubble of diameter 5nm-100cm, then by the microorganism Bubble enters exhaust gas waste water engineering by airflow circulating, and air-flow and water flow is followed to move together.
CN201811580524.7A 2018-12-24 2018-12-24 A kind of microorganism bubble liquid and its preparation method and application Pending CN109847572A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180378A (en) * 2019-06-18 2019-08-30 广州亿奇科技股份有限公司 A kind of efficient deodorizing composition and its production method
CN110721561A (en) * 2019-11-07 2020-01-24 深圳市淳睿科技发展有限公司 Environment-friendly enzyme, preparation method and application thereof
CN110813077A (en) * 2019-11-07 2020-02-21 深圳市淳睿科技发展有限公司 Environment-friendly deodorant enzyme, and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015126269A1 (en) * 2014-02-19 2015-08-27 Instytut Biochemii I Biofizyki Polskiej Akademii Nauk Method for synthesis of a biopolymer derivative, a biopolymer derivative and its use
CN105413421A (en) * 2015-11-05 2016-03-23 菏泽鑫鼎环境工程设备有限公司 SO2 and dust comprehensive treatment absorber
CN105536509A (en) * 2015-12-22 2016-05-04 湖南普泰尔微科环保科技有限公司 Plant extract and microbe composite deodorant
WO2018014919A1 (en) * 2016-07-21 2018-01-25 Biogasclean A/S Process and apparatus for removal of hydrogen sulphide from a gas

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015126269A1 (en) * 2014-02-19 2015-08-27 Instytut Biochemii I Biofizyki Polskiej Akademii Nauk Method for synthesis of a biopolymer derivative, a biopolymer derivative and its use
CN105413421A (en) * 2015-11-05 2016-03-23 菏泽鑫鼎环境工程设备有限公司 SO2 and dust comprehensive treatment absorber
CN105536509A (en) * 2015-12-22 2016-05-04 湖南普泰尔微科环保科技有限公司 Plant extract and microbe composite deodorant
WO2018014919A1 (en) * 2016-07-21 2018-01-25 Biogasclean A/S Process and apparatus for removal of hydrogen sulphide from a gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180378A (en) * 2019-06-18 2019-08-30 广州亿奇科技股份有限公司 A kind of efficient deodorizing composition and its production method
CN110721561A (en) * 2019-11-07 2020-01-24 深圳市淳睿科技发展有限公司 Environment-friendly enzyme, preparation method and application thereof
CN110813077A (en) * 2019-11-07 2020-02-21 深圳市淳睿科技发展有限公司 Environment-friendly deodorant enzyme, and preparation method and application thereof

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Application publication date: 20190607