CN109706328A - 一种金属镍酸溶解液反萃负载镍钴锰有机相制备三元料液的方法 - Google Patents
一种金属镍酸溶解液反萃负载镍钴锰有机相制备三元料液的方法 Download PDFInfo
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- CN109706328A CN109706328A CN201910099990.1A CN201910099990A CN109706328A CN 109706328 A CN109706328 A CN 109706328A CN 201910099990 A CN201910099990 A CN 201910099990A CN 109706328 A CN109706328 A CN 109706328A
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- nickel
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 165
- 239000002253 acid Substances 0.000 title claims abstract description 51
- 239000007788 liquid Substances 0.000 title claims abstract description 51
- 238000000605 extraction Methods 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000012074 organic phase Substances 0.000 title claims abstract description 38
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 62
- 229910052742 iron Inorganic materials 0.000 claims abstract description 34
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 29
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 12
- 239000010941 cobalt Substances 0.000 claims abstract description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 239000011572 manganese Substances 0.000 claims abstract description 8
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 230000008929 regeneration Effects 0.000 claims abstract description 6
- 238000011069 regeneration method Methods 0.000 claims abstract description 6
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000010790 dilution Methods 0.000 claims description 9
- 239000012895 dilution Substances 0.000 claims description 9
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 7
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 10
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- QSNQXZYQEIKDPU-UHFFFAOYSA-N [Li].[Fe] Chemical compound [Li].[Fe] QSNQXZYQEIKDPU-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229960004887 ferric hydroxide Drugs 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- -1 hydrogen Nickel oxide Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical group [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112322894A (zh) * | 2020-10-29 | 2021-02-05 | 格林美(江苏)钴业股份有限公司 | 一种镍钴锰三元素共萃取提纯除杂方法 |
CN112941338A (zh) * | 2019-12-11 | 2021-06-11 | 格林美(江苏)钴业股份有限公司 | 一种共萃取富集混合溶液中镍钴的方法 |
CN113046574A (zh) * | 2021-03-17 | 2021-06-29 | 沈阳有色金属研究院有限公司 | 一种利用铜电解脱铜后液处理粗氢氧化钴制备高纯镍、钴产品的方法 |
CN114058850A (zh) * | 2021-11-04 | 2022-02-18 | 中南大学 | 一种从烧结镍合金体中浸出镍的工艺 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101450815A (zh) * | 2008-10-07 | 2009-06-10 | 佛山市邦普镍钴技术有限公司 | 一种以废旧锂离子电池为原料制备镍钴锰酸锂的方法 |
CN101898802A (zh) * | 2010-07-23 | 2010-12-01 | 陕西华泽镍钴金属有限公司 | 从低品位钴渣提取钴生产氯化钴的方法 |
CN102557153A (zh) * | 2010-12-28 | 2012-07-11 | 上海轻工业研究所有限公司 | 一种从硫酸镍溶液中去除钙镁杂质的方法 |
CN105206889A (zh) * | 2015-07-29 | 2015-12-30 | 刘嘉因 | 一种废旧镍钴锰酸锂三元电池正极材料的处理方法 |
CN106319228A (zh) * | 2016-08-26 | 2017-01-11 | 荆门市格林美新材料有限公司 | 一种从含镍钴锰废渣中同步回收镍钴锰的方法 |
CN106505272A (zh) * | 2016-12-12 | 2017-03-15 | 江西赣锋锂业股份有限公司 | 一种锂电池正极材料废料的处理方法 |
CN108517409A (zh) * | 2018-04-04 | 2018-09-11 | 长沙矿冶研究院有限责任公司 | 一种从废旧动力电池正极废料中回收有价金属的方法 |
-
2019
- 2019-01-31 CN CN201910099990.1A patent/CN109706328B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101450815A (zh) * | 2008-10-07 | 2009-06-10 | 佛山市邦普镍钴技术有限公司 | 一种以废旧锂离子电池为原料制备镍钴锰酸锂的方法 |
CN101898802A (zh) * | 2010-07-23 | 2010-12-01 | 陕西华泽镍钴金属有限公司 | 从低品位钴渣提取钴生产氯化钴的方法 |
CN102557153A (zh) * | 2010-12-28 | 2012-07-11 | 上海轻工业研究所有限公司 | 一种从硫酸镍溶液中去除钙镁杂质的方法 |
CN105206889A (zh) * | 2015-07-29 | 2015-12-30 | 刘嘉因 | 一种废旧镍钴锰酸锂三元电池正极材料的处理方法 |
CN106319228A (zh) * | 2016-08-26 | 2017-01-11 | 荆门市格林美新材料有限公司 | 一种从含镍钴锰废渣中同步回收镍钴锰的方法 |
CN106505272A (zh) * | 2016-12-12 | 2017-03-15 | 江西赣锋锂业股份有限公司 | 一种锂电池正极材料废料的处理方法 |
CN108517409A (zh) * | 2018-04-04 | 2018-09-11 | 长沙矿冶研究院有限责任公司 | 一种从废旧动力电池正极废料中回收有价金属的方法 |
Non-Patent Citations (1)
Title |
---|
易爱飞: "废旧三元电池正极活性材料盐酸浸出液中钴锰共萃取分离镍锂", 《有色设备》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112941338A (zh) * | 2019-12-11 | 2021-06-11 | 格林美(江苏)钴业股份有限公司 | 一种共萃取富集混合溶液中镍钴的方法 |
CN112322894A (zh) * | 2020-10-29 | 2021-02-05 | 格林美(江苏)钴业股份有限公司 | 一种镍钴锰三元素共萃取提纯除杂方法 |
CN113046574A (zh) * | 2021-03-17 | 2021-06-29 | 沈阳有色金属研究院有限公司 | 一种利用铜电解脱铜后液处理粗氢氧化钴制备高纯镍、钴产品的方法 |
CN113046574B (zh) * | 2021-03-17 | 2022-07-29 | 沈阳有色金属研究院有限公司 | 一种利用铜电解脱铜后液处理粗氢氧化钴制备高纯镍、钴产品的方法 |
CN114058850A (zh) * | 2021-11-04 | 2022-02-18 | 中南大学 | 一种从烧结镍合金体中浸出镍的工艺 |
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